Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of...

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Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese Academy of Sciences, China [email protected] Presented by Yves HENON Asiaster Pte Ltd, Singapore [email protected]

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Page 1: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

Status of Radiation Processing

of Polymers in China

Prepared by Guozhong WU

Shanghai Institute of Applied Physics

Chinese Academy of Sciences, China

[email protected]

Presented by Yves HENON

Asiaster Pte Ltd, Singapore

[email protected]

Page 2: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

• Research started in the 1960s

• Technological transfers from USRR and Japan

• Commercial applications have reached a large scale

• International players have now come to China (Raychem, Sterigenics…)

• Many facilities that can be used / are built for these applications

• Accelerators : about 150 (50 in 2000)

• Gamma irradiators: about 180

Page 3: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

Most accelerators are from 1.2 MeV to 3.0 MeV

Most were manufactured in China or in Russia

< 1 MeV machine made in Japan

10 MeV machine made in China

Machines under development:

- 500-800 keV / 50-100 mA

- 5 MeV / 20 mA

Page 4: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

Main commercial application

Heat-shrinkable material

Cable & wire

Other large scale applications:

Cross-linking

Polyethylene foam

Grafting

Battery membranes

Polymerisation

Adhesives

Page 5: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

About to reach commercial scale

0

10

20

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cum

ula

tive

dis

trib

uti

on Q

3(x

) /

%

0

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1.0

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den

sity

dis

trib

uti

on q

3lg

(x)

0.100.10 0.5 1 5 10 50

particle size / µm

3 micron

Particle size distribution

Degradation of PTFE Irradiation + micronisation

Degradation of chitosan Irradiation + pulverisation

Antibacterial viscose fibre

Page 6: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

4 reasons why a strong growth is expected

1))))The market will increase with the expected growth of

the Chinese economy. By 2020, the GDP is expected to

increase by a 4-fold.

Main market should remain heat-shrinkable material,

cables and wires.

Page 7: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

4 reasons why a strong growth is expected

2))))By 2020, China will be the world largest automobile

market, producing 20 million cars per year.

The need for radiation modified parts will increase.

tyres

Heat shrinkable tubeFoamed polymer

Page 8: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

4 reasons why a strong growth is expected

3))))In order to meet the energy needs, 30 new nuclear

power plants should be built by 2020.

They will require radiation resistant cables, wires and

tubes.

Page 9: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

4 reasons why a strong growth is expected

4))))There is strong government support

In 2004, the Chinese National Development & Reform

Commission (NDRC) approved 21 projects for non-power

nuclear applications.

- 8 projects related to radiation processing of polymer including

battery membranes, rubber modification and heat-shrinkable

materials.

- 3 projects for the production of electron accelerators.

Page 10: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

Conclusion

Within a few years, China is likely to become the

world number 1 for radiation processing of

polymers, both in terms of number of irradiation

facilities in use and of market value.

Page 11: Status of Radiation Processing of Polymers in China WU.pdf · Status of Radiation Processing of Polymers in China Prepared by Guozhong WU Shanghai Institute of Applied Physics Chinese

Events to come:

- Electron beam and machines and applications

Shanghai, 27-31 October 2008

Contact: Guozhong WU

[email protected]

- Regional Workshop on Radiation Processing

Suzhou, 22-23 October 2008

Contact: Pr Zhu Nankang

[email protected]

- Forum on Radiation Processing

Beijing, December 2008

Contact: China Isotopes and Radiation Association

[email protected]