T Br KB Br Br - CSUSM
2
T Brees Br KB Br Br Hot Hn Br N m Br Hoy ne n Br p t.BHzi.tl s Emit 2 those 011 ion Baat N in catalyst 11702 Pdk y y N 2 Hey NHz Pdk NY I
Transcript of T Br KB Br Br - CSUSM
T Brees Br KBBr Br
HotHnBr N mBr
Hoyne nBr
p t.BHzi.tl sEmit
2those011 ion Baat
N incatalyst11702Pdk
yy N 2 Hey NHz
PdkNY I
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Bromination/Chlorination
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NBS
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Hydration
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Hydroboration
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Hydrogenation
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CHEM 201: Reactions of Alkenes
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Stereospecific > Anti addition: attack from opposite sides of the plane
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Markovnikov: OH goes to more substituted carbon
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Syn Addition: attack from same sideAnti-Markovnikov: OH goes to less substituted carbon
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Reduction H-HCatalyst usedSyn Addition
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Radical Reaction
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Basic Conditions
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Reacts
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Reacts
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Does not react
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Radical Substitution, electrophilic addition, electrophilic subsititution
984 to enantiomer
in As INftIaenantiomer
in 7 0OH
N Fino o coz om o
IN to0
A 3 in t.IE3ah
it's ka
itcHzI IF7nccu Zn Iz
µ HBS µHzf2 frfr HBr BrynCHIK
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Oxidations (O,N,Cl) (or removing H)
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Stronger Oxidation
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Ozone
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Carbenes
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Mirror
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Syn AdditionDiols: alcohol with two hydroxyl groups
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Anti AdditionTrans Diols: alcohol with two trans hydroxyl groups
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Formaldehyde from
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KMnO4:KetonesCarboxylic AcidsCO2
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Ozonolysis:KetonesAldehydesFormaldehyde
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Simmons-Smith Reaction
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H2O2 = Anti Markovnikov
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Mild Base
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Simmons-Smith Reaction
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Double Bond Cleavage
