specialty polyolefinsSPECIALTY REACTIVE … · 18334 LLDPE 1 125 101 PE, PA, EVOH 18340 LLDPE 3 118...

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Let’s progress together specialty polyolefins Let’s progress together SPECIALTY REACTIVE POLYOLEFINS / Lotader ® / Orevac ® / Evasin®

Transcript of specialty polyolefinsSPECIALTY REACTIVE … · 18334 LLDPE 1 125 101 PE, PA, EVOH 18340 LLDPE 3 118...

A global chemical company and France’s leading chemicals producer, Arkema is building the future of the chemical industry every day. Deploying a responsible, innovation-based approach, we produce state-of-the-art specialty chemicals that provide customers with practical solutions to such challenges as climate change, access to drinking water, the future of energy, fossil fuel preservation and the need for lighter materials. With operations in more than 40 countries, some 14,000 employees and 10 research centers, Arkema generates annual revenue of €6.1 billion, and holds leadership positions in all its markets with a portfolio of internationally recognized brands.

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GradesEthylene content (% mol)

Melt index (g/10min) Melting point

(°C)Crystalization

point (°C)Glass transition

point (°C)

O2 Transmission Rate (65% RH)

(20°C)Main applications

190°C - 2.16kg 210°C - 2.16kg

2951-F 29 3 187 162 60 0.3 Bottles, pipes

3251-F 32 1.6 3.5 183 159 59 0.38 Bottles, sheets, fi lms

3851-F 38 1.6 3.7 173 151 54 0.71Sheets, thermoforming,

fi lms

4405-F 44 5.5 166 146 56 1.35Sheets, thermoforming,

shrinks, fi lms

4451-F 44 1.8 167 146 56 1.35Sheets, thermoforming,

shrinks, fi lms

Test methodASTM D1238

ISO 1133DSC

ISO 11357DSC

ISO 11357DMA

ISO 11357ASTM D3985 ISO 14663-2

Let’s progress together

specialty polyolefins

Let’s progress together

SPECIALTY REACTIVE POLYOLEFINS /

Lotader® / Orevac® / Evasin®Ethylene - Vinyl alcohol copolymers

The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since the conditions and methods of use of the product and of the information referred to herein are beyond our control, the data showed in the tables of this leafl et are typical values and cannot be considered as specifi cations. Arkema expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information; NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specifi c product designated and may not be,applicable when such product is used in combination with other materials or in any process. The user should thoroughly test any application before commercialization. Nothing contained,herein constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent and the user is advised to take appropriate steps to be sure that,any proposed use of the product will not result in patent infringement.

See MSDS for Health & Safety Considerations. The information contained in this document is based on trials carried out by our Research Centres and data selected from the literature, but shall in no event be held to constitute or imply any warranty, undertaking, express or implied commitment from our part. Our formal specifi cations defi ne the limit of our commitment. No liability whatsoever can be accepted by Arkema with regard to the handling, processing or use of the product or products concerned which must in all cases be employed in accordance with all relevant laws and/or regulations in force in the country or countries concerned.

Arkema has implemented an internal policy regarding the use of its products in medical devices applications that are in contact with the body or circulating bodily fl uids. In addition, except for limited cases as determined by the Medical Device Policy, Arkema strictly prohibits the use of any Arkema products in Medical Device applications that are implanted in the body or in contact with bodily fl uids or tissues for greater than 30 days.Arkema Functional Polyolefi ns are not designed neither produced in conditions suitable for medical device applications. Please contact Arkema sales representatives if you would like to use Arkema Functional Polyolefi ns in medical device applications.

Headquater: Arkema France 420, Rue d’Estienne d’Orves - 92700 Colombes - France

Tel.: 33 (0)1 49 00 80 80 - Fax: 33 (0)1 49 00 83 96arkema.com

lotader.comorevac.com

EUROPEHeadquater Arkema France420, rue d’Estienne d’Orves92700 COLOMBESFRANCETel.: (+33) 1 49 00 80 80Fax: (+33) 1 49 00 83 96

NORTH AMERICAArkema Inc.900 First Avenue - P.O. Box 6153619406-0936 KING OF PRUSSIA, PAUNITED STATES Tel.: (+1) 610 878 6500 Fax: (+1) 610 878 6400

ASIAArkema PTE Ltd - Branch Offi ce19th Floor, ITF Tower140/40 Silom Road,Suriyawonge Bangrak10500 BANGKOKTHAILAND Tel.: (+66) 2 237 62 57 Fax: (+66) 2 237 5797

SOUTH AMERICAArkema Quimica LtdAv. Ibarapuera 20334th fl or - Moema04029 - 901 SÃO PAULOBRAZIL Tel.: (+55) 11 21 48 85 22

Reactive group

Grades Acrylate

Properties (typical values) Main applications

Acrylate content (%)

Reactive group (%)

Melt index (g/10 min)

(190°C–2.16 kg)

Melting point (°C)

Vicat softening temp. (°C)

Tensile strength at break (MPa)

Elongation at break (%)

Flexural modulus (MPa)

Coating on to aluminium

Coating and lamination with

plastic fi lmsCoextrusion

Heat adhesive fi lm and powder

Modifi cation of thermoplastic polymers

Hot melt adhesives

Compounds/ Additives/

Coupling agent

GMAAX8840 - 0 8 5 106 87 8 400 85 Alloys, toners AX8900 MA 24 8 6 65 <40 4 1100 <30 PET, PBT, alloys

MAH high content

3210 BA 6 3.1 5 107 76 12 600 120 PA4210 BA 6.5 3.6 9 105 69 10 650 120

LX4110 EA 5 3 5 105 78 11 650 1406200 EA 6.5 2.8 40 102 66 6 600 958200 EA 6.5 2.8 200 100 57 6 400 40

TX8030 EA 13 2.8 3 95 65 12 700 130HX8290 EA 17 2.8 70 85 <40 6 700 30

3410 BA 17 3.1 5 89 47 8 700 24 PA3430 MA 15 3.1 6 84 45 12 750 26 PA5500 EA 20 2.8 20 80 45 10 700 20

MAH low content

4503 MA 20 0.3 8 80 45 9 750 204700 EA 29 1.3 7 65 <40 5 800 <30 PA4720 EA 29 0.3 7 65 <40 5 800 <30 PA

Test methodFTIR FTIR ASTM D1238 DSC ASTM D1525 ASTM D638 ASTM D638 ASTM D790

Internal method internal method ISO 1133 ISO 11357-3 ISO 306 ISO 527-2 ISO 527-2 ISO 178

Type Grades Base polymer

Properties (typical values) Main applications

Adhesion to/ Affi nity withMelt index (g/10 min)

(190°C–2.16 kg)

Melting point (°C)

Vicat softening temp. (°C)

Blow moulding Coex tube Pipe coating Cable HFFR Blow fi lm Cast fi lm SheetExtrusion Coating

Compounds (coupling agent / impact modifi er )

PE/EVA grades

18211 EVA 3.5 75 51 PE, PA, EVOH, PS, PET18300 LLDPE 2.3 120 85 PE, PA, EVOH, antifog

18302N LLDPE 1.5 123 84 PE, EVOH, PA (cast)18334 LLDPE 1 125 101 PE, PA, EVOH18340 LLDPE 3 118 99 coupling agent

18342N / 18410* HDPE 3.5 125 110 3LPE coating PE, Epoxy primer18360 LLDPE 2 120 87 PE, PA, EVOH, PEX, PERT18507 HDPE 5 128 - coupling agent HDPE / mineral fi llers / natural fi bers18910 LLDPE 1.5 117 77 PE, PS, EVOH, PAIM300 LLDPE 1.2 112 31 impact modifi er PAOE825 LLDPE 3 118 99 coupling agent PE, PA, EVOH

PP grades

18722 Random PP 7*** 143 120 PP, PA, EVOH18725 Random PP 13*** 124 - PP, PA, Epoxy, Metals18729 Homo PP 4.5*** 162 137 PP, PA, EVOH

18732* Copo PP 8*** 134 120 PP, PA, EVOH, Alu, Epoxy18750 Homo PP 35*** 160 121 PP, PA, EVOH, Alu18751 Homo PP 35*** 160 138 PP, PA, EVOH, Alu

CA100 Homo PP 10** 167 147 coupling agentPP / mineral fi llers (including HFFR) / glass fi ber,

bubbles and beds

Test methodASTM D1238 DSC ASTM D1525

ISO 1133 ISO 11357-3 ISO 306

Ethylene - Acrylate reactive terpolymers

Grafted polyolefi ns

* Available in powder ** Melt index (190°C–325g) *** Melt index (230°C–2.16 kg)

GMA: epoxide reactive group; MAH: maleic anhydride

A global chemical company and France’s leading chemicals producer, Arkema is building the future of the chemical industry every day. Deploying a responsible, innovation-based approach, we produce state-of-the-art specialty chemicals that provide customers with practical solutions to such challenges as climate change, access to drinking water, the future of energy, fossil fuel preservation and the need for lighter materials. With operations in more than 40 countries, some 14,000 employees and 10 research centers, Arkema generates annual revenue of €6.1 billion, and holds leadership positions in all its markets with a portfolio of internationally recognized brands.

Evasin®

ARK

EMA

- 42

0 ru

e d’

Estie

nne

d’O

rves

927

05 C

olom

bes

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ex -

Fran

ce -

A F

renc

h so

ciét

é an

onym

e w

ith a

a s

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cap

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the

Nan

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and

Com

pani

es R

egist

er u

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the

num

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45 0

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.201

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- PO

F - P

hoto

s A

rkem

a, T

hink

stock

, Fot

olia

- C

once

ptio

n/Ré

alisa

tion

: Ryt

hmic

01

47 4

9 56

60

GradesEthylene content (% mol)

Melt index (g/10min) Melting point

(°C)Crystalization

point (°C)Glass transition

point (°C)

O2 Transmission Rate (65% RH)

(20°C)Main applications

190°C - 2.16kg 210°C - 2.16kg

2951-F 29 3 187 162 60 0.3 Bottles, pipes

3251-F 32 1.6 3.5 183 159 59 0.38 Bottles, sheets, fi lms

3851-F 38 1.6 3.7 173 151 54 0.71Sheets, thermoforming,

fi lms

4405-F 44 5.5 166 146 56 1.35Sheets, thermoforming,

shrinks, fi lms

4451-F 44 1.8 167 146 56 1.35Sheets, thermoforming,

shrinks, fi lms

Test methodASTM D1238

ISO 1133DSC

ISO 11357DSC

ISO 11357DMA

ISO 11357ASTM D3985 ISO 14663-2

Let’s progress together

specialty polyolefins

Let’s progress together

SPECIALTY REACTIVE POLYOLEFINS /

Lotader® / Orevac® / Evasin®Ethylene - Vinyl alcohol copolymers

The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since the conditions and methods of use of the product and of the information referred to herein are beyond our control, the data showed in the tables of this leafl et are typical values and cannot be considered as specifi cations. Arkema expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information; NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specifi c product designated and may not be,applicable when such product is used in combination with other materials or in any process. The user should thoroughly test any application before commercialization. Nothing contained,herein constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent and the user is advised to take appropriate steps to be sure that,any proposed use of the product will not result in patent infringement.

See MSDS for Health & Safety Considerations. The information contained in this document is based on trials carried out by our Research Centres and data selected from the literature, but shall in no event be held to constitute or imply any warranty, undertaking, express or implied commitment from our part. Our formal specifi cations defi ne the limit of our commitment. No liability whatsoever can be accepted by Arkema with regard to the handling, processing or use of the product or products concerned which must in all cases be employed in accordance with all relevant laws and/or regulations in force in the country or countries concerned.

Arkema has implemented an internal policy regarding the use of its products in medical devices applications that are in contact with the body or circulating bodily fl uids. In addition, except for limited cases as determined by the Medical Device Policy, Arkema strictly prohibits the use of any Arkema products in Medical Device applications that are implanted in the body or in contact with bodily fl uids or tissues for greater than 30 days.Arkema Functional Polyolefi ns are not designed neither produced in conditions suitable for medical device applications. Please contact Arkema sales representatives if you would like to use Arkema Functional Polyolefi ns in medical device applications.

Headquater: Arkema France 420, Rue d’Estienne d’Orves - 92700 Colombes - France

Tel.: 33 (0)1 49 00 80 80 - Fax: 33 (0)1 49 00 83 96arkema.com

lotader.comorevac.com

EUROPEHeadquater Arkema France420, rue d’Estienne d’Orves92700 COLOMBESFRANCETel.: (+33) 1 49 00 80 80Fax: (+33) 1 49 00 83 96

NORTH AMERICAArkema Inc.900 First Avenue - P.O. Box 6153619406-0936 KING OF PRUSSIA, PAUNITED STATES Tel.: (+1) 610 878 6500 Fax: (+1) 610 878 6400

ASIAArkema PTE Ltd - Branch Offi ce19th Floor, ITF Tower140/40 Silom Road,Suriyawonge Bangrak10500 BANGKOKTHAILAND Tel.: (+66) 2 237 62 57 Fax: (+66) 2 237 5797

SOUTH AMERICAArkema Quimica LtdAv. Ibarapuera 20334th fl or - Moema04029 - 901 SÃO PAULOBRAZIL Tel.: (+55) 11 21 48 85 22