Symmetry Operations
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Transcript of Symmetry Operations
Symmetry Operations
brief remark about the general role of symmetry in modern physics
V(X)
x
V(X1)
X1
V(X2)
X2
x
dVF
dx
change of momentumx
x
dpF
dt
V(X)
x
x
dVF 0
dx
conservation of momentum
xdp0
dt
X1 X2
xp const.
V(X1) = V(X2)
translationalsymmetry
Emmy Noether 1918: Symmetry in nature
conservation law1882 in Erlangen, Bavaria, Germany
1935 in Bryn Mawr, Pennsylvania, USA
Breaking the symmetry with magnetic field
Hamiltonian invariant with respect to rotation
Example for symmetry in QM
angular momentum conservedJ good quantum number
B=0 B0
mJ=-1
mJ=0
mJ=+1
EProton and Neutron 2 states of one particle
breaking the Isospin symmetry
Magnetic phase transition
T>TC T<TC
Zeeman splitting
called basis
Symmetry in perfect single crystals
ideally perfect single crystal
infinite three-dimensional repetition of identical building blocks
basis
single atom simple molecule very complex molecular structure
Quantity of matter contained in the unit cell Volume of space (parallelepiped) fills all of space by translation of discrete distances
Example: crystal from
square unit cell hexagonal unit cell
there is often more than one reasonable choice of a repeat unit (or unit cell)
most obvious symmetry of crystalline solid
Translational symmetry
3D crystalline solid 3 translational basis vectors a, b, c
translational operation T=n1a+n2b+n3c where n1, n2, n3
arbitrary integers
-connects positions with identical atomic environments
ab n1=2
n2=1
-by parallel extensions the basis vectors form a parallelepiped, the unit cell, of volume V=a(bxc)
concept of translational invariance is more general
physical property at r (e.g.,electron density) is also found at r’=r+T
Set of operations T=n1a+n2b+n3c
r’
defines
space lattice or Bravais lattice
purely geometrical concept
+ =
lattice basis crystal structure
r
lattice and translational vectors a, b,c are primitive if every point r’ equivalent to r
identical atomic arrangementis created by T according to r’=r+T
r
x
y
x
y rr’=r+0.5 a4
No integer!
no primitive translationvector
no primitive unit cell
Primitive basis: minimum number of atoms in the primitive (smallest) unit cell which issufficient to characterize crystal structure
r’=r+ a2
2 important examples for primitive and non primitive unit cells
face centered cubic
body centered cubic
a1=(½, ½,-½) a2=(-½, ½,½) a3=(½,- ½,½)
a1=a(½, ½,0) a2=a(0, ½,½) a3=a(½,0,½)
Primitive cell: rhombohedronprimitive 1 2 3V a a a 3
conventional
1 1a V
4 4=
1atom/Vprimitive4 atoms/Vconventinal
primitiveV 3conventional
1 1a V
2 2
1atom/Vprimitive 2 atoms/Vconventinal
Lattice Symmetry
Symmetry of the basis point group symmetry
has to be consistent with symmetry of Bravais lattice
Limitation of possible structures
Operations (in addition to translation) which leave the crystal lattice invariant
No change of thecrystal after symmetry
operation
• Reflection at a plane
(point group of the basis must be a point group of the lattice)
• Rotation about an axis H2o
NH3
SF5 Cl
Cr(C6H6)2
= 2 -fold rotation axis2
2
n
2= n -fold rotation axis
Click for more animations and details about point group theory
• point inversion
)z,y,x( )z,y,x(
• Glide = reflection + translation
• Screw = rotation + translation
Notation for the symmetry operations
Origin of the Symbols after Schönflies:
E:identity from the German Einheit =unity
Cn :Rotation (clockwise) through an angle 2π/n, with n integer
: mirror plane from the German Spiegel=mirror
h :horizontal mirror plane, perpendicular to the axis of highest symmetry
v :vertical mirror plane, passing through the axis with the highest symmetry
* rotation by 2/n degrees + reflection through plane perpendicular to rotation
axis
*
n-fold rotations with n=1, 2, 3,4 and 6 are the only rotation symmetries
consistent with translational symmetry !
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Intuitive example: pentagon
Two-dimensional crystal with lattice constant a in horizontal direction
a1 2Row A (m-1) a m
α α
Row B
X1’ m’
If rotation by α is a symmetry operation 1’ and m’ positions of atoms in row B
X=p a
p integer!
= (m-1)a – 2a + 2a cos α = (m-3)a + 2a cos α
1cos
2
3 mpcos
p-m integer 1
p-m cos
-1 1 0/2π1
2=1-fold
-2 1/2 π/3 62 / =6-fold
-3 0 π/2 42 / =4-fold
-4 -1/2 2π/3 32 / =3-fold
-5 -1 π 22 / =2-fold
order ofrotation
Plane lattices and their symmetries
5 two-dimensional lattice types
Point-group symmetry
of lattice: 2
2mm
2mm
4mm
6 mm
10 types of point groups (1, 1m, 2, 2mm,3, 3mm, 4, 4mm, 6, 6mm)possible basis:
Combination of point groups and translational symmetry 17 space groupsin 2D
Crystal=lattice+basis may have lower symmetry
Three-dimensional crystal systems
oblique lattice in 2D triclinic lattice in 3D
,cba
Special relations between axes and angles 14 Bravais (or space) lattices
7 crystal systems
There are 32 point groups in 3D, each compatible with one of the 7 classes
32 point groups and compound operations applied to 14 Bravais lattices
230 space groups or structures exist
Many important solids share a few relatively simple structures