Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University...

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Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation, Hillsboro, OR 3 IBM Research Division, TJ Watson Research Center, Yorktown Heights, NY • Why carbon nanotube transistors? • Evidence for Schottky barriers • Carbon nanotube Schottky barrier transistors • Gas adsorption versus doping • Scaling of transistor performance • New device designs & capabilities • Conclusions S. Heinze 1 , M. Radosavljević 2 , J. Tersoff 3 , and Ph. Avouris 3

Transcript of Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University...

Page 1: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Scaling of the performance ofcarbon nanotube transistors

1 Institute of Applied Physics, University of Hamburg, Germany2 Novel Device Group, Intel Corporation, Hillsboro, OR

3 IBM Research Division, TJ Watson Research Center, Yorktown Heights, NY

• Why carbon nanotube transistors?• Evidence for Schottky barriers• Carbon nanotube Schottky barrier transistors• Gas adsorption versus doping• Scaling of transistor performance• New device designs & capabilities• Conclusions

S. Heinze1, M. Radosavljević2, J. Tersoff3, and Ph. Avouris3

Page 2: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Carbon nanotube field-effect transistors comparable with Si MOS-FETs

Nanotube FETs with top gates: Nanotube FETs with top gates: • turn-on gate voltage is about 1Vturn-on gate voltage is about 1V

S. J. Wind et al., Appl. Phys. Lett. 80, 3817 (2002).

260nm CNFET

26015~ 0.52100

1501302321

50nm SOI MOSFET

501.5~ -0.2650

970650

Gate length (nm)Gate oxide thickness (nm)Vt (V)ION (A/m)(Vds = Vgs-Vt ~ -1V)IOFF (nA/m)Subthreshold slope (mV/dec)Transconductance (S/m)

(all p-type)

• favorable device characteristicsfavorable device characteristics

Page 3: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Vtip = -2V

map transport current as a function of moving, charged AFM tip

current increase when gating the source junction barrier thinning.

(a)

(b)

M. Freitag et al., Appl. Phys. Lett. 79, 3326 (2001).

Evidence for Schottky barriers:scanned gate microscopy at contacts

Page 4: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Evidence for Schottky barriers:ambipolar conduction in SWNTs

R. Martel et al., PRL 87, 256805 (2001).

Bottom gate CNFETs with Ti contacts annealed;conversion from p-type to ambipolar conductance

Page 5: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Evidence for Schottky barriers: Influence of the contacts for CNFETs

NT

Vg

Vs = 0

Vd

-500

-400

-300

-200

-100

0-1.5-1.0-0.50.0

Drain Voltage [V]

Vg=-1.5V to 0V0.5V steps

Cur

rent

[nA

]

10-13

10-12

10-11

10-10

10-9

10-8

10-7

10-6

Cur

rent

[A]

-2.0 -1.0 0.0 1.0

Gate Voltage [V]

Vd=-0.9V to -0.5V0.2V steps

Vd

Vs = 0

L=300nm

tox=5nm

Switching S & D changes:– Slope by factor of 2– ON-state by factor of 5

not due to bulk, it is a contact effect

M.Radosavljević et al.

Page 6: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

dNT=1.4nm Eg~0.6eVTypical SBs for NTs ~ 0.3eV

Conventional vs. Schottky barrier FET

Schottky Barrier Transistor

ambipolar Characteristic

Conventional Transistor

p-type Characteristic

Page 7: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Transmission through Schottky barrier

Landauer-Büttikerformula for current:

WKB approximation + single NT band:

1086420Distance from Contact (nm)

Conduction Band

1.00.80.60.40.20.0Transmission (E)

0.3

0.2

0.1

0.0

-0.1

E (

eV)

T(E)*[F(E)-F(E-eVd)] (arb.units)

Page 8: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Self-consistent SB-transistor modelfor needle-like contact

• Cylindrical gate at RGate

• Metal electrode of NT diameter• Analytic electrostatic kernel G• Test of approximations for

Solution by self-consistency cycle

V ( )) )(4

(V gate

RG zz z dzz

( )

V( )() ) )( (cE z

ef F E g Ez e z dE

Charge on thenanotube:

Electrostaticpotential:

NTMetal

Gate

Page 9: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Needle-like contact:conductance vs. gate voltage NT

Metal

Gate

10-9

10-8

10-7

10-6

10-5

10-4

Con

duct

ance

(S

)

-1.0 -0.5 0.0 0.5 1.0

Gate Voltage (V)

50

40

30

20

10

0C

onductance (S

)

holetunneling

electrontunneling

Ideal sharp Metal-NT Contact turn-on voltage ~ Eg/2

Page 10: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Carbon nanotube transistors with planar gates

Calculated NT-potential

• Solve a 2D boundary value problem Vext(x)• Local approximation for potential from NT charge

Electrostatic Potential

10-9

10-8

10-7

10-6

10-5

10-4

Co

nd

uct

ance

(S

)

-20 -10 0 10 20

Top Gate Voltage (V)

Conductance Modulation

Page 11: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Influence of the contact geometry

NTMetal

Gate

PRL 89, 106801 (2002)

Scaled Characteristics

Page 12: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Gas adsorption vs. doping:Experimental observations

V. Derycke et al., APL 80, 2773 (2002).

Doping with Potassium Gas Adsorption (O2)

Increase of Potassium

4

3

2

1

0C

urr

ent

(nA

)

-15 -10 -5 0 5 10 15

Gate Voltage (V)

In Air

Annealed in Vacuum

Increase of O2

Page 13: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Uniform doping:Experiment vs. SB model

Doping with Potassium Needle-Contact Model

NTMetal

Gate

Increase of Potassium

Page 14: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

CalculatedDoping Characteristics

n-doped at510-4 e/atom

NTMetal

Gate

Uniform doping of nanotube

Page 15: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

n-doped at110-3 e/atom

CalculatedDoping Characteristics

Uniform doping of nanotubeNT

Metal

Gate

Page 16: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Gas adsorption: Experiment vs. SB model

Gas Adsorption (O2) Needle-Contact Model

4

3

2

1

0

Cu

rren

t (n

A)

-15 -10 -5 0 5 10 15

Gate Voltage (V)

In Air

Annealed in Vacuum

Increase of O2

NTMetal

Gate

Page 17: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Gas adsorption:Change in metal workfunction

Metal workfunctionincreased by 0.2eV

Calculated Gas Adsorption Characteristics

NTMetal

Gate

Page 18: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

How does the performance of Schottky barrier CNFETs scale?

J. Appenzeller et al., PRL 89, 126801 (2002).

10-13

10-12

10-11

10-10

10-9

10-8

Cu

rren

t (

A)

-1.5 -1.0 -0.5 0.0 0.5 1.0

Gate Voltage (V)

110 mV/dectox=2nm

130 mV/dectox=2nm

170 mV/dectox=5nm

280 mV/dectox=20nm

ultra-thin oxide CNFETs:

Why is the thermal limit of 60 mV/decade not reached?

Scaling law with oxide thickness?

Page 19: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Device geometry

Turn-on vs oxide thickness for bottom gate SB-CNFETs

Vscale ~ sqrt(tox)

Page 20: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Analytic model for thin sheet contact

Source

Gate

Gate

z

Gate

tox

tox

Potential near the Edge:

Page 21: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Analytic model applied to bottom gate SB-CNFETs

Single, empirical factor for bottom gate devices

Page 22: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Scaling of turn-on performance of CNFETs with oxide thickness

Largest improvementsby optimization of thecontact geometry

Analytic Model

PRB 68, 235418 (2003)

120

80

40

0

He

igh

t (n

m)

4003002001000

Length (nm)

Source Drain

Top Electrode

Bottom Gate

Nanotube 0.9

0.4

0.3

0.2

tox

Page 23: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Scaling of drain voltage for ultra-thin oxide CNFETs?

-1.2

-0.9

-0.6

-0.3

0.0

0.3E

ner

gy

(eV

)

4003002001000Position along Nanotube (nm)

So

urc

e

Dra

in

tox=30nm tox=2nm

Vdrain=+0.8V, Vgate=+0.4V

Minimal Current (OFF-current)

rises with lower oxide thickness0.3

0.2

0.1

0.0

-0.1

En

erg

y (e

V)

20151050-5

Distance from Contact (nm)

• independent barriers – one controlled by Vg, the other by Vd–Vg

• identical (and minimal) hole/electron current at Vg = Vd–Vg Vd = 2Vg

120

80

40

0

Hei

gh

t (n

m)

4003002001000

Length (nm)

Source Drain=0.5V

Top Electrode

Bottom Gate=1V 0.9

Nanotube

0.4

0.3 0.2

0.1

Ultra-thin oxide: turn-on voltage ~ Vd

Page 24: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Effect of drain voltage for ultra-thin oxide CNFET

exponential increase of OFF current with Vd

Bottom-gate: tox=2nm

Page 25: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Scaling of drain voltage: model vs. experiment

APL 83, 2435 (2003)

tox=2nm

Page 26: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

OFF state problem for transistor light emission device

Infrared light emission from a SWNT: J. Misewich et al., Science 300, 783 (2003).

Page 27: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Asymmetric device design to solve OFF state problem

Symmetric CNFET (tox=2nm) unfavorable OFF state

APL 83, 5038 (2003)

Asymmetric CNFET low OFF current & p- and n-type device for Vd<0 and Vd>0

Page 28: Scaling of the performance of carbon nanotube transistors 1 Institute of Applied Physics, University of Hamburg, Germany 2 Novel Device Group, Intel Corporation,

Conclusions

• Transistor action in CNFETs due to Schottky barriers ambipolar transfer characteristic (I vs Vg)• Nanoscale features of contacts are essential• Gas adsorption modifies band line-up at the contact• Scaling in turn-on regime with sqrt(tox)• Scaling of drain voltage at ultra-thin oxides necessary• New device physics: light emission device• New device designs may be favorable

CN Transistors competetive with Si MOSFETs, however: