The First Framework Solid Composed of Vanadosilicate Clusters.
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2003 Vanadium Vanadium I 5000 The First Framework Solid Composed of Vanadosilicate Clusters. — As revealed by single crystal XRD, (III) crystallizes in the tetragonal space group P4 2 /n with Z = 8 and (V) in the tetragonal space group P421/c with Z = 4. The isostructural cluster anions [V14O44(GeOH)8] 8- and [H4V14O44(SiO)8] 12- are present in the structures of (III) and (V), respectively, with the latter being bridged by (VO)O2N2 pyramids in three dimensions. — (TRIPATHI, A.; HUGHBANKS, T.; CLEARFIELD*, A.; J. Am. Chem. Soc. 125 (2003) 35, 10528-10529; Dep. Chem., Tex. A&M Univ., College Station, TX 77842, USA; Eng.) — W. Pewestorf 49- 025
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Transcript of The First Framework Solid Composed of Vanadosilicate Clusters.
2003 Vanadium
VanadiumI 5000 The First Framework Solid Composed of Vanadosilicate Clusters. — As revealed
by single crystal XRD, (III) crystallizes in the tetragonal space group P42/n with Z = 8 and (V) in the tetragonal space group P421/c with Z = 4. The isostructural cluster anions [V14O44(GeOH)8]8- and [H4V14O44(SiO)8]12- are present in the structures of (III) and (V), respectively, with the latter being bridged by (VO)O2N2 pyramids in three dimensions. — (TRIPATHI, A.; HUGHBANKS, T.; CLEARFIELD*, A.; J. Am. Chem. Soc. 125 (2003) 35, 10528-10529; Dep. Chem., Tex. A&M Univ., College Station, TX 77842, USA; Eng.) — W. Pewestorf
49- 025
