The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic...
-
date post
20-Dec-2015 -
Category
Documents
-
view
218 -
download
3
Transcript of The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic...
![Page 1: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/1.jpg)
The Bottom-up ApproachThe Bottom-up Approach
• Weak interactions between molecules
• Vesicles and micelles
• Thermodynamic aspects of self-assembling nanostructures
• Self-assembled molecular monolayers
• Kinetic control of growth: nanowires and quantum dots
Copyright Stuart Lindsay 2008
![Page 2: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/2.jpg)
C60C60C70C70
![Page 3: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/3.jpg)
![Page 4: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/4.jpg)
![Page 5: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/5.jpg)
![Page 6: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/6.jpg)
![Page 7: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/7.jpg)
Single wallSingle wall
Multi wallMulti wall
Graphene Graphene sheetssheets
![Page 8: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/8.jpg)
![Page 9: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/9.jpg)
![Page 10: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/10.jpg)
Molecular carrier Molecular carrier and storageand storage
Charge transportCharge transport
Molecular wiresMolecular wires
![Page 11: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/11.jpg)
![Page 12: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/12.jpg)
•Drug delivery• Nucleic acid and protein sensing
![Page 13: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/13.jpg)
K. A. Williams, P. T. M. Veenhuizen, B. G. de la Torre, R. Eritja and C. Dekker Nature 420, 761(2002)
![Page 14: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/14.jpg)
![Page 15: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/15.jpg)
![Page 16: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/16.jpg)
![Page 17: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/17.jpg)
![Page 18: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/18.jpg)
Emission 530 nm
N N
N
N
N
N
Me2N
Me2N
Me2N
Me2NNMe2
NMe2
NMe2
N
N
NN
N
N
N N
NMe2
SO2 SO2
SO2
SO2
O2S
O2S O2S
O2S
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
OO
O
O
O
O
OO
OO
OOO
O
O
O
O
O
O
O
O
O
O
O
O
O
O O
OO O
O
O
COOHBr Br
BrBrOHO
Eosin
E
DansNaph
UV abs
hh’’
Angew. Chem. Int. Ed. 2002, 41, 3595
![Page 19: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/19.jpg)
![Page 20: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/20.jpg)
Un motore lineare che funziona con energia chimica
Stazioneammonio
Stazionebipiridinio
_ H+
+ H+
O
O
O
O O
O
O
OH2N
N
N+
+
+
_ H+
+ H+
A linear motor driven by chemical energyA linear motor driven by chemical energy
Ammoniumstation
Piridiniumstation
![Page 21: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/21.jpg)
![Page 22: The Bottom-up Approach Weak interactions between molecules Vesicles and micelles Thermodynamic aspects of self-assembling nanostructures Self-assembled.](https://reader036.fdocuments.in/reader036/viewer/2022062421/56649d405503460f94a1a84d/html5/thumbnails/22.jpg)
An artificial nanomotor driven by solar lightAn artificial nanomotor driven by solar light
Balzani, Leon, Credi, Ferrer, Venturi, Flood, Stoddart, PNAS, Jan 23, 2006