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    Fatal Incident Involving aTemporary Enclosure at a

    Chemical Facility

    From an OSHA Technical Information

    Bulletin

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    Purpose

    Provide information

    Hazard alert

    Requirements and regulations

    Recommendations and guidance

    Other information

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    Incident Description

    Facility unit undergoing a turnaround.

    2 workers to inspect the flange surfaces

    of an open 48-inch piping system. Piping system opened to remove a

    piece of process equipment for

    cleaning.

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    Black Tarp

    48 Pipe

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    Incident Description

    Plastic-wrapped pipe

    New moisture-sensitive catalystupstream

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    Incident Overview

    N2

    Injection

    Reactor w/newcatalyst

    Open 48"Piping

    Open Valve

    Closed Valve

    N2

    Venting

    Note: Actual process/piping significantly more complex. N2 injection

    point 150' and several stories in elevation from pipe opening.

    North

    South

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    Incident Overview

    NitrogenPurge

    Reactor with

    Catalyst

    Open valvesto north sideopen piping

    In-Line Mixer (removed)

    Black Tarp

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    Incident Description

    Southside open pipe & enclosure

    Midday black light inspection.

    Black tarps draped to block light. Workers entered enclosure.

    No problems with inspection.

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    Incident Description

    North side open pipe & enclosure

    Midday backlight inspection.

    Black tarps draped to block light. Workers entered enclosure.

    Workers overcome upon entering.

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    Incident Conclusions

    One worker died, another hospitalized.

    N2 throughout system.

    Piping system was not straightforward. OSHA cited the employer for 1910.146

    Permit-Required Confined Space

    violations.

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    Permit Required

    Confined Space Hazards

    Oxygen deficiency

    Flammable atmosphere

    Toxic atmosphere

    Oxygen enrichment

    Chemical exposure

    Thermal hazards

    Electrical shock

    Temperature extremes

    Engulfment

    Mechanical hazards

    Trapping/Pinch points

    Physical hazards

    Slips, Trips, Falls

    Unstable working surface

    Structural failure

    Other recognized hazards

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    Nitrogen Hazard

    Cant be detected by human senses

    N2 displaces oxygen in enclosures

    (confined spaces) resulting in oxygen-deficient atmospheres

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    Human Response to Oxygen-

    Deficient Atmospheres

    Atmospheric Oxygen

    Concentration [%O2]Possible Consequences

    19.5Meets OSHA minimum requirements for

    worker protection

    8-10

    Unconsciousness without warning; so

    quickly that individuals cannot help or

    protect themselves

    6-8 Fatal injury < 6 minutes

    4-6 Coma < 40 seconds with subsequent death

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    Requirements, Recommendations

    & Guidance

    If space meets the definition of a PRCS,must follow 1910.146.

    Even if not technically a PRCS, 1910.146

    recommended. Other OSHA standards may apply:

    1910.134 Respiratory Protection IDLH Atmospheres

    Recognition that temporary enclosures maybe PRCSs.

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    Requirements, Recommendations,

    & Guidance

    Comprehensive confined space

    training.

    Particular attention on hazardousatmospheres

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    Related Information

    OSHA Technical Information Bulletin onincident at: http://www.osha.gov

    CSB Morten Report at:http://www.csb.gov/reports/1998/union_carbide/98005lafr.htm

    OSHA PRCS Standard, Directive andInterpretation at: http://www.osha.gov