German Society for Petroleum and CoalScience and Technology

Tagungsbericht 2003-2

Proceedings of the DGMK-Conference“Innovation in the Manufacture and

Use of Hydrogen”October 15 - 17, 2003, Dresden, Germany

(Authors' Manuscripts)

edited by G. Emig, S. Ernst, K. Harth & M. Rupp

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CONTENTS

Meeting Future Needs for Hydrogen — Possibilities andChallengesG. Q. Miller, D. W. Penner

Hydrogen Production Technology — Status and NewDevelopmentsH. Ranke, N. Schdédel

Novel Sol-Gel Derived Catalyst Systems for High-Temperature Partial Oxidation of MethaneM. Kirchhoff, U. Specht, G. Veser

Hydrogen with Intrinsic CO, Sequestration:The ENI “One Step Hydrogen” ProcessS. Rossini, U. Cornaro, F. Mizia, A. Malandrino, V. Piccoli,D. Sanfilippo, I. Miracca

Novel Cu/ZnO and Cu/ZrO,-Catalysts for Methanol Synthesisand Steam Reforming|. Ritzkopf, C. Kiener, S. Vukojevic, R. Brinkmann, H. Bónnemann.F. Schüth

Separation of Hydrogen from Dilute Streams(e.g. Using Membranes)H. E. A. Brüschke

Optimised Hydrogen Production — A Key Process BecomingIncreasingly Important in RefineriesJ. Bezler

The BP / Davy compact reformer — the syngas adventureJ. J. H. M. Font Freide, T. Gamlin

Refinery Hydrogen Management - The Big PictureA. Zagoria, R. Huycke, P. Boulter

Hydrogen Management in the MiRO RefineryG. Neumann

Fuel Cell Plants for Large Scale ApplicationsM. Gnann

Internal Steam Reforming in Molten Carbonate Fuel CellsP. Heidebrecht, M. Gundermann, K. Sundmacher

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New Catalysts for an Old Molecule — The Challenge toproduce Hydrogen for Fuel CellsM. Hoelzle, H. Wessel, C. Kuhrs, M. Hesse, N. Wilden

Short contact time methane partial oxidationI. Tavazzi, A. Beretta. G. Groppi, P. Forzatti

On-Board Hydrogen Production for Fuel Cell Applications Uin VehiclesD. zur Megede, M. Sommer

K doped Ni/MgO catalyst: a suitable catalytic system forhydrogen production by steam reforming of bio-ethanolF, Frusteri, S. Freni, V. Chiodo, L. Spadaro, G. Bonura, S. Cavallaro

Autothermal Reforming of Methane over Mono- and Bi-metal aCatalysts Prepared from Hydrotalcite-like PrecursorsK. Nagaoka, A. Jentys, J. A. Lecher

Generation of Hydrogen from Renewable ResourcesD. Volkmann, M. Schingnitz

Make the best out of your Hydrogen PlantS. Ratan, W. Konter

Combined Production of Hydrogen, Clean Powerand Quality FuelsA. Rojey, A. Minkkinen, J.-P. Arlie, E. Lebas

Large-scale Hydrogen Plants. Uhde and UOP's ExperienceM. Michel, M. Whysall

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POSTERSESSION

Production of Hydrogen by Catalytical Decomposition ofWatermethanol MixturesA. L. Lapidus, S. N. Antonyuk, V. I. Yakerson, E. Z. Golosman

Is the Production of Hydrogen and Propylene From Methaneand Ethylene Feasible?Y. Traa, D. Singer

Features and Potential of the Multipurpose Ni/MgO CatalyticSystem for Making Hydrogen from Methane and HigherHydrocarbonsF. Arena, A. Parmaliana

IR study on methanol steam reforming for onboard hydrogen Mgeneration in the field of fuel cell technologyF. Kiesslich, M. A. Liauw, N. Popovska, G. Emig

Production of hydrogen by reforming of bioethanol in atwo-layer fixed bed reactor for fuel cell applicationsV. Galvita, K. Sundmacher

New Innovative Catalysts for Fuel ProcessorsH. Wessel, M. Hoelzle, C. Kuhrs, M. Hesse

Steam Reforming of Light Alkanes in Micro-StructuredReactorsJ. Find, K. Nagaoka, J. A. Lercher

Hydrogen from Methanol using Microstructured ReactorsP. Pfeifer K. Schubert, M. A. Liauw, G. Emig

Combined autothermal reforming and hydrogenolysis ofalkanesM. Brandmair, J. Find, J. A. Lercher

Hydro cracking of n-paraffins produced from synthesis gasA. L. Lapidus, A. J. Krylova, M. V. Tsapkina

Study of the Nickel-Molybdenum Containing Forms of AI-MCM-41/ZSM-5 Materials for the Hydrocracking of n-DecaneA. Klemt, W. Reschetilowski

Bimetallic Clusters Supported on ALMCM-41 as Catalysts for UIsomerization and Hydrocracking of n-DecaneS. P. Elangovan, L. Iniesta, M. Hartmann

CO, Hydrogenation over Metal Supported on Carbon FeitA. Lapidus, A. Krylova, L. Tishkova, Ya. Durandina, N. Gaigai

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The Relevance of Metal-Support Interactions to the Synthesis 277of Methanol and the Water-Gas Shift ReactionH. Wilmer, M. Kurtz, O. Hinrichsen, M. Muhler

Hydrogen-free Deep Desulphurization of Diesel Oil byExtraction with lonic LiquidsA. Jess, P. Wasserscheid, J. ERer

Improvement of the Deep Desulphurization of Diesel Oil byPre-saturation and a Recycle of the Liquid PhaseL. Datsevitch, N. J. Gudde, A. Jess, C. Schmitz

Experimental and Theoretical Studies on Hydrogenation ofOlefins in Multiphase Fixed Bed ReactorsB. Battsengel, L. Datsevitch, A. Jess

Hydrogenation of Maleic Anhydride over Noble Metal-Containing ZeolitesS. Ost, M. Hartmann, S. Ernst

Investigation of different catalysts for autothermal reformingof i-octaneH. Ehwald, U. Kürschner, Q. Smejkal, H. Lieske

Promoting effect of H, in low temperature selective reduction 7of NO by propane over Ag/ALO,: A catalytic and in situ FTIR-spectroscopic studyU. Bentrup, M. Richter, R. Fricke