Seung-Kon Lee - Mo-99 Technology...
Transcript of Seung-Kon Lee - Mo-99 Technology...
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Seung-Kon Lee Division of Radioisotope Research
Deptatment of HANARO Utilization Research
KAERI
12th Sept. 2015 Mo-99 Topical Meeting @ St. Louis, USA
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Contents
1. KJRR Project: Update
2. Fission 99Mo Production Facility Development
3. Fission 99Mo Production Process Development
4. Summary
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1. KJRR Project: Update
2. Fission 99Mo Production Facility Development
3. Fission 99Mo Production Process Development
4. Summary
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Kijang New Research Reactor Project
Insecurity of Medical Radioisotopes (Mo-99) Supply in Korea Major issue (Now 100% imported)
– Self-sufficiency of RI demand became an issue for health care
– Require to secure the medical welfare.
New Research Reactor Project in Korea
- Launched in 2012. - Location: Kijang, Busan. - Phase: PSAR review for C.L. - Aiming for 1st Criticality: March of 2019. - Fission Mo Production Capacity: 2,000Ci/w - NTD, Ir-192, I-125, Lu-177 etc.
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KJRR Location
KJRR
GORI NPP
Pacific (East Sea)
City of Busan (2nd, 3.5 M)
City of Ulsan (7th, 1.2 M)
Furthest from North Korea
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KJRR Location
KJRR
Heavy Ion Accelerator
Nuclear medical Science and Industry
Complex
RI Convergence Research Center
Hospital (Cancer center)
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Plot Plan: KJRR
7
Utility
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FMPF (Fission Molybdenum Production Facility)
RIPF (Radioisotope Production Facility)
Reactor
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8
Schedule
Construction Full-scale, Production Equipment
Research Fission Mo-99
Process
Launching (2012.03.01)
Development Proto-type
Processing Units Establishment QA/QC Protocols
Development U-Powder & Target
Fabrication
Fabrication Mini & Real Size
Targets
Establishment Target Production
Protocols
FM Production
Target Irradiation Test
at HANARO
March
Test Production at HANARO
Establishment Target
Production line
Establishment Mo-99
Production line Test
Production System
Reactor Criticality
HANARO will be back in Nov.
PSAR (Dec. 2016)
Construction Start (Jan. 2017)
Reactor assembly
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Contents
1. KJRR Project: Update
2. Fission 99Mo Production Facility Development
3. Fission 99Mo Production Process Development
4. Summary
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Arrangement of Reactor and FMPF
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FMPF General Arrangement
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Hot Cell for Fission Mo-99 Production (Two hot cell banks for back-up)
Hot Cell No. Name Function Hot Cell No.
Name Function
MA-2 Receiving Isolation of FMPF from Rx
MA-6 Packaging Packaging Mo-99 Solution
MA-3 Dissolution Target Dissolution MA-7 Distribution RI Target Transfer
MA-4/MA-5 Separation/ Purification
Mo-99 Separation/ Purification
MA-9 Waste Storage Temporary Storage for Solid Radwastes
Transfer Receiving Dissolution Sep./Purif. Pack.
FNI Dist. Waste Storage
U: 6-9 Months Iodine: 3-6 Months
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Hot Cell Cross Section
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Hot Cell Arrangement (Fl. 1)
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Long-term (50 yr.) Storage of U-Residue
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Disposal of ISW and LSW (other than U residues)
KORAD LILW disposal facility in Gyeongju (2014
Current plan: Cementation of ILW from FM production (Disposal experience)
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1. KJRR Project: Update
2. Fission 99Mo Production Facility Development
3. Fission 99Mo Production Process Development
4. Summary
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FM Target and KJRR Reactor Model
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FM Target Irradiation
KJRR Reactor Core
Fission Mo Target
Assembly
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FM Target Assembly (8 Plates with Combs)
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II. FMPF: FM Target Specification
Al 6061 T6 @cladding Al 1050 @ meat (matrix) UAlx powder @ meat
• Weight: 53 g • Total U: 15 g • Total U-235: 3 g • U density: 2.6 g-U/cc
Green light for the HANARO irradiation test
- Flow rate & pressure drop: satisfied - Vibration test: satisfied
60-days ex-core test
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Process Scheme
Uranium Filter
Iodine removal
Chemical Treat.
Dissolving process
Dissolution of Target in Alkaline Solution
Iodine Adsorption Column
Al removal
Conditioning
99Mo separation
Further purification
FM final product
Optimization for the Separation of 99Mo
Separation column
Purification columns
Spent Uranium
Uranium Precipitates
Other Wastes
Aluminum residue Iodine Column
ILW Generation
Intermediate Level Liquid Wastes
Vacuum Tank
QC/ Packaging & Transport
Iodine Removal Xenon Treatment
Fission Mo Targets (UAlx)
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Full-scale Prototype (cold test)
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DUAL SL2 Fil DUAL SL2 T 2Th/Th l k d St t 10 000 ° E d 69 998 ° St 0 021 ° St ti 19 2 T 25 °C (R ) Ti St t d 0 2 Th t 10 000 ° Th t 5 000 ° Chi
Lin
(C
ounts
)
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
2-Theta - Scale10 20 30 40 50 60 7
Dissolution
Na2U2O7 / UO2
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Fission Mo Production: Hot Test Module (1/8 scale)
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Fission Mo Production: Hot Test
Tool MCNP6
Result
(from
2 target
plates)
1 hr Irradiation – 0.1390 Ci
6 hr Irradiation – 0.8317 Ci
1 day Irradiation – 3.025 Ci
7 day Irradiation –10.84 Ci
Fission Mo Target (DU) Combustion Analysis
Irradiation in HANARO Fission Mo Target Capsule / Rig and Irradiation Hole
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Compact Xenon Treatment System (Cryogenic)
Experimental Setup Mark1
- Single column retains 7 batches - Integrated column now testing (TSA operation) - Continuous operation
Prototype Experimental Setup Mark2
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1. KJRR Project: Update
2. Fission 99Mo Production Facility Development
3. Fission 99Mo Production Process Development
4. Summary
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Summary
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1. Mo-99 facility and process development is in progress
2. KJRR project is moving forward in spite of some
obstacles: budget / licensing
3. Requesting hands from Mo-99 society (ILW disposal)
Summary
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Thank You !!!