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April 28,2009

Jessica OIlnstead Arizona Dept. of Env. Quality 1 11 0 W. Washington St. MC5000 Phoenix, AZ 85007

RE: Felton Kjag

Work Order No.: 09040 166

Dear Jessica,

Columbia AnaIyticaI Services, Inc. received 9 samples on 4/09/09. The results of the analyses are presented in 111e following report.

The Case Narrative of tliis report addresses any Quality Control and/or Quality Assuraiice issues associated with this Work Order.

Analyses were performed according lo our Iabordtory's KELAP-approved quality assurance program. The test results meet requirements of the current NBLAP standards, where applicahIe, and except as noted in the laboratoiy case narrative provided. For a specific list of NELAP- accredited a~ialytes, refer lo tlie certifications section at www.casfab.com.

If you have any rluestiolls regarding tliese test results, please feel free to call us at (602) 437- 0330.

Sinccrel y,

r/lhd.e- tc,dp- MarceIa Hodge Project Manager

ADHS License No. AZ0 1 33/AZ0667/AZM133

. . . . . . , .., . .. , - .~ < ' A , , , . . . "

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SDMS DOCID# 1117668

I

&alum bia Analytical Senrices-

Client: Arizona Department ofEnvirornenta1 Qualj

Work Order: 09040 I 66 Project Name: Felton Icing

Date Printed: 28-Apr-09

Case Narrative

Project Number: n

Samples were received intact and within proper temperature criteria.

Results are reported 011 a wet weight basis unless dry-cossection is denoted in the units iicld on the analytical report ("mgtkg-dry").

All method blanks, laboratory spikes, andlor matrix spikes met quality control objectives for the parameters associated with this Work Order except as detailed below or on the Data Qualifier page of this report. Data QualiIiess used in tliis report are in accordailce with ADEQ Arizona Data Qualifiers, Revision 3.0 9/20/2007.

Data qualifiers ("flags") contailled within this analytical report have been issued to explain a quality control deficiency, and do not affect the quality (validity) of the data unless noted otherwise in the case narrative.

C O ~ U ~ bia Datc Printed 27-Apr-09

Analytical S E W ~ C ~ S - License NO. AZO 1 33/AZM 133

CLIENT: Arizona Department of Environme~~tal Quali

Project Name: Felton Icing

Proj ecl Nomber:

Case Narrative Data Qualifiers

Worlc Order: 09040166 Ilate Receivcd: 09-Apr-09

One or more of the following data qualifiers inay be associated with yoirr analytical and/or quality control data.

D I Sample required dilution due to matrix.

D2 Sample required dilutioil due to high concentration of target analytc.

E2 Concentration estimated. Analyte exceeded calibration range. Reailalysis not performed due to sample matrix.

H3 Sample was received and analyzed past llolding time.

115 '1-11is test is specified to be performed in the field within IS minutes of sampling; sainpte was received and analyzed past the regulatory holding time.

M 1 Matrix spike recovery was high, the associated blank spilce recovery was acceptable.

h4 2 Matrix spike recovery was low, thc associated blank spike recovery was acccptabie.

M 3 The spike recovery valite is unusable since the analyte concentration in the sa t~~ple is disproportionate to spilce level. 'I'he associated blank spike recovely was acceptable.

M 4 The analysis of dte spiked sa~llple required a dilution such that the spilce recovery catculation does not provide irseful information. Tile assoc~atcd blanlc spilce recovery was acceptable.

C&.8ium bia Date Printed 27-Apr-09

Anafytical Se~ims- License NO. AZO I WAZM I 33

CLIENT: Arizona Depart~nent ofEnvironmenta1 Quali Project Name: Felton King Work Order Sample Summary Project Nurnber: Worfc Order: 09040166

Client S-ample 11) Lab Sample ID Test Code

NlA

SW1311/6010R

SW6010R

SW7471.4

SW9045D

N/ A

SW1311/60lOB

SWGOIOB

SW747 I A

SW9045D

N/A

SWG010B

SW7473A

SW9045D

sw6olon

SW9040C

N/A

SW6010B

SW747 1A

SW9045D

N/A

SW1311/6010B

SWG010B

SW7471A

S W904.5 D

N/A

SWGOIOB

SW747 I A

SW90 1 OC/9014

ColIection Date

4/09/09 09: I0 AM

4/09/09 09: 10 AM

4/09/09 09: 10 AM

4/09/09 09: 10 AM

4/09/09 09: 10 AM

4/09/09 09.10 AM

4/09/09 09: 10 AM

4/09/09 09: 10 AM

4/09/09 09: 10 A M

4/09/09 09: 10 AM

4/09/09 09: 1 2 AM

4/09/09 09: 12 AM 4/09/09 09: 12 AM

4/09/09 09.12 AM 4/09/09 1020 A M

4/09/09 1 050 AM

4/09/09 09:25 AM

4/09/09 09:25 A M

4/09/09 09:25 AM

4/09/09 0925 AM

4/09/09 0950 AM

4/09/09 09:30 AM

4/09/09 09:30 A M

4/09/09 09 30 AM

4/09/09 09.30 AM

4/09/09 09:45 AM

4/09/09 09:45 AM

4/09/09 09.45 AM

4/09/09 09:45 AM 4/09/09 09:45 AM

4/09/09 10:45 AM

4109109 10:45 AM

4/09/09 10:45 AM

4/09/09 10:45 AM

Date Received

4/09/09 1230 PM 4/09/09 12:30 PM

4/09/09 12.30 PM

4/09/09 12.30 PM 4/09/09 12:30 PM

4/09/09 1230 PM

4/09/09 1230 PM

4/09/09 12:30 PM

4/09/09 12:30 PM

4/09/09 1230 PM 4/09/09 1230 PM

4/09/09 1230 PM

4/09/09 12:30 PM

4/09/09 1230 PM

4/09/09 12:30 PM 4/09/09 1230 PM 4/09/09 1255 PM

4/09/00 1230 PM 4/09/09 12:30 PM

4/09/09 12:30 I'M

4/09/09 12:30 PM

4/09/09 12.30 PM 4/09/09 1250 PM

4/09/09 1230 PM 4/09/09 1250 PM

4/09/09 12.30 PM

4/09/09 12:30 PM

4/09/09 12:30 PM

4/09/09 1220 I'M

4/09/09 12.30 PM

4/09/09 1230 PM

4/09/09 12:30 PM

4/09/09 12:30 PM

4/09/09 12:30 PM

CLIENT: Arizor~a Deparlrnent of Enviro~lmcntal Quali

Project Name: Fehon King Work Order Sample Summary Project Number: Worlc Order: 090401 66

Client Sample ID Lab Sample ID Test Code Collection Date Date Received

P-04-A 09040 166-09A NiA 4i09/0910:1OAM 4/09/0912:30PM

SW1311/6010B 4/09/09 10: 10 AM 4/09/09 1230 PM SWGOIOB 4/09/09 10: 10 AM 4/09/09 12:30 PM SW7471A 4/09/09 10: 10 AM 4/09/09 12:30 PM

SW904SD 4/09/09 10: 10 AM 4/09/09 1230 PM

Columbia Analytical Senrices-

Date Printed 27-Apr-09

Licensc No. AZO133/AZM 133

CLIENT: Arizona Department of Environmental Quali

Project Name: Felton King Project Number: WOI-li Order: 09040 166

Definitions

Dstc Received: 09-Apr-09

Analytical Spike (AS) The AS is a Icnown alnount ofa target analytcadded to a sampleafter it has been distilled, digested, or extracted and is ready for analysis. Tile AS is genesally pcrfor~med it-the MS has failed. It is used lo indicate i~iterfweice that arises Eom sample distil$~tion, digestion, or extraction as opposed to interference that is iniiatc to the matrix.

Confir? uing Curve - The CCV is also rcferred to as a curve check. 'I'liis is a standard analyzed at specified / Verificalion (CCV) intervals during an analysis. The CCV veri ii es the stability and accuracy of the

calibration curve. There are specific CCV lecovery acceptance criteria for each nlethod.

Dilution Factor (DF) The DF is an indication o f h o ~ r much a sample had to be diluted in order to quantitate it on a standard curve. The DF is iudicatcd in the reported sample result. Tlie sample PQL increases as tile dilution increases.

Internal Standard (IS) The IS is a cotnpound that is siinilar to the organic co~npound of interest in terms)of chemical co~nposition but is unique in that it is rare in the environment. The sarile concel~t lati 011 of IS is added lo every sa~nptc for some organic methods.

Laboratory Control 'The LACS is also referred to as a blanlc spike. The LCS is an addition of a known a~noi~nt S~nipl e (1,CS) of a target analyie(from the same source as calibratioii statldards or spiltes) to an aliquot

of deionized water or other appropriate clean matrix. The LCS is processed through the entire method procedure in the same manner as samples.

Matrix Spilcc (IMS) Tile MS is ti lcnown amount of a target analyte added to a sample. The MS is processed through the entire method procedi~rc in tlie same nianncr as saniples.

Method Blank (MU) The MB is an aliquot of deionized water or other appropriate clean matrix that is thought to be fice ofthe analyte in question. The MB is processed tllrougli tlie entire ex<racfion or analysis procedure and is used to indicate contamination in tlie lab.

Method Detec~ion The MDL is the lowest level of detecfion ofwhich a 111ct11od is capable. Limit (MDL)

I'racticai Q~~antitation Thc PQL is the Iowcst value at which Colu~nbia Analytical Services can delect an Limit (PQL) a1121lyte in niatrix with a high degree of confidence. 'The PQI, will increase as the DF

increases. The PQL is greatel. than or equal to the MDL.

Relative Percent The RPD is a measute orprecision (the ability to obtain the same result on re-analysis of Differcnce (RPD) the same saniple). It is calculated using the result of a sa~iiple, MS, 1,CS, or LCSV and

its associated duylicatc result.

Seco~idary Source QC Sample (1,CSV)

Sunogate

Trip l3 lank (7'R)

The LCSV is also referred to as a second source laboratory control san?plc. It is the same type of standard as a calibration or spiking standard but is obtained fiom a different source. Tile LCSV is an indication oftlie primary standard quality, nietllod performance, and instrument perfo rrnance.

A si~rrogate cotnpou nd is simi lar to the organic compound of interest in telliis or cl~emical con~position but is unique in that it is rarc in the environnlent. When surrogates are used, they are addcd to every sample, blank and standard. Surrogate lecovety is used as an indication of extraction atldlor analytical success.

The TB is a portion ofdeionized water preserved in the same nianncr as the samples. The T B travels fi-om the lab. to tile field, and then back to the lab with the samples from thc field. Tile TB serves as an indication of containination introduced during sai-nple transportation.

Columbia Analytical Services-

Date Printed: 27-Apr-09

License No. AZ0133/AZM 133 - CLIENT: Arizona Depart~nent of Environ~nental Quality Project Name: Felton King

Project Number: References

Work Order: 090401 66 Date Rcceivect: 09-Apr-09

Colu~nbia Analytical Services, Inc. uses the n~cthods outlined in the following references:

Code of Federal Regulations, 40CFR, Part 136, Appendix A, J~rly 2005.

Standard Methods l'or the Exatnination of Water and Wastewater, 20th Edition, 1998.

Methds for Chetnical Analysis of Water a11d Wastes, EPA-600/4-79-020, Revised March 1983.

Methods for tlie Determination of Inorganic Substances i11 Environniental Sarnples, EPAIGOOIR-93/ 100, Revised August 1993.

Methods for llie Deterniination of Metals in Environmental Sanlplcs, Supplement 1 : EPA/6OO/R-94/1 I I , Revised May 1 994.

Mett~ods Tor the Determination of Organic Cornpo~~nds in Drinlclng Water, EPhfG00/4-881039, Revised July, 1991 ; EPA- 60014-90/020, Siipplcn~etrt 1, July 1990; 13PA-GOO/R-92/1 29; Supl~lelnent 11, August 1992; EPA-600/R-951131, Supplement 111, 1.2ugust 1995.

Hach, Water Analysis I.Iandbook, 3rd Edition, 1997.

Test Methods fbr Evaluating Solid Waste, Physical/Chemica1 Metl~ods, SW846, 3rd !?&tion, 1986 including Update I, July IcN2; Update IIA, August 1993; Update 11; Septenlber 1994; Update HB, January 1995; Updatc Iii, Deccinber 1996. Update IIIA, Jnnc 1999; and Update 11113 July 2005.

I3ureau of Services, Statc of Arizona Department oFHealth Services &/lethod 801 SAZ.RI, September 1998. (Comtnent: CG-C10 GRO reported by this method is not to Ix used in coinpliance situations)

AS'I'M Met11odD4982, Annual Rool< ofASTM Standards, Volu~nes 11.01 aiid 1 1.02, 1995

'l 'heDeter~~~ination of Polychlorinated Biphenyls in 'l'ral~sfornier Fluid and Waste Oils, EPA-GOO 4-81-045, September 1982.

GIJA Methoct 901 3A, Cyanide Extraction Procedure for Solids and Oils. (Rev, I Xovemkr 200.1)

EPA Method 5035A, Closed-Systen~ Purge-and-Tiap and Extraction for Volatile Organics in Soil and Waste Saniples (draft rev. 1 July 2002)

EPA Mcthod 5030C, Purge-and-Trap for Aqueous Samples (1-ev.3 May 2003) -

Office of Ground Water and Drinking Water Technical Support Center; EPA 8 15-R-05-004, Manual for Certification of Drinlting Water., (5Ih Edition January 2005)

I o f l

Columbia Analflical S ~ W ~ C ~ F Date Printed 27-~pr-09

Lieerlse No. A20 133/AZM 133

CLIENT: ~ ~ b o n a Department of Enviromnental Quali Client Sample ID: FICC-01-A

Work Order: 09040 166 ColIection Date: 4/9/2009 9: 10:OO AM

Lab ID: 090401 66-0 I Matrix: Solid

Project Name: Fellon King Project Nuinber:

Test Date Date Analyte Result PQL Qua1 Units DF Code Prepared Analyzed Analyst Batch 1D

PREP METHOD: SW9045 Test Performed By: AZ0.133

PH 8.7 NIA H3 1 .O SbIJ9045D NIA 6114109 RI-I PH-S-4/14/2009 Temperature "C. 22.0 NIA 1,O SW9045D NIA 4/14/09 RY PI?-S-4114!2009

PREP METHOD: SW3OZOA Tesf Petformed By: A20133

Chromium 400 5.0 D l rnglt 5 0 SW~3111601OB 4/15/09 7 23 4117109 10 02 MDD 2978

PREP METHOD: SW30506 Ted Performed By: AZO133

Arsenic '

Barium

Cadmium Chromium Lead Selenium

Silver

Mercury

PREP METHOD: SW7471A

MOD 2979

MDD 2979 MDD 2979 MDD 2979

MDD 2979 MDD 2979 MOD 2979

Test Perionned By: AZ0133

BJL 2969

1 of9 Confide~~lirl and Privileged

Caium bia Analytical Senrices- Date Printed 27-Apr-09

License No. AZ0133JAZM 133

CLIENT: Arizona Dcparlinent of Environmetltal Quali Client Sample ID: FKC-02-A Work Order: 09040166 Collection Date: 4/9/2009 9: 10:00 AM + "r

Lab ID: 09040 166-02 Matrix: Solid Project Name: Felton Icing

Project Number:

Test Date Date Analyte Result PQL Qua1 Units DF Code Prepared A~~alyzed Analyst Batch ID

PREP METHOD: SW9045 Test Perfwmed By: A20133

pH 1 9.7 NIA ti3 I 0 SW9M6D NIA 4114109 RH PH_S-4!14I2009

Temperature "C. 21.5 NIA 1.0 SW9045D N A 4114109 RH PH-S-411412009

Cadmium

Arsenic

Barium Cadmium Chromium Lead Selenium Silve:

Mercu ty

PREP IdETHOD: ~ ~ 3 0 1 0 ~ Test Performed By: AZOf33

1200 2 5 D2 mglL 5.0 SW1317i6010B 4115109 7 23 4!17109 i0:06 MDD 2978

PREP METHOD: SW30505 Test Performed By: AZ0133

4123309 12 30 MDD 2979

4121108 '5 23 MDD 2979

41'23109 12:30 M D D 2979

4121109 1923 MDO 2979

4121109 1523 MDD 2979

4Rlfi9 1523 MDD 2979

4121109 15 23 MDD 2979

PREP METHOD. SW7471A Test Performed By: A20133

0.099 0.083 mglKg 1.0 SW7471A 41131396 54 4121109 16'57 BJL 2969

Columbia Analytical Services- Date Printed 27-Apr-09

License No. AZ0133iAZMI 33

CLIENT: Arizona Departme~~t of E~~vil-onmcntal Quali Client Sarnple ID: FKC-03-A

Worlc Order: 09040166 Collection Date: 4/9/2009 9: 12:OO AM Lab 11): 09040 166-03 Matrix: Solid Project Name: Felton King P~~ojcct Number:

Test Date Date Analyte Result PQL, Qua1 U~zils DF Code Prepared Analyzed Analyst Batch ID

PREP METHOD: SW9045 Test Performed By: AZ0133

pH Temperature "C.

Arsenlc Bar~um

Cadmium Chromium Lead Selen~urn Silver

NIA H3 NIA -

PREP METHOD: SW3050B

500 D l mglKg

50 D l mglKg 100 D2 mglKg

50 D2 mgKg 50 D1 mgli(g

50 D l mg/Kg

50 D l mglKg

NIA

NIA

Test Performed By: AZOf33

MDD 2979

MDD 2979

MDD 2979

MDD 2979

MDD 2979

MDD 2979

MDD 2979

PREP METHOD: SW747fA Test Performed By: A20133

Mercury (0.083 0.083 pg;Kg 1.0 SN7471A 41:31C9 6 54 4/21/09 iE58 BJL 2969

Date Yrintcd 27-Apr-09

License No. AZ0 1 33/AZM 133

CLIENT: Arizona Department of Environnlel~tal Qi~ali Client Sample ID: FICC-04-A

Wor-I< Order: 09040 166 Collection Date: 4/9/2009 10:30:00 AM Lab ID: 09040 166-04 Matrix: Liquid Project Name: Felton King Project Numbcr:

Test Dale Date Analyte Result PQI, Qua1 Units DF Code Prepared Analyzed Analyst Ratcli ID

PREP METHOD: NONE Test Performed By: AZ0133

PH 0.2 NIA H5, E2 1.0 SW9040C NIA 4/14/09 RH PH-WASTE-4/14/2009

Temperature "C, 22.0 NIA 1.0 SW9040C NIA 4114109 RH PH-WASTE-411412009

PREP METHOD: SW3050B Test Performed By: AZ0133

Chromium 1~0000 100 D2 mglKg 100 SWGDIOB 4/22/09 9 39 4123109 15 36 MDD 3044

4 of9 Conlidential a ~ t d Privileged

P

Columbia AnaEytical Se~ims- Date Printed 27-Apr-09

License No. AZO 1331AZM 133

CLIENT: Arizona Department of Envirotii~~ental Quali Client Sample ID: P-01 -A Work Order: 09040166 Collection Date: 4/9/2009 9:25:00 AM Lab If): 09040 166-05 Matrix: Solid Project Name: Felton King Project Number:

Test Date Date Analyte Res~ili PQL Qua1 Units DF Code Prepared Analyzed Analyst Batci~ lD

PREP METHOD: SW9045 T e s f P er fo rmed By: AZOZ33

PH 6.f Temperature "C. 22.5

Arsenic 4 0 0

Barium 75 Cadmium 51000 Chromium 38000 Lead 1200 Selenium 6 0 S~lver 4 0

NIA H3 1.0 NIA 1,O

PREP METHOD: SW3050B

Nlli

NIA

Test Performed By: ,420133

MDD 2979

MUD 2579

lVlDD 2979

ivlDD 2979

MDD 2979

MDD 2979

MDD 2979

PREP METHOD: SW747iA Test Performed By' A20133

Mercury ~0.083 0083 mgKg 1.0 SW7471A 41~31096 54 4/21/09 1703 BJL 2969

Columbia Anafvical SenricesaNc Date Printed 27-Apr-09

License No. AZO 133/AZM 133

CI,IENT: Arizo~la Department of E~lviroi~rnet>tal Quali Client Sample ID: P-02-A

Worlc Ordcr: 09040 I66 Collection Date: 4/9/2009 9:30:00 AM Lab ill: 09040 166-06 Matrix: Solid

Project Narne: Felton King Projcct Number:

Test Date Date Ailalyle Result PQL Qual Units DDF Code Preparcd Analyzed Analyst Batch 11)

PREP METHOD: SW9045 Test PerformodBy: A20133

PH 7.5 NIA H3 1 0 SW9045D NIA 411 4109 RH PH-S-411412009 Temperature "C. 22.0 NIA 1 0 SW3045D YIA 41!4/09 RH PH-S-41i412C09

PREP METHOD: SW3OIOA Test Performed By: A20133

Chromium

Arsenic Barium

Cadmium Chromium lead Seleliium Siiver

Mercury

980 5.0 D l mg/l. 5.0 SW1311I6010B 4115109 7 23 4i17M9 1011 MDD 2478

PREP METHOD: SW30XIB Test Performed By: A20133

~ 5 0 0 500 D l mg/Kg 100 SW60100 4115/09 8 2: 41231C9 42 58 MDD 2973

<50 50 D 1 mglKg 10 SWGOlOB MY09 821 4/21/09 15.53 MDD 2979

47000 130 D 2 mg/Kg 100 SWGO?CB 41:5/09 821 4/23/09 1258 MDD 2979

63000 50 D2 mg/Kg 10 SWGOlOB 4/15/09 8.21 4121109 15.53 MDD 2979

400 50 D j mglKg 10 SWGOIOB 415i09 8:21 4121109!5 53 M D D 2979

<50 50 D l mglKg 10 SW60106 dl15109 8.21 412109 15 53 MDD 2979

<50 50 Dl mg/Kg 10 SW60106 4115109 8 27 4/21/09 15 53 M D D 2973

PREP METHOD: SW747iA Test Performed By. A20133

0.12 0.083 mg/Kg 1 0 SLN7471A 4113109 6 54 4/21/09 17 04 BJL 2969

Cof urn bia Analvical Services>- Ilate Printed 27-Apr-09

License No. AZO 1 33/AZM 133

CLIENT: Arizona Department of Envirownental Quali Client Sample ID: P-03-A Work Ordcr: 09040166 Collection Date: 4/9/2009 9:45:00 AM

Lab ID: 09040 166-07 Matrix: Solid

Project Name: Felton Icing Project Number:

Test Date Date Analyte Result PQL Qua1 Uliits DF Code Prepared Analyzed Al~alyst Batch ID

PREP METHOD: SW9010C Tesf Performed By: AZM33

Cyanide, Total 880 80 02 m g i ~ g 200 SW90lx19014 4122109 14 05 4/22/09 ?A 3045

PREP METHOD: SW9045 Test Performed By: A20133

- PH 7.3 KIA H3 - 1.0 SW9045D NIA 411 4/03 RH PH.2-4H412009

Temperature "C. 22.0 NIA ? o ~ ~ 9 0 4 5 ~ MA 4~4109 RH P~!-S-~/I~I~OO~

PREP METHOD: SW30508 Test Performed By: A20133

Arsen~c Barium Cadmium Chromium Lead Selenum

Silver

Mercury

500 D l " w g

50 01 mglKg 'I00 D2 mglKg 50 D l mglKg

50 D l mdK9

50 01 mglKg

50 D l mglKg

PREP METHOD: SW7471A

MDD 2979

MOD 2979

MOD 2979

MDD 2979

MDD 2979

MDD 2879

MDD 2979

Test Periormed By: AZ0133

BJL 2969

7 9 f 9 Confidential aod Privileged

Caiumbia Analytical Services- Datc Printed 27-hpr-09

License No. AZOI 33IAZM 133

CLIENT: Arizol~a Depai-tment of Environmental Quali Client Sample ID: P-05-A Work Order: 09040 166 Collection Date: 4/9/2009 10:45:00 AM Lab Ti): 09040 1 66-08 Matrix: Sludge Project Narne: Felton IGng Project Number:

Test Date Date Analyte Result PQL Qua1 Units DF )Code Prepared Analyzed A~~alyst Batch ID

PREP METHOD: SW9045 Test Performed By: AZ0133

PH 13.5 NIA H3, €2 1.0 S'N9045D NIA 4114E9 RH PH-S-411412009

Temperature "C. 22.0 NIA 1.0 Sfl$040460 NIA 41141G9 RH PH-S-4/14/2009

PREP METHOD: SW3050B Test Performed By: AZ0133

Arsenic

Barium

Cadmium Chromium Lead Selenium

Silver

4 0 0 500 D l mglKg 100 SW60100 4115109 821 4:23/09 13 06 MDD 2979

4 0 50 0 1 mglKg 10 SW6010B 4115109 8 21 4121109 1601 MDD 2979

6600 $00 D2 mgiKg 100 SW6OiOB 41151G9 ab21 4/23/09 i 3 06 MOD 2979

3000 50 Dl mg/Kg 10 SINGO!OB 4/151098 21 4/21/09 26 01 MDD 2979

290 50 0 1 n;glKg 20 SW60lOB 41151098.21 4121109 16.01 MDD 5979

(50 50 D l mglKg 10 SW6O!OB 4115109 8 21 4121/09 16 0: MDD 2979

c50 50 D l mglKg I 0 S1N6010B 4/15/09 8 21 4121109 16 01 MDD 2979

PREP METHOD: SW7471A Test Performed By: AZ0133

Mercury ~ 0 0 8 3 0.083

Columbia Anarytical Senricesu Datc Printed 27-Apr-09

License No. AZO 133lAZM 133

CLIENT: Arizona Department of Environ~nental Quali Client Sample 111: P-04-A

Worlc Order: 09040 166 Collectior~ Date: 4/9/2009 10: 10:OO AM Lab ID: 09040 166-09 Matrix: Solid

Project Narne: Felton King Project Numbcr:

Test Date Date A~lafyte Result PQL, Qua1 Units DF Code Prepared Analy7ed At~alyst Ratch ID

PREP METHOD: SW9045 Test Performed By: A20133

pH 20.1 NIA H3 I 0 S ~ N ~ ~ E NIA 4114109 RH ~~-~.41:4i2009 Temperature "C. 22.5 NIA - 2.0 SW9045D NIA 4/14/09 RH PH-S414Q009

PREP METHOD: SW3010A Test Performed By: AZ0133

Chromium 8400 5.0 D I mg1L 5.0 SvV1311/50108 4/151(M 7 23 4117109 10.15 MDD 2978

PREP METHOD: SW30SOB Test Performed By: AZOi33

Arsenic

Barium

Cadmium Chromium Lead Selen~urn Silver

PREP METHOD: SW47 lA

100 swsoloe 4/15/09 8:2t 4/23/09 13:1o MDD 2979

10 SW6C10B 4115109 8:21 4121109 16:05 MDD 2379

103 SWGOIOB 4/151098:21 4123109 13:13 MDD 2979

10 SW6010B 41151098:23 4121109 16:05 MDD 2979

10 SW601OB 4115109 8:21 4121109 16305 MDD 2979

10 SW60108 4/15/09 8:2? 4121109 16:05 MDD 2979

10 SW60108 4M5109 8:21 4121109 1605 MOD 2979

Test Performed By: A20133

Mercury (0,083 0 083 rnglKg 1.0 SW7471A 4/13/09 6 54 4121109 17 10 @.JL 2969

9 of9

Confidential and Privilrgcd

cslum bia Date: 27-A~POF)

Analytical Sewices License NO. ~ ~ 0 1 3 3 1 ~ ~ ~ 1 3 3

CLIENT: Airzona Depai-tinent of Enviro~llnental Quali

Worlc 01-der: 09040 I66 QC SUMMARY REPORT Projcct: Felton Icing Method Blailk

Test Date Date Analyte Result PQI, Qua1 Units DF Code Prepared Analyzed Analyst Batch ID

Cyanide, Total co 40 0 40 mglKg 1 SW9010C19014 4122109 14:OS 4122109 TA 3045

Cadmium

Chromium

'Arsenic Cadmium

Barium Chromium Lead

Selenium Silver

Chromium 4 .o 1 .o mgNg 1 S\NMilOB 4/22/99 9 39 M23109 15:24 MDD 3044

412fi09 ?61 BJL 2969

Csf umbia Analytical Senrices-

Date: 27-Apr-09

Liccnse No. AZO l33IAZMl33

CLIENT: Arizona Llepartinent of Environ~neiltal Quali Work Order: 090401 66 QC SUMMARY REPORT Project: Felton King Ssllnpie Duplicate

RPD % RPD Test Date Date Analyte Result PQL Units Ref Val IiPD i n Code Prepared Analyzed Analyst Qua1 - - Sample ID: 09040033-01A-D Batch ID: 1'1~WAS'l'E-4/14/200(,

Clllenl ID.

Temperature "C 22.0 NIA -- 23.0 4% 0 s'~4804Oc N/A 4/14h?g RH

PH 3 92 NIA -- 4 29 9% 20 sw9045c MM 111 4109 RH

Sample IT): 09040099-01A-D Batch JD: PI+-S-4/14/2009

Client ID:

PH -- 7.35 MIA -- 7.36 0% 20 SWSC45D NIA 41141G9 RH

Sruuplc ID: 09040166-03A-1) Batch ID: PH-S-4/14/2009

(:lien1 lD: ]:KC-03-A

FH 6 58 NIA - 6.53 1% 20 sw99459 NIA 4/14/09 RH

Columbia Date: 2 7 - ~ p r - 0 9

Analytical S ~ W ~ C ~ S ~ ( ~ License NO. AZO I ~ ? / A % M I ~ ~

CLIENT: Arizona Depar tmet~t of Environmental Quali W o r k Order: 09040366

Projec t : Felton King Sample Matrix Spike

SPIC SPK % Low High RPD % RPD hna ly t c Result PQL value Iief Val Rec Lirnit Limit Ref Val l i P D Limit Qua1

Snmple 11) 09040166-07A-hlS 13arch 113 3045 rest C:o(ie: SM790 10C/90 14 Date Analyzed. 04/22/09 00 00

Client Ill) 1'-03-A Units: mdKg Date Prepared. 4/22/09 14 05

80 50.0 880 200% 85 115 -- -- - - - -- - - .- -- - -- .- .- - --- " . -. - - -

M1,M4 - . -

Sanlple LD: 09040166-07A-YISD Batch ID. '3045 Test Code: SW9010C/3014 Iktc Analyzed 04/22/09 00 00

Cl~cnl ID: P-03-A tji~ils: III@<& Date P~'el)i~rcd 4/22/09 14 05

880 260°io 85 115 -.--- - - - - - . . .. - - - 980 3% .- -- - . - - 23 M l , M 4 .- - -

Test Code SW131116010B Date Analyzed: 04/17/09 10 40

Cllcnt If) Uii~ts; mgl- Date Prepared 411 5/09 7 20

Cadm~um 103% 75 (25 112% 75 125 - - -- . --- - - - . - . . . - ..- - - - -

Sfimplc 11). 090J0O90-02A-~lS1~ Batch I l l . 2978 Test Codc: SWl311/6010B 13atc Analyzed: 04/17/09 I0 54

Clicnt 11) IJnits. inglL Date Picpared 4/15/09 7 20

Cadm~uni 10 3 050 100 103% 75 125 10.3 0% 20 Chromium 1 1 2 1% 20

-. .- - - - - - - . -- - - - - -. --.- - -

1)atc Andlyzccl. 04/21/09 15 27

Clicnt 11) ITKC'-02-.A Unlts. m&/Kg [)ate lJrcpared' 411 5/09 8 22

Bariurn 700 50 550 532 118% 75 125 Chromium 10600 50 50 0 14300 0% 75 125 M2 Lead 1020 50 500 1260 0% 75 125 M2 Sekn~um 61 7 50 50 0 123% 75 125 Sllver

- - . - c50 50 250 0% 75 125 . - - - - - --- - . - - - . - - M2

-- -- - - -- ---- - - -- - . -- - - . .. . - -- - - Sa~nplc fD 09040116-02,\-i\.I5 Batch 1L) 2979 Test Code: SW6OlOB Dale Analyzd: 04/23/09 12 34

Client ID FKC-02-A Unlts: @Kg Date Prepared. 411 5/09 8.22

Arsen~c (500 500 50 0 0% 75 125 M2 M3

- - -- -- - - . - - , - - - . -

Ilate Antllyzcd: 04/21/09 15 32

I I [<KC'-02-4 Units: mdKg Date l'rcpared. 411 5/09 8 22

Bar~um 645 50 550 53 2 108% 75 125 700 8% 20 Chrom~um 15300 50 50 0 14300 2000% 75 125 10600 36% 20 Ml,R2 Lezd 1450 50 500 1260 440% 75 125 1020 37% 20 MI,R2 Selenium c50 50 50.0 0% 75 125 6.1.7 200% 20 M2,R2 Silver 6 0 50 25.0 0% 75 125 0 0% 20 M2

. - - - - - - --- - - - . - - -- - .- - - S,~mplc: I I > 09040166-02A-VISD Batch ID 2979 Tcsl Code. SW6010B I)alc A~lalyzed 04/23/09 12 38

Cl~en t ID. 1ii<V-O2-11 U n ~ t s , mUI<g Date Prepared. 411 5/09 8 22

Arsenic 4 0 0 500 50 0 0% 75 125 0 0% 20 M2

- 104000 - - 100 500 70100 67800% 75 125 55200 61% 20 M3,R2 - - - - . . - . . --- - -- - - - . . - -. - " ... - .-..- - - -- - - - " a < " *

C'onfidenlirl aort Privilrgcd 1 0j.2

Columbia Analytical Sentices-

Date: 27-Apr-09

License No. A201 33/AZM 133

CLIENT: Arizona Department of E~~virori~nental Quali Woric Order: 09040 166 i QC SUMMARY REPORT Project: Felt011 King Sample Matrix Spike

SPlC SPIC % t o w High RPD % RPD Analyte Result PQ14 value Ref Val Rec Limit Limit RefVal RPD Limit Qua1

Sa~nple lD. 09040166-04A-%IS Batch 11): 3044 Test Cocic: SW601013 Date Analyzetl. 04/23/09 15.40

Client In: 12KC-04-1\ [.inits: m$Kg Date Prepared: 4/22/09 939

Chromium 1 13000 - - - .- .- -..... ................-.-... . .....-. ..... ... . ... ... ......................

Datc Anolyncd. 04/23/09 11:44

C l ~ e t ~ t ID FKC-04-A \!nits' mg/I/Kg Dale PI e p a ~ cd 4/22/09 9 40

Chrom~um - - --- - 1090GO - - -- - - - - - - - - - - - 100 25 G 106000 12000% 75 125 f13000 4% 20 M3

- -- - - -. -

Sarnplc ID. 09040166-01.1-hIS Batch 1L): 2969 'Tcst Code SW747lA

f:licnt ID FIX:-01-A I'~iils' m@Kg Ilalc Preparcd 4/13/09 6 54

Mercury - - - - - -- 0 613 0.083 0.417 0 337 66% 75 125

- - - - . - - - - - - -- A - - - - - - - - -- -- - -- - - - -- - - - - - M2

Sample 11) O9040166-01A-hlSD Batch In- 2969 'l'cst Code SW747 1 A Date l\naly7,ed 04/21/09 16 55

IJnils: n1dKg Date Prepared' 4/13/09 6 54

Confidential a110 Privileged 20f2

Columbia Analytical Services-

Date: 27-Apr-09

License No. AZ0133/AZM 133

CLIENT: Arizona Department o f Environlnerltal Quali

Work Order: 09040166 QC SUMMARY REPORT

Project: Felton I< ing Blank Spilte

SPK SPIC O/o Low High RPD % RPD Anillyte Rcsult PQL value Re fVa l Rec Limit Limit RefVal RPD Limit Qua1

Samplc ID. LCS I3atcb ID: 3045 I'cst Code: SW9010C/9014 Datc Atlalyzed: 04/22/09 00 00

Units: mg/ICg Dale l'reparcd. 4/22/09 14 05

94% 85 115 - - - - .- - - -- . -. . - - - -. - . - -- -- - -

l'cst Codc. SWOOIOC/9014 I>ate Analyzcd. 04R2109 00 00

Un~ts: nlg/Kg Date Prepared 4/22/09 14 05

Cyanide, Total 8.00 94% 85 115 7 5 0% 20 - - -- - - - - - . - -- -- - -. --- - - --- -- . - - . -

Botch ID: 2978 'rest Code SW 13 1 1 I60 10B Dak Ar\a\y'~cd* 04/17/09 09 $3

Tlnits: a ~ d l . Date Prepared 4/15/09

Cadmium 10 4 0.50 10.0 104% 91 123

-- --- - -- - . .". - . . . - -

Dale Alzalyzed: 0411 7/09 09 58

U11its: iilg/ld Date Prepalcd 411 5/09

Cadm~um 10.5 0.50 10.0 105% 91 123 104 1% 20

10.9 1% 20 - - - - - -

Date A~~ctlyred 0412 1/09 15 02

IJnlts: mglKg Date Prepared: 411 5/09

Bar~um 576 5.0 550 105% 83 122 Chromium 56 4 5 0 500 113% 86 115 Lead 56,l 5 0 500 112% 85 119 Selenium 52 2 5.0 500 104% 86 117

114 - - - - - - - . - - - .-

Snmplc 713 l.CS-2979 Ba~ch It): 2079 Test Code: SWG010U Date Aualyzed: 04/23/09 12 10

Units: 111glCg Date Prepared: 411 5/09

109% 86 116 116% 85 122

Date Analyzed: 04/23/09 15 28

l Jn~ts mg/l(g Dare Prepared: 4/22/09 9.30

Chrom~um 111% 86 115

Sample in: S,C'SI)-2979 Batcli ID. 2979 Date Analyzed 04/21/09 15 06

U111ts. mdlCg Date l'repared: 411 5/09

Banum 569 5.0 550 !C3% 83 122 576 1% 20 Chromium 55 3 5 0 50,O 111% 86 115 56.4 2% 20 Lead 54 2 5.0 50.0 i08% 85 179 567 3% 20

107% 86 117 52.2 3% 20 104% 87 114 262 2 % 20 - -- -- . - - . - -- . - - . - -- - - -- -

Conlidelitial and Privileged I (If2

Columbia Analytical Sewices-

Date: 27-Apr-09

License No. AZ0 133lAZM 133

CLIENT: Arizona Depal.tlnent of Enviro~u~~ental Quali Work Order: 09040 166

QC StilMMARY REPORT Y reject: Felton King Blank Spilte Dupljcatc

SPXC SPIC % Low High RPD % RPD Analyte Resuh PQL value lief Val Rec 12imit Limit Ref Val RPD Limit Qua1

Sample ID. LC:SI)-2979 Batch ID: 2979 'Test Code. SW6010H ]late Analyzed: 04/23/09 12.14

Ijnils mg/lCg I)atc Prepared 411 5/09

ArSefl~: 51.5 5.0 50 0 103% 86 216 546 6% 20 Cadmium 55 0 1.0 500 110% 85 1 - -- -- - - - - __ - _ - _ __.

Sample ID. 1,CSD-3044 Batch ID: 3043 'i'esr Codc: SW60I OB

Lin~ts mg/i<g Date Prepared: 4/22/09 9:39

Chrom~um -. - -. - - - . 27.7 1 0 250

-- -- - - - - ---- -- _ -. . --- - - - - A . . 111% 86 115

Sample ID. I,CS-2969 13atch ID: 2969

Units, nid[<g Date Prcparcd. 4/13/09

Mercury 0.413 0.083 0 417 99% 80 120 - .-- - -- . - - -- ----- - ^ - - _ _ _ _ _ _ _ _ _ _ _ Sanlplo I{): LOSII-2369 Batch ID: 2969 'Itst Code: SW7471A Date Analy7,ede 04/21/09 16 49

Ijnits 111gfiCg Date P~epared 4/13/09

Mercury 0405 0 083 0.417 - - . -- -- - - - - - .- a=-..- -- -- . 97% 80 120 0 41 - " - " . -

Container type : fi

Sample Reeeip t C hecMist

Client Name: ,143 G Q, Date and Time Received: lJ/fbq / 230 I '

I Work Order Number: Oq OL/ o 1 (, 1;; Checked by: 1

Checklist completed by: 0;ac:4/9,/6 9 Logged in by: Date:

~ a t r i x : G( ~ourier ~ a m e : CAS Reviewed by: Date: 4- 1 5-09 -2

Shipping containerlcooler in good condition? Y esf No C3 Not Present i3 Custody seals intact on shipping container/cooler? Yes E No P Not Present 8 Custody seals intact on sample bottles? yes$ No 5 Not Present El

Chain of custody signed when relinquished and received? Yes ,F No i7 Not Present 3

Chain of custody agrees with sample labels? yes ;Z( No C

Samples in proper containerlbottle? Y e s F No E

Sample containers intact? Y e s y No D

Sufficient sample volume for indicated test? y e s 1 No ;l;

All samples received within holding time? yes,$ No 2

Samples received same day of collection? yes$ No0 Temp: 3 . 5 Wet Ice ~ r e s e n t y

Where was the temperature reading taken at? Sample 5: Temp Blank a/ Other:

VOA Water - VOA vials have zero headspace? Yes L7 No 5 Water - Colilert containers have = 2.5 cm headspace? Yes ZI NO C Water - pH acceptable upon receipt? Yes TJ NO El N/ A Checked by:

pH adjusted and still unacceptable? Yes 2 or pH adjusted and is now acceptable? Yes I3

CN Water - Sulfides present in Cyanide samples? Yes C NoG NIA 83 s2- Water - Beadspace present in Sulfide samples ? , Yes J N o r NIA (Beadspace > than neck of bottle)

Dissolved water Analytes - Field Filtered? Yes 3 NoC NIA b - - Are samples received out of control? NOD Yes If "yes" then complete section below PM Notified? Date: Inir: PM Init:

Client Notified? Date: Init: LMD Date: UMr) Date: Contact Name: Yes E No C

Action to take? Analyze C Cancel G Hold n Other D ChangesIComments made on original COC? Yes Ci N/A C: Date: Init:

Changes made in LIKS? Yes 2 N/A O Date: Init:

Additional Comments:

CS-002-SRChecklist RV3