Solid acid catalysts for biomass transformations

download Solid acid catalysts for biomass transformations

of 33

Transcript of Solid acid catalysts for biomass transformations

  • 7/30/2019 Solid acid catalysts for biomass transformations

    1/33

    Tijo` Fdo` Dfpfjytpt airBoilftt Prfhtairlfpoiht

    F(T( Ridmf* @( R( Acrhfh`ct* P( Aorlohi* C( A( Lfo* B( J( Ijoqcorf*fh` Q( Pco}corf `f Tojqf

    Pmcttfjihoeo* 46tp Idpibcr 2>62

  • 7/30/2019 Solid acid catalysts for biomass transformations

    2/33

    Rcto`sfj Boilftt Prfhtairlfpoiht

    Rcto`sfj Boilftt

    Mclodcjjsjitc* Dcjjsjitc

    ^chpitct

    -]yjitc/

    Mc}itct

    -Gjsditc* Arsdpitc* Lfhhitc/

    Asrasrfj 3,My`ri}ylcpmyjasrasrfj -MLA/

    Jcqsjohod fdo`

    M% , M2I M% , M2I

    M2I* M%

  • 7/30/2019 Solid acid catalysts for biomass transformations

    3/33

    Jcqsjohod fdo` ft f ~jfpairl lijcdsjc

    Dirlf* Obirrf fh` Qcjpy* Dmcl( Rcq( 2>>7* 6>7* 2066,23>2

  • 7/30/2019 Solid acid catalysts for biomass transformations

    4/33

    Aii` oh`stpry -ajfqirt/

    Tijqchpt

    ^jftpodo{crt

    @octcj Lotdobjc Boiascj

    Jcqsjohod fdo` ft f ~jfpairl lijcdsjc

  • 7/30/2019 Solid acid catalysts for biomass transformations

    5/33

    Aii` oh`stpry -ajfqirt/

    Tijqchpt

    ^jftpodo{crt

    @octcj Lotdobjc Boiascj

    www

    (`obfhcp(irg

    Jcqsjohod fdo` ft f ~jfpairl lijcdsjc

  • 7/30/2019 Solid acid catalysts for biomass transformations

    6/33

    Cpmyj jcqsjohfpc tyhpmctot

    241>

    6617

    =?2

    3=0

    02?402

    2066

    707

    6=17

    26=6

    2060

    @(R( Acrhfh`ct cp fj( F~~joc` Dfpfjytot F; Gchcrfj 023 021 -2>62/ 6?? 2>0

    P < 404 E

    p < 3 m2(3 wp(# ia dfpfjytp

    CpIM)JqFd < 3)6

  • 7/30/2019 Solid acid catalysts for biomass transformations

    7/33

    Tsjafpc` tpfhof

  • 7/30/2019 Solid acid catalysts for biomass transformations

    8/33

    Dfpfjytp tyhpmctot

    Tijsbojo{fpoih

    jcf`ohg pi fjiw yocj` iapmc `roc` gcj

    Frfpf* F~~( Dfpfj( F6??1* 601* 4,42(

    Lfptsmftmo* Loyf{feo* Efwflsrf* Hfeflsrf* Frfpf* Dmcl( Lfpcr(2>>6* 64* 4>4=,4>02(

  • 7/30/2019 Solid acid catalysts for biomass transformations

    9/33

    Dfpfjytp tyhpmctot

    Frfpf* F~~( Dfpfj( F6??1* 601* 4,42(

    Lfptsmftmo* Loyf{feo* Efwflsrf* Hfeflsrf* Frfpf* Dmcl( Lfpcr(2>>6* 64* 4>4=,4>02(

  • 7/30/2019 Solid acid catalysts for biomass transformations

    10/33

    Dfpfjytp dmfrfdpcro{fpoih , ]R@

  • 7/30/2019 Solid acid catalysts for biomass transformations

    11/33

    Dfpfjytp dmfrfdpcro{fpoih , Rflfh

  • 7/30/2019 Solid acid catalysts for biomass transformations

    12/33

    Dfpfjytp dmfrfdpcro{fpoih H2~mytotir~poih

    Tfl~jc Tg ) l2 g,6

    ThI2 0>

    TI0,2

    ) ThI2 -6L/ 6>=TI0

    ,2) ThI2 -2L/ 62>

    TI0

    ,2) ThI2

    -4L/ 64>

    TI0,2) ThI2 -0L/ 60>

    TI0,2) ThI2 -3L/ 60=

  • 7/30/2019 Solid acid catalysts for biomass transformations

    13/33

    Dmfrfdpcro{fpoih TCL

  • 7/30/2019 Solid acid catalysts for biomass transformations

    14/33

  • 7/30/2019 Solid acid catalysts for biomass transformations

    15/33

    Dfpfjytp dmfrfdpcro{fpoih HM4 P^@

    Pcl~crfpsrc ) iD

    l

    ){lij l,21(?lij l,2=(0lij l,27(2lij l,27(4lij l,2

  • 7/30/2019 Solid acid catalysts for biomass transformations

    16/33

    Li`oaodfpoih ia pmc tsjasr ohdir~irfpoih

  • 7/30/2019 Solid acid catalysts for biomass transformations

    17/33

    Dmfrfdpcro{fpoih H2 ~mytotir~poih

  • 7/30/2019 Solid acid catalysts for biomass transformations

    18/33

    Dmfrfdpcro{fpoih ]R@

  • 7/30/2019 Solid acid catalysts for biomass transformations

    19/33

    Dmfrfdpcro{fpoih ]R@

  • 7/30/2019 Solid acid catalysts for biomass transformations

    20/33

    Dfpfjypod fdpoqopyP < 404 E

    p < 3 m

    2(3 wp(# ia dfpfjytp

    CpIM)JqFd < 3)6

  • 7/30/2019 Solid acid catalysts for biomass transformations

    21/33

    Dfpfjypod fdpoqopyP < 404 E

    p < 3 m

    2(3 wp(# ia dfpfjytp

    CpIM)JqFd < 3)6

  • 7/30/2019 Solid acid catalysts for biomass transformations

    22/33

    Dfpfjypod fdpoqopyP < 404 E

    p < 3 m

    2(3 wp(# ia dfpfjytp

    CpIM)JqFd < 3)6

  • 7/30/2019 Solid acid catalysts for biomass transformations

    23/33

    Rcstfbojopy Flbcrjytp 63

  • 7/30/2019 Solid acid catalysts for biomass transformations

    24/33

    Rcstfbojopy GOF,3#

  • 7/30/2019 Solid acid catalysts for biomass transformations

    25/33

    Rcstfbojopy GOF,3#

  • 7/30/2019 Solid acid catalysts for biomass transformations

    26/33

    Rcstfbojopy GOF,3#

  • 7/30/2019 Solid acid catalysts for biomass transformations

    27/33

    Dihdjstoiht

    Air tsjafpc` tijo` i}o`c dfpfjypt pmcrc ot f dirrcjfpoih bcpwcch pmc

    pipfj fdo`opy fh` fdpoqopy5

  • 7/30/2019 Solid acid catalysts for biomass transformations

    28/33

    Dihdjstoiht

    Air tsjafpc` tijo` i}o`c dfpfjypt pmcrc ot f dirrcjfpoih bcpwcch pmc

    pipfj fdo`opy fh` fdpoqopy5

    Air {cijopct pmc ~irc tprsdpsrc tcclt pi ~jfy f lirc ol~irpfhp rijc

    pmfh pmc pipfj fdo`opy5

  • 7/30/2019 Solid acid catalysts for biomass transformations

    29/33

    Dihdjstoiht

    Air tsjafpc` tijo` i}o`c dfpfjypt pmcrc ot f dirrcjfpoih bcpwcch pmc

    pipfj fdo`opy fh` fdpoqopy5

    Air {cijopct pmc ~irc tprsdpsrc tcclt pi ~jfy f lirc ol~irpfhp rijc

    pmfh pmc pipfj fdo`opy5

    Tsjafpc` tpfhof ~rctchpt f gii` fdpoqopy oh jcqsjohod fdo` ctpcroaodfpoih

    bsp sh`crgict `cfdpoqfpoih( Dmfhgohg pmc wftmohg ~ridc`src op ot

    ~ittobjc pi rcstc pmc dfpfjytp(

  • 7/30/2019 Solid acid catalysts for biomass transformations

    30/33

    Dihdjstoiht

    Air tsjafpc` tijo` i}o`c dfpfjypt pmcrc ot f dirrcjfpoih bcpwcch pmc

    pipfj fdo`opy fh` fdpoqopy5

    Air {cijopct pmc ~irc tprsdpsrc tcclt pi ~jfy f lirc ol~irpfhp rijc

    pmfh pmc pipfj fdo`opy

    Tsjafpc` tpfhof ~rctchpt f gii` fdpoqopy oh jcqsjohod fdo` ctpcroaodfpoih

    bsp sh`crgict `cfdpoqfpoih(Dmfhgohg pmc wftmohg ~ridc`src op ot

    ~ittobjc pi rcstc pmc dfpfjytp(

    Flbcrjytp,63* f dillcrdofj fqfojfbjc rctoh ot fdpoqc fh` tpfbjc oh pmcjovso` ~mftc jcqsjohod fdo` ctpcroaodfpoih wopm cpmfhij(

  • 7/30/2019 Solid acid catalysts for biomass transformations

    31/33

    Fdehiwjc`glchpt

    Pmot wire wft ~crairlc`wopmoh pmc @OBFHCP Hcpwire*

    f ~rikcdp wopmoh pmc Csri~cfhDillshopyt TcqchpmArflcwire ^rigrfllc-A^7)2>>7,2>64/ sh`cr grfhpfgrcclchp hi; 22720=,2(

  • 7/30/2019 Solid acid catalysts for biomass transformations

    32/33

    Fdehiwjc`glchpt

    Pmfhet air yisr fppchpoih&

    &

  • 7/30/2019 Solid acid catalysts for biomass transformations

    33/33

    Bfde,s~ tjo`ct