The Electronic Structure of the Atom

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    , .

    ().

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    ().

    F ,

    , .

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    E

    A

    : (),

    = 3.00108 /.

    ,

    =

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    N E

    .

    M

    .

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    N E

    E

    .

    H

    :

    =

    , 6.63 1034 J.

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    N E

    , ,

    , , :

    = =

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    N E

    A

    .

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    N E

    O ,

    .

    O

    .

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    N E

    N B

    :

    1. E

    ( ).

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    N E

    N B

    2. E ,

    ; .

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    N E

    N B :

    3. E ;

    =

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    N E

    :

    where RH is the Rydberg constant,

    2.18 x 1018

    J, and ni and nf are theinitial and final energy levels of the

    electron.

    E = RHnf

    2 ni

    2

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    (E A H)

    = 1

    J = 2

    F I = 3

    F F = 4

    A H = 5

    C J. = 6

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    N M L B , .

    H :

    , (, , .) (,, .) .

    =h

    mv

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    H

    ,

    .

    I , !

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    M

    G().

    , 2,

    .

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    N

    , , .

    E .

    A .

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    A N,

    .

    A 0 1.

    , , .

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    A N,

    Value of l 0 1 2 3

    Type of orbital s p d f

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    M N,

    D .

    , , 1 , 3, 5 , 7, .

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    M N,

    O .

    D .

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    O

    = 0.

    .

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    O

    O

    , 1

    , 0 .

    (N: .

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    O

    = 1.

    H .

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    O

    2.

    F 4

    .

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    E O

    F

    ,

    .

    ,

    .

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    E O

    A ,,

    .

    , , .

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    N,

    I 1920 (O G),

    .

    , .

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    N,

    , ,

    2 : +1/2 1/2.

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    E

    N .

    F , .

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    E C

    D

    .

    :N

    .

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    E C

    Distribution of all electrons in an

    atom.

    Electron configurations consist of:

    Number denotin the ener

    level. Letter denoting the type of

    orbital.

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    E C

    D .

    E :

    N .

    L .

    .

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    O D

    E .

    H .

    .

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    H

    F

    ,

    .

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    A

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    A. F

    A

    ( ) ,

    .

    A /,

    .

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    F

    , .

    . H .

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    F (1)

    F ,

    .

    .

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    IE C M ()

    .

    .

    F ,

    .

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