Self-Levelling Flooring Compounds Based on Ternary Binder ... · Self-Levelling Flooring Compounds...
Transcript of Self-Levelling Flooring Compounds Based on Ternary Binder ... · Self-Levelling Flooring Compounds...
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Self-Levelling Flooring Compounds
Based on
Ternary Binder Systems
CIMSA Dry-Mix Mortar Seminar
Istanbul, 21 September 2017
Prof. Dr. Johann Plank
Technische Universität München
Chair for Construction Chemistry
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Content ……
….. Dry-Mix Mortar Products
….. Principle Properties of CAC
….. SLUs - Properties & Composition
….. Admixtures for SLUs
….. Raw Materials and Formulations
….. Ageing of SLUs
….. Conclusion
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Modern Building Technology
Phaeno Center, Wolfsburg
Residence of German
Chancellor, Berlin
© Prof. Plank 2017
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The Origin of Dry-Mix Mortar Technology
© Prof. Plank 2017
• rebuilding German cities
after World War II
• shortage of workers for con-
struction in the 1960s/1970s
• dry-mix mortar allows to
build faster and in
better qualityNuremberg, May 1945
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The Origin of Dry-Mix Mortar
- traditional building: manual mixing on construction site
- no quality control
- many workers required
In the 1970s, beginning of dry-mix mortar industry
Early mortar mixing machine from
Kalkwerk Mathis, Merdingen (early 1970s)
Traditional job-site mortar mixing
© Prof. Plank 2017
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Thin-Bed Tile Adhesives
• Thin-bed technology invented by Sponagel in Switzerland in 1930s
• First dry-mix CTA introduced in 1959 by ARDEX and
Polychemie GmbH (PCI) Augsburg
Laying tiles by conventional
„buttering“ method
Laying tiles by modern thin-
bed mortar technology
Thin-bed mortar allows to save approx. 35 % of material
© Prof. Plank 2017
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Wall Renders and Plasters
Exterior and interior wall
plasters / renders
© Prof. Plank 2017
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CTAs and Joint Fillers (Grouts)
Tile grout Flooring using CTA
© Prof. Plank 2017
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External Insulation and Finishing
System (EIFS)
Adhesives and mortars for EIFS
© Prof. Plank 2017
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© Prof. Plank 2012
EIFs Systems
© Prof. Plank 2017
- difficult to place
- expensive
- problem of waste
- fire hazard
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Fire at Grenfell Tower, London
• Fire on 14 June 2017
• at least 80 people were killed
• polystyrene boards behind Al sheets caught fire
© Prof. Plank 2017
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© Prof. Plank 2012
Fire Hazard of Conventional EIFS
Istanbul, July 2012
© Prof. Plank 2017
Shanghai, 2011
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Inorganic Insulation Materials
Glass wool
Mineral wool
Aerogel granulate
Application of aerogel render© Prof. Plank 2017
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Self-Levelling Underlayments (SLUs)
• Perfect self-spreading and self-healing property
• Excellent smooth surface
© Prof. Plank 2017
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Self-Levelling Underlayments (SLUs)
SLU based on a
ternary binder system
Demonstration of
self-levelling and self-healing
property of a SLU
© Prof. Plank 2017
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SLU Formulation Based on Ternary Binder
Grey alumina cement (~ 40 % Al2O3) for high early strength
Portland Cement (CEM I 42,5 R) 18,50 wt.-%
Calcium Alumina Cement (~ 40% Al2O3) 11,50 wt.-%
CaSO4 (synthetic anhydrite) 6,50 wt.-%
Quartz sand (0,1 to 0,315 mm) 41,00 wt.-%
Limestone powder (10 to 20 µm) 19,40 wt.-%
Casein or PCE (Superplasticizer) 0,40 wt.-%
Vinylacetate-Copolymer (Redispersible Powder) 2,00 wt.-%
NaK-tartrate (Retarder) 0,40 wt.-%
Li2CO3 (Accelerator) 0,10 wt.-%
Cellulose ether (Water Retention Agent) 0,05 wt.-%
Polyglycol (Defoamer) 0,15 wt.-%
Mixing Water (for 100 wt.-% powder blend) 20,00 wt.-%
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Dry-Mix Mortar Industry
© Prof. Plank 2017
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Content ……
….. Dry-Mix Mortar Products
….. Principle Properties of CAC
….. SLUs - Properties & Composition
….. Admixtures for SLUs
….. Raw materials and formulations
….. Ageing of SLUs
….. Conclusion
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Definition and Origin of CAC
Cements with at least 35 % of Al2O3
Main hydraulic phases: CA, C12A7 and less reactive CA2
1840 J.L. Vicat realized the sulfate resistance of CAC
1908 Industrial development of Aluminate Cement is
associated with the work of J. Bied (British Pat. 8193)
1918 Ciment Fondu first CAC marketed by Lafarge Company
After World War II, aluminate cement was developed as binder for refractory castables
In the 1950‘s, development of complex mortars containing combinations of aluminate
cement, Portland cement and Ca- Sulfates for the building industry (dry mortars)
© Prof. Plank 2017
Alumina cement based concrete used
in WW I for heavy guns
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Portland Cement
Aluminate Cement
Chemical Composition of Aluminate Cements
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Main Phases in CAC
• Monocalcium aluminate CA
• Grossite CA2
• Mayenite C12A7
• Gehlenite C2AS
• Belite C2S
• Ferrite C4AF CA CA2
C12A7 C2AS© Prof. Plank 2017
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Chemical Composition of Aluminate Cements
Oxide Aluminate Cement Portland Cement
Al2O3 36% to 80% 4% to 8%
CaO 20% to 42% 60% to 70%
SiO2 0,2% to 8% 18% to 24%
Fe2O3 0,2% to 20% 1% to 5%
TiO2 < 2%
MgO < 1% < 3%
Na2O < 0,3% < 1%
K2O < 0,1% < 1%
© Prof. Plank 2017
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2-Theta - Scale
Fondu
Secar 51
Secar 71 CA
CA
2
CA
CA
2
CA
CA
CA
CA
CA
CA
CA
XRD Diagrams of Aluminate Cement
15 20 30 40
Type
(white)
(grey)
(dark)
CA CA
2
CA
2
CA
CA
CA
CA
Geh
lenit
e
Per
ow
skit
e
CA
CA
CA
CA
CA
Ca3
Fe2
TiO
8
Geh
lenit
e
May
enit
e
Per
ow
skit
e
Bro
wnm
ille
rite
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Manufacture of Aluminate Cements
Raw Materials: Limestone and Bauxite
Usually made by melting in
furnaces at 1600 °C
Standard grade Aluminate Cement
Up to 50% Al2O3
Grades of higher Aluminate Cement
60% to 80% Al2O3
Usually made by sintering in
rotary kilns at 1450 °C
Up to 20% Fe2O3
Several per cent TiO2
Silica content must be fairly low
Very low Fe2O3
Very low SiO2
In many cases, red mud from the Bayer process is used as raw material
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Advantages of CAC vs. OPC
Rapid hardening with setting time similar to Portland Cement
High Resistance to sulfate attack and acids
Ability to withstand repeated heating to high temperatures
Ability to hydrate and perform at low temperatures (e.g. 2 °C)
Resistance to abrasion
Adjustable properties in mixtures with Portland Cement and
calcium sulfates
© Prof. Plank 2017
Unique properties of CAC:
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Alumina Cements harden more rapidly than Portland Cements;
within one or two days they reach their specified strength
0
10
20
30
40
50
60
70
80
co
mp
ressiv
e s
tre
ng
th
MP
a
3h 6h 1 day 7 days 28 days
OPC
CAC
0
5
10
15
20
25
30
0 10 20 30 40
Zeit [Stunden]
Wä
rme
flu
ß [
mW
/g] Fondu
PZ 42,5 Mielke Classic
Strength development of CAC and OPC Heat flow of CAC and OPC
CAC is used to accelerate strength development of OPC
CEM I 42,5 R Milke Classic
© Prof. Plank 2017
CAC 40 % Al2O3
CAC Develops Higher Early Strength Than OPC
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Shrinkage Behavior of Calcium Aluminate Cement
© Prof. Plank 2017
Addition od CAC to OPC compensates the shrinkage of OPC
through ettringite formation
Shrinkage as a function of alumina cement content in binder:
A = OPC; B = OPC-rich blend; C = CAC-rich blend
OPC
OPC/CAC
CAC/OPC
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Applications of Aluminate Cements
© Prof. Plank 2017
Corrosive
environments
Rotary Kiln, Cement Plant
Dry-mix mortars
Sewage pipes
Refractory
Tile grouts
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Benefits from Aluminate Cements
© Prof. Plank 2017
Self-levelling underlayment Tile adhesive
Cementitious tile grout
Quick
Drying
Rapid
Hardening
Shrinkage
Compensation
Chemical
Resistance
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Tile grouts: CAC vs. OPC
© Prof. Plank 2017
Tile grouts based on CAC are much more durable
CAC grout
Cleaning machine
dissolved OPC grout
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Content ……
….. Dry-Mix Mortar Products
….. Principle Properties of CAC
….. SLUs - Properties & Composition
….. Admixtures for SLUs
….. Raw Materials and Formulations
….. Ageing of SLUs
….. Conclusion
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Self-Levelling Underlayments (SLUs)
© Prof. Plank 2017
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Three Principle Types of SLUs
© Prof. Plank 2017
Component CAC -rich w/CSA cement OPC - rich
CAC 40 27 % 48 % 56 %
OPC 54 % - 30 %
β - HH - 17 % 14 %
α - HH 19 % - -
CSA - 35 % -
Superplasticizer 0.38 – 0.78 %
Set Control agents 1 – 2 %
Na3-citrate × × ×
Tartaric acid × × ×
Li2CO3 × × ×
Na2CO3 × - -
Ca(OH)2 × - -
Water-to-Binder 0.59 0.76 0.92
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CAC – Rich SLU Formulation
Component Function Mass %
CAC 40 % Al2O3 Aluminate Cement 18.00
CEM I 52,5 N Portland Cement 3.60
CaSO4 ∙ 0.5 H2O HH - Binder 6.30
CaCO3 powder Filler 24.35
Sand Filler 45.34
Tartaric acid Retarder for OPC 0.06
Li2CO3 Accelerator for CAC 0.03
RDP Latex Powder Provides adhesion 2.00
Polyglycol Defoamer 0.10
Methyl cellulose Water retention 0.10
PCE powder Superplasticizer 0.12
Total 100.00
Water 23.00
Water/Cement Ratio 1.06
Water/Binder Ratio 0.82
© Prof. Plank 2017
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OPC – Rich SLU Formulation
Grey alumina cement (~ 40 % Al2O3)
Portland Cement (CEM I 42,5 R) 18,50 wt.-%
Calcium Alumina Cement (~ 40% Al2O3) 11,50 wt.-%
CaSO4 (synthetic anhydrite) 6,50 wt.-%
Quartz sand (0,1 to 0,315 mm) 41,00 wt.-%
Limestone powder (10 to 20 µm) 19,40 wt.-%
Casein or PCE (Superplasticizer) 0,40 wt.-%
Vinylacetate Copolymer (Redispersible Powder) 2,00 wt.-%
NaK tartrate (Retarder) 0,40 wt.-%
Li2CO3 (Accelerator) 0,10 wt.-%
Cellulose ether (Water Retention Agent) 0,05 wt.-%
Polyglycol (Defoamer) 0,15 wt.-%
Mixing Water (for 100 wt.-% Powder blend) 20,00 wt.-%
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Setting Time of Mixtures CAC/OPC
• blends of CAC and OPC often show
extremely fast setting
no workability
• only CAC/OPC 20:80 or 85:15 work
• retarders for OPC required to prevent
rapid setting
© Prof. Plank 2017
CAC-
rich
OPC-
rich
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Combinations of Alumina Cement and Portland Cement
Mixtures of OPC and CAC are used to accelerate setting/strength
development of cement
Such mixtures show lower compressive strength than pure OPC or CAC
0
10
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0 20 40 60 80 100
Alumina Cement %
Co
mp
ressiv
e S
tre
ng
th [M
Pa
]
28d
7d
1d
6h
3h
Compressive strength
of OPC and CAC
combinations
© Prof. Plank 2017
Pure
OPC
Pure CAC
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Combination of Alumina Cement and Portland Cement
Influence of OPC type on setting time
Combinations of CAC and Portland cement are very sensitive
to variations in OPC composition
Influence of OPC type
on 1 day compressive strength
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0% 5% 10% 15% 20% 25% 30% 35% 40% 45%
Alumina Cement added
Initi
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et [
min
]
Portland Cement A
Portland Cement B
Portland Cement C
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0% 5% 10% 15% 20% 25% 30% 35% 40% 45%
Alumina Cement added
com
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ssiv
e s
trength
Portland Cement A
Portland Cement B
Portland Cement C
© Prof. Plank 2017
AB C B
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Rapid Hardening Owed to Ettringite Formation
© Prof. Plank 2017
Ettringite
Ettringite crystals formed in the matrix of a ternary binder
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Rapid Drying of SLU
„Chemical“ drying owed to huge water consumption for ettringite formation
3 CaAl2O4 + 3 CaSO4 ∙ 0.5 H2O [Ca3Al(OH)6•12H2O]2•(SO4)3•2H2O
Ettringite crystalsStructure of ettringite, showing
plenty of water molecules
ettringite
© Prof. Plank 2017
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Shrinkage Behavior of SLUs
Shrinkage compensation through addition of alumina cement
© Prof. Plank 2017
Reason for reduced shrinkage: expansion because of ettringite formation
OPC
OPC-rich
CAC-rich
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Shrinkage of OPC
OPC develops high shrinkage
After addition of superplasticizers shrinkage becomes even much higher
ettringite formation in ternary binder compensates shrinkage from OPC
Anhydrite (CaSO4)
floor screed
Shrinkage-reduced
cement screed
OPC - based screed
OPC - based screed
with superplasticizer
© Prof. Plank 2017
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Shrinkage of Hardened Cement
Chemical shrinkage Drying shrinkage
Only pores between 10 and 100 nm
cause shrinkage© Prof. Plank 2017
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Shrinkage Problem of Floor Screeds
Dry Shrinkage
- Severe at high w/c ratio (e.g. 0.70)
Chemical Shrinkage
- Severe at low w/c ratio (e.g. 0.40)
Drying shrinkageChemical shrinkage
© Prof. Plank 2017
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Experimental Determination of Chemical and
Drying Shrinkage
© Prof. Plank 2017
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Content ……
….. Dry-Mix Mortar Products
….. Principle Properties of CAC
….. SLUs - Properties & Composition
….. Admixtures for SLUs
….. Raw Materials and Formulations
….. Ageing of SLUs
….. Conclusion
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Portland cement (CEM I 42,5 R) 18,50 mass-%
Grey alumina cement (ca. 40 % Al2O3) 11,50 mass-%
Calcium sulfate (anhydrous, synthetic anhydrite) 6,50 mass-%
Silica sand (0,1 - 0,315 mm) 41,00 mass-%
Limestone powder (calciumcarbonate, 10 - 20 µm) 19,40 mass-%
Superplasticizer casein or PCE 0,40 mass-%
Latex polymer (redispersible powder based on vinylacetate) 2,00 mass-%
Retarder (K/Na tartrate / trisodium citrate) 0,40 mass-%
Accelerator (lithium carbonate) 0,10 mass-%
Stabilizer (cellulose ether, low-viscosity type) 0,05 mass-%
Defoamer (powder) 0,15 mass-%
Sum of powder components Total 100,00 mass-%
Water (for 100,00 mass-% powder): 20,00 mass-%
SLU Formulation Based on Ternary Binder
© Prof. Plank 2017
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Casein Superplasticizer
- casein content in bovine milk 2,5 - 3%
- heterogeneous mixture of partly
glycosylated phosphoproteins
- manufactured by acid precipitation
from milk at pH 4,6 / 20 °C
Four major casein fractions:
-casein ~ 50%
β-casein 35- 40%
κ-casein ~ 10%
γ-casein < 5%
© Prof. Plank 2017
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Casein Superplasticizer in SLU
Superplasticizers: Casein
Melamine Formaldehyde Sulfite (MFS) Polycondensate
Polycarboxylate (PCE)
© Prof. Plank 2017
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Casein Forms Micelles
Casein micelle according to WALSTRA (1999)
Sub-micelles :
hydrophobic core, consisting
of 20-25 -/b- caseins and
calcium phosphate
Micelle :
Electrostatic and steric stabilization
through formation of an outer ``hairy
layer´´, containing hydrophilic
saccharide residues from the k-
caseins© Prof. Plank 2017
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-Casein
- 199 amino acids with 8 phosphate groups
- phosphate groups esterified with serine
- net anionic charge: –24 (at pH 6,7)
- above 2 mmol/L Ca2+ charge neutralization
precipitationPhosphoserine
CH2
O
H3N
O
H
P
O
OO
O-
-
+
-
Tertiary structure of αS1-casein
~ 50,8 % in bovine casein
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209 amino acids and 5 phosphate groups
net anionic charge –13 (at pH 6,7)
Formation of Ca precipitate depends on temperature
b- Casein
Tertiary structure of β1-casein
~ 36,3 % in bovine casein
© Prof. Plank 2017
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k- Casein
- 169 amino acids, up to 5
trisaccharide groups
- only one phosphate group
- net anionic charge –11 (at pH 6,7)
- charge derives from glutamine and
asparagine and saccharides
- soluble in presence of calcium
sialinic acid
Tertiary structure of κ1-casein
~ 12,9 % in bovine casein
© Prof. Plank 2017
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Spread of SLU in mini slump test :
Dispersing Effect of Casein Protein
Fractions
© Prof. Plank 2017
α-casein
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Problems Associated with Casein
• Unstable quality
• Decomposes in alkaline cement strong smell of ammonia !
• Enhances proliferation of mould “sick house syndrom“
Replacement by PCEs
© Prof. Plank 2017
Mould
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PCEs in SLUs
• Excellent dispersing performance…….
but……
• poor compatibility with retarders (tartrate, citrate)
• no self-healing property
60
80
100
120
140
160
0 10 20 30 40 50 60
time after water addition [min]
slu
mp
flo
w [
mm
] Tartrat (0,4%)
Citrat (0,4%)
fsafsffs
Tartrat (0,4%)
Citrat (0,4%)
Casein (0,4%) w ith:
PCE (0,4%) w ith:
© Prof. Plank 2017
This PCE is not compatible with citrate
PCE: poor fluidity with citrate
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Adsorption of Casein with/without Retarder
80 80 80
50
0
10
20
30
40
50
60
70
80
90
100
Ad
so
rpti
on
sra
te [
%]
Casein mit Tartrat Casein mit Citrat
© Prof. Plank 2017
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Adsorption of PCE with / without Retarder
0
10
20
30
40
50
60
70
80
90
100
PC mit Tartrat PC mit Citrat
67
48
67
7
Ad
so
rpti
on
[%
]
© Prof. Plank 2017
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Optimized PCE For Ternary SLU
82
47
82
56
0
10
20
30
40
50
60
70
80
90
100
Ad
so
rpti
on
[%
]
PC 2 mit Tartrat PC 2 mit Citrat
Optimized PCE has high anionic charge density
© Prof. Plank 2017
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Rapidly Dissolving PCE Powder
© Prof. Plank 2017
Modified PCEs which hydrate and adsorb immediately (e.g. Melflux® 5581)
Cementitious flowing floor screed
PCE Molecule
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Self-Healing Property of PCE-Based SLU
© Prof. Plank 2017
• requires a second admixture: „viscosity - modifying agent“ (VMA)
• e.g. copolymer of AMPS/NNDMA („Starvis“, BASF)
• combination of PCE and VMA provides comparable properties than from
casein
AMPS/NNDMA copolymer
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Tartrate and Citrate Retarders
© Prof. Plank 2017
• generally, tartrate works better as retarder than citrate and is more
compatible with superplasticizers
• however, tartrate is more expeasive
• tartrate has to be the NaK salt of natural tartaric acid („Seignette salt“,
L(+) type), not of the D(-) type or the racemic mixture !
L(+) tartaric acid
citric acid
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Content ……
….. Dry-Mix Mortar Products
….. Principle Properties of CAC
….. SLUs - Properties & Composition
….. Admixtures for SLUs
….. Raw Materials and Formulations
….. Conclusion
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CAC - Rich PCE-Based SLU
© Prof. Plank 2017
CAC 40 % Al2O3 20.0 Mass %
CEM I 52.5 R 4.0 Mass %
α - hemihydrate 7.0 Mass %
Durcal 15 (limestone) 19.0 Mass %
Durcal 130 (limestone) 9.0 Mass %
Sand (0 - 0.315 mm) 37.8 Mass %
Li2CO3 0.1 Mass %
Citric acid, Na salt 0.02 Mass %
PCE (Melflux, BASF) 0.25 Mass %
VMA (Starvis, BASF) 0.05 Mass %
MHEC Dow 0.05 Mass %
RDP (Vinnapas, Wacker) 2.00 Mass %
Defoamer (Agitan, Münzing) 0.10 Mass %
Water 24.00 Mass %
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CAC - Rich PCE-Based SLU
© Prof. Plank 2017
CAC 40 % Al2O3 60.00 Mass %
CEM I 32.5 R (Heidelberg) 39.00 Mass %
Anhydrite (Solvay, Hannover) 36.00 Mass %
Quartz sand (H33, 0.1 - 0.315 mm) 83.70 Mass %
CaCO3 powder (Omyacarb 20 - BG) 72.70 Mass %
Calciumhydroxide 4.50 Mass %
PCE (Melflux PP 100 F, BASF) 2.70 Mass %
RDP (Vinnapas RE 523 Z, Wacker) 4.50 Mass %
Tartaric acid (L(+), Merck) 0.90 Mass %
Li2CO3 (< 40 µ, Chemetall) 0.90 Mass %
MHEC (Walocel MT 400, Dow) 0.09 Mass %
Defoamer (Agitan P 800, Münzing) 0.60 Mass %
Water demand: ~ 20 mL for 100 g dry blend
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CAC - Rich Melamine-Based SLU
© Prof. Plank 2017
CAC 40 % Al2O3 200.00 Mass %
CEM I 32.5 R (Heidelberg) 100.00 Mass %
Anhydrite (Solvay) 125.00 Mass %
Sand (H33, Quarzwerke Köln) 300.00 Mass %
CaCO3 powder (Omyacarb 20 - BG) 240.00 Mass %
MFS (Melment F 10, BASF) 6.00 Mass %
RDP (Vinnapas RE 523 Z, Wacker) 25.00 Mass %
Tartaric acid (L(+), Merck) 1.00 Mass %
MHEC (Tylose H 300P, SE Tylose) 1.00 Mass %
Li2CO3 (< 40 µ, Chemetall) 0.80 Mass %
SRA (1,6 - Hexanediol, BASF) 5.00 Mass %
Defoamer (Agitan P 800, Münzing) 2.00 Mass %
Water demand: 22 mL for 100 g dry blend
Open time: ~ 20 min
Walk-on time: ~ 2.5 hours (shore D ≥ 50)
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OPC - Rich Melamine-Based SLU
© Prof. Plank 2017
CEM I 32.5 R (Heidelberg) 300.00 Mass %
CAC 40 % Al2O3 70.00 Mass %
Anhydrite (Solvay, Hannover) 50.00 Mass %
Quartz sand (H33, Quarzwerke Köln) 379.20 Mass %
CaCO3 powder (Omyacarb 20 - BG) 165.00 Mass %
MFS (Melment F 10, BASF) 6.00 Mass %
RDP (Vinnapas RE 523Z, Wacker) 20.00 Mass %
Tartaric acid (L(+), Merck) 1.70 Mass %
Li2CO3 (< 40 µ, Chemetall) 0.60 Mass %
MHEC (Walocel MT 400, Dow) 1.00 Mass %
SRA (1,6 - hexanediol, BASF) 5.00 Mass %
Defoamer (Agitan P 800, Münzing) 1.50 Mass %
Water demand: 22 mL for 100 g dry blend
Open time: ~ 35 min
Walk-on time: ~ 7 hours (shore D ≥ 50)
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OPC - Rich Casein-Based SLU
© Prof. Plank 2017
CEM I 32.5 R (Heidelberg) 54.00 Mass %
CAC 40 % Al2O3 36.00 Mass %
Anhydrite (Solvay, Hannover) 21.00 Mass %
Quartz sand (H33, 0.1 - 0.315mm) 120.00 Mass %
CaCO3 powder (Omyacarb 20 BG) 61.95 Mass %
Casein (Ardex) 1.20 Mass %
RDP (Vinnapas RE 523Z, Wacker) 4.50 Mass %
Na3 - citrate (Merck) 0.60 Mass %
Li2CO3 (< 40 µ, Chemetall) 0.30 Mass %
MHEC (Tylose H 300P, SETylose) 0.15 Mass %
Defoamer (Agitan P 800, Münzing) 0.30 Mass %
Water demand: ~ 20 mL for 100 g dry blend
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Content ……
….. Dry-Mix Mortar Products
….. Principle Properties of CAC
….. SLUs - Properties & Composition
….. Admixtures for SLUs
….. Raw Materials and Formulations
….. Ageing of SLUs
….. Conclusion
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SLU Formulation Tested
© Prof. Plank 2017
SLU prehydrated for 1 or 3 days at 35 °C @ 90 % RH
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Rapid Moisture Uptake by SLU
© Prof. Plank 2017
SEM imagesfresh SLU
SLUaged 1 day
SLUaged 3 days
Ettringite crystalsEttringite crystals
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Impact of Moisture on Flow Behaviour of SLU
© Prof. Plank 2017
System PCE - Tartrate
fresh SLU is relatively tolerant
towards increased water contents
Ageing affects SLU stronger than variation of w/b ratio in fresh SLU
• fresh SLU – good flowabilityw/b = 0.25
• aged SLU – no flowabilityat w/b = 0.25
Time (min)
w/binder ratio
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Impact of Moisture Uptake on Flow Behavior of SLU
© Prof. Plank 2017
System PCE - Tartrate
Workability of aged SLU with tartrate significantly lower
Time (min)
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1 Day Ageing – Comparison Tartrate / Citrate
© Prof. Plank 2017
Tartrate Citrate
System PCE – Tartrate / Citrate (w/b = 0.25)
After only 1 day of exposure to moist air, SLU containing tartrate or citrate was no longer fluid;but tartrate system behaved better than citrate system
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Flow Behavior of SLU with Citrate
© Prof. Plank 2017
System PCE – Citrate dosages 0.44/ 0.44 M.-%
In the aged SLU, the retarding effect of citrate becomes stronger,leading to longer open times but poor fluidity
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Lower compressive
strength because of
higher water demand
and air voids
Compressive Strengths: Fresh vs. Aged SLU
fresh SLU aged SLU
fresh prehydrated0
10
20
30
40
50
60
70
80
Co
mp
ressiv
e s
tre
ng
th (
N/m
m2)
- 40 %
SLU: citrate + PCE
aged 1 dfreshSEM
1 day compressive strength
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© Prof. Plank 2017
Compressive Strengths: Fresh vs. Aged SLU
Comparison of different admixture combinations
fresh prehydrated0
10
20
30
40
50
60
70
80
Co
mp
ressiv
e s
tren
gth
(N
/mm
2)
- 50 %
tartrate + casein
aged 1 d
citrate + PCE
fresh prehydrated0
10
20
30
40
50
60
70
80
Co
mp
res
siv
e s
tre
ng
th (
N/m
m2)
- 40 %
aged 1 d fresh prehydrated0
10
20
30
40
50
60
70
80C
om
pre
ss
ive s
tren
gth
(N
/mm
2)
- 40 %
citrate + casein
aged 1 dfresh fresh fresh
1 day compressive strengths
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© Prof. Plank 2017
Prism prepared from fresh SLU (w/b = 0.25)
Prism prepared from aged SLU (w/b = 0.27)
Aged SLU
contains
air voids
Water Demand and Appearance of SLU
SLU with citrate and PCE, aged 1 day
w/b ratio adjusted to18 cm flow
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© Prof. Plank 2017
CaSO4
CAC
CAC
1 cmfresh aged
Compressive Strengths: Fresh vs. Aged SLU
SLU: citrate + PCE
SLU aged 1 day contains unreacted binders (CAC, anhydrite)
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Appearance of Aged SLU
© Prof. Plank 2017
Gypsum
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Packaging Requirements For SLUs
• bags must have a plastic inlet which functions as a water vapor barrier
• some SLU producers use bags with Al foil inside, similar as in some food
products
© Prof. Plank 2017
Al foil
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Content ……
….. Dry-Mix Mortar Products
….. Principle Properties of CAC
….. SLUs - Properties & Composition
….. Admixtures for SLUs
….. Raw Materials and Formulations
….. Ageing of SLUs
….. Conclusion
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Summary - Part I
• SLUs are high - performance dry mixes
• SLUs provide a perfect smooth substrate for tiles, carpets, parquet,
vinyl floors etc.
• SLUs are easy to place and spread
• SLUs develop strength rapidly, owed to CAC
• Especially CAC - rich formulations can be walked on within 2 - 3 hours
• Rapid and massive ettringite formation provides „chemical“ drying and
shrinkage compensation
© Prof. Plank 2017
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Summary - Part II
• SLUs require high quality packaging (bags) and fresh cements
• SLUs require proper on-site mixing device
Western Europe: batch mixing in bin Scandinavia: mixing by machine
© Prof. Plank 2017
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Why CAC - Based SLU ?
• SLUs can be formulated as well based on α-hemi hydrate ….
but ……….
• CaSO4 - based SLUs show longer walk-on times and slower strength development
• CaSO4 - based SLUs develop a glass-like skin of CaCO3/superplasticizer on the
surface which prevents proper adbesion of the next layer (tiles, carpet…)
• Glassy layer has to be removed by using a milling machine
costly additional step!
• Gypsum is not water - resistant!
Milling machine
Removing glassy skin of
gypsum-based SLU
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SLUs – Perfect Products For Modern Building
© Prof. Plank 2017
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Chair For Construction Chemistry at
TU München
© Prof. Plank 2017
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International PCE Conference 2017
2nd International Conference
on Polycarboxylate Superplasticizers
(PCE 2017)
September 27 - 28, 2017
Munich, Germany
www.pce-conference.org
Hosted by