. SAMPLE DATA PACKET · 2018-06-19 · 80 79 -awr 17:11 80 1, 000 a bb jmb98i 20, 000 ug/l 2. is 81...
148
. SAMPLE DATA PACKET E.P.A. CASE NO. __ E.P.A. Sample No. = CompuChem No. A, HSL Results -Organic Analysis •£. TODD Chromatogram(s)/ Data Sheets Quantltatlon Report B, Tentatively Identified Compounds U8t 'F. PeatloldeChromatoflramls)/ •C. VOAChromatogram(s)/ Quantltatlon Report Quantltatlon Report • Mass Spectra ol GO/MS • Dual Mass Spectra ofHSL Continuation II Required Compounds .Q, WorK Sheets • Library Search Spectra . ^^ ^M^ •0. Semi-volatile Chromatoflram(s)/ • Extraction WorKsheeta Ml < Quantllatlon Report • Compound Lists • Dual Mass Spectra of HSL . • Miscellaneous Calcutatlon Compounds • Library Search Spectra •Sequence repeated as required 003111.7 »
Transcript of . SAMPLE DATA PACKET · 2018-06-19 · 80 79 -awr 17:11 80 1, 000 a bb jmb98i 20, 000 ug/l 2. is 81...
. SAMPLE DATA PACKETE.P.A. CASE NO. __
E.P.A. Sample No. = CompuChem No.
A, HSL Results -Organic Analysis •£. TODD Chromatogram(s)/Data Sheets Quantltatlon Report
B, Tentatively Identified CompoundsU8t 'F. PeatloldeChromatoflramls)/
•C. VOAChromatogram(s)/ Quantltatlon ReportQuantltatlon Report • Mass Spectra ol GO/MS• Dual Mass Spectra ofHSL Continuation II Required
Compounds .Q, WorK Sheets• Library Search Spectra . ^ ^M^•0. Semi-volatile Chromatoflram(s)/ • Extraction WorKsheeta
Ml < Quantllatlon Report • Compound Lists• Dual Mass Spectra of HSL . • Miscellaneous Calcutatlon
Compounds• Library Search Spectra
•Sequence repeated as required
003111.7»
A. HSL Results — Organic Analysis Data SheetsResults are reported on the specified forms for each fraction of each sample, Detectionlimits are CompuChem's, determined as described In IV-Q. Differences In sample sizes ordilutions require application of correction factors, noted In appropriate boxes to bechecked, Dry weights have been determined for solid samples, and the values on theOrganic Analysis Data Sheets represent dry weight concentrations, % moisture figuresare also noted for each sample. Where footnotes are applicable, they have been notedwith data qualifiers as described In I -D,
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CRGANICS ANALYSIS DATA SHEET
NMIWI Mtad CompuOhem C»a Humbert
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Sample 10 No.! tfZHf /< ' 00 Roport No.iSample Matrix: Liquid ______ ________ Contract No.tData Ro loose Autliorliej By; 1 1. Wn> Data Sonple Rocolvoai
SEM(VOLATILE CONFOUNDS
CONCENTRATION!< )l€DIUM HIGH (circle one)DATE EXTRACTEO/PREPARsDi jW-
DATE ANALYZED! .3PERCENT HOISTUREl '
Multiply Detection I hit; by 1 Jj or loQ or|Vj- if.if.tte Factor)(C'mck Box for Appropriate Factor)
crug/kg(circle one)
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CROANICS ANALYSIS DATA SHEET
Nsmet Head ConpuChem__________ Case Number! 3"& 2>_uab Sample ID No. i________________Sample Matrix! Liquid______ ________ Contract No.iData Release Autliorliad By; IWWq, Date Sample Received!
SEN(VOLATILE COMPOUNDS
CONCENTRATION< )lCDIllH HIGH (circle one)DATE EXTRACTED/PREPARED! 3-t.~ri/_______
DATE ANALYZED! .g. a<PERCENT MOISTURE! ''
Multiply Detection llmlti by 1 __ or iqQ »]_)- V.«<(Check Box for Appropriate Factor)
PPf CASf or ug/kg PPf CASf orugTkg"""" "~~ (circle one) "~" "~~ (circle one)I21A1 88-08-2 2,4,8-trlchlorophanol_____tOU (8») tl-tt-J hexaehlorobutadlene______IOU
U.S. ENVIRONMENTAL PROTECTION AGENCY - CU> Sample Management OfficeP.O. Box 818, Alexandria, Virginia 22313 - 703/997-2490
ORGANICS ANALYSIS DATA SHEET
Laboratory Name! _ComniCheiii______ ____ Caie Number S 3Lab Sample ID Noi /^i/?_____________ OC Report No.Sample Matrix! Llould ________ Contract No.t ______Data Rolerao Authcrlied Bvi C«*t/>*J& Date Sample Received! /-;
VOLATILES PESTICIDES
CONCENTRATIONl ' * ijf5\$h HIGH (circle) CONCENTRATION! (Zjj) MEDIUM HIGH (circle one)DATE EXTRACTED/rla>AfiED! l'»V.f^f________ DATE EXTRACTED/PREPAREDiDATE ANALYZED! JL ,/t flf______________ DATE ANALYZED! /-.2 UPERCENT MOISTURE! _______________ffl- PERCENT MOISTURE! ___
Multiply Detection llmltt by I Qor|_}~|___ Multiply Detection limits by I 0or£J ___(Check Box for Appropriate Factor) _ (Check Box for Appropriate Factor)
PPI CAS<
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(circle one)2,3,7,B-tetrechlorodlbenio-
(I29B1 1746-01-6 p-dloxln________0.004U
July, 1983010120
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B. Tentatively Identified Compounds ListThe form used to list tentatively Identified compounds la generated at CompuChem by theQC/MS Instrument data system for each fraction analyzed, This form lists the fraction,sample number, scan number, CAS#, name, and estimated concentration for compoundswhose peaks exceed 25% of the nearest Internal standard's response, Appropriatefactors for correction of sample or extract volumes, dilutions, etc, are added by theanalyst prior to Injection, so that the concentration has been adjusted when It Is printed onthe form, There are places on the form for the spectral interpretation expert to noteInformation and opinions about the Identification, and to Initial the searches,
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C. VOA Chromatogram(s)/Quantltation ReportFor those compounds detected at greater than '/i the detection limits on the MSL listing,dual mass spectra are provided, These spectra are labeled with the CAS* and theCompuChem compound number associated, and can also be Identified wllh reference tonon-HSL compounds present at greater than 25% of the response of the nearest Internalstandard are also Included, These are obtained from a library search of me EPA/NIHThese spectra were generated via a limited-library search against standards run at thebeginning of the contract work, on each Instrument,
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PROCEDURE'. RK DIAGNOSTIC REPORT 2/10/84 __-.»_•. B8DATA FILE'. CN019247A11REFERENCE', V237A METHOD: V237 INITIALIZATION OPTION', 2 PROCESSING OPTION'. 3
REPORT: VH37B1
< —— STANDARDS ——— X —— PLUS UNKNOWNS —— X. - LIST NAPIEB - >PROC USED P088 RM8 PROC USED POSS RUB STANDARD/UNKNOWN
3 2 i 0 44 il 1 68 V23781/V_37Ui
44 COMPOUNDS PROCESSED. -A FOUND
< COMPOUND X ———————— SEARCH ———————— X BAT X ———— CHRP ————— 3'NO LIB ENTRY REF PRED BEL DELTA PEAKS PIT PEAKS -M/E- TOP DELTA PBAK8i Pi 1 -161 163 163 . 1 96B 130 - 168 -1 12 PS i -337 33B . . . , 79 338 13 P3 1 -416 416 416 . 1 973 55 416 . 14 PI 2 -30 31 . . , 50 34 15 PI 3 -43 44 . . . . 946 PI 4 -52 53 . . 62 54 ' . 17 PI 5 -6B 69 . . . , 64 71 iB PI 6 -182 103 . . . . . 84 104 , 19 PI 7 -112 113 . . . . SB 113 110 PI 8 -112 113 . . . . 56 115 111 PI 9 -134 125 , . . 53IS PI 10 -139 140 ... , 101 140 113 PI 11 -129 130 , . . , 76 132 114 PI IS -152 153 , , . . , 9615 PI 13 -176 177 . . 65 177 2
PA 14 -190 191 191 . 1 961 96 191 , 17 PI 15 -201 202 , . . . 83 202 . 1IB PI 16 -215 216 , . 62 216 11 9 P I 1 7 -213 2 1 4 . , . , 7 2 2 1 4 . 180 PI IB -239 240 , . . , , 9721 PI 19 -247 24B , . . , , 1172 2 P 2 S -251 2 5 2 . . . . . 4 3S3 PS 3 -25B 259 . . . . , 127 . . .2 4 P S 4 -2B4 2 B 5 . 6 5 . . .S5 P2 5 -2B9 290 . . 7526 P2 6 -300 301 , . . . . 130 300 . 127 PS 7 -310 311 310 -1 1 990 , 7B 310 , 12B PS B -314 315 . . , . 9729 PS 9 -314 315 , . . , 75 , '30 PS 10 -312 313 . . 12731 PS 11 -336 337 . . . , 633 2 P S 1 2 -365 3 6 6 . . . . . 1 7 3 . , ,33 P3 13 -374 375 . . . . . . SB . . ,34 P3 2 -404 405 . ... . SB 405 . 13 5 P 3 3 -410 4 1 1 . . . . . 8 3 . . .36 P3 4 -411 412 164 418 . 137 pa g -436 437 437 . 1 9B5 . IS 437 138 P3 6 -458 459 459 . 1 968 112 459 , 139 P3 7 -496 497 496 -1 1 995 . 106 496 i40 P3 B -566 567 i . . . . .104 567 141 P3 9 -5B9 590 590 . 1 993 106 590 , 148 P4 S -213 214 214 . 1 957 . 65 314 1
P4 3 -433* 433 433 . 1 946 100 4381 Hi 27 •>•P4 4 -540 541 541 . 1 991 176 H#*UI-I 1
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QUANTITATION REPORT FILE: CN019247A11
DATA: CNB19847A11, TIB/10/B4 11: 41'. 00
!: S ML * 19247 •«• 5 UL 10990 + 109B5SUBMITTED BY: 11 ANALYST: 577
AMOUNT-AREA * REF. AMNT/(REF. AREA)* REBP. FACT)REBP, FAC, FROM LIBRARY ENTRY
NO NAME1 * BROMOCHLOROMETHANE (IS)8 321 CHLOROMETHANE3 820 BROMOMETHANE4 331 VINYL CHLORIDE5 309 CHLOROETHANE6 388 MEtHYLENE CHLORIDE7 358 ACETONE <2-PROPANONE)B 301 ACROLEIN9 308 ACRYLONITRILE10 330 TRICHLOROFLUOROMETHANEU 354 CARBON DI8ULFIDE12 816 1,1-DICHLOROETHYLENE13 814 1.1-DICHLOROETHANE14 386 TRANB-1,8-DICHLOROETHYLENE15 811 CHLOROFORM16 _15 i. 8-DICHLOROETHANE17 353 2-BUTANONEIB 387 1.1.1-TRICHLOROETHANE.9 806 CARBON TETRACHLORIDE
* 2-BROMO-l-CHLOROPROPANE81 857 VINYL ACETATE • '88 312 BROMODICHLOROMETHANE83 317 1,3-OICHLOROPROPANE84 850 TRAN8-1.3-DICHLOROPROPENE85 339 TRICHUOROETHYLENE86 303 BENZENE87 88B 1.1. 8-TRICHLOROETHANE88 31B CIS-1. 3-DICHLOROPROPENE89 80B DIBROMOCHLOROMETHANE30 810 8-CHLOROETHYL VINYL ETHER31 305 BROMOFORM38 856 4-METHYL-3-PENTANONE33 * DICHLOROBUTANE34 355 2-HEXANONE35 383 1.1.2, 3-TETRACHLOROETHANE36 334 TETRACH-OROETHENE37 335 TOLUENE38 807 CHLOROBENZENE39 819 ETHYLBENZENE40 851 STYRENE41 339 0-XYLENE48 * D4-1.8-DICHLOROETHANE43 * DB-TOLUENE44 « BROMOFLUOROBENZENE
M/E SCAN TIME REF RRT METH AREA(MGHT) AMOUNT
01103988
NO M/E SCAN TIME REF RRT METH AREA<HCHT> AMOUNT V.TOT130 162 B: 14 1 1. 000 A BB 13976, 20, 000 UG/L 2. IS50 $S2 ii44 1 0,210 ABB • 5025, 4, 3B2 UC/L 0, 4 7 A/0
3 NOT FOUND _ ———————__4 62 <Sp 2:45 1 0, 333 A BB 127B8, Ca. A7& UC/L 0.5 64 71 3:37 1 0. 438 A BB 853,. VOTI IIP./L 0,106 84 *«3? 5:17 1 0, 642 A BB 7540, QTiiiBa uc/L a. at,7 58 <33> 5:4S 1 0, 698 A BB 345S, /-105. 360 UC/L 11. 34B 56 J33> 5i 51 1 0. 710 A BV 787, V;=iiT47644 UG/L i. 5B9 NOT FOUND10 101 140 7:07 1 0. B64 A BB 1893, 1, 338 UC/L ' 0, 1411 76 132 6:43 1 0, 815 A BB 15B2, 0. 570 UG/L 0, 0618 NOT FOUND13 65 433 9:00 1 1, 093 A*BB 1632,14 96 igjj? 9:43 1 1. 179 A BB 15615.15 83 202 10:16 1 1. 247 A BB 1507. 0. 576 UG/L O516 62 816 10:59 1 1, 333 A BB 1B95, 1.907 UG/L 0, 2117 72 814 10:53 1 1. 321 A BB 913. 4.523 UG/L 0. 49IB NOT FOUND19 NOT FOUND/£2. _80 79 -awr 17:11 80 1, 000 A BB JMB98I 20, 000 UG/L 2. IS81 NOT FOUND88 NOT FOUND83 NOT FOUND84 NOT FOUND85 130 300 15:15 1 1, 858 A BB 1335, f 77* "r-" ft, ft026 78 TSJP 15:45 1 1.914 A BB 84811. g-ffl»A iin;;, i 0187 NOT FOUND
NOT FOUNDNOT FOUND
30 NOT FOUND31 NOT FOUND38 NOT FOUND/**-.33 55 -*ttT 21:09 33 1, 000 A BB 37973-, 20. 000 UG/L 2, 1534 SB 405 20:35 1 2, 500 A BB 1693, 4, 349 UG/L 0. 4735 NOT FOUND36 164 412 20:57 1 2,543 A BB 8861, 1 72 UC/L 0. is37 92 <_SP 22: 13 i 2, 696 A BV 819469. (gSg-'ytn IIP./L -A ig3B 118 _3S> 23:20 1 2, B33 A BV 257330, eSS -A-J »C/L B, 5639 106 2P 25:13 1 3. 062 A BB 83556, Jl 9BB UC/L 1. 2940 104 567 28:49 1 a 500 A BB 8024, 0. 601 U6/L 0. B641 106 gJD 2* 59 i 3--4H ABB 187656, d5£T46 UC/L '6. 6a'£>48 65 814 10:53 1 1, 321 A BB " 24249. 24. 109 UG/L——ST5?—43 100 433 32:01 1 8.673 A BB 85480, 86, 943 UC/L 2.9044 176 540 87:27 1 a 333 A BB 83706, 20, 157 UG/L 2. 17
NO RET(L) RATIO RRT(L) RATIO AMNT ArffTtL) R. FAC R, FAC(L> RATIO1 8:11 101 1000 1.00 20.00 20.00 1.000 1,000 1.002 1:31 113 0,186 113 4.38 80,00 0,090 1,641 0.053 2:11 0,267 60.00 3,0454 2t 39 104 0.323 103 8.68 60.00 0,289 a 109 0.115 3:27 104 0,428 104 0.97 80.00 0,015 1257 0,016 5:11 1.08 0,634 101 4.25 80.00 0.135 8,537 0.057 5; 42 101 0.696 1. 00 105. 36 600,00 0.00B 0, 047 0. IBB 5:42 1.03 0.696 102 14.64 800,00 0,001 0,077 0A02A1oQ
M? 6:18 0,770 800,00 0,102 UTUJ.-"10 7:04 1.01 0.863 1,00 1.33 80,00 0,034 2,033 0.02
NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R. FAC(L) RATIO11 6:33 1 02 0.801 1, 02 0.57 80, 00 0, 02B 3, 972 0, 01
7:44 0.944 80,00 1,1618:57 1,01 1.093 100 3,43 BO, 08 0,029 0. 6B1 0,04
14 9:39 1, 01 1. 180 1, 00 22,73 BO, 00 0. 279 0,983 0, 2815 10:13 1 00 1.248 1 00 0, SB 80, 08 0. 027 3,743 0, 0116 18:56 1 00 1. 335 100 1.91 BO, 00 0. 034 1422 0, 0217 19i SO 100 1.323 100 4,52 80,00 0,016 0,289 0,06IB 12:09 1484 80,00 8.43519 12:33 1.534 80,00 2.993'20 17:08 100 1.000 100 20,00 20,00 1.000 1000 '10021 12:46 1.559 80,00 0,80322 13:07 1.602 BO, 00 - 8,-26223 14:26 1.764 80.00 0,43324 14:41 1.795 80,00 3.59125 15:15 100 1.863 0.99 0,77 80.00 0,024 3.469 0,0126 15:45 100 1.925 0,99 36.33 80.00 1517 3.341 0.4527 15; SB 1,950 . 80.00 1,02126 15:58 1.950 60,00 101629 15:52 1.938 80.00 1,74430 17:05 2.087 BO. 00 0.45531 18:33 2,267 BO, 00 1,39932 Wi 01 2,323 120,00 0.24233 21:09 100 1.000 1,00 20,00 20,00 1,000 1,000 1,0034 20; 32 1.00 2,509 1.00 4.35 120,00 0.020 0.557 0,0435 20:50 2,547 80.00 114036 20:54 1.00 2,553 1,00 1.07 60,00 0,051 3,619 0,0137 22:10 100 2,70S 1.00 428.70 80.00 14,659 2,735 5,3636 83:17 1.00 2,645 1,00 79.57 80,00 4.603 4.62B 0,99
25:13 100 3,081 0.99 11,99 80,00 0,421 2. B12 0.1540 28:46 100 3,516 1,00 0,60 60,00 0,036 4.620 0.0141 29:56 1.00 3,656 1,00 61.55 ' 60.00 2,284 8,966 0,7748 10:50 100 1,383 1,00 24,11 20,00 1,735 1,439 1,2143 81: A3 1.04 2,683 1,00 26,94 20,00 6,116 4,540 A. 3344 27:27 100 3, 354 0,99 20,16 20, 00 5,9B9 5.943 101
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PROCEDURE: RK DIAGNOSTIC REPORT 1/31/84 7:90:DATA FILE: 4H019247C14REFERENCE: FSCC7
METHOD: FSCC7 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3REPORT: FSCC7S1
< —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSB RMS PROC USED PCGS RMS STANDARD/UNKNOWN
6 6 1 73 94 6 1 73 F8CC7S1/FSCC7U16 6 1 73 34 13 1 110 FBCC7S2/FBCC7U2
'9ITC3 •11J19 -1607' 160B , , , '. . 166 ' .91 C3 16 -1623 1624 . , , . 138,92 C3 17 -1640 1641 . . . . 19893 C3 IB -1648 1649 . , , . 1699 4 C 3 1 9 -1691 1693 . . . . . 7 7 .99 C4 2 -1725 1727 . , , . 24896 C4 3 -1749 1791 . . . . 28497 C4 4 -1794 1796 . , . . 26698 C4 9 -1821 1822 , . , . . 178 .99 C4 6 -1831 1832 . . ... 1786 0 C 4 7 -1989 1990 . . . . . 1 4 9 199061 C4 B -2093 2094 . . . , 20262 C9 2 -2142 2143 . , , . . 202 . .63 C9 3 . , . . . . . 1B4 '. . .64 C9 4 -2327 2328 , . . . 14969 C9 9 -2433 2434 . , . . 29266 C9 6 -2420 2421 . . . . ."" 22867 C9 7 -2471 2471 . . . . . 149 .68 C9 B -2429 2430 . . . . . 228 .69 C9 9 -2609 2609 . . . . . 149 260770 C6 2 -2693 2693 . . . . 29271 C6 3 -2696 2698 . . . . 29272 C6 4 -2716 2716 . . . , 29273 C6 9 -2994 2994 . . . . 27674 C6 6 -3004 3004 . . . . 27B79 C6 7 -3072 3072 . . . . 27676 C7 2 -991 994 996 2 1 927 . 1 1 2 99677 C7 3 -778 781 783 2 1 981 . 99 7837B C7 4 -944 947 946 -179 C7 9 -1343 1349 1344 -180 C7 6 -1666 1668 166881 C7 7 -2138 2139 213982 C7 8 -2199 2196 2196
907 . 82 946860 . 172 1344804 . 330 1668786 . 212 2139938 . 244 2196
010162
QUANTITATION REPORT FILE: OH019247C14
DATA: OH019247C14, TI01/31/84 7: OB: 00SAMPLE: 1UL 19347 + 3UL IS (10910)SUBMITTED BY: 14 ANALYST: 794
AMOUNT»AREA # REF. AMNT/(REF, AREA)* RESP.FACT)RESP. FAC. FROM LIBRARY ENTRY
NO NAME1 «D4-1.4-DICHLOROBENZENE (IS)2 441 N-NITR08QDIMETHYAMINE3 610 PHENOL4 473 ANILINE •- •9 411 B IS (2-CHLOROETrlYL) ETHER6 601 2-CHLOROPHENOL7 421 li 3-DICHLQROBENZENE8 422 1.4-DICHLOROBENZENE9 474 BENZYL ALCOHOL10 420 1,2-DICHLdRQBENZENE11 620 2-METHYLPHENOL12 412 BIS(2-CHLOROISOPROPYL>ETHER13 622 4-METHYLPHENOL14 442 N-NITROSO-DI-N-PRQPYLAMINE19 436 HEXACHLOROETHANE16 440 NITROBENZENE17 *460 OB-NAPHTHALENE (IB)18 43B I80PHQRONE19 606 2-NITRQPHENOL20 603 2,.4-DIMETHYLPHENOL21 410 BI8(2-CHLOROETHOXY)METHANE22 629 BENZOIC ACID23 602 2,4-DICHLOROPHENOL24 446 1.2.4-TRICHLOROBENZENE29 439 NAPHTHALENE26 479 4-CHLOROANILINE27 434 HEXACHLOROBUTADIENE28 608 P-CHLQRD-M-CRE8QL29 477 2-METHYLNAPHTHALENE30 439 HEXACHLOROCYCLOPENTADIENE31 611 2,4.6-TRICHLOROPHENCn.32 626 2>4.9-TRXCHLOROPHENOL33 *D10-ACENAPHTHENE (IB)34 416 2-CHLORONAPHTHALENE39 479 3-NITROANILINE36 429 DIhETHYLPHTHALATE37 402 ACENAPHTHYLENE38 428 2.6-DINITROTOLUENE39 478 2-NITROANILINE40 401 ACENAPHTHENE41 609 2,4-DINITROPHENOL42 607 4-NITROPHENOL43 476 DIBENZOFURAN44 427 2i 4-DINITROTOLUENE49 424 DIETHYLPHTHALATE46 417 4-CHLOROPHENYL PHENYL ETHER _ _ n « O O. 010163
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NO NAME47 433 FLUORENE48 480 4-NITROANILINE49 604 4,6-DINITRO-Q-CRESOL90 443 DIPHENYLAMINE (N-NITROSO)91 430 1,8-DIPHENYLHYDRAZINE (AZOBENZENE)92 *467 D10-PHENANTHRENE (IS)93 414 4-BROMOPHENYL PHENYL ETHER94 433 HEXACHLOROBENZENE99 609 PENTACHLORQPHENQL96 444 PHENANTHRENE97 403 ANTHRACENE ' '98 426 DI-N-BUTYLPHTHALATE99 431 FLUORANTHENE - •60 «499 D12-CHRY8ENE (IB)61 449 PYRENE62 404 BENZIDENE63 419 BUTYLBENZYLPHTHALATE64 423 3>3'-DICHLOROBENZIDINE69 409 BENZO(A)ANTHRACENE66 413 BX8(2-ETHYLHEXYL)PHTHALATE67 418 CHRYBENE68 429 DI-N-DCTYLPHTHALATE69 «D12-BENZO(A)PYRENE (18)70 407 BENZO(B)FLUORANTHENE71 409 BENZO(K)FLUORANTHENE72 406 BENZO(A)PYRENE73 437 IND_NO(l,2,3-C, DJPYRENE74 419 DIBENZO(A.H)ANTHRACENE79 408 BENZO(0,Hi I>PERYLENE76 619 2-FLUOROPHENOL (SURROGATE)77 D9-PHENOL (SURROGATE) , . ,78 447 D9-NITROBENZENE (SURROGATE)79 448 2-FLUOROBIPHENYL (SURROGATE)80 TRIBROMOPHENOL (SURROGATE)81 D10-PYRENE (BURROOATE)82 D14-TERPHENYL (SURROGATE)
NO M/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT XTQT1 190 829 10:19 1 1,000 ABB 29793. 40.000 NO 2.142 74 332 4:09 1 0.402 A«VB 4447. 17. 31 NO 0.93 W3 94 789 9:49 1 0.992 A BB 9130. £ 14T429NCJ> 0.774 NOT FOUND9 93 794 9:99 1 0.962 A BB6 NOT FOUND7 NOT FOUNDB 146 827 10; 20 1 1.002 A BB9 NOT FOUND10 146 864 10:4B 1 1.047 A BB11 10B 901 11:16 1 1.092 ABB12 NOT FOUND13 108 933 11:40 1 1.131 ABB14 NOT FOUND19 NOT FOUND16 NOT FOUND17 136 1092 13:39 17 1.000 ABB 62971. 40.000 NO 2.14IB NOT FOUND .
010164
26
NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT XTOT19 NOT FOUND20 NOT FOUND
0| 21 JHOT FOUND22 NoT~FtraND/o23 NOT FOUND24 NOT FOUND29 12B 1099 13:41 17 1.003 ABB 7219. 4. 141 NO 0.2226 NOT FOUND27 NOT FOUND28 107 1239 19: 29 17 1. 139 A BV 3099. 9, 999 TIG 0. 3229 NOT FOUND30 NOT FOUND31 NOT FOUND ~ •32 NOT FOUND33 164 1486 18:34 33 1.000 A VB 30976. 40. 000 NO 2.1434 NOT FOUND39 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND . ————— .49 149 1616 20:12 33 1.087 A VB 6899. Ct. 240 N(Q 0.4'46 NOT FOUND
• . . _ 47 NOT FOUND1 48 NOT FOUND , • . .
49 NOT FOUND . ,• 90 NOT FOUND
91 NOT FOUND, 92 1BB 1817 22: 43 92 1. 000 A VB 46810, 40. 000 NO 2. 14
93 NOT FOUND94 NOT FOUND99 NOT FOUND96 NOT FOUND
I 97 NOT FOUND98 149 1990 24: 92 92 1. 099 A BB 1960. 0. 998 NO 0. 09
• 99 NOT FOUND60 240 2424 30:18 60 1.000 A BV 49009. 40. 000 NO ' 2.1461 NOT FOUND62 NOT FOUND63 NOT FOUND64 NOT FOUND69 NOT FOUND66 NOT FOUND67 NOT FOUND68 149 2607 32: 39 60 1. 079 A BB 479. 0. 276 NO 0. 0169 264 2712 33:94 69 1.000 A VB 31609. 40. 000 NO 2,1470 NOT FOUND71 NOT FOUND72 NOT FOUND f\\ (\\tft
01U1"373 NOT FOUND74 NOT FOUND
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79 NOT FOUND76 112 596 7:27 1 0.732 ABB /• 14999. 36,487 NO 1,9877 99 783 9:47 17 0.717 A BB / 14850, 20,896 NO 1,1178 83 946 11:49 17 0,866 ABB VJ|c7477. 11.649 NO 0,6279 173 1344 16:48 17 1.231 ABB,, } 42193. 46. 139 NO 2,4680 330 1668 30:91 33 1.132 AVfifX^ 3477. 29.043 NO 1.3481 212 2139 26:44 60 0.882 A BBvv „ I 94191, 43.972 NO 2.33
1 10:16 1.00 1.000 1,00 40,00 / [40.00 1.000 l.'OOO' 1.002 4:09 1.02 0.398 1.01 17.43 90.00 0.138 0.396 0.393 9:49 1.01 0.949 t.00 14.42 90.00 0.283 . 0.982 0.294 9:37 0.937 100.00 .0.4909 9:92 1.01 0,960 1.00 1183.32 100.00 9.639 0.477 11.836 9:91 0.999 90.00 0.7077 10:10 0.990 90.00 0.784B 10:19 1,00 1.009 1.00 7.27 90.00 0.123 0.849 0.199 10:48 1.091 90.00 0.37610 10:46 1.00 1.049 1.00 2.88 90.00 0.044 0.762 0.0611 11:13 1.00 1.092 1,00 4.12 90.00 0.039 0.473 0,0812 11:19 1.099 90.00 0.21913 11:37 1.00 1.130 1.00 193.93 90.00 1.616 0.929 3,0814 11:37 1.130 90.00 0.12119 11:33 1.124 90.00 0.37616 11:91 1.193 90.00 0.38417 13:38 1.00 1,000 1.00 40.00 40.00 1.000 1.000 1,0018 12:31 0.918 90.00 0.97B19 12:43 0.932 90.00 0. 18320 12:99 0,992 90.00 0.42321 13:19 0.972 90.00 0.40022 13:36 1.000 290.'00 0.08723 13:22 0.980 90.00 0.27024 13:34 0.999 90.00 0.32929 13:41 1.00 1.004 1.00 4.14 90.00 0.092 1.114 0,0826 14:01 1.02B 249.99 0.14927 14:16 1.047 90.00 0.17928 19:28 1.00 1.134 1.00 9.99 90.00 0.039 0.328 0.1229 19:37 1.149 90.00 0.29730 16:17 1. 194 90.00 0. 19331 16:33 1.214 90.00 0.29832 16:38 1.2-0 249.99 0.17033 18:34 1.00 1.000 1.00 40.00 40.00 1.000 1.000 1,0034 16:97 0.913 90.00 1.09939 17:28 0.941 249.99 0.36836 18:10 0.978 90.00 1.17337 18:07 0.976 90.00 1.06638 18:19 0,987 90.00 0.26839 16:33 0.999 249.99 0.03740 18:39 1.009 90.00 0.81241 18:99 1.020 249.99 0.12342 19:16 1.03B 129.00 0. 19943 19:07 1.030 90.00 1.44644 19:22 1.044 90.00 0.37149 20:12 1.00 1.088 1.00 9.24 90.00 0.232 1.294 0.1846 20:12 . 1.088 90.00
NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R. FAC(L) RATIO47 20: 09 . OB2 90. 00 0. 86148 20: 17 . 093 249. 99 0. 03649 20: 30 , 104 249, 99 0. 1BB90 20:36 .110 90.00 0.27491 20:38 .112 90.00 1.48292 22:42 1.00 .000 1.00 40.00 40.00 1.000 1.000 1.0093 21:34 0.990 90.00 0.19194 21:92 0.963 90.00 0.28099 22: 29 0. 988 90. 00 0. 14296 22:46 .003 90.00 I.'.I 9697 22:93 .008 90.00 1.01898 24:92 1,00 .099 1.00 0.96 90.00 0.027 1.392 0.0299 26:10 .193 90.00 ~ -1.20160 30:18 1.00 .000 1.00 40.00 40.00 1.000 4. 000 1.0061 26:46 0.884 90.00 1.32062 30:01 0.908 90.00 0.01063 29:09 0.960 90.00 0.99864 30:29 1.004 90.00 0.07169 30:19 0.998 90.00 1.20166 30:93 .019 90.00 0.92167 30:22 .002 90.00 1.01168 32:34 1.00 .079 1.00 0. 28 90.00 0.009 1.941 0.0169 33:93 1.00 , 000 1. 00 40.00 40.00 1.000 1.000 1.0070 33:10 .979 90.00 1.36271 33:13 .980 90.00 0.79372 33: 97 . 002 90. 00 0. 98173 37: 29 . 104 90. 00 0. 69074 37:33 .108 90.00 0.76179 38:24 .133 90.00 0.87976 7:23 1,01 0.719 1.00 36.49 90.00 0.493 0.621 0.73
- --- - -- 20,86 90.00 0.190 0.499 0.4211.69 90,00 0.096 0.410 0,2346. 14 90. 00 0. 939 0. 989 0. 9229,04 90.00 0.091 0.182 0.9043.97 90.00 0.962 1.104 0.87
77 9:43"78 11:4879 16! 4780 20:4981 26! 4382 27:26
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PROCEDURE: RK DIAGNOSTIC REPORT 2/03/84 4:23: KDATA FILE: OR019247C14REFERENCE: F8CC7
nETHOD: FSCC7 INITIALIZATION OPTION: 2 PROCESSINS OPTION: 3REPORT: FSCC7SI
< ——— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - ?PROC USED PQS5 RCIS PROC USED POS8 RMS STANDARD/UNKNOWN
6 6 I 40 34 B 1 33 FBCC7S1/FSCC7U16 6 1 40 34 13 1 73 F8CC7B2/F8CC7US
1 Cl 1 -BBS 828 828 . 1 782 . 190 8882 C2 1 -1099 1099 10993 C3 1 -1491 1491 14914 G4 1 -1823 1823 18239 C9 1 -2430 2430 2431 16 C6 1 -2719 2719 2719
978 . 136 1099981 , 164 1491994 . 188 1823798 . 840 2430 -1906 , 264 2719
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010203
*«
QUANTITATION REPORT FILE: OR019247C14
DATA: OR019247C14, TI02/03/84 3:42:00SAMPLE: 1 UL 19247R<2/1) QUA «14SUBMITTED BY: 14 ANALYST: 763
AMOUNT-AREA * REF, AUNT/<REF. AREA)t REBP. FACT)RESP. FAC. FROM LIBRARY ENTRY
NO NAME1 *D4-1>4-DICHLOROBENZENE (IS)2 441 N-NITROSQDIMETHYAMINE3 610 PHENOL4 47,1 ANILINE9 411 BIS(2-CHLORaETHYL)ETHER6 601 2-CHLOROPHENQL7 421 li3-DICHLdROBENZENEB 422 li4-DJCHLQROBENZENE9 474 BENZYL ALCOHOL10 420 1.2-DICHLOROBENZENE11 620 2-METHYLPHENOL12 412 BIS(2-CHLOROIBOPROPYL)ETHER13 622 4-METHYLPHENOL14 442 N-NITROBO-DI-N-PROPYLAMINE19 436 HEXACHLORDETHANE16 440 NITROBENZENE17 *460 DB-NAPHTHALENE (IS)IB 438 ISOPHDRONE19 606 2-NITROPHENOL20 603 2.4-DIMETHYLPHENQL21 410 BIS(2-CHLOROETHOXY>METHANE22 ' 629 BENZQIC ACID23 602 2i4-DICHLOROPHENOL24 446 1.2i4-TRICHLOROBENZENE29 439 NAPHTHALENE26 479 4-CHLOROANILINE27 434 HEXACHLOROBUTADIENE2B 608 P-CHLORQ-M-CRESOL29 477 2-METHYLNAPHTHALENE30 439 HEXACHLOROCYCLOPENTADIENE31 611 2, 4.6-TRICHLCROPHENOL32 626 2, 4, 9-TRICHLOROPHENOL33 «D10-ACENAPHTHENE (IB)34 416 2-CHLORONAPHTHALENE39 479 3-NITROANILINE36 429 DIMETHYLPHTHALATE37 402 ACENAPHTHYLENE38 428 2,6-DINITROTOLUENE39 478 2-NITROANILINE40 401 ACENAPHTHENE41 609 2i 4-DINITROPHENOL42 607 4-NITROPHENOL43 476 DIBENZOFURAN44 427 2,4-DINITROTOLUENE49 424 DIETHYLPHTHALATE46 417 4-CHLOROPHENYL PHENYL ETHER
10
NO NAME47 432 FLUORENE48 480 4-NITRQANILINE49 604 4.6-DINITRO-O-CRESQL90 443 DIPHENYLAMINE (N-NITROSO)91 430 1.2-DIPHENYLHYDRAZINE (AZQBENZENE)92 #467 D10-PHENANTHRENE (IS)93 414 4-BROMOPHENYL PHENYL ETHER94 433 HEXACHLOROBENZENE99 609 PENTACHLOROPHENOL96 444 PHENANTHRENE97 403 ANTHRACENE98 426 DI-N-BUTYLPHTHALATE99 431 FLUORANTHENE60 «499 D12-CHRYSENE (IB)61 449 PYRENE62 404 BENZIDENE63 419 BUTYLBENZYLPHTHALATE64 423 3.3'-DICHLQROBENZIDINE69 409 BENZO(A)ANTHRACENE66 413 BI8(2-ETHYLHEXYL)PHTHALATE67 418 CHRYSENE68 429 DI-N-OCTYLPHTHALATE69 »D12-BENZO(A)PYRENE (IB)70 407 BENZO(B)FLUORANTHENE71 409 BENZO(K)FLUORANTHENE72 406 BENZO(A)PYRENE73 437 INDENO<1,2.3-C,D)PYRENE74 419 DIBENZO<A, H)ANTHRACENE79 408 BENZO(O.H. DPERYLENE76 619 2-FLUOROPHENOL (SURROGATE)77 D9-PHENOL (SURROGATE)78 447 D9-NITROBENZENE (SURROGATE)79 448 2-FLUOROBIPHENYL (SURROGATE)80 TRIBROMOPHENOL (SURROGATE)81 D10-PYRENE (SURROGATE)82 D14-TERPHENYL (SURROGATE)
NO fl/E 8CAN TIME REF RRT METH AREA(HGHT) AMOUNT XTOT1 190 828 10:21 1 1.000 ABB 37969. 40.000 NO 4.612 NOT FOUND3 94 789 9:92 1 0.993 A BV 7808, 7.671 NO 0.4 NOT FOUND9 93 796 9:97 1 0.961 A BV 326421. 327.408 NO 37.7.6 NOT FOUND7 NOT FOUND8 146 831 10:23 1 1,004 ABB 2009. 2.338 NO 0.279 NOT FOUND10 146 868 10:91 1 1.048 ABB 487. 0.660 NO O.OB11 108 906 11:19 1 1.094 ABB 1022. 1.890 NO 0.2112 NOT FOUND13 108 937 11:43 1 1.132 A BV 13302. 21.642 NO 2.14 NOT FOUND19 NOT FOUND16 NOT FOUND17 136 1099 13:41 17 1.000 ABB 79104, 40. fcbOlttfUO 4.6118 NOT FOUND •
NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT19 NOT FOUND20 NOT FOUND
A 21 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOUND29 128 1099 13:44 17 1.004 ABB 3492. 1.931 NC 0.1826 NOT FOUND27 NOT FOUND28 107 1249 19:34 17 1.137 A BV 1014. 1.613'NO 0,1929 NOT FOUND ' '30 NOT FOUND31 NOT FOUND - •32 NOT FOUND33 164 1491 1B:3B 33 1.000 ABB 32632. 40.000 NO 4.6134 NOT FOUND39 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND49 149 1621 20:16 33 1.087 ABB 1820. 1,901 NO 0.1746 NOT FOUND47 NOT FOUND
(*H 48 NOT FOUND49 NOT FOUND90 NOT FOUND31 NOT FOUND92 188 1823 22:47 92 1.000 A BB 91333. 40,000 NO 4.6133 NOT FOUND34 NOT FOUND99 NOT FOUND96 NOT FOUND97 NOT FOUND98 149 1996 24:97 92 1.099 A BB 822. 0.3B4 NO 0.0499 NOT FOUND60 240 2430 30:22 60 1.000 ABB 24771. 40.000 NO • 4.6161 NOT FOUND62 NOT FOUND63 NOT FOUND64 NOV FOUND69 NOT FOUND66 NOT FOUND67 NOT FOUND68 149 2612 32:39 60 1.079 ABB 2114. 1.491 NO 0.1769 264 2719 33:99 69 1.000 A BB 18833. 40.000 NO 4.6170 NOT FOUND71 NOT FOUND72 NOT FOUND73 NOT FOUND74 NOT FOUND .
00311780
79 NOT FOUND76 112 999 7:29 1 0.723 A BV 28391. 44. 633 N8 9.1777 99 787 9:30 17 0.719 A BV 22967. 28. 091 NO 3.2478 82 990 11:92 17 0.868 A BV 2442. 3. 174 NO 0.3779 172 1348 16:91 17 1,231 ABB 47911. 41. 980 NO 4.84BO 330 1673 20:99 33 1.122 ABB 9821. 49. 810 NO 9. 2881 212 2149 26:49 60 0.883 A BV 93941. 49. 999 NO 9.7682 244 2202 27:31 92 1.208 A BB 38732. 49.863 NO 9.29
NO RET(L) RATIO RRT(L) RATIO AUNT AMNT(L) R. FAC R. FAC(L> RATIO1 10:21 1.00 1.000 1.00 40.00 40.00 1.000 1.000 1.002 4: 14 0, 409 90. 00 0. 6373 9:91 1.00 0.992 1.00 7.87 90.00 0.469 -1.049 0,164 9:43 0.940 90.00 .0.9389 9:96 1.00 0.960 1.00 327.41 90.00 6.878 1.090 6.996 9: 96 0. 960 90. 00 0. 7727 10:14 0. 989 90.00 0.8278 10:23 1.00 1.004 1.00 2.34 90,00 0.042 0.903 0.099 10:93 '1.092 90,00 0.41410 10:91 1.00 1,048 1.00 0.66 90.00 0.010 0.778 0.0111 11:19 1.00 1.093 1.00 1.89 90.00 0.022 0. 982 0.0412 11:19 1.093 30,00 0.20113 11:42 1.00 1.130 1.00 21.64 90.00 0.280 0.648 0.4314 11:40 1.128 90.00 0.10719 11:37 1.122 90.00 0.32816 11:33 1.192 90.00 0.34117 13:41 1.00 1.000 1.00 40.00 40.00 1.000 1.000 1.0018 12:39 0.920 30.00 0.64919 12: 46 0. 933 90. 00 0. 17120 13:04 0.999 90.00 0. 28921 13: 19 0. 974 • 90. 00 0. 4B222 13:44 1.004 290.00 0.16423 13:26 0,982 90.00 0.24124 13:37 0.999 90.00 0.31729 13:49 1.00 1.009 1.00 1.93 90.00 0,039 1.140 0.0326 14:11 1.037 249.99 0.029 \27 14:19 1,047 90.00 0.19128 19:33 1.00 1.136 1.00 1.62 90.00 0.010 0.317 0.0329 19:41 1.146 90.00 0.22930 16:21 1.199 90.00 0.07231 16:37 1,214 90,00 0.16232 16:43 1.221 249,99 0.149'33 18:38 1.00 1.000 1.00 40.00 40.00 1.000 1.000 1.0034 17:01 0.913 90.00 1.32239 17:33 0.942 249.99 0.40736 16:14 0.979 90.00 1.29337 18:11 0,976 90.00 1.18038 18:23 0.987 90.00 0.24739 18:3640 18:4341 19:0142 19:2443 19:1144 19:2749 20:16 1.00
.46 20: 17 .
000 249.99 0.012003 90.00 1.194020 249.99 0.066041 123.00 0.111030 30,00 1.667044 90.00 0.334088 1.00 1.90 90.00 0.049 1.486089 90, 00 0. 489
ND RET.L) RATIO RRT(L) RATIO ft* AMNT<L) R.F* H- '«£>47 20:10 1. 088 M9 w 0.00848 20: 2B 1-099 _^ £ 0.116
S SiS !:iS BS '?.» .§_ SS LOO I'.OOO 1.00 40,00 JJ 00 1.000 ..000 LOO93 21: SB 0.990 |_; OQ 0.29794 21:96 0.963 ™ Q0 0.11399 22:31 0. 9BB ™ ~ 1..8621_ 8a:9l 1-003 =°;°° 1/017'97 88:98 1-008 ™ 00 0_ 013 _. 666 0.019B 24:97 1.00 1.099 1.00 0.38 w. w _ x OB199 26:13 »• »« , „ 40 __. 40 00 1.000 .1.000 1.0060 30:22 1.00 1.000 1.00 40.00 40. uu ^ 61 86:92 0.884 "' 0.01068 30:01 0.908 =°;™ Q. 97963 89:10 0.960 « _„ 0.02964 30:31 1.009 00 1,49069 30:20 0.999 ™'VQQ 1,484
67 30:27 1.002 '°'_2 0 06B _/ 393 0.03
SS !:S tS tS iS SS t« _« «--72 34:03 1.002 B- Q0
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E. TCDD Chromatogram(s)/Quantltatlon ReportInstead of the QC chromatogram required In the contract, the TCDD extract Is analyzedby GO/MS, and the RIC, EICP, and mass chromatogram Is Included, as wall as theautomatic quantltatlon report, An Internal standard, carbon- 13-labeled 2,3,7,8-TCDD, laused for quantltatlon of surrogate and any native which might be present, If the presenceof an Interference Is detected, an external standard calculation la used, If the presence ofnative 2,3,7,8-TCDD Is detected, the Sample Management Office Is Informed so furtheranalysis can be performed,
010228
003X*7
PROCEDURE'. RK DIAGNOSTIC REPORT 2/10/84 1:34'. 53DATA FILE'. TC019247C05INFERENCE'. TC~ METHOD) TC INITIALIZATION OPTION; 2 PROCESSING OPTIONi 3
REPORT'. TC9
< —— STANDARDS ——— >< —— PLUS UNKNOWNS —— >< - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN
3 8 2 7 3 7 7 1 3 * TCB/TCU
7 COMPOUNDS PROCESSED* 7 FOUND
< COMPOUND X —————-—'-- SEARCH ———————— X SAT X- -———— CHRO ————— 3'NO LIB ENTRY REF PRED BEL DELTA PEAKS FIT PEAKS H/E • TOP DELTA PEAKSi TC 1 707 706 707 i 3 B32 332 707 . -2 TC 2 665 669 664 -i i 9913 TC 3 665 664 664 . 1 9914 TC 4 665 664 664 . 1 9915 TC 5 70B 707 707 . 1 6906 TC 6 70B 707 707 . 1 6907 TC 7 70S 707 707 . 1 930
320 664 13-2 664 . i257 664 . 1320 706 -1 2322 707 12S7
010228
MEAD COMPUCHEMQUANTITATION REPORT FILE'. TC019247CC5
'. TC019247C05, TI/10/84 1'.14'.00
SAMPLE: 2/90 UL CC»19347<EPA»R3672 1-26) OUA «BSUBMITTED BY: 5 ANALYST', 763
AMOUNT-AREA*HCHT) * RF.F, AMNT/(REF. AREA(HCHT)* RE8P. FACT)RE8P. FAC. FROM LIBRARY ENTRY
NO NAME1 »13C12-2,3,7, B-TCDD(INT_RNAL STANDARD) ... .2 1. _» 3.4-TCDD3 -,2,3.4-TCDO4 1, a 3,4-TCDD5 2,3.7.B-TCDD6 2,3.7,8-TCDD7 2, 3, 7. B-TCDD
NO M/E SCAN TIME REF RRT METH AREA<HCHT> AMOUNT XTOT1 332 707 15:55 1 1.000 A BV 1356360. 800,000 PC/UL 30.162 320 664 15:24 1 0.967 A BV 1593760. 1B9.663 PC/UL 26.603 322 684 15:24 1 0.967 A BV 19BSB30. 1B7.995 PC/UL 28,284 257 664 15:24 1 0.967 A BB 922667. 79.060 PC/UL II 925 330 706 19:53 1 0.999 A»VV 22145. & 220 PC/UL 0.496 322 707 19:59 1 1.000 AW 30734. a 612 PC/UL 0.547 NOT FOUND
___« R_T»L> RATIO RRT ID RATIO AUNT AMNT(L) R, FAC R, FAC (L) RATIO"l 15:56 100 1.080 100 200.00 200.00 1.000 1.000 1.00 .
2 15'.-9 1.00 0.966 100 169.66 200.00 1173 1,237 0.953 15:25 100 0.966 100 167.59 200.00 1462 1559 0.944 15t 26 100 0.969 100 79.06 200.00 0.679 1716 0.405 15136 100 1,000 100 a 22 200.00 0.016 1013 0.026 15;S6 1,00 1.000 100 3.61 200.00 0.023 1253 0.027 15:56 1.000 200.00 0.561
010229
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F. Pesticide Chromalogram(a)/Quantltatlon ReportChromatograma from the packed and capillary column QC analyses of pesticide fractionsare Included, Where the retention time Indicates the presence of a pesticide on the HSLlist In the sample, It Is confirmed on an alternate column, If the concentration la highenough, GC/MS confirmation Is provided and documented with a spectrum, as describedIn the contract, Exhibit D, page 8 of 70, sections 1.1 • 1,2,
010231
V
flMPLITUDE x.2S uV-seconds (Enlarged x 41.SU
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s1 010232
26
Report. 3077.21 Channel. 2 C$2333 R3672Sanple. PP 19347 • Tnjflcted at 8.B6.44 ON JAN 26, 1984
%>TJ) Method. PAKflS 8nq. 8EQ.20 3uhsq/3anpi J/34 Bill 34Si-width MV/Min Delay Mln-Ar fiwnch,500 ,3(IQ 0,0(1 . 20 AutoSuD-Unk j)MT T.D-I.MX R"f"8IW XRTU %Dll-f Iso
Actual run tine. 25,017 Minutes
RT XTM Factor Area UC/HL Nane •
.lOOOOEtOl 214969. SB 214969,370
.lOOOOEtQl 11601. SB 11601.T~
.10000E+01 2192. " "•"• '
.100QOE+fll 26472,,lQOOQE+fl1, 1528..iO.QOOE+fl.l 1573?,100ROE+01 2683.IOOOOE+01.10000E+01,100001,10000-i+fii_ _ _ jj -tOl;i°0000ttoi 5237; SB 5.36:641,10000F-+fll 2225. 8J ?Il5.469.10000E+01, 6353. §S 6353.063.lOOOOE+Qi 12982. 8) 12982.344
_. ...._ .10000E+01 20. SJ 20.180bO 12,34 .100001+01 a??B5. SB 29985.375
_, 32 13.40 .lOOOORtOt 4013. SB 4012.0633,01 14. '31 .10000E+Q1 1994. SB 1994,4693,30 15.66 • .lOOOOFl+Ot 418. SB 418.219, . . . .3,51 16.66 .lOOQOEtfll 5752. SB 5752.000, . . . .4 64 22.07 lOOOOE+Ol 6390. 8B 6390.438S. 46 25.94 ,10765E-(5 25191 . SB ,027 ENDQ3ULFAN I6,31 30.00 8029BE-I6 1131, SB .001 PP'DDE
418.752..000
.438
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.100QOE+01,'.71?8l-06 SA373, SB ".016 »DBR
Total Aroa = 491365, Total UG/ML «= 56373.000Proces.ed data file. P2Q34 Raw data film R2034
010233
RHPLITUDE x.25 uV-s»conds (Enlarged x 3.Z3)yg M ff* <D"* O O S>H, (B w O3» o o o
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010234
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RT ITM Factor
lOOUUbtUl *,-,,«, _,, _. .IOOOOF.+01 208386. 81 208385.750lOOOOEtOl S1B03, 81 21802,50041101E-Q7 291502, 81 .012 DELTA BHCIOOOOE+01, 19164. 81 19163.750lOOOOEtQl 89924, 8H 89924,500tnnnriE+IH 21304, SH 21304.000-.-.— „,, -,*CLIC cnn1 ,IQOOOEtOI. 81304, 84 21304.00IDOOOEtOl 345635, 81 345635.500OE+01 201363, 81 201362.500.lOOOOE+01:iOOOQF.+01
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104925.'000_..... -„„w$&-bbiaa.34810 . '/su.017 HEPTACHI.OR40617.375110474,750179468.000
1! Ii ***ill.3 B5
1 18.31 72,75 .10000E+01 76698, SU 76698,50019.1576,08 .10000E+01, 7568B, SB 75688,00020.39 81,01 .10000E+01 114)49. BB 114149,50020,74 82,41 .IOOOOE+01 67417, SB 67417,00020,9783,34 ,IOOOQF.+ 01 119369, SU 119269.250
tm\?.i.Zi 84,28 ,lOOOOE+Ot 120847, SU I!20fl47.250~2i.44 85,17 .10000E+01 115803, SU 115803.000
21,74 86,39 , lOOOOE+Ol 181,482, SU 1B.14B1.75021,90 87.00 ,iflflOOE+fll 769BO. SU 76979,87522 04 87 56 IOOOOE+01 141623 SU 141622:00022.51 89,45 .lOOOOE+Ol 105032. SU 105032,500a;*.4J 23'9? .iflOflOE+01 110306, SU 110306.50023.70 94,16 .10QOOE+U1 93496, SU 93496,25023.9995.32 .1QOQOE+01 76819, SU 76819.0002.4,60 97,73 .1QOOOF.+01 81237, SU 81237.00024.90 9a:?S .lOOOOE+fll 90SB2. SU 90282.000§517105 00 Ji096E-05 1SS75S SU ——173 tDBC25.33100 66 .lOOOOE+01 113772. SU 113772,5005.57101,61 .lOOOOE+fll 55353. SU 55353.000 - '3.76102,37 ,10000Ef01 606341, SU 606341,000' ~'03 26 .1QOOOE+01 85964, SU 85963.750
- - .lOOOOE+Ol 77232, SU 77232.250.IQOOOE+Ol 84736, SU 84736.500.IOOOOE+01 74779, SU 74778.750.IQOOOE+Ol 55140, SU 55140.000_.........- -x& ....a: ssuu immi9fl:§66iiii.-4677 mm ?»• it 9«:25io0
Total Arta * 17411120, Total AREA X ° 94430,250Procesiid data file. P9225 Raw data file. R9225
01023
88
ft
G. Work SheetsWorksheets lor each type ol fraction are Included, There are extraction worksheets,describing which samples are processed In a batch, and listing the associated reagentblanK, date, analyst, standards used, and conditions, Analysis worksheets are used at theInstrument station to denote condition o) extracts, (He names, standards used, dilutions,etc, Compound lists are the wlthln-lab reporting forms used by the analysts to record hitsand perform calculations to determine concentrations of compounds, Data Is transferredfrom compound lists to EPA forms (Organic Analysis Data Sheets), When secondary Ioncalculations or other adjustments are necessary, these calculations are performed onseparate pages and Included with the associated worksheets to document thecalculation,
M
010237
j
CASE * 2315 DATE DUE 3
HORKSHEET CompuChem * / 9 3 7 EPA I £34Instrument Code ___ 233 ___Compound List _____________
———————— ~MEDIUM LEVEL LIQUIDDeliverable* Code 069 SUIT Std List 3B3 Int Std List 002
QUA* H" II Disk f ____i__Jll. GC/H5 Analyst -&r%~' S T\BFBLot* /oT3? _______ Shift /f Date T7-fr7&*Standards File C rMlfi/9 -c^e.ioflu Results Verified ____ HardcopledBlank File 6£-¥otSye./7 CctM.mcnSUIT Std I 3B3 Lot | A>4# 10 9°iuInt Std I 002 Lot! X6rfr3tSmple Volume Used StodfrJ /O .' /
1. 10 Peak Se(irch Required:2. I of Peaks Found I
\ 3, EPA, sign Chronicles _____ (Initials)Coiments:
Checked by J _ _ _ _ D a t eSecondary Analysis Required
Initiator Date
• 1 XSURROGATE:J____I I /^sl i- .BDTT
12/83
CASE f .agfl?,_____ UUt IMIt' , . • • •
1 '
ft SEHI'VOLATILES1C7HS HURHSHEET
tLOH LEVEL LIQUID ,<'.'Del Iverabli Code - 069
SAS EPA itBlink Associated with Cases ___COMHEHTS:
/ *2n 0s.COMPUCHEHf \°[ ?- uSampletrioTbde (
f fr
iDoZpt :1)25
Instrument code .39Compound ListSurroaite Std. " — 3Internal Std. L1sl —— I
V P— . — _ — __-
82.3 (added Sy cc/ns)
mmmmm
Original BC/MS Analysis: Extraction Oatc of Vial Analyzed ____BN Vol x_?0 ul Acid Vol /00 ulInt Std. Lotf /pl'OInt. Std. Vol. Added jfInJected Sample Volume /
Standard Lot 1 /c??/Standard F11e /(J ;?/c/'4- DiskOKA* '-V- Dlskf '$6
» Analyst -r*^
Second GC/HS Analysis:Sample Vol. Injected
Standard Lot fStandard File OlsklOHA f Disk 1Analyst
\
1. 20 Piak Search Results \2. 1 of Peaks Found ^ _JLcomrs: /
Initial ReviewFinal Review
•
ulul
DFTPP Lot f /#?( /95} DFTPP Flit pHwoi-il
Date t/3//g"/ •'
//./ Dlskl/ )
LJ Dilution ( :1) [j Relnjectlonul
DFTPP Lot ff) OFTPP Flltv
Date \\
Surrogates: j jffl
)h Date
Disk! )
U
S/fl// Dat,/// ..
r'a\\'> n-*8
/ oiu^jytii-j£*a vp
OA^*1 "fl
CASEI JS33 DATE DUEft TCDD
WORKSHEET • •
LOH LEVEL LIQUID '' 'Deliverable Code - 069
SAS EPA IfBlank Associate with Case ___COWENTS:
Analysis,Instrument I "( }
IT 7 " ^
.COHPUCHEHf /q<3/'?Sample Prep code alinsirument code " 116
. Compound List ~ "63iurroQiw std. ~~36Ainternal std. List 028.
——— , ——— . ——— .. — ._
Instrumentation CodeAnalyst 7.7
Calibration Std. Lot 1 f?frPiss 1 Piss 2
Dite ___ ___Log Reference t _ __ _ __Commits:f <>
Area Count TCDD Surrogate StandardArea Count Surrogate In Simple
Chicked By
Piss 3 Piss 4
unitsunits
Recovery / I
^ Diti *•/(*/#
s 010241
00?1F2
CASE f oWiK DATE DUi.• . ~ '" PESTICIDES
EXTRACTIONS GCWORKSHEET
'|fi|OH LEVEL WATER - DELIVERABLE CODE
SASBlank Associated with Case _ ______COMMENTS:
Analysis, No FlorlsllInstrument 1 o. tfCalibration Std. Lot t /2e><j
Pass 1 Pass 2Date fitflgf tfclffLog Reference t _____ _ __
Comments : ^
' Florlsll <Sample VolumeReagent SetDate Florlsll Complete _____Final Volume I. II.
Analysis, 3 ExtractsInstrument fCalibration Standard LotJK.** i. si/. .Log Reference c//? >
II. Vfito"I- ____ .
Checked By
CompuChem l/ ?,sample Prep CodeInstrument Codecompound List
. surrogate sunolrJ
EPA 1 £i_j /_? t?^^ ^ ^ ^ ^ ^ B ^ ^ ^ mm^mmmemm
Instrumentation CodeAnalyst tTf?
Pass 3 Pass •»
" Florlsll _
Sample Prep CodeTechnician
III.
Instrumentation Code
———— ————
/".
———— ————
Date
7"7——— •••4011994
JbB-Pest: dbt-iiuu
- —— —
•'
___ yes
w e&f
010242
88
,;. . ....TV;?"''WriS*'.- .••: . .*•:... ..•,&~; -.r. *:.:..v;v....^Si'., •••-',•„..•..••...........,•'.:*->»Mi,jfg v JM i" .1 -- -
*KI» -ME «/y
tapUMlgtit (gl
.**',.
X
S
AWL
M
-M( IWTOgat* m-3f' ttm+lto RttlTMa.
a<-mmrnt CaMttf fitly*.7
.35
•o
01CJ . . . . . . . . . . . . . .
_\
\ f If
s"?3
•
I
-In fi
COHPUCHEH NO. __•___ DATE ______ 1 of 1COMPOUND LIST NO. ____ ————— ——————
———— IDENTIFIER VOLATILES — MEDIUM LEVEL LIQUID
M QUANT.COMPOUND REPORT CORRECTION RESULTS DETECTION
COUNTER NUMBER COMPOUNDS_____ _VAL_UE_ x FACTOR • (ug/1) l.IMIT(ug/lj
2. 221 CHLOROMETHANE ............3. 220 BROMOMETHANE .............4. 231 VINYL CHLORIDE ...........5. 209 CHLOROETHANE..............6. 222 METHYLENE CHLORIDE .......7. 252 ACETONE ..................8. 201 ACROLEIN .................9. 202 ACRYLONITRILE ............10. 230 TRICHLOROFLUOROMETHANE ...11. 254 CARBON DISULFIDE .........12. 216 1,1-DICHLOROETHYLEhE .....13. 214 1,1-DICHLOROETHANE .......14. . 226 TRANS-1,2-DICHLOROETHYLENE15. 211 CHLOROFORM ...............16. 215 1,2-DICHLOROETHANE .......*17. 253 2-BUTANONE ...............18. 227 1,1.1-TRICHLOROETHANE ....19. 206 CARBON TETRACHLORIDE .....21. 257 VINYL ACETATE ............22. 212 BROMOD1CHLQROMETHANE .....23. 217 1,2-DICHLOROPROPANE ......24. 250 TRANS-l,3-DIChLOROPROPENE.25. 229 TRICHLOROETHYt.ENE ........26. 203 BENZENE ..................27. 228 1,1,2-TRICHLOROETHANE ....28. 218 CIS-1,3, DICHLOROPROPENE..29. 208 DIBROMOCHLOROMETHANE .....30. 210 CHLOROETHYLVINYL ETHER....31. 205 BROMOFORH ................32. 256 4-METHYL-2-PENTANONE .....34. 255 2-HEXANONE ...............35. 223 1,1,2,2-TETRACHLOROETHANE.
* ' 010248PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OF THE COMPOUND LIST! 11
COMPUCHEM NO. _____ DATE ______ 2 of 2HPOUND LIST NO. ____ ' —————
———— IDENTIFIER VOLATILES - MEDIUM LEVEL LIQUID
QUANT.COMPOUND REPORT CORRECTION RESULTS DETECTION
COUNTER NUMBER COMPOUNDS VALUE x FACTOR • lug/1) LIMIT! ug/1)
36. 224 TETRACHLOROETHENE.37. 225 TOLUENE...........38. 207 CHLOROBENZENE.. ...39. 219 ETHYLBENZENE .....40. 251 STYRENE..... ......41. 239 0-XYLENE,,.. ......
QUANT.COMPOUND SURROGATE REPORT AMOUNT I S RECOVERYNUMBER COMPOUNDS VALUE SPIKED RECOVERY HINDOH
258 D4-1.2.DICHLOROETHANE (SURR) -*\\\ 20.0 lao (90-130)*233 DB-TOLUENE ISURR").......... a-fl1/ 20.0 /5f \ (84-iu»
BROMOFLUOROBENZENE (SURR).. AJau 20.0 I od (63-127)*
*Adv1sory Limits
CORRECTION FACTOR CALCULATION:
5000 ul '......Volume of sample Analyzed lull •
5000 ul________(Ul)
t I Recovery • Quant. Report Value 1001Mount spued *
JRT010249
•.* it
IPIOTIFIEP.
QUANT.COMPOUND REPORT CORRECTION RESULTS DET. LIR'.T
COURTER NUHBER _COMPOUNSS_____ VALUE X _£MTOR__ • ______ J"9'1)
2 44) N«NITROSOD1KETHYLA«1KE .....3 610 PHENOL ..................... /'•»4 473 ANILINE ...................S 411 BlS(2-CHLOROETHYLttTHER .... /3.0Q.6 601 MHLOROPHENOL ............7 421 1,3-DICHLOROBENZENE .......B 422 1,4-DlCHLOROBENZENE .......9 474 IEHZYL ALCOHOL ............10 420 1,2-DICHLOROBENZENE........11 620 2'HETHYLPHENOL ............12 412 BISI2.CHLOR01SOPROPYHETHER ____13 622 4-METHYLPHENOL ............. l<o,14 442 N-NITROSO-Dl-N-PROPYLAHINE .15 436 HEXACHLOROETHANE ...........16 440 NITROBENZENE ...............18 438 ISOPHORONE .................19 606 2-N1TROPHENDL ..............20 603 2.4-D1METHYLPHENOL .........21 410 «S(2.CHLOROETHOXY)METHANE . __22 625 IENZ01C ACID ............... _____23 602 2,4'DICHLOROPHENDL .........24 446 1,2,4-TRlCHLOROBEHZENE .....25 439 NAPHTHALENE ................26 475 4-CHLOROANIL1NE ............27 434 KEXACHLOROBUTA01ENE ........28 608 P-CHLORO-M-CRESOL ..........29 477 2-nETHYLHAPTHALENE .........30 435 HEXACHLOROCYCLOPENTADIENE ..31 611 2,4,6-TRlCW.OMPHEHOL.......32 626 2,4,5-TRlCHLOROPHENOL ......34 416 2.CKLOROHAPHTHALENE ........35 479 MHTROADILINE .............36 425 DIHETHYLPHTHALATE ..........37 402 ACENAPHTHYLENE .............38 428 2,6*DIN1TROTOLUENE .........
PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON THIRD SHEET OF THE
it 8P
40 401 ACENAPHTHEN:41 605 2,4-DINITROPHENOL42 .607 .'44ITROPHENOL43 476 D1BENZOFURAN .....................44 427 2.4.DIN1TROTOLUENE................45 424 DIETHYLPHTHALATE ................46 417 4.CKLOROPHENYL PHENYL ETHER.......47 432 FLUORENE .........................48 ' 480 4.NITROAN1L1NE49 604 4,6.DINITRO'0*CRESOLSO 443 OIPHENYLAM1NE (N-NITROSO)51 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE)63 414 44ROMOPHENYL PHENYL ETHER .......54 433 HEXACHLOROBENZENE65 609 PENTACHLOROPHENOL66 44« PHENANTHRENE57 403 . .ANTHRACENE56 426 Dl-N-BUTYLPHTHALATE59 431 FLUORANTHENE ........61 445 PYRENE ..............62 404 BENZ1DINE ...........63 415 BUTYLBENZYLPHTHALATE
COMPOUND LIST NC. ___——— IDENTIFIER SEH1-VDLAT1LES - LOK LEVEL LIQUIDt • mmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmt
QUANT.COMPOUND REPORT CORRECTION RESULTS DET UP"
'^COUNTER NUMBEP COMPOUNDS_____ . VALUE x FACTOR •lug/I) (ug/11
39 47B 2.NITROANILINE ................... ____ I 3.V I ___ 100'10'iSD |
100 ,10 !
' 20 I10 j10 ;101002010 ,20101020,10'
ID10104C10;20'10
W i10 !10'2°:2020202020;
64 423 3,3'-DICHLOROBENZIDlNE65 405 BENZO(A)ANTHRACENE ...66 413 B1S(2'ETHYLHEXYL)PHTHALATE67 418 CHRYSENE66 429 DI-N-OCTYLPHTHALATE70 407 BENZO(B)FLUORANTHENE71 40972 406 IENZO(A)PVI_NE73 437 INDENO(1,2,S-C,0)PYREHE ..........74 419 D1BENZO(A,H)AHTHRACEHE75 408 BE«0(6,H,I)PERYLENE ..
(See calculatlons.ind surrogates on back)
18
•COMPUCHEK ND. _____ DATE ______ 3 of
COMPOUND LIST NO. ___ ' ————— ————————— IDENTIFIER SEH1-VOLATILE5 •• LOK LEVEL LIQUID
QUANT.QUANT. REPORT
COMPOUND SURROGATE REPORT AMOUNT ' l" ACCEPTABLENUMBER . COMPOUNP5 VALUE SPIKED RECOVERY RANGE
619 2-FLUOROPHENOL 3£ 604T"7T1 x" (25-115)612 DS-PKENOL . a/ 804 #2- ciwo'r .447 DS-NITMBENZENE /g BO* stf 142-m)446 2-FLUOROBIPHENYL «£ 604 _, ' ?.£ (60-154)626 TRIBROMOPHENOL 2.5 804 SO . (47-I23)«471 OIO-PVRENE 4x so 4 && ( NA )»496 DH-TERPHENYL <^f 804 « _, ^ (S4-iiB)«
*For Advisory Purposes Onlyul.,0 . HOI
CORRECTIOK FACTOR CALCULATION;
DilutionS-i „ TolT Sl.Wunin «
(El)
Final wtractlen veliimeffil ) 1000 nilimi Tor Adc, iini Tor w * voi . Hitipit wtncteo IIM ) * Factor » 2
KPORT »F«f 8>1KEP COHVERSIOJLQCMi
100 uL -—•13JRT 11/63
010252
' COMPOUND LIST NO. ___ ————— ————i , _ . ——— IDENTIFIER SEM1-VOLAT1LES - LOK LEVEL LIQUID
QUANT.COMPOUND REPORT CORRECTION RESULTS DET. LIMIT
COMPOUNDS_____ VALUE n FACTOR « (ug/1) (ug/1)
2 441 N-NJTROSOD1METHYLAMINE .....3 610 PHENOL .....................4 473 ANILINE ....................5 411 BIS(2-CHLOROETHYL)ETHER ....6 601 2-CHLOROPHENOL .............7 421 1,3-DICHLOROBENZENE ........8 422 1,4-DICHLOROBENZENE ........9 474 BENZYL ALCOHOL .............10 420 1,2-DICHLOROBENZENE.........11 620 2-HETHYLPHENOL ............12 412 BIS(2-CHLOROISOPROPYL)ETHER13 622 4-METHYLPHENOL .............14 442 N-NITROSO-DI-N-PROPYLAMINE .15 436 HEXACHLOROETHANE ...........16 440 NITROBENZENE ...............18 438 1SOPHORONE .................19 606 2-NITROPHENOL ..............20 603 2,4-DIMETHYLPHENOL .........21 410 BIS(2-CHLOROETHOXY)METHANE .22 625 BENZ01C ACID ...............23 602 2,4-DICHLOROPHENOL .........24 446 1,2,4-TRICHLOROBENZENE .....25 439 NAPHTHALENE ................26 475 4-CHLOROAN1LINE ............27 434 HEXACHLOROBUTADIENE ........28 608 P-CHLORO-M-CRESOL ..........29 477 2-HETHYLNAPTHALENE .........30 435 HEXACHLOROCYCLOPEHTADIENE ..31 611 2,4,6-TRKHLOROPHENOL.......32 626 2,4,5-TKICHLOROPHENOL ......34 416 2-CHLORONAPHTHALENE ........35 479 3-MTROANILINE .............36 425 DIMETHYLPHTKALATE ..........37 402 ACENAPHTHYLENE .............38 428 2,6-OIMITROTOLUENE ......... ___ __.»__ __ 10'
'" 010253PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON THIRD SHEET OF THE COMPOUND LIST!!)
• • Wwi »t wwnwi i itwf -!•>••COMPOUND LIST NO. ___ ————— ——————
——— IDENTIFIER SEMI-VOLATILES •• LOU LEVEL LIQUID
QUANT.; COMPOUND REPORT CORRECTION RESULTS DET LIMIT(•MOUNTER NUMBER COMPOUNDS_____ VALUE x FACTOR •(ug/11 _(_U9/1)
39 478 2-NITROANILINE40 401 ACENAPHTHENE41 605 2,4-DINITRO.PHENOL42 607 4-NITROPHENOL43 476 OIBENZOFURAN44 427 2,4-DINITROTOLUENE.45 424 D1ETHYLPHTHALATE46 417 4-CHLOROPHENYL PHENYL ETHER.......47 432 FLUORENE ......46 480 4-NITROANILINE49 604 4,6-DINITRO-O-CRESOL50 443 DIPHENYLAMINE (N-NITROSO)51 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE)53 414 4-BROMOPHENYL PHENYL ETHER54 433 HEXACHLOROBENZENE55 609 PEHTACHLOROPHENOL56 444 PHENANTHRENE
** 57 403 ANTHRACENESB 426 Dl-N-BUTYLPHTHALATE59 431 FLUORANTHENE61 445 PYREHE ..............62 404 BENZIDINE ...........63 415 BUTYLBENZYLPHTHALATE64 423 3,3'-DICHLOROBENZIDINE65 405 BENZO(A)ANTHRACENE66 413 BIS(2-ETHYLHEXYL)PHTHALATE.67 418 CHRVSENE ..................68 429 DI-N-OCTYLPHTHALATE70 407 BEKZO(B)FLUORANTHENE71 409 BENZOIKJFLUORANTHENE.72 406 BENZO(A)PYRENE .........73 437 INDENO(1,2,3-C,D)PYRENE74 419 D1BENZO(A,H)ANTHRACENE75 408 BENZO(6,H,I)PERYLENE
. (See calculations and surrogates on back)-* 010 54
I*
COMPUCHEM NO. _____ DATE ______ 3 of 3MOMPOUND LIST NO. ___ ————— ————————— IDENTIFIER SEM1-VOLAT1LES - LOU LEVEL LIQUID
QUANT. .QUANT. REPORT
COMPOUND SURROGATE REPORT AMOUNT l" ACCEPTABLENUMBER COMPOUNDS VALUE SPIKED RECOVERY RANGE
619 2-FLUOROPHENOL Vf 80 *T""T) ff°. (25-115)'612 OS-PHENOL in 504 _ yi (is-90 )447 DS-NITMBENZENE i so f ~ & (42-131)448 2-FLUOROB1PHENYL ifr 504 gf (50-154)628 TR1BROMOPHENOL Wfe 604 3* (47-123)*471 D.O-PYRENE ft 504 ~ IQQ ( NA )*496 D.«-TERPHENY'u 50 4 < H (54-118)*
•For Advisory Purposes Only* ' ^u " loos
Final extraction volimtjinl) 1000 ml Dilutiontor MIC, mi for K * «T. sampitrtxtracted vm) * Factor * 2
ANT REPORT AMOUNT SPIKED CONVERSION FACTOR;
TCDD 069 D_AONC»T_C»TC019847CeS
320/382 RATZO:_URftMATB (0. 60 - 0, 94) 0. 79
(0. 67 - 0, B7> 0. 72
-KPARATIB AT _.A»T 5•CAN* PRPM ANAUyTB'.
PMm
ANM.VTI KLUTIB MXTHIN 3 MANBOF XMTBKNM. STANPMO'. PftM
£8
TCDD ton LIVBL UiouxoTC019247COS CDMPUCH«M No, ____L__1_ DATB 02/10/642/50 UL CC(U9S47<EPA*R3672 1-26) OWA «5
EPA SAMPUT. ______-Z<£ CAU NUMMR: .___£-'—
COMPOUND COMPOUND QUANT RBPDRT « COR-BCTZON • RBIUUT DBTBCTSDN LIMITNo. VAL.UB FACTOR <uo/u > <uo/- >469 237B-TCDD a 22 0.0002 BDU - • 0.006 (0.004)
SmmooATB <!. 2» 3» 4-TCDD) RBCOVBRV • (Aurr MBAMMEO / AMT MIHID) t -00%
RBCOVBRV • 75, 95S
COIWBCTXON FACTO-;• (EXTRACT V0_ (ML.) / 0. JL ML> « (1000 ML / VOL BMTRACTBD) * 0, 000E
FACTOR • 0. 0002
NOTB! THB 0. 004 DBTBCTIDN LXMXT I» THB OPTINA4. (100X RBCDVBRV) DBTBCTIDN LIMIT.THB 0. 006 DETECTION JUXMXT » THB RKOVBRV-CORRICT.O.
DBTBCTXON LIMIT.
\s
010S57
COMPUCHEM NO.______DATE_IDENTIFIER PESTICIDES (LOH LEVEL-HATER)
COMPOUND LIST - NO.,____
COHPUCHEMCOMPOUNDNUMBER COMPOUND NAME RESULT
ALDR1N -——-ALPHA-BHC —•BETA-BHC —-'6AKMA-BHC —-DELTA-BHC •••••«—««««-••CHLORDANE ................4,4'.DOT ..........-—..4,4'-DDE —.—•—.—..•4|4 *DDD ••••••'•••>••••••••OIELOR1N —.——......ALPHA-ENDOSULFAN -..-—-BHA-ENDOSULFAN ———
' EHDOSULFAN SULFATE ———
ENDRIN ALDEHVDE — • —'HEPTACHLOR— «— —HEPTACHLOR EPOX1DEPCB-1242 —--—•PCB-'2S4 —..———PCB-1221K8-1232PCB-1248PCB-1260PCB-W16 —— —WKWSW ———
0738 01BUTYL CHLORENOATE (67-114)*
•Advisory Unit
RECJVE5I
GC LABORATORY
CM
EXTRACTION INFORMATION.
Wt. «r vol. of M«pl«_____j_____
portion of wt. OP vol in n-tt/h-pb /ildry wt. correction f-etar
fin.l voluni «f •xtr_ct______nlsdilution <f«ctor»______for run »_
/ for punfor pun •_
___^for run t_
ANALYSTS COMMENTS.
QUALITY ASSURANCE NOTICEsanple * f9l
Surrogate recoveries for the ^ fraction of this sample fell out-side quality control limit* in both the original and repeated extraction*,It w.i ascertained that no errors were incurred from calculations/ instrumentperformance/ surrogate or internal standard solutions/ or sample preparation,Ue have attributed these surrogate recoveries to the particular sample matrix/rather than laboratory error, ' • •
Bob Uhi teheed JMu/l"b-frfQuality Assurance Specialist
QflNH831.20
PI QUALITY ASSURANCE NOTICEsample * l'«tn
Interferences were observed in the quantitation ion for one or more of .the surrogate compounds used to evaluate the volatile fraction of this sample.resulting in recovery outside .quality control limits, Because thei.e inter-ferences arc inherent in the sample matrix/ repreparing and repurging the sampleuill not improve surrogate recovery. For this reason/ we are reporting the datawith this qualifier, . ~ •
Bob UhitehcadQuality Assurance Specialist
OAM13'640130
M
I ' te
