Synchrotron Based Techniques for Fuel Cell...
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Synchrotron Based Techniques for Fuel Cell Applications
Mohammad Norouzi Banis
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Research Background
Catalyst Pt and Pt Alloys
Catalyst Support Carbon Powder
Electrocatalyst
Challenges: High Cost
Pt Price Low Durability and Stability
Pt Agglomeration Support Degradation
Slow Reactions Oxygen Reduction Reaction
Nanostructured Catalysts Nanostructured Pt:
Nanoparticles, Nanowires, … Pt Alloys: PtxNiy, PtRu, … Non-Nobel Catalysts
Nanostructured Supports: Carbon Based: Nanotubes,
Nanosheets Metal Based: SnO2, WC, … Composite Nanostructures
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Fuel Cell in Dr. Sun’s Group Catalyst:
Pt nanoparticles Pt nanowires Porous Pt nanostructures Pt Alloys: PtAu, PtxNiy Non-Nobel Catalysts: NCNTs,
Catalyst Supports:
Carbon Based: Graphene, NCNTs, CNTs,
Fibers, Metal Based:
Oxides: TiO2, SnO2, MnO, W18O49
Carbides: TiC, WC, TaC ….
My Research Synthesis of Catalyst
supports Metal Oxides, Silicides, Carbides Composites
Synthesis of Catalysts
Pt nanoparticles Pt nanowires Pt Sub Nano
Clusters (atomic)
Physical and Chemical Characterization SEM, TEM, XRD, XPS
Electrochemical Characterization and Fuel Cell Testing
In depth analysis of the Nanostructured System
Synchrotron Based Techniques
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Synthesis of Nanostructures
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Electrochemical Characterization
Cyclic Voltammetry curves
Oxygen Reduction Reaction
Methanol Oxidation
CO stripping Curves
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Application of XAS Study the chemical state of elements
Amorphous structures Low concentration elements
Interaction between material
Qualitative and Quantitative Analysis of Pt L2,3 edges Electron vacancies in 5d orbitals
Interaction between components
Catalytic activity
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Application of XAS
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Future Opportunities
Controlled Synthesis of Electrocatalysts: Alloyed Catalysts Composite Catalysts Composite Supports
Atomic Layer Deposition
Study the interaction between supports
Study the alloy and composite catalysts
(a) (b) Proposed analysis methods: XAS (Hard and soft
X-ray) Ultra HRTEM and
EELS
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Future Opportunities Synthesis of Novel Nanostructures:
Alloyed Catalysts Networked or Dendrite Catalysts Hollow Nanostructures
Solution based: Replacement methods
Vapor based: PECVD and Sputtering
Proposed Analysis Methods: XAS (Hard and Soft X-
rays) STXM
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Summary Application of Nanomaterials to Fuel Cell Challenges Interdisciplinary Research Field
Synthesis and Characterization of Nanomaterials Electrochemical and Fuel Cell testing
In Depth Study of Electrocatalyst Structure Understanding the Underlying Mechanisms Optimizing the Electrocatalysts Structure
New Opportunities: Atomic Layer Deposition Replacement and PECVD Methods
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Thank You
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