SAFETY DATA SHEET Page 1 / 10 NEXBASE® 3043 Date 28.11 ... · Lubricating oils (petroleum),...

SAFETY DATA SHEET / 10

NEXBASE® 3043 EN

Date 28.11.2013 Previous date: 27.6.2013

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier1.1.1 Commercial Product Name

NEXBASE® 3043

1.1.2 Product code

(ID 12553) 192508, 822600REACH Registration Number01-2119474889-13-0000 / 01-2119474889-13-0003

Substance name Lubricating oils (petroleum), C20-C50, hydrotreated neutral oilbased

1.2 Relevant identified uses of the substance or mixture and uses advised against1.2.1 Recommended use

Manufacture of substanceUse as an intermediateDistribution of substanceFormulation & (re)packing of substances and mixturesUses in CoatingsUse in Cleaning AgentsUse in Oil and Gas field drilling and production operationsMetal working fluids / rolling oilsUse as binders and release agentsUse in AgrochemicalsRoad and construction applications Rubber production and processingPolymer processing LubricantsUse as a fuel Use in laboratoriesMining chemicalsWater treatment chemicalsExplosives manufacture & useFunctional fluid

See the PROC/SU/ERC codes of the identified uses in Section 16.

1.3 Details of the supplier of the safety data sheet1.3.1 Supplier

Neste Oil N.V.

P.O.Box Industriezone Ravenshout 7304Industrieweg 154

Postcode and post office B-3583 Beringen, BELGIUM

Telephone +32 11 459 511

Telefax +32 11 459 512

Business ID BE451.251.225

Email [email protected]

1.4 Emergency telephone number1.4.1 Telephone number, name and address

+358-9-471 977, +358-9-4711, Poison Information Centre/HUS P.O.B 340 (Tukholmankatu 17) 00029 HUS (Helsinki, Finland)

2. HAZARDS IDENTIFICATION


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2.1 Classification of the substance or mixtureIn accordance with paragraph (d) of 2012 29 CFR §1910.1200 [OSHA GHS].

1272/2008 (CLP)Asp. Tox. 1, H304

67/548/EEC - 1999/45/EC-;

2.2 Label elementsIn accordance with paragraph (f) of 2012 29 CFR §1910.1200 [OSHA GHS].

1272/2008 (CLP)GHS08Signal word DangerHazard StatementsH304 May be fatal if swallowed and enters airways.

Precautionary StatementsP301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.P331 Do NOT induce vomiting.P501 Dispose of the content/package according to the local and national regulations.

2.3 Other hazardsOil mist may irritate the eyes and the respiratory tract. Prolonged or repeated skin contact may irritate the skin and produce dermatitis. Risk of soil and ground water contamination.

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances.CAS number Chemical name of the substance Concentration Classification

72623-87-1 /276-38-4(CAS/EC)

Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based; Baseoil - unspecified

100% CLP: Asp. Tox. 1, H304DSD-DPD: -

3.3 Other informationA petroleum product. DMSO extract < 3 Weight % (IP 346). The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346. This note applies only to certain complex oil derived substances. (1272/2008/EC ("CLP"), Annex VI, Note L)

Registration number, See chapter 1.1.2.

4. FIRST AID MEASURES

4.1 Description of first aid measures

4.1.2 Inhalation

Inhalation is unlikely because of the low vapour pressure of the substance at ambient temperature. If breathed in, move person into fresh air. Consult a physician.

4.1.3 Skin contact

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Splashes of hot product cause burns in the eyes and on the skin. Seek medical attention in all cases of serious burns.

4.1.4 Eye contact

Rinse immediately with plenty of water, also under the eyelids. If eye irritation persists, consult a specialist.

4.1.5 Ingestion

DO NOT INDUCE VOMITING. In case of ingestion, always assume that aspiration has occurred. Consult a physician (risk of aspiration into the lungs especially if nausea or irritation occurs).


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4.2 Most important symptoms and effects, both acute and delayedAspiration into the lungs can cause fatal chemical pneumonitis. Oil mist may irritate the eyes and the respiratory tract.

4.3 Indication of immediate medical attention and special treatment neededAspiration into the lungs can cause fatal chemical pneumonitis.

5. FIREFIGHTING MEASURES

5.1 Extinguishing media5.1.1 Suitable extinguishing media

Dry powder, carbon dioxide. Sand. Heavy foam and water fog for professional fire-fighters.

5.1.2 Extinguishing media which must not be used for safety reasons

Water jet.

5.2 Special hazards arising from the substance or mixtureIncomplete combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates, gases, including carbon monoxide

5.3 Advice for firefightersPrecautions for fire-fighting: Self-contained breathing apparatus and full protective clothing.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency proceduresEvacuate unnecessary personnel. Avoid skin contact and inhalation of oil mist. Wear adequate protective equipment at all operations. Spillages make surfaces slippery.

Remove all sources of ignition. Take measures to prevent the build up of electrostatic charge. Large spillages may be cautiously covered with foam, if available, to limit fire risk.

6.2 Environmental precautionsTry to restrict the release and prevent spread of the product into the environment. Collect liquid before it spreads into drains, the ground and waters. In case of spill, immediately contact local authorities. Risk of soil and ground water contamination.

6.3 Methods and materials for containment and cleaning upImmediately start clean-up of the liquid and contaminated soil. Large spills should be collected mechanically (remove by pumping) for disposal. Small amounts can be collected using absorbent material.

If possible, large spillages in open waters should be contained with floating barriers or other mechanical means. If this not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means. The use of dispersants should be advised by an expert, and, if required, approved by local authorities

6.4 Reference to other sectionsFor personal protection see section 8. Product waste should be disposed in accordance with section 13.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling


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Provide sufficient ventilation when handling the product. Avoid skin contact and inhalation of oil mist. Wear protective equipment when needed. Do not ingest. When using, do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Spillages make surfaces slippery. Wear safety shoes while handling containers.

Keep away from fire, sparks and heated surfaces. Take measures to prevent the build up of electrostatic charge. Avoid splash filling of bulk volumes when handling hot liquid product For personal protection see section 8.

7.2 Conditions for safe storage, including any incompatibilitiesKeep tightly closed in a dry, cool and well-ventilated place. Protect against light. Take precautionary measures to prevent product spills into drains, the ground or waters. Take precautions against leakage by constructing collecting pools and sewerage systems as well as by surfacing the loading and unloading stations. Store in accordance with local regulations..

Keep in properly labelled containers. Recommended materials for containers, or container linings use mild steel, stainless steel. Some synthetic materials may be unsuitable for containers or container linings depending on the material specification and intended use.

7.3 Specific end use(s)None known.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

8.1.1 Threshold limits

5 mg/m3 (8 h)HTP 2011/ FIN

Oil mist

8.1.2 Other information on limit values

The occupational exposure monitoring method: Oil mist: NIOSH Method 5026, SFS-EN 689.

8.1.3 Limit values in other countries

5 mg/m³, TWA PEL (OSHA)5 mg/m³, TLV-TWA (ACGIH)10 mg/m³, TLV-STEL (ACGIH)

8.1.4 DNELs

No information available.

8.1.5 PNECs

No information available.

8.2 Exposure controls8.2.1 Appropriate engineering controls

Ensure adequate ventilation. Use personal protective equipment and/or local ventilation when needed.

8.2.2 Individual protection measures8.2.2.1 Respiratory protection

Oil mist: respirator (combined particle and organic vapour filter, type A2/P2). Filter device could be used maximum 2 hours at a time. Filter devices must not be used in conditions where the oxygen level is low (< 17 vol.-%). At high concentrations a breathing apparatus must be used (self-contained or fresh air hose breathing apparatus). Filter must be changed often enough. Respirators according to standards EN 140 and EN 141.

8.2.2.2 Hand protection

Protective gloves: PVC, nitrile rubber. Change protective gloves regularly. Protective gloves according to standards EN 420 and EN 374.

8.2.2.3 Eye/face protection

Tightly fitting safety goggles.

8.2.2.4 Skin protection

Protective clothing (antistatic), splash-proof chemical protective clothing when needed.


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8.2.3 Environmental exposure controls

Take precautions against leakage by constructing collecting pools and sewerage systems as well as by surfacing the loading and unloading stations.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties9.1.1 Appearance

colourless, clear liquid.

9.1.2 Odour almost odourless

9.1.3 Odour threshold -

9.1.4 pH -

9.1.5 Melting point/freezing point Pour point / Melting point (Melting/pour point) ≤ -12 °C (ASTM D-97).

9.1.6 Initial boiling point and boiling range 350-600 °C

9.1.7 Flash point > 220°C (ASTM D-92).

9.1.8 Evaporation rate -

9.1.9 Flammability (solid, gas) -

9.1.10 Explosive properties9.1.10.1 Lower explosion limit -

9.1.10.2 Upper explosion limit -

9.1.11 Vapour pressure < 0,1 hPa (20 °C)

9.1.12 Vapour density -

9.1.13 Relative density 0,82-0,84 (15°C) (ASTM D-4052).

9.1.14 Solubility(ies)9.1.14.1 Water solubility insoluble

9.1.14.2 Fat solubility (solvent /oil to be specified) -

9.1.15 Partition coefficient: n-octanol/water Base oil hydrocarbons log Kow > 6

9.1.16 Auto-ignition temperature -

9.1.17 Decomposition temperature -

9.1.18 Viscosity Kinematic viscosity, typical value: 20 mm²/s (40°C) (ASTM D-445)

9.1.19 Explosive properties None.

9.1.20 Oxidising properties None.

9.2 Other informationMelting/pour point ≤ -12 °C (ASTM D-97)Viscosity, dynamic 39,4 mPa.s (+20°C)Viscosity, dynamic approx. 50 mPa.s (+16°C)

10. STABILITY AND REACTIVITY

10.1 ReactivityNo dangerous reaction known under conditions of normal use.

10.2 Chemical stabilityStable under recommended storage conditions.

10.3 Possibility of hazardous reactionsNone known.


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10.4 Conditions to avoidKeep away from fire, sparks and heated surfaces.

10.5 Incompatible materialsIncompatible with strong acids and oxidizing agents.

10.6 Hazardous decomposition productsNo hazardous decomposition products are known.

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

11.1.1 Acute toxicity

Very low toxicity:LD50/oral/rat > 5000 mg/kg (OECD 401).LD50/dermal/rabbit > 2000 mg/kg (OECD 402).LC50/inhalation/4h/rat = > 5,53 mg/L (OECD 403).

11.1.2 Irritation and corrosion

Not classified. (OECD 404, 405). Oil mist may irritate the eyes and the respiratory tract. Prolonged or repeated skin contact may irritate the skin and produce dermatitis.

11.1.3 Sensitisation

Not a skin sensitizer. (OECD 406)

11.1.4 Subacute, subchronic and prolonged toxicity

Not classifiable as a human carcinogen. (OECD 451, 453).No toxicity to reproduction (OECD 421).Damage to fetus not classifiable (OECD 414).Genotoxicity tests (in vitro and in vivo) have been negative. (OECD 471, 473, 474, 476)

11.1.5 STOT-single exposure

No known effect.

11.1.6 STOT-repeated exposure

No known effect. (OECD 408, 410, 411, 412, 453)

11.1.7 Aspiration hazard

Aspiration into the lungs can cause fatal chemical pneumonitis.

11.1.8 Other information on acute toxicity

Toxicological data are based on tests with corresponding products or componentsUsed oils may contain accumulated contaminants dangerous to health and the environment.

NTP: Not listed. IARC: Not listed.

12. ECOLOGICAL INFORMATION

12.1 Toxicity12.1.1 Aquatic toxicity

Very low toxicity:

Acute aquatic toxicityfish: LL50/96h > 100 mg/L; NOEL/96h >= 100 mg/L (OECD 203)crustacean: EL50/24-48h; NOEL/48-96h; LL50/24-96h > 10 000 mg/L (OECD 202)alga: NOEL/72h >= 100 mg/L (OECD 201)

Chronic aquatic toxicity:crustacean: NOEL/21d = 10 mg/L (OECD 211)


NEXBASE® 3043 EN


12.1.2 Toxicity to other organisms

Very low toxicity. Toxicity to microorganisms: NOEL/10min > 1,93 mg/L (DIN 38412, DIN38409)

12.2 Persistence and degradability12.2.1 Biodegradation

Not readily degradable (OECD301B).

12.2.2 Chemical degradation

Not readily degradable.

12.3 Bioaccumulative potentialBase oil hydrocarbons are possibly accumulative (log Kow > 6).

12.4 Mobility in soilThe product is insoluble in water and mainly not volatile. Product can penetrate soil until reaching the surface of ground water. Degradation occurs extremely slowly under anaerobic conditions. Base oil hydrocarbons can be adsorbed onto organic material in soil or sediment (log Kow > 6).

12.5 Results of PBT and vPvB assessmentThis substance is not considered to be persistent, bioaccumulating nor toxic (PBT). This substance is not considered to be very persistent nor very bioaccumulating (vPvB). (anthracene < 0,1 %)

12.6 Other adverse effectsInformation given is based on data on the components and the ecotoxicology of similar products.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methodsProduct waste is hazardous waste. It should be treated according to national regulations and local authorities' advice.

13.2 Waste from residues / unused productsUsed oils may contain accumulated contaminants dangerous to health and the environment. Empty containers may contain combustible product residues Empty containers should be taken for local recycling or waste disposal.

14. TRANSPORT INFORMATION

14.1 UN number Not classified as dangerous in the meaning of transport regulations.

14.2 UN proper shipping name -

14.3 Transport hazard class(es) -

14.4 Packing group -

14.5 Environmental hazards-

14.6 Special precautions for users-

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeBulk : (MARPOL 73/78, Annex II): Noxious liquid, NF, (5) n.o.s. ( NEXBASE 3043, contains Cycloalkanes C 12+), ST 2, Cat. Y. According to MARPOL: "Non-solidifying substance".

15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture


NEXBASE® 3043 EN


WGK = 1 (Wassergefährdungsklasse, Germany)

To the best of our knowledge, the product components are not listed on any US national/regional regulatory lists except the TSCA inventory.

The product has been listed in the following chemical inventories: TSCA (USA), DSL (Canada), AICS (Australia), ECL (South Korea), PICCS (Philippines), NZIoC (New Zealand), IECS (China), ENCS (Japan); inventories of Taiwan and Switzerland.

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Updated according to regulation (EU) N:o 453/2010 amending regulation (EC) N:o 1907/2006 (REACH).

15.2 Chemical safety assessmentA Chemical Safety Assessment has been carried out for this substance.

16. OTHER INFORMATION

16.1 Additions, Deletions, Revisions9.1.18 Viscosity 9.2 Further information 16.8 Date of last revision

16.2 Key or legend to abbreviations and acronymsCLP= Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006DSD= Council Directive (67/548/EEC) on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances DPD= Directive 1999/45/EC of the European Parliament and of the Council concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations

DNEL = Derived No-Effect LevelPNEC = Predicted No-Effect ConcentrationPROC = Process CategoryPC = Product CategorySU = Sector of UseERC = Environmental Release Category

PEL = Permissible Exposure LimitSTEL = Short-Term Exposure LimitTLV = Threshold Limit ValueTWA = Time-Weighted Average

OSHA = Occupational Safety and Health AdministrationACGIH = American Conference of Governmental Industrial Hygienists

IARC = International Agency for Research on CancerNTP = National Toxicology Program

16.3 Key literature references and sources for dataConcawe Report no. 11/2010; Hazard Classification and labelling of petroleum substances in the EEA - 2010 (Concawe, 2010).Chemical Safety Report; Other Lubricant Base Oils (Concawe, 2012).

16.5 List of relevant R phrases, hazard statements, safety phrases and/or precautionarystatements


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H304 May be fatal if swallowed and enters airways.

16.7 Recommended restrictionsIdentified uses:

Manufacture of substance (PROC 1, 2, 3, 4, 8a/b, 15; SU 3, 8, 9; ERC 4)Use as an intermediate (PROC 1, 2, 3, 4, 8a/b, 15; SU 3, 8, 9; ERC 6a)Distribution of substance (PROC 1, 2, 3, 4, 8a/b, 9, 15; SU 3; ERC 4, 5, 6a/b/c/d, 7)Formulation & (re)packing of substances and mixtures (PROC 1, 2, 3, 4, 5, 8a/b, 9, 14, 15; SU 10; ERC 2)Uses in Coatings:Industrial use (PROC 1, 2, 3, 4, 5, 7, 8a/b, 10, 13, 15; SU 3; ERC 4);Professional use (PROC 1, 2, 3, 4, 5, 8a/b, 10, 11, 13, 15, 19; SU 22; ERC 8a/d);Consumers (PC 1, 4, 8, 9a/b/c, 18, 23, 24, 31, 34; SU 21; ERC 8a/d)Use in Cleaning Agents:Industrial use (PROC 1, 2, 3, 4, 7, 8a/b, 10, 13, SU 3; ERC 4);Professional use (PROC 1, 2, 3, 4, 5, 8a/b, 10, 11, 13, 15, 19; SU 22; ERC 8a/d);Consumers (PC 1, 4, 5, 8, 9, 10, 18, 23, 24, 31; SU 21; ERC 8a/d)Use in Oil and Gas field drilling and production operations:Industrial use (PROC 1, 2, 3, 4, 8a/b; SU 3; ERC 4);Professional use (PROC 1, 2, 3, 4, 8a/b; SU 22; ERC 9b)Metal working fluids / rolling oils:Industrial use (PROC 1, 2, 3, 4, 5, 7, 8a/b, 9, 10, 13, 17; SU 3; ERC 4);Professional use (PROC 1, 2, 3, 5, 8a/b, 10, 11, 13, 17; SU 22; ERC 8a/d)Use as binders and release agents:Industrial use (PROC 1, 2, 3, 4, 6, 7, 8b, 10, 13, 14; SU 3; ERC 4);Professional use (PROC 1, 2, 3, 4, 6, 8a/b, 10, 11, 14; SU 22; ERC 8a/d)Use in Agrochemicals:Professional use (PROC 1, 2, 4, 8a/b, 11, 13; SU 22; ERC 8a/d);Consumers (PC 12, 27; SU 21; ERC 8a/d)Road and construction applications: Professional use (PROC 8a/b, 9, 10, 11, 13; SU 22; ERC 8d/f)Rubber production and processing: Industrial use (PROC 1, 2, 3, 4, 5, 6, 7, 8a/b, 10, 13, 14, 15, 21; SU 3, 10, 11; ERC 4, 6d)Polymer processing:Industrial use (PROC 1, 2, 3, 4, 5, 6, 8a/b, 9, 13, 14, 21; SU 10; ERC 4, 6d);Professional use (PROC 1, 2, 6, 8a/b, 14, 21; SU 22; ERC 8a/d)Use as a fuel:Industrial use (PROC 1, 2, 3, 8a/b, 16; SU 3; ERC 7)Professional use (PROC 1, 2, 3, 8a/b, 16; SU 22; ERC 9a/b)Consumers (PC 13; SU 21; ERC 9a/b)Lubricants: Industrial use (PROC 1, 2, 3, 4, 7, 8a/b, 9, 10, 13, 17, 18; SU 3; ERC 4, 7);Professional use (PROC 1, 2, 3, 4, 8a/b, 9, 13, 17, 20; SU 22; ERC (low release) 9a/b; ERC (high release) 8a/d);Consumers (PC 1, 24, 31; SU 21; ERC (low release) 9a/b; ERC (high release) 8a/d)Use in laboratories:Industrial use (PROC 10, 15, SU 3; ERC 4);Professional use (PROC 10, 15, SU 22; ERC 8a)Mining chemicals: Industrial use (PROC 1, 2, 3, 4, 5, 8a/b, 9; SU 10; ERC 4)Water treatment chemicals:Industrial use (PROC 1, 2, 3, 4, 8a/b, 13; SU 10; ERC 4);Professional use (PROC 1, 2, 3, 4, 8a/b, 13; SU 22; ERC 8a/d/f)Explosives manufacture & use: Professional use (PROC 1, 3, 5, 8a/b; SU 22; ERC 8e)Functional fluid:Industrial use (PROC 1, 2, 3, 4, 8a/b, 9; SU 3; ERC 7);Professional use (PROC 1, 2, 3, 8a, 9, 20; SU 22; ERC 9a/b);Consumers (PC 16, 17; SU 21; ERC 9a/b)


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16.8 Further informationDate of last revision: 28 November 2013

ADDITIONAL INFORMATION AVAILABLE FROM: Neste Oil Corporation, Base Oils, Finland, tel. +358 10 45811, fax +358 10 45 85244 , e-mail: [email protected] Neste Oil N.V., Beringen, Belgium tel. +32 11 459 511, fax. +32 11 459 512, e-mail: [email protected]

ANNEX TO THE SAFETY DATA SHEET Page 1 / 125

NEXBASE 3043 [ENG] Date: 19.6.2013 Previous date: - ID 12553

SECTION 1 EXPOSURE SCENARIO TITLE Title 1. Manufacture of Substance - Industrial

Use Descriptor Sector(s) of Use SU 3: Industrial uses

SU 8: Manufacture of bulk, large scale chemicals (including petroleum products)

SU 9: Manufacture of fine chemicals

Process Categories PROC 1: Use in closed process, no likelihood of exposure.

PROC 2: Use in closed, continuous process with occasional controlled exposure.

PROC 3: Use in closed batch process (synthesis or formulation).

PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.

PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.

PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.

PROC 15: Use as laboratory reagent

Environmental Release Categories

ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles

Specific Environmental Release Category

ESVOC 1.1.v1

Processes, Tasks and Activities Covered

Manufacture of the substance or use as an intermediate or a process chemical or extraction agent. Includes recycling/recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and bulk container).

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure

Product characteristics

Physical form of product Liquid, with potential for aerosol generation [CS138]

Vapour pressure < 0.5 kPa at STP. [OC3]

Concentration of substance in product

Covers percentage substance in the product up to 100% (unless stated

differently) [G13]

Frequency and duration of use

Covers daily exposures up to 8 hours (unless stated differently). [G2].

Other operational conditions affecting worker exposure

Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]

Assumes a good basic standard of occupational hygiene is implemented. [G1].

Contributing Scenarios

Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)

General exposures (closed systems) [CS15]

No other specific measures identified. [EI20]

General exposures (open systems) [CS16]


Process sampling [CS2] No other specific measures identified. [EI20]

ANNEX TO THE SAFETY DATA SHEET Page 2 / 125 NEXBASE 3043 [ENG] Date: 19.6.2013 Previous date: - ID 12553

Laboratory activities [CS36]


Bulk transfers [CS14] (open systems) [CS108]


Bulk transfers [CS14] (closed systems) [CS107]


Equipment cleaning and maintenance [CS39]

Drain down system prior to equipment break-in or maintenance [E65]

Bulk product storage [CS67]

Store substance within a closed system [E84]

Section 2.2 Control of environmental exposure

Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].

Amounts used Fraction of EU tonnage used in region: 0.1

Regional use tonnage (tonnes/year): 8.5E+5

Fraction of regional tonnage used locally: 1

Annual site tonnage (tonnes/year): 6.0E+5

Maximum daily site tonnage (kg/day): 2.0E+6


Continuous release. [FD2].

Emission days (days/year): 300

Environmental factors not influenced by risk management

Local freshwater dilution factor: 10

Local marine dilution factor: 100

Other operational conditions affecting environmental exposure

Release fraction to air from process (initial release prior to RMM): 1.0E-4

Release fraction to wastewater from process (initial release prior to RMM): 1.0E-5

Release fraction to soil from process (initial release prior to RMM): 0.0001

Technical conditions and measures at process level (source) to prevent release

Common practices vary across sites thus conservative process release estimates used [TCS1].

Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil

Risk from environmental exposure is driven by Freshwater Sediment [TCR1b].

Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14].

If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].

Treat air emission to provide a typical removal efficiency of 90%.

Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 84.8 %

If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %


Organizational measures to prevent / limit release from site

Do not apply industrial sludge to natural soils [OMS2].

Sludge should be incinerated, contained or reclaimed [OMS3].

Conditions and measures related to municipal sewage treatment plant

Not applicable as there is no release to wastewater [STP1].

Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.

Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.

Maximum allowable site tonnage (MSafe) based on following total wastewater treatment removal 5.7E+6 kg per day.

Assumed domestic sewage treatment plant flow 10 000 m3 per day.

Conditions and measures related to external treatment of waste for disposal

During manufacturing no waste of the substance is generated [ETW4].

Conditions and measures related to external recovery of waste

During manufacturing no waste of the substance is generated [ERW2].

SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health

The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].

Section 3.2 Environment

The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].

SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health

Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. G22.

Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. G23.

Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. G32. Available hazard data do not support the need for a DNEL to be established for other health effects. G36. Risk Management Measures are based on qualitative risk characterisation. G37.


Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4]. Scaled assessments for EU refineries have been performed using site-specific data and are attached in PETRORISK file – “Site-Specific Production” worksheet [DSU6].

http://cefic.org/en/reach-for-industries-libraries.html


SECTION 1 EXPOSURE SCENARIO TITLE Title 2. Use as Substance as Intermediate - Industrial


SU 8: Manufacture of bulk, large scale chemicals (including petroleum products)

SU 9: Manufacture of fine chemicals









ERC 6a: Industrial use resulting in manufacture of another substance (use of intermediates)


ESVOC 6.1a.v1


Manufacture of the substance or use as an intermediate or process chemical or extraction agent. Includes recycling/ recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and bulk container).




Vapour pressure < 0.5 kPa at STP. [OC3]


Covers percentage substance in the product up to 100% (unless stated differently) [G13]




Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].

















Bulk product storage [CS67]

Store substance within a closed system [E84]














Other given operational conditions affecting environmental exposure

Release fraction to air from process (initial release prior to RMM: 1.0E-5






Risk from environmental exposure is driven by Freshwater Sediment [TCR1a].














Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 9.8E+4 kg per day.



This substance is consumed during use and no waste of the substance is generated. [ETW5]


This substance is consumed during use and no waste of the substance is generated. [ERW3]






Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. G22.

Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. G23.

Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. G32. Available hazard data do not support the need for a DNEL to be established for other health effects. G36. Risk Management Measures are based on qualitative risk characterisation. G37.


Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].




SECTION 1 EXPOSURE SCENARIO TITLE Title 3. Distribution of Substance – Industrial








PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)




ERC 5: Industrial use resulting in inclusion into or onto a matrix

ERC 6a: Industrial use resulting in manufacture of another substance (use of intermediates)

ERC 6b: Industrial use of reactive processing aids

ERC6c: Industrial use of monomers for manufacture of thermoplastics

ERC 6d: Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers

ERC 7: Industrial use of substances in closed systems


ESVOC 1.1b.v1


Bulk loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) of substance, including its sampling, storage, unloading, maintenance and associated laboratory activities. Excludes emissions during transport.



Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]







Contributing Specific Risk Management Measures and Operational Conditions


Scenarios (only required controls to demonstrate safe use listed)












Drum and small package filling [CS6]



Drain down system prior to equipment break-in or maintenance. [E65]

Storage [CS67] Store substance within a closed system. [E84]





















Risk from environmental exposure is driven by Freshwater Sediment [TCR1b].



Treat onsite wastewater (prior to receiving water discharge) to provide


the required removal efficiency ≥ 64.4 %












External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].


External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].






Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].

Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].

Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].






SECTION 1 EXPOSURE SCENARIO TITLE Title 4. Formulation & (re)packing of substances and mixtures

Use Descriptor Sector(s) of Use SU 10: Formulation [mixing] of preparations and/or re-packaging (excluding alloys)





PROC 5: Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact)



PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)

PROC 14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation



ERC 2: Formulation of preparations


ESVOC 2.2.v1


Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, tabletting, compression, pelletization, extrusion, large and small scale packing, maintenance, sampling and associated laboratory activities

















Batch processes at elevated temperatures [CS136]


Use in contained batch processes [CS37]




Bulk transfers [CS14] Dedicated facility [CS81]


Mixing operations (open systems) [CS30]


Transfer from/pouring from containers [CS34] Manual [CS22] Non-dedicated facility [CS82]


Drum/batch transfers [CS8] Dedicated facility [CS81]


Production or preparation or articles by tabletting, compression, extrusion or pelletisation [CS100]


Drum and small package filling [CS6]



















Release fraction to air from process (after typical onsite RMMs, consistent with EU Solvent Emissions Directive requirements): 1.5E-3

Release fraction to wastewater from process (initial release prior to


RMM): 5.0E-6





Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]




















ECETOC TRA has been used to estimate workplace exposures unless otherwise indicated [G21].





Where other Risk Management Measures/Operational Conditions are adopted, then users should


ensure that risks are managed to at least equivalent levels. [G23].







SECTION 1 EXPOSURE SCENARIO TITLE Title 5. Uses in Coatings – Industrial







PROC 7: Industrial spraying



PROC 10: Roller application or brushing

PROC 13: Treatment of articles by dipping and pouring





ESVOC 4.3a.v1


Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, spreader, dip, flow, fluidised bed on production lines and film formation) and equipment cleaning, maintenance and associated laboratory activities.







Covers daily exposures up to 8 hours (unless stated diffetently). [G2].





General exposures (closed systems) [CS15] with sample collection [CS56]

No other specific measures identified [EI20]




Film formation – force drying, stoving and other technologies [CS99] Use in contained systems [CS38] Elevated temperature [CS111]


Film formation - air drying [CS95] [CS108] (Open systems)


Preparation of material for application [CS96] Mixing operations (closed systems) [CS29]


Preparation of material for application [CS96] Mixing operations (open systems) [CS30]


Spraying (automatic/robotic) [CS97]

Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60]

Spraying/fogging by manual application [CS24]

Wear a respirator conforming to EN140 with Type A filter or better. [PPE22]

Material transfers [CS3] Non-dedicated facility [CS82]


Material transfers [CS3] Dedicated facility [CS81]


Roller, spreader, flow application [CS98]


Dipping, immersion and pouring [CS4]




Material transfers [CS3] Drum/batch transfers [CS8] Transfer from/pouring from containers [CS22]


Production or preparation or articles by tabletting, compression, extrusion or pelletisation [CS100]




Storage [CS67] Store substance within a closed system [E84]
















Release fraction to air from process (initial release prior to RMM): 0.98


Release fraction to soil from process (initial release prior to RMM): 0




Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation). [TCR1k]



Treat air emission to provide a typical removal efficiency of 90 %.










Maximum allowable site tonnage (MSafe) based on release following totalwastewater treatment removal 1.0E+5 kg per day.




Conditions and measures related to external

External recovery and recycling of waste should comply with applicable


recovery of waste local and/or national regulations [ERW1].






Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22]


Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. G32. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].





SECTION 1 EXPOSURE SCENARIO TITLE Title 6. Uses in Coatings – Professional

Use Descriptor Sector(s) of Use SU 22: Professional uses:









PROC11: Non industrial spraying



PROC 19: Hand-mixing with intimate contact and only PPE available


ERC 8a: Wide dispersive indoor use of processing aids in open systems

ERC 8d: Wide dispersive outdoor use of processing aids in open systems


ESVOC 8.3b.v1


Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, brush, spreader by hand or similar methods, and film formation), and equipment cleaning, maintenance and associated laboratory activities.



Physical form of product Liquid, with potential for aerosol generation. [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]







Contributing Specific Risk Management Measures and Operational Conditions


Scenarios (only required controls to demonstrate safe use listed)

Filling / preparation of equipment from drums or containers. [CS45] Dedicated facility [CS81]




Preparation of material for application [CS96] Mixing operations (closed systems) [CS29]


Film formation - air drying (indoor/outdoor) [CS95]


Preparation of material for application [CS96] Mixing operations (open systems) [CS30] Pouring from small Containers [CS9] (indoor / outdoor)


Material transfers [CS3] Drum/batch transfers [CS8] Non-dedicated facility [CS82]

Use drum pumps. [E53]

Roller, spreader, flow application [CS98] (indoor/outdoor)


Spraying/fogging by manual application [CS24] Indoor [OC8]

Carry out in a vented booth or extracted enclosure. [E57]

Spraying/fogging by manual application [CS24] Outdoor [OC8]

Wear a half mask respirator conforming to EN140, 149 or equivalent [PPE22]

Dipping, immersion and pouring [CS4] (indoor/outdoor)




Hand application – finger paints, pastels, adhesives [CS72] (indoor/outdoor)





















Release fraction to wastewater from process (initial release prior to RMM): 0.01







Treat air emission to provide a typical removal efficiency of N/A.










Maximum allowable site tonnage (MSafe) based on domestic sewage treatment release 3.5E+1 kg per day.








SECTION 1 EXPOSURE SCENARIO TITLE Title 7. Uses in Coatings - Consumer

Use Descriptor Sector(s) of Use SU 21: Consumer uses

Products Categories PC 1: Adhesives, sealants

PC 4: Anti-Freeze and de-icing products

PC 8: Biocidal products (e.g. Disinfectants, pest control)

PC 9a: Coatings and paints, thinners, paint removers

PC 9b: Fillers, putties, plasters, modelling clay

PC 9c: Finger paints

PC 18: Ink and toners

PC 23: Leather tanning, dye, finishing, impregnation and care products

PC 24: Lubricants, greases, release products

PC 31: Polishes and wax blends

PC 34: Textile dyes, finishing and impregnating products; including bleaches and other processing aids.


ERC 8a: Wide dispersive indoor use of processing aids in open systems.

ERC 8d: Wide dispersive outdoor use of processing aids in open systems.


ESVOC 8.3c.v1


Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning.

SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of consumer exposure



Vapour Pressure (kPa) Liquid, vapour pressure < 0.5 kPa at STP. [OC3]



Frequency and duration of use/exposure

Covers daily exposures up to 8 hours (unless stated differently) [G2]

Other operational conditions affecting exposure


Product Category

Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed)

No exposure scenario presented for human health. Re fer to Appendix 2 for the qualitative assessment of consumer aerosol exposure.

Section 2.2 Control of environmental exposure Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.


[PrC4a].



Fraction of regional tonnage used locally: 0.0005

Annual site tonnage (tonnes/year): .1.0E+0









Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.985

Release fraction to wastewater wide dispersive use [OOC8]: 0.01

Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.005




Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal (kg/d) 1.9E+3.

Assumed domestic sewage treatment plant flow (m3/day): 2000





SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.

[G21]









Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures.


SECTION 1 EXPOSURE SCENARIO TITLE Title 8. Use in Cleaning Agents – Industrial














ESVOC 4.4a.v1


Covers the use as a component of cleaning products including transfer from storage, pouring/unloading from drums or containers. Exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping, automated and by hand), related equipment cleaning and maintenance.





Covers percentage substance in the product up to 100% (unless stated differently). [G13]









Automated process with (semi) closed systems. [CS93] Use in contained



systems[CS38]



Automated process with (semi) closed systems.[CS93] Use in contained batch processes [CS37] Elevated temperature [CS111]




Cleaning with low-pressure washers [CS42]


Cleaning with high-pressure washers [CS44]

Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings[E60]

Manual [CS34] Cleaning [CS47] Surfaces [CS48] no spraying [CS60]
























Technical onsite conditions and measures to reduce or limit

Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] Prevent discharge of undissolved substance to or recover from onsite


discharges, air emissions and releases to soil

wastewater [TCR14]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].










Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %. Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 3.3E+4 kg per day. Assumed domestic sewage treatment plant flow 2 000 m3 per day.














Environment Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet


(http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].



SECTION 1 EXPOSURE SCENARIO TITLE Title 9. Use in Cleaning Agents – Professional






PROC 5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact)







PROC 19: Hand-mixing with intimate contact and only PPE available





ESVOC 8.4b.v1


Covers the use as a component of cleaning products including pouring/unloading from drums or containers; and exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping automated and by hand).













Filling / preparation of equipment from drums or containers. [CS45]

Avoid carrying out activities involving exposure for more than 1 hours [OC27]

Automated process with (semi) closed systems. [CS93] Use in contained systems [CS38]


Semi Automated process. (e.g.: Semiautomatic application of floor care and maintenance products) [CS76]


Filling / preparation of equipment from drums or containers. [CS45] Non-dedicated facility [CS82] Outdoor [OC9]

Use drum pumps [E53]

Manual [CS34] Surfaces [CS48] Cleaning [CS47] Dipping, immersion and pouring [CS4]


Cleaning with low-pressure washers [CS42] Rolling, Brushing [CS51]


Cleaning with high pressure washers [CS44] Spraying [CS10] (Indoor / outdoor)


Treatment by dipping and pouring [CS34] Surfaces [CS48] Cleaning [CS47] Wiping [CS50] Rolling, Brushing [CS51]


Degreasing small objects in cleaning station [CS41]


Ad hoc manual application via trigger sprays, dipping, etc. [CS27]


Hand-mixing with intimate contact and only PPE available Indoor


Cleaning of medical devices [CS74]






Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.


[PrC4a].















Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0




Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].















Conditions and measures External recovery and recycling of waste should comply with applicable local and/or national regulations. [ERW1]


related to external recovery of waste






Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22.]








SECTION 1 EXPOSURE SCENARIO TITLE Title 10. Use in Cleaning Agents – Consumer


Products Categories PC 3: Air care products

PC 4: Anti-Freeze and de-icing products

PC 8: Biocidal products (e.g. Disinfectants, pest control)

PC 9a: Coatings and paints, thinners, paint removers


PC 35: Washing and cleaning products (including solvent based products)

PC 38: Welding and soldering products (with flux coatings or flux cores.), flux products





ESVOC 8.4c.v1


Covers general exposures to consumers arising from the use of household products sold as washing and cleaning products, aerosols, coatings, lubricants and air care products.










Product Category




[PrC4a].




















Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal (kg/d) 1.8 E+1.







[G21]










SECTION 1 EXPOSURE SCENARIO TITLE Title 11. Use in Oil and Gas Field Drilling and Production Operations – Industrial CES5.1











Not Applicable


Offshore and onshore oil field well drilling (including drilling muds use and well cleaning) and hydraulic fracturing operations; including material transfers, on-site formulation of drilling/fracturing fluid, well head/well bore operations, shaker room activities and related maintenance.



Physical form of product Liquid, vapour pressure < 0.5 kPa at STP [OC3].



Amount used No limit.


Covers daily exposures up to 8 hours (unless stated). [G2].


Assumes use at not > 20oC above ambient [G15].

Assumes a good basic standard of occupational hygiene has been implemented [G1]







Drilling mud (re-) formulation [CS115] Use in contained batch processes [CS37]



Drill floor operations [CS116]


Operation of solids filtering equipment [CS117] Elevated temperature [CS111]

Provide the operation with a properly sited receiving hood [E71]

Cleaning of solids filtering equipment [CS120] Non-dedicated facility [CS82]


Treatment and disposal of filtered solids [CS121] Use in contained batch processes [CS37]





Pouring from small containers [CS9] Non-dedicated facility [CS82]











Amounts used Fraction of EU tonnage used in region [A1]: 1

Regional use tonnage (tonnes/year) [A2]: 10

Fraction of regional tonnage used locally [A3]: N/A

Annual site tonnage (tonnes/year) [A5]: N/A

Maximum daily site tonnage (kg/day) [A4]: N/A


Emission days (days/year) [FD4]: N/A


Local freshwater dilution factor [EF1]: N/A

Local marine water dilution factor [EF2]: N/A


Release fraction to air from process (initial release prior to RMM): N/A

Release fraction to wastewater from process (initial release prior to RMM): N/A


Discharge to aquatic environment is restricted (see Section 4.2) [TCS2].




Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency N/A.

If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of N/A.


Prevent environmental discharge consistent with regulatory requirements [OMS4].


Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs (%) N/A

Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal (kg/d) N/A

Assumed domestic sewage treatment plant flow (m3/d) N/A


External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3]. Cuttings and process water are disposed according to local and/or national regulations.


External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1]. Cuttings and process water are re-injected according to local and/or national regulations.


Estimated workplace exposures are not expected to exceed DNELs when the identified risk management measures are adopted. [G8]


Quantitative exposure and risk assessment not possible due to lack of emissions to aquatic environment [EE7]. Qualitative approach used to conclude safe use [EE8].




Offshore drilling Discharge to aquatic environment is restricted by law and industry prohibits release1 [DSU9]. 1OSPAR Commission 2009. Discharges, Spills and Emissions from Offshore Oil and Gas Installations in 2007, including the assessment of data reported in 2006 and 2007. Onshore drilling Environmental releases are minimized during onshore drilling operations2; waste recycling and disposal is managed according to national and/or local regulations3. 2 International Finance Corporation 2007. Environmental, Health, and Safety Guidelines: onshore oil and gas development. 3Mining Waste Directive (2006/21/EC), European Waste Directive (2008/98/EC) and national transpositions, e.g. Novelle des Kreislaufwirtschaftsgesetzes (KrWG) in Germany Hydraulic fracturing Releases to surface water and soil are minimized during hydraulic fracturing operations. Releases to groundwater are controlled by existing local and EU4 regulations. 4 European Groundwater Directive (2006/118/EC), complementary to the Water Framework Directive.


SECTION 1 EXPOSURE SCENARIO TITLE Title 12. Use in Oil and Gas Field Drilling and Production Operations – Professional

CES5.2

Use Descriptor Sector(s) of Use SU 22: Professional uses








ERC 9b: Wide dispersive outdoor use of substances in closed systems


Not Applicable


Oil field well drilling operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related maintenance.



Physical form of product Liquid, vapour pressure < 0.5 kPa at STP [OC3].



Amount used No limit.




Assumes use at not > 20oC above ambient [G15].

Assumes a good basic standard of occupational hygiene has been implemented [G1]







Drilling mud (re-) formulation [CS115] Use in contained batch processes [CS37]



Drill floor operations [CS116]


Operation of solids filtering equipment –aerosol exposures [CS118] Elevated temperature [CS111]

Provide the operation with a properly sited receiving hood [E71]

Cleaning of solids filtering equipment [CS120] Non-dedivated facility [CS82]

Provide extract ventilation to points where emissions occur [E54]

Treatment and disposal of filtered solids [CS121] Use in contained batch processes [CS37]





Pouring from small containers [CS9] Non-dedicated facility [CS82]

Carefully pour from containers [E62]










Amounts used Fraction of EU tonnage used in region [A1]: 1

Regional use tonnage (tonnes/year) [A2]: 10

Fraction of regional tonnage used locally [A3]: N/A

Annual site tonnage (tonnes/year) [A5]: N/A

Maximum daily site tonnage (kg/day) [A4]: N/A


Emission days (days/year) [FD4]: N/A


Local freshwater dilution factor [EF1]: N/A

Local marine water dilution factor [EF2]: N/A


Release fraction to air from wide dispersive use (regional use only) [OOC7]: N/A Release fraction to wastewater wide dispersive use [OOC8]: N/A

Technical conditions and measures at process level

Discharge to aquatic environment is restricted (see Section 4.2) [TCS2].


(source) to prevent release



Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency N/A.

If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of N/A.


Prevent environmental discharge consistent with regulatory requirements [OMS4].


Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs (%) N/A

Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal (kg/d) N/A

Assumed domestic sewage treatment plant flow (m3/d) N/A


External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3]. Cuttings and process water are disposed according to local and/or national regulations.


External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1]. uttings and process water are re-injected according to local and/or national regulations.


Estimated workplace exposures are not expected to exceed DNELs when the identified risk management measures are adopted. [G8]


Quantitative exposure and risk assessment not possible due to lack of emissions to aquatic environment [EE7]. Qualitative approach used to conclude safe use [EE8].




Offshore drilling Discharge to aquatic environment is restricted by law and industry prohibits release1 [DSU9]. 1OSPAR Commission 2009. Discharges, Spills and Emissions from Offshore Oil and Gas Installations in 2007, including the assessment of data reported in 2006 and 2007. Onshore drilling Environmental releases are minimized during onshore drilling operations2; waste recycling and disposal is managed according to national and/or local regulations3. 2 International Finance Corporation 2007. Environmental, Health, and Safety Guidelines: onshore oil and gas development. 3Mining Waste Directive (2006/21/EC), European Waste Directive (2008/98/EC) and national transpositions, e.g. Novelle des Kreislaufwirtschaftsgesetzes (KrWG) in Germany Hydraulic fracturing Releases to surface water and soil are minimized during hydraulic fracturing operations. Releases to groundwater are controlled by existing local and EU4 regulations. 4 European Groundwater Directive (2006/118/EC), complementary to the Water Framework


Directive.

SECTION 1 EXPOSURE SCENARIO TITLE Title 13. Use in Metal Working Fluids/Rolling Oils - Industrial






PROC 5: Mixing or blending in batch processes for formulation of preparations* and ar-ticles (multistage and/or significant con-tact)




PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)



PROC 17: Lubrication at high energy conditions and in partly open process




ESVOC 4.7a.v1


Covers the use in formulated MWFs/rolling oils including transfer operations, rolling and annealing activities, cutting/machining activities, automated and manual application of corrosion protections (including brushing, dipping and spraying), equipment maintenance, draining and disposal of waste oils.









Operation is carried out at elevated temperature (> 20°C above ambient temperature). OC7. Assumes a good basic standard of occupational hygiene is implemented. G1.













Metal machining operations [CS79]


Treatment by dipping and pouring [CS35]


Spraying [CS10] Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings E60

Manual [CS34] Roller, brushing [CS51]


Automated metal rolling/forming [CS80] Use in contained systems [CS38] Elevated temperature [CS111]


Semi-automated metal rolling/forming [CS83] Elevated temperature [CS111]


Equipment cleaning and maintenance [CS39] Dedicated facility [CS81]


Equipment cleaning and maintenance [CS39] Non- dedicated facility [CS81]
























Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]. Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10]. Treat air emission to provide a typical removal efficiency of 70%.





















SECTION 1 EXPOSURE SCENARIO TITLE Title 14. Use in Metal working fluids / rolling oils – Professional: high environmental

release






PROC 5: Mixing or blending in batch processes for formulation of preparations* and ar-ticles (multistage and/or significant con-tact)








ERC 8a:

ERC 8d:


ESVOC 8.7c.v1


Covers the use in formulated MWFs including transfer operations, open and contained cutting/machining activities, automated and manual application of corrosion protections, draining and working on contaminated/ reject articles, and disposal of waste oils.



Physical form of product Liquid, with potential for aerosol generation. [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
















Filling / preparation of equipment from drums or containers. [CS45] Non-dedicated facility [CS82]

Avoid carrying out activities involving exposure for more than 1 hour [OC27]


Metal machining operations [CS79]

Provide a good standard of controlled ventilation (10 to 15 air changes per hour) [E40] Avoid carrying out activities involving exposure for more than 4 hours [OC28] Limit the substance content in the product to 25 % [OC18]



Spraying [CS10] Avoid carrying out activities involving exposure for more than 1 hour [OC27] Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11] , or: [G9] Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29]











Annual site tonnage (tonnes/year): 4.5E-1









Release fraction to air from wide dispersive use (regional use only) [OOC7]: 5.0E-3

Release fraction to wastewater wide dispersive use [OOC8]: 0.05 Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.05





Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].


























Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures


[DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].




SECTION 1 EXPOSURE SCENARIO TITLE Title 15. Use as Release Agents or Binders - Industrial






PROC 6: Calendering operations




PROC 14:




ESVOC 4.10a.v1


Covers the use as binders and release agents including material transfers, mixing, application (including spraying and brushing), mould forming and casting, and handling of waste.



Physical form of product Liquid, with potential for aerosol generation. [CS138] Vapour pressure < 0.5 kPa at STP [OC3].









Material transfers [CS3] (closed systems) [CS107]


Drum/batch transfers [CS8] Dedicated facilities [CS81]


Mixing operations (closed systems) [CS29]


Mixing operations (open No other specific measures identified. [EI20]


systems) [CS30]



Mold forming [CS31] No other specific measures identified. [EI20]

Casting operations [CS32] (open systems) [CS108] Elevated temperature [CS111]

Apply extract ventilation to emissions [E60]

Spraying [CS10] Carry out in a vented booth or extracted enclosure [E57] , or: [G9] Wear a full face respirator conforming to EN140 with Type A filter or better. [PPE24]




























Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]. Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].

Treat air emission to provide a typical removal efficiency of 80%



SECTION 1 EXPOSURE SCENARIO TITLE Title 16. Use as Release Agents or Binders – Professional







PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities



PROC 11: Non industrial spraying

PROC 14: Production of preparations or articles by tableting, compression, extrusion, pelletisation





ESVOC 8.10b.v1


Covers the use as binders and release agents including material transfers, mixing, application by spraying, brushing, and handling of waste.










Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1.]



Material transfers [CS3] (closed systems) [CS107]





Drum/batch transfers [CS8] Non-dedicated facility [CS81]






Mold forming [CS31] No other specific measures identified. [EI20]

Casting operations [CS32] (open systems) [CS108] Elevated temperature [CS111]

Apply extract ventilation to emissions [E60]

Spraying [CS10] Machine [CS33]

Carry out in a vented booth or extracted enclosure E57 Avoid carrying out activities involving exposure for more than 4 hours [OC28]

Spraying [CS10] Manual [CS34]

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11] Avoid carrying out activities involving exposure for more than 1 hour [OC27] , or: [G9] Wear a respirator conforming to EN140 with Type A filter or better [PPE22]







[PrC4a].














Release fraction to wastewater wide dispersive use [OOC8]: 0.025 Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.025





Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].





Do not apply industrial sludge to natural soils [OMS2]. Sludge should be incinerated, contained or reclaimed [OMS3].












[G21]









SECTION 1 EXPOSURE SCENARIO TITLE Title 17. Use in Agrochemicals - Professional


Products Categories PROC 1: Use in closed process, no likelihood of exposure.





PROC 11: Non industrial spraying






8.11a.v1


Use as an agrochemical excipient for application by manual or machine spraying, smokes and fogging; including equipment clean-downs and disposal.













Transfer from/pouring from containers [CS22] Dedicated facility [CS81]


Mixing operations (open No other specific measures identified. [EI20]


systems) [CS30]

Spraying/fogging by manual application [CS24]

Wear a respirator conforming to EN140 with Type A filter or better. [PPE22]

Spraying/fogging by machine application [CS25]

Apply within a vented cab supplied with filtered air under positive pressure and with a protection factor of >20 [E70]

Ad hoc manual application via trigger sprays, dipping, etc. [CS27]






[PrC4a].





















Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency 68.7%

If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of 0.0%

Organisation measures to prevent/limit release from site


Conditions and measures related to municipal


Estimated substance removal from wastewater via domestic sewage


sewage treatment plant

treatment 94.7 %.

Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %








[G21]












SECTION 1 EXPOSURE SCENARIO TITLE Title 18. Use in Agrochemicals - Consumer


Process Categories PC 12: Fertilizers

PC 27: Plant protection products





ESVOC 8.11b.v1


Covers the consumer use in agrochemicals in liquid and solid forms.



Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
























SECTION 1 EXPOSURE SCENARIO TITLE Title 19. Use in Road and Construction Applications – Professional


Process Categories PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.








ERC 8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix


ESVOC 8.15.v1


Application of surface coatings and binders in road and construction activities, including paving uses, manual mastic and in the application of roofing and water-proofing membranes
















Small scale weighing [CS90]



Rolling, brushing [CS51] No other specific measures identified. [EI20]

Spraying/ fogging by machine application [CS25]

Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60] Operation to be undertaken outdoors [E69] , or: [G9] Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29]






































SECTION 1 EXPOSURE SCENARIO TITLE Title 20. Rubber Production and Processing - Industrial


SU 10: Formulation [mixing] of preparations and/or re-packaging (excluding alloys)

SU 11: Manufacture of rubber products




PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises







PROC 13: Treatment of articles by dipping andpouring

PROC 14: Production of preparations* or articles by tabletting, compression, extrusion, pelletisation


PROC 21: Low energy manipulation of substances bound in materials and/or articles



ERC 6d: Industrial use of process regulators for polymerisa-tion processes in produc-tion of resins, rubbers, polymers


ESVOC 4.19a.v1


Manufacture of tyres and general rubber articles, including processing of raw (uncured) rubber, handling and mixing of rubber additives, calendaring, vulcanising, cooling and finishing as well as maintenance





Up to 100% (unless stated).

Frequency and duration of Covers daily exposures up to 8 hours (unless stated differently). [G2].


use









Bulk weighing [CS91] (closed systems) [CS107]


Small scale weighing [CS90] Dedicated facility [CS81]


Additive premixing [CS92] (open systems) [CS108]




Calendering (including Banburys) [CS64] Operation is carried out at elevated temperature (> 20°C above ambient temperature) [OC7]


Pressing uncured rubberblanks [CS73]


Tyre build up [CS112] Spraying [CS10]

Minimise exposure by extracted full enclosure for the operation or equipment [E61]

Vulcanisation [CS70] Operation is carried out at elevated temperature (> 20°C above ambient temperature) [OC7]

Provide extract ventilation to material transfer points and other openings [E82]

Cooling cured articles [CS71] Operation is carried out at elevated temperature (> 20°C above ambient temperature) [OC7]


Production of articles by dipping and pouring [CS113]


Finishing operations [CS102]






















Release fraction to air from process (initial release prior to RMM: 0.01






















External treatment and disposal of waste should comply with applicable local and/or national regulations.[ETW3]



External recovery and recycling of waste should comply with applicable local and/or national regulations. [ERW1]













SECTION 1 EXPOSURE SCENARIO TITLE Title 21. Use in Polymer Processing - Industrial




PROC 3: Use in closed batch process (synthesis or formulation)












ERC 6d: Industrial use of process regulators for polymerisa-tion processes in produc-tion of resins, rubbers, polymers


ESVOC 4.21a.v1


Processing of formulated polymers including material transfers, additives handling (e.g. pigments, stabilisers, fillers, plasticisers, etc.), moulding, curing and forming activities, material re-works, storage and associated maintenance



Physical form of product Liquid, with potential for aerosol generation [CS138]. Vapour pressure < 0.5 kPa at STP [OC3].














Bulk weighing [CS91] (closed systems) [CS107]


Small scale weighing [CS90]


Additive premixing [CS92]


Calendering (including Banburys) [CS64] Operation is carried out at elevated temperature (> 20°C above ambient temperature) [OC7]

Provide extract ventilation to material transfer points and other openings. [E82]

Production of articles by dipping and pouring [CS113]


Extrusion and masterbatching [CS88]


Injection moulding of articles [CS89]


Finishing operations [CS102]




















Release fraction to wastewater from process (initial release prior to RMM): 0






























Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects.


[G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].





SECTION 1 EXPOSURE SCENARIO TITLE Title 22. Use in Polymer Processing - Professional


Products Categories PROC 1: Use in closed process, no likelihood of exposure

PROC 2: Use in closed, continuous process with occasional controlled exposure

PROC 6: Calenderin operations

PROC 8a: Transfer of substance or preparation (charging/discharging) from/to ves-sels/large containers at non-dedicated facilities

PROC 8b: Transfer of substance or preparation (charging/discharging) from/to ves-sels/large containers at dedicated facili-ties







8.21b.v1


Processing of formulated polymers including material transfers, moulding and forming activities, material re-works and associated maintenance.


























Release fraction to wastewater from process (initial release prior to RMM): 0




























Injection moulding of articles [CS89]



Rework of articles [CS86]






[PrC4a].










Local freshwater dilution fraction: 10

Local marine dilution fraction: 100










Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.9 %.

If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %.

Organisation measures to prevent/limit release from site




Estimated substance removal from wastewater via domestic sewage treatment 94.7 %. Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.

Maximum allowable site tonnage (MSafe) based on domestic sewage treatment release (kg/d) 2.7E+1.








[G21]











SECTION 1 EXPOSURE SCENARIO TITLE Title 23. Use as a Fuel – Industrial







PROC 16: Using material as fuel sources, limited exposure to unburned product to be expected


ERC 7: Industrial use of sub-stances in closed systems


ESVOC 7.12a.v1


Covers the use as a fuel (or fuel additives and additive components) and includes activities associated with its transfer, use, equipment maintenance and handling of waste.





Covers percentage substance in the product up to 100% (unless stated differently) G13













Covers the use as a fuel (or fuel additive) and includes activities associated with its transfer, use, equipment



maintenance and handling of waste. [GES12] (closed systems) [CS107]



































Maximum allowable site tonnage (MSafe) based release following total wastewater treatment removal 6.7E+5 kg per day.




Combustion emissions limited by required exhaust emission controls [ETW1]. Combustion emissions considered in regional exposure assessment [ETW2]. External treatment and disposal of waste should comply with applicable local and/or national regulations.[ETW3]








Predicted exposures are not expected to exceed the DN(M)EL when the Risk ManagementMeasures/Operational Conditions outlined in Section 2 are implemented. [G22].







SECTION 1 EXPOSURE SCENARIO TITLE Title 24. Use as a Fuel – Professional







PROC 16: Using material as fuel sources, limited exposure to unburned product to be expected


ERC 9a: Wide dispersive indoor use of substances in closed systems



ESVOC 9.12b.v1


Covers the use as a fuel (or fuel additives and additive components) and includes activities associated with its transfer, use, equipment maintenance and handling of waste.
















Refuelling vehicles, light aircraft or marine [CS507]




Covers the use as a fuel (or fuel additive) and

Limit the substance content in the product to 5 % [OC17]


includes activities associated with its transfer, use, equipment maintenance and handling of waste. [GES12] (closed systems) [CS107]


































Total efficiency of removal from wastewater after onsite and offsite


(domestic treatment plant) RMMs 94.7 %.



















SECTION 1 EXPOSURE SCENARIO TITLE Title 25. Use as a Fuel – Consumer


Products Categories PC 13: Fuels





9.12c.v1


Covers consumer uses in fuels




Vapour Pressure (Pa) 231







Product Category




[PrC4a].












Other given operational Release fraction to air from wide dispersive use (regional use only)


conditions affecting environmental exposure

[OOC7]: 1.0E-4













[G21].










SECTION 1 EXPOSURE SCENARIO TITLE Title 26. Lubricants - Industrial


Process Categories PROC 1: Use in closed process, no likelihood of exposure



PROC 4: Use in batch and other process (syn-thesis) where opportunity for exposure arises








PROC 18: Greasing at high energy conditions



ERC 7: Industrial use of sub-stances in closed systems


ESVOC 4.6a.v1


Covers the use of formulated lubricants in closed and open systems including material transfers operations, operation of machinery/engines and similar articles, reworking on reject articles, equipment maintenance and disposal of wastes.












General exposures No other specific measures identified. [EI20]


(closed systems) [CS15]



Bulk ransfers [CS14] Dedicated facility [CS81]




Initial factory fill of equipment [CS75]


Operation and lubrication of high energy open equipment [CS17]






Spraying [CS10] Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings [E60]

Maintenance (of larger plant items) and machine set up [CS77] Dedicated facility [CS81] Elevated temperature [CS111]


Maintenance of small items [CS18] Non-dedicated facility [CS82]


Remanufacture of reject articles [CS19]
















Other operational conditions affecting



environmental exposure Release fraction to wastewater from process (initial release prior to RMM): 1.0E-6





Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]. Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].

























SECTION 1 EXPOSURE SCENARIO TITLE Title 27. Lubricants – Professional: Low Environmental Release











PROC 20: Heat and pressure transfer fluids in dispersive, professional use but closed systems




Environmental Release Category

ESVOC 9.6b.v1


Covers the use of formulated lubricants in closed or contained systems including material transfers operations, operation of engines and similar articles, reworking on reject articles, equipment maintenance and disposal of waste oil.














Operation of equipment containing engine oils and



similar [CS26] (Closed systems) [CS107]









Operation and lubrication of high energy open equipment [CS17] Indoor [OC8]


Operation and lubrication of high energy open equipment [CS17] Outdoor [OC9]

Ensure operation is undertaken outdoors [E69] Avoid carrying out operation for more than 4 hours [OC12] Limit the substance content in the product to 25 % [OC18]


Drain down system prior to equipment break-in or maintenance [E65] Provide extract ventilation to emission points when contact with warm (>50oC) lubricant is likely) [E67]

Maintenance of small items [CS18] Non-dedicated facility [CS82] Elevated temperature [CS11]

Drain or remove substance from equipment prior to break-in or maintenance [E81] Provide a good standard of general ventilation (3 to 5 air changes per hour) [E11]

Engine lubricant service [CS78]




Spraying [CS10] Carry out in a vented booth or extracted enclosure [E57], or: [G9] Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings [E60] Avoid carrying out activities involving exposure for more than 1 hr [OC27] , or: [G9] Wear a respirator conforming to EN140 with Type A filter or better [PPE22]











Maximum daily site tonnage (kg/day): 365

























Maximum allowable site tonnage (MSafe) based release following total wastewater treatment removal 6.5E+2 kg per day.









SECTION 1 EXPOSURE SCENARIO TITLE Title 28. Lubricants – Professional: High Environmental Release
















ESVOC 8.6c.v1


Covers the use of formulated lubricants in open systems including material transfers operations, operation of engines and similar articles, reworking on reject articles, equipment maintenance and disposal of waste oil.












General exposures No other specific measures identified. [EI20]


(closed systems) [CS15]

Operation of equipment containing engine oils and similar [CS26] (Closed systems) [CS107]










Operation and lubrication of high energy open equipment [CS17] Indoor [OC8]


Operation and lubrication of high energy open equipment [CS17] Outdoor [OC9]

Ensure operation is undertaken outdoors [E69] Avoid carrying out operation for more than 4 hours [OC12] Limit the substance content in the product to 25 % [OC18]


Drain down system prior to equipment break-in or maintenance [E65] Provide extract ventilation to emission points when contact with warm (>50oC) lubricant is likely) [E67]

Maintenance of small items [CS18] Non-dedicated facility [CS82] Elevated temperature [CS111]

Drain or remove substance from equipment prior to break-in or maintenance [E81] Provide a good standard of general ventilation (3 to 5 air changes per hour) [E11]

Engine lubricant service [CS78]




Spraying [CS10] Carry out in a vented booth or extracted enclosure [E57], or: [G9] Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings [E60] Avoid carrying out activities involving exposure for more than 1 hr [OC27] , or: [G9] Wear a respirator conforming to EN140 with Type A filter or better [PPE22]





Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.


[PrC4a].






























Maximum allowable site tonnage (MSafe) based on following total wastewater treatment removal 2.6E+2 kg per day.






SECTION 3 EXPOSURE ESTIMATION


Section 3.1 Health












SECTION 1 EXPOSURE SCENARIO TITLE Title 29. Lubricants – Consumer: Low Environmental Release


Process Categories PC 1: Adhesives, sealants







ESVOC 9.6d.v1


Covers the consumer use of formulated lubricants in closed or contained systems including transfer operations, application, operation of engines and similar articles, equipment maintenance and disposal of waste oil.










Product Category

















SECTION 1 EXPOSURE SCENARIO TITLE Title 30. Lubricants – Consumer: high environmental release


Process Categories PC 1: Adhesives, sealants







ESVOC 8.6e.v1


Covers the consumer use of formulated lubricants in open systems including transfer operations, application, operation of engines and similar articles, equipment maintenance and disposal of waste oil.










Products Category













Environmental factors not influenced by risk




management

























SECTION 1 EXPOSURE SCENARIO TITLE Title 31. Use in Laboratories - Industrial


Process Categories PROC 10: Roller application or brushing





Not Applicable


Use of the substance within laboratory settings, including material transfers and equipment cleaning





























Release fraction to wastewater from process (initial release prior to


environmental exposure RMM): 0.02




























Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32].


Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].


Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3].


SECTION 1 EXPOSURE SCENARIO TITLE Title 32. Use in Laboratories - Professional


Process Categories PROC 10: Roller application or brushing





ESVOC 8.17a.v1


Use of the substance within laboratory settings, including material transfers and equipment cleaning































Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0



























Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32].


Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].





SECTION 1 EXPOSURE SCENARIO TITLE Title 33. Use in Mining Operations – Industrial








PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities





ESVOC 4.23.v1


Covers the use of the substance in extraction processes at mining operations, including material transfers, winning and separation activities, and substance recovery and disposal.
















Pouring from small No other specific measures identified. [EI20]


containers [CS9]





Phase separation [CS106] No other specific measures identified. [EI20]

Ion exchange processes [CS105] (closed systems) [CS107]




























Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, additional onsite wastewater treatment required [TCR14].




Organizational measures to prevent / limit release



from site Sludge should be incinerated, contained or reclaimed [OMS3].

















Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].





SECTION 1 EXPOSURE SCENARIO TITLE Title 34. Use in Water Treatment Chemicals - Industrial












ESVOC 4.23.v1


Covers the use of the substance for the treatment of water at industrial facilities in open and closed systems












Bulk transfers [CS14] Use in contained systems [CS38]




Geneal Exposures (Closed systems) [CS15]


General exposures (open No other specific measures identified. [EI20]


systems) [CS16]

Pouring from small containers [CS9]

























Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, additional onsite wastewater treatment required [TCR14].














SECTION 1 EXPOSURE SCENARIO TITLE Title 35. Use in Water Treatment Chemicals - Professional












ERC 8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix


ESVOC 8.22b.v1


Covers the use of the substance for the treatment of water in open and closed systems



















Pouring from small containers [CS9]





















Release fraction to soil from wide dispersive use (regional use only) n [OOC9]: 0





Treat air emission to provide a typical removal efficiency of N/A..










Maximum allowable site tonnage (MSafe) based on release following


total wastewater treatment removal 1.1E+1 kg per day.

















SECTION 1 EXPOSURE SCENARIO TITLE Title 36. Explosives Manufacture and Use - Professional








ERC 8e: Wide dispersive outdoor use of reactive substances in open systems


Not Applicable


Covers exposures arising from the manufacture and use of slurry explosives (including materials transfer, mixing and charging) and equipment cleaning












Bulk transfers [CS14] Use in contained batch process [CS37]








Material transfers [CS3] Non-dedicated facility [CS82]

Ensure operation is undertaken outdoors [E69]. Avoid carrying out activities involving exposure for more than 4 hours [OC28]


Transfer from/pouring from containers [CS22] Non-dedicated facility [CS82]

Ensure operation is undertaken outdoors [E69]. Avoid carrying out activities involving exposure for more than 4 hours [OC28]




















Release fraction to soil from wide dispersive use (regional use only) n [OOC9]: 0.01






























Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3].


SECTION 1 EXPOSURE SCENARIO TITLE Title 37. Use as Functional Fluids - Industrial










ERC 7: Industrial use of substances in closed systems


ESVOC 7.13a.v1


Use as functional fluids e.g. cable oils, transfer oils, coolants, insulators, refrigerants, hydraulic fluids in industrial equipment including maintenance and related material transfers
















Filling of articles/equipment [CS84] (closed systems) [CS107]







General exposures (open systems) [CS16] Elevated temperature [CS111]

Restrict area of openings and provide extract ventilation to emission points when substance handled at elevated temperatures [E75]




















Release fraction to air from process (initial release prior to RMM): 5.0E-4 Release fraction to wastewater from process (initial release prior to RMM): 1.0E-6 Release fraction to soil from process (initial release prior to RMM): 0.001




Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].

Treat air emission to provide a typical removal efficiency of 0 %


If discharging to domestic sewage treatment plant, provide the required


onsite wastewater removal efficiency of ≥ 0.0 %


























SECTION 1 EXPOSURE SCENARIO TITLE Title 38. Use as Functional Fluids – Professional












ESVOC 9.13b.v1


Use as functional fluids e.g. cable oils, transfer oils, insulators, refrigerants, hydraulic fluids in professional equipment including maintenance and related material transfers.
















Filling of articles/equipment [CS84] (closed systems) [CS107]


Filling / preparation of equipment from drums or



containers. [CS45] Non-dedicated facilities [CS82]



General exposures (open systems) [CS16] Elevated temperature [CS111]

Restrict area of openings and provide extract ventilation to emission points when substance handled at elevated temperatures [E75]


































SECTION 1 EXPOSURE SCENARIO TITLE Title 39. Use as Functional Fluids - Consumer


Process Categories PC 16: Heat transfer fluids

PC 17: Hydraulic fluids





ESVOC 9.13c.v1


Use of sealed items containing functional fluids e.g. transfer oils, hydraulic fluids, refrigerants












No exposure scenario presented for human health. Re fer to Appendix 2 for the qualitative assessment of consumer aerosol exposure

















environmental exposure Release fraction to wastewater wide dispersive use [OOC8]: 0.025




















SAFETY DATA SHEET Page 1 / 10 NEXBASE® 3043 Date 28.11 ... · Lubricating oils (petroleum),...

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