Sofia Training School 6 Project: Solutions for Critical ...€¦ · - Zara Cherkezova-Zheleva, TS...
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Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" 6-8 February 2018 Project: Solutions for Critical Raw Materials Under Extreme Conditions CRM-EXTREME-CA15102
COST is supported by the EU Framework Programme Horizon 2020
TS outcomes were prepared by prof. Zara Cherkezova-Zheleva, TS Leader of COST project CA15102 CRM-Extreme
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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P R O G R A M
1st day - February 6 2018
Morning session
8.30 – 9.00 - Registration
9.00 – 9.30 - Opening remarks, Welcomes,
- Zara Cherkezova-Zheleva, TS Leader of CA15102 COST project - Presentation of
Sofia TS and introduction on the CRMs issue: reduction, substitution and recycling
- Mrs. Zlatina Karova, National Horizon2020 Coordinator, Ministry of Education and
Science
- Prof. Georgi Mihov – Rector of Technical University of Sofia
- Assoc. Prof. Olya Stoilova, Scientific Secretary of “Nanosciences, Materials and
New Technologies" Research field in Bulgarian Academy of Sciences
- Prof. Rositsa Nikolova, President of BCS and Young Scientists Commission in
Bulgarian Academy of Sciences
- Prof. Tatyana Tabakova, Deputy Director of Institute of Catalysis, Bulgarian
Academy of Sciences
9.35 – 10.35 - Saurav Goel – “Understanding material behavior for nanoscale precision
manufacturing”
10.35 – 11.05 Coffee break
11.05 – 12.05 - Ernst Gamsjäger – “Theory guided and experimentally validated Materials
Design”
12.05 – 13.05 Soft lunch
Afternoon session
13.05 -14.05 - Mihaela Girtan - “Ellipsometric modelling as a solution to reduce the
experimental tests and the waste of materials in the optimization of multilayers thin films
fabrication process”
14.10 – 15.10 - Ion Marius Sivebæk - "Nanotribology as a key point in replacement of
CRMs"
15.10-15.45 Coffee break
15.45-17.00 - Ion Marius Sivebæk - case report(s)
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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2nd day - February 7 2018
Morning session
9.00 – 10.00 - Pavel Novak - "How to design a CRM-free tool material?"
10.00 – 10.30 Coffee break
10.30 – 11.30 - Pavel Novak - "Future of high-temperature alloys without CRM"
11.30 – 12.30 - Vyacheslav Lapkovsky- “Sustainable Recycling of Critical Raw Materials”
12.30 – 13.30 Soft lunch
Afternoon session
13.30 -14.30 - Dirk Lehmhus – “Metal Matrix Syntactic Foams: A Lightweight Material
Concept with Potential for Saving Critical Ressources”
14.30 - 15.30 Andrej Shishkin – „By the means of Physical Vapor Deposition Metal Coated
ceramic microspheres: A New Approach for Realizing Metal Matrix Syntactic Foams”
15.30 -16.00 Coffee break
16.00 – 17.00 Discussion – chairman: Vyacheslav Lapkovsky, Andrej Shishkin
3nd day - February 8 2018
Morning session
9.00 – 10.00 Yakoumis Iakovos - "Towards Decoupling Europe from Platinum Group Metals
Supply Risk for the Automotive Sector"
10.00 – 10.30 Coffee break
10.30 – 11.30 A.Sezai Sarac - „Gold/Poly Anthranilic Acid (Au/PANA) Core/Shell
Nanostructures“
11.30 – 12.30 Antonio Jose Sala Candela – “Metal Fiber Brushes for Slip Ring and an
Innovative Application”
12.30 – 13.30 Soft lunch
Afternoon session
13.30 -14.30 Silviya Boycheva – “Understanding the role of CRMs in the development of
strategic energy technologies”
14.30 -15.30 - Panel discussion trainees and trainers
15.30 -16.00 Coffee break
16.00 – 17.00 Concluding remarks
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Dr. Saurav Goel FHEA CEng MIET MIMechE Lecturer, Precision Engineering Institute Cranfield University, United Kingdom, MK430AL [email protected]
Understanding material behaviour for nanoscale precision manufacturing
Abstract:
Miniaturization has emerged in a strong way in the 21st Century. Example products include micro-moulds used in biomedical arena, ultra-precision quality finished mirrors in space and defense arena, flexible electronic displays in modern electronic gadgets, solar cells used in renewable energy resources, microholes used for fibre optics, micronozzles for high temperature jets in automotive and aerospace, laser joining and welding of dissimilar materials in various engineering applications. Use of these products in our day-to-day life is becoming ubiquitous as it enables to drive multifarious benefits, such as savings in materials, space and power consumption, improved system’s overall efficiency and ease of transportation. At the epicenter of miniaturization, lies the role of manufacturing and materials which hinders further developments primarily because of limited understanding on how material behaves at sub-micron scale. With the descend of scale, surface properties start to be dominating compared to the bulk properties of materials and complex interplay of these together contributes to significant manufacturing challenges at the nanoscale. Today’s industries can sustain themselves based on their ability of being able to process materials efficiently at low cost. However significant challenges exist with the inception of newer and smart materials in healthcare, aerospace, energy and electronics e.g. carbon fibre reinforced plastic (CFRP), carbon based 2D materials, titanium alloys, nanopolymer composite coatings and polymeric materials, organic feedstock materials in bioenergy area and semiconductor materials like silicon and its derivative. Tools such as nanoindentation and nanoscratching, nanoimpact testing and diamond anvil cell exist to probe the nanoscale properties yet, a complete understanding of the newly developing materials or even to synthesize new class of hybrid and composite materials requires more scientific efforts. One formidable challenge with processing of these smart and novel materials is that the mode of material removal at fine precision level changes from continuous to discrete. An accurate understanding of this phenomenon requires an insight into the energetic, structural, dynamic and rheological aspects of the system. Hence understanding the relevant atomic level phenomena is the key to obtain full knowledge of the atomistic mechanism of ultra-precision machining and this can be accomplished efficiently through using atomic simulations which will be the theme of the discussions/talk.
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Assoc. Prof. Ernst Gamsjäger Institute of Mechanics, Montanuniversität Leoben, Leoben, Austria [email protected]
Theory guided and experimentally validated Materials Design
Abstract:
The microstructures of materials evolve during processing and determine the properties of these
materials. All materials are subject to phase transformations and other microstructural changes
during processing, which is a strong motivation to investigate the kinetics of phase transformations,
grain growth and grain coarsening both experimentally and by modelling. Models based on the
relevant physical principles are a precondition to improve the understanding of microstructure-
property relationships. Based on in-situ experiments the evolving microstructures can be subjected
to a controlled thermo-mechanical treatment [1-3]. The experimental results will be interpreted by
means of thermodynamically based modelling in order to gain new insights about the underlying
physics when designing new materials, see e.g. [4]. Recent advances in thermo-mechanically
controlled processing enables cost-effective and energy efficient production of steels with excellent
properties [5]. The role of certain critical components like niobium in microalloyed steels, cobalt in
high speed steels or chromium in tool steels will be investigated in future research as a first step for
possible reduction or replacement of these critical raw materials.
References:
[1] H. Chen, E. Gamsjäger, S. Schider, H. Khanbareh, S. van der Zwaag: Acta mater. 61 (2013)
2414-2424.
[2] E. Gamsjäger, M. Wiessner, S. Schider, H. Chen, S. van der Zwaag: Philos. Mag. 95 (2015)
2899-2917.
[3] M. Wiessner, E. Gamsjäger, S. van der Zwaag, P. Angerer: Mater. Sci. Eng. A 682 (2017) 117–
125.
[4] E. Gamsjäger, H. Chen, S. van der Zwaag: Comp. Mat. Sci. 83 (2014) 92 - 100.
[5] M. Militzer: “Thermomechanical processed steels” in Comprehensive materials processing,
Vol. 1, 2014, Elsevier.
Lecture overview
1. Thermodynamic modelling of microstructural changes like phase transformations, grain
growth and coarsening.
2. Verification by in-situ experiments.
3. A working procedure for future projects to reduce critical raw materials.
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Assoc. Prof. Mihaela Girtan Head of the group Thin films for photovoltaic applications at Photonics Laboratory,
University of Angers,
Angers, France
Ellipsometric modelling as a solution to reduce the experimental tests and the
waste of materials in the optimization of multilayers thin films fabrication process
Abstract:
Ellipsometry is a non-destructive, non-invasive non-contact, very precise, reproducible and very
sensitive technique for study the ultra-thin films. Spectroscopic ellipsometry (SE) provides a widely
applicable method for determining accurate characterization of optical and electrical transport
properties of thin films multilayers structures, in particularly when the multilayer of device
structure, is of critical importance to their effective implementation.
The purpose of this talk is to provide a comprehensive study of the spectroscopic ellipsometric
measurements and modelling by taking as examples the study of single oxide films and
oxide/metal/oxide (Oxide = ITO, AZO, TiO2 and Bi2O3, Metal = Au) multi layers thin-film using a two-
modulator generalized ellipsometer by continuing the study much further than usual given in
literature and by also comparing the calculated the transmission coefficient from ellipsometry with
the experimental values obtained from direct spectrophotometry measurements. This procedure
allows to establish in a more accurate way the best dispersion model for each sample. The
ellipsometric modelling, can hence give the possibility in the future to predict, by ellipsometric
simulations, the proper device architecture in function of the preferred optical and electrical
properties.
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Assoc. Prof. Ion Marius Sivebæk
Department of Mechanical Engineering,
Section of Manufacturing Engineering,
Technical University of Denmark
Lyngby, Denmark
Nanotribology as a key point in replacement of CRMs
Abstract:
Tribology is the science and technology of interacting surfaces in relative motion. This implies that it
is an interface phenomenon and a material property. Tribology is usually seen as a side activity in a
given application. An example is the substitution of CRM's. In my lectures I will put tribology in the
headline to ensure that the trainees get a clear picture of how complicated it is to make a
tribological analysis.
The lectures will comprise views on friction and wear and how to deal with these (and how not to).
There are two cases that will require analyses from the trainees.
Please have your phone, tablet or PC ready and connected to the internet when we reach the cases.
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Assoc. Prof. Pavel Novak, Department of Metals and Corrosion Engineering
of University of Chemistry and Technology, Prague (UCT Prague)
vice-dean of Faculty of Chemical Technology of UCT Prague
Prague, Czech Republic
How to design a CRM-free tool material?
Abstract:
The most commonly applied tool materials are tool steel and cemented carbides. Both of these
groups of materials contain the elements which are currently listed as critical raw materials. The
lecture explains the role of the constituents of these materials on their processing and properties.
The history of these materials is presented, showing that the substitution of critical elements was
done already in 1970 – 1990’s in connection with the political situation, as well as the new trends in
substitution.
Future of high-temperature alloys without CRM
Abstract:
Current high-temperature alloys (steel, nickel and cobalt alloys) need critical raw materials (CRM)
for their production. During the decades, many alternative materials have been developed, but
some of them failed due to technical problems and some still need CRMs. The consequences of the
development, as well as the current and future trends in substituting high-temperature materials
are revealed in the lecture. Modern metallic alloys, ODS materials and intermetallics are presented.
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Mr. Vjaceslavs Lapkovskis (Dr.Sc.ing. (PhD) Assistant prof. at Institute of Aeronautics of Riga Technical University, Researcher at Laboratory of Powder Materials of Riga Technical University Riga, Latvia [email protected]
Sustainable Recycling of Critical Raw Materials
Abstract:
Sustainability for critical raw materials in a framework of COST Action CA15102 CRM-EXTREME will be covered. During the lecture up-to-date and emerging technological approaches and methods will be overviewed for CRM-EXTREME critical raw materials, such as Cobalt, Tungsten, Niobium, Rare Earth elements and some others. Several examples of good manufacturing practice in the field of raw materials recycling and reuse will be presented. SOURCE MATERIALS
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Dr.-Ing. Dirk Lehmhus Fraunhofer Institute for Manufacturing Technology and Advanced Materials (IFAM), Bremen, Germany [email protected]
Metal Matrix Syntactic Foams: A Lightweight Material Concept with Potential for
Saving Critical Ressources
Dirk Lehmhus, Jörg Weise, Joachim Baumeister
Abstract:
Metal-Matrix Syntactic Foams or MMSFs follow a unique approach for realizing a lightweight
cellular structure: Hollow particles embedded in a metallic matrix are employed to create a defined
level of porosity and with it a very attractive combination of properties.
Exemplary image of the microstructure of a 316L/cenosphere syntactic foam.
In the past, several different matrices and fillers as well as a considerable number of processes have
been studied in order to synthesize such materials, ranging from melt infiltration to powder
metallurgical approaches. The present lecture will describe the main process variants as well as the
materials which originate from them both in terms of their composition, their (micro-) structural
features and their properties, the latter with a focus on mechanical characteristics.
The overview shows that even at the current stage of development, e. g. density-related strength
levels can be achieved which surpass the respective characteristics of the matrix materials at full
density. Using syntactic foams produced from Fe-based matrices and cenosphere- or glass
microsphere-type fillers as starting point, development trends as well as potential application
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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scenarios for this type of material will be highlighted and discussed. In doing so, a link to the issue
of critical raw material usage is established: The rationale is that a material concept which
facilitates improvements in weight-specific performance levels while using the identical matrix
materials plus low-cost and abundant fillers directly paves the way towards resource efficiency via
component weight reduction.
Bibliography (selected publications):
1. Shishkin, A., Drozdova, M., Kozlov, V., Hussainova, I., Lehmhus, D. Vibration-assisted sputter
coating of cenospheres; A new approach for realizing Cu-based Metal Matrix Syntactic Foams,
Metals 7 (2017), article number 16
2. Luong, D. D., Lehmhus, D., Gupta, N., Weise, J., Bayoumi, M. Structure and compressive
properties of Invar-cenosphere syntactic foams, Materials 9 (2016), article number 115
3. Luong, D. D., Shunmugasamy, V. C., Gupta, N., Lehmhus, D., Weise, J., Baumeister, J.
Quasi-static and high strain rates compressive response of iron and Invar matrix syntactic foams,
Materials and Design 66 (2015), p. 516-531
4. Peroni, L., Scapin, M., Fichera, C., Lehmhus, D., Weise, J., Baumeister, J., Avalle, M.,
Investigation of the mechanical behaviour of AISI 316L stainless steel syntactic foams at different
strain rates, Composites Part B: Engineering 66 (2014), p. 430-442
5. Weise, J., Salk, N., Jehring, U., Baumeister, J., Lehmhus, D., Bayoumi, M. A., Influence of
powder size on production parameters and properties of syntactic invar foams produced by means
of metal powder injection moulding, Advanced Engineering Materials 15 (2013), p. 118-122
6. Peroni, L., Scapin, M., Avalle, M., Weise, J., Lehmhus, D., Dynamic mechanical behavior of
syntactic iron foams with glass microspheres, Materials Science and Engineering A 552 (2012), p.
364-375
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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M.Sc.Eng Andrej Shishkin Riga Technical University Riga, Latvia [email protected]
By the means of Physical Vapor Deposition Metal Coated ceramic microspheres: A
New Approach for Realizing Metal Matrix Syntactic Foams
Abstract:
Composite materials containing hollow microparticles (known as microbubbles, hollow microspheres, or micro balloons) as spaceholders in a polymer, metal or ceramic matrix are designated "syntactic foams" (SF). The present lecture discloses a new method of preparation of a metal matrix material which combines features of a closed-cell syntactic foam with additional open porosity. The main stages of this process are microsphere preparation, coating and sintering, resulting in a lighweight part with considerable levels of specific strength. As examples, copper, stainless steel and titanium coating of microspheres as well as sintering techniques employed and the properties of the final material are presented. In order to further enhance the mechanical properties of this complex material, tungsten/boron composite rods are introduced, mimicking reinforcement approaches knowm from polymer matrix syntactic foams. The density-related strength of these materials is contrasted to similar, previously published findings for several types of established metal foams. Besides discussing these first experimental results, the presentation outlines the potential of coated microspheres as optimized filler particles in conventional, entirely closed-cell metal matrix syntactic foams and suggests future research paths for the various material concepts covered.
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Iakovos V. Yakoumis, Founder and CEO
Monolithos Catalysts & Recycling Ltd.,
Athens, Greece
Towards Decoupling Europe from Platinum Group Metals Supply Risk for the
Automotive Sector
Abstract:
The global emission control catalysts market is expected to reach €15 Billion by 2021 growing at a compound
annual growth rate (CAGR) of 10.37% during the forecast period, being driven primarily by growth in
automotive vehicle sales and tightening regulatory trends. Almost 42% of the European demand for these
precious metals is from the automotive sector with a recovery of just 15%. The recycling and the substitution
of platinum group metals (PGMs; especially palladium, platinum and rhodium) from spent autocatalysts is of
great interest today because of their high prices as well as of their increasing demand in technology.
The PLATIRUS (PLATInum group metals Recovery Using Secondary raw materials) project is an international
collaboration for the development of a cost-efficient and miniaturized recovery process for PGMs funded by
the EU in the H2020 framework. Key targets of the PLATIRUS project build on new, green and
environmentally friendly developments in iono- and solvometallurgical leaching, separation and recovery,
resulting in a novel route to PGM recycling with higher yields, lower energy consumption and improved
environmental impact.
The PROMETHEUS (Platinum group metals saving by Monolithos efficient and disruptive catalyst innovation)
project is an EU H2020 SME-Instrument Phase II Project aiming in Substituting Platinum Group Metals with
Copper Based Nano-Catalytic Washcoat for emission control automotive applications.
Both projects are aiming in decoupling Europe from PGMs supply risk. PGMs have been characterized as
Critical Raw Materials for European Economy since more than 72% of their production is based in third
countries (Russia, South Africa, South America). PLATIRUS and PROMETHEUS technologies will help to save
more than 9 tones of PGMs per year (~25% of European current demand) reducing Europe’s dependency on
PGMs of up to 60% (20 tones per year – the current demand/supply deficit).
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Prof. A. Sezai Sarac
Istanbul Technical University,
Polymer Science and Technology &
Nanoscience and Nanotechnology,
Maslak, Istanbul, Turkey
Gold/Poly Anthranilic Acid (Au/PANA) Core/Shell Nanostructures
Abstract:
Keywords: Precious and Critical Raw Materials, Gold nanoparticles(AuNPs) , Nanofiber, Impedance
spectroscopy , Metal –Polymer Complex Nanostructure
Precious and Critical Raw Materials (CRMs) are widely used in different kinds of products. Their
applications include electric ,electronic and industrial applications .CRMs contained in components
with high-performance requirements.For this reason ,they are critical for the functioning of the
product,and the challenge is that these materials are widely used in small amounts in metal-
complex structures.
This study reports a facile and simple method to prepare (Gold/Poly Anthranilic acid) (Au/PANA)
core/shell nanostructures with uniform size and morphology in an aqueous solution through
oxidation of the monomer (3-aminobenzoic acid) and reduction of the Au(III) ions simultaneously
,and to fabricate their nanofibers .Gold nanoparticles were highly dispersed and stabilized by the
oxidation of 3-aminobenzoic acid in order to form a uniform metal–polymer core/shell
nanocomposite. Fabricated nanocomposites have been characterized by UV–Visible spectroscopy,
attenuated total reflection–Fourier transform infrared (ATR–FTIR) and X-ray diffraction.
Morphology of nanocomposites was analyzed by atomic force microscopy (AFM), and scanning
electron microscopy (SEM). Electroactivity of Au/PANA core/shells were investigated by
electrochemical impedance spectroscopy (EIS) and equivalent circuit modeling was performed1,2.
In situ spectroscopic characterization of polymerization reaction indicated the reaction between
gold ions and 3-aminobenzoic acid and formation of Au/PANA core/shell nanoparticles during
reaction period. Spectroscopic results evidenced the incorporation of Au nanoparticles into PANA.
XRD analyses indicated the high degree of crystallinity of Au. Scanning Electron Microscopy (SEM)
images showed homogeneous distribution of Au/PANA core/Shell nanocomposites with the size of
20 nm. EIS data suggested that as the initial concentrations of Au and PANA increased, the
core/Shell nanocomposites started to act like as an ideal capacitor.
The electrochemical behavior and functional groups of Au/PANA nanocomposites (AuNPs )
encourage to fabricate their nanofibers considering their high surface area to volume ratio which
can enhance the loading capacity for protein immobilization. PANA with the active carboxyl groups
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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(−COOH) on its main structure is a suitable choice not only for modification of the Au nanoparticles
but also for protein immobilization3,4 .
Nanofibers of (Au/PANA) core/shell nanostructures were obtained by electrospinning following to
blending with polyvinylacetate(PVAc) .Albumin (Alb) and streptavidin (STDV) were covalently
immobilized onto (Au/PANA/PVAc) nanofibers by EDC/NHS activation by using (−COOH) groups of
PANA modified gold particles and amine groups on the proteins. Albumin and streptavidin
immobilized nanofibers mats were characterized spectroscopically by ATR–FTIR and UV–Vis
spectrophotometer and morphologically with SEM/Energy-Dispersive X-ray Spectroscopy (EDX).
The interaction between albumin and streptavidin with carboxylic acid groups was investigated by
means of electrochemical impedance spectroscopic (EIS) analysis(Fig. 1).
Carboxyl groups (−COOH) on the surface of Au/PANA/PVAc nanofibers were activated by EDC and
NHS for covalent immobilization of albumin and streptavidin. PVAc nanofibers before and after
protein immobilization were compared with Au/PANA/PVAc nanofibers. In the elemental analyses
(EDX), the amounts of the (N) and (O) changed due to the immobilization of albumin and
streptavidin which confirmed the successful protein attachment onto electrospun nanofiber mats.
ATR–FTIR analysis also exhibited amide peaks in protein attached nanofibers. EIS analysis and
equivalent circuit modeling were performed to observe the immobilized proteins.The nanofibers
became resistive due to protein immobilization and the higher charge transfer resistance was
observed after higher amount of protein was immobilized. This study showed that (−COOH) group
containing, semiconductive Au/PANA/PVAc nanofibers is a suitable support for covalent
immobilization of amino group (−NH) containing biomolecules and EIS analysis and can be
successfully applied for the characterization of biologically modified AuNPs surfaces.
Fig.1 Bode phase plots obtained after streptavidin immobilization onto Au/PANA/PVAc (1/3)
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Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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References
1) Golshaei R., Guler Z., Ünsal C.,, Sarac AS ,In situ spectroscopic and electrochemical impedance
study of gold/poly (anthranilic acid) core/shell nanoparticles, ,Eur.Polym. Journal 66, 502-512
(2015)
2)Golshaei R., Guler Z., Sarac A.S,(Au/PANA/PVAc) nanofibers as a novel composite matrix for
Albumin and streptavidin immobilization , Materials Sci. & Eng.C, Mater Biol Appl. 60, 260–275(
2016)
3)Golshaei, R., Gokce, Z. G., Ghoreishi, S. M.,Sarac A.S.,Au/PANA/PVAc and Au/P(ANA-co-
CNTA)/PVAc electrospun nanofibers as tyrosinase immobilization supports, Int. J. Polym.Mater and
Polym.Biomater 66 ( 13 )658-668 ( 2017)
4)Golshaei R.,Karazehir T.,Ghoreishi S.M.,Ates M.,Sarac A.S.,”Glucose oxidase immobilization onto
Au/poly[anthranilic acid-co-3-carboxy-N-(2-thenylidene)aniline]/PVAc electrospun nanofibers”,
Polymer Bull. 74( 5) 1493–1517(2017)
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Antonio-José Sala Candela Industrial Engineer Polytechnic University of Madrid
Madrid, Spain
Metal Fiber Brushes for Slip Ring and an Innovative Application
Abstract:
Although graphite and metal-graphite brushes have for nearly 100 years dominated the field of
electrical brushes, for many applications there now exists a superior form of sliding electrical
conduction; high performance fiber brushes wherein typically the fibers are made of metal for
which reason they are called metal fiber brushes. Prime candidates for this new technology include
sliding electrical systems which require high current densities, high sliding speeds, low electrical
noise, high efficiency (low brush losses), compact size, or long brush lifetimes.
In particular, low voltage electric motors and generators can be made smaller, more powerful and
longer lasting owing to the increased current capacity, higher efficiency and longer wear life. This
has a direct bearing on electric vehicular and ship drive systems as well as low voltage electrical
power generators. Other applications which require high currents, such as high-force linear
actuators, electromagnetic brakes, and armatures, are similarly well suited.
As an application we will show a “slip ring” to transmit electric current from the car frame to the
interior of a tire to refrigerate or heat it and thus optimize its performance.
Sofia Training School "Solutions for Critical Raw Materials in extreme conditions: from fundamental science to industrial innovations" – 6-8 February 2018, CRM-EXTREME-CA15102
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Assoc. Prof. Silviya Boycheva Department of Thermal and Nuclear Power Engineering Techical University of Sofia,
Sofia, Bulgaria
Understanding the role of CRMs in the development of strategic energy
technologies
Lecture overview:
Overview of the constructional materials of great importance for safety and long-term
operation of Light water reactor Nuclear Power Plants (NPP);
Understanding the role of some CRMs for the application relevant properties of the
constructional materials in Pressurized Water Reactors (PWR) in NPPs;
Outlying the specifics of the corrosion problems with the constructional materials in PWR
NPPs;
Challenges in front of the constructional materials for Generation IV nuclear reactors ;
Carbon capture technologies decisions for fossil fuel Thermal Power Plants in the context of
CRMs saving.