SDS Binder 2019mhisafety.ca/PDF/WHMIS/Lab Trailers.pdf · 2020-01-20 · Explosive Notproperties...

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SDS Binder 2019

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SAFETY DATA SHEET

Product Name: ABC Dry Chemical Fire Extinguishant Other Identifiers: Multi-purpose Dry Chemical Product Code(s): CH555, F13, F11 Model Code(s) of Extinguishers: 402, IS 18ABC, IS35ABC, IS 45ABC, 13ABC,

V25ABC, VH25ABC, V30ABC, VH30ABC, V50ABC, VS50ABC, VS75ABC, V250ABC

Recommended Use: Fire suppression, not for human or animal drug use. Manufacturer: AMEREX CORPORATION Internet Address: www.amerex-fire.com Address: 7595 Gadsden Highway, P.O. Box 81 Trussville, AL 35173-0081 Company Telephone: (205) 655-3271 E-mail Address: [email protected] Emergency Contacts: Chemtrec 1(800) 424-9300 or (703) 527–3887 Revised: March 13, 2018

GHS – Classification

Health Environmental Physical Acute Toxicity: Category 5 None None Skin Corrosion/Irritation: Category 3 None None Skin Sensitization: NO None None Eye: Category 2A None Warning STOT – Category 3 None Warning Carcinogen: Category None None None

GHS – Label Symbol(s):

If Pressurized: Gas Under Pressure GHS – Words(s): Warning Other Hazards Not Resulting in Classification: Mica may contain small quantities of quartz

(crystalline silica). Prolonged exposure to respirable crystalline silica dust at concentrations exceeding the occupational exposure limits may increase the risk of developing a disabling

Section 1. PRODUCT AND COMPANY IDENTIFICATION

Section 2. HAZARDS IDENTIFICATION

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lung disease known as silicosis. IARC found limited evidence for pulmonary carcinogenicity of crystalline silica in humans. In the case of normal use of this product, exposure to silica should be nil.

The attapulgite clay used in this product has a fiber length of less than 5um; therefore, the clay

is not considered to be carcinogenic in animals or humans. GHS – Hazard Phrases

GHS Hazard GHS Codes(s) Code Phrase(s) Physical H229 *- Contents under pressure; may explode if heated. Health H303

315 319 335

May be harmful if swallowed Causes skin irritation Causes serious eye irritation May cause respiratory irritation

Environmental None Precautionary: General P101 If medical advice is needed, have product container or label at hand Prevention P251

261 264 280

Do not pierce or burn, even after use. Avoid breathing dust/fumes/gas/mist/vapours/spray. Wash exposed skin thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection.

Response P312 321 362

302+352 304+340

305+351+338

332+313 342+311 337+313

Call a doctor if you feel unwell. Specific treatment (see Section 4. First Aid Measures) Take off contaminated clothing. IF ON SKIN: Wash with plenty of water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing. If skin irritation occurs: Get medical advice/attention. If experiencing respiratory symptoms: Call a doctor. If eye irritation persists get medical advice/attention.

Storage P410 +403 *- Protect from sunlight. Store in well-ventilated place. Disposal P501 Dispose of contents through a licensed disposal company. Contaminated container should

be disposed of as unused product. *- If under pressure

Chemical Name EC No. REACH Reg. No. CAS-No. Weight % Classification Mono-ammonium phosphate 231-764-5 01-2119488166-29 7722-76-1 80-98 NA Attapulgite clay 601-805-5 Not Available 12174-11-7 3-16 NA Mica- potassium aluminum silicate

310-1276 Not Available 12001-26-2 1-2 NA

Silicone oil methyl hydrogen polysiloxane

613-152-3 Not Available 63148-57-2 <1 NA

Calcium carbonate 207-439-9 Not Available 1317-65-3 <1 NA Amorphous silica precipitated synthetic zeolite

231-545-4 01-2119379499-16-0036

7631-86-9 <1 NA

Yellow 14 pigment – di-azo dye 226-789-3 Not Available 5468-75-7 <1 NA Emergency overview: Light yellow, fine solid powder, odorless. Adverse health effects and symptoms: Mild irritant to the respiratory system. Irritant to eyes,

and skin. Symptoms may include coughing,

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS

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shortness of breath, and irritation of the lungs, eyes, and skin. Ingestion, although unlikely, may cause cramps, nausea and diarrhea.

Eye Exposure: May cause irritation. Irrigate eyes with water and

repeat until pain free. Seek medical attention if irritation develops, or if vision changes occur.

Skin Exposure: May cause skin irritation. In case of contact, wash with plenty of soap and water. Seek medical attention if irritation persists.

Inhalation: May cause irritation, along with coughing. If respiratory irritation or distress occurs remove victim to fresh air. Seek medical attention if irritation persists.

Ingestion: Overdose symptoms may include numbness or tingling in hands or feet, uneven heart rate, paralysis, feeling faint, chest pain or heavy feeling, pain spreading to the arm or shoulder, nausea, diarrhea, sweating, general ill feeling, or seizure (convulsions). If victim is conscious and alert, give 2-3 glasses of water to drink. If conscious, do not induce vomiting. Seek immediate medical attention. Do not leave victim unattended. To prevent aspiration of swallowed product, lay victim on side with head lower than waist.

Medical conditions possibly aggravated by exposure: Inhalation of product may aggravate existing chronic

respiratory problems such as asthma, emphysema, or bronchitis. Skin contact may aggravate existing skin disease. Chronic overexposure may cause pneumoconiosis (“dusty lung” disease).

Flammable Properties: Not flammable Flash Point: Not determined Suitable Extinguishing Media: Non-combustible. Use extinguishing media suitable for surrounding conditions. Hazardous Combustion Products: Carbon oxides

Section 4. FIRST AID MEASURES

Section 5. FIRE-FIGHTING MEASURES

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Explosion Data: Sensitivity to Mechanical Impact: Not sensitive Sensitivity to Static Discharge: Not sensitive Unusual fire/explosion hazards: In a fire this material may decompose, releasing

oxides of carbon, potassium and nitrogen (see Section 10).

Protective Equipment and Precautions for Firefighters: As in any fire, wear self-contained breathing

apparatus pressure-demand. NIOSH (approved or equivalent) and full protective gear.

Personal Precautions: Avoid contact with skin, eyes, and clothing. Personal Protective Equipment: Minimum - safety glasses, gloves, and a dust respirator. Emergency Procedures: NA Methods for Containment: Prevent further leakage or spillage if safe to do so. Methods for Clean Up: Avoid dust formation; clean up released material

using vacuum or wet sweep and shovel to minimize generation of dust. Bag and transfer to properly labeled containers. Ventilate area and wash spill site after material pickup is complete.

Other: If product is contaminated, use PPE and containment appropriate to the nature of the most toxic chemical/material in the mixture.

Personal Precautions: Use appropriate PPE when handling or maintaining

equipment, and wash thoroughly after handling (see Section 8).

Conditions for Safe Storage: Keep product in original container or extinguisher. Contents may be under pressure – inspect for extinguisher rust periodically to ensure container integrity.

Incompatible Products: Do not mix with other extinguishing agents, particularly potassium bicarbonate and sodium bicarbonate. Incompatible with strong oxidizing agents and strong acids. Do not store in high humidity. Do not combine with chlorine compounds.

Section 6. ACCIDENTAL RELEASE MEASURES

Section 7. HANDLING AND STORAGE

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Chemical

Name OSHA PEL ACGIH TLV DFG MAK * EU BLV

Mono-ammonium phosphate

PNOC** Total dust, 15 mg/m3 Respirable fraction, 5 mg/m3

PNOC Total dust, 10 mg/m3 Respirable fraction, 3 mg/m3

PNOC Total dust, 4 mg/m3 Respirable fraction, 1.5 mg/m3

NA

Mica 6 mg/m3 3 mg/m3 ------- NA Attapulgite clay

PNOC** Total dust, 15 mg/m3 Respirable fraction, 5 mg/m3


PNOC Total dust, 4 mg/m3 Respirable fraction,

1.5 mg/m3

Silicone oil

NR** NR

Calcium carbonate



-------

NA

Amorphous silica

20mppcf 80 mg/m3 or % SiO2

10 mg/m3 4 mg/m3 NA

Yellow 14 pigment

NR NR NR NA

*German regulatory limits **PNOC = Particulates not otherwise classified (ACGIH) also known as Particulates not otherwise regulated (OSHA) *** NR = Not Regulated. All values are 8 hour time weighted average concentrations. Engineering Controls: Showers Eyewash stations Ventilation systems Personal Protective Equipment – PPE Code E: The need for respiratory protection is not probable during short-term exposure. During production, the manufacturer should use judgement concerning the need for PPE.

Eye/Face Protection: Tightly fitting safety goggles Skin and Body Protection: Wear protective gloves/coveralls

Respiratory Protection: If exposure limits are exceeded or irritation is experienced, NIOSH approved respiratory protection should be worn. Use P100 respirators for limited exposure. Use air-purifying respirator (APR) with high efficiency particulate air (HEPA) filters for prolonged

Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

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exposure. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. The need for respiratory protection is not likely for short-term use in well ventilated areas.

Hygiene Measures: Good personal hygiene practices essential, such as

avoiding food, tobacco products, or other hand-to-mouth contact when handling. Wash thoroughly after handling.

Appearance: Light yellow powder, finely divided odorless solid Molecular Weight: NH4H2PO4: 115.03 Odor: Odorless Odor Threshold: No information available Decomposition Temperature OC: 100 - 120 Freezing Point OC: No information available Initial Boiling Point OC: No information available Physical State: Crystalline Powder pH: Approximately 4.4 to 4.9 Flash Point OC: None Autoignition Temperature OC: None Boiling Point/Range OC: No information available Melting Point/Range OC: NH4H2PO4: 190 Flammability/Explosion Limits in Air OC: Upper – None; Lower-None Explosive Properties: None Oxidizing Properties: None Volatile Component (%vol) Not applicable Evaporation Rate: No information available Vapor Density: No information available Vapor Pressure: NH4H2PO4: 1.41 mm/Hg Specific gravity at 25 OC: NH4H2PO4: 1.80 Solubility: 40.4 g/100 ml Partition Coefficient: NH4H2PO4 Est: -4.11 Viscosity: No information available NOTE: NH4H2PO4 – Monoammonium Phosphate

Section 9. PHYSICAL AND CHEMICAL PROPERTIES

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Stability: Stable under recommended storage and handling

conditions. Incompatibles: Strong oxidizing agents; Strong acids; sodium

hypochlorite and chlorine compounds. Protect from moisture

Conditions to Avoid: Storage or handling near incompatibles. Hazardous Decomposition Products: Carbon, nitrogen, and potassium oxides. Heat of fire

may release carbon monoxide. Possibility of Hazardous Reactions: None Hazardous Polymerization Does not occur

Likely Routes of Exposure: Inhalation, skin and eye contact. Symptoms:

Inhalation: Irritation, coughing. Eyes: Irritation. Skin: Irritation.

Acute Toxicity: Relatively non-toxic. Chronic Toxicity:

Short-term Exposure: None known. Long-term Exposure: As with all dusts, pneumoconiosis, or “dusty lung”

disease, may result from chronic exposure. Acute Toxicity Values - Health

Chemical Name

LD50 LC50 (Inhalation) Oral Dermal

Mono-ammonium phosphate 5750 mg/kg (rat) >7940 mg/kg (rabbit) Not available Mica None None None Attapulgite clay None None None Silicone oil None None None Calcium carbonate 6450 mg/kg (rat) 500 mg/24 hr (rabbit) Not available Amorphous silica >5000 mg/kg (rat) >2000 mg/kg (rabbit) >2.2 mg/L (rat) Yellow 14 pigment >17000 mg/kg (rat) >3000 mg/kg (rat) >4448 mg/m3 (rat) Reproductive Toxicity: This product’s ingredients are not known to have

reproductive or teratogenic effects. Target Organs and Effects (TOST): Respiratory system (mild irritant). This product is a mild irritant to epithelial tissue,

(eyes, mucous membranes, skin) and may aggravate dermatitis. No information was found indicating the product causes sensitization.

Section 10. STABILITY AND REACTIVITY

Section 11. TOXICOLOGICAL INFORMATION

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Other Toxicity Categories Chemical Name Germ Cell

Mutagenicity Carcino-genicity

Repro-ductive

TOST Single Exp

TOST Repeated Exp

Aspiration

Mono-ammonium phosphate None None None Cat 3 None None Attapulgite clay None None None None None None Mica

None None None None None None

Silicone oil

None None None None None None

Calcium carbonate None None None None None None Amorphous silica None None None None None None Yellow 14 pigment None None None None None None

Ecotoxicity: Negative effects unknown. Provides nutrient nitrogen and phosphorus to plant life.

Persistence/Degradability: Degrades rapidly in humid/wet environment. Probability of rapid biodegradation: NH4H2PO4 Est: 0.693 (Rapid); (NH4)2SO4: Est: 0.684 (Rapid) Anaerobic biodegradation probability: NH4H2PO4 Est: 0.398 (Slow); (NH4)2SO4: Est: 0.398 (Slow) Bioaccummulation potential: Low. Bioconcentration factor: NH4H2PO4: 3.16 L/kg (wet weight) (Low BCF) Bioaccummulation factor: NH4H2PO4: 63.04 L/kg (wet weight) Mobility in soil: Slow evaporation rate; water soluble, may leach to

groundwater Log Koc: NH4H2PO4 Est: -1.25 Log Koa: NH4H2PO4 Est: 16.72 Log Kaw: NH4H2PO4 Est: -20.86 NOTE: NH4H2PO4 – Mono-ammonium Phosphate Other Adverse Ecological Effects: No other known effects at this time Aquatic Toxicity Values – Environment – Research

Chemical Name Acute (LC50) Chronic (LC50) Mono-ammonium phosphate N/A N/A Mica N/A N/A Attapulgite clay N/A N/A Silicone oil N/A N/A Calcium carbonate N/A N/A Amorphous silica N/A N/A Yellow 14 pigment N/A N/A

Section 12. ECOLOGICAL INFORMATION

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Aquatic Toxicity Values – Environment – Estimates Chemical Name Acute (LC50) EC50

Mono-ammonium phosphate 2,91e+07 mg/L Fish 96 hr; 9.4e+06 mg/l Daphnid 48 hr;

6.70e+05 mg/L Gr. Algae 96 hr

Mica N/A N/A Attapulgite clay N/A N/A Silicone oil N/A N/A Calcium carbonate N/A N/A Amorphous silica N/A N/A Yellow 14 pigment N/A N/A

Safe Handling Use appropriate PPE when handling, and wash thoroughly after handling (see Section 8).

Waste Disposal Considerations Dispose in accordance with federal, state, and local regulations.

Contaminated Packaging Dispose in accordance with federal, state, and local regulations.

NOTES: This product is not a RCRA characteristically hazardous or listed hazardous waste. Dispose of according to state or local laws, which may be more restrictive than federal laws or regulations. Used product may be altered or contaminated, creating different disposal considerations. UN Number: NA UN Proper Shipping Name: NA Transport Hazard Class: NA Packing Group: NA Marine Pollutant?: NO IATA Not regulated DOT Not regulated NOTES: This product is not defined as a hazardous material under U.S. Department of Transportation (DOT) 49 CFR 172, or by Transport Canada “Transportation of Dangerous Goods” regulations. Special Precautions for Shipping: The transportation information above covers the ABC 555 dry chemical extinguisher agent as shipped in bulk containers and not when contained in fire extinguishers or fire extinguisher systems. If shipped in a stored pressure-type fire extinguisher, and pressurized with a non-flammable, non-toxic

Section 13. DISPOSAL CONSIDERATIONS

Section 14. TRANSPORT INFORMATION

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inert expellant gas, the fire extinguisher is considered a hazardous material by the US Department of Transportation and Transport Canada. The proper shipping name shall be FIRE EXTINGUISHER and the UN designation is UN 1044. The DOT hazard class/division is LIMITED QUANTITY when pressurized to less than 241 psig and when shipped via highway or rail. UN Class 2.2. Non-Flammable Gas, when shipping via air. Packing Group – N/A

International Inventory Status: All ingredients are on the following inventories

Country(ies) Agency Status United States of America TSCA Yes Canada DSL Yes Europe EINECS/ELINCS Yes Australia AICS Yes Japan MITI Yes South Korea KECL Yes REACH Title XVII Restrictions: No information available Chemical Name Dangerous

Substances Organic Solvents

Harmful Substances Whose Names Are to be Indicated on Label

Pollution Release and Transfer Registry (Class II)

Pollution Release and Transfer Registry (Class I)

Poison and Deleterious Substances Control Law

Monoammonium Phosphate

Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable

Component ISHA – Harmful

Substances Prohibited for Manufacturing, Importing, Transferring, or Supplying

ISHA – Harmful Substances Requiring Permission

Toxic Chemical Classification Listing (TCCL) – Toxic Chemicals

Toxic Release Inventory (TRI) – Group I

Toxic Release Inventory (TRI) – Group II

Monoammonium Phosphate 7722-76-1

Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable

Attapulgite clay 12174-11-7 (>3) Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable

Mica- potassium aluminum silicate 120001-26-2 (>2)

Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable

Calcium carbonate 471-34-1 Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable

Amorphous silica 69012-64-2 Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable

Yellow 14 pigment 5468-75-7 Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable

Section 15. REGULATORY INFORMATION

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European Risk and Safety phrases: EU Classification: Xn - Irritant R Phrases: 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. S Phrases: 22 Do not breath dust. 24/25 Avoid contact with skin and eyes

26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

36 Wear suitable protective clothing. U.S. Federal Regulatory Information:

SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) - This product does not contain and chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. None of the chemicals in this product are under SARA reporting requirements or have SARA threshold planning quantities (TPQs) or CERCLA reportable quantities (RQs), or are regulated under TSCA 8(d). SARA 311/312 Hazard Categories: Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No *-Sudden Release of Pressure Hazard Yes Reactive Hazard No

* - Only applicable if material is in a pressurized extinguisher. Clean Water/Clean Air Acts: This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) or Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) and Section 112 of the Clean Air Act Amendments of 1990. U.S. State Regulatory Information: Chemicals in this product are covered under specific State regulations, as denoted below: Alaska - Designated Toxic and Hazardous Substances: NoneCalifornia – Permissible Exposure Limits for Chemical Contaminants: None Florida – Substance List: Mica Dust Illinois – Toxic Substance List: None Kansas – Section 302/303 List: None Massachusetts – Substance List: Mica Dust

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Minnesota – List of Hazardous Substances: None Missouri – Employer Information/Toxic Substance List: None New Jersey – Right to Know Hazardous Substance List: None North Dakota – List of Hazardous Chemicals, Reportable Quantities: None Pennsylvania – Hazardous Substance List: None Rhode Island – Hazardous Substance List: Mica Dust Texas – Hazardous Substance List: No West Virginia – Hazardous Substance List: None Wisconsin – Toxic and Hazardous Substances: None California Proposition 65: No component is listed on the California Proposition 65 list. Other: Mexico – Grade No component listed Canada – WHMIS Hazard Class No component listed

This SDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU regulations or standards, and conforms to the proposed 2003 ANSI Z400.1 format. Issuing Date 17-June-2012 Revision Date 13-March-2018 Revision Notes None The information herein is given in good faith but no warranty, expressed or implied, is made. Updated by William F. Garvin, CIH.

Section 16. OTHER INFORMATION

Product name: DEGIL 12435A INS REP LIQ 120ml 30%DEET I Product #: 12435A Version #: 02 Issue date: 07-19-2017 Revision date: 07-30-2018

SDS CANADA

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SAFETY DATA SHEET

1. Identification Product identifier Other means of identification

Product code Recommended use Recommended restrictions

DEGIL 12435A INS REP LIQ 120ml 30%DEET I 12435A Pesticide None known.

Manufacturer/Importer/Supplier/Distributor information Manufacturer

Company name Croc Bloc Products Inc Address Unit #1 200 Zenway Blvd

Vaughan, ON L4H 0L6 Canada

Telephone Not available. E-mail Not available. Emergency phone number Emergency - US 1-866-836-8855

Emergency - Outside US 1-952-852-4646 Supplier

2. Hazard(s) identification

Physical hazards Health hazards

Label elements

Not available. Flammable liquids Skin corrosion/irritation Serious eye damage/eye irritation

Category 4 Category 2 Category 2

Signal word Warning Hazard statement Combustible liquid. Causes skin irritation. Causes serious eye irritation. Precautionary statement

Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep away from flames and hot surfaces-No smoking. Wash thoroughly after handling. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection.

Response IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. In case of fire: Use appropriate media to extinguish.

Storage Store in a well-ventilated place. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Environmental hazards Hazardous to the aquatic environment, acute hazard Hazardous to the aquatic environment, long-term hazard

Category 3 Category 3

Other hazards None known. Supplemental information None.

3. Composition/information on ingredients

Mixtures


SDS CANADA

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Chemical name Ethyl Alcohol

N,n-diethyl-m-toluamide (deet)

Common name and synonyms CAS number % 64-17-5 51.36

134-62-3 30.54 Other components below reportable levels 18.1

All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures Inhalation Skin contact

Eye contact

Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information

5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards

Move to fresh air. Call a physician if symptoms develop or persist. Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Headache. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Coughing. Skin irritation. May cause redness and pain.

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. The product is combustible, and heating may generate vapors which may form explosive vapor/air mixtures. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. Combustible liquid.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures

Methods and materials for containment and cleaning up

Environmental precautions

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Prevent product from entering drains. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.


SDS CANADA

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7. Handling and storage Precautions for safe handling

Conditions for safe storage, including any incompatibilities

Keep away from open flames, hot surfaces and sources of ignition. When using do not smoke. Avoid contact with eyes, skin, and clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Keep away from heat, sparks and open flame. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection Occupational exposure limits

US. ACGIH Threshold Limit Values Components Type

Value

Ethyl Alcohol (CAS 64-17-5)

STEL 1000 ppm

Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Components Type Value


TWA 1880 mg/m3

1000 ppm

Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Components Type Value


STEL 1000 ppm

Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) Components Type Value


STEL 1000 ppm

Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Components Type Value


STEL 1000 ppm

Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Components Type Value


Biological limit values Appropriate engineering controls

TWA 1880 mg/m3

1000 ppm No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.

Individual protection measures, such as personal protective equipment Eye/face protection

Skin protection

Hand protection

Other Respiratory protection

Thermal hazards

General hygiene considerations

Wear safety glasses with side shields (or goggles). Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier.

Wear appropriate chemical resistant clothing. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Wear appropriate thermal protective clothing, when necessary. When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties Appearance

Physical state Liquid.


SDS CANADA

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Form Color

Odor

Liquid. Not available. Not available.

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available. Initial boiling point and boiling range

212 °F (100 °C) estimated

Flash point 143.3 °F (61.8 °C) estimated Evaporation rate Not available. Flammability (solid, gas) Not applicable.

Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%)

3.3 % estimated

19 % estimated

Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available.

Vapor pressure 63.1 psig @70F estimated Vapor density Not available.

Relative density Not available. Solubility(ies)

Solubility (water) Not available. Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature 642.59 °F (339.22 °C) estimated Decomposition temperature Not available.

Viscosity Not available. Other information

Density 0.48 g/cm3 estimated Explosive properties Not explosive.

Flammability class Combustible IIIA estimated Heat of combustion (NFPA 30B) Oxidizing properties

21.3 kJ/g estimated Not oxidizing.

Percent volatile 69.33 % estimated

Specific gravity 0.485 estimated

VOC (Weight %) 51.42 % estimated

10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid

Incompatible materials Hazardous decomposition products

The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong oxidizing agents. No hazardous decomposition products are known.

11. Toxicological information Information on likely routes of exposure

Inhalation No adverse effects due to inhalation are expected.


SDS CANADA

5 / 7

Skin contact Causes skin irritation.

Eye contact Causes serious eye irritation.

Ingestion Expected to be a low ingestion hazard.

Symptoms related to the physical, chemical and toxicological characteristics

Headache. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Coughing. Skin irritation. May cause redness and pain.

Information on toxicological effects Acute toxicity Components Species Ethyl Alcohol (CAS 64-17-5)

Acute Inhalation

Test Results

LC50 Cat 85.41 mg/l, 4.5 Hours

43.68 mg/l, 6 Hours

Mouse > 60000 ppm

79.43 mg/l, 134 Minutes

Rat > 115.9 mg/l, 4 Hours

51.3 mg/l, 6 Hours

Oral LD50 Monkey 6000 mg/kg

Mouse 10500 ml/kg

Pig > 5000 mg/kg

Rat 10470 mg/kg

7800 ml/kg

* Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation

Respiratory or skin sensitization

Causes skin irritation. Causes serious eye irritation.

Respiratory sensitization Not a respiratory sensitizer. Skin sensitization

Germ cell mutagenicity

Carcinogenicity

This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Canada - Manitoba OELs: carcinogenicity ETHANOL (CAS 64-17-5) Confirmed animal carcinogen with unknown relevance to humans.

Reproductive toxicity Specific target organ toxicity - single exposure

Specific target organ toxicity - repeated exposure

This product is not expected to cause reproductive or developmental effects. Not classified.

Not classified.

Aspiration hazard Not an aspiration hazard.

12. Ecological information Ecotoxicity

Components Ethyl Alcohol (CAS 64-17-5)

Aquatic

Harmful to aquatic life with long lasting effects.

Species

Test Results

Crustacea

Fish

EC50

LC50

Water flea (Daphnia magna)

Fathead minnow (Pimephales promelas)

7700 - 11200 mg/l, 48 hours

> 100.1 mg/l, 96 hours


SDS CANADA

6 / 7

Components N,n-diethyl-m-toluamide (deet) (CAS 134-62-3)

Aquatic

Species Test Results

Fish LC50 Fathead minnow (Pimephales promelas) 106 - 114 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown. Persistence and degradability Bioaccumulative potential

No data is available on the degradability of this product.

Partition coefficient n-octanol / water (log Kow) Ethyl Alcohol -0.31 N,n-diethyl-m-toluamide (deet) 2.02

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations Disposal instructions

Local disposal regulations Hazardous waste code

Waste from residues / unused products

Contaminated packaging

14. Transport information

TDG

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

Not regulated as dangerous goods. IATA

Not regulated as dangerous goods. IMDG

Not regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

15. Regulatory information

Canadian regulations

Not established.

Controlled Drugs and Substances Act Not regulated.

Export Control List (CEPA 1999, Schedule 3) Not listed.

Greenhouse Gases Not listed.

Precursor Control Regulations Not regulated.

International regulations Stockholm Convention

Not applicable. Rotterdam Convention

Not applicable. Kyoto protocol

Not applicable.


SDS CANADA

7 / 7

Montreal Protocol Not applicable.

Basel Convention Not applicable.

International Inventories

Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical

Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances

(PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

No Yes No No No

No No No No No

Yes

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other Information Issue date 07-19-2017 Revision date 07-30-2018 Version # 02 Disclaimer

Revision information

We cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Product and Company Identification: Alternate Trade Names

SAFETY DATA SHEET

NeoChem, Div. of ENERCON WATER TREATMENT LTD. 3606 – 6 Avenue North, Lethbridge, AB T1H 5C4

Phone: (403) 328-9730 * Toll Free: 1-800-248-1195 * Fax: (403) 327-4375 Website: www.neochem.ca * Email: [email protected]

EMERGENCY PHONE NUMBER (CANUTEC): (613) 996-6666 Call Collect or *666 on Cell Phone

FastAction

Section 01: Identification Product State: FastAction Recommended Use: Cleaner and Degreaser (see Technical Data Sheet Section 02: Hazards Identification/Emergency Overview Physical State: Liquid GHS Classification: Physical Hazard: Flammable Liquids- Category 3 Health Hazard: Respiratory or skin sensitization – Category 1 Serious eye damage – Category 2 Acute toxicity- category 4 Hazard Statements: It may be fatal or harmful if swallowed. Skin and eye damage may occur. Signal Word: Warning Precautionary Statement: Avoid contact with skin and eyes. Wear suitable clothing, gloves, eye protection and footwear. In the presence of vapours, avoid inhaling. Do not ingest. Section 03: Composition/Information on Ingredients Ingredient % Conc. C.A.S. # Ingredient % Conc. C.A.S. # D’limonene 60 - 98 5989-27-5 Ethoxylated Alcohol 5 - 10 68131-39-5 Section 04: First Aid Measures Flush affected skin and eyes thoroughly for at least 15 minutes. Remove contaminated clothing, if necessary. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. Casualties experiencing breathing difficulties should be move to fresh air and administered oxygen or artificial respiration as needed. If ingested, do not induce vomiting. A small amount of water may be given to casualty. Never give anything by mouth to an unconscious person. Seek medical attention for any serious, prolonged or aggravated condition. Section 05: Fire Fighting Measures Flammable: Non-Flammable If yes, under what conditions: Combustible at high temperatures. Means of extinction: Standard procedure for chemical fires. Cool containers / tanks with water spray. Hazardous combustion products: Carbon Monoxide, Carbon Dioxide and other organic compounds. Special protective equipment and precautions for firefighters: Standard equipment for chemical fires. Section 06: Accidental Release Measures Personal precautions, protective equipment and emergency procedures: See Section 8. Environment precautions: Avoid entry into sewers or waterways. Methods and materials for containment and cleaning-up: Use appropriate tools to contain the spilled chemical, use absorbent material to absorb spilled chemical, dispose of absorbed material in a waste disposal container. Section 07: Handling and Storage Precautions for safe handling: Open and handle container with care. Do not eat, drink or smoke in the presence of open container. Follow routine safe-handling procedures. Storage requirements: When not in use, keep container tightly closed in a dry, cool, well-ventilated area. Avoid contact with incompatible materials listed in Section 10. Store away from food, drink and ignition sources. Empty containers can retain product residue and may be hazardous. Do not cut, drill, grind, weld or perform similar operations on or near empty containers. Section 08: Exposure Controls/Personal Protection Note: These recommendations provide general guidelines for handling this product. Personal protective equipment should be selected according to individual application of the material, safe handling practices to consider include: exposure potential, chemical concentration and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local, provincial and federal authorities. Recommended Personal Protective Equipment: Gloves: PVC or Nitrile Rubber Respiratory: NIOSH approved respirator or mask Eye: Chemical goggles or face shield Footwear: Chemical resistant footwear

Clothing: Cover exposed skin Engineering controls: Local mechanical exhaust ventilation Other: Eyewash station and safety shower are proximal to workstation

Section 09: Physical and Chemical Properties Physical State: Liquid Appearance: Clear Odour: Citrus Odour threshold: Not Available pH: Not Applicable Melting point / Freezing point (°C): -35° C Initial boiling point and boiling range (°C): 175.5° C - 178° C Flash point (°C): > 43° C Evaporation rate: Not Applicable

Flammability: Non-Flammable (Combustible at high temperatures) Upper / Lower flammability or explosive limits: Not Available Vapour pressure (mmHg): Not Available Vapour density (Air=1): Not Available Relative density: Not Available Solubility: Not Soluble Partition coefficient: n-octanol/water: Not Available Auto-ignition temperature (°C): Not Available Decomposition temperature: 260° C Specific Gravity: 0.848

FastAction Section 10: Stability and Reactivity Chemical stability under normal conditions: Stable. If no, under what conditions: Possibility of hazardous reactions: Normally stable when used as directed. Incompatible materials: Avoid contact with: Strong oxidizing agents. Reactivity and under what conditions: Presents no specific hazards concerning stability. Hazardous decomposition products: Carbon Monoxide, Carbon Dioxide and other organic compounds. Section 11: Toxicological Information Hazardous Ingredients (Section 3): LD50, (Oral) LD50, (Dermal) LC50, (Inhalation) D’Limonene 4400 – 5100 mg/kg (Rat) >5000 mg/kg (Rabbit) Not Available Ethoxylated Alcohol 2500 mg/kg (Rat) 2000 mg/kg (Rabbit) Not Available Exposure Acute ChronicSkin Contact (Absorption – No) Irritating to skin. Eye Irritating to eyes. Inhalation (in presence of fumes) Irritating to throat lungs and pulmonary tract. Ingestion Repeated ingestion has been shown to result in

kidney damage. Note: No other information available. Teratogenicity: Not Available Reproductive toxicity: Not Available Mutagenicity: Not Available Carcinogenicity: This product does not contain ingredients considered carcinogenic, by the National toxicity Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration. Section 12: Ecological Consideration Ecotoxicity (aquatic and terrestrial): Not Available Persistence and degradability: Not Available Bioaccummulative potential: Not Available

Mobility in soil: Not Available Other adverse effects: Not Available

Section 13: Disposal Considerations Waste Disposal: Dispose of this material and its container in accordance with local, provincial and federal regulations. Section 14: Transport Information UN Number: Not Applicable Shipping Name: Not Applicable Packing Group: Not Applicable

Special Shipping Information: Freeze/Thaw Stable. Agitation Not Required. Freeze at: -35° C

Section 15: Regulatory Information This safety data sheet has been prepared in accordance with the GHS standards. All materials used appear on the Canadian DSL. Materials not listed are either non-hazardous or in concentrations of less than 0.1%. Section 16: Other Information Responsibility Statement The information contained herein is provided as a guide to the handling of this product. It is our belief that the information provided in this safety data sheet is reliable. This product should not be used by any person who is not familiar with the contents of this safety data sheet, the recommendation found on the label and the technical data sheet. No warranty of any kind is given or implied and Enercon Water Treatment Ltd. assumes no responsibility for damages, losses, injuries or events resulting from damages incurred from its use. The information on this material safety data sheet relates only to the specific material designated herein and does not relate to material use in combination with any other material or in any process. Prepared By: Technical Services Preparation Date: March 1, 2017 Modified: December 3, 2018

Made in the USA

Safety Data SheetMay be used to comply with OSHA's Hazard Communication Standard, Quick Identifier

29 CFR 1910. 1200(g). Standard must be reviewed for specific requirements.

THIS PRODUCT IS EXEMPT FROM THE GLOBAL HARMONIZED STANDARD (GHS) 29CFR §1910.1200(b)(5)(v)

PRODUCT NAME: FRONTIERSMAN Bear Attack DeterrentSYNONYMS: Bear Spray, Bear Pepper SprayCHEMICAL NAME:CHEMICAL FAMILY: Deterrent, Irritant AgentPRODUCT USE:

MODEL #'s:Importer's Name: Sale and use in Canada

Address: PMRA Registration #: 26619

Phone Number: Fax: Further Information obtainable from Info Trac. Tel.: +1-800-535-5053 (Open 24 hours)

Information in case of emergency: Tel.: +1-352-323-3500 Fax: +1-352-323-0050

Manufacturer's Name: Security Equipment Corporation

Address: 747 Sun Park Drive

City, State, Zip Fenton, MO 63026

Emergency Phone: 800-325-9568 Other Calls: 636-343-0200 636-343-1318

HAZARD DESCRIPTION:Name: Concentration ClassificationOleoresin Capsicum 6% @ 0.857% Absolute Capsaicin Irritating to skin, eyes, respiratory and digestive systemsPOISONS SCHEDULE: NoneRISK: SAFETY:Irritating to skin. Do not breathe gas/fumes/vapor/spray. Irritating to eyes. Wear eye/face protection.Irritating to respiratory system.Irritating to digestive system. Take off immediately all contaminated clothing.

HMIS Ratings: Health: 2 Fire: 3 Reactivity: 0Signs & Symptoms Of Exposure: Ingredients cause irritation through all routes of entry. EYE: Liquid or vapors may cause redness, burning, tearing, swelling and/or pain.SKIN: Frequent or repeated contact with skin may cause burning, redness or skin irritation and dermatitis.

CARCINOGEN DATA: None of the Ingredients in this product are listed with OSHA, IARC or NTP as carcinogenic.

Hazardous Component(s) (chemical & common name(s) Content(s) OSHA TWA ACGIH TLVOleoresin Capsicum (OC or Red Pepper) CAS# 8023-77-6 6%* N/A N/AAcetone CAS# 67-64-1 ** N/A 500 ppmIsopropyl Alcohol CAS# 67-63-0 ** N/A 200 ppmPropylene Glycol CAS# 57-55-6 ** N/A N/AHFC-134A CAS# 811-97-2 ** 1000 ppm N/A*6% @ 0.857% Absolute CapsaicinMajor Capsaicinoids are determined via A.O.A.C. Method 995.03. ** Other ingredients are trade secrets as defined in Hazard Communications ACT 29 CFR 1910.1200(g) Para 1 (1) end Appendix D to CFR 1910.1200(g).

SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTSCarcinogen (Yes / No)

No

No

NoNoNo

SECTION 2 - HAZARD IDENTIFICATION

To clean the floor and all objects contaminated by this material, use water.

MEDICAL CONDITIONS AGRAVATED: May cause more severe, temporary, effects on those persons who are asthmatics or suffer from emphysema.

SEVERE SKIN, EYE, RESPIRATORY & DIGESTIVE IRRITANT. CONTENTS UNDER PRESSURE. KEEP OUT OF THE REACH OF CHILDREN. DO NOT PUNCTURE OR INCINERATE CAN. DO NOT EXPOSE TO HEAT OR STORE ABOVE 120° F. DO NOT USE AFTER CANISTER'S EXPIRATION DATE. CONTENTS ARE DANGEROUS, USE WITH CARE.

INGESTION: Ingestion may cause irritation to the mouth, throat and stomach, as well as nausea, vomiting, and/or diarrhea.INHALATION: May cause irritation of the respiratory tract as coughing, sneezing, gagging chest tightness and irritation to the throat and lungs.

HAZARDOUS SUBSTANCE. SEVERE IRRITANT. DANGEROUS GOODS. CONTENTS UNDER PRESSURE. According to the Criteria of NOHSC, and the ADG Code.

In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Center.

Risk of explosion if heated under confinement.Material and container must be disposed of as hazardous waste.

If swallowed, IMMEDIATELY contact Doctor or Poisons Information Center. (show this container or label).

Fax Number:

FRONTIERSMAN - Canada

01.01.2018

SECTION 1 - CHEMICAL PRODUCT & COMPANY IDENTIFICATION

Oleoresin Capsicum (Red Pepper)

Handheld aerosol canister that sprays an irritating formula in the eyes, nose and mouth of a bear threatening your personal safety.

Manufactured for:CFBAD-01, CFBAD-02, CFBAD-01G, CFBAD-02G, CFBAD-321, CFBAD-322, CFBAD-321G, CFBAD-322G

Page 1 of 3

Made in the USA

1. Inhalation

3. Skin

FLAMMABLEExtinguishing Media: Halon, Carbon Dioxide, Dry Chemical or WaterSpecial Fire Fighting Procedures:

Wear respirator or self-contained breathing apparatus.

Unusual Fire and Explosion Hazards:

If inside: Ventilate area and after absorbent process, wash area with soap and cold waterIf outside: Stay upwindWaste Disposal Method: Dispose of in accordance with current laws and regulations.

Respiratory Protection:

Ventilation:Protective Gloves:Eye Protection:

Not required

Work/Hygienic Practices:

Engineering Controls:

Appearance & Odor: LiquidBoiling Point: 370° F 0.8144 @ 25° CSolubility in Water: Insoluble 110 PSI

Unstable Incompatibility (Materials To Avoid) N/AStable XMay OccurWill Not Occur X X Hazardous Decomposition Products: N/A

Standard Draize Test: Skin, rabbit, 500 mg Severity: Moderately IrritatingStandard Draize Test: Eye, rabbit, 100 mg Severity: Moderately IrritatingACUTE INHALATION LC50 (rat): > 100.5 mg/L

Vapor Pressure:

YesSuggested (not required)Yes. Exposure without protection in training environment is acceptable.

SECTION 10 - STABILITY AND REACTIVITYConditions To Avoid

Hazardous Polymerization: Conditions To Avoid

Stability

SECTION 11 - TOXICOLOGICAL INFORMATION

Not normally required in well-ventilated areas, however, NIOSH approved respiratory protection may be required when the material is used in confined areas. Avoid overexposure for long periods in enclosed areas.

Physical State:

Other Precautions: Assure can is in a secure place to prevent accidental rupture.

Red/Orange in color. Odor is pungent

Avoid absorption of product on clothing. If absorbed in clothing, remove and wash clothes at once. Do not eat, drink, or smoke while handling product.Provide ventilation if working in confined areas.

Specific Gravity (H20 = 1)

Other Protective Clothing/Equipment:

SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES

SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION

Precautions to be taken in handling & storage:

Store upright in a cool, dry area. Avoid direct light and heat. DO NOT expose to temperatures over 120º F / 50º C.DO NOT puncture or incinerate container.

Flammability Classification 16 CFR 1500.45:

Smoke would be irritating to eyes and mucous membranes. Containers may burst in the heat of a fire.

SECTION 7 - HANDLING AND STORAGE

SECTION 6 - ACCIDENTAL RELEASE MEASURESSteps to follow if material is spilled or released:

Wipe up small spills with absorbent material. With large spills, use respiratory equipment, to avoid irritation, and collect absorbent materials.

Emergency & First Aid Procedures:

SECTION 4 - FIRST AID MEASURESRemove victim from contaminated area and remove contaminated clothing. Provide fresh air, irrigate with copious amounts of cool water. Obtain medical advice is symptoms persist.

Remove from contaminated area immediate. Provide fresh air. If breathing is difficult, administer oxygen. If the victim is not breathing, administer CPR. Seek immediate medical attention.

SECTION 5 - FIRE-FIGHTING MEASURES

DO NOT INDUCE VOMITING. If victim is conscious and not convulsing, rinse mouth with water. Ingest milk or water. Call 800-535-5053 or obtain medical advice immediately. If victim is convulsing or unconscious, do not give anything by mouth, ensure the victim’s airway is open and lay the victim on his/her side with the head lower than the body. IMMEDIATELY transport the victim to a hospital.

2. Eyes

4. Ingestion

Only exposed subject or EMS should remove subject’s contact lenses. Irrigate with cool water for at least 15 minutes, or until relieved. Seek medical attention if irritation persists.Flush with cool water for at least 15 minutes. Wash with mild soap and water. Seek medical attention if irritation persists.

Page 2 of 3

Made in the USA

This product has not been tested for environmental effects.

Consult Federal, State, and Local RegulationsEvacuate contents in a safe area, & dispose of container.

DOT HM-181 INFORMATIONGROUND AIR

Proper Shipping Name: Aerosol, Flammable Aerosol, FlammableHazard Class or Division: 2.1 2.1Identification Number: UN1950 UN1950Packaging Group: none noneLabel(s) Required: 2.1 FLAMMABLE GASINTERNATIONAL TRANSPORTATION REGULATIONSRegulations vary from country to country. Check regulations for your country.

GROUND AIR OCEANProper Shipping Name: Aerosol, Flammable Aerosol, Flammable Aerosols, FlammableHazard Class or Division: 2.1 2.1 2.1Identification Number: UN1950 UN1950 UN1950Packaging Group: none none noneLabel(s) Required: 2.1 FLAMMABLE GAS 2.1

Information concerning particular hazards for human and environment:

Health hazard symbol:

Xi IRRITANTR36/37/38 IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. S2 KEEP OUT OF REACH OF CHILDREN.S24/25S36/37 WEAR SUITABLE PROTECTIVE CLOSTHING AND GLOVES.Warning! Pressurized container.

POISONS SCHEDULE: NoneTOXIC SUBSTANCES CONTROL ACT: This product is in compliance with the U.S. Toxic Substances

Control Act (TSCA) inventory requirements.SARA TITLE III, SECTION 313: CAS# 67-63-0CLEAN AIR ACT (CAA): Not ListedCLEAN WATER ACT (CWA): Not ListedCALIFORNIA PROPOSITION 65: Not ListedMASSACHUSETTS RIGHT TO KNOW: CAS# 67-64-1 67-63-0PENNSYLVANIA RIGHT TO KNOW: CAS# 67-64-1 67-63-0 57-55-6NEW JERSEY RIGHT TO KNOW: CAS# 67-64-1 67-63-0 57-55-6CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATIONS SYSTEMS (WHMIS): Not Listed

Format and Preparation Complies with ANSI Z400.1-1993

SECTION 15 - REGULATORY INFORMATION

SECTION 16 - OTHER INFORMATION

DISCLAIMER: This brief provides a general overview of the safety data sheet requirements in the Hazard Communication Standard (see 29 CFR 1910.1200(g) and Appendix D of 29 CFR 1910.1200). It does not alter or determine compliance responsibilities in the standard or the Occupational Safety and Health Act of 1970. Since interpretations and enforcement policy may change over time, the reader should consult current OSHA interpretations and decisions by the Occupational Safety and Health Review Commission and the courts for additional guidance on OSHA compliance requirements. Please note that states with OSHA-approved state plans may have additional requirements for chemical safety data sheets, outside of those outlined above. For more information on those standards, please visit: http://www.osha.gov/dcsp/osp/statestandards.html.

Contact with skin and inhalation of aerosols/vapors should be avoided. The product has to be labeled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version.

AVOID CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MDEICAL ADVICE.

Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use.

SECTION 14 - TRANSPORT INFORMATION

SECTION 13 - DISPOSAL CONSIDERATIONS

SECTION 12 - ECOLOGICAL INFORMATION

Waste Disposal Methods:

Page 3 of 3

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PS-HTR-ST-43-E_Lead Acid Battery SDS US Version #: 05 Issue Date: 04/01/2015 Revision Date: 03/16/2017 1 of 11

Safety Data Sheet

1. IDENTIFICATION

Product Name: Lead Acid Battery Synonyms: SLI Battery

Product Use: Vehicle Electrical System Manufacturer/Supplier: Johnson Controls Battery Group Address: P.O. Box 590 Milwaukee, WI 53201 US

General Information Number: (800)-333-2222 ext. 3138 Contact Person: Industrial Hygiene & Safety Department

Emergency number: CHEMTREC: 800-424-9300

NOTE: The Johnson Controls sealed cell/battery is considered an article as defined by 29 CFR 1910.1200 (OSHA Hazard Communication Standard). The information contained in this SDS is supplied at the customer’s request for information only.

2. HAZARD(S) IDENTIFICATION

Health Environmental Physical Acute Toxicity (Oral, dermal, inhalation)

Category 4 Aquatic Chronic 1 Aquatic Acute 1

Explosive Chemical, Division 1.3

Skin corrosion/irritation Category 1A

Eye Damage Category 1

Reproductive Category 1A

Carcinogenicity (lead) Category 1B

Carcinogenicity (acid mist) Category 1A

Specific target organ toxicity (repeated exposure)

Category 2

Label Elements:

Health Environmental Physical

Hazard Statements DANGER! Causes severe skin burns and eye damage. Causes serious eye damage. May damage fertility or the unborn child if ingested or inhaled. May cause cancer if ingested or inhaled. Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure.

Precautionary Statements Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing, eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Causes skin irritation, serious eye damage. Contact with internal components may cause irritation or severe burns. Avoid contact with internal acid. Irritating to eyes, respiratory system, and skin.


May form explosive air/gas mixture during charging. Extremely flammable gas (hydrogen). Explosive, fire, blast or projection hazard.

3. COMPOSITION / INFORMATION ON INGREDIENTS

INGREDIENTS (Chemical/Common Names): CAS No.: % by Wt: Lead 7439-92-1 34 Lead Oxide 1309-60-0 31 Sulfuric Acid 7664-93-9 34 Lead Sulfate 7446-14-2 <1 Composition Comments All concentrations are in percent by weight.

4. FIRST AID MEASURES

Note: Under normal conditions of battery use, internal components will not present a health hazard. The following information is provided for battery electrolyte (acid) and lead for exposures that may occur during battery production or container breakage or under extreme heat conditions such as fire. Inhalation Sulfuric Acid: Remove to fresh air immediately. If not breathing, give artificial respiration. If breathing is

difficult, give oxygen. Consult a physician. Lead: Remove from exposure, gargle, wash nose and lips; consult physician.

Skin contact Sulfuric Acid: Flush with large amounts of water for at least 15 minutes; remove contaminated clothing completely, including shoes. If symptoms persist, seek medical attention. Wash contaminated clothing before reuse. Discard contaminated shoes. Lead: Wash immediately with soap and water.

Eye contact Sulfuric Acid and Lead: Flush immediately with large amounts of water for at least 15 minutes while lifting lids; Seek immediate medical attention if eyes have been exposed directly to acid.

Ingestion Sulfuric Acid: Give large quantities of water; Do NOT induce vomiting or aspiration into the lungs may occur and can cause permanent injury or death; consult physician. Lead: Consult physician immediately.

5. FIRE FIGHTING MEASURES

Flash Point Not applicable unless individual components exposed. Auto ignition Temperature

No data available.

Flammable Limits LEL = 4.1% (Hydrogen Gas in air) ; UEL = 74.2% Extinguishing Media

CO2; foam; dry chemical. Do not use carbon dioxide directly on cells. Avoid breathing vapors. Use appropriate media for surrounding fire.

Special Fire Fighting Procedures

Use positive pressure, self-contained breathing apparatus. Beware of acid splatter during water application and wear acid-resistant clothing, gloves, face and eye protection. If batteries are on charge, shut off power to the charging equipment, but note that strings of series connected batteries may still pose risk of electric shock even when charging equipment is shut down.

Unusual Fire and Explosion Hazard

Highly flammable hydrogen gas is generated during charging and operation of batteries. If ignited by burning cigarette, naked flame or spark, may cause battery explosion with dispersion of casing fragments and corrosive liquid electrolyte. Carefully follow manufacturer's instructions for installation and service. Keep away all sources of gas ignition and do not allow metallic articles to simultaneously contact the negative and positive terminals of a battery. Follow manufacturer's instructions for installation and service.


6: ACCIDENTAL RELEASE MEASURES

Protective Measures to be Taken if Material is Released or Spilled

Stop flow of material, contain/absorb small spills with dry sand, earth, and vermiculite. Do not use combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc. Wear acid-resistant clothing, boots, gloves, and face shield. Do not allow discharge of un-neutralized acid to sewer. Acid must be managed in accordance with approved local, state, and federal requirements. Consult state environmental agency and/or federal EPA.

Waste Disposal Method

Dispose of as a hazardous waste. Dispose of in accordance with applicable local, state and federal regulations.

7. HANDLING AND STORAGE

Handling Unless involved in recycling operations, do not breach the casing or empty the contents of the battery. Handle carefully and avoid tipping, which may allow electrolyte leakage. There may be increasing risk of electric shock from strings of connected batteries. Keep containers tightly closed when not in use. If battery case is broken, avoid contact with internal components. Keep vent caps on and cover terminals to prevent short circuits. Place cardboard between layers of stacked automotive batteries to avoid damage and short circuits. Keep away from combustible materials, organic chemicals, reducing substances, metals, strong oxidizers and water. Use banding or stretch wrap to secure items for shipping.

Storage Store batteries under roof in cool, dry, well-ventilated areas separated from incompatible materials and from activities that may create flames, spark, or heat. Store on smooth, impervious surfaces provided with measures for liquid containment in the event of electrolyte spills. Keep away from metallic objects that could bridge the terminals on a battery and create a dangerous short-circuit. Room ventilation is required for batteries utilized for standby power generation. Never recharge batteries in an unventilated, enclosed space.

Charging: There is a possible risk of electric shock from charging equipment and from strings of series connected batteries, whether or not being charged. Shut-off power to chargers whenever not in use and before detachment of any circuit connections. Batteries being charged will generate and release flammable hydrogen gas. Charging space should be ventilated. Keep battery vent caps in position. Prohibit smoking and avoid creation of flames and sparks nearby. Wear face and eye protection when near batteries being charged.

Other Follow Manufacturers Recommendations regarding maximum recommended currents and operating temperature range. Do not overcharge beyond the recommended upper charging voltage limit. Applying pressure or deforming the battery may lead to disassembly followed by eye, skin and throat irritation.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure limits

US OSHA Specifically Regulated Substances (29 CFR 1910.1001 – 1050) Ingredient CAS Number Type Value

Lead 7439-92-1 TWA 0.05 mg/m³ Lead Oxide 1309-60-0 TWA 0.05 mg/m³ Lead Sulfate 7446-14-2 TWA 0.05 mg/m³

US OSHA Table Z-1 Limits for Air Contaminants ( 29CFR 1910.1000)

Ingredient CAS Number Type Value Sulfuric Acid 7664-93-9 PEL 1 mg/m³

US ACGIH Threshold Limit Values

Ingredient CAS Number Type Value Form Lead 7439-92-1 TWA 0.05 mg/m³ Lead Oxide 1309-60-0 TWA 0.05 mg/m³ Lead Sulfate 7446-14-2 TWA 0.05 mg/m³ Sulfuric Acid 7664-93-9 TWA 0.2 mg/m³ Thoracic Fractions


US NIOSH: Pocket Guide to Chemical Hazards

Ingredient CAS Number Type Value Lead 7439-92-1 TWA 0.05 mg/m³ Lead Oxide 1309-60-0 TWA 0.05 mg/m³ Sulfuric Acid 7664-93-9 TWA 1 mg/m³

International Exposure Limits (mg/m3) *Chemical & Common Name Quebec PEV Ontario OEL EU OEL Lead and Lead Compounds (inorganic) 0.05 0.05 0.15 (a) Electrolyte (H2SO4/H2O) 1 0.2 0.05 (b)

(a) As inhalable aerosol (b) Thoracic fraction

Biological limit values ACGIH Biological Exposure Indices

Ingredient Value Determinant Specimen Sampling Time Lead 300 µg/l Lead Blood * Lead Oxide 300 µg/l Lead Blood * Lead Sulfate 300 µg/l Lead Blood *

* - For Sampling details please see the source document. Engineering Controls (Ventilation): Store and handle in well-ventilated area. If mechanical ventilation is used, components must be acid-resistant. Handle batteries cautiously, do not tip to avoid spills. Make certain vent caps are on securely. If battery case is damaged, avoid bodily contact with internal components. Wear protective clothing, eye and face protection, when filling, charging, or handling batteries. Do not allow metallic materials to simultaneously contact both the positive and negative terminals of the batteries. Charge batteries in areas with adequate ventilation. General dilution ventilation is acceptable. Respiratory Protection (NIOSH/MSHA approved): NONE REQUIRED FOR NORMAL HANDLING OF THE FINISHED PRODUCT. When concentrations of sulfuric acid mist are known to exceed PEL, use NIOSH or MSHA-approved respiratory protection. Skin Protection: NONE REQUIRED FOR NORMAL HANDLING OF THE FINISHED PRODUCT. If battery case is damaged, use rubber or plastic acid-resistant gloves with elbow-length gauntlet, acid-resistant apron, clothing and boots. Eye Protection: NONE REQUIRED FOR NORMAL HANDLING OF THE FINISHED PRODUCT. If necessary to handle damage product where exposure to the organic electrolyte is a possibility, chemical splash goggles and a face shield are recommended. Other Protection: In areas where water and sulfuric acid solutions are handled in concentrations greater than 1%, emergency eyewash stations and showers should be provided, with unlimited water supply. Chemically impervious apron and face shield recommended when adding water or electrolyte to batteries. Wash Hands after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance and Odor Manufactured article; no apparent odor. Electrolyte is a clear liquid with a sharp, penetrating, pungent odor.

Odor Threshold Not applicable. pH Not applicable Boiling Point Not applicable unless individual components exposed.


Battery Electrolyte (Acid) - 230 - 233.6 °F (110 - 112 °C) Lead - 3191 °F (1755 °C)

Melting Point Lead - 621.32 °F (327.4 °C) Specific Gravity (H2O = 1)

1.215 to 1.350

Flash Point 498.2 °F (259.0 °C) Hydrogen Evaporation Rate (Butyl Acetate = 1)

< 1

Vapor Pressure (mm Hg @ 20 ° C)

Battery Electrolyte (Acid) 11.7

Flammability Upper/lower flammability or explosive limits

Hydrogen Flammability Limit Lower- 4.1 %

Flammability Limit Upper – 74.2 %

Vapor Pressure Not applicable. Vapor Density 3.4 (Air = 1) Battery Electrolyte (Acid) Relative Density 1.21 - 1.3 Battery Electrolyte (Acid) Solubility Lead and Lead dioxide are not soluble.

100 % Battery Electrolyte (Acid). % Volatile by Weight Not applicable unless individual components exposed. Partition coefficient (n-octanol/water)

Not applicable

Auto-ignition temperature 1076 °F (580 °C) Hydrogen.

Decomposition temperature

Not applicable

Viscosity Not applicable 10. STABILITY AND REACTIVITY

Stability The sealed battery is considered stable. Conditions to Avoid Sparks and other sources of ignition; high temperature; over charging. Incompatibility (materials to avoid)

Electrolyte: Contact with combustibles and organic materials may cause fire and explosion. Also reacts violently with strong reducing agents, metals, sulfur trioxide gas, strong oxidizers, and water. Contact with metals may produce toxic sulfur dioxide fumes and may release flammable hydrogen gas. Lead compounds: Avoid contact with strong acids, bases, halides, halogenates, potassium nitrate, permanganate, peroxides, nascent hydrogen, and reducing agents. Arsenic compounds: strong oxidizers; bromine azide. NOTE: hydrogen gas can react with inorganic arsenic to form the highly toxic gas – arsine

Hazardous Decomposition Products

Electrolyte: Sulfur trioxide, carbon monoxide, sulfuric acid mist, sulfur dioxide, hydrogen sulfide. Lead compounds: Temperatures above the melting point are likely to produce toxic metal fume, vapor, or dust; contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine gas.

Hazardous Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION

NOTE: Under normal conditions of use, this product does not present a health hazard. The following information is provided for organic electrolyte and lead exposure that may occur due to container breakage or under extreme conditions such as fire. Organic electrolyte – reacts with moisture/water to produce hydrofluoric acid in trace quantities. Hydrofluoric acid is extremely corrosive and toxic. In severe exposures it acts as a systemic poison and causes severe burns. The reaction may be delayed. Any contact with this material, even minor, requires immediate medical attention.


ROUTES AND METHODS OF ENTRY Inhalation EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

Sulfuric Acid: Breathing of sulfuric acid vapors or mists may cause severe respiratory irritation. Lead Compounds: Inhalation of lead dust or fumes may cause irritation of upper respiratory tract and lungs.

Skin Contact EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE. Sulfuric Acid: Severe irritation, burns and ulceration. Lead Compounds: Not absorbed through the skin.

Skin Absorption EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

In the event of overcharging or damage to the unit, exposure to organic electrolyte solution/mist is possible. Extreme exposures to the organic electrolyte can be absorbed through the skin.

Eye Contact EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

Sulfuric Acid: Severe irritation, burns, cornea damage, and blindness. Lead Compounds: May cause eye irritation.

Ingestion EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

Sulfuric Acid: May cause severe irritation of mouth, throat, esophagus and stomach. Lead Compounds: Acute ingestion may cause abdominal pain, nausea, vomiting, diarrhea and severe cramping. This may lead rapidly to systemic toxicity and must be treated by a physician.

SIGNS AND SYMPTONS OF OVEREXPOSURE Acute Effects EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

Sulfuric Acid: Severe skin irritation, damage to cornea, upper respiratory irritation. Lead Compounds: Symptoms of toxicity include headache, fatigue, abdominal pain, loss of appetite, muscular aches and weakness, sleep disturbances and irritability

Chronic Effects EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

Sulfuric Acid: Possible erosion of tooth enamel, inflammation of nose, throat & bronchial tubes. Lead Compounds: Anemia; neuropathy, particularly of the motor nerves, with wrist drop; kidney damage; reproductive changes in males and females. Repeated exposure to lead and lead compounds in the workplace may result in nervous system toxicity. Some toxicologists report abnormal conduction velocities in persons with blood lead levels of 50 μg/100 ml or higher. Heavy lead exposure may result in central nervous system damage, encephalopathy and damage to the blood-forming (hematopoietic) tissues.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Overexposure to sulfuric acid mist may cause lung damage and aggravate pulmonary conditions. Contact of sulfuric acid with skin may aggravate diseases such as eczema and contact dermatitis. Lead and its compounds can aggravate some forms of kidney, liver and neurologic diseases.

ADDITIONAL HEALTH DATA All heavy metals, including the hazardous ingredients in this product, are taken into the body primarily by inhalation and ingestion. Most inhalation problems can be avoided by adequate precautions such as ventilation and respiratory protection covered in Section 8. Follow good personal hygiene to avoid inhalation and ingestion: wash hands, face, neck and arms thoroughly before eating, smoking or leaving the work site. Keep contaminated clothing out of non-contaminated areas, or wear cover clothing when in such areas. Restrict the use and presence of food, tobacco and cosmetics to non-contaminated areas. Work clothes and work equipment used in contaminated areas must remain in designated areas and never taken home or laundered with personal non-contaminated clothing. This product is intended for industrial use only and should be isolated from children and their environment. The 19th Amendment to EC Directive 67/548/EEC classified lead compounds, but not lead in metal form, as possibly toxic to reproduction. Risk phrase 61: May cause harm to the unborn child, applies to lead compounds, especially soluble forms.

Toxicological Data Constituents Species Test Results


Sulfuric Acid (CAS 7664-93-9) Acute Oral LD50 Rat 2140 mg/kg

CARCINOGENICITY

Sulfuric Acid: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mist containing sulfuric acid" as a Category I carcinogen, a substance that is carcinogenic to humans. This classification does not apply to liquid forms of sulfuric acid or sulfuric acid solutions contained within a battery. Inorganic acid mist (sulfuric acid mist) is not generated under normal use of this product. Misuse of the product, such as overcharging, may result in the generation of sulfuric acid mist. Lead Compounds: Lead is listed as a Group 2A- carcinogen, likely in animals at extreme doses. Per the guidance found in OSHA 29 CFR 1910.1200 Appendix F, this is approximately equivalent to GHS Category 1A. Proof of carcinogenicity in humans is lacking at present. IARC Monographs. Overall Evaluation of Carcinogenicity Lead (CAS 7439-92-1) Lead oxide (CAS 1309-60-0) Lead sulfate (CAS 7446-14-2)

2A Probably carcinogenic to humans. 2A Probably carcinogenic to humans. 2A Probably carcinogenic to humans.

NTP Report on Carcinogens Lead oxide (CAS 1309-60-0) Lead sulfate (CAS 7446-14-2)

Reasonably Anticipated to be a Human Carcinogen. Reasonably Anticipated to be a Human Carcinogen.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed.

Reproductive toxicity May damage fertility or the unborn child. Specific target organ toxicity - single exposure

No data available.

Specific target organ toxicity - repeated exposure

Lead: May cause damage to organs (blood, central nervous system) through prolonged or repeated exposure.

Aspiration hazard Not classified. 12. ECOLOGICAL INFORMATION

Environmental Fate Lead is very persistent in soil and sediments. No data on environmental degradation. Mobility of metallic lead between ecological compartments is slow. Bioaccumulation of lead occurs in aquatic and terrestrial animals and plants but little bioaccumulation occurs through the food chain. Most studies include lead compounds and not elemental lead

Environmental toxicity Aquatic Toxicity: Sulfuric Acid 24-hr LC50, freshwater fish (Brachydanio rerio): 82 mg/L

96 hr- LOEC, freshwater fish (Cyprinus carpio): 22 mg/L Lead 48 hr LC50 (modeled for aquatic invertebrates): <1 mg/L, based on lead bullion Additional Information No known effects on stratospheric ozone depletion

Volatile organic compounds: 0% (by Volume) Water Endangering Class (WGK): NA

13. DISPOSAL CONSIDERATIONS

Waste disposal method Material should be recycled if possible. Lead-acid batteries are completely recyclable. Dispose waste and residues in accordance with applicable federal, state, and local regulations.

Hazardous waste code D008: Lead Waste from residues / unused products

Dispose of in accordance with local regulations. Empty containers or packaging may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).


Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. TRANSPORT INFORMATION

Note: Transportation requirements do not apply once the battery pack has been installed in a vehicle as part of the vehicle’s functional components. United States DOT: DOT rules specified in 49 CFR 173.159 regulate the transport of wet spillable batteries. 49 CFR 173.159 (e) specifies that when transported by highway or rail, electric storage batteries containing electrolyte or corrosive battery fluid are not subject to any other requirements of this subchapter, if all of the following are met: (1) No other hazardous materials may be transported in the same vehicle; (2) The batteries must be loaded or braced so as to prevent damage and short circuits in transit; (3) Any other material loaded in the same vehicle must be blocked, braced, or otherwise secured to prevent contact with or damage to the batteries; and (4) The transport vehicle may not carry material shipped by any person other than the shipper of the batteries. If any of these requirements are not met, the batteries must be shipped as hazardous materials GROUND – US-DOT/CAN-TDG/EU-ADR/APEC-ADR: Proper Shipping name Batteries, Wet, Filled with Acid UN number UN2794 Hazard classification 8 Packing group N/A Labels Corrosive AIRCRAFT – ICAO-IATA: Proper Shipping name Batteries, Wet, Filled with Acid Packing group None Hazardous class 8 Label/Placard Required Corrosive UN Identification UN2794 Environmental Hazards No ERG Code 8L Reference IATA packing instructions 870 (IATA DRG Edition 54) VESSEL – IMO-IMDG: Proper Shipping name Batteries, Wet, Filled with Acid Packing group N/A Hazardous class 8 Label/Placard Required Corrosive UN Identification UN2794 Environmental Hazards No EmS F-A, S-B Reference IMDG packing instructions P801

15. REGULATORY INFORMATION

This product is an article pursuant to 29 CFR 1910.1200 and as such is not subjected to the OSHA Hazard Communication Standard. TSCA TSCA Section 8b – Inventory Status: Inventory Status: All chemicals comprising this product are either exempt or listed on the TSCA Inventory. TSCA Section 12b (40 CFR Part 707.60(b)) No notice of export will be required for articles, except PCB articles, unless the Agency so requires in the context of

individual section 5, 6, or 7 actions.


TSCA Section 13 (40 CFR Part 707.20) No import certification required (EPA 305-B-99-001, June 1999, Introduction to the Chemical Import Requirements

of the Toxic Substances Control Act, Section IV.A) OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Lead (CAS 7439-92-1) Reproductive toxicity Central nervous system Kidney Blood Acute toxicity Lead Oxide (CAS 1309-60-0) Reproductive toxicity Central nervous system Kidney Blood Acute toxicity Lead Sulfate (CAS 7446-14-2) Reproductive toxicity Central nervous system Kidney Blood Acute toxicity EPA SARA Title III Section 302 EPCRA Extremely Hazardous Substances (EHS): Sulfuric acid is a listed "Extremely Hazardous Substance" under EPCRA, with a Threshold Planning Quantity (TPQ) of

1,000 lbs. EPCRA Section 302 notification is required if 500 lbs. or more of sulfuric acid is present at one site (40 CFR 370.10). For more information consult 40 CFR Part 355.

Section 304 CERCLA Hazardous Substances: Reportable Quantity (RQ) for spilled 100% sulfuric acid under CERCLA (Superfund) and EPCRA (Emergency Planning

and Community Right to Know Act) is 1,000 lbs. State and local reportable quantities for spilled sulfuric acid may vary.

Section 311/312 Hazard Categorization: EPCRA Section 312 Tier Two reporting is required for non-automotive batteries if sulfuric acid is present in

quantities of 500 lbs. or more and/or if lead is present in quantities of 10,000 lbs. or more. For more information consult 40 CFR 370.10 and 40 CFR 370.40

Section 313 EPCRA Toxic Substances: 40 cfr section 372.38 (b) states: If a toxic chemical is present in an article at a covered facility, a person is not

required to consider the quantity of the toxic chemical present in such article when determining whether an applicable threshold has been met under § 372.25, § 372.27, or § 372.28 or determining the amount of release to be reported under § 372.30. This exemption applies whether the person received the article from another person or the person produced the article. However, this exemption applies only to the quantity of the toxic chemical present in the article.

Supplier Notification: This product contains toxic chemicals that may be reportable under EPCRA Section 313 Toxic Chemical Release

Inventory (Form R) requirements. For a manufacturing facility under SIC codes 20 through 39, the following information is provided to enable you to complete the required reports:

RCRA Spent Lead Acid Batteries are subject to streamlined handling requirements when managed in compliance with 40

CFR section 266.80 or 40 CFR part 273. Waste sulfuric acid is a characteristic hazardous waste; EPA hazardous waste number D002 (corrosivity) and D008 (lead).

Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Lead ( CAS 7439-92-1) Lead Oxide (CAS 1309-60-0) Lead Sulfate (CAS 7446-14-2) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Lead Sulfate (CAS 7446-14-2) Safe Drinking Water Act (SDWA)


Not regulated Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Sulfuric acid (CAS 7664-93-9) 6552 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Sulfuric acid (CAS 7664-93-9) 20 % WV DEA Exempt Chemical Mixtures Code Number Sulfuric acid (CAS 7664-93-9 6552 US State Regulations US. Massachusetts RTK – Substance List Lead ( CAS 7439-92-1) Lead Oxide (CAS 1309-60-0) Lead Sulfate (CAS 7446-14-2) US New Jersey Worker and Community Right-to-know Act Lead ( CAS 7439-92-1) Lead Oxide (CAS 1309-60-0) Lead Sulfate (CAS 7446-14-2) Sulfuric acid (CAS 7664-93-9) US Pennsylvania Worker and Community Right-to-know Law Lead ( CAS 7439-92-1) Sulfuric acid (CAS 7664-93-9) US Rhode Island RTK Lead ( CAS 7439-92-1) Lead Oxide (CAS 1309-60-0) Lead Sulfate (CAS 7446-14-2) Sulfuric acid (CAS 7664-93-9) US. California Proposition 65 WARNING: This product contains chemicals known to the State of California to cause cancer. Battery posts, terminals and related accessories contain lead and lead compounds, chemicals known to the state of

California to cause cancer and reproductive harm. Wash hands after handling. *Battery companies not party to the 1999 consent judgment with Mateel Environmental Justice Foundation should include a Proposition 65 Warning that complies with the current version of Proposition 65.

US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Lead ( CAS 7439-92-1) Lead Oxide (CAS 1309-60-0) Lead Sulfate (CAS 7446-14-2) Sulfuric acid (CAS 7664-93-9) International Inventories Country(s) or Region Inventory Name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA)

Inventory Yes

* A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s). A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). CANADIAN ENVIRONMENTAL PROTECTION ACT: These products are manufactured articles and are exempt from regulation.

CANADIAN WHMIS CLASSIFICATION: This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.

16. OTHER INFORMATION

Issue Date: 04/01/2015 Further information: NFPA Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3=Serious 4 = Severe


NFPA ratings

Disclaimer Johnson Controls Battery Group, Inc. cannot anticipate all conditions under which this information

and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

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Conforms to HazCom 2012/United States

SAFETY DATA SHEET LKD

Section 1. Identification GHS product identifier : LKD Other means of identification : LKD Identified uses : Water treatment, Caustic agent, pH adjustment, Neutralization, Acid gas absorption, Construction Supplier's details : Pete Lien & Sons, Inc. PO Box 440 Rapid City, SD 57702 Emergency telephone : (605) 342-7224 (Monday-Friday 8am-5pm) number (hours of operation)

Section 2. Hazards identification

Classification of the : SKIN IRRITATION - Category 2 substance or mixture EYE DAMAGE - Category 1 SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE [Respiratory System] - Category 3

CARCINOGEN - Category 1 GHS label elements

Hazard pictograms : Signal word : Danger Hazard statements : Causes skin irritation. Causes serious eye damage. May cause cancer through inhalation. May cause respiratory irritation. Reacts violently with water, releasing heat which can ignite combustible material. Causes damage to lungs through prolonged and repeated exposure. Precautionary statements Prevention : Wear protective gloves and eye protection. Wash exposed skin thoroughly after handling.

Avoid breathing dust. Use only outdoors or in a well-ventilated area. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust. Do not eat, drink or smoke when using this product.

Response : IF ON SKIN: Wash exposed skin with plenty of water. If skin irritation occurs: get medical

attention. Take off contaminated clothing and wash it before reuse.

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IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek immediate medical attention.

IF INHALED: Remove person to fresh air and keep comfortable for breathing. Seek medical attention if you feel unwell

If exposed or concerned: Get medical advice Storage : Store to minimize dust generation Disposal : Dispose of contents or containers in accordance with applicable regulations. Do not use water on material spills. Hazards not otherwise : Calcium oxide reacts violently with water, releasing heat which can ignite combustible classified materials. Ingredients with : Not Applicable unknown toxicity

Section 3. Composition/information on ingredients

Substance/mixture : LKD CAS number/other identifiers Component CAS # % by weight Calcium Oxide 1305-78-8 >50 Magnesium Oxide 1309-48-4 <4 Crystalline Silica 14808-60-7 >0.1

Section 4. First aid measures

Description of necessary first aid measures

Eye Contact : Contact can cause severe irritation or burning of eyes, including permanent damage. Immediately flush eyes with generous amounts of water for at least 15 minutes. Pull back the eyelid to ensure that all lime dust has been washed out. Seek medical attention immediately. Do not rub eyes.

Skin Contact : Contact can cause severe irritation or burning of skin, especially in the presence of moisture. Wash exposed area with large amounts of water. Seek medical attention immediately.

Ingestion : This product can cause severe irritation or burning of gastrointestinal tract if swallowed. Do not induce vomiting. Seek medical attention immediately. Never give anything by mouth unless instructed to do so by medical personnel.

Inhalation :This product can cause severe irritation of the respiratory system. Move victim to fresh air. Seek medical attention if necessary. If breathing has stopped, give artificial respiration.

Most important symptoms/effects, acute and delayed : Irritation of skin, eyes, gastrointestinal tract or respiratory tract. Long-term exposure by inhalation may cause permanent damage. This product contains crystalline silica, which

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has been classified by IARC as (Group I) carcinogenic to humans when inhaled. Inhalation of silica can also cause a chronic lung disorder, silicosis. Indication of immediate medical attention and special treatment needed, if necessary: See first aid information above. Note to Physicians: Provide general supportive measures and treat symptomatically.

Section 5. Fire-fighting measures

Extinguishing Media :Use dry chemical fire extinguisher. Do not use water or halogenated compounds, except that large amounts of water may be used to deluge small quantities of LKD. Fire Hazards :LKD is not combustible or flammable. However, LKD reacts violently with water, and can release heat sufficient to ignite combustible materials. LKD is not considered to be an explosion hazard, although reaction with water or other incompatible materials may rupture containers. Hazardous Combustion Products: None. Special Protective Equipment and Fire Fighting Instructions: Keep personnel away from and upwind of fire. Wear full fire-fighting turn-out gear (full Bunker gear), and respiratory protection (SCBA)

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures Spill/Leak Procedures :Do NOT use water on bulk material spills. Lime reacts violently with water, releasing heat. Use proper protective equipment. Small Spills :Use dry methods to collect spilled materials. Avoid generating dust. Do not clean up with compressed air. Store collected materials in dry, sealed plastic or metal containers. Residue on surfaces may be water washed. Large Spills :Use dry methods to collect spilled materials. Evacuate area downwind of clean-up operations to minimize dust exposure. Store spilled materials in dry sealed plastic or metal containers. Methods and materials for containment and cleaning up Containment : For large spills, as much as possible, avoid the generation of dusts. Prevent release to sewers

or waterways. Cleanup : Residual amounts of material can be flushed with large amounts of water. Equipment can be

washed with either mild vinegar and water solution, or detergent and water.

Section 7. Handling and storage

Precautions for safe handling Keep in tightly closed containers. Protect containers from physical damage. Avoid direct skin contact with the material. Conditions for safe storage, including any incompatibilities

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Store in a cool, dry, and well-ventilated location. Do not store near incompatible materials (see Section 10 below). Keep away from moisture. Long-term storage in aluminum containers is not recommended, as calcium oxide may corrode aluminum over long periods of time.

Section 8. Exposure controls/personal protection Exposure limits Component CAS # Exposure limits Calcium Oxide 1305-78-8 OSHA PEL: 5mg/m3 ACGIH TLV: 2mg/m3

Magnesium Oxide 1309-48-4 OSHA PEL: 15mg/m3 ACGIH TLV: 10mg/m3 Crystalline Silica 14808-60-7 OSHA PEL: 10mg/m3 divided by (the percentage of silica in the dust plus 2) (respirable) ACGIH TLV: 0.025 mg/m3 Engineering controls : Provide ventilation adequate to maintain PELs. Individual Protection Measures Respiratory Protection :Use NIOSH/MSHA approved respirators if airborne concentration exceeds PEL. Skin Protection :Use appropriate gloves to prevent skin contact. When there is a risk of skin contact, wear

suitable clothing to prevent such contact. Eye Protection : Use safety glasses with side shields or safety goggles. Contact lenses should not be worn when

working with lime products. Other : Eye wash fountain and emergency showers are recommended

Section 9. Physical and chemical properties Physical State : Solid Appearance : White or grayish-white material Odor : Odorless Odor threshold : Not applicable pH at 25 degrees C : 12.45 Melting point : 4658°F, 2570°C Initial boiling point : 5162°F, 2850°C Flash point : Not applicable. Evaporation rate : Not applicable. Flammability (solid, gas) : Not applicable. Lower and upper explosive : Not applicable. (flammable) limits Vapor pressure : Not applicable. Vapor density : Not applicable. Relative density : Not applicable. Solubility in water : Negligible, but reacts with water to produce calcium hydroxide and heat

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Partition coefficient: n : Not applicable. octanol/water Auto-ignition temperature : Not applicable. Decomposition temperature : Not applicable. Viscosity : Not applicable.

Section 10. Stability and reactivity Reactivity : LKD reacts violently with water to form calcium hydroxide, releasing heat. See also

Incompatibility below Chemical stability :LKD is chemically stable Possibility of : See above hazardous reactions Conditions to avoid : Do not allow LKD to come in contact with incompatible materials Incompatible materials : LKD should not be mixed or stored with the following materials, due to the potential for violent

reaction and release of heat: WATER ACIDS REACTIVE FLUORIDATED COMPOUNDS REACTIVE BROMINATED COMPOUNDS REACTIVE POWDERED METALS ALUMINUM POWDER ORGANIC ACID ANHYDRIDES NITRO-ORGANIC COMPOUNDS REACTIVE PHOPHOROUS COMPOUNDS INTERHALOGENATED COMPOUNDS Hazardous : None decomposition products

Section 11. Toxicological Information Information on the likely routes of exposure: See First Aid discussion above. Symptoms related to the physical, chemical and toxicological characteristics: See First Aid discussion above. Delayed and immediate effects and also chronic effects from exposure: See First Aid discussion above. Numerical measures of toxicity: No LD50/LC50 have been identified for this product’s components. Carcinogen listing: LKD is not listed by MSHA, OSHA, or IARC as a carcinogen, but this product contains crystalline silica, which has been classified by IARC as (Group I) carcinogenic to humans when inhaled

Section 12. Ecological information Ecotoxicity : Because of the high pH of this product, it would be expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems in high concentrations. Persistence and degradability : There is no data available.

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Bioaccumulative potential : This material shows no bioaccumulation effects of food chain concentration toxicity. Mobility in soil : There is no data available. Other adverse effects : This material is alkaline and if released into water or moist soil will cause an increase in pH.

Section 13. Disposal considerations Dispose of in accordance with all applicable federal, state, and local environmental regulations. If this product as supplied, and unmixed, becomes a waste. It will not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act.

Section 14. Transport information UN number : UN1910 UN proper shipping name : LKD Transport hazard class(es) : When transported by air only: Hazard Class 8-Corrosive Packing group : When transported by air only: Packing Group III Environmental hazards : This material is alkaline and if released into water or moist soil will cause an increase in pH. Transport in bulk according to : Not available. Annex II of MARPOL 73/78 and the IBC Code Special Precautions which a user needs to be aware of , or needs to comply with, in connection with transport or conveyance either within or outside their premises: When being transported by air, LKD is classified in the Department of Transportation (DOT) regulations as a hazardous material. (49 CFR 172.101). For aircraft transport only, Calcium Oxide is classified as Hazard Class 8-Corrosive, UN1910, Packing Group III. For passenger aircraft, the maximum net quantity allowed per container is 25 kg. For cargo aircraft the maximum net quantity allowed per container is 100kg. For quantities greater than 25kg up to and including 100kg, the container shall be labeled with CARGO AIRCRAFT ONLY. Because express carriers (i.e., Federal Express, Airborne Express, and United Parcel Service) ship by air, LKD presented to these carriers for shipment must be packaged, marked, and labeled in accordance with IATA requirements, and must be accompanied by the appropriate shipping documentation. Only personnel trained and certified under applicable DOT Hazardous Materials Regulations (contained in Title 49 of the Code of Federal Regulations) may prepare any LKD product for air transport. LKD is not classified as a hazardous material by DOT when transported by means other than air.

Section 15. Regulatory information EPA Regulations: RCRA Hazardous Waste Number: not listed (40 CFR 261.33) RCRA Hazardous Waste Classification (40 CFR 261): not classified CERCLA Hazardous Substance (40 CFR 302.4) unlisted specific per RCRA, Sec. 3001; CWA, Sec. 311 (b)(4); CWA, Sec. 307(a), CAA, Sec. 112 CERCLA Reportable Quantity, not listed. SARA 311/312 Codes: not listed. SARA Toxic Chemical (40 CFR 372.65): not listed. SARA EHS (Extremely Hazardous Substance) ( 40 CFR 355): Not listed, Threshold Planning Quantity (TPQ): not listed

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OSHA/MSHA Regulations: Air Containment (29 CFR 1910.1000, Table Z-1, Z-1-A): 5 mg/M3 TWA-8 MSHA: not listed OSHA Specifically Regulated Substance ( 29 CFR 1910) not listed State Regulations: Consult state and local authorities for guidance

Section 16. Other information History Date of issue (mm/dd/yyyy) : 06/01/2015 Version : 1 Disclaimer: The information contained in this document applies to this specific material as supplied. Pete Lien & Sons, Inc. believes that the information contained in this SDS is accurate. The suggested precautions and recommendations are based on recognized good work practices and experience as of the date of publication. They are not necessarily all-inclusive or fully adequate in every circumstance as not all use circumstances can be anticipated. The suggestions should not be confused with nor followed in violation of applicable laws, regulation, rules or insurance requirement. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for one’s own particular use. Since the actual use of the product described herein is beyond our control, Pete Lien & Sons, Inc. , assumes no liability arising out of the use of the product by others. Appropriate warnings and safe handling procedures should be provided to handlers and users. Product must not be used in a manner which could result in harm.

Date Printed: 5/12/2017

Safety Data Sheet* Trusted Quality Since 1921 *

www.rustoleum.com

1. Identification

Product Name: PRO LSPR 6PK MARK FLUORESCENTORANGE

Revision Date: 5/12/2017

Product Identifier: 2554838 Supercedes Date: 6/5/2015

Product Use/Class: Marking Paint/Aerosols

Supplier: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA

Manufacturer: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA

Preparer: Regulatory Department

24 Hour Hotline: 847-367-7700Emergency Telephone:

2. Hazard Identification

Classification

Symbol(﴾s)﴿ of Product

Signal WordDanger

Possible Hazards27% of the mixture consists of ingredient(﴾s)﴿ of unknown acute toxicity.

GHS HAZARD STATEMENTSCarcinogenicity, category 2 H351 Suspected of causing cancer.Compressed Gas H280 Contains gas under pressure;; may explode if heated.Flammable Aerosol, category 1 H222 Extremely flammable aerosol.STOT, repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated exposure.

GHS LABEL PRECAUTIONARYSTATEMENTSP201 Obtain special instructions before use.P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking.P211 Do not spray on an open flame or other ignition source.P251 Do not pierce or burn, even after use.P260 Do not breathe dust/fume/gas/mist/vapors/spray.P280 Wear protective gloves/protective clothing/eye protection/face protection.P308+P313 IF exposed or concerned: Get medical advice/attention.P314 Get medical advice/attention if you feel unwell.P405 Store locked up.P410+P403 Protect from sunlight. Store in a well-ventilated place.P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F.

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P501 Dispose of contents/container in accordance with local, regional and national regulations.

3. Composition/Information On Ingredients

HAZARDOUS SUBSTANCES

Chemical Name CAS-No. Wt.%Range

GHS Symbols GHS Statements

Propane 74-98-6 10-25 GHS04 H280

Naphtha, Petroleum, Hydrotreated Light 64742-49-0 2.5-10 GHS08 H304

n-Butane 106-97-8 2.5-10 GHS04 H280

Hydrotreated Light Distillate 64742-47-8 2.5-10 GHS08 H304

Xylenes (﴾o-, m-, p- isomers)﴿ 1330-20-7 2.5-10 GHS02-GHS07 H226-315-319-332

Barium Sulfate 7727-43-7 2.5-10 Not Available Not Available

Ethylbenzene 100-41-4 1.0-2.5 GHS02-GHS07-GHS08 H225-304-332-351-373

Stoddard Solvent 8052-41-3 0.1-1.0 GHS08 H304-372

Pigment Orange 13 3520-72-7 0.1-1.0 Not Available Not Available

Crystalline Silica / Quartz 14808-60-7 0.1-1.0 Not Available Not Available

4. First-aid Measures

FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.

FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.

FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.

FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.

5. Fire-fighting Measures

EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted.

SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.

6. Accidental Release Measures

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STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (﴾provincial)﴿ and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.

7. Handling and Storage

HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only in a well-ventilated area. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of flammable aerosols. Keep away from heat, sparks, flame and sources of ignition. Contents under pressure. Do not expose to heat or store above 120 ° F. Avoid excess heat. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials.

8. Exposure Controls/Personal Protection

Chemical Name CAS-No. Weight %Less Than

ACGIH TLV-TWA

ACGIH TLV-STEL

OSHA PEL-TWA

OSHA PEL-CEILING

Propane 74-98-6 20.0 N.E. N.E. 1000 ppm N.E.Naphtha, Petroleum,Hydrotreated Light 64742-49-0 10.0 N.E. N.E. N.E. N.E.

n-Butane 106-97-8 10.0 N.E. 1000 ppm N.E. N.E.Hydrotreated Light Distillate 64742-47-8 10.0 N.E. N.E. N.E. N.E.Xylenes (﴾o-, m-, p- isomers)﴿ 1330-20-7 5.0 100 ppm 150 ppm 100 ppm N.E.Barium Sulfate 7727-43-7 5.0 5 mg/m3 N.E. 15 mg/m3 N.E.Ethylbenzene 100-41-4 5.0 20 ppm N.E. 100 ppm N.E.Stoddard Solvent 8052-41-3 1.0 100 ppm N.E. 500 ppm N.E.Pigment Orange 13 3520-72-7 1.0 N.E. N.E. N.E. N.E.Crystalline Silica / Quartz 14808-60-7 1.0 0.025 mg/m3 N.E. 50 µg/m3 N.E.

PERSONAL PROTECTION

ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.

RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.

SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.

EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.

OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.

HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.

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9. Physical and Chemical Properties

Appearance: Aerosolized Mist Physical State: LiquidOdor: Solvent Like Odor Threshold: N.E.Relative Density: 0.857 pH: N.A.Freeze Point, °C: N.D. Viscosity: N.D.Solubility in Water: Slight Partition Coefficient, n-

octanol/water: N.D.Decompostion Temp., °C: N.D.Boiling Range, °C: -37 - 537 Explosive Limits, vol%: 0.9 - 12.6Flammability: Supports Combustion Flash Point, °C: -96Evaporation Rate: Faster than Ether Auto-ignition Temp., °C: N.D.Vapor Density: Heavier than Air Vapor Pressure: N.D.

(﴾See "Other information" Section for abbreviation legend)﴿

10. Stability and Reactivity

CONDITIONS TO AVOID: Avoid temperatures above 120°F (﴾49°C)﴿. Avoid contact with strong acid and strong bases. Avoid all possible sources of ignition.

INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.

HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

STABILITY: This product is stable under normal storage conditions.

11. Toxicological information

EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. May cause skin irritation. Allergic reactions are possible. Prolonged or repeated contact may cause skin irritation.

EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.

EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Aspiration hazard if swallowed;; can enter lungs and cause damage.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (﴾e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision)﴿ and/or damage. High concentrations may lead to central nervous system effects (﴾drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision)﴿ and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (﴾group 2B)﴿.

PRIMARY ROUTE(﴾S)﴿ OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUESThe acute effects of this product have not been tested. Data on individual components are tabulated below:CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC5074-98-6 Propane N.I. N.I. 658 mg/L Rat64742-49-0 Naphtha, Petroleum, Hydrotreated Light >5000 mg/kg Rat >3160 mg/kg Rabbit >4951 mg/L Rat106-97-8 n-Butane N.I. N.I. 658 mg/L Rat64742-47-8 Hydrotreated Light Distillate >5000 mg/kg Rat >2000 mg/kg Rabbit >5000 mg/L Rat1330-20-7 Xylenes (﴾o-, m-, p- isomers)﴿ 3500 mg/kg Rat >4350 mg/kg Rabbit 29.08 mg/L Rat100-41-4 Ethylbenzene 3500 mg/kg Rat 15400 mg/kg Rabbit 17.4 mg/L Rat3520-72-7 Pigment Orange 13 >5000 mg/kg Rat N.I. N.I.14808-60-7 Crystalline Silica / Quartz 5500 mg/kg Rat 5500 100 mg/L

N.I. - No Information

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12. Ecological Information

ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems.

14. Transport InformationDomestic (﴾USDOT)﴿ International (﴾IMDG)﴿ Air (﴾IATA)﴿ TDG (﴾Canada)﴿

UN Number: N.A. 1950 1950 N.A.

Proper Shipping Name: Paint Products inLimited Quantities Aerosols Aerosols Paint Products in

Limited Quantities

Hazard Class: N.A. 2.1 2.1 N.A.

Packing Group: N.A. N.A. N.A. N.A.

Limited Quantity: Yes Yes Yes Yes

15. Regulatory Information

U.S. Federal Regulations:CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (﴾SARA Title III)﴿ and is considered, under applicable definitions, tomeet the following categories:

Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard

Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name CAS-No.Xylenes (﴾o-, m-, p- isomers)﴿ 1330-20-7Ethylbenzene 100-41-4

Toxic Substances Control Act:This product contains the following chemical substances subject to the reporting requirements of TSCA 12(﴾b)﴿ if exportedfrom the United States:

Chemical Name CAS-No.Castor oil, sulfated, sodium salt 68187-76-8

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16. Other Information

HMIS RATINGSHealth: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X

NFPA RATINGSHealth: 2 Flammability: 4 Instability 0

VOLATILE ORGANIC COMPOUNDS, g/L: 551

SDS REVISION DATE: 5/12/2017

REASON FOR REVISION: Product Composition ChangedSubstance and/or Product Properties Changed in Section(﴾s)﴿: 02 - Hazard Identification 05 - Fire-fighting Measures 16 - Other InformationStatement(﴾s)﴿ Changed

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

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Propane Safety Data Sheet E-4646 according to the Hazardous Products Regulation (February 11, 2015) Date of issue: 10-15-1979 Revision date: 08-03-2016 Supersedes: 10-15-2013

This document is only controlled while on the Praxair Canada Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or accuracy of any version of this document after it has been downloaded or removed from our website.

EN (English) SDS ID : E-4646 1/10

SECTION 1: Identification 1.1. Product identifier Product form Name CAS No Formula Other means of identification

: Substance : Propane : 74-98-6 : C3H8 : Propane, Liquefied Petroleum Gas, n-propane,dimethylmethane,propyl hydride, refrigerant gas

R290 Product group : Core Products

1.2. Recommended use and restrictions on use Recommended uses and restrictions : Industrial use

Use as directed

1.3. Supplier Praxair Canada inc. 1200 – 1 City Centre Drive Mississauga - Canada L5B 1M2 T 1-905-803-1600 - F 1-905-803-1682 www.praxair.ca

1.4. Emergency telephone number Emergency number : 1-800-363-0042

Call emergency number 24 hours a day only for spills, leaks, fire, exposure, or accidents involving this product. For routine information, contact your supplier or Praxair sales representative.

SECTION 2: Hazard identification 2.1. Classification of the substance or mixture

GHS-CA classification Flam. Gas 1 H220 Liquefied gas H280

2.2. GHS Label elements, including precautionary statements

GHS-CA labelling

Hazard pictograms :

GHS02 GHS04

Signal word : DANGER

Hazard statements : EXTREMELY FLAMMABLE GAS CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION MAY CAUSE FROSTBITE MAY FORM EXPLOSIVE MIXTURES WITH AIR

Precautionary statements : Do not handle until all safety precautions have been read and understood Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Use and store only outdoors or in a well-ventilated area Leaking gas fire: Do not extinguish, unless leak can be stopped safely In case of leakage, eliminate all ignition sources


This document is only controlled while on the Praxair Canada Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the

integrity or accuracy of any version of this document after it has been downloaded or removed from our website.

EN (English) SDS ID : E-4646

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Protect from sunlight when ambient temperature exceeds 52°C (125°F) Use a back flow preventive device in the piping Close valve after each use and when empty Never put cylinders into unventilated areas of passenger vehicles Do not open valve until connected to equipment prepared for use

2.3. Other hazards Other hazards not contributing to the classification

: Contact with liquid may cause cold burns/frostbite.

2.4. Unknown acute toxicity (GHS-CA) No data available

SECTION 3: Composition/information on ingredients

3.1. Substances

Name CAS No. % (Vol.) Common Name (synonyms) Propane (Main constituent)

(CAS No) 74-98-6 100 Propane liquefied / Normal propane / n-Propane / PROPANE

3.2. Mixtures Not applicable

SECTION 4: First-aid measures

4.1. Description of first aid measures First-aid measures after inhalation : Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep

victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped. First-aid measures after skin contact : The liquid may cause frostbite. For exposure to liquid, immediately warm frostbite area with

warm water not to exceed 105°F (41°C). Water temperature should be tolerable to normal skin. Maintain skin warming for at least 15 minutes or until normal coloring and sensation have returned to the affected area. In case of massive exposure, remove clothing while showering with warm water. Seek medical evaluation and treatment as soon as possible.

First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an ophthalmologist immediately. Get immediate medical attention.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects (acute and delayed) No additional information available

4.3. Immediate medical attention and special treatment, if necessary Other medical advice or treatment : None.

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media Suitable extinguishing media : Carbon dioxide, dry chemical powder, water spray, fog.

5.2. Unsuitable extinguishing media No additional information available

5.3. Specific hazards arising from the hazardous product Fire hazard : EXTREMELY FLAMMABLE GAS. If venting or leaking gas catches fire, do not extinguish

flames. Flammable vapors may spread from leak, creating an explosive reignition hazard. Vapors can be ignited by pilot lights, other flames, smoking, sparks, heaters, electrical equipment, static discharge, or other ignition sources at locations distant from product handling point. Explosive atmospheres may linger. Before entering an area, especially a confined area, check the atmosphere with an appropriate device.

Explosion hazard : EXTREMELY FLAMMABLE GAS. Forms explosive mixtures with air and oxidizing agents. Reactivity : No reactivity hazard other than the effects described in sub-sections below. Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.





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5.4. Special protective equipment and precautions for fire-fighters Firefighting instructions : Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA)

and protective clothing. Immediately cool containers with water from maximum distance. Stop flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must comply with their provincial and local fire code regulations.

Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen. Special protective equipment for fire fighters : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire

fighters. Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat

radiation may cause gas containers to rupture. Cool endangered containers with water spray jet from a protected position. Prevent water used in emergency cases from entering sewers and drainage systems Stop flow of product if safe to do so Use water spray or fog to knock down fire fumes if possible.

Other information : Containers are equipped with a pressure relief device. (Exceptions may exist where authorized by TC.).

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures General measures : Wear self-contained breathing apparatus when entering area unless atmosphere is proven to

be safe. Evacuate area. Ensure adequate air ventilation. Stop leak if safe to do so. 6.2. Methods and materials for containment and cleaning up 6.3. Reference to other sections For further information refer to section 8: Exposure controls/personal protection

SECTION 7: Handling and storage

7.1. Precautions for safe handling Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking. Use only non-sparking tools. Use only explosion-proof equipment Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver, pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the valve is hard to open, discontinue use and contact your supplier. Close the container valve after each use; keep closed even when empty. Never apply flame or localized heat directly to any part of the container. High temperatures may damage the container and could cause the pressure relief device to fail prematurely, venting the container contents. For other precautions in using this product, see section 16.





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7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store only where temperature will not exceed 125°F (52°C). Post “No Smoking" or "Open

Flames” signs in storage and use areas. There must be no sources of ignition. Separate packages and protect against potential fire and/or explosion damage following appropriate codes and requirements (e.g, NFPA 30, NFPA 55, NFPA 70, and/or NFPA 221 in the U.S.) or according to requirements determined by the Authority Having Jurisdiction (AHJ). Always secure containers upright to keep them from falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand when the container is not in use. Store full and empty containers separately. Use a first-in, first-out inventory system to prevent storing full containers for long periods. For other precautions in using this product, see section 16 OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may become part of an electrical circuit.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters Propane (74-98-6) USA - OSHA OSHA PEL (TWA) (mg/m³) 1800 mg/m³

USA - OSHA OSHA PEL (TWA) (ppm) 1000 ppm

Canada (Quebec) VEMP (mg/m³) 1800 mg/m³ Canada (Quebec) VEMP (ppm) 1000 ppm Alberta OEL TWA (ppm) 1000 ppm British Columbia OEL TWA (ppm) 1000 ppm

Northwest Territories OEL STEL (ppm) 1250 ppm

Northwest Territories OEL TWA (ppm) 1000 ppm

Québec VEMP (mg/m³) 1800 mg/m³ Québec VEMP (ppm) 1000 ppm Saskatchewan OEL STEL (ppm) 1250 ppm

Saskatchewan OEL TWA (ppm) 1000 ppm

8.2. Appropriate engineering controls Appropriate engineering controls : An explosion-proof local exhaust system or a mechanical system is acceptable if it can prevent

oxygen deficiency and keep hazardous fumes and gases below all applicable exposure limits in the worker's breathing area. During welding, ensure that there is adequate ventilation to keep worker exposure below applicable limits for fumes, gases, and other by-products of welding. Do not breathe fumes or gases. Short-term overexposure to fumes may cause dizziness, nausea, and dryness or irritation of the nose, throat, and eyes, or may cause other similar discomfort.

8.3. Individual protection measures/Personal protective equipment Personal protective equipment : Safety glasses. Face shield. Gloves.

Hand protection : Wear work gloves when handling containers. Wear heavy rubber gloves where contact with

product may occur. Eye protection : Wear goggles when transfilling or breaking transfer connections. Select in accordance with the

current CSA standard Z94.3, "Industrial Eye and Face Protection", and any provincial regulations, local bylaws or guidelines.





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Skin and body protection : As needed for welding, wear hand, head, and body protection to help prevent injury from radiation and sparks. (See ANSI Z49.1.) At a minimum, this includes welder’s gloves and protective goggles, and may include arm protectors, aprons, hats, and shoulder protection as well as substantial clothing.

Respiratory protection : Respiratory protection: Use respirable fume respirator or air supplied respirator when working in confined space or where local exhaust or ventilation does not keep exposure below TLV. Select in accordance with provincial regulations, local bylaws or guidelines. Selection should be based on the current CSA standard Z94.4, "Selection, Care, and Use of Respirators." Respirators should also be approved by NIOSH and MSHA. For emergencies or instances with unknown exposure levels, use a self-contained breathing apparatus (SCBA).

Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections. Environmental exposure controls : Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for

specific methods for waste gas treatment. Other information : Other protection : Safety shoes for general handling at customer sites. Metatarsal shoes and

cuffless trousers for cylinder handling at packaging and filling plants. Select in accordance with the current CSA standard Z195, "Protective Foot Wear", and any provincial regulations, local bylaws or guidelines. For working with flammable and oxidizing materials, consider the use of flame resistant anti-static safety clothing.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties Physical state : Gas

Appearance : Colorless gas.

Molecular mass : 44 g/mol Colour : Colourless.

Odour : Poor warning properties at low concentrations. Stenchant often added. Sweetish.

Odour threshold : No data available

pH : Not applicable.

pH solution : No data available

Relative evaporation rate (butylacetate=1) : No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : No data available

Freezing point : -187.69 °C (-305.8°F)

Boiling point : -42.1 °C (-44.32°F)

Flash point : -104.4 °C (-155.2°F) TCC

Critical temperature : 96.8 °C (206°F) Auto-ignition temperature : 450 °C (842°F)

Decomposition temperature : No data available

Vapour pressure : 8.58 bar (109.73 psig)

Vapour pressure at 50 °C : No data available

Relative vapour density at 20 °C : No data available

Relative density : 0.58

Relative density of saturated gas/air mixture : No data available

Density : 0.506 - 0.583 g/cm³ (at 15 °C)

Relative gas density : 1.5

Solubility : Water: 75 mg/l

Log Pow : 2.36

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Viscosity, kinematic (calculated value) (40 °C) : No data available

Explosive properties : Not applicable.

Oxidizing properties : None.

Flammability (solid, gas) : 2.1 - 9.5 vol %





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9.2. Other information Gas group : Liquefied gas Additional information : Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below

ground level

SECTION 10: Stability and reactivity

10.1. Reactivity Reactivity : No reactivity hazard other than the effects described in sub-sections below. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : Can form explosive mixture with air. May react violently with oxidants. Conditions to avoid : Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Incompatible materials : Air, Oxidiser. Chlorine dioxide. Hazardous decomposition products : Thermal decomposition or burning may produce carbon monoxide, carbon dioxide, and

hydrogen. The welding and cutting process may form reaction products such as carbon monoxide and carbon dioxide. Other decomposition products of normal operation originate from the volatilization, reaction, or oxidation of the material being worked.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Not classified

Propane ( \f )74-98-6 LC50 inhalation rat (mg/l) 658 mg/l/4h ATE CA (vapours) 658.00000000 mg/l/4h ATE CA (dust,mist) 658.00000000 mg/l/4h

Skin corrosion/irritation : Not classified pH: Not applicable.

Serious eye damage/irritation : Not classified pH: Not applicable.

Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified

Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure)

: Not classified

Aspiration hazard : Not classified

Propane (74-98-6) Hydrocarbon Yes

SECTION 12: Ecological information

12.1. Toxicity Ecology - general : No ecological damage caused by this product.





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12.2. Persistence and degradability Propane (74-98-6) Persistence and degradability The substance is biodegradable. Unlikely to persist.

12.3. Bioaccumulative potential Propane (74-98-6) Log Pow 2.36 Log Kow Not applicable. Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Refer to section 9.

12.4. Mobility in soil Propane (74-98-6) Mobility in soil No data available. Log Pow 2.36 Log Kow Not applicable. Ecology - soil Because of its high volatility, the product is unlikely to cause ground or water pollution.

12.5. Other adverse effects Effect on the ozone layer : None Effect on global warming : No known effects from this product

SECTION 13: Disposal considerations

13.1. Disposal methods Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international

regulations. Contact supplier for any special requirements.

SECTION 14: Transport information

14.1. Basic shipping description In accordance with TDG TDG UN-No. (TDG) : UN1978 TDG Primary Hazard Classes : 2.1 - Class 2.1 - Flammable Gas. Proper shipping name : PROPANE ERAP Index : 3 000 Explosive Limit and Limited Quantity Index : 0.125 L Passenger Carrying Ship Index : 110 kg Passenger Carrying Road Vehicle or Passenger Carrying Railway Vehicle Index

: Forbidden

14.3. Air and sea transport

IMDG UN-No. (IMDG) : 1978 Proper Shipping Name (IMDG) : PROPANE Class (IMDG) : 2 - Gases MFAG-No : 115 IATA UN-No. (IATA) : 1978 Proper Shipping Name (IATA) : PROPANE Class (IATA) : 2

SECTION 15: Regulatory information





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15.1. National regulations Propane (74-98-6) Listed on the Canadian DSL (Domestic Substances List)

15.2. International regulations Propane (74-98-6) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on INSQ (Mexican national Inventory of Chemical Substances) Listed on CICR (Turkish Inventory and Control of Chemicals)

SECTION 16: Other information Date of issue : 15/10/1979 Revision date : 03/08/2016 Supersedes : 15/10/2013

Indication of changes: Training advice : The hazard of asphyxiation is often overlooked and must be stressed during operator training.

Ensure operators understand the flammability hazard.





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Other information : When using this product in welding and cutting, read and understand the manufacturer’s instructions and the precautionary label on the product. Ask your welding products supplier for a copy of Praxair’s free safety booklet, P-2035, Precautions and Safe Practices for Gas Welding, Cutting, and Heating, and for other manufacturers’ safety publications. For a detailed treatment, get ANSI Z49.1, Safety in Welding, Cutting, and Allied Processes, published by the American Welding Society (AWS), www.aws.org. Order AWS documents from Global Engineering Documents, global.ihs.com. Arcs and sparks can ignite combustible materials. Prevent fires. Refer to NFPA 51B, Standard for Fire Prevention During Welding, Cutting, and Other Hotwork. Do not strike an arc on the container. The defect produced by an arc burn may lead to container rupture Fumes and gases produced during welding and cutting processes can be dangerous to your health and may cause serious lung disease. KEEP YOUR HEAD OUT OF FUMES. DO NOT BREATHE FUMES AND GASES. Use enough ventilation, local exhaust, or both to keep fumes and gases from your breathing zone and the general area. Short-term overexposure to fumes may cause dizziness, nausea, and dryness or irritation of the nose, throat, and eyes; or may cause other similar discomfort. Contaminants in the air may add to the hazard of fumes and gases When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an industrial hygienist or other trained person when you evaluate the end product. Before using any plastics, confirm their compatibility with this product Praxair asks users of this product to study this SDS and become aware of the product hazards and safety information. To promote safe use of this product, a user should (1) notify employees, agents, and contractors of the information in this SDS and of any other known product hazards and safety information, (2) furnish this information to each purchaser of the product, and (3) ask each purchaser to notify its employees and customers of the product hazards and safety information The opinions expressed herein are those of qualified experts within Praxair Canada Inc. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and the conditions of use are not within the control of Praxair Canada Inc, it is the user's obligation to determine the conditions of safe use of the product. Praxair Canada Inc, SDSs are furnished on sale or delivery by Praxair Canada Inc, or the independent distributors and suppliers who package and sell our products. To obtain current SDSs for these products, contact your Praxair sales representative, local distributor, or supplier, or download from www.praxair.ca. If you have questions regarding Praxair SDSs, would like the document number and date of the latest SDS, or would like the names of the Praxair suppliers in your area, phone or write Praxair Canada Inc, (Phone: 1-888-257-5149; Address: Praxair Canada Inc, 1 City Centre Drive, Suite 1200, Mississauga, Ontario, L5B 1M2). PRAXAIR and the Flowing Airstream design are trademarks or registered trademarks of Praxair Technology, Inc. in the United States and/or other countries.

NFPA health hazard : 2 - Intense or continued exposure could cause temporary

incapacitation or possible residual injury unless prompt medical attention is given.

NFPA fire hazard : 4 - Will rapidly or completely vaporize at normal pressure and temperature, or is readily dispersed in air and will burn readily.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 4 Severe Hazard - Flammable gases, or very volatile flammable liquids with flash points below

73 F, and boiling points below 100 F. Materials may ignite spontaneously with air. (Class IA) Physical : 2 Moderate Hazard - Materials that are unstable and may undergo violent chemical changes at

normal temperature and pressure with low risk for explosion. Materials may react violently with water or form peroxides upon exposure to air.





10/10

SDS Canada (GHS) - Praxair This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

Section 5 Fire Fighting Measures

Section 6 Accidental Release Measures

Section 4 First Aid Measures

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Section 3 Composition / Information on Ingredients

Product

CHEMTREC 24 Hour Emergency USA Phone Number (800) 424-9300

For laboratory and industrial use only. Not for drug, food or household use.

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Synonyms

Chemical Name CAS # % EINECS

Page E1 of E2

SAFETY DATA SHEET

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SDS No.:66 GENERAL STORAGE CODE GREEN

1RW.QRZQ1RW.QRZQ

AldonCorporation

221 Rochester StreetAvon, NY 14414(585) 226-6177

Section 7 Handling & Storage

Section 9 Physical & Chemical Properties

Section 10 Stability & Reactivity

Section 11 Toxicological Information

Section 16 Other Information

Section 12 Ecological Information

Section 13 Disposal Considerations

Section 14 Transport Information (US DOT / CANADA TDG)

Section 15 Regulatory InformationA chemical is considered to be listed if the CAS number for the anhydrous form is on the Inventory list.

These disposal guidelines are intended for the disposal of catalog-size quantities only. Federal regulations may apply to empty container. State and/or local UHJXODWLRQVPD\EHGLႇHUHQW'LVSRVHRILQDFFRUGDQFHZLWKDOOORFDOVWDWHDQGIHGHUDOUHJXODWLRQVRUFRQWUDFWZLWKDOLFHQVHGFKHPLFDOGLVSRVDODJHQF\

Component TSCA CERLCA (RQ) RCRA code DSL NDSL CA Prop 65

Section 8 Exposure Controls / Personal ProtectionExposure Limits: Chemical Name ACGIH (TLV) OSHA (PEL) NIOSH (REL)

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7R[LFLW\WR¿VK/HSRPLVPDFURFKLUXVEOXHJLOO/&PJ/>&DOFLXPFKORULGH@Toxicity to daphnia and other aquatic invertebrates:'DSKQLDPDJQDZDWHUÀHD/&PJ/>&DOFLXPFKORULGH@Toxicity to algae:1RGDWDDYDLODEOHPersistence and degradability:1RGDWDDYDLODEOH Bioaccumulative potential:1RGDWDDYDLODEOHMobility in soil:1RGDWDDYDLODEOH PBT and vPvB assessment:1RGDWDDYDLODEOH2WKHUDGYHUVHHႇHFWV$QHQYLURQPHQWDOKD]DUGFDQQRWEHH[FOXGHGLQWKHHYHQWRIXQSURIHVVLRQDOKDQGOLQJRUGLVSRVDO

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UN/NA number:1RWDSSOLFDEOH Shipping name: 1RW5HJXODWHG+D]DUGFODVV1RWDSSOLFDEOH Packing group:1RWDSSOLFDEOH Reportable Quantity: 1R Marine pollutant:1RExceptions:1RWDSSOLFDEOH 2016 ERG Guide # 1RWDSSOLFDEOH

Appearance:&OHDUFRORUOHVVOLTXLGOdor:1RRGRUOdor threshold: Data not available.S+ Data not available.0HOWLQJ)UHH]LQJSRLQW Data not availableBoiling point: &)ZDWHU Flash point: Data not available

Evaporation rate (:DWHU = 1):!Flammability (solid/gas): Data not available. Explosion limits: Lower / Upper: Data not available9DSRUSUHVVXUHPP+JZDWHUVapor density (Air = 1):ZDWHU5HODWLYHGHQVLW\6SHFL¿FJUDYLW\Solubility(ies): &RPSOHWHLQZDWHU

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WARNING -Cancer - www.P65Warnings.ca.gov.

SAFETY DATA SHEET

1. IdentificationSolventProduct identifier

Other means of identification2183Product codeVARSOL 3139 SOLVENTSynonymsSolvent. Fuel. Diluter Feedstock.Recommended useNone known.Recommended restrictions

Manufacturer/Importer/Supplier/Distributor informationManufacturer Consumers' Co-operative Refineries LimitedAddress P.O. Box 260; 9th Avenue North

Regina, SK S4P 3A1 CanadaTelephone (306) 719-4353Supplier Consumers' Co-operative Refineries LimitedAddress P.O. Box 260; 9th Avenue North

Regina, SK S4P 3A1 CanadaTelephone (306) 719-435324-Hour emergencytelephone

(613) 996-6666 - Canutec

2. Hazard(s) identificationCategory 3Flammable liquidsPhysical hazardsCategory 1Physical hazards not otherwise classifiedCategory 2Skin corrosion/irritationHealth hazardsCategory 3 narcotic effectsSpecific target organ toxicity following single

exposureCategory 1Aspiration hazardCategory 2Hazardous to the aquatic environment, acute

hazardEnvironmental hazards

Category 2Hazardous to the aquatic environment,long-term hazard

Label elements

Signal word DangerHazard statement Flammable liquid and vapour. Static accumulating flammable liquid can become electrostatically

charged even in bonded and grounded equipment. Sparks may ignite liquid and vapour. Maycause flash fire or explosion. May be fatal if swallowed and enters airways. Causes skin irritation.May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects.

Precautionary statementsPrevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Keep container tightly closed. Ground and bond container and receiving equipment. These alonemay be insufficient to remove static electricity. Use explosion-proof electrical/ventilating/lightingequipment. Use non-sparking tools. Take action to prevent static discharges. Avoid breathing mistor vapour. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoidrelease to the environment. Wear protective gloves/protective clothing/eye protection/faceprotection.

Solvent SDS Canada904346 Version #: 01 Revision date: - Issue date: 10-January-2017 1 / 8

Response IF SWALLOWED: Immediately call a POISON CENTRE/doctor. Do NOT induce vomiting. IF ONSKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. If skinirritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IFINHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISONCENTRE/doctor if you feel unwell. In case of fire: Use foam, carbon dioxide, dry powder or waterfog to extinguish. In case of leakage, eliminate all ignition sources. Collect spillage.

Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Other hazards None known.Supplemental information None.

3. Composition/information on ingredientsSubstances

8052-41-3 60 - 100Stoddard solvent

CAS numberCommon name andsynonyms

%Chemical name

All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume. Components not listed are either non-hazardous or are below reportablelimits.

Composition comments

4. First-aid measuresRemove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTRE or doctor/physician if you feel unwell.

Inhalation

Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritationoccurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Skin contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Get medical attention if irritation develops and persists.

Eye contact

Call a physician or poison control centre immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Ingestion

Aspiration may cause pulmonary oedema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Direct contact with eyes may cause temporary irritation. Skinirritation. May cause redness and pain.

Most importantsymptoms/effects, acute anddelayed

Provide general supportive measures and treat symptomatically. Thermal burns: Flush with waterimmediately. While flushing, remove clothes which do not adhere to affected area. Call anambulance. Continue flushing during transport to hospital. Keep victim under observation.Symptoms may be delayed.

Indication of immediatemedical attention and specialtreatment needed

Take off all contaminated clothing immediately. Ensure that medical personnel are aware of thematerial(s) involved, and take precautions to protect themselves. Wash contaminated clothingbefore reuse.

General information

5. Fire-fighting measuresWater fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth maybe used for small fires only.

Suitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishingmedia

Vapours may form explosive mixtures with air. Vapours may travel considerable distance to asource of ignition and flash back. This product is a poor conductor of electricity and can becomeelectrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures canoccur. To reduce potential for static discharge, use proper bonding and grounding procedures.This liquid may accumulate static electricity when filling properly grounded containers. Staticelectricity accumulation may be significantly increased by the presence of small quantities of wateror other contaminants. Material will float and may ignite on surface of water. During fire, gaseshazardous to health may be formed.

Specific hazards arising fromthe chemical

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipmentand precautions for firefighters

In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can doso without risk.

Fire fightingequipment/instructions

Use standard firefighting procedures and consider the hazards of other involved materials.Specific methodsFlammable liquid and vapour.General fire hazards


6. Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate allignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriateprotective equipment and clothing during clean-up. Avoid breathing mist or vapour. Do not touchdamaged containers or spilled material unless wearing appropriate protective clothing. Ventilateclosed spaces before entering them. Use appropriate containment to avoid environmentalcontamination. Transfer by mechanical means such as vacuum truck to a salvage tank or othersuitable container for recovery or safe disposal. Local authorities should be advised if significantspillages cannot be contained. For personal protection, see section 8 of the SDS.

Personal precautions,protective equipment andemergency procedures

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keepcombustibles (wood, paper, oil etc) away from spilled material. Take precautionary measuresagainst static discharge. Use only non-sparking tools. Prevent entry into waterways, sewer,basements or confined areas.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Use a non-combustible material like vermiculite, sand or earth to soak up the productand place into a container for later disposal. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containersfor later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Methods and materials forcontainment and cleaning up

Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground. Use appropriate containment to avoid environmentalcontamination.

Environmental precautions

7. Handling and storageDo not handle, store or open near an open flame, sources of heat or sources of ignition. Protectmaterial from direct sunlight. When using do not smoke. Explosion-proof general and local exhaustventilation. Minimize fire risks from flammable and combustible materials (including combustibledust and static accumulating liquids) or dangerous reactions with incompatible materials. Handlingoperations that can promote accumulation of static charges include but are not limited to: mixing,filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and containerfilling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Takeprecautionary measures against static discharges. All equipment used when handling the productmust be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste orswallow. Avoid breathing mist or vapour. Avoid contact with eyes, skin, and clothing. Wearappropriate personal protective equipment. Wash hands thoroughly after handling. Avoid releaseto the environment. Observe good industrial hygiene practices.

For additional information on equipment bonding and grounding, refer to the Canadian ElectricalCode in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or NationalFire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or NationalFire Protection Association (NFPA) 70, "National Electrical Code".

Precautions for safe handling

Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic chargebuild-up by using common bonding and grounding techniques. Eliminate sources of ignition. Avoidspark promoters. Ground/bond container and equipment. These alone may be insufficient toremove static electricity. Store in a cool, dry place out of direct sunlight. Store in original tightlyclosed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Storeaway from incompatible materials (see section 10 of the SDS).

Conditions for safe storage,including any incompatibilities

8. Exposure controls/personal protectionOccupational exposure limits

US. ACGIH Threshold Limit Values

ValueTypeMaterialTWA 100 ppmSolvent (CAS Mixture)

ValueTypeComponentsTWA 100 ppmStoddard solvent (CAS

8052-41-3)


Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

ValueTypeMaterialTWA 572 mg/m3Solvent (CAS Mixture)

100 ppmValueTypeComponents

TWA 572 mg/m3Stoddard solvent (CAS8052-41-3)

100 ppm

Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health andSafety Regulation 296/97, as amended)

ValueTypeMaterialSTEL 580 mg/m3Solvent (CAS Mixture)TWA 290 mg/m3

ValueTypeComponentsSTEL 580 mg/m3Stoddard solvent (CAS

8052-41-3)TWA 290 mg/m3

Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)



8052-41-3)Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)



8052-41-3)Canada. Quebec OELs. (Ministry of Labour - Regulation Respecting the Quality of the Work Environment)

ValueTypeMaterialTWA 525 mg/m3Solvent (CAS Mixture)

100 ppmValueTypeComponents

TWA 525 mg/m3Stoddard solvent (CAS8052-41-3)

100 ppmNo biological exposure limits noted for the ingredient(s).Biological limit valuesExplosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 airchanges per hour) should be used. Ventilation rates should be matched to conditions. Ifapplicable, use process enclosures, local exhaust ventilation, or other engineering controls tomaintain airborne levels below recommended exposure limits. If exposure limits have not beenestablished, maintain airborne levels to an acceptable level. Provide easy access to water supplyor an emergency shower.

Appropriate engineeringcontrols

Individual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles).Eye/face protection

Skin protectionWear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glovesupplier.

Hand protection

Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other


If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn. Selection and use of respiratoryprotective equipment should be in accordance with OSHA General Industry Standard 29 CFR1910.134; or in Canada with CSA Standard Z94.4.

Respiratory protection

Wear appropriate thermal protective clothing, when necessary.Thermal hazards

Observe any medical surveillance requirements. When using do not smoke. Always observe goodpersonal hygiene measures, such as washing after handling the material and before eating,drinking, and/or smoking. Routinely wash work clothing and protective equipment to removecontaminants.

General hygieneconsiderations

9. Physical and chemical properties AppearanceLiquid.Physical stateLiquid.FormClear. Colourless.ColourMild. Petroleum.Odour

Odour threshold Not available.

pH Not applicable.

Melting point/freezing point -58 °C (-72.4 °F)

Initial boiling point and boilingrange

158 - 195 °C (316.4 - 383 °F)

Flash point 43.0 °C (109.4 °F) Closed cup

Evaporation rate 0.1 (Butyl acetate = 1)Not applicable.Flammability (solid, gas)

Upper/lower flammability or explosive limitsFlammability limit - lower(%)

1 %

Flammability limit - upper(%)

13.3 %

Explosive limit - lower (%) Not available.

Explosive limit – upper(%)

Not available.

Vapour pressure 0.04 kPa

Vapour density 5

Relative density Not available.

Solubility(ies)Solubility (water) Not available.

Partition coefficient(n-octanol/water)

Not available.

Auto-ignition temperature 229 °C (444.2 °F)

Decomposition temperature Not available.

Viscosity Not available.

Other informationNot explosive.Explosive propertiesNot oxidising.Oxidising properties

Surface tension 27 - 50 mN/m (20 °C (68 °F))

VOC 100 %

10. Stability and reactivityThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityHazardous polymerisation does not occur.Possibility of hazardous

reactionsAvoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials.Conditions to avoid


Strong oxidising agents.Incompatible materialsThermal decomposition of this product can generate carbon monoxide and carbon dioxide.Hazardous decomposition

products

11. Toxicological informationInformation on likely routes of exposure

Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting.

Skin contact Causes skin irritation.

Eye contact Direct contact with eyes may cause temporary irritation.

Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Symptoms related to thephysical, chemical andtoxicological characteristics

Aspiration may cause pulmonary oedema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Skin irritation. May cause redness and pain.

Information on toxicological effectsAcute toxicity Not expected to be acutely toxic.

Test resultsComponents SpeciesStoddard solvent (CAS 8052-41-3)

DermalAcute

LD50 Rabbit > 2000 mg/kg

InhalationLC50 Rat > 5.2 mg/l, 4 hours

OralLD50 Rat > 5000 mg/kg

Causes skin irritation.Skin corrosion/irritationDirect contact with eyes may cause temporary irritation.Serious eye damage/eye

irritationRespiratory or skin sensitisation

Respiratory sensitisation Not a respiratory sensitiser.This product is not expected to cause skin sensitisation.Skin sensitisationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Germ cell mutagenicity

Carcinogenicity Not classifiable as to carcinogenicity to humans.This product is not expected to cause reproductive or developmental effects.Reproductive toxicity

Specific target organ toxicity -single exposure

May cause drowsiness and dizziness.

Specific target organ toxicity -repeated exposure

Not classified.

Aspiration hazard May be fatal if swallowed and enters airways.

Chronic effects Prolonged inhalation may be harmful.

12. Ecological informationToxic to aquatic life with long lasting effects.EcotoxicityNo data is available on the degradability of this product.Persistence and degradability Bioaccumulative potential

Partition coefficient n-octanol / water (log Kow)Stoddard solvent (CAS 8052-41-3) 3.16 - 7.15

No data available.Mobility in soilOther adverse effects The product contains volatile organic compounds which have a photochemical ozone creation

potential.


13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allowthis material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditcheswith chemical or used container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.

Disposal instructions

Dispose in accordance with all applicable regulations.Local disposal regulationsThe waste code should be assigned in discussion between the user, the producer and the wastedisposal company.

Hazardous waste code

Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).

Waste from residues / unusedproducts

Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.

Contaminated packaging

14. Transport informationTDG

UN1268UN numberPetroleum distillates, n.o.s.UN proper shipping name

3ClassTransport hazard class(es)

-Subsidiary riskIIIPacking groupYesEnvironmental hazardsRead safety instructions, SDS and emergency procedures before handling.Special precautions for user

IATAUN1268UN numberPetroleum distillates, n.o.s.UN proper shipping name


-Subsidiary risk3Label(s)IIIPacking groupYesEnvironmental hazardsRead safety instructions, SDS and emergency procedures before handling.Special precautions for user

IMDGUN1268UN numberPETROLEUM DISTILLATES, N.O.S.UN proper shipping name


-Subsidiary riskIIIPacking group

YesMarine pollutantEnvironmental hazards

F-E, S-EEmSRead safety instructions, SDS and emergency procedures before handling.Special precautions for userNot applicable.Transport in bulk according to

Annex II of MARPOL 73/78 andthe IBC Code

15. Regulatory informationThis product has been classified in accordance with the hazard criteria of the HPR and the SDScontains all the information required by the HPR.

Canadian regulations

Controlled Drugs and Substances ActNot regulated.

Export Control List (CEPA 1999, Schedule 3)Not listed.

Greenhouse GasesNot listed.


Precursor Control RegulationsNot regulated.

International regulationsStockholm Convention

Not applicable.Rotterdam Convention

Not applicable.Kyoto protocol

Not applicable.Montreal Protocol

Not applicable.Basel Convention

Not applicable.

International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*

Australian Inventory of Chemical Substances (AICS) YesAustraliaDomestic Substances List (DSL) YesCanadaNon-Domestic Substances List (NDSL) NoCanadaInventory of Existing Chemical Substances in China (IECSC) YesChinaEuropean Inventory of Existing Commercial ChemicalSubstances (EINECS)

YesEurope

European List of Notified Chemical Substances (ELINCS) NoEuropeInventory of Existing and New Chemical Substances (ENCS) YesJapanExisting Chemicals List (ECL) YesKoreaNew Zealand Inventory YesNew ZealandPhilippine Inventory of Chemicals and Chemical Substances(PICCS)

YesPhilippines

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico

16. Other information10-January-2017Issue date-Revision date

Version No. 01The classification for health and environmental hazards is derived by a combination of calculationmethods and test data, if available.

Further information

To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.

Disclaimer


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Safety Data Sheet

1 - Identification Trade Name: WD-40 Aerosol Product Use: Lubricant, Penetrant, Drives Out Moisture, Removes and Protects Surfaces From Corrosion Restrictions on Use: None identified SDS Date Of Preparation: November 15, 2016

Canadian Office: WD-40 Products [Canada] Ltd. P.O. Box 220 Toronto, Ontario M9C 4V3 Information Phone #: (416) 622-9881 Emergency Phone # 24 hr: Canutec: (613) 996-6666 - Designated for use only in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals

2 – Hazards Identification WHMIS 2015/GHS Classification: Flammable Aerosol Category 1 Gas Under Pressure: Compressed Gas Aspiration Toxicity Category 1 Specific Target Organ Toxicity Single Exposure Category 3 (nervous system effects) Note: This product is a consumer product and is labeled in accordance with the Consumer Chemicals and Containers Regulations (CCCR) which take precedence over WHMIS 2015 labeling. The actual container label will not include the label elements below. The labeling below applies to industrial/professional products. Label Elements: DANGER! Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Avoid breathing mist or vapors. Use only outdoors or in a well-ventilated area. Response IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you fell unwell. Storage Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Store in a well-ventilated place. Disposal

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Dispose of contents and container in accordance with local and national regulations. 3 - Composition/Information on Ingredients

Ingredient CAS # Weight Percent WHMIS 2015/ GHS Classification Aliphatic Hydrocarbon 64742-47-8 50-70% Flammable Liquid Category 3

Aspiration Toxicity Category 1 Specific Target Organ Toxicity Single Exposure Category 3

(nervous system effects) Petroleum Base Oil 64742-56-9

64742-65-0 64742-53-6 64742-54-7 64742-71-8

30-35% Not Hazardous

Carbon Dioxide 124-38-9 2-3% Simple Asphyxiant 4 – First Aid Measures Ingestion (Swallowed): Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40 Safety Hotline at 1-888-324-7596 immediately. Eye Contact: Flush thoroughly with water. Remove contact lenses if present after the first 5 minutes and continue flushing for several more minutes. Get medical attention if irritation persists. Skin Contact: Wash with soap and water. If irritation develops and persists, get medical attention. Inhalation (Breathing): If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms develop and persist. Signs and Symptoms of Exposure: Harmful or fatal is swallowed. If swallowed, may be aspirated and cause lung damage. May cause eye irritation. Inhalation of mists or vapors may cause nasal and respiratory tract irritation and central nervous system effects such as headache, dizziness and nausea. Skin contact may cause drying of the skin. Indication of Immediate Medical Attention/Special Treatment Needed: Immediate medical attention is needed for ingestion. 5 – Fire Fighting Measures Suitable (and unsuitable) Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. Specific Hazards Arising from the Chemical: Contents under pressure. Keep away from ignition sources and open flames. Exposure of containers to extreme heat and flames can cause them to rupture often with violent force. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. Combustion will produce oxides of carbon and hydrocarbons. Special Protective Equipment and Precautions for Fire-Fighters: Firefighters should always wear positive pressure self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use shielding to protect against bursting containers. 6 – Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and ventilate area. Methods and Materials for Containment/Cleanup: Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required. 7 – Handling and Storage Precautions for Safe Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use only with adequate ventilation. Keep away from heat, sparks, pilot lights, hot surfaces and open flames. Unplug electrical tools, motors and appliances before spraying or bringing the can near any source of electricity. Electricity can burn a hole in the can and cause contents to burst into flames. To avoid

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serious burn injury, do not let the can touch battery terminals, electrical connections on motors or appliances or any other source of electricity. Wash thoroughly with soap and water after handling. Keep containers closed when not in use. Keep out of the reach of children. Do not puncture, crush or incinerate containers, even when empty. Conditions for Safe Storage: Store in a cool, well-ventilated area, away from incompatible materials Do not store above 120F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. Store away from oxidizers. 8 – Exposure Controls/Personal Protection Chemical Occupational Exposure limits Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended) Petroleum Base Oil 5 mg/m3 TWA (Inhalable) ACGIH TLV (as mineral oil)

5 mg/m3 TWA, 10 mg/m3 STEL Canada- Québec (as oil mist, mineral) 5 mg/m3 TWA, 10 mg/m3 STEL Canada- Ontario (as oil mist, mineral) 1 mg/m3 TWA British Columbia (as Oil mist-mineral, severely refined)

Carbon Dioxide 5000 ppm TWA, 30000 ppm STEL ACGIH TLV 5000 ppm TWA, 30000 ppm STEL Canada- Ontario 5000 ppm TWA, 30000 ppm STEL Canada- Québec 5000 ppm TWA. 15000 ppm STEL British Columbia

The Following Controls are Recommended for Normal Consumer Use of this Product Appropriate Engineering Controls: Use in a well-ventilated area. Personal Protection: Eye Protection: Avoid eye contact. Always spray away from your face. Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where skin contact is likely. Respiratory Protection: None needed for normal use with adequate ventilation. For Bulk Processing or Workplace Use the Following Controls are Recommended Appropriate Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels below that occupational exposure limits. Personal Protection: Eye Protection: Safety goggles recommended where eye contact is possible. Skin Protection: Wear chemical resistant gloves. Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded, wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant type, form and concentration. Follow applicable regulations and good Industrial Hygiene practice. Work/Hygiene Practices: Wash with soap and water after handling. 9 – Physical and Chemical Properties Appearance: Light amber liquid Flammable Limits:

(Solvent Portion) LEL: 0.6% UEL: 8%

Odor: Mild petroleum odor Vapor Pressure: 95-115 PSI @ 70F Odor Threshold: Not established Vapor Density: Greater than 1 (air=1) pH: Not Applicable Relative Density: 0.8 – 0.82 @ 60F Melting/Freezing Point: Not established Solubilities: Insoluble in water Boiling Point/Range: 361 - 369F (183 -

187°C) Partition Coefficient; n-octanol/water:

Not established

Flash Point: 122F (49°C) Tag Open Cup (liquid)

Autoignition Temperature:

Not established

Evaporation Rate: Not established Decomposition Temperature:

Not established

Flammability (solid, gas): Flammable Aerosol Viscosity: 2.79-2.96 cSt @ 100F VOC: 65% Pour Point: -63C (-81.4F ) ASTM

D-97

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10 – Stability and Reactivity Reactivity: Not reactive under normal conditions Chemical Stability: Stable Possibility of Hazardous Reactions: May react with strong oxidizers generating heat. Conditions to Avoid: Avoid heat, sparks, flames and other sources of ignition. Do not puncture or incinerate containers. Incompatible Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. 11 – Toxicological Information Symptoms of Overexposure: Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as headache, dizziness and nausea. Intentional abuse may be harmful or fatal. Skin Contact: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis. Eye Contact: Contact may be irritating to eyes. May cause redness and tearing. Ingestion: This product has low oral toxicity. Swallowing may cause gastrointestinal irritation, nausea, vomiting and diarrhea. This product is an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis, severe lung damage and death. Chronic Effects: None expected. Carcinogen Status: None of the components are listed as a carcinogen or suspect carcinogen by IARC, NTP, ACGIH or OSHA. Reproductive Toxicity: None of the components is considered a reproductive hazard. Numerical Measures of Toxicity: Acute Toxicity Estimates: Oral > 5,000 mg/kg; Dermal >2,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. 12 – Ecological Information Ecotoxicity: No specific aquatic toxicity data is currently available; however components of this product are not expected to be harmful to aquatic organisms Persistence and Degradability: Components are readily biodegradable. Bioaccumulative Potential: Bioaccumulation is not expected based on an assessment of the ingredients. Mobility in Soil: No data available Other Adverse Effects: None known 13 - Disposal Considerations Aerosol containers should not be punctured, compacted in home trash compactors or incinerated. Empty containers may be disposed of through normal waste management options. Dispose of all waste product, absorbents, and other materials in accordance with applicable Federal, state and local regulations. 14 – Transportation Information DOT Surface Shipping Description: UN1950, Aerosols, 2.1 Ltd. Qty (Note: Shipping Papers are not required for Limited Quantities unless transported by air or vessel – each package must be marked with the Limited Quantity Mark) Canadian TDG Classification: Limited Quantity IMDG Shipping Description: Un1950, Aerosols, 2.1, LTD QTY ICAO Shipping Description: UN1950, Aerosols, flammable, 2.1 NOTE: WD-40 Company does not test aerosol cans to assure that they meet the pressure and other requirements for transport by air. We do not recommend that our aerosol products be transported by air.

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15 – Regulatory Information

National Pollutant Release Inventory (NPRI): This product contains the following chemicals that are listed on the NPRI Substance List: Aliphatic Hydrocarbon (64742-47-8) 50-70% Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian Domestic Substances List or exempt from notification.

16 – Other Information HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Physical Hazard – 0 (minimal hazard) Revision Date: November 15, 2016 Supersedes: March 27, 2014 Prepared by: Industrial Health & Safety Consultants, Inc. Shelton, CT, USA Reviewed by: I. Kowalski Regulatory Affairs Dept. 1014100/No.0084103

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