Steel - Wikipedia, The Free Encyclopedia

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The steel cable of a colliery winding tower Steel From Wikipedia, the free encyclopedia Steels are alloys of iron and carbon, widely used in construction and other applications because of their high tensile strengths and low costs. Carbon, other elements, and inclusions within iron act as hardening agents that prevent the movement of dislocations that otherwise occur in the crystal lattices of iron atoms. The carbon in typical steel alloys may contribute up to 2.1% of its weight. Varying the amount of alloying elements, their formation in the steel either as solute elements, or as precipitated phases, retards the movement of those dislocations that make iron so ductile and weak, and thus controls qualities such as the hardness, ductility, and tensile strength of the resulting steel. Steel's strength compared to pure iron is only possible at the expense of ductility, of which iron has an excess. Although steel had been produced in bloomery furnaces for thousands of years, steel's use expanded extensively after more efficient production methods were devised in the 17th century for blister steel and then crucible steel. With the invention of the Bessemer process in the mid19th century, a new era of massproduced steel began. This was followed by SiemensMartin process and then GilchristThomas process that refined the quality of steel. With their introductions, mild steel replaced wrought iron. Further refinements in the process, such as basic oxygen steelmaking (BOS), largely replaced earlier methods by further lowering the cost of production and increasing the quality of the metal. Today, steel is one of the most common materials in the world, with more than 1.3 billion tons being produced annually. It is a major component in buildings, infrastructure, tools, ships, automobiles, machines, appliances, and weapons. Modern steel is generally identified by various grades defined by assorted standards organizations. Contents 1 Definitions and related materials 2 Material properties 2.1 Heat treatment 3 Steel production 4 History of steelmaking 4.1 Ancient steel 4.2 Wootz steel and Damascus steel 4.3 Modern steelmaking 4.3.1 Processes starting from bar iron 4.3.2 Processes starting from pig iron

description

properties and uses

Transcript of Steel - Wikipedia, The Free Encyclopedia

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    Thesteelcableofacollierywindingtower

    SteelFromWikipedia,thefreeencyclopedia

    Steelsarealloysofironandcarbon,widelyusedinconstructionandotherapplicationsbecauseoftheirhightensilestrengthsandlowcosts.Carbon,otherelements,andinclusionswithinironactashardeningagentsthatpreventthemovementofdislocationsthatotherwiseoccurinthecrystallatticesofironatoms.

    Thecarbonintypicalsteelalloysmaycontributeupto2.1%ofitsweight.Varyingtheamountofalloyingelements,theirformationinthesteeleitherassoluteelements,orasprecipitatedphases,retardsthemovementofthosedislocationsthatmakeironsoductileandweak,andthuscontrolsqualitiessuchasthehardness,ductility,andtensilestrengthoftheresultingsteel.Steel'sstrengthcomparedtopureironisonlypossibleattheexpenseofductility,ofwhichironhasanexcess.

    Althoughsteelhadbeenproducedinbloomeryfurnacesforthousandsofyears,steel'suseexpandedextensivelyaftermoreefficientproductionmethodsweredevisedinthe17thcenturyforblistersteelandthencruciblesteel.WiththeinventionoftheBessemerprocessinthemid19thcentury,aneweraofmassproducedsteelbegan.ThiswasfollowedbySiemensMartinprocessandthenGilchristThomasprocessthatrefinedthequalityofsteel.Withtheirintroductions,mildsteelreplacedwroughtiron.

    Furtherrefinementsintheprocess,suchasbasicoxygensteelmaking(BOS),largelyreplacedearliermethodsbyfurtherloweringthecostofproductionandincreasingthequalityofthemetal.Today,steelisoneofthemostcommonmaterialsintheworld,withmorethan1.3billiontonsbeingproducedannually.Itisamajorcomponentinbuildings,infrastructure,tools,ships,automobiles,machines,appliances,andweapons.Modernsteelisgenerallyidentifiedbyvariousgradesdefinedbyassortedstandardsorganizations.

    Contents

    1Definitionsandrelatedmaterials2Materialproperties

    2.1Heattreatment3Steelproduction4Historyofsteelmaking

    4.1Ancientsteel4.2WootzsteelandDamascussteel4.3Modernsteelmaking

    4.3.1Processesstartingfrombariron4.3.2Processesstartingfrompigiron

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    4.3.2Processesstartingfrompigiron5Steelindustry6Recycling7Contemporarysteel

    7.1Carbonsteels7.2Alloysteels7.3Standards

    8Uses8.1Historical8.2Longsteel8.3Flatcarbonsteel8.4Stainlesssteel8.5Lowbackgroundsteel

    9Seealso10References

    10.1Bibliography11Furtherreading12Externallinks

    Definitionsandrelatedmaterials

    Thecarboncontentofsteelisbetween0.002%and2.1%byweightforplainironcarbonalloys.Thesevaluesvarydependingonalloyingelementssuchasmanganese,chromium,nickel,iron,tungsten,carbonandsoon.Basically,steelisanironcarbonalloythatdoesnotundergoeutecticreaction.Incontrast,castirondoesundergoeutecticreaction.Toolittlecarboncontentleaves(pure)ironquitesoft,ductile,andweak.Carboncontentshigherthanthoseofsteelmakeanalloycommonlycalledpigironthatisbrittleandnotmalleable.Alloysteelissteeltowhichalloyingelementshavebeenintentionallyaddedtomodifythecharacteristicsofsteel.Commonalloyingelementsinclude:manganese,nickel,chromium,molybdenum,boron,titanium,vanadium,andniobium.[1]Additionalelementsmaybepresentinsteel:manganese,phosphorus,sulfur,silicon,andtracesofoxygen,nitrogen,andcopper.

    Alloyswithahigherthan2.1%carboncontent,dependingonotherelementcontentandpossiblyonprocessing,areknownascastiron.Castironisnotmalleableevenwhenhot,butitcanbeformedbycastingasithasalowermeltingpointthansteelandgoodcastabilityproperties.[1]Steelisalsodistinguishablefromwroughtiron(nowlargelyobsolete),whichmaycontainasmallamountofcarbonbutlargeamountsofslag.Notethatthepercentagesofcarbonandotherelementsquotedareonaweightbasis.

    Materialproperties

    IroniscommonlyfoundintheEarth'scrustintheformofanore,usuallyanironoxide,suchasmagnetite,hematiteetc.Ironisextractedfromironorebyremovingtheoxygenthroughcombinationwithapreferredchemicalpartnersuchascarbonthatislosttotheatmosphereascarbondioxide.Thisprocess,knownassmelting,wasfirstappliedtometalswithlowermeltingpoints,suchastin,whichmeltsatapproximately250C(482F)andcopper,whichmeltsatapproximately1,100C(2,010F).Incomparison,castironmeltsatapproximately1,375C(2,507F).[2]Smallquantitiesofironweresmeltedinancienttimes,inthe

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    Ironcarbonphasediagram,showingtheconditionsnecessarytoformdifferentphases

    solidstate,byheatingtheoreburiedinacharcoalfireandweldingthemetaltogetherwithahammer,squeezingouttheimpurities.Withcare,thecarboncontentcouldbecontrolledbymovingitaroundinthefire.

    AllofthesetemperaturescouldbereachedwithancientmethodsthathavebeenusedsincetheBronzeAge.Sincetheoxidationrateofironincreasesrapidlybeyond800C(1,470F),itisimportantthatsmeltingtakeplaceinalowoxygenenvironment.Unlikecopperandtin,liquidorsolidirondissolvescarbonquitereadily.Smeltingresultsinanalloy(pigiron)thatcontainstoomuchcarbontobecalledsteel.[2]Theexcesscarbonandotherimpuritiesareremovedinasubsequentstep.

    Othermaterialsareoftenaddedtotheiron/carbonmixturetoproducesteelwithdesiredproperties.Nickelandmanganeseinsteeladdtoitstensilestrengthandmaketheausteniteformoftheironcarbonsolutionmorestable,chromiumincreaseshardnessandmeltingtemperature,andvanadiumalsoincreaseshardnesswhilemakingitlesspronetometalfatigue.[3]

    Toinhibitcorrosion,atleast11%chromiumisaddedtosteelsothatahardoxideformsonthemetalsurfacethisisknownasstainlesssteel.Tungsteninterfereswiththeformationofcementite,allowingmartensitetopreferentiallyformatslowerquenchrates,resultinginhighspeedsteel.Ontheotherhand,sulfur,nitrogen,andphosphorusmakesteelmorebrittle,sothesecommonlyfoundelementsmustberemovedfromthesteelmeltduringprocessing.[3]

    Thedensityofsteelvariesbasedonthealloyingconstituentsbutusuallyrangesbetween7,750and8,050kg/dm3(484,000and503,000lb/cuft),or7.75and8.05g/cm3(4.48and4.65oz/cuin).[4]

    Eveninanarrowrangeofconcentrationsofmixturesofcarbonandironthatmakeasteel,anumberofdifferentmetallurgicalstructures,withverydifferentpropertiescanform.Understandingsuchpropertiesisessentialtomakingqualitysteel.Atroomtemperature,themoststableformofpureironisthebodycenteredcubic(BCC)structurecalledferriteoriron.Itisafairlysoftmetalthatcandissolveonlyasmallconcentrationofcarbon,nomorethan0.005%at0C(32F)and0.021wt%at723C(1,333F).At910Cpureirontransformsintoafacecenteredcubic(FCC)structure,calledausteniteoriron.TheFCCstructureofaustenitecandissolveconsiderablymorecarbon,asmuchas2.1%[5](38timesthatofferrite)carbonat1,148C(2,098F),whichreflectstheuppercarboncontentofsteel,beyondwhichiscastiron.[6]

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    Whensteelswithlessthan0.8%carbon(knownasahypoeutectoidsteel),arecooled,theausteniticphase(FCC)ofthemixtureattemptstoreverttotheferritephase(BCC).ThecarbonnolongerfitswithintheFCCstructure,resultinginanexcessofcarbon.Onewayforcarbontoleavetheausteniteisforittoprecipitateoutofsolutionascementite,leavingbehindasurroundingphaseofBCCironthatislowenoughincarbontotaketheformofferrite,resultinginaferritematrixwithcementiteinclusions.CementiteisahardandbrittleintermetalliccompoundwiththechemicalformulaofFe3C.Attheeutectoid,0.8%carbon,thecooledstructuretakestheformofpearlite,namedforitsresemblancetomotherofpearl.Onalargerscale,itappearsasalamellarstructureofferriteandcementite.Forsteelsthathavemorethan0.8%carbon,thecooledstructuretakestheformofpearliteandcementite.[7]

    Perhapsthemostimportantpolymorphicformofsteelismartensite,ametastablephasethatissignificantlystrongerthanothersteelphases.Whenthesteelisinanausteniticphaseandthenquenchedrapidly,itformsintomartensite,astheatoms"freeze"inplacewhenthecellstructurechangesfromFCCtoadistortedformofBCCastheatomsdonothavetimeenoughtomigrateandformthecementitecompound.Dependingonthecarboncontent,themartensiticphasetakesdifferentforms.Belowapproximately0.2%carbon,ittakesanferriteBCCcrystalform,butathighercarboncontentittakesabodycenteredtetragonal(BCT)structure.Thereisnothermalactivationenergyforthetransformationfromaustenitetomartensite.Moreover,thereisnocompositionalchangesotheatomsgenerallyretaintheirsameneighbors.[8]

    Martensitehasalowerdensitythandoesaustenite,sothatthetransformationbetweenthemresultsinachangeofvolume.Inthiscase,expansionoccurs.Internalstressesfromthisexpansiongenerallytaketheformofcompressiononthecrystalsofmartensiteandtensionontheremainingferrite,withafairamountofshearonbothconstituents.Ifquenchingisdoneimproperly,theinternalstressescancauseaparttoshatterasitcools.Attheveryleast,theycauseinternalworkhardeningandothermicroscopicimperfections.Itiscommonforquenchcrackstoformwhensteeliswaterquenched,althoughtheymaynotalwaysbevisible.[9]

    Heattreatment

    Therearemanytypesofheattreatingprocessesavailabletosteel.Themostcommonareannealing,quenching,andtempering.Annealingistheprocessofheatingthesteeltoasufficientlyhightemperaturetosoftenit.Thisprocessgoesthroughthreephases:recovery,recrystallization,andgraingrowth.Thetemperaturerequiredtoannealsteeldependsonthetypeofannealingtobeachievedandtheconstituentsofthealloy.[10]

    Quenchingandtemperingfirstinvolvesheatingthesteeltotheaustenitephasethenquenchingitinwateroroil.Thisrapidcoolingresultsinahardbutbrittlemartensiticstructure.[8]Thesteelisthentempered,whichisjustaspecializedtypeofannealing,toreducebrittleness.Inthisapplicationtheannealing(tempering)processtransformssomeofthemartensiteintocementite,orspheroiditeandhencereducestheinternalstressesanddefects.Theresultisamoreductileandfractureresistantsteel.[11]

    Steelproduction

    Whenironissmeltedfromitsore,itcontainsmorecarbonthanisdesirable.Tobecomesteel,itmustbereprocessedtoreducethecarbontothecorrectamount,atwhichpointotherelementscanbeadded.Inmodernfacilities,thisliquidisthencontinuouslycastintolongslabsorcastintoingots.Approximately

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    Ironorepelletsfortheproductionofsteel

    BloomerysmeltingduringtheMiddleAges

    96%ofsteeliscontinuouslycast,whileonly4%isproducedasingots.[12]

    Theingotsarethenheatedinasoakingpitandhotrolledintoslabs,blooms,orbillets.Slabsarehotorcoldrolledintosheetmetalorplates.Billetsarehotorcoldrolledintobars,rods,andwire.Bloomsarehotorcoldrolledintostructuralsteel,suchasIbeamsandrails.Inmodernsteelmillstheseprocessesoftenoccurinoneassemblyline,withorecominginandfinishedsteelcomingout.[13]Sometimesafterasteel'sfinalrollingitisheattreatedforstrength,howeverthisisrelativelyrare.[14]

    Historyofsteelmaking

    Ancientsteel

    Steelwasknowninantiquity,andmayhavebeenproducedbymanagingbloomeriesandcrucibles,orironsmeltingfacilities,inwhichtheycontainedcarbon.[15][16][17]

    TheearliestknownproductionofsteelarepiecesofironwareexcavatedfromanarchaeologicalsiteinAnatolia(KamanKalehoyuk)andarenearly4,000yearsold,datingfrom1800BC.[18][19]HoraceidentifiessteelweaponslikethefalcataintheIberianPeninsula,whileNoricsteelwasusedbytheRomanmilitary.[20]

    SouthIndianandMediterraneansourcesincludingAlexandertheGreat(3rdc.BC)recountthepresentationandexporttotheGreeksof100talentsofSouthIndiansteel.ThereputationofSericironofSouthIndia(wootzsteel)amongsttheGreeks,Romans,Egyptians,EastAfricans,ChineseandtheMiddleEastgrewconsiderably,ahighqualityhighcarbonironandsteelimportedfromTamilpeopleofthedynastyChera.[17]MetalproductionsitesinSriLankautilizedthesenoveltechniquesusinguniquewindfurnacesdrivenbythemonsoonwinds,capableofproducinghighcarbonsteel,aswellasimportedartefactsofancientironandsteelfromKodumanal.LargescaleWootzsteelproductioninTamilakamusingcruciblestheyinventedandcarbonsourcessuchastheplantAvramoccurredbythesixthcenturyBC,thepioneeringprecursortomodernsteelproductionandmetallurgy.[16][17]

    SteelwasproducedinlargequantitiesinSpartaaround650BC.[21][22]

    TheChineseoftheWarringStatesperiod(403221BC)hadquenchhardenedsteel,[23]whileChineseoftheHandynasty(202BC220AD)createdsteelbymeltingtogetherwroughtironwithcastiron,gaininganultimateproductofacarbonintermediatesteelbythe1stcenturyAD.[24][25]TheHayapeopleofEast

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    Africainventedatypeoffurnacetheyusedtomakecarbonsteelat1,802C(3,276F)nearly2,000yearsago.EastAfricansteelhasbeensuggestedbyRichardHookertodatebackto1400BC.[26][27]

    WootzsteelandDamascussteel

    EvidenceoftheearliestproductionofhighcarbonsteelintheIndianSubcontinentarefoundinKodumanalinTamilNaduarea,GolcondainAndhraPradeshareaandKarnataka,andinSamanalawewaareasofSriLanka.[28]ThiscametobeknownasWootzsteel,producedinSouthIndiabyaboutsixthcenturyBCandexportedglobally.[29][30]Thesteeltechnologyexistedpriorto326BCintheregionastheyarementionedinliteratureofSangamTamil,ArabicandLatinasthefineststeelintheworldexportedtotheRomans,Egyptian,ChineseandArabsworldsatthattimewhattheycalledSericIron.[31]A200BCTamiltradeguildinTissamaharama,intheSouthEastofSriLanka,broughtwiththemsomeoftheoldestironandsteelartefactsandproductionprocessestotheislandfromtheclassicalperiod.[32][33][34][35]TheChineseandlocalsinAnuradhapura,SriLankahadalsoadoptedtheproductionmethodsofcreatingWootzsteelfromtheCheraDynastyTamilsofSouthIndiabythe5thcenturyAD.[36][37]InSriLanka,thisearlysteelmakingmethodemployedauniquewindfurnace,drivenbythemonsoonwinds,capableofproducinghighcarbonsteel.[38][39]SincethetechnologywasacquiredfromtheTamiliansfromSouthIndia,theoriginofsteeltechnologyinIndiacanbeconservativelyestimatedat400500BC.[29][39]

    Wootz,alsoknownasDamascussteel,isfamousforitsdurabilityandabilitytoholdanedge.Itwasoriginallycreatedfromanumberofdifferentmaterialsincludingvarioustraceelements,apparentlyultimatelyfromthewritingsofZosimosofPanopolis.However,thesteelwasanoldtechnologyinIndiawhenKingPoruspresentedasteelswordtotheEmperorAlexanderin326BC.Itwasessentiallyacomplicatedalloywithironasitsmaincomponent.Recentstudieshavesuggestedthatcarbonnanotubeswereincludedinitsstructure,whichmightexplainsomeofitslegendaryqualities,thoughgiventhetechnologyofthattime,suchqualitieswereproducedbychanceratherthanbydesign.[40]Naturalwindwasusedwherethesoilcontainingironwasheatedbytheuseofwood.TheancientSinhalesemanagedtoextractatonofsteelforevery2tonsofsoil,[38]aremarkablefeatatthetime.OnesuchfurnacewasfoundinSamanalawewaandarchaeologistswereabletoproducesteelastheancientsdid.[38][41]

    Cruciblesteel,formedbyslowlyheatingandcoolingpureironandcarbon(typicallyintheformofcharcoal)inacrucible,wasproducedinMervbythe9thto10thcenturyAD.[30]Inthe11thcentury,thereisevidenceoftheproductionofsteelinSongChinausingtwotechniques:a"berganesque"methodthatproducedinferior,inhomogeneous,steel,andaprecursortothemodernBessemerprocessthatusedpartialdecarbonizationviarepeatedforgingunderacoldblast.[42]

    Modernsteelmaking

    Sincethe17thcenturythefirststepinEuropeansteelproductionhasbeenthesmeltingofironoreintopigironinablastfurnace.[43]Originallyemployingcharcoal,modernmethodsusecoke,whichhasprovenmoreeconomical.[44][45][46]

    Processesstartingfrombariron

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    ABessemerconverterinSheffield,England

    ASiemensMartinsteelovenfromtheBrandenburgMuseumofIndustry.

    Intheseprocessespigironwas"fined"inafineryforgetoproducebariron,whichwasthenusedinsteelmaking.[43]

    TheproductionofsteelbythecementationprocesswasdescribedinatreatisepublishedinPraguein1574andwasinuseinNurembergfrom1601.AsimilarprocessforcasehardeningarmourandfileswasdescribedinabookpublishedinNaplesin1589.TheprocesswasintroducedtoEnglandinabout1614andusedtoproducesuchsteelbySirBasilBrookeatCoalbrookdaleduringthe1610s.[47]

    Therawmaterialforthisprocesswerebarsofiron.Duringthe17thcenturyitwasrealizedthatthebeststeelcamefromoregroundsironofaregionnorthofStockholm,Sweden.Thiswasstilltheusualrawmaterialsourceinthe19thcentury,almostaslongastheprocesswasused.[48][49]

    Cruciblesteelissteelthathasbeenmeltedinacrucibleratherthanhavingbeenforged,withtheresultthatitismorehomogeneous.Mostpreviousfurnacescouldnotreachhighenoughtemperaturestomeltthesteel.TheearlymoderncruciblesteelindustryresultedfromtheinventionofBenjaminHuntsmaninthe1740s.Blistersteel(madeasabove)wasmeltedinacrucibleorinafurnace,andcast(usually)intoingots.[49][50]

    Processesstartingfrompigiron

    ThemodernerainsteelmakingbeganwiththeintroductionofHenryBessemer'sBessemerprocessin1855,therawmaterialforwhichwaspigiron.[51]Hismethodlethimproducesteelinlargequantitiescheaply,thusmildsteelcametobeusedformostpurposesforwhichwroughtironwasformerlyused.[52]TheGilchristThomasprocess(orbasicBessemerprocess)wasanimprovementtotheBessemerprocess,madebyliningtheconverterwithabasicmaterialtoremovephosphorus.

    Another19thcenturysteelmakingprocesswastheSiemensMartinprocess,whichcomplementedtheBessemerprocess.[49]Itconsistedofcomeltingbariron(orsteelscrap)withpigiron.

    ThesemethodsofsteelproductionwererenderedobsoletebytheLinzDonawitzprocessofbasicoxygensteelmaking(BOS),developedinthe1950s,andotheroxygensteelmakingmethods.Basicoxygensteelmakingissuperiortoprevioussteelmakingmethodsbecausetheoxygenpumpedintothefurnacelimitsimpuritiesthatpreviouslyhadenteredfromtheairused.[53]Today,electricarcfurnaces(EAF)areacommonmethodofreprocessingscrapmetaltocreatenewsteel.Theycanalsobeusedforconvertingpigirontosteel,buttheyusealotofelectricalenergy(about440kWhpermetricton),andarethusgenerallyonlyeconomicalwhenthereisaplentifulsupplyofcheapelectricity.[54]

    Steelindustry

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    Whitehotsteelpouringoutofanelectricarcfurnace.

    Steelproductionbycountryin2007

    Itiscommontodaytotalkabout"theironandsteelindustry"asifitwereasingleentity,buthistoricallytheywereseparateproducts.Thesteelindustryisoftenconsideredanindicatorofeconomicprogress,becauseofthecriticalroleplayedbysteelininfrastructuralandoveralleconomicdevelopment.[55]

    In1980,thereweremorethan500,000U.S.steelworkers.By2000,thenumberofsteelworkersfellto224,000.[56]

    TheeconomicboominChinaandIndiahascausedamassiveincreaseinthedemandforsteelinrecentyears.Between2000and2005,worldsteeldemandincreasedby6%.Since2000,severalIndian[57]andChinesesteelfirmshaverisentoprominencelikeTataSteel(whichboughtCorusGroupin2007),ShanghaiBaosteelGroupCorporationandShagangGroup.ArcelorMittalishowevertheworld'slargeststeelproducer.

    In2005,theBritishGeologicalSurveystatedChinawasthetopsteelproducerwithaboutonethirdoftheworldshareJapan,Russia,andtheUSfollowedrespectively.[58]

    In2008,steelbegantradingasacommodityontheLondonMetalExchange.Attheendof2008,thesteelindustryfacedasharpdownturnthatledtomanycutbacks.[59]

    Theworldsteelindustrypeakedin2007.Thatyear,ThyssenKruppspent$12billiontobuildthetwomostmodernmillsintheworld,inCalvert,AlabamaandSepetiba,RiodeJaneiro,Brazil.TheworldwideGreatRecessionstartingin2008,however,sharplylowereddemandandnewconstruction,andsopricesfell.ThyssenKrupplost$11billiononitstwonewplants,whichsoldsteelbelowthecostofproduction.Finallyin2013,ThyssenKruppofferedtheplantsforsaleatunder$4billion.[60]

    Recycling

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    AsteelplantintheUnitedKingdom.

    BethlehemSteelinBethlehem,Pennsylvaniawasoneoftheworld'slargestmanufacturersofsteelbeforeits2003closureandlaterconversionintoacasino.

    Steelisoneoftheworld'smostrecycledmaterials,witharecyclingrateofover60%globally[61]intheUnitedStatesalone,over82,000,000metrictons(81,000,000longtons)wasrecycledintheyear2008,foranoverallrecyclingrateof83%.[62]

    Contemporarysteel

    Carbonsteels

    Modernsteelsaremadewithvaryingcombinationsofalloymetalstofulfillmanypurposes.[3]Carbonsteel,composedsimplyofironandcarbon,accountsfor90%ofsteelproduction.[1]Lowalloysteelisalloyedwithotherelements,usuallymolybdenum,manganese,chromium,ornickel,inamountsofupto10%byweighttoimprovethehardenabilityofthicksections.[1]Highstrengthlowalloysteelhassmalladditions(usually

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    Arollofsteelwool

    Somemoremodernsteelsincludetoolsteels,whicharealloyedwithlargeamountsoftungstenandcobaltorotherelementstomaximizesolutionhardening.Thisalsoallowstheuseofprecipitationhardeningandimprovesthealloy'stemperatureresistance.[1]Toolsteelisgenerallyusedinaxes,drills,andotherdevicesthatneedasharp,longlastingcuttingedge.OtherspecialpurposealloysincludeweatheringsteelssuchasCorten,whichweatherbyacquiringastable,rustedsurface,andsocanbeusedunpainted.[69]Maragingsteelisalloyedwithnickelandotherelements,butunlikemoststeelcontainslittlecarbon0.01%).Thiscreatesaverystrongbutstillmalleablesteel.[70]

    Eglinsteelusesacombinationofoveradozendifferentelementsinvaryingamountstocreatearelativelylowcoststeelforuseinbunkerbusterweapons.Hadfieldsteel(afterSirRobertHadfield)ormanganesesteelcontains1214%manganesewhichwhenabradedstrainhardenstoformanincrediblyhardskinwhichresistswearing.Examplesincludetanktracks,bulldozerbladeedgesandcuttingbladesonthejawsoflife.[71]

    In2015abreakthroughincreatingastronglightaluminiumsteelalloywhichmightbesuitableinapplicationssuchasaircraftwasannouncedbyresearchersatPohangUniversityofScienceandTechnology.AddingsmallamountsofnickelwasfoundtoresultinprecipitationasnanoparticlesofbrittleB2intermetalliccompoundswhichhadpreviouslyresultedinweakness.TheresultwasacheapstronglightsteelalloywhichisslatedfortrialproductionatindustrialscalebyPOSCO,aKoreansteelmaker.[72][73]

    Standards

    Mostofthemorecommonlyusedsteelalloysarecategorizedintovariousgradesbystandardsorganizations.Forexample,theSocietyofAutomotiveEngineershasaseriesofgradesdefiningmanytypesofsteel.[74]TheAmericanSocietyforTestingandMaterialshasaseparatesetofstandards,whichdefinealloyssuchasA36steel,themostcommonlyusedstructuralsteelintheUnitedStates.[75]

    Uses

    Ironandsteelareusedwidelyintheconstructionofroads,railways,otherinfrastructure,appliances,andbuildings.Mostlargemodernstructures,suchasstadiumsandskyscrapers,bridges,andairports,aresupportedbyasteelskeleton.Eventhosewithaconcretestructureemploysteelforreinforcing.Inaddition,itseeswidespreaduseinmajorappliancesandcars.Despitegrowthinusageofaluminium,itisstillthemainmaterialforcarbodies.Steelisusedinavarietyofotherconstructionmaterials,suchasbolts,nails,andscrewsandotherhouseholdproductsandcookingutensils.[76]

    Othercommonapplicationsincludeshipbuilding,pipelines,mining,offshoreconstruction,aerospace,whitegoods(e.g.washingmachines),heavyequipmentsuchasbulldozers,officefurniture,steelwool,tools,andarmourintheformofpersonalvestsorvehiclearmour(betterknownasrolledhomogeneousarmourinthisrole).

    Historical

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    Acarbonsteelknife

    Asteelbridge

    Asteelpylonsuspendingoverheadpowerlines

    BeforetheintroductionoftheBessemerprocessandothermodernproductiontechniques,steelwasexpensiveandwasonlyusedwherenocheaperalternativeexisted,particularlyforthecuttingedgeofknives,razors,swords,andotheritemswhereahard,sharpedgewasneeded.Itwasalsousedforsprings,includingthoseusedinclocksandwatches.[49]

    Withtheadventofspeedierandthriftierproductionmethods,steelhasbecomeeasiertoobtainandmuchcheaper.Ithasreplacedwroughtironforamultitudeofpurposes.However,theavailabilityofplasticsinthelatterpartofthe20thcenturyallowedthesematerialstoreplacesteelinsomeapplicationsduetotheirlowerfabricationcostandweight.[77]Carbonfiberisreplacingsteelinsomecostinsensitiveapplicationssuchasaircraft,sportsequipmentandhighendautomobiles.

    Longsteel

    AsreinforcingbarsandmeshinreinforcedconcreteRailroadtracksStructuralsteelinmodernbuildingsandbridgesWiresInputtoreforgingapplications

    Flatcarbonsteel

    MajorappliancesMagneticcoresTheinsideandoutsidebodyofautomobiles,trains,andships.

    Stainlesssteel

    CutleryRulersSurgicalinstrumentsWatchesGunsRailpassengervehicles

    Lowbackgroundsteel

    SteelmanufacturedafterWorldWarIIbecamecontaminatedwithradionuclidesduetonuclearweaponstesting.Lowbackgroundsteel,steelmanufacturedpriorto1945,isusedforcertainradiationsensitiveapplicationssuchasGeigercountersandradiationshielding.

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    Astainlesssteelgravyboat

    Seealso

    CarbonsteelGlobalsteelindustrytrendsIroninfolkloreKnifemetalMachinabilityPelletizingRolling

    RollingmillRustBeltSecondindustrialrevolutionSiliconsteel

    SteelabrasiveSteelmillGalvanisingDamascussteelWootzsteelTamahagane,usedinSamuraiswords.Tinplate

    References

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    28.Retrieved20070228.4. Elert,Glenn."DensityofSteel"(http://hypertextbook.com/facts/2004/KarenSutherland.shtml).Retrieved

    20090423.5. Sourcesdifferonthisvaluesoithasbeenroundedto2.1%,howevertheexactvalueisratheracademicbecause

    plaincarbonsteelisveryrarelymadewiththislevelofcarbon.See:Smith&Hashemi2006,p.3632.08%.Degarmo,Black&Kohser2003,p.752.11%.Ashby&Jones19922.14%.

    6. Smith&Hashemi2006,p.363.7. Smith&Hashemi2006,pp.365372.8. Smith&Hashemi2006,pp.373378.9. "Quenchhardeningofsteel"(http://steel.keytometals.com/default.aspx?ID=CheckArticle&NM=12).Retrieved

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    TreatingofSteel,pp.525660.R.J.Fruehan,Editor.1998,TheAISESteelFoundation:Pittsburgh.55. "SteelIndustry"(http://bx.businessweek.com/steelindustry/).Retrieved20090712.56. "CongressionalRecordV.148,Pt.4,April11,2002toApril24,2002(http://books.google.com/books?

    id=iOgfSDKecCcC&pg=PA4557&dq&hl=en#v=onepage&q=&f=false)".UnitedStatesGovernmentPrintingOffice.

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    59. Uchitelle,Louis(20090101)."SteelIndustry,inSlump,LookstoFederalStimulus"(http://www.nytimes.com/2009/01/02/business/02steel.html?_r=1&partner=permalink&exprod=permalink).TheNewYorkTimes.Retrieved20090719.

    60. JohnW.MillerandIkeHenning,"Thiessengetsoffersformills:FinalbidsforsteelcomplexesinAlabama,Brazilwilllikelyfallshortofthecompany'shopes,"WallStreetJournalMarch1,2013

    61. Hartman,RoyA.(2009).Recycling(http://web.archive.org/web/20080414215636/http://encarta.msn.com/encyclopedia_761556346/Recycling.html).Encarta.Archivedfromtheoriginal(http://encarta.msn.com/encyclopedia_761556346/Recycling.html)on20080414.

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    65. Werner,Ewald."TransformationInducedPlasticityinlowalloyedTRIPsteelsandmicrostructureresponsetoacomplexstresshistory"(http://www.wkm.mw.tum.de/Forschung/projekte_html/transtrip.html).Retrieved20070301.

    66. Mirko,CentiSalicetiStefano."TransformationInducedPlasticity(TRIP),TwinningInducedPlasticity(TWIP)andDualPhase(DP)Steels"(https://web.archive.org/web/20080307200557/http://www.dimet.unige.it/resta/studenti/2002/27839/26/TWIP,TRIPandDualphase+mirko.doc).TampereUniversityofTechnology.Archivedfromtheoriginal(http://www.dimet.unige.it/resta/studenti/2002/27839/26/TWIP,TRIPandDualphase%20mirko.doc)on20080307.Retrieved20070301.

    67. Galvanicprotection.EncyclopdiaBritannica.2007.68. "SteelGlossary"(http://steel.org).AmericanIronandSteelInstitute(AISI).Retrieved20060730.69. "SteelInterchange"(https://web.archive.org/web/20071222180444/http://aisc.org/MSCTemplate.cfm?

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    Bibliography

    Ashby,MichaelF.Jones,DavidRaynerHunkin(1992).Anintroductiontomicrostructures,processinganddesign.ButterworthHeinemann.Bugayev,K.Konovalov,Y.Bychkov,Y.Tretyakov,E.Savin,IvanV.(2001).IronandSteelProduction(http://books.google.com/?id=MJdIVtmwuUsC).TheMinervaGroup,Inc.ISBN9780894991097.Retrieved20090719..Degarmo,E.PaulBlack,JT.Kohser,RonaldA.(2003).MaterialsandProcessesinManufacturing(9thed.).Wiley.ISBN0471656534.Gernet,Jacques(1982).AHistoryofChineseCivilization.Cambridge:CambridgeUniversityPress.VereinDeutscherEisenhttenleute(Ed.).SteelAHandbookforMaterialsResearchandEngineering,Volume1:Fundamentals.SpringerVerlagBerlin,HeidelbergandVerlagStahleisen,Dsseldorf1992,737p.ISBN3540529683,ISBN3514003777.VereinDeutscherEisenhttenleute(Ed.).SteelAHandbookforMaterialsResearchandEngineering,Volume2:Applications.SpringerVerlagBerlin,HeidelbergandVerlagStahleisen,Dsseldorf1993,839p.ISBN354054075x,ISBN3514003785.Smith,WilliamF.Hashemi,Javad(2006).FoundationsofMaterialsScienceandEngineering(4thed.).McGrawHill.ISBN0072953586.

    Furtherreading

    69. "SteelInterchange"(https://web.archive.org/web/20071222180444/http://aisc.org/MSCTemplate.cfm?Section=Steel_Interchange2&Template=/CustomSource/Faq/SteelInterchange.cfm&FaqID=2311).AmericanInstituteofSteelConstructionInc.(AISC).Archivedfromtheoriginal(http://aisc.org/MSCTemplate.cfm?Section=Steel_Interchange2&Template=/CustomSource/Faq/SteelInterchange.cfm&FaqID=2311)on20071222.Retrieved20070228.

    70. "PropertiesofMaragingSteels"(http://steel.keytometals.com/default.aspx?ID=CheckArticle&NM=103).Retrieved20090719.

    71. Hadfieldmanganesesteel.(http://answers.com/topic/hadfieldmanganesesteel)Answers.com.McGrawHillDictionaryofScientificandTechnicalTerms,McGrawHillCompanies,Inc.,2003.Retrievedon20070228.

    72. "Wingsofsteel:Analloyofironandaluminiumisasgoodastitanium,atatenthofthecost"(http://www.economist.com/news/scienceandtechnology/21642107alloyironandaluminiumgoodtitaniumtenth).TheEconomist.February7,2015.RetrievedFebruary5,2015."E02715"

    73. SangHeonKim,HansooKim&NackJ.Kim(February5,2015)."Brittleintermetalliccompoundmakesultrastronglowdensitysteelwithlargeductility"(http://www.nature.com/nature/journal/v518/n7537/full/nature14144.html).Nature(NaturePublishingGroup)518:7779.doi:10.1038/nature14144(https://dx.doi.org/10.1038%2Fnature14144).RetrievedFebruary5,2015."weshowthatanFeAltypebrittlebuthardintermetalliccompound(B2)canbeeffectivelyusedasastrengtheningsecondphaseinhighaluminiumlowdensitysteel,whilealleviatingitsharmfuleffectonductilitybycontrollingitsmorphologyanddispersion."

    74. Bringas,JohnE.(2004).HandbookofComparativeWorldSteelStandards:ThirdEdition(https://web.archive.org/web/20070127135646/http://www.astm.org/BOOKSTORE/PUBS/DS67B_SampleChapter.pdf)(PDF)(3rd.ed.).ASTMInternational.p.14.ISBN0803133626.Archivedfromtheoriginal(http://astm.org/BOOKSTORE/PUBS/DS67B_SampleChapter.pdf)(PDF)on20070127.

    75. SteelConstructionManual,8thEdition,secondrevisededition,AmericanInstituteofSteelConstruction,1986,ch.1page15

    76. Ochshorn,Jonathan(20020611)."Steelin20thCenturyArchitecture"(http://www.ochshorndesign.com/cornell/writings/steel.html).EncyclopediaofTwentiethCenturyArchitecture.Retrieved20100426.

    77. Materialsscience.EncyclopdiaBritannica.2007.

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    WikimediaCommonshasmediarelatedtoSteel.

    LookupsteelinWiktionary,thefreedictionary.

    MarkReutter,MakingSteel:SparrowsPointandtheRiseandRuinofAmericanIndustrialMight(https://books.google.com/books?id=bdkUfDoY24QC&printsec=frontcover&dq=Making+Steel:+Sparrows+Point+and+the+Rise+and+Ruin+of+American+Industrial+Might&hl=en&sa=X&ei=NxHuVIe6DIzcoASoICICQ&ved=0CB4Q6AEwAA#v=onepage&q=Making%20Steel%3A%20Sparrows%20Point%20and%20the%20Rise%20and%20Ruin%20of%20American%20Industrial%20Might&f=false)(2005).DiscussionwithMarkReutter,part1of3(http://therealnews.com/t2/index.php?option=com_content&task=view&id=31&Itemid=74&jumival=13277)(February2015),part2of3(http://therealnews.com/t2/index.php?option=com_content&task=view&id=31&Itemid=74&jumival=13284)(February2015),part3of3(http://therealnews.com/t2/index.php?option=com_content&task=view&id=31&Itemid=74&jumival=13298)(March2015),TheRealNewsDuncanBurn,TheEconomicHistoryofSteelmaking,18671939:AStudyinCompetition(http://questia.com/PM.qst?a=o&d=3914930).CambridgeUniversityPress,1961.HarukiyuHasegawa,TheSteelIndustryinJapan:AComparisonwithBritain(http://questia.com/PM.qst?a=o&d=108742046).1996.J.C.CarrandW.Taplin,HistoryoftheBritishSteelIndustry(http://questia.com/PM.qst?a=o&d=808791).HarvardUniversityPress,1962.H.LeeScamehorn,Mill&Mine:TheCf&IintheTwentiethCentury(http://questia.com/PM.qst?a=o&d=94821694).UniversityofNebraskaPress,1992.Needham,Joseph(1986).ScienceandCivilizationinChina:Volume4,Part1&Part3.Taipei:CavesBooks,Ltd.Warren,Kenneth,BigSteel:TheFirstCenturyoftheUnitedStatesSteelCorporation,19012001(http://eh.net/bookreviews/library/0558).UniversityofPittsburghPress,2001.

    Externallinks

    WorldSteelAssociation(worldsteel)(http://www.worldsteel.org/)steeluniversity.org:OnlinesteeleducationresourcesfromworldsteelandtheUniversityofLiverpool(http://steeluniversity.org/)Hugearchiveonsteels,CambridgeUniversity(http://www.msm.cam.ac.uk/phasetrans/2005/Fealloys.html)CookingwithSteels(http://www.wastedtalent.ca/comic/cookingsteel)MetallurgyfortheNonMetallurgistfromtheAmericanSocietyforMetals(http://books.google.com/books?id=brpxLtdCLYC&pg=PA26&lpg=PA26&d#v=onepage&q&f=true,)MATDATDatabaseofPropertiesofUnalloyed,LowAlloyandHighAlloySteelsobtainedfrompublishedresultsofmaterialtesting(http://www.matdat.com)Newsfeatureon"openhearth"steelworkersattheU.S.SteelFairlessMillsnearPhiladelphia(https://news.google.com/newspapers?id=ArNdAAAAIBAJ&sjid=0V0NAAAAIBAJ&pg=1275%2C782046)

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