Self Healing Systems in Aircraft

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    SELF HEALING SYSTEMS IN AIRCRAFT

    Contents:

    1. Abstract

    2. Introduction. Causes o! aircra!t !ai"ure

    #. se"!$%ea"in& 'ateria"s

    (. t)*es o! %ea"in& *o")'ers

    +. se"!$%ea"in& conce*ts

    ,. Ad-anta&es

    . /isad-anta&es

    0. Conc"usion

    1.Future sco*e

    11.Re!erences

    Abstract:

    A new technique that mimics healing processes found in nature could enable

    damaged aircraft to mend themselves automatically, even during a flight. Self-

    healing materials are a class of materials that have the structurally incorporated

    ability to repair damage caused by mechanical usage over time. The inspiration

    comes from biological systems, which have the ability to heal after being

    wounded. Initiation of cracks and other types of damage on an aircraft has beenshown to change thermal, electrical, and acoustical properties, and eventually lead

    to whole scale failure of the aircraft sometimes. or a material to be defined as

    self-healing, it is necessary that the healing process occurs without human

    intervention.

    Self-healing, how it works! If a tiny hole"crack appears in the aircraft #e.g. due to

    wear and tear, fatigue, a stone striking the plane etc.$, epo%y resin would &bleed&

    from embedded vessels near the hole"crack and quickly seal it up, restoring

    structural integrity. 'y mi%ing dye into the resin, any &self-mends& could be made toshow as colored patches that could easily be pinpointed during subsequent ground

    inspections, and a full repair carried out if necessary. In tests, the self-healed

    composite material regained as much as () percent of its original strength.

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    As well as the obvious safety benefits, this breakthrough could make it possible to

    design lighter airplanes in the future. This would lead to fuel savings, cutting costs

    for airlines and passengers and reducing carbon emissions too.

    Introduction:

    Self-healing can be de*ned as the ability of a material to heal #recover"repair$

    damages automatically and autonomously, that is, without any e%ternal

    intervention. +any common terms such as self-repairing, autonomic-healing, and

    autonomic-repairing are used to de*ne such a property in materials. Incorporation

    of self-healing properties in manmade materials very often cannot perform the self-

    healing action without an e%ternal trigger. Thus, self-healing can be of the

    following two types $ autonomic #without any intervention$,2)nonautonomic

    #needs human intervention"e%ternal triggering$.

    Causes o! aircra!t !ai"ure:

    ommonly, failures are associated with stress concentrations, which can occur for

    several reasons including

    . /esign errors, #e.g. the presence of holes, notches, and tight fillet radii$.

    0. The microstructure of the material may contain voids, inclusions etc.

    1. orrosive attack of the material, #e.g. pitting, can also generate a local stressconcentration$.

    ommon failure modes of aircraft

    atigue.

    /uctile or overload.

    orrosion.

    Stress corrosion.

    2ydrogen embrittlement.

    3%cessive yielding.

    4verheating"fire.

    There are types of failures in aircraft also namely

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    $normal failure.

    0$medium failure,

    1$catastrophic failure.

    A normal failure is a small failure which occurs generally in every 561 hours ofan aircraft and the aircraft can complete its mission if it is a normal failure.

    A medium failure is a some more damaged than the normal and immediate

    assistance is required and the aircraft should be landed.

    atastrophic failure is the failure in which the entire aircraft goes down any

    assistance is also waste and the aircraft should be removed.

    Se"!$%ea"in& 'ateria"s:

    Self-healing materials are a class of smart materials that have the structurally

    incorporated ability to repair damage caused by mechanical usage over time.

    Self-healing polymers and fiber-reinforced polymer composites possess the

    ability to heal in response to damage wherever and whenever it occurs in the

    material.

    All classes of polymers, from thermosets to thermoplastics to elastomers,

    have potential for self-healing.

    igure shows the stretchable self-healing polymer and the figure 0 showsthe micro capsule releasing a healing agent.

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    igure stretchable self-healing polymer

    Fi&ure 2:+icro capsules releasing a healing agent

    7ormally what happens is if any modes of failure occur structurally then the

    gas or liquid comes from the tube and structural damaged gets sealed.

    The inspiration comes from biological systems, which have the ability to

    heal after being wounded. Initiation of cracks and other types of damage on

    a microscopic level has been shown to change thermal, electrical, and

    acoustical properties, and eventually lead to whole scale failure of the

    material. 8sually, cracks are mended by hand, which is unsatisfactory

    because cracks are often hard to detect. A material that can intrinsically

    correct damage caused by normal usage could lower costs of a number of

    different industrial processes through longer part lifetime, reduction of

    inefficiency over time caused by degradation, as well as prevent costs

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    incurred by material failure. or a material to be strictly defined as self-

    healing, it is necessary that the healing process occurs without human

    intervention. Some e%amples shown below, however, include healing

    polymers that require intervention to initiate the healing process.

    T)*es o! %ea"in& *o")'ers:

    o")'er brea3do4n:rom a molecular perspective, traditional polymers

    yield to mechanical stress through cleavage of sigma bonds. 9hile newer

    polymers can yield in other ways, traditional polymers typically yield

    through homolytic or heterolytic bond cleavage. The factors that determine

    how a polymer will yield include type of stress, chemical properties

    inherent to the polymer, level and type of solvation, and temperature. rom a

    macromolecular perspective, stress induced damage at the molecular level

    leads to larger scale damage called microcracks. A microcrack is formedwhere neighboring polymer chains have been damaged in close pro%imity,

    ultimately leading to the weakening of the fiber as a whole.

    Ho'o")tic bond c"ea-a&e:

    :olymers have been observed to undergo homolytic bond cleavage through

    the use of radical reporters such as /::2 #0,0-diphenyl--picrylhydra;yl$

    and :+7' #pentamethylnitrosoben;ene.$ 9hen a bond is cleaved

    homolytically, two radical species are formed which can recombine to repair

    damage or can initiate other homolytic cleavages which can in turn lead tomore damage. igure shows the 2omolytic bond cleavage of polymer

    #methyl methacrylate$.

    igure homolytic bond cleavage of polymer #methyl methacrylate$

    Hetero")tic bond c"ea-a&e:

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    :olymers have also been observed to undergo heterolytic bond cleavage

    through isotope labeling e%periments. 9hen a bond is cleaved

    heterolytically, cationic and anionic species are formed which can in turn

    recombine to repair damage, can be quenched by solvent, or can react

    destructively with nearby polymers, figure 0 shows the 2eterolytic bondcleavage of polyethylene glycol.

    Fi&ure 2:2eterolytic bong cleavage of polyethylene glycol

    Re-ersib"e bond c"ea-a&e:

    ertain polymers yield to mechanical stress in an atypical, reversible

    manner. /iels-Alder-based polymers undergo a reversible cycloaddition,

    where mechanical stress cleaves two sigma bonds in a retro /iels-Alder

    reaction. This stress results in additional pi-bonded electrons as opposed to

    radical or charged moieties.

    Su*ra'o"ecu"ar brea3do4n:

    Supramolecular polymers are composed of monomers that interact non-

    covalently. ommon interactions include hydrogen bonds, metal

    coordination, and van der 9aals forces. +echanical stress in supramolecular

    polymers causes the disruption of these specific non-covalent interactions,

    leading to monomer separation and polymer breakdown.

    Re-ersib"e %ea"in& *o")'ers:

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    e%ternal stimulus for it to occur. or a reversible healing polymer, if the

    material is damaged by means such as heating and reverted to its

    constituents, it can be repaired or =healed= to its polymer form by applying

    the original condition used to polymeri;e it.

    Co-a"ent") bonded s)ste':

    /iels-Alder and

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    There are different methods to effect healing that are applicable for each

    individual mode of damage as well as each unique damaged material. Self-

    healing has been demonstrated by some of these conceptual approaches

    apsule-based healing systems.

    ascular healing systems.

    Intrinsic healing polymers.

    arbon 7ano tubes #7Ts$.

    +icroencapsulated 2ealing systems.

    2ollow tube approach

    SBI:S

    /irect Ink 9riting

    /iscrete channels

    Ca*su"e$ based %ea"in& s)ste':

    apsules containing the healing agents and other chemicals are distributed

    throughout the material. If a breakage occurs, the capsules release their contents

    causing a chemical reaction to =heal= the breakage. If the amount of damage is

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    microscopic, capsule-based is the best option

    Fi&ure 1:Sequester healing agents in capsule-based system.

    5ascu"ar %ea"in& s)ste's:

    ascular systems use networks of refillable channels #like capillaries, veins and

    arteries$ within the material to deliver the healing agent to the site of damage and

    polymeri;es to the breakage point. ascular networks offer e%ceptional healing

    efficiency and vast possibilities.

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    Fi&ure 2:

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    one maDor factor to take into account is that the closer the tubes are together, the

    lower the strength will be, but the more efficient the recovery will be. A sandwich

    structure is a type of discrete channels that consists of tubes in the center of the

    material, and heals outwards from the middle. The stiffness of sandwich structures

    is high, making it an attractive option for pressuri;ed chambers. or the most partin sandwich structures, the strength of the material is maintained as compared to

    vascular networks. Also, material shows almost full recovery from damage.

    /irect In3 6ritin&:

    The /irect Ink 9riting #/I9$ technique is a controlled e%trusion of viscoelastic

    inks to create three-dimensional interconnected networks. It works by first setting

    organic ink in a defined pattern. Then the structure is infiltrated with a material like

    an epo%y. This epo%y is then solidified, and the ink can be sucked out with amodest vacuum, creating the hollow tubes.

    Microca*su"e %ea"in&:

    This method is similar in design to the hollow tube approach. +onomer is

    encapsulated and embedded within the thermosetting polymer. 9hen the crack

    reaches the microcapsule, the capsule breaks and the monomer bleeds into the

    crack, where it can polymeri;e and mend the crack.

    igure 1 /epiction of crack propagation through microcapsule-imbedded material.

    +onomer microcapsules are represented by pink circles and catalyst is shown by

    purple dots.

    A good way to enable multiple healing events is to use living #or unterminated

    chain-ends$ polymeri;ation catalysts. If the walls of the capsule are created too

    thick, they may not fracture when the crack approaches, but if they are too thin,

    they may rupture prematurely. In order for this process to happen at roomtemperature, and for the reactants to remain in a monomeric state within the

    capsule, a catalyst is also imbedded into the thermoset. The catalyst lowers the

    energy barrier of the reaction and allows the monomer to polymeri;e without the

    addition of heat. The capsules #often made of wa%$ around the monomer and the

    catalyst are important maintain separation until the crack facilitates the reaction.

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    There are many challenges in designing this type of material. irst, the reactivity of

    the catalyst must be maintained even after it is enclosed in wa%. Additionally, the

    monomer must flow at a sufficient rate #have low enough viscosity$ to cover the

    entire crack before it is polymeri;ed, or full healing capacity will not be reached.

    inally, the catalyst must quickly dissolve into monomer in order to reactefficiently and prevent the crack from spreading further.

    This process has been demonstrated with dicyclopentadiene #/:/$ and Erubbs&

    catalyst #ben;ylidene-bis#tricyclohe%ylphosphine$dichlororuthenium$. 'oth /:/

    and Erubbs& catalyst are imbedded in an epo%y resin. The monomer on its own is

    relatively unreactive and polymeri;ation does not take place. 9hen a microcrack

    reaches both the capsule containing /:/ and the catalyst, the monomer is

    released from the coreFshell microcapsule and comes in contact with e%posed

    catalyst, upon which the monomer undergoes ring opening metathesispolymeri;ation #

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    Carbon Nano tubes 7CNTs8:

    'y infusing a polymer with electrically conductive carbon 7ano tubes once a crack

    is located, an electrical charge is sent to the area in order to heat up the carbon7ano tubes and in turn melt an embedded healing agent that will flow into and seal

    the crack with a (5 percent recovery in strength.

    Fi&ure #:arbon 7ano tubes healing system

    Ad-anta&es:

    3ffectively reducing the weight of planes and thus both their fuel needs andcarbon emissions.

    2igher volume of healing agent is available to repair damage.

    /ifferent activation methods"types of resin can be used.

    isual inspection of the damaged site is feasible.

    2ollow fibers can easily be mi%ed and tailored with the conventional

    reinforcing fibers.

    /isad-anta&es:

    ibers must be broken to release the healing agent

    Bow-viscosity resin must be used to facilitate fiber infiltration.

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    +ultistep fabrication is required.

    Conc"usion:

    Self-healing approaches applied in composite materials to-date have

    primarily been bio inspired.

    A more recent advance is the detailed study of natural healing to allow true

    biometric self-healing.

    Tailored placement of healing components and the adoption of biometric

    vascular networks for self-healing are very active research topics at the

    cutting edge of self-healing.

    Future sco*e:

    A self-healing aircraft could be available in the near future, an epo%y

    resin that bleedsC from embedded vessels near the holes or cracks and

    quickly seals them up, restoring structural integrity.

    As well as the obvious safety benefits, this breakthrough could make it

    possible to design lighter aero planes in the future.

    This would lead to fuel savings, cutting costs for airlines and passengers and

    reducing carbon emissions too.

    Re!erences:

    1. S4a*an 9u'ar G%os% Se"!$%ea"in& Materia"s: Funda'enta"s; /esi&n

    Strate&ies; and A**"icationsac; 9at%erine First Se"!$Hea"in& Coatin&s 7%tt*:? ? 444.

    tec%no"o&) re-ie4. co'? business? 2112?@ a!8. tec%no"o&)re-ie4.co'.

    /ece'ber 12; 2.

    . Se"!$%ea"in& 'ateria" Source: %tt*:??en.4i3i*edia.or&?4?indeB.*%*@

    o"did+220((21.

    #. 6einer; S. and 6a&ner; H./. 71008 Annua" Re-ie4 o! Materia"s

    Science; 2.

    http://en.wikipedia.org/w/index.php?oldid=622955021http://en.wikipedia.org/w/index.php?oldid=622955021http://en.wikipedia.org/w/index.php?oldid=622955021http://en.wikipedia.org/w/index.php?oldid=622955021
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