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Wise, S. W., Jr., Schlich, R., et al., 1992Proceedings of the Ocean Drilling Program, Scientific Results, Vol. 120
60. DATA REPORT: X-RAY MINERALOGY DATA FROM KERGUELEN PLATEAU, LEG 120,SITE 7511
James R. Breza2
INTRODUCTION
The purpose of this paper is to present data from a claymineralogy investigation of the sediments analyzed for ice-rafteddebris (IRD) from Hole 751A (see Breza, this volume). This datais significant in that the change in clay mineralogy may provideinformation about the Neogene evolution of climate and oceaniccirculation near the Kerguelen Plateau and adjacent to Prydz Bay,Antarctica.
Site 751 is located in the central part of the Raggatt Basin onthe Southern Kerguelen Plateau in 1633.8 m of water (5743.56'S,7948.89'E) (Fig. 1). The plateau is a structural high isolated fromany continental input by means of turbidities or nepheloid trans-port. It is bounded to the northeast by the Australian-AntarcticBasin, to the southwest by the African-Antarctic Basin, and to thenorthwest by the Crozet Basin. To the south it is separated fromAntarctica by the Princess Elizabeth Trough.
Site 751 consists of two lithologic units (Fig. 2). Unit I iscomposed of 40 m of upper Pleistocene to lower Pliocene diatomooze with varying amounts of IRD and foraminifers. Unit IIconsists of 126 m of upper to lower Miocene diatom nannofossilooze, with nannofossils as the primary sedimentary component.
METHODS
Mineral identification of the 62-mfraction was retained for clastic material identification as part ofan ice-rafted debris study of the Kerguelen Plateau (see Breza,this volume). The ODP Leg 120 Sites
70c
90c
Figure 1. Bathymetric chart of the Kerguelen Plateau showing the Leg 120 site
locations. The contour interval is 1000 m.
and the filter membrane removed, leaving the extract adhered tothe petrographic slide.
Two X-ray diffractograms (XRDs) were made of the orientedmounts: (1) an untreated sample X-rayed from 2 to 40 2, and(2) a sample (treated with ethylene glycol for more than 24 hr atroom temperature) X-rayed from 2 to 20 2. A Philips diffrac-tometer equipped with cobalt radiation and a receiving slit of 1/4was used at a scan speed of 1 /min.
The procedures for mineral identification followed those out-lined by Brown and Brindley (1980). Smectite was identified froma peak at approximately 15 , which shifted to approximately 17 upon glycolation. Illite was identified from an approximate10-A peak, which did not shift upon glycolation. A 7- mineralwas also identified; however, no attempt was made to differentiatethis mineral between chlorite and kaolinite, which both have 7-peaks. The assumption was made that the minerals present whena 7- diffraction peak occurred were either chlorite and/or kao-linite. Figure 3 is a representative diffractogram of smectite, illite,and chlorite and/or kaolinite. An amorphous peak was also de-tected in most diffractograms. This peak is identified by a largediffuse broad silica peak occurring between 20 and 25 2 (Fig.4). The amorphous content largely consist of biogenic silica.
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DATA REPORT
0 -
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20 -
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40 -
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60 -
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1 0 0 -
1 2 0 -
M H
1 4 0 -
1 6 0 -
i
1H
2H
3H
4H
5H
6H
7H
8H
9H
10H
11H
12H
13H
14H
15H
16H
17H
18H
H R
ecov
ery I
]
I111j11i11i1111
Age
Pleistocene
Lithology
- -- J - i - J - . . .
v
Description
Diatom ooze, minor IRD,volcanic ash, foraminifers,calcareous debris
Diatom ooze,chert/porcellanite
Diatom ooze,minor IRD, volcanic ash
Diatom ooze
Diatom nannofossil ooze
White diatom nannofossilooze, variable proportion ofnannofossils/diatoms
Nannofossil ooze withdiatoms (mottles diatom-enriched)
Nannofossil ooze withdiatoms, faint greenlaminae
White diatom nannofossilooze, variable proportionnannofossils/diatoms
Nannofossil diatom ooze/diatom nannofossil ooze;alternating dominance
Color changes (white-lightgrey) on meter scalewithin core
Diatom nannofossil ooze,nannofossils predominant
Nannofossil oozewith diatoms, varyingdominance within cores.
Diatom ooze
Diatomnannofossil
ooze
166.2 m = TDFigure 2. Lithostratigraphy of Site 751, Raggatt Basin, Southern Kerguelen Plateau. Recovered intervals indicated byshading in recovery column. For key tpatterns in lithology column, see Schlich, Wise, et al. (1990, "Explanatory Notes"chapter). Figure from Schlich, Wise, et al. (1990). IRD = ice-rafted debris and TD = total depth.
RESULTS
The results of this clay mineralogy study are presented in aqualitative occurrence format in Table 1. However, because of thesmall amount of
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DATA REPORT
2-eFigure 3. X-ray diffractogram for untreated clay fraction from Sample 120-751A-2H-2, 23-25 cm. S = smectite, I = illite, C/K = chlorite and/or kaolinite. Thex-axis is 2, and the y-axis is intensity.
provided by National Science Foundation Grant No. DPP-8917976 and USSAC funds.
REFERENCES
Brown, G., and Brindley, G. W., 1980. X-ray diffraction procedures forclay mineral identification. In Brindley, G. W., and Brown, G. (Eds.),Crystal Structures of Clay Minerals and Their X-ray Identification.London Mineral. Soc. Monogr., 5:305-360.
Folk, R. L., 1980. Petrology of Sedimentary Rocks: Austin, TX (HemphillPubl.).
Holmes, M. A., 1989. Lateral distribution of detrital clay minerals inLower Cretaceous sediment, western North Atlantic and its continen-tal margin [Ph.D. dissert.]. Florida State Univ., Tallahassee.
Pollastro, R. M., 1982. A recommended procedure for the preparation oforiented clay-mineral specimens for X-ray diffraction analysis: modi-fications to Drever's filter-membrane peel technique. Open-File Rep.,U.S.Geol. Surv., 82-71.
Schlich, R., Wise, S. W., Jr., et al., 1990. Proc. ODP, Init. Repts., 120:College Station, TX (Ocean Drilling Program).
Date of initial receipt: 28 June 1990Date of acceptance: 12 November 1990Ms 120B-135
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DATA REPORT
Q Q I
(3.37 ) (4.23 ) (4.44 )
(15.24 A)
UNTREATED
zLJz
i i r r r i40
I35
1 I30
T25 20
2-
I15
I10
Figure 4. X-ray diffractogram for untreated clay fraction from Sample 120-751A-7H-5, 83-85 cm. The x-axis is 2, and the y-axis is intensity.
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DATA REPORT
Table 1. Results of X-ray diffraction analysis from Hole 751A. Table 1 (continued).
Core, section,interval (cm)
Depth(mbsf) Smectite Illite
Chlorite/ Amorphouskaolinite silica
120-751A-
1H-1, 23-251H-1, 63-651H-1, 123-1251H-2, 23-251H-2, 79-811H-2, 140-142IH-3, 97-99IH-3, 137-1392H-1, 23-252H-1, 63-652H-1, 123-1252H-2, 23-252H-2, 63-652H-2, 142-1452H-4, 63-653H-1, 63-653H-1, 123-1253H-2, 23-253H-2, 83-853H-2, 123-1253H-3, 63-653H-3, 123-1253H-4, 23-253H-4, 83-853H-4, 103-1053H-5, 23-253H-5, 83-853H-5, 142-1454H-2, 83-854H-2, 142-1454H-3, 63-654H-3, 123-1254H-4, 23-254H-4, 83-854H-4, 142-1444H-5, 63-654H-5, 142-1444H-6, 23-254H-6, 83-854H-6, 142-1445H-1, 63-655H-1, 123-1255H-2, 23-255H-2, 83-855H-2, 142-1445H-3, 63-655H-3, 123-1255H-4, 23-255H-4, 83-855H-4, 142-1445H-5, 63-655H-5, 123-1255H-6, 23-256H-1, 83-856H-1, 142-1446H-2, 63-656H-2, 103-1056H-3, 23-256H-3, 83-856H-3, 142-1446H-4, 63-656H-5, 23-256H-5, 83-856H-5, 142-1446H-6, 63-656H-6, 123-1256H-7, 23-257H-1, 83-857H-1, 142-1447H-2, 63-657H-2, 103-1057H-3, 23-257H-4, 63-657H-5, 23-257H-5, 83-85
0.230.601.231.732.292.903.974.374.935.335.936.436.837.629.83
14.8315.4315.9316.5316.9317.8318.4318.9319.5319.7320.4321.0321.6226.0326.6227.3327.9328.4329.0329.6230.3331.1231.4332.0332.6233.8234.4334.9335.5336.1236.8337.4337.9338.5339.1239.8340.4340.9343.5344.1244.8345.2345.9346.5347.1247.8348.9349.5350.1250.8351.4351.9353.0353.6254.3354.7355.4357.3358.4359.03
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Core, section,interval (cm)
Depth Chlorite/ Amorphous(mbsf) Smectite Illite kaolinite silica
120-751 A- (Cont.)
8H-3, 83-858H-4, 103-1058H-5, 23-258H-5, 83-858H-5, 142-1449H-1, 23-2510H-1, 83-8510H-1, 142-14410H-2, 123-12510H-3, 23-2510H-3, 83-8510H-3, 142-14510H-4, 63-6510H-4, 123-12510H-5, 23-2510H-5, 83-8510H-5, 142-14410H-6, 63-6510H-6, 123-12510H-7, 23-25
65.5367.2367.9368.5369.1271.4381.5382.1283.4383.9384.5385.1285.8386.4386.9387.5388.1288.8389.4389.93
Notes: X = mineral present in the sample analyzed, = mineral not presentin the sample analyzed.
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