SAFETY DATA SHEET - Roberts HVAC · Product name: 2-Ethylhexanol, 99.5% Issue Date: 04/27/2015 Page...

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow

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SAFETY DATA SHEET UNION CARBIDE CORPORATION

Product name: 2-Ethylhexanol, 99.5% Issue Date: 04/27/2015 Print Date: 04/28/2015

UNION CARBIDE CORPORATION encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.

1. IDENTIFICATION

Product name: 2-Ethylhexanol, 99.5% Recommended use of the chemical and restrictions on use Identified uses: COMPANY IDENTIFICATION UNION CARBIDE CORPORATION A Subsidiary of The Dow Chemical Company 1254 ENCLAVE PARKWAY HOUSTON TX 77077-1607 UNITED STATES Customer Information Number: 800-258-2436

[email protected] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: 989-636-4400 Local Emergency Contact: 800-424-9300

2. HAZARDS IDENTIFICATION

Hazard classification This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Flammable liquids - Category 4 Acute toxicity - Category 4 - Inhalation Skin irritation - Category 2 Eye irritation - Category 2A Specific target organ toxicity - single exposure - Category 3 Acute aquatic toxicity - Category 3 Label elements Hazard pictograms

Product name: 2-Ethylhexanol, 99.5% Issue Date: 04/27/2015

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Signal word: WARNING! Hazards Combustible liquid. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. Harmful to aquatic life. Precautionary statements

Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/ eye protection/ face protection. Response IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of contents/ container to an approved waste disposal plant.

Other hazards no data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms: Xi;R36/38 This product is a substance.


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Component CASRN Concentration

2-Ethylhexanol 104-76-7 > 99.5 %

4. FIRST AID MEASURES

Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin contact: Wash off with plenty of water. Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately. Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Notes to physician: Maintain adequate ventilation and oxygenation of the patient. The decision of whether to induce vomiting or not should be made by a physician. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

5. FIREFIGHTING MEASURES

Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. General purpose synthetic foams (including AFFF type) or protein foams are preferred if available. Alcohol resistant foams (ATC type) may function. Unsuitable extinguishing media: no data available Special hazards arising from the substance or mixture


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Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide. Unusual Fire and Explosion Hazards: Violent steam generation or eruption may occur upon application of direct water stream to hot liquids. Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Do not use direct water stream. May spread fire. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Avoid accumulation of water. Product may be carried across water surface spreading fire or contracting an ignition source. Contain fire water run-off if possible. Fire water run-off, if not contained, may cause environmental damage. Review the "Accidental Release Measures" and the "Ecological Information" sections of this (M)SDS. Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Refer to section 7, Handling, for additional precautionary measures. Keep personnel out of low areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Methods and materials for containment and cleaning up: Small spills: Contain spilled material if possible. Collect in suitable and properly labeled containers. Large spills: Dike area to contain spill. Pump into suitable and properly labeled containers. See Section 13, Disposal Considerations, for additional information.

7. HANDLING AND STORAGE

Precautions for safe handling: Keep away from heat, sparks and flame. Avoid contact with eyes, skin, and clothing. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Conditions for safe storage: Store in accordance with good manufacturing practices. Storage stability

Steel drums. 24 Month

Bulk 12 Month


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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters Exposure limits are listed below, if they exist. None established Exposure controls Engineering controls: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Individual protection measures

Eye/face protection: Use chemical goggles. Skin protection

Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Natural rubber ("latex"). Neoprene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. Examples of acceptable glove barrier materials include: Nitrile/butadiene rubber ("nitrile" or "NBR"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.

Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. Selection of air-purifying or positive-pressure supplied-air will depend on the specific operation and the potential airborne concentration of the material. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate pre-filter.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Physical state Liquid.

Color Colorless

Odor Mild

Odor Threshold No test data available

pH No test data available

Melting point/range No test data available

Freezing point -70 °C ( -94 °F) Literature


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Boiling point (760 mmHg) 184.6 °C ( 364.3 °F) Literature

Flash point closed cup 72 °C ( 162 °F) Tag Closed Cup ASTM D56

Evaporation Rate (Butyl Acetate = 1)

No test data available

Flammability (solid, gas) Not applicable to liquids

Lower explosion limit 0.88 % vol Literature

Upper explosion limit 9.7 % vol Literature

Vapor Pressure < 0.1 mmHg at 20 °C (68 °F) Literature

Relative Vapor Density (air = 1) 4.5 Literature

Relative Density (water = 1) 0.8335 at 20 °C (68 °F) / 20 °C Literature

Water solubility 0.07 % at 20 °C (68 °F) Literature

Partition coefficient: n-octanol/water

log Pow: 3.1 Measured

Auto-ignition temperature 281.9 °C (539.4 °F) Literature

Decomposition temperature No test data available

Dynamic Viscosity 10.3 cP at 20 °C (68 °F) Literature

Kinematic Viscosity No test data available

Explosive properties Not explosive

Oxidizing properties No

Molecular weight no data available

Molecular formula C4 H9 CH(C2 H5) CH2 OH

Volatile Organic Compounds No test data available

NOTE: The physical data presented above are typical values and should not be construed as a specification.

10. STABILITY AND REACTIVITY

Reactivity: no data available Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. Possibility of hazardous reactions: Polymerization will not occur. Conditions to avoid: Exposure to elevated temperatures can cause product to decompose. Incompatible materials: Avoid contact with: Strong acids. Strong oxidizers. Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Carbon monoxide. Carbon dioxide.

11. TOXICOLOGICAL INFORMATION


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Toxicological information on this product or its components appear in this section when such data is available. Acute toxicity

Acute oral toxicity Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. May cause central nervous system effects. LD50, Rat, > 2,000 mg/kg Acute dermal toxicity Prolonged skin contact is unlikely to result in absorption of harmful amounts. LD50, Rabbit, > 2,000 mg/kg Acute inhalation toxicity Prolonged excessive exposure may cause adverse effects. May cause respiratory irritation and central nervous system depression. If material is heated or aerosol/mist is produced, concentrations may be attained that are sufficient to cause respiratory irritation and other effects. LC50, Rat, 4 Hour, dust/mist, 2.17 mg/l

Skin corrosion/irritation Prolonged contact may cause moderate skin irritation with local redness. May cause more severe response on covered skin (under clothing, gloves). Serious eye damage/eye irritation May cause severe eye irritation. May cause severe corneal injury. Sensitization Did not cause allergic skin reactions when tested in humans. For respiratory sensitization: No relevant data found. Specific Target Organ Systemic Toxicity (Single Exposure) May cause respiratory irritation. Route of Exposure: Inhalation Target Organs: Respiratory Tract Specific Target Organ Systemic Toxicity (Repeated Exposure) In animals, effects have been reported on the following organs: Blood. Kidney. Liver. Spleen. Carcinogenicity In laboratory animals, evidence of carcinogenic activity was observed. The observed tumors do not appear to be relevant for men.


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Teratogenicity Has caused birth defects in laboratory animals only at doses toxic to the mother. Has been toxic to the fetus in laboratory animals at doses toxic to the mother. These concentrations exceed relevant human dose levels. Reproductive toxicity No relevant data found. Mutagenicity In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative. Aspiration Hazard May be harmful if swallowed and enters airways.

12. ECOLOGICAL INFORMATION

Ecotoxicological information on this product or its components appear in this section when such data is available. Toxicity

Acute toxicity to fish Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested). LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 32 - 37 mg/l Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), 48 Hour, 35.2 mg/l, OECD Test Guideline 202 EC50, Daphnia magna (Water flea), 48 Hour, 39 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants ErC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate inhibition, 11.5 mg/l, OECD Test Guideline 201 Toxicity to bacteria EC50, Bacteria, 16 Hour, 256 - 320 mg/l

Persistence and degradability

Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent biodegradability). 10-day Window: Pass Biodegradation: 68 % Exposure time: 17 d Method: OECD Test Guideline 301B or Equivalent 10-day Window: Not applicable Biodegradation: > 95 % Exposure time: 5 d Method: OECD Test Guideline 302B or Equivalent


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Theoretical Oxygen Demand: 2.95 mg/mg Chemical Oxygen Demand: 2.70 mg/mg Biological oxygen demand (BOD)

Incubation Time

BOD

5 d 26 - 70 %

10 d 75 - 81 %

20 d 86 - 87 %

Photodegradation Sensitizer: OH radicals Atmospheric half-life: 9.7 Hour Method: Estimated.

Bioaccumulative potential

Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5). Partition coefficient: n-octanol/water(log Pow): 3.1 Measured

Mobility in soil

Potential for mobility in soil is low (Koc between 500 and 2000). Partition coefficient(Koc): 800 Estimated.

13. DISPOSAL CONSIDERATIONS

Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device.

14. TRANSPORT INFORMATION

DOT Proper shipping name Combustible liquid, n.o.s.(2-Ethylhexanol) UN number NA 1993 Class CBL Packing group III

Classification for SEA transport (IMO-IMDG):


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Not regulated for transport Transport in bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code

Consult IMO regulations before transporting ocean bulk

Classification for AIR transport (IATA/ICAO):

Not regulated for transport

This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION

OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Fire Hazard Acute Health Hazard Chronic Health Hazard Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) Section 103 This material does not contain any components with a CERCLA RQ. Pennsylvania (Worker and Community Right-To-KnowAct): Pennsylvania Hazardous Substances List and/or Pennsylvania Environmental Hazardous Substance List: The following product components are cited in the Pennsylvania Hazardous Substance List and/or the Pennsylvania Environmental Substance List, and are present at levels which require reporting. Components CASRN 2-Ethylhexanol 104-76-7 California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances knownto the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute.


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United States TSCA Inventory (TSCA) All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

16. OTHER INFORMATION

Revision Identification Number: 101234144 / A004 / Issue Date: 04/27/2015 / Version: 4.1 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Information Source and References This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company. UNION CARBIDE CORPORATION urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version.

SAFETY DATA SHEET

Date Issued: 2/23/15 Page 1 of 5

SECTION 1 – COMPANY and PRODUCT IDENTIFICATION

MANUFACTURER GARDNER-GIBSON CORPORATION 4161 East 7th Avenue Tampa, FL 33605

EMERGENCY TELEPHONE NUMBER 1-800-424-9300 CHEMTREC Product Class

Product Information 813-248-2101

gardner-gibson.com

Acrylic Latex Sealant used in building construction. Trade Name

Product Code Number 5019-1-61

Gardner A5 Siliconized Acrylic Sealant - White

SECTION 2 – HAZARDS IDENTIFICATION

Product Classification: No need for classification according to GHS criteria. Effects of acute toxicity: EYES: Direct contact may cause irritation. SKIN: May cause irritation to sensitive skin or open wounds. INHALATION: May cause irritation to respiratory passages. INGESTION: May cause nausea.

Precautions: Wear suitable protective clothing, gloves and eye protection. If the product adheres to exposed skin, irritation may occur when the product dries. Use with local exhaust ventilation. Do not take internally. Wash hands before eating or drinking.

SECTION 3 – COMPOSITION / INFORMATION on INGREDIENTS

There are no ingredients in this product of unknown acute toxicity. N.E. = Not Established N.A. = Not Applicable

INGREDIENT Content (By Weight) TLV PPM

PEL - TWA PPM

Diisononyl Phthalate (DINP) CAS # 28553-12-0 3.0 - 6.0% N.E. N.E.

Mineral Spirits (Stoddard solvent) CAS # 8052-41-3 1.0 - 2.0% 100 100

All nonhazardous ingredients in this waterborne product are trade secret. 92.0 - 96.0% N.A. N.A.

SAFETY DATA SHEET Gardner A5 Siliconized Acrylic Sealant - White Page 2 of 5

SECTION 4 – FIRST-AID MEASURES

Inhalation: If inhaled, remove victim to fresh air and keep at rest in a position comfortable for breathing. If signs/symptoms of difficulty in breathing continue, get immediate medical attention. Skin: Rinse skin immediately with plenty of clean water for 5 to 10 minutes. Remove contaminated clothing. If skin irritation occurs get medical advice/attention. Eye(s): Rinse cautiously with water for several minutes. Remove contact lenses if present and if it is easy to do so. Continue rinsing. If eye irritation persists get medical advice/attention. Ingestion: If swallowed, do not induce vomiting. If conscious, give 2 to 3 glasses of water and seek medical advice/attention immediately.

SECTION 5 – FIRE-FIGHTING MEASURES

Extinguishing Media: Carbon dioxide, dry chemical, foam, or water spray

Unusual Fire and Explosion Hazards: None known

Special Fire Fighting Procedures: Water can be used to cool fire-exposed containers. Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals.

SECTION 6 – ACCIDENTAL RELEASE MEASURES

Steps to be taken in case material is released or spilled: Observe all personal protective equipment recommendations described in Section 8. Wipe up or scrape up spilled material and contain for disposal. Final cleaning may require use of hot water and/or detergents. Dispose of saturated absorbent or cleaning materials appropriately.

SECTION 7 – HANDLING and STORAGE

Precautions for safe handling: Keep away from extreme heat. Do not get in eyes, on skin, on clothing. Do not swallow product. Wash thoroughly after handling. Use with adequate ventilation. Conditions for safe storage: Store in a cool, dry place in the original container. Keep container closed when not in use. Store the product away from strong oxidizing chemicals. Avoid extreme heat. Store above 7 °C (45 °F). Product will freeze below 0 °C (32 °F).

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION

Respiratory Protection: Use with adequate ventilation. Skin Protection: Chemical resistant gloves are recommended for prolonged exposure. Eye Protection: Wear safety glasses with side shields. OTHER PROTECTIVE EQUIPMENT: None required.

SAFETY DATA SHEET Gardner A5 Siliconized Acrylic Sealant - White Page 3 of 5

SECTION 9 – PHYSICAL and CHEMICAL PROPERTIES

Appearance (Physical state, color): Thick fluid paste, bright white Odor: Mild, acrylic-like

Odor Threshold: No information is available. pH: 7.5 – 8.5

Melting point: No data is available. Initial Boiling Point & Boiling Range: 100 °C to 244 °C (212 °F to 471 °F)

Flash Point: >94 °C (>201 °F) Evaporation Rate: Slower than Ether

Flammability: Nonflammable Upper/Lower Flammability Limits: No data is available.

Vapor Pressure: 17.5 mm Hg @ 20 °C (68 °F) Vapor Density: Heavier than air

Density: 1.62 g/cm3 (13.5 Lbs/gal) 21 °C (70 °F) Solubility (in water): Dispersible in water

Partition coefficient (n-octanol/water): No data is available. Auto-ignition temperature: No data is available.

Decomposition temperature: >250 °C (482 °F) Viscosity (Brookfield RV, 5 rpm): 360,000 cP ±80,000 @ 21 °C (70 °F)

SECTION 10 – STABILITY and REACTIVITY

Reactivity: No hazardous reactions if stored and handled as prescribed. Chemical Stability: The product is stable if stored and handled as prescribed. Hazardous decomposition products: Carbon dioxide, carbon monoxide, and hydrocarbons. Hazardous polymerization: Will not occur. The product is chemically stable.

SECTION 11 – TOXICOLOGICAL INFORMATION

Primary routes of exposure: Routes of entry for the product into the human body are accidental ingestion, accidental eye contact, and prolonged skin contact. Inhalation of the vapor released from the product as it dries is dependent upon the absence of proper ventilation during use of the product. Acute Toxicity/Effects: EYES: Direct contact may cause irritation. SKIN: May cause irritation to sensitive skin or open wounds. INHALATION: May cause irritation to respiratory passages. INGESTION: May cause nausea/gastrointestinal distress. No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.

SAFETY DATA SHEET

Gardner A5 Siliconized Acrylic Sealant - White Page 4 of 5

SECTION 11 – TOXICOLOGICAL INFORMATION (continued from page 3)

No human toxicological studies (Oral, Inhalation or Dermal) have been conducted on this compounded product.

No animal toxicological studies (Oral, Inhalation or Dermal) have been conducted on this compounded product.

Chronic Toxicity/Effects: EYES: No data available. SKIN: No data available. INHALATION: No data available. INGESTION: No data available.

SECTION 12 – ECOLOGICAL INFORMATION

Ecological Fate: * No data available. Persistence/Degradability: * No data available. Bioaccumulation Potential: * No data available. Mobility in Soil: * No data available.

SECTION 13 – DISPOSAL CONSIDERATIONS

Dispose of unused product and/or empty containers in accordance with local, regional, national, and/or international regulations. Do not discharge into drains/surface waters/groundwater or open ground/soil.

SECTION 14 – TRANSPORT INFORMATION

DOT Proper Shipping Name: Not Regulated by D.O.T. DOT Hazard Class: None DOT UN/NA Number: None Packing Group: None

IMO/IMDG – International Maritime Transport Shipping Name: Not Regulated. IATA – International Air Transportation Association: Not Regulated.

Do not transport this product on passenger seats or inside the passenger compartment of any vehicle. Transport product in the cargo area of the vehicle and secure it on and under protective cloths or plastic wrap to prevent damage due to accidental spills.

SECTION 15 – REGULATORY INFORMATION

SARA Title III – No substances are contained in this product subject to the reporting requirements of EPCRA Section 313 of the Super Fund Amendments and Reauthorization Act, 40 CFR Part 372. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. California Proposition 65 Chemical Warning (California Health and Safety Code #25249.5 et seq): This product contains chemicals known to the state of California to cause cancer, birth defects or reproductive harm.

SAFETY DATA SHEET

Gardner A5 Siliconized Acrylic Sealant - White Page 5 of 5

SECTION 16 – OTHER INFORMATION

Hazardous Materials Identification System (HMIS) Health Flammability Physical Hazard Personal Protection Equipment (PPE) 1 0 0 B – Safety glasses and gloves

Legend: 0 = Insignificant 1 = Slight 2 = Moderate 3 = High Other Precautions: Keep out of the reach of children. Protect from freezing. Disclaimer/Statement of Liability: This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user's responsibility to verify the suitability and completeness of such information for a particular use. Gardner-Gibson does not accept liability for any loss or damage that may occur from the use of this information. Prepared by: Morton Jones 2-23-15 Product # 5019-1-61

Material Name: HERCULES ABS BLACK, MEDIUM BODY, FAST SET

____________________________________________________________ Page 1 of 8 Issue Date 08/30/12 Revision 1.0000 Print Date: 10/1/2012

* * * Section 1 - Product and Company Identification * * *

MSDS #64

Part Numbers: 60503, 60513, 60515, 60520, 60525

Manufacturer Information HCC Holdings, Inc.

An Oatey Affiliate

Phone: 216-267-7100

4700 West 160th Street

Cleveland, OH 44135

For Emergency First Aid call 1-877-740-5015. For chemical

transportation emergencies ONLY, call Chemtrec at 1-800-424-

9300. Outside the U.S. 1- 703-527-3887.

* * * Section 2 - Hazards Identification * * *

GHS Classification: Flammable Liquids - Category 2

Eye Damage/Irritation - Category 2A

Specific Target Organ Toxicity Single Exposure - Category 3

GHS LABEL ELEMENTS

Symbol(s)

Signal Word Danger

Hazard Statements Highly flammable liquid and vapor.

Causes serious eye irritation.

May cause respiratory irritation.

May cause drowsiness or dizziness.

Precautionary Statements Prevention

Keep away from heat/sparks/open flames and hot surfaces. - No smoking.

Keep container tightly closed.

Use explosion-proof electrical/ventilating/lighting/equipment.

Use only non-sparking tools.

Take precautionary measures against static discharge.

Wear protective gloves/eye protection/face protection.

Wash thoroughly after handling.

Do not eat, drink or smoke when using this product.

Avoid breathing fume/gas/mist/vapors.

Use only outdoors or in a well-ventilated area.



Response

If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash

contaminated clothing before reuse.

If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center

or doctor/physician if you feel unwell.

If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. Immediately call a poison center or doctor/physician.

In case of fire: Use dry chemical, CO2, or foam to extinguish fire.

Storage

Store in a well-ventilated place. Keep cool.

Store locked up.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

* * * Section 3 - Composition / Information on Ingredients * * *

CAS # Component Percent

78-93-3 Methyl ethyl ketone 40-60

9003-56-9 ABS resin 30-40

* * * Section 4 - First Aid Measures * * *

First Aid: Eyes If material gets into eyes or if fumes cause irritation, immediately flush eyes with plenty of water until chemical is

removed. If irritation persists, get medical attention immediately.

First Aid: Skin

Remove contaminated clothing immediately. Wash all exposed areas with soap and water. Get medical attention

if irritation develops. Remove dried cement with hand cleaner or baby oil.

First Aid: Ingestion DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is

unconscious or drowsy. Get immediate medical attention by calling a Poison Control Center, or hospital

emergency room. If medical advice cannot be obtained, then take the person and product to the nearest medical

emergency treatment center or hospital.

First Aid: Inhalation If symptoms of exposure develop, remove to fresh air. If breathing becomes difficult, administer oxygen.

Administer artificial respiration if breathing has stopped. Seek immediate medical attention.

* * * Section 5 - Fire Fighting Measures * * *

General Fire Hazards See Section 9 for Flammability Properties.

Highly flammable liquid and vapor. Keep away from heat and all sources of ignition including sparks, flames,

lighted cigarettes and pilot lights. Containers may rupture or explode in the heat of a fire. Vapors are heavier than

air and may travel to a remote ignition source and flash back.

Hazardous Combustion Products Combustion will produce toxic and irritating vapors including carbon monoxide, carbon dioxide and hydrogen

chloride.



Extinguishing Media

Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container with water. Water may be

ineffective as an extinguishing agent.

Unsuitable Extinguishing Media None.

Fire Fighting Equipment/Instructions Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires

in areas where chemicals are used or stored.

* * * Section 6 - Accidental Release Measures * * *

Recovery and Neutralization

Stop leak if it can be done without risk.

Materials and Methods for Clean-Up Remove all sources of ignition and ventilate area. Soak up spill with an inert absorbent such as sand, earth or

other noncombusting material. Put absorbent material in covered, labeled metal containers.

Emergency Measures Isolate area. Keep unnecessary personnel away.

Personal Precautions and Protective Equipment Personnel cleaning up the spill should wear appropriate personal protective equipment, including respirators if

vapor concentrations are high.

Environmental Precautions Prevent liquid from entering watercourses, sewers and natural waterways.

Prevention of Secondary Hazards None

* * * Section 7 - Handling and Storage * * *

Handling Procedures Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation

(equivalent to outdoors). Wash thoroughly after handling. Do not eat, drink or smoke in the work area. Keep

product away from heat, sparks, flames and all other sources of ignition. No smoking in storage or use areas.

Keep containers closed when not in use. "Empty" containers retain product residue and can be hazardous. Follow

all SDS precautions in handling empty containers. Do not cut or weld on or near empty or full containers.

Storage Procedures Store in a cool, dry, well-ventilated area away from incompatible materials. Keep containers closed when not in

use.

Incompatibilities Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium,

calcium and sodium hypochlorite) and hydrogen peroxides. May attack plastic, resins and rubber.



* * * Section 8 - Exposure Controls / Personal Protection * * *

Component Exposure Limits

Methyl ethyl ketone (78-93-3)

ACGIH: 200 ppm TWA

300 ppm STEL

OSHA: 200 ppm TWA; 590 mg/m3 TWA

NIOSH: 200 ppm TWA; 590 mg/m3 TWA

300 ppm STEL; 885 mg/m3 STEL

Engineering Measures Open doors & windows. Provide ventilation capable of maintaining emissions at the point of use below

recommended exposure limits. If used in enclosed area, use exhaust fans. Exhaust fans should be explosion-

proof or set up in a way that flammable concentrations of solvent vapors are not exposed to electrical fixtures or

hot surfaces.

Personal Protective Equipment: Respiratory

For operations where the exposure limit may be exceeded, a NIOSH approved organic vapor respirator or

supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration,

select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self-

contained breathing apparatus.

Personal Protective Equipment: Hands

Rubber gloves are suitable for normal use of the product. For long exposures chemical resistant gloves may be

required such as 4H(tm) or Silver Shield(tm) to avoid prolonged skin contact.

Personal Protective Equipment: Eyes Safety glasses with side shields or safety goggles.

Personal Protective Equipment: Skin and Body

No additional protective equipment needed.

* * * Section 9 - Physical & Chemical Properties * * *

Appearance: Black Odor: Sharp, penetrating odor

Physical State: Liquid pH: NA

Vapor Pressure: 145 mmHg @ 20°C Vapor Density: 2.5

Boiling Point: 151°F (66°C) Melting Point: NA

Solubility (H2O): Negligible Specific Gravity: 0.89 +/- 0.02 @ 20°C

Evaporation Rate: (BUAC = 1) = 5.5 - 8.0 VOC: 60-70%

Octanol/H2O Coeff.: ND Flash Point: 14-23°F (-10 to -5°C)

Flash Point Method: CCCFP Upper Flammability Limit

(UFL):

11.8

Lower Flammability Limit

(LFL):

1.8 Burning Rate: ND

Auto Ignition: ND

* * * Section 10 - Chemical Stability & Reactivity Information * * *

Chemical Stability This is a stable material.

Hazardous Reaction Potential

Will not occur.



Conditions to Avoid

Avoid heat, sparks, flames and other sources of ignition.

Incompatible Products Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium,

calcium and sodium hypochlorite) and hydrogen peroxides. May attack plastic, resins and rubber.

Hazardous Decomposition Products Combustion will produce toxic and irritating vapors including carbon monoxide, carbon dioxide and hydrogen

chloride.

* * * Section 11 - Toxicological Information * * *

Acute Toxicity

Component Analysis - LD50/LC50


Inhalation LC50 Mouse 32 g/m3 4 h; Oral LD50 Rat 2737 mg/kg; Dermal LD50 Rabbit 6480 mg/kg

Potential Health Effects: Skin Corrosion Property/Stimulativeness May cause irritation with redness, itching and pain. Methyl ethyl ketone may be absorbed through the skin

causing effects similar to those listed under inhalation.

Potential Health Effects: Eye Critical Damage/ Stimulativeness

Vapors may cause irritation. Direct contact may cause irritation with redness, stinging and tearing of the eyes.

May cause eye damage.

Potential Health Effects: Ingestion Swallowing may cause abdominal pain, nausea, vomiting and diarrhea. Aspiration during swallowing or vomiting

can cause chemical pneumonia and lung damage. May cause kidney and liver damage.

Potential Health Effects: Inhalation Vapors or mists may cause mucous membrane and respiratory irritation, coughing, headache, dizziness,

dullness, nausea, shortness of breath and vomiting. High concentrations may cause central nervous system

depression, narcosis and unconsciousness. May cause kidney, liver and lung damage.

Respiratory Organs Sensitization/Skin Sensitization

This product is not reported to have any skin sensitization effects.

Generative Cell Mutagenicity Acetone and methyl ethyl ketone are generally thought not to be mutagenic.

Carcinogenicity

A: General Product Information

This product is not reported to have any carcinogenic effects.

B: Component Carcinogenicity

ABS resin (9003-56-9)

IARC: Supplement 7 [1987]; Monograph 19 [1979] (Group 3 (not classifiable))

Reproductive Toxicity Methyl ethyl ketone has been shown to cause embryofetal toxicity and birth defects in laboratory animals.

Acetone has been found to cause adverse developmental effects only when exposure levels cause other toxic

effects to the mother.



Specified Target Organ General Toxicity: Single Exposure

May cause respiratory irritation. Inhalation of high concentrations may cause central nervous system depression,

narcosis and unconsciousness. May cause kidney, liver and lung damage.

Specified Target Organ General Toxicity: Repeated Exposure This product is not reported to have any specific target organ toxicity repeat exposure effects.

Aspiration Respiratory Organs Hazard Aspiration during swallowing or vomiting can cause chemical pneumonia and lung damage. May cause kidney

and liver damage.

* * * Section 12 - Ecological Information * * *

Ecotoxicity


This product is not expected to be toxic to aquatic organisms.

B: Component Analysis - Ecotoxicity - Aquatic Toxicity


Test & Species Conditions

96 Hr LC50 Pimephales promelas 3130-3320 mg/L

[flow-through]

48 Hr EC50 Daphnia magna >520 mg/L

48 Hr EC50 Daphnia magna 5091 mg/L

48 Hr EC50 Daphnia magna 4025 - 6440 mg/L

[Static]

Persistence/Degradability No information available for the product.

Bioaccumulation

No information available for the product.

Mobility in Soil No information available for the product.

* * * Section 13 - Disposal Considerations * * *

Waste Disposal Instructions See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.

Disposal of Contaminated Containers or Packaging Dispose of contents/container in accordance with local/regional/national/international regulations.

* * * Section 14 - Transportation Information * * *

DOT Information For Greater than 1 liter (0.3 gal):

Shipping Name: Adhesives

UN #: 1133 Hazard Class: 3 Packing Group: II

Required Label(s): Flammable Liquid

For Less than 1 liter (0.3 gal):

Shipping Name: Consumer Commodity, ORM-D



IMDG Information For Greater than 1 liter (0.3 gal):



Required Label(s): Flammable Liquid

For Less than 1 liter (0.3 gal):



Required Label(s): None (Limited Quantities are expected from labeling)

* * * Section 15 - Regulatory Information * * *

Regulatory Information US Federal Regulations

Component Analysis

This material contains one or more of the following chemicals required to be identified under SARA Section 302

(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).


CERCLA: 5000 lb final RQ; 2270 kg final RQ

State Regulations

Component Analysis - State

The following components appear on one or more of the following state hazardous substances lists:

Component CAS CA MA MN NJ PA RI

Methyl ethyl ketone 78-93-3 Yes Yes Yes Yes Yes No

Component Analysis - WHMIS IDL

The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:

Component CAS # Minimum Concentration

Methyl ethyl ketone 78-93-3 1 %

Additional Regulatory Information


This product does not contain any chemicals subject to California Proposition 65 regulations.



B: Component Analysis - Inventory

Component CAS # TSCA CAN EEC

Methyl ethyl ketone 78-93-3 Yes DSL EINECS

ABS resin 9003-56-9 Yes DSL No

* * * Section 16 - Other Information * * *

Key/Legend

EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference

of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National

Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety

and Health Administration., NJTSR = New Jersey Trade Secret Registry.

Literature References

None

Other Information NFPA and HMIS:

NFPA Hazard Signal: Health: 2 Flammability: 3 Reactivity: 1 Special: None

HMIS Hazard Signal: Health: 2* Flammability: 3 Reactivity: 1 PPE: G

Disclaimer:

The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the

best of our knowledge. However, we cannot give any guarantees regarding information from other sources, and

expressly do not make warranties, nor assume any liability for its use.

End of Sheet OAT-12

SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTION Component ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL:

Methyl Ethyl Ketone (MEK) Acetone

200 ppm 500 ppm

300 ppm 750 ppm

200 ppm 1000 ppm

GHS SAFETY DATA SHEET

Spears® ABS-73 Low VOC ABS Pipe Cement

Date Revised: M A Y 2 0 1 3

Supersedes: JUNE 2011

SECTION I - PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME:

PRODUCT USE:

Spears® ABS-73 Low VOC ABS Pipe Cement

Low VOC Solvent Cement for ABS Plastic Pipe

MANUFACTURER: Spears® Manufacturing Company 15853 Olden Street Sylmar, CA 91342 Tel. 818-364-1611

SUPPLIER:

EMERGENCY: Transportation/Medical issues: Tel. 800-535-5053 or 352-323-3500 (outside of USA) INFOTRAC

SECTION 2 - HAZARDS IDENTIFICATION GHS CLASSIFICATION:

Health Environmental Physical Acute Toxicity: Category 4 Acute Toxicity: None Known Flammable Liquid Category 2 Skin Irritation: Category 3 Chronic Toxicity: None Known Skin Sensitization: NO Eye: Category 2B

GHS LABEL: Signal Word: WHMIS CLASSIFICATION: CLASS B, DIVISION 2 OR Danger

Hazard Statements Precautionary Statements

H225: Highly flammable liquid and vapor P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking H319: Causes serious eye irritation P261: Avoid breathing dust/fume/gas/mist/vapors/spray

H336: May cause drowsiness or dizziness P280: Wear protective gloves/protective clothing/eye protection/face protection

EUH 066: Repeated exposure may cause skin dryness or cracking. P337+P313: Get medical advice/attention

P403+P233: Store in a well ventilated place. Keep container tightly closed

P501: Dispose of contents/container in accordance with local regulation

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS CAS# EINECS # REACH CONCENTRATION

Methyl Ethyl Ketone (MEK)

78-93-3

201-159-0

Pre-registration Number % by Weight

05-2116297728-24-0000 40 - 60 Acetone 67-64-1 200-662-2 05-2116297713-35-0000 5 - 15 All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing. * Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).

SECTION 4 - FIRST AID MEASURES Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately. Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice. Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice. Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.

SECTION 5 - FIREFIGHTING MEASURES

Suitable Extinguishing Media: Dry chemical powder, carbon dioxide gas, foam, Halon, water fog. HMIS NFPA 0-Minimal Unsuitable Extinguishing Media: Water spray or stream. Health 2 2 1-Slight Exposure Hazards: Inhalation and dermal contact Flammability 3 3 2-Moderate Combustion Products: Oxides of carbon and smoke Reactivity 0 0 3-Serious Protection for Firefighters: Self-contained breathing apparatus or full-face positive pressure airline masks.

SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: Keep away from heat, sparks and open flame.

4-Severe

Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment. Prevent contact with skin or eyes (see section 8).

Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course. Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel. Materials not to be used for clean up: Aluminum or plastic containers

SECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.

Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods. Do not eat, drink or smoke while handling.

Storage: Store in ventilated room or shade below 44 °C (110 °F) and away from direct sunlight. Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates. Follow all precautionary information on container label, product bulletins and solvent cementing literature.

EXPOSURE LIMITS:

Engineering Controls: Use local exhaust as needed. Monitoring: Maintain breathing zone airborne concentrations below exposure limits. Personal Protective Equipment (PPE): Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,

etc. as may be appropriate for the exposure. Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.

Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application practices and procedures are used for making structural bonds.

Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use local exhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above. With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Black, medium syrupy liquid Odor: Ketone Odor Threshold: 1 ppm (Acetone) pH: Not Applicable Melting/Freezing Point: -95 °C (-139 °F) Based on first melting component: Acetone Boiling Range: 56 °C (133 °F) to 80 °C (176 °F) Boiling Point: 56 °C (133 °F) Based on first boiling component: Acetone Evaporation Rate: >1.0 (BUAC = 1) Flash Point: -20 °C (-4 °F) T.C.C. based on Acetone Flammability: Category 2 Specific Gravity: 0.890 ± 0.01 @23 °C ( 73 °F) Flammability Limits: LEL: 1.4% based on MEK Solubility: Solvent portion soluble in water. Resin portion separates out. UEL: 12.8% based on Acetone Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 190 mm Hg @ 20 °C (68 °F): Acetone Auto-ignition Temperature: 404 °C (759 °F): MEK Vapor Density: > 2.0 (Air = 1) Decomposition Temperature: Not Applicable Other Data: Viscosity: Medium bodied VOC Content: When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 325 g/l.

SECTION 10 - STABILITY AND REACTIVITY Stability: Stable Hazardous decomposition products: None in normal use. When forced to burn, this product gives off oxides of carbon and smoke. Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources. Incompatible Materials: Oxidizers, strong acids and bases, amines, ammonia

SECTION 11 - TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Inhalation, Eye and Skin Contact Acute symptoms and effects:

Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages. Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid. Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact. Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.

Chronic (long-term) effects: None known to humans Toxicity: LD50 LC50

Methyl Ethyl Ketone (MEK) Oral: 2737 mg/kg (rat), Dermal: 6480 mg/kg (rabbit) Inhalation 8 hrs. 23,500 mg/m3 (rat) Acetone Oral: 5800 mg/kg (rat) Inhalation 50,100 mg/m3 (rat)

Reproductive Effects Not Established

Teratogenicity Not Established

Mutagenicity Not Established

Embryotoxicity Not Established

Sensitization to Product Not Established

Synergistic Products Not Established

SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: None Known Mobility: In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 325 g/l. Degradability: Biodegradable Bioaccumulation: Minimal to none.

SECTION 13 - WASTE DISPOSAL CONSIDERATIONS Follow local and national regulations. Consult disposal expert.

SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Adhesives Hazard Class: 3 EXCEPTION for Ground Shipping Secondary Risk: None DOT Limited Quantity: Up to 1L per inner packaging, 30 kg gross weight per package. Identification Number: UN 1133 Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" . Packing Group: PG II Label Required: Class 3 Flammable Liquid Marine Pollutant: NO

TDG CLASS:

TDG INFORMATION FLAMMABLE LIQUID 3

SECTION 15 - REGULATORY INFORMATION

SHIPPING NAME: ADHESIVES UN NUMBER/PACKING GROUP: UN 1133, PG II

Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS) Risk Phrases: R11: Highly flammable.

R36/37: Irritating to eyes and respiratory system. R66: Repeated exposure may cause skin dryness or cracking R67: Vapors may cause drowsiness and dizziness

Safety Phrases: S2: Keep out of the reach of children S9: Keep container in a well-ventilated place. S16: Keep away from sources of ignition - No smoking.

S25: Avoid contact with eyes. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S33: Take precautionary measures against static discharges.

SECTION 16 - OTHER INFORMATION Specification Information: Department issuing data sheet: Environmental Health & Safety All ingredients are compliant with the requirements of the European E-mail address: [email protected] Directive on RoHS (Restriction of Hazardous Substances). Training necessary: Yes, training in practices and procedures contained in product literature. Reissue date / reason for reissue: 05-01-2013 / Technical Update Intended Use of Product: Solvent Cement for ABS Plastic Pipe

This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.

mailto:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]

MATERIAL SAFETY DATA SHEET #Hercules ABS/PVC Transition Cement

Date Prepared: 2/1/1990 Last Reviewed: 8/27/2007 Hercules Chemical Company Inc.111 South StreetPassaic NJ 07055Phone (800) 221-9330Fax (800) 333-3456

Section 1

65

This Material Safety Data Sheet (MSDS) was requested moments ago from Hercules Automated Fax Information System. Please forward it

immediately to the person in charge of MSDS's, or retain it at the machine until claimed.

OSHA-Required Health And Safety Information!

Meets OSHA 29 CFR 1910.1200

200PPM 200PPM N/A - -Methyl Ethyl Ketone (78-93-3) 200PPM 200PPM N/A - -

Cyclohexanone (108-94-1) 50PPM 20PPM N/A - -

HMIS Hazard Rating: Health: 3 Flammability: 4 Reactivity:1 Personal Protection: G

151 Based on first boiling component-THF

Specific Gravity(H2O = 1):

0.910 ± 0.03

Vapor Density(Air = 1):

2.0 to 2.5

Melting Point (° F):

N/A

Evaporation Rate: (Butyl Acetate = 1)

7-11

Solubility in Water:

60% to 85%

Green Viscous Liquid Odor: Ethereal & Acetone-like

Flash Point:

7.0° F (T.C.C.) (Based on THF)

Flammable Limits: LEL:

2%

UEL:

11.8%

Extinguishing Media: Foam/Dry Chemical/Carbon Dioxide.

Special Firefighting Procedures:Handle as flammable liquid. Wear self-contained breathing apparatus & chemical goggles. Water may be ineffective, but should be used to keep fire-exposed containers cool.

Unusual Fire And Explosion Hazards:Vapor is heavier than air and travels considerable distance to source of ignition and flashback. On long standing may form peroxides which may cause violent reaction especially upon evaporation to dryness.

Section 2 - Hazardous Ingredients/Identity InformationHazardous Components (Specific Chemical Identity; Common Name(s), CAS Numbers) Upper Bound

Limit if SARA Reportable

Tetrahydrofuran (109-99-9)

Section 3 - Physical/Chemical CharacteristicsBoiling Point (°F): Vapor Pressure

(mm Hg):

143 Based on first boiling component-THF

Appearance And Color:

Section 4 - Fire And Explosion Hazard Data

OSHA PEL ACGIH TLV Other Limits

Continued on Next Page

Hercules Chemical Material Safety Data Sheet # Hercules ABS/PVC Transition Cement Page 265

Stability: Stable Conditions To Avoid: Keep in closed containers away from sparks and open flame.Incompatability(Materials To Avoid):

Strong oxidizing materials, Lithium Aluminum Hydride, Sodium Aluminum Hydroxide, Sodium and Potassium Hydroxides.

Hazardous Decomposition: Carbon dioxide and carbon monoxide are formed. Irritating peroxide fumes formed when heated to decomposition.

Hazardous Polymerization: Avoid excessive exposure to air and cationic initiators like Lewis Acids.

Inhalation YES/Primary Skin YES/Primary Ingestion YES/Secondary

Health Hazards:

Corrosive to eyes and skin irritant. Severe overexposure can cause headache, dizziness and narcosis. May cause dermatosis and dermatitis with prolonged repeated contact.

NTP NO IARC NO OSHA Regulated NOSigns And Symptoms of Exposure:

INGESTION: No effects of exposure expected. INHALATION: Will cause irritation of mucous membranes, nose, eyes & throat coughing, difficulty of breathing. Exposure to high vapor concentration may cause headache, dizziness, nausea, narcosis. SKIN CONTACT: Prolonged contact causes common solvent defatting effect. EYE CONTACT: Vapors slightly uncomfortable, splashes irritating. Will cause painful burning or stinging of eyes and lids, watering of eyes and conjunctiva.Medical Conditions Generally Aggravated By Exposure:No data found.Emergency And First Aid Procedures:

INGESTION: DO NOT INDUCE VOMITING. If conscious, dilute by giving two glasses of water. Call a physician immediately. INHALATION: Remove to fresh air, if not breathing; give artificial respiration preferably mouth to mouth. If breathing is difficult give oxygen. Call a physician. SKIN CONTACT: Wash affected skin area with soapy water. Remove contaminated clothing. EYE CONTACT: Immediately flush eyes with plenty of water for 15 minutes. Consult a physician

Section 5 - Reactivity Data

Section 6 - Health Hazard DataRoutes of Entry:

Carcinogenicity:

Continued on Next Page

Hercules Chemical Material Safety Data Sheet # Hercules ABS/PVC Transition Cement Page 365

Steps To Be Taken In Case Material Is Released Or Spilled:

Eliminate sources of ignition. Absorb with sand or inert absorbing material and dispose of with solid waste according to federal, state and local regulations. Flush spill area with water, avoid flushing into confined areas.Waste Disposal Method:

Incinerate in accordance with federal, state and local regulations.Precautions To Be Taken In Handling And Storing:

Store in cool place, well-ventilated area. Keep away from open flame and sources of ignition.Other Precautions:Use normal good personal hygiene.

Respiratory Protection:In confined spaces or other circumstances where adequate ventilation cannot be assured use NIOSH-approved respirator, positive pressure airline mask, or self contained breathing apparatus.

Local Exhaust As required Special When using cements in an area of limited ventilation, use a ventilation device such as a fan or air mover to maintain a safe air concentration.

Mechanical All ventilating devices must be located so they do not provide a source of ignition.

Other: N/AGloves: PVA gloves.

Eye Protection: Chemical safety gogglesOther ProtectiveClothing: Apron, boots, eye bath, safety shower.Work/Hygienic Practices: Wash thoroughly after handling. Avoid ingestion of the cements. Do not eat or drink when

using cements or in the vicinity where such cements are being used.

Section 7 - Precautions For Safe Handling And Use:

Section 8 - Control Measures:

Ventilation:

For Hercules Material Safety Data Sheets by fax anytime, day or night, just call 1-800-942-INFO (1-800-942-4636) from any Touch-Tone phone. Have your fax number ready. Checking the product label for the correct MSDS # will save time.

MATERIAL SAFETY DATA SHEET HMIS CODES:H F R P1 0 0 B

May be used to comply with OSHA’s Hazard CommunicationStandard, 29 CFR 1910.1200. Standard must be consulted forspecific requirements.

U.S. Department of LaborOccupational Safety and Health Administrator

(Non-Mandatory Form)Form Approved OMB No. 1218-0072

IDENTITY (AS USED ON LABEL AND LIST):

ALL PURPOSE BOILER CLEANER AND TREATMENT BT

NOTE: Blank spaces are not permitted. If any item is notapplicable, or no information is available, the space must bemarked to indicate that.

Section I

Manufacturer’s Name:J.C. WHITLAM MANUFACTURING COMPANY

Emergency Telephone Number:(330) 334 - 2524

Address (Number, Street, City, State, and ZIP Code):200 WEST WALNUT STREET

Telephone Number for Information:(330) 334 - 2524

P.O. BOX 380 Date Prepared: January 24, 2014

WADSWORTH, OHIO 44282-0380 Signature of Preparer (optional):

Section II - Hazardous Ingredients/Identity Information

HAZARDOUS COMPONENTS(SPECIFIC CHEMICAL IDENTITY: COMMON NAME(S)

OSHA PEL ACGIHTLV

OTHER LIMITSRecommended

% (optional)

SODIUM NITRITE (CAS# 7632-00-0) N/A N/A N/A < 5

Section III - Physical/Chemical Characteristics

Boiling Point: 212 EF (100 EC) Specific Gravity (H20 =1 @ 20 EC): 1.04

Vapor Pressure (mm Hg @ 20 EC): NONE Melting Point: N/A

Vapor Density (AIR = 1): NONE Evaporation Rate (WATER = 1): < 1

pH 8.5 Percent Volatile by Weight (%) 90

Solubility in Water: MISCIBLE VOC Content: 0 g/l

Appearance and Odor: CLEAR LIQUID WITH MILD ODOR

Section IV - Fire and Explosion Hazard Data

Flash Point (Method Used): NONE Flammable Limits: LEL: N/A UEL: N/A

Extinguishing Media: NOT COMBUSTIBLE

Special Fire Fighting Procedures: WEAR APPROPRIATE PROTECTIVE EQUIPMENT INCLUDING RESPIRATORY PROTECTION AS CONDITIONSWARRANT. STOP SPILL/RELEASE IF IT CAN BE DONE WITHOUT RISK. WATER SPRAY MAY BE USEFUL IN MINIMIZING OR DISPERSINGVAPORS AND COOLING EQUIPMENT EXPOSED TO HEAT AND FLAME. AVOID SPREADING BURNING LIQUID WITH WATER USED FORCOOLING PURPOSES.

Unusual Fire and Explosion Hazards: MAY DECOMPOSE DURING CONTACT WITH FLAMES, HEATING ELEMENTS, OR IN COMBUSTIONENGINES RELEASING IRRITATING GASES. CONTAINER MAY EXPLODE IF HEATED DUE TO RESULTING PRESSURE RISE. OXIDES OFNITROGEN MAY BE LIBERATED IN HOT FIRE.

Section V - Reactivity Data

Stability:Unstable:

Conditions to Avoid: N/AStable: X

Incompatibility (Materials to Avoid): THIS PRODUCT IS INCOMPATIBLE WITH: OXIDIZING AGENTS, STRONG ACIDS AND BASES.

Hazardous Decomposition or Byproducts: THERMAL DECOMPOSITION IN THE PRESENCE OF AIR MAY YIELD CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN.

Hazardous Polymerization:May Occur: Conditions to Avoid: N/AWill Not Occur: X

Page 1

Section VI - Health Hazard Data ALL PURPOSE BOILER CLEANER ANDTREATMENT BT

Route(s) of Entry: Inhalation? YES Skin? YES Ingestion? YES

Health Hazards (Acute and Chronic): EYE CONTACT: ONE OR MORE COMPONENTS OF THIS MATERIAL MAY BE AN EYE IRRITANT. SKIN CONTACT: CONTINUOUS CONTACT WITH THIS MATERIAL MAY CAUSE DRYING OF SKIN. CHEMICAL ITSELF IS AN IRRITANT ORSENSITIZER. SKIN ABSORPTION: SYMPTOMS OF TOXICITY ARE ANTICIPATED BY THIS ROUTE. INHALATION: NOT EXPECTED TO BE A HAZARD UNDER NORMAL OPERATING CONDITIONS. INGESTION: INGESTION OF LARGE QUANTITIES MAY CAUSE THE FOLLOWING: IRRITATION OF DIGESTIVE TRACT, SIGNS OF NERVOUSSYSTEM DEPRESSION, SUCH AS HEADACHE, DROWSINESS, DIZZINESS, LOSS OF COORDINATION, FATIGUE AND NAUSEA.

Carcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? NO

Signs and Symptoms of Exposure:IRRITATING TO EYES AND MUCOUS MEMBRANES. SKIN IRRITANT. INGESTION: IRRITATES GASTROINTESTINAL TRACT. MAY CAUSEDIARRHEA, CENTRAL NERVOUS SYSTEM DEPRESSION.

Medical Conditions Generally Aggravated by Exposure: NONE KNOWN.

Emergency and First Aid Procedures :EYE CONTACT: MOVE PERSON AWAY FROM EXPOSURE AND INTO FRESH AIR. IF IRRITATION OR REDNESS DEVELOPS, FLUSH EYESWITH CLEAN WATER AND SEEK MEDICAL ATTENTION. FOR DIRECT CONTACT, HOLD EYELIDS APART FOR AT LEAST 15 MINUTES. SEEKMEDICAL ATTENTION. SKIN CONTACT: REMOVE CONTAMINATED SHOES AND CLOTHING AND CLEANSE AFFECTED AREASTHOROUGHLY BY WASHING WITH MILD SOAP AND WATER. IF IRRITATION PERSISTS SEEK MEDICAL ATTENTION. INHALATION: NOT EXPECTED TO BE A HAZARD UNDER NORMAL OPERATING CONDITIONS, MOVE TO FRESH AIR. INGESTION: IF SWALLOWED, INDUCE VOMITING AND SEEK EMERGENCY MEDICAL ATTENTION. DO NOT GIVE ANYTHING BY MOUTH.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Released or Spilled: COLLECT FREE LIQUID. ABSORB REMAINDER WITH INERT MATERIAL. PLACE ALL MATERIAL IN APPROVED CONTAINERS. DO NOTFLUSH INTO WATERWAYS.

Waste Disposal Method: OBSERVE ALL FEDERAL, STATE, AND LOCAL REGULATIONS.

Precautions to Be Taken in Handling and Storing:KEEP CONTAINERS TIGHTLY CLOSED, COOL, DRY, AND AWAY FROM ALL SOURCES OF IGNITION. USE AND STORE THIS PRODUCT WITH ADEQUATE VENTILATION.

Other Precautions:“EMPTY” CONTAINERS CONTAIN RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS. THOROUGHLY CLEAN, THEN RECYCLE,REUSE OR DISPOSE IN ACCORDANCE WITH GOVERNMENTAL REGULATIONS. DO NOT PRESSURIZE, CUT, WELD, SOLDER, DRILL, GRINDOR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND MAY CAUSEINJURY OR DEATH.

Section VIII - Control Measures

Respiratory Protection (Specify Type): THE USE OF RESPIRATORY PROTECTION IS ADVISED WHEN CONCENTRATES EXCEED THE ESTABLISHED EXPOSURE LIMITS (SEESECTION II). DEPENDING ON THE AIRBORNE CONCENTRATION, USE A RESPIRATOR OR GAS MASK WITH APPROPRIATE CARTRIDGESOR CANISTERS (NIOSH APPROVED) OR SUPPLIED AIR.

Ventilation:

Local Exhaust: IF CURRENT VENTILATION PRACTICES ARE NOTADEQUATE TO MAINTAIN AIRBORNE CONCENTRATIONS BELOWESTABLISHED EXPOSURE LIMITS (SEE SECTION II) ADDITIONALVENTILATION OR EXHAUST SYSTEMS MAY BE REQUIRED.

Special: N/A

Mechanical (General): N/A Other: N/A

Protective Gloves: THE USE OF GLOVESIMPERMEABLE TO THE SPECIFIC MATERIAL HANDLED IS ADVISED TO PREVENT POSSIBLEIRRITATION.

Eye Protection: APPROVED EYE PROTECTION TO SAFEGUARD AGAINSTPOTENTIAL EYE CONTACT, IRRITATION OR INJURY IS RECOMMENDED.

Other Protective Clothing or Equipment: NONE

Work/Hygienic Practices: WASH WITH SOAP AND WATER.

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MATERIAL SAFETY DATA SHEET HMIS CODES:H F R P1 0 0 A

May be used to comply with OSHA’s HazardCommunication Standard, 29 CFR 1910.1200. Standardmust be consulted for specific requirements.

U.S. Department of LaborOccupational Safety and Health Administrator

(Non-Mandatory Form)Form Approved OMB No. 1218-0072

IDENTITY (AS USED ON LABEL AND LIST): WHITLAM ALL PURPOSE SILICONIZED ACRYLIC CAULK TTC, TTL, TTW

NOTE: Blank spaces are not permitted. If any item isnot applicable, or no information is available, the spacemust be marked to indicate that.

Section I

Manufacturer’s Name:J.C. WHITLAM MANUFACTURING COMPANY

Emergency Telephone Number:(330) 334 - 2524

Address (Number, Street, City, State, and ZIP Code):200 WEST WALNUT STREET

Telephone Number for Information:(330) 334 - 2524

P.O. BOX 380 Date Prepared: January 24, 2014

WADSWORTH, OHIO 44282-0380 Signature of Preparer (optional):

Section II - Hazardous Ingredients/Identity Information

HAZARDOUS COMPONENTS(SPECIFIC CHEMICAL IDENTITY: COMMON NAME(S)

OSHAPEL

ACGIHTLV

OTHER LIMITSRecommended

%(optional)

STODDARD SOLVENT [CAS#8052-41-3] 500 ppm 100 ppm N/A

ETHYLENE GLYCOL [CAS#107-21-1] N/A 50 ppm N/A

Section III - Physical/Chemical Characteristics

Boiling Point: 200°F Specific Gravity (H20 =1): 1.54

Vapor Pressure (mm Hg): N/A Melting Point: N/A

Vapor Density (AIR = 1): N/A Evaporation Rate (Butyl Acetate = 1): < 1

Solubility in Water: SLIGHT VOC Content: < 50 g/l

Appearance and Odor: AVAILABLE IN CLEAR, BISCUIT/LINEN AND WHITE - LATEX ODOR.

Section IV - Fire and Explosion Hazard Data

Flash Point (Method Used): >200°F (-93.3°C) TCC Flammable Limits: LEL: 1.0% UEL: N/A

Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, FOAM AND WATER SPRAY.

Special Fire Fighting Procedures: FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BEUSED.

Unusual Fire and Explosion Hazards: CLOSED CONTAINERS MAY RUPTURE WHEN EXPOSED TO EXTREME HEAT.

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Section V - Reactivity DataWHITLAM ALL PURPOSE SILICONIZED ACRYLIC CAULK TTC, TTL, TTW

Stability:Unstable: Conditions to Avoid: N/AStable: X

Incompatibility (Materials to Avoid): NONE

Hazardous Decomposition or Byproducts: INCOMPLETE COMBUSTION CAN YIELD LOW MOLECULAR WEIGHTHYDRO CARBONS AND CARBON MONOXIDE.

Hazardous Polymerization:May Occur:

Conditions to Avoid: N/AWill Not Occur: X

Section VI - Health Hazard Data

Route(s) of Entry: Inhalation? YES Skin? YES Ingestion? NO

Health Hazards (Acute and Chronic): SIGNS AND SYMPTOMS OF EXPOSURE: ACUTE - EYES: CONTACT MAYCAUSE IRRITATION. SKIN: PROLONGED OR REPEATED CONTACT MAY CAUSE IRRITATION. INHALATION: HIGH VAPOR CONCENTRATIONS MAY CAUSE DIZZINESS OR HEADACHES.

Carcinogenicity: NTP? N/A IARC Monographs? N/A OSHA Regulated? N/A

Signs and Symptoms of Exposure: SKIN CONTACT: REDNESS OF SKIN.

Medical Conditions Generally Aggravated by Exposure: N/A

Emergency and First Aid Procedures: EYES: FLUSH IMMEDIATELY WITH WATER FOR 15 MINUTES AND CONSULT A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER.INHALATION: REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Released or Spilled: CONFINE SPILL, ALLOW TO SET UP, THEN SCRAPE OR SWEEP UP RESIDUE AND PLACE IN A TRASHCONTAINER. DO NOT INCINERATE.

Waste Disposal Method: THIS PRODUCT IS NOT CONSIDERED A HAZARDOUS WASTE. DISPOSE OF ACCORDING TO FEDERAL,STATE, AND LOCAL REGULATIONS.

Precautions to Be Taken in Handling and Storing: KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE AWAY FROM SOURCES OF IGNITION. AVOIDPROLONGED OR REPEATED CONTACT WITH SKIN.

Other Precautions: KEEP OUT OF REACH OF CHILDREN AND PETS.

Section VIII - Control Measures

Respiratory Protection (Specify Type): N/A

Ventilation:Local Exhaust: AS NECESSARY TO PREVENT VAPORBUILDUP.

Special: N/A

Mechanical (General): N/A Other: N/A

Protective Gloves: RUBBER GLOVES Eye Protection: SAFETY GLASSES

Other Protective Clothing or Equipment: WEAR APRON, COVERALLS, OR STANDARD WORK APPAREL.

Work/Hygienic Practices: USE NORMAL SAFETY AND HEALTH PROCEDURES. REMOVE ANYCONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE.

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STAY CLEAN ALUMINUM FLUX - ALSOLDER 500 KIT

IMPORTANT! THIS IS A CONDENSED VERSION OF TWO FULL SIZE MATERIAL SAFETY

DATA SHEETS (MSDS). READ THE FULL MSDS BEFORE USING THIS PRODUCT.

WARNING! Protect yourself and others. PRODUCT COMPONENTS PRESENT POSSIBLE HEALTH AND SAFETY HAZARDS. Use of this product may expose you or others to fumes and gases at levels exceeding those established by the American Conference of Governmental Industrial Hygienists (ACGIH) or the Occupational Safety and Health Administration (OSHA). READ AND UNDERSTAND THIS LITERATURE. ALSO, FOLLOW YOUR EMPLOYER’S SAFETY PRACTICES. The information contained herein relates only to the specific product. If the product is combined with other materials, all component properties must be considered. BE SURE TO CONSULT THE LATEST EDITION OF THE FULL MATERIAL SAFETY DATA SHEETS (MSDS). MATERIAL SAFETY DATA SHEETS ARE AVAILABLE FROM HARRIS PRODUCTS GROUP

E-MAIL: [email protected], TELEPHONE:513-754-2000, WEB SITE: ww.harrisproductsgroup.com

STATEMENT OF LIABILITY – DISCLAIMER To the best of the Harris Products Group knowledge, the information and recommendations contained in this publication are reliable and accurate as of the date prepared. However, accuracy, suitability, or completeness are not guaranteed, and no warranty, guarantee, or representation, expressed or implied is made by Harris Products Group. as to the absolute correctness or sufficiency of any representation contained in this and other publications. Harris Products Group. assumes no responsibility in connection therewith; nor can it be assumed that all acceptable safety measures are contained in this and other publications, or that other or additional measures may not be required under particular or exceptional conditions or circumstances. Data may be changed from time to time.

STAY CLEAN ALUMINUM SOLDERING FLUX DANGER! CORROSIVE. MAY BE HARMFUL OR FATAL IF INHALED OR SWALLOWED. CAUSES SKIN OR EYE BURNS.

ALSOLDER 500 SOLDER CAUTION! FUMES MAY BE HARMFUL IF INHALED. FUMES CAN CAUSE SKIN AND EYE IRRITATION. FUMES OR CONTACT WITH PLASTIC CORE MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTIONS. MOLTEN SOLDER CAN CAUSE THERMAL BURNS.

SUMMARY OF IMPORTANT SAFE-WORK PRACTICES Keep out of reach of children. Do not taste or swallow. Do not get on skin or in eyes. Avoid breathing fumes, vapors or mist. Keep container closed when not in use. Use only with adequate ventilation. Wash thoroughly after handling. Wear gloves, goggles, face-shields, suitable body protection,

and NIOSH/OSHA-approved respiratory protection, as appropriate. For maximum safety, be certified for and wear a respirator at all times when welding or

soldering.

See American National Standard Z49.1, Safety in Welding, Cutting, and Allied Processes, published by the American Welding Society, 550 NW LeJeune Rd., Miami, FL 33126. Also see OSHA Safety and Health Standards, 29 CFR 1910, available from the U.S. Government Printing Office, Superintendent of Documents, P.O. Box 371954,Pittsburgh, PA 15250-7954.

SECTION 1 - PRODUCT IDENTIFICATION Manufacturer: HARRIS PRODUCTS GROUP Address 4501 Quality Place; Mason, Ohio 45040 Emergency Telephone No. CHEMTREC: 1-800-424-9300 Information Telephone No. 513-754-2000 FAX 513-754-8778 Date Prepared November 30, 2010 REVIEWED July 2, 2004

SECTION 2 - COMPOSITION and INFORMATION ON INGREDIENTS STAY CLEAN ALUMNIUM SOLDERING FLUX

CHEMICAL CAS # % w/w

ACGIH-TLV mg/m3

OSHA-TWA mg/m3

NIOSH-REL mg/m3

Triethanolamine 102-71-6 30-60% TWA = 5

NE NE

Aminoethyletha-nolamine

111-41-1 35% NE NE NE

Ammonium Fluoborate

Exposure limits are for inorganic,

solid Fluoride compounds, as F

13826-83-0 20 % TWA=2.5 TWA=2.5

DFG MAKs: TWA = 2.5 (Inhalable

Fraction) PEAK = 5MAK 30

min., average value

Carcinogen: IARC-3, TLV-A4

IDLH = 250

Tin, Metal 7440-31-5 10 % TWA = 2 TWA = 2 TWA = 2

Zinc Oxide Exposure limits

given are for fume.

1314-13-2 10 %

TWA = 5 (fume) 10 (dust) STEL=10

(fume)

5 (fume)

NIOSH RELs: TWA = 5 (fume &

dusts) STEL = 10 (fume), 15

(ceiling, 15 minutes, dusts) DFG MAKs: TWA = 1.5

(Respirable fraction, fume)

Carcinogen: EPA-D

Zinc (exposure limits

are for zinc oxide, fume&dust)

7440-66-6 5%

TWA = 5 (fume) 10 (dust) STEL=10

(fume)

5 (fume) 5 (total dust)

15 (dust, respirable

dust) 5 (dust,

respirable dust,

Vacated 1989 PEL)

NIOSH RELs: TWA = 5 (fume &

dusts) STEL = 10 (fume), 15

(ceiling, 15 minutes, dusts) DFG MAKs: TWA = 1.5

(Respirable fraction, fume)

Carcinogen: EPA-D ALSOLDER 500 SOLDER (85/15)- Included in kit

CHEMICAL CAS # % w/w ACGIH-TLV mg/m3

OSHA-TWA mg/m3

NIOSH-REL mg/m3

Tin The following

exposure limits are for “Tin,

Metal”.

7440-31-5 85.0-96.6%

TWA = 2 2 TWA = 2

Zinc (exposure limits

are for zinc oxide, fume)

7440-66-6 1.5-15.0%

TWA = 5 STEL = 10 5

TWA = 5 (fume & dusts)

STEL = 10 (fume) STEL = 15 (ceiling, 15

minutes, dusts) * Vacated 1989 OSHA PEL. NE = Not Established. C = Ceiling Level.

NOTE: Fumes may be generated during the use of these welding products. To appropriately assess inhalation hazards, one recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an air sample in the worker’s breathing zone. See ANSI/AWS F1.1 “Method for Sampling Airborne Particulates Generated by Welding and Allied Processes”, and F1.5M, “Methods for Sampling and Analyzing Gases from Welding and Allied Processes”, available from the American Welding Society, 550 NW LeJeune Rd., Miami, FL 33126.

SARA SECTION 313 SUPPLIER INFORMATION: These products contain the following chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (per 40 CFR 372).Zinc Oxide, Zinc

SECTION 3 - HAZARD IDENTIFICATION STAY CLEAN ALUMINUM SOLDERING FLUX

This acidic, corrosive solution can irritate and burn the skin, eyes, and any other contaminated tissue. Symptoms of inhalation over-exposure may include sore throat, choking, coughing, difficulty breathing. Lung damage may occur after severe inhalation exposures. Depending on the duration and concentration of over-exposure, skin or eye contact with this product can cause tissue damage, which may be permanent. Ingestion overexposure may be harmful or fatal. Prolonged or repeated inhalation over-exposure may cause burns and ulcers to the nose and throat, dental erosion, bronchitis, and stomach pains. Repeated or prolonged over-exposure to this product may result in dermatitis (red, dry, itchy skin) and ulceration. This product is not flammable nor reactive under normal circumstances; however, it may produce toxic fumes and vapors.

ALSOLDER 500 SOLDER (85/15)

There are no immediate hazards with these solders. The chief acute health hazard associated with these products would be the potential for inhalation of the fumes during soldering operations. Inhalation of metal oxide and zinc oxide fumes can cause metal fume fever. Symptoms are flu-like. Inhalation of large amounts of particulates generated by these products during metal processing operations can result in pneumoconiosis (a disease of the lungs). Contact with molten solder will burn contaminated tissue. Chronic skin over-exposure to the fumes of these products generated during soldering operations may produce dermatitis (red, inflamed skin).

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