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    Boltzmann, Ludwig (1844-1906), an Austrian physicist, made a major contribution to the foundation and development of statistical

    mechanics, the study of temperature, pressure, and related phenomena by a mathematical analysis of movements of molecules that

    are assumed to obey the laws of mechanics.

    The son of an Austrian taxation official, Ludwig Eduard Boltzmann grew up in Wels and Linz. He earned his doctorate in 1866 from

    the University of Vienna. His doctoral thesis, written under the direction of Josef Stefan, was on the kinetic theory of gases. Hebegan his academic career the following year with an appointment at the Physikalisches Institut in Vienna, which was followed by a

    series of professorial positions in different related disciplines. He left a professorship in theoretical physics at the University of Graz

    (1869-1873), in southeast Austria, for a professorship in mathematics at the University of Vienna (1873-1876), and then returned to

    the University of Graz (1876-1879) as a professor of experimental physics. After serving as director of the Physikalisches Institut

    (1879-1889), Boltzmann took a position as professor of theoretical physics at the University of Munich. In 1894, he returned to

    Vienna as professor of theoretical physics at the university, succeeding his mentor, Josef Stefan. The following year, Ernst Mach

    (whose name today is used to measure the speed of sound, as the Mach I) was appointed to the chair of history and philosophy of

    science at Vienna. The two men not only were scientific opponents, with Boltzmann championing the point of view of the atomists

    and Mach of the energeticists, but also were on bad personal terms. Boltzmann's dislike of working alongside Mach led him to

    move to the University of Leipzig in 1900, where he became professor of theoretical physics. Even though the move made him the

    colleague of his most vigorous scientific opponent, Wilhelm Ostwald, Boltzmann and Ostwald had a good personal relationship.

    Nonetheless, a bout of severe depression led Boltzmann to make a suicide attempt while in Leipzig.

    Boltzmann at least partly in jest, attributed his peripatetic nature to the fact that he was born during the dying hours of a Mardi Gras

    ball. He recognized early on that he was subject to what today is called bipolar disorder, characterized by periods of mania

    alternating with periods of depression, usually separated by lengthy intervals of normal mood. How much of his depression was

    attributable to chemical imbalances and how much to the lack of acceptance of his ideas can never be known for sure.

    After Mach's retirement from the University of Vienna in 1901, Boltzmann returned there in 1902 to his chair of theoretical physics,

    which had remained unfilled in the interim. The university also honored him with a second chair, which Mach had just vacated.

    Responsible now for teaching Mach's course in the philosophy of science, Boltzmann became famous as a lecturer in this field. The

    audience for his lectures soon grew too large to be accommodated in the largest available lecture hall. Boltzmann's reputation even

    reached the imperial court, and Austrian emperor Franz Josef invited him to the royal palace.

    Boltzmann is best known for establishing statistical mechanics, the branch of science independently invented by the American

    mathematical physicist Josiah Willard Gibbs. Their work connected the properties and behavior of molecules, atoms, or elementary

    particles with the large-scale properties of the substances of which they are the building blocks. Boltzmann used probability to

    describe how atomic properties determine the properties of matter.

    Over the course of his career, Boltzmann made significant contributions to mechanics, dynamics, and electromagnetism, all of which

    were being developed during his student years. He was one of the first European scientists to recognize the importance of Scottish

    physicist James Clerk Maxwell's research in the field of electromagnetism. Theory of Electricity and Magnetism, a book based on

    Boltzmann's lectures on Maxwell's theories, which was published in 1897 with a preface by Boltzmann, helped disseminate

    Maxwell's work.

    Boltzmann's first published paper (1865) was stimulated by a lecture given by Josef Stefan on electrical theory. Three years later, he

    published a paper on thermal equilibrium in gases, which both cited and extended Maxwell's work on this topic. In 1871, he obtained

    an equation for the distribution of atoms due to collision. According to this equation, which became known as the Maxwell-Boltzmann distribution, the average amount of energy required for atomic motion in all directions is equal. In 1884, Boltzmann

    expanded on the work of his mentor by demonstrating how the empirical law for black-body radiation that Stefan formulated in 1879

    could be derived from the principles of thermodynamics. According to the Stefan-Boltzmann law, the total energy radiated from a

    black body is proportional to the fourth power of its absolute temperature. The law is illustrated by the fact that a blue star that is the

    same size as a red star is very much brighter. In the 1890's, Boltzmann derived the second law of thermodynamics from the

    principles of mechanics. He asserted that entropy increases almost always, rather than always.

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    electromagnetism, on which he wrote a two-volume treatise. Boltzmann also worked on a derivation for black-body

    radiation based on the Stefans law, which was later termed by Hendrik Antoon Lorentz as a true pearl of theoretical

    physics. His work in statistical mechanics was vocally criticized by Wilhelm Ostwald and the energeticists who

    disregarded atoms and based physical science exclusively on energy conditions. They were unable to understand the

    statistical nature of Boltzmanns logic.

    His ideas were supported by the later discoveries in atomic physics in the early 1900, for instance Brownian motion,

    which can only be explained by statistical mechanics.

    Later Life and Death:

    Ludwig Boltzmann was greatly demoralized due to the harsh criticism of his work. He committed suicide on

    September 5, 1906 at Duino, Italy by hanging himself. He was 62 years old.

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    JOSEPH STEFAN

    Both Josef Stefan's parents, although living near Klagenfurt in Austria-Hungary (now Austria), were of

    Slovenian origin and spoke Slovenian. His father, Ales Stefan (1805-1872), worked as a miller of flour and

    as a baker. Josef's mother, Marija Startinik (1815-1863), was employed as a maidservant. They were

    both illiterate and were not married. Josef showed his brilliance when at elementary school in

    Klagenfurt and he showed himself to have both the desire and ability to do well at the Gymnasium

    which was recommended by his teachers. However, as an illegitimate child he would not be allowed to

    attend a Gymnasium so, when he was eleven years old, his parents married to give Josef to opportunity

    of a good education. Stefan entered the Gymnasium in Klagenfurt in 1846.

    On 13 March 1848, eleven days before Stefan's thirteenth birthday, a Revolution began in Austria. It was

    prompted by the Paris Revolution in February of the same year. People sought basic freedoms but the

    country was divided and revolutionary and counter-revolutionary groups fought for power. Stefan was

    at an impressionable age and the Revolution made him much more aware of the various ethnic

    groupings and his own Slovenian origins. He reacted by writing Slovenian poetry which he published. His

    poetry touched on scientific topics as well as sometime being fiercely patriotic while at other times it

    was romantic. In 1853 he completed his studies at the Gymnasium as the top student in his class and,although having a range of interests which he could have chosen to study at university, nevertheless was

    quite certain that mathematics and physics were for him. He did consider joining the Benedictine Order

    for a while but soon gave up the idea.

    Stefan entered the University of Vienna in 1853. He graduated four years later with a degree in

    mathematics and physics. He continued to write Slovenian poetry and prose throughout his student

    years but after criticisms by the Slovenian literary experts, he gave this up around the time he graduated

    from the University of Vienna. For the next year he taught physics for pharmacy students, then accepted

    a position with Karl Ludwig at the Physiology Institute of Vienna University. Here he carried out

    experimental work on the flow of water through tubes. During this period he was preparing to habilitate

    which he did in 1858. Appointed a lecturer in mathematical physics at the University of Vienna in 1858,he was elected to the Austrian Academy of Sciences in 1860, then he became a professor at the

    University of Vienna in 1863. In 1866 he became director of the Physical Institute at Vienna. This

    Institute had been founded byDopplerin 1850.

    His career at the University of Vienna included a spell as dean of the Philosophy Faculty in 1869-70, and

    rector in 1876-77. We noted his election to the Austrian Academy of Sciences in 1860. He became a full

    member in 1865, was secretary of the Mathematical Sciences Class of the Academy from 1875, and was

    vice-president of the Academy from 1885 until his death.

    The programme of research that Stefan embarked on was wide ranging across a number of different

    areas. He was a great admirer ofMaxwell's contributions and was a major player in making his work

    known on the Continent. It was inMaxwell's papers that he came across the following:-

    It would be almost impossible to establish the value of the conductivity of a gas by direct experiment, asthe heat radiated from the sides of the vessel would be far greater than the heat conducted through theair, even if current could be entirely prevented.

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    He used the tools of advanced mathematics and understood how to present the most difficultdevelopments in the clearest and most lucid form without ever having to resort to mathematical

    formalism. ... [He]never tried to flaunt [his]mental superiority. [His]uplifting humour, which turned themost difficult discussion into an entertaining game for the student, made such a deep impression on me.

    Boltzmannpainted a picture of a wonderful research environment:-

    Nothing diminishes the excellence of [Stefan's]character, the magic [he]worked on the youngacademics. That magic could only be experienced personally. [The experience]stayed with me my wholelife as a symbol of serious, inspired experimental activity.

    For most of his life Stefan was unmarried, too dedicated to his profession to have space for wife or

    family. However, in 1891 when he was 56 years old, he married Marija Neumann who was a widow. He

    lived only a little over a year after his marriage, suffering a stroke. He was buried in the Zentralfriedhof

    in Vienna.

    http://www-history.mcs.st-andrews.ac.uk/history/Mathematicians/Boltzmann.htmlhttp://www-history.mcs.st-andrews.ac.uk/history/Mathematicians/Boltzmann.htmlhttp://www-history.mcs.st-andrews.ac.uk/history/Mathematicians/Boltzmann.html
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    Blackbody Concepts

    Incident energy striking an object from the surroundings, can be absorbed by the object,reflected by the object, or transmitted through the object (if it is not opaque) as seen in

    Figure 2-1. If the object is at a constant temperature, then the rate at which it emits energymust equal the rate at which it absorbs energy, otherwise the object would cool (emittancegreater than absorption), or warm (emittance less than absorption). Therefore, for bodies atconstant temperature, the emittance (absorption), the reflection and the transmittance of

    energy equals unity. Central to radiation thermometry is the concept of the blackbody. In

    1860, Kirchhoff defined a blackbody as a surface that neither reflects or transmits, butabsorbs all incident radiation, independent of direction and wavelength. The fraction of

    radiation absorbed by a real body is called absorptivity, For an ideal blackbody, the

    absorptivity is 1.0 . For non-blackbodies, the absorption is a fraction of the radiation

    heat transfer incident on a surface, or Hence, in term of radiation heat transfer, q":

    In addition to absorbing all incident radiation, a blackbody is a perfect radiating body. To

    describe the emitting capabilities of a surface in comparison to a blackbody, Kirchoff defined

    emissivity of a real surface as the ratio of the thermal radiation emitted by a surface ata given temperature to that of a blackbody at the same temperature and for the same

    spectral and directional conditions.This value also must be considered by a non-contact temperature sensor when taking a

    temperature measurement. The total emissivity for a real surface is the ratio of the total

    amount of radiation emitted by a surface in comparison to a blackbody at the same

    temperature. The tables beginning on p. 72 give representative emissivity values for a widerange of materials. If precise temperature measurements are required, however, the

    surface's actual emittivity value should be obtained. (Although often used interchangeably,the terms emissivity and emittivity have technically different meanings. Emissivity refers to

    a property of a material, such as cast iron, whereas emittivity refers to a property of aspecific surface.)

    In 1879, Stefan concluded based on experimental results that the radiation emitted from

    the surface of an object was proportional to the fourth power of the absolute temperature ofthe surface. The underlying theory was later developed by Boltzmann, who showed that theradiation given off by a blackbody at absolute temperatureTs(K) is equal to:

    where ( is the Stefan-Boltzmann constant The heat transfer rate byradiation for a non-blackbody, per unit area is defined as:

    where Tsis the surface temperature and Tsuris the temperature of the surroundings.

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    Figure2-2:Spectral Distributions

    Although some surfaces come close to blackbody performance, all real objects and

    surfaces have emissivities less than 1. Non-blackbody objects are either graybodies, whose

    emissivity does vary with wavelength, or non-graybodies, whose emissivities vary withwavelength. Most organic objects are graybodies, with an emissivity between 0.90 and 0.95(Figure 2-2). The blackbody concept is important because it shows that radiant powerdepends on temperature. When using non-contact temperature sensors to measure the

    energy emitted from an object, depending on the nature of the surface, the emissivity must

    be taken into account and corrected. For example, an object with an emissivity of 0.6 isonly radiating 60% of the energy of a blackbody. If it is not corrected for, the temperaturewill be lower than the actual temperature. For objects with an emissivity less than 0.9, the

    heat transfer rate of a real surface is identified as:

    The closest approximation to a blackbody is a cavity with an interior surface at a uniform

    temperature Ts, which communicates with the surroundings by a small hole having a

    diameter small in comparison to the dimensions of the cavity (Figure 2-3). Most of theradiation entering the opening is either absorbed or reflected within the cavity (to ultimatelybe absorbed), while negligible radiation exits the aperture. The body approximates a perfect

    absorber, independent of the cavity's surface properties.

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    Figure 2-3: An Isothermal Blacbody Cavity

    The radiation trapped within the interior of the cavity is absorbed and reflected so that the

    radiation within the cavity is equally distributed--some radiation is absorbed and some

    reflected. The incident radiant energy falling per unit time on any surface per unit area

    within the cavity is defined as the irradiance If the total irradiation G (W/m2)represents the rate at which radiation is incident per unit area from all directions and at allwavelengths, it follows that:

    If another blackbody is brought into the cavity with an identical temperature as the interior

    walls of the cavity, the blackbody will maintain its current temperature. Therefore, the rate

    at which the energy absorbed by the inner surface of the cavity will equal the rate at whichit is emitted. In many industrial applications, transmission of radiation, such as through a

    layer of water or a glass plate, must be considered. For a spectral component of theirradiation, portions may be reflected, absorbed, and transmitted. It follows that:

    In many engineering applications, however, the medium is opaque to the incident radiation.

    Therefore, and the remaining absorption and reflection can be treated as surface

    phenomenon. In other words, they are controlled by processes occurring within a fraction of

    a micrometer from the irradiated surface. It is therefore appropriate to say that theirradiation is absorbed and reflected by the surface, with the relative magnitudes

    of depending on the wavelength and the nature of the surface.

    Radiation transfer by a non-blackbody encompasses a wide range of wavelengths and

    directions. The spectral hemispherical emissive power, is defined as the rate at

    which radiation is emitted per unit area at all possible wavelengths and in all possible

    directions from a surface, per unit wavelength and per unit surface area.

    Although the directional distribution of surface emission varies depends on the surfaceitself, many surfaces approximate diffuse emitters. That is, the intensity of emitted radiationis independent of the direction in which the energy is incident or emitted. In this case, the

    total, hemispherical (spectral) emissive power, is defined as:

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    or

    where Ieis the total intensity of the emitted radiation, or the rate at which radiant energy is

    emitted at a specific wavelength, per unit area of the emitting surface normal to the

    direction, per unit solid angle about this direction, and per unit wavelength. Notice that is

    a flux based on the actual surface area, where is based on the projected area. In

    approximating a blackbody, the radiation is almost entirely absorbed by the cavity. Anyradiation that exits the cavity is due to the surface temperature only.

    The spectral characteristics of blackbody radiation as a function of temperature and

    wavelength were determined by Wilhelm Wien in 1896. Wien derived his law for thedistribution of energy in the emission spectrum as:

    where (b for blackbody) represents the intensity of radiation emitted by a blackbody at

    temperature T, and wavelength per unit wavelength interval, per unit time, per unit solidangle, per unit area. Also, h = 6.626 x 10-24Js and k = 1.3807 x 10-23JK-1are the

    universal Planck and Boltzman constants, respectively; co= 2.9979 x 108m/s is the speed of

    light in a vacuum, and T is the absolute temperature of the blackbody in Kelvins (K). Dueto the fact that deviations appeared between experimental results and the equation, Plancksuggested in 1900 a refinement that better fit reality:

    It is from this equation that Planck postulated his quantum theory. A more convenientexpression for this equation, referred to as the Planck distribution law (Figure 2-4), is:

    where the first and second radiation constants are

    and Planck's distribution shows that as wavelength varies,emitted radiation varies continuously. As temperature increases, the total amount of energyemitted increases and the peak of the curve shifts to the left, or toward the shorter

    wavelengths. In considering the electromagnetic spectrum, it is apparent that bodies withvery high temperatures emit energy in the visible spectrum as wavelength decreases.

    Figure 2-4 also shows that there is more energy difference per degree at shorterwavelengths.

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    Figure 2-4: Planck Prediction of Blackbody Emissive Power

    From Figure 2-4, the blackbody spectral distribution has a maximum wavelength value,

    lmax, which depends on the temperature. By differentiating equation 2.12 with respect to

    and setting the result equal to zero:

    where the third radiation constant, C3 = 2897.7 K.This is known as Wien'sdisplacement law. The dashed line in Figure 2-4 defines this equation and locates the

    maximum radiation values for each temperature, at a specific wavelength. Notice thatmaximum radiance is associated with higher temperatures and lower wavelengths.

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    THE CONCEPTS MAP OF BLACK BODY

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    Abstract

    There are several mechanisms whereby thermal energyheat- can be transferredbetween

    two bodies of different temperature. The flow of heat is of great interest and use in

    engineering applications and thermodynamical processes. This is the mechanism

    responsible for the absorption of thermal energy from the sun. One of thesemechanisms is

    Thermal Radiation. This was the most complex to understand of the three. In light ofmodern

    Physics and electromagnetic radiation theory, this flow of thermal energy is nowunderstood

    to be electromagnetic radiation from the infra-red and visible light sections of thespectrum.

    The Stefan-Boltzmann law of radiation was the first successful model of theexperimental

    data obtained by heating a radiating blackbody and analysing the colour and thermal

    energy

    flux at higher temperatures. This law describes a dependency upon energy per unitarea of

    output radiation on the 4th power of the objects temperature. Qualitatively warmer

    objects

    emit more radiation with smaller wavelengths. This empirical relationship of P~T4was

    investigated in this experiment by using an incandescent Tungsten filament lightbulband

    heating it by applying a higher current to it in successive steps, whilst analysing thevoltage

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    (and hence Temperature of) a thermocouple stack referred to as a thermopile placedlevel to

    the radiating bulb. It was found that the colour of the filament became whiter as its

    temperature increased, and that in fact the output energy per unit area is related to the

    filaments temperature to the power 4 by means of a plot of thermopile potential ( ameasure

    of its temperature) versus filament temperature converted via its resistance. Indeed

    the

    Stefan Boltzmann Law of radiation is a good description of the radiative flow of heatfrom a

    hot object to its surroundings.

    PHY 263 Practical Experiment :

    Stefan-Boltzmann Law of Radiation

    ALISSA KRIEL

    11123002

    Practical performed on 18 October 2013

    (Group 2 , Friday session)

    Immediate Laboratory partner : S. Congolo

    Other group members : M.L. Jacobs, K. Van Der Laarse

    The analysis of the power per unit area emitted by a

    Tungsten filament as a function of filament temperature

    to verify the 4th power relation of the Stefan-Boltzmann

    Law of radiation

    I ntroduction

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    The movement and flow of heat is a cardinally important thermodynamical process

    that is at

    the same time a life-source for Earth and a property that can be used in many modern

    applications of technology and industry. The heat from the sun provides the surface ofthe

    earth with the necessary light and heat for nature to thrive. The important question ishow

    this heat travels through space to our atmosphereor generally how heat istransferred

    between two bodies of differing temperature. ([4], p100)

    There are three mechanisms whereby thermal energy is transferred between objects :

    Conduction (by direct contact) , Convection (by means of a fluid medium around theobjects)

    and Thermal Radiation, the mechanism of interest in this practical investigation. ([1],p I-4)

    The radiation of thermal energy has been a field of great interest and a source of great

    confusion for many scientists over the years. It was found that an object that absorbed

    thermal energy also emitted thermal energy. An ideal radiator of heat (and hence atotal

    absorber of heat) was labelled aBlackbody Radiator. Experimentally acquired data of

    intensity of radiation from a heated body yielded spectral distribution graphs thatcould not

    be accurately derived from theory in the 19th century.

    An example of a failed theory for the shape of the spectral distribution graph is theRayleigh-

    Jeans formula that relies on classical physics theory. The formula somewhatapproaches the

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    experimental data for long wavelengths of emitted radiation, but deviates badly forradiation

    with shorter wavelengths. The experimental data basically showed that the maximum

    irradiated lights wavelength tended to decrease as the temperature of the object was

    increased, which Wiens displacement law describes. The second trend noted in the

    experimental results is that the total power of radiation increased with increasing

    temperature. This observation was accurately quantified by considering the powerradiated

    per unit area as a function of object TemperatureThis is the Stefan-Boltzmann Law

    of

    radiation : ([2], p 96-100)

    _ = ____......................(1)

    Planck further investigated functions that could describe the spectral distribution ofradiation

    due to temperature, assuming Maxwells electromagnetic wave theory. He came to the

    conclusion that the electromagnetic thermal radiation particles can only have discrete

    energies. Therefore, the heat energy must be radiated by EM waves, which we mostly

    encounter as Infrared radiation.

    In order to physically measure the thermal radiation given off by a Tungsten filament,it is

    necessary to manipulate the equations of theory, whereafter the 4th power relation

    between

    Irradiance per unit area and Temperature can be determined. This proportionality isvalid for

    the Non-Blackbody radiator filament since it has an absorption coefficient of less thanone.

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    Plancks Law of radiation:

    __, __ = ______

    __ __

    ______

    .....................(2)

    By integrating the above equation over all wavelengths, we obtain the Stefan-Boltzmann

    Law:

    ____ = ___

    __ . __

    __ . __............................(3),

    where =

    ___

    __ . __

    __ = 5.67 x 10-8 W.m-2.K-4

    The thermal energy flux which reaches a detector a fixed distance from the heatedsource is

    proportional to P(T). As this thermal energy reaches a detector, which in our case

    is a

    series of thermocouples whose potential difference reading indicates temperature

    of

    the detector absorbing the thermal radiation, the potential difference, Utherm is

    proportional to the 4th power of the temperature of the heat source.

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    For the thermocouple pile detector at room temperature, a correction must beincorporated.

    Finally, taking logarithms on both sides of the proportionality:

    !"__#$ = %&'()*'). __............................(4)

    Thus, a straight line trend with a gradient of 4 will arise in a Logarithmic-Logarithmicplot if

    the thermal radiation obeys the Law in (3):

    +&,!"__#$ = +&,%&'()*') + 4+&,_............................(5)

    The Tungsten filament used in the incandescent lamp in this experiments temperature

    could

    be determined by measuring its current at an applied potential difference after whichits

    Resistance could be calculated using Ohms Law. The resistance of the filament at

    0oC is

    given by: ([3], p 143)

    /0 = 1_"2_

    _34."235."2_

    ...................(6),

    where tR denotes the room temperature in oC, and R(tR) is the filament resistance atroom

    temperature.

    Finally, the temperature of the filament related to its measured resistance at any

    Temperature T is :

    _ = 273 + _

    _5 . 9:;_ + 4< =1_>_

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    1?

    1B D....................................(7)

    Method:

    In order to finally utilize equation (5), which is the double-logarithmic plot, we willfirstly need

    to measure the thermocouple stacks potential difference (Utherm) at its exposure to

    the

    heated filament at various intensitiesor equivalently powers of radiation. Thebrighter the

    filament glows, by Wiens displacement law the hotter it is and thus the greater willbe the

    power with which it emits thermal radiation which the thermocouple stack will absorbto

    increase its own temperature and thus Utherm values.

    These voltages are very small, and in order to record data that may be quantitatively

    manipulated, an amplifier was connected between the thermopile and the voltmeter.Output

    voltage readings of the order of 0.1 mV could be expected.

    Before the bulb was placed nearby the sensor, The reading of the Utherm voltmeterwas

    zeroed by means of adjusting the amplifier.

    The thermopile sensor was placed approximately 29.5 cm away from the lamp, andlevel to

    the light bulb. A DC power supply to the lamp was connected, along with an ammeterto

    monitor applied current and a voltmeter to record Potential difference across thefilament in

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    order to compute Resistance via Ohms Law.

    To compute the filaments resistance at 0oC via Equation (6), Room temperature was

    recorded and the resistance of the filament at room temperature was determined by

    connecting a 100 resistor in series between the power supply and the filament, and

    measuring the voltage across it at several supplied currents between 100mA and200mA to

    prevent heating of the filament which would of course change its resistance.

    When this was complete, the resistor was removed, and the light bulb was suppliedwith

    electricity at Voltages between 0.5 V and 7.0 V, several measurements of the current

    through the bulb and the thermocouple stack Potential difference being made.

    The corresponding Filament Temperature at each recorded step could now becomputed

    using equation (7).

    Results:

    Below follows a table containing several measured voltages and current of the Wfilament at

    room temperature, as well as calculated resistances and an average resistance at room

    temperature.

    Another table containing the measured filament current, filament voltage andThermopile

    Potentials follows that, along with computed Reistance of the filament andcorresponding

    Temperatures of the Filament.

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    Using the applicable data, a Log-Log plot of Thermopile potential as a function ofFilament

    temperature is shown.

    Table 1 : Measured values of current and Voltage over the Tungsten filament atroom

    Temperature 26oC

    Applied Current I (mA)

    1 mA

    Voltage over Filament (V)

    0.001 V

    Computed Resistance*

    () 0.01

    100 0.023 0.23

    125 0.029 0.23

    150 0.034 0.23

    175 0.040 0.23

    200 0.046 0.23

    The Resistance was computed via / = E

    F

    Average Filament Resistance at 26oC :

    R (tR) = 0.23 0.01

    Thus, the filaments resistance at 0oC by equation (6):

    /0 =

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    0.23H

    1 + ;. 26 +

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    Utherm (mV)

    0.1 mv

    1.257 1.857 0.68 700.5 0.1

    2.504 2.702 0.93 960.6 0.2

    3.109 3.027 1.03 1047.0 0.3

    3.538 3.289 1.08 1088.2 0.4

    4.039 3.557 1.14 1138.4 0.5

    4.427 3.738 1.18 1179.0 0.6

    4.849 3.920 1.24 1222.3 0.8

    5.460 4.192 1.30 1275.7 0.9

    5.95 4.430 1.34 1308.4 1.1

    6.53 4.631 1.41 1361.9 1.3

    7.08 4.843 1.46 1403.0 1.5

    Resistance was calculated by Ohms Law.

    The Temperature of the Filament was calculated using equation (7). For the first line

    in Table 2:

    _ = 273 +

    1

    2