Sili tSilicate St tSt ructures
Transcript of Sili tSilicate St tSt ructures
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Sili t St tSilicate Structures
The building blocks of the common rock forming mineralscommon rock‐forming minerals
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Though there are may minerals that compose the Earth system, ili t (Si d 4O) i ll i th E th’ t d tlsilicates (Si and 4O) are especially in the Earth’s crust and mantle
The basic unit for all silicates is the (SiO4) tetrahedron.( 4)This is an overall 4‐ charge.
The variety of silicate minerals is produced by the (SiO4)4‐
tetrahedra linking to self‐similar units sharing one, two, three, or all four corner oxygens of the tetrahedron.
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(SiO4)4‐(Si2O6)4‐
Single chain silicates
(Si4O11)6‐
Double chain silicates( 4)
OrthosilicatesSingle chain silicates
(Si2O7)6‐
Orthosilicates
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(Si6O18)12‐
(Si2O5)2‐
Tetrahedral sheet (6‐fold)
( 6 18)Tetrahedral ring (6‐fold)
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(SiO2)Infinite tetrahedral network
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Nesosilicates
• Isolated (SiO4)4‐ tetrahedra and bounded to one another via ionic bonds with interstitial cations.
• Dense packing – high density.Dense packing high density.
• Independent tetrahedral – crystal habits are equidimensional and lack pronounced cleavage.q p g
• Al3+ substitution in T‐site generally low.
• Many nesosilicates (but not all) have orthogonal crystallographic systems.y g p y
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Olivine (Forsterite‐Fayalite)(SiO4)4‐ tetrahedra linked by divalent atoms in a six‐fold coordination.
What shape is the interstitial site?
The octahedral sites share edges and are not equivalent
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M1 is slightly more distorted relative to the M2 site.relative to the M2 site.
The octahedral sites may be occupied by Mg2+ and/or Fe2+, while (Mg + Fe) must = 2.
The effective ionic radius of Mg2+ (0.72 Å) is very similar to that of Fe2+ (0.78 Å), in 6‐fold coordination,similar to that of Fe (0.78 Å), in 6 fold coordination, and the two elements are totally inter‐changeable.
Thi i ll d ( ti ) lid l ti
Mg2SiO4 + 2Fe2+ ↔ Fe2SiO4 + 2Mg2+
This is called a (continous) solid‐solution.And occurs via simple (cation) exchange (substitution).
l1
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Industrial Olivine
It is mined as a gemstone (peridot), and has industrial uses such as refractory sands and abrasives. It is also an
important magnesium ore.
As of the year 2000, the largest producers include Norway, Japan, and Spain.
Slag conditioning, foundry sand, refractories, abrasives, soil conditioning heat storage.
When doped with a small amount of Cr2+, forsterite is one of the few materials that acts as a tunable laser in the near IR regionfew materials that acts as a tunable laser in the near IR region
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Colorless in ppl except Fe‐rich (fayalite) end‐
member
High birefringence colors (.035‐.05) with commonly “stubby”commonly stubby shaped crystals
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Garnet (Group)
Garnet group minerals are particularly characteristic of metamorphic rocks.
Garnet is an isometric (cubic) mineral and has 7 ( )compositional isomorphous end‐members.
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Garnet has a generalised structural formula of A3B2Si3O12
A M F 2+ M C ( l di i d l )A = Mg ,Fe2+, Mn or Ca (pyrope, almandine, spessartine and grossular).
B = Al, Cr, or (Fe3+ ± Ti). (The latter two give uvarovite and andradite).
The A‐site is 8 coordinated, the Y ‐site is 6‐coordinated (octahedral) and the T‐site is 4‐coordinated (tetrahedral)the T site is 4 coordinated (tetrahedral)
Isolated (SiO4)4‐ tetrahedra( 4)
are linked to distorted octahedrons (the B‐site).
And, to distorted dodecahedrons ,(the A‐site).
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Two alternative views
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Characteristic Properties
Most garnets are isotropic, and therefore isometric.
They have a hardness of 6‐7½, no cleavage and subconchoidal fracturesubconchoidal fracture.
They have a wide range of colors including reds browns greensThey have a wide range of colors, including reds, browns, greens, yellows, pinks or even white.
Medium to high relief, often pinky in thin section and of course l i d lare permentantly extinct under cross‐polars.
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Paragenesis and Composition
Pure end‐member compositions of garnet are rare. The majority are some intermediate composition which ismajority are some intermediate composition, which is
determined by a combination of factors.
P ↑ ( 15 25 kb 1000°C)P ↑ (>15-25 kbar, 1000°C)Ca increase. Fe3Al2Si3O12 + KMg3AlSi3O10(OH)2
↕
Pres
sure 350°
Mn cores T ↑Mg for Fe
↕
Mg3Al2Si3O12 + KFe3AlSi3O10(OH)2
h l hP gexchange in
pelites
This reaction is a classic thermometer.
Exchange between Mg, Fe, Ca and Mn
Temperature
g g, ,is favourable because of similarities in
ionic radii and same charge.
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Industrial and Economic Importance
All species, except uvarovite are cut as gemstones.The most valuable are green andradite (demantoid) from the Urals
and almandine from Gore Mountain (NY)and almandine from Gore Mountain (NY)
Th b h id l f t d l f t l d ith thThe subconchoidal fracture and angular fracture, coupled with the high hardness, also make garnet a valuable abrasive.
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Aluminosilicates (Al2SiO5)2 5
This is the general term for the three mineralskyanite sillimanite and andalusitekyanite, sillimanite and andalusite.
These three minerals are polymorphs and mayThese three minerals are polymorphs, and may be found in metamorphosed aluminous rocks.
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The stability of the phases is very well known of is of t l t t hi t lgreat value to metamorphic petrology
This is a famous diagram and can be used as a first approximation of
metamorphic conditions.p
Kyanite – High pressure – Subduction zones
Sillimanite – High pressure and temperature (regional)
Andalusite – High temperature – thermal metamorphism.
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Andalusite – Al[6]Al[5]SiO5 ‐ orthorhombic
The structure of the mineral consists of chains of AlO6 octahedra parallel to
the c‐axis.
Cross linked by AlO polyhedra andCross linked by AlO5 polyhedra and SiO4 tetrahedra.
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Andalusite is length fast has a high 2V andfast, has a high 2V, and is biaxial negative.
May be riddled with inclusionswith inclusions of quartz and
micas (“Chiastolite(“Chiastolite
cross”)
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Kyanite – Al[6]Al[6]SiO5 ‐ triclinic
The structure of the mineral consists of chains of AlO6 octahedra.
C li k d b AlO h d dCross linked by AlO6 octahedra and SiO4 tetrahedra.
Kyanite is typically colourless in TS. Has high relief, low BR, excellent l h hi h 2 d i bi i l icleavage, has a high 2V, and is biaxial negative.In the most part, it also has oblique extinction.
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Kyanite is typically colourless in TS. Has high relief, low BR, excellent cleavage has a high 2V and is biaxial negativecleavage, has a high 2V, and is biaxial negative.In the most part, it also has oblique extinction.
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Sillimanite – Al[6]Al[4]SiO5 ‐ orthorhombic
The structure of the mineral consists of chains of AlO6 octahedra parallel to
the c‐axis.
Cross linked by AlO4 and SiO4 tetrahedra.
Sillimanite is also known as fibrolite is typically colourless in TS HasSillimanite is also known as fibrolite, is typically colourless in TS. Has high relief, low BR, good cleavage, a low 2V, and is biaxial positive.
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Sillimanite is also known as fibrolite, is typically colourless in TS. Has high relief low BR good cleavage a low 2V and is biaxial positivehigh relief, low BR, good cleavage, a low 2V, and is biaxial positive.
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Industrial and Economic ImportanceLike many minerals, when occurring in optically perfect form, it can
be cut as a gemstone – particularly kyanite.
This absence of Fe in the aluminosilicates also makes them very
d hi h f igood high temperature refractories.
This property is exploited for the p p y pproduction of spark plugs and high
refractory porcelains.