SAFETY DATA SHEET · EMERGENCY OVERVIEW Signal Word Danger • Suspected of causing cancer Chemtrec...
Transcript of SAFETY DATA SHEET · EMERGENCY OVERVIEW Signal Word Danger • Suspected of causing cancer Chemtrec...
WPS-CHI-011 Eleven Revision Date 1/10/2018
Issuing Date Revision Date
Synonyms:
2. HAZARD IDENTIFICATION
GHS label elements, including precautionary statements
EMERGENCY OVERVIEW
Signal Word Danger
• Suspected of causing cancer
Chemtrec 1-800-424-9300
1-866-634-5100Emergency Telephone Number
Chicago Aerosol
1300 North St.
Coal City, IL 60416
Tel: 815-634-5100
SAFETY DATA SHEET Revision Number
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
Dry Shampoo 265-89(DD)Q04169-2
none
Product Name:
GHS Product Identifier
Other means of Identification
010/14/20141/10/18
Supplier's Details
No information available
No information available
Recommended Use:
Uses advised against:
Emergency telephone number
Recommended use of the chemical and restrictions on use
Supplier Address
• Extremely flammable aerosol
Hazard Statements• Causes serious eye irritation
Classification
Serious Eye Damage/Eye Irritation
Carcinogenicity
Specific Target Organ Systemic toxicity (Single Exposure)
Simple Asphyxiant
Flammable Aerosols
Gases Under Pressure
Category 2A
Category 2
Category 3
Yes
Category 1
• May cause respiratory irritation• May cause drowsiness or dizziness
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MATERIAL SAFETY DATA SHEET
SECTION 1-CHEMICAL SUBSTANCE/PRODUCT AND
COMPANY IDENTIFICATION Finished Product Name: Dry shampoo paste Item Code: Manufacturer information: Guangzhou Beaver Cosmetics Co., Ltd Add:No.5 Zhenxing Rd.,High-tech Industrial Park,Taiping Development Zone Conghua
Guangzhou China 510990 Tel: 86-20-37940773 Fax: 86-20-37940775 Email: [email protected] DATE: March 28th, 2016
SECTION 2-HAZARDS INENTIFICATION EMERGENCY OVERVIEW: This is a personal care or cosmetic product that is safe for consumers and other users under intended and reasonably foreseeable use. Additional information on toxicological endpoints is available from the supplier upon request. POTENTIAL HEALTH EFFECTS: Eye:
Contact may cause mild, transient irritation. Some redness and/or stinging may occur. Skin:
Not expected to be irritating, sensitizing, photoallergenic or phototoxic when used as intended. If irritation occurs following intended use or prolonged contact it is expected to be mild and transient. Inhalation:
Not expected to be irritating to the respiratory system. Not volatile therefore limited inhalation exposure anticipated. Ingestion:
Product used as intended is not expected to cause gastrointestinal irritation. Accidental ingestion of undiluted product may cause mild gastrointestinal irritation with nausea, vomiting and diarrhea.
SECTION 3-COMPOSITION AND INGREDIENTS The complete ingredient list for the finished product(s) is as follows: ZEOLITE�
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MAGNESIUM SULFATE � CAPRYLIC/CAPRIC TRIGLYCERIDE � ISOHEXADECANE �CETEARETH-20�HYDROGENATED VEGETABLE OIL�STEARYL ALCOHOL�COCOS NUCIFERA (COCONUT) OIL�OLETH-20�STEARALKONIUM HECTORITE�PARFUM�ALCOHOL� SILICA�HEXYL CINNAMAL� SCLEROCARYA BIRREA SEED OIL�BIXA ORELLANA SEED OIL�CARAPA GUAIANENSIS SEED OIL�LINALOOL�GERANIOL�LIMONENE
SECTION 4-FIRST AID MEASURES Eye:
Thorough rinsing for 15-20 minutes of the affected eye with water is recommended. If Discomfort or irritation persists, contact a physician. Skin Problem:
Discontinue use of product. Apply cold compresses to affected areas to relieve and discomfort. If discomfort persists, contact a physician. Inhalation: If respiratory irritation occurs, remove individual to fresh air. Ingestion: Accidental ingestion of product may necessitate medical attention. In case of accidental Ingestion dilutes with fluids (water or milk) and treats symptomatically. Do not induce vomiting. Note: After first aid treatment, the caller should be advised that 1) a hospital emergency room or Family physician should be consulted if anything unusual occurs or appears necessary in the Judgment of the caller, and 2) that the subsequent management of the accident should be dictated by any persistency symptoms and under the direction of the physician.
SECTION 5-FIRE FIGHTING MEASURES Flash Point & Method: Not applicable. Extinguishing Media: Use chemical foam, dry chemical, carbon dioxide or water. Explosion Hazard: No applicable information has been found. Fire Fighting Instructions: Contact emergency personnel. Use self-contained
breathing apparatus and full protective gear, if large quantities of product are involved. Hazardous decomposition products may be released. Thermal degradation may produce oxides of carbon and/or nitrogen: hydrocarbons and/or derivatives.
SECTION 6-ACCIDENTAL RELEAS4 MEASURES Procedures for Spil l/Leak Clean-up:
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For Household Settings: Absorb liquid and scrub the area with detergent. Dilute with water. For Non-Household Settings :Use safety glasses or safety goggles if splash hazards exist: use Gloves and other protective clothing (apron, boots, etc) to prevent skin contact.
SECTION 7-HANDLIND STORAGE Precautions for Safe Handling: For Household Settings: Avoid contact with eyes. For Non-Household Settings: No unusual handling or storage requirements. Storage in large Quantities (as in warehouses) should be in a well-ventilated, cool area. Conditions for Safe Storage: For Household Settings: No acquirable information has been found. For Non-Household Settings: No unusual handling or storage requirements. Storage in large Quantities (as in warehouses) should be in a well-ventilated, cool area. Other Recommendations: None.
SECTION 8-EXPOSURE CONTROLS, PERSONAL
PROTECTION For Household settings: This is a personal care or cosmetic product that is safe for consumers and other users under Normal and reasonably foreseen use. For Non-Household Settings: Use safety glasses or safety goggles if splash hazards exist; use gloves and other protective clothing (apron, boots, etc) to prevent skin contact. Always follow good hygienic work practices. Avoid prolonged contact with skin and clothing.
SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES Color, and Appearance : White Paste Physical State: White Paste Odor�Perfume Odor
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SECTION 10-STABILITY AND REACTIVITY Conditions to Avoid: No applicable information has been found. Other Recommendations : None
SECTION 11-TOXICOLOGICAL INFORMATION This is a hair care product that is safe for consumers and other users under Intended and reasonably foreseeable use. Additional information on toxicological endpoints is Available from the supplier upon request. Chronic Effects: Finished product is not expected to have chronic health effects. Target Organs: No adverse health effects on target organs expected for finished product.
SECTION 12-ECOLOGICAL INFORMATION The product ingredients are expected to be safe for the environment at concentrations predicted under normal use and accidental spill scenarios. Packing components are compatible with the conventional solid management practices. Additional information is available from the supplier on request.
SECTION 13-DISPOSAL CONSIDERATIONS Disposal should be in accordance with Federal, state/provincial and local regulations. For Household settings: The following instructions are for consumer usage only. Do not discharge product into natural waters without pre-treatment or adequate dilution. For Non-Household settings: Products covered by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste according. Disposal should be in accordance with local, state and federal regulations.
SECTION 14-TRANSPORT INFORMATION Finished packaged product transported by ground (DOT):Non hazardous Finished packaged product transported by vessel (IMDG): Non hazardous Finished packaged product transported by air (IATA): Non hazardous
SECTION 15- REGULATORY INFORMATION Regulated as a Cosmetic and /or Drug under GMPC (US, EU) Other
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Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance.
SECTION 16-OTHER INFORMATION This MSDS is intended to provide a brief summary of our knowledge and Guidance regarding the use of this material. The information contained here has been compiled from sources considered to be dependable and is accurate to the best of the company’s knowledge .It is not meant to be an all-inclusive document on worldwide hazard communication regulations. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose.
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare 3 minute Repair Rinse Other Name: Treatment Product Use: To condition and beautify hair after cleansing, or before or after other hair treatments. Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Behentrimonium Chloride 17301-53-0 <1.50 Cyclomethicone 69430-24-6 <2.50 Other ingredients to 100
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up,
wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: white opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 0.95 – 1.00 Water Solubility: Completely soluble in water. pH: 3.00 – 4.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms: ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Ozdare Business Services Chemwatch Hazard Alert Code: 4
ELEVEN GIVE ME CLEAN HAIR DRY SHAMPOO
Chemwatch: 33-4541Version No: 2.1.1.1Safety Data Sheet according to WHS and ADG requirements
Issue Date: 01/01/2013Print Date: 23/05/2016
Initial Date: Not AvailableS.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name ELEVEN GIVE ME CLEAN HAIR DRY SHAMPOO
Synonyms Not Available
Proper shipping name AEROSOLS
Other means ofidentification Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified usesSDS are intended for use in the workplace. For domestic-use products, refer to consumer labels.Application is by spray atomisation from a hand held aerosol packDry hair shampoo.
Details of the supplier of the safety data sheet
Registered company name Ozdare Business Services
Address 7 Endeavour Way Sunshine West VIC 3020 Australia
Telephone +61 3 9314 9099
Fax +61 3 9314 9211
Website Not Available
Email Not Available
Emergency telephone number
Association / Organisation Not Available
Emergency telephonenumbers Not Available
Other emergency telephonenumbers Not Available
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGSMaxMin
Flammability 4 Toxicity 0Body Contact 2 Reactivity 1 Chronic 0
0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme
Poisons Schedule Not Applicable
Classification [1] Aerosols Category 1, Specific target organ toxicity - single exposure Category 3 (narcotic effects)
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD DANGER
Hazard statement(s)
H222 Extremely flammable aerosol.
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H336 May cause drowsiness or dizziness.
AUH044 Risk of explosion if heated under confinement
Precautionary statement(s) Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing mist/vapours/spray.
Precautionary statement(s) Response
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Precautionary statement(s) Storage
P405 Store locked up.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s) Disposal
P501 Dispose of contents/container in accordance with local regulations.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
SubstancesSee section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
64-17-5 10-30
73513-42-5 10-30
68476-85-7. 30-60
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If aerosols come in contact with the eyes: Immediately hold the eyelids apart and flush the eye with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact Wipe off excess with absorbent tissue or towel.
Inhalation
If aerosols, fumes or combustion products are inhaled:Remove to fresh air. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag-valve mask device, orpocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor.
Ingestion Not considered a normal route of entry.
Indication of any immediate medical attention and special treatment neededTreat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing mediaSMALL FIRE:
Water spray, dry chemical or CO2 LARGE FIRE:
Water spray or fog.
Special hazards arising from the substrate or mixture
Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
ethanol
isohexanes
hydrocarbon propellant
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Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. If safe, switch off electrical equipment until vapour fire hazard removed. Use water delivered as a fine spray to control fire and cool adjacent area. DO NOT approach containers suspected to be hot.
Fire/Explosion Hazard
Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat or flame. Vapour forms an explosive mixture with air. Severe explosion hazard, in the form of vapour, when exposed to flame or spark. Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition with violent container rupture. Aerosol cans may explode on exposure to naked flames.
Other combustion products include:, carbon dioxide (CO2), other pyrolysis products typical of burning organic material
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Wear protective clothing, impervious gloves and safety glasses. Shut off all possible sources of ignition and increase ventilation. Wipe up. If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated. Undamaged cans should be gathered and stowed safely.
Major Spills
Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
None required when handling small quantities.OTHERWISE:
Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials.
Other information
Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can Store in original containers in approved flammable liquid storage area. DO NOT store in pits, depressions, basements or areas where vapours may be trapped. No smoking, naked lights, heat or ignition sources. Keep containers securely sealed. Contents under pressure. Store away from incompatible materials. Store in a cool, dry, well ventilated area.
Conditions for safe storage, including any incompatibilities
Suitable container Aerosol dispenser. Check that containers are clearly labelled.
Storage incompatibility Avoid storage with oxidisers
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
Australia Exposure Standards ethanol Ethyl alcohol 1880 mg/m3 / 1000 ppm Not Available Not Available Not Available
Australia Exposure Standards isohexanes Hexane, other isomers 1760 mg/m3 / 500 ppm 3500 mg/m3 / 1000 ppm Not Available Not Available
Australia Exposure Standards hydrocarbon propellant LPG (liquified petroleum gas) 1800 mg/m3 / 1000 ppm Not Available Not Available Not Available
EMERGENCY LIMITS
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
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ethanol Ethyl alcohol; (Ethanol) Not Available Not Available Not Available
hydrocarbon propellant Liquified petroleum gas; (L.P.G.) 3,000 ppm 3200 ppm 19000 ppm
Ingredient Original IDLH Revised IDLH
ethanol 15,000 ppm 3,300 [LEL] ppm
isohexanes Not Available Not Available
hydrocarbon propellant 19,000 [LEL] ppm 2,000 [LEL] ppm
Exposure controls
Appropriate engineeringcontrols
None required when handling small quantities.OTHERWISE:Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highlyeffective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and"removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must matchthe particular process and chemical or contaminant in use.Employers may need to use multiple types of controls to prevent employee overexposure.
Personal protection
Eye and face protection
No special equipment for minor exposure i.e. when handling small quantities.OTHERWISE:
Safety glasses with side shields.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing oflenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class ofchemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should bereadily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable.
Skin protection See Hand protection below
Hands/feet protection
No special equipment needed when handling small quantities. OTHERWISE: For potentially moderate exposures: Wear general protective gloves, eg. light weight rubber gloves. For potentially heavy exposures: Wear chemical protective gloves, eg. PVC. and safety footwear.
Body protection See Other protection below
Other protection
No special equipment needed when handling small quantities.OTHERWISE:
Overalls. Skin cleansing cream. Eyewash unit. Do not spray on hot surfaces.
Thermal hazards Not Available
Recommended material(s)GLOVE SELECTION INDEXGlove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: ELEVEN GIVE ME CLEAN HAIR DRY SHAMPOO
Material CPI
BUTYL A
NEOPRENE A
NITRILE A
NITRILE+PVC A
PE/EVAL/PE A
PVC B
NATURAL RUBBER C
NATURAL+NEOPRENE C
* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of the glove, a finalselection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequent basis, factors such as"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwisebe unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
Respiratory protectionType AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSIZ88 or national equivalent)
Selection of the Class and Type of respirator will depend upon the level of breathing zonecontaminant and the chemical nature of the contaminant. Protection Factors (defined as theratio of contaminant outside and inside the mask) may also be important.
Requiredminimumprotection factor
Maximum gas/vapourconcentration present in airp.p.m. (by volume)
Half-faceRespirator
Full-FaceRespirator
up to 10 1000 AX-AUS /Class1
-
up to 50 1000 - AX-AUS /Class 1
up to 50 5000 Airline * -
up to 100 5000 - AX-2
up to 100 10000 - AX-3
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demandA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogencyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)
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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable hydrocarbon propellant.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available Partition coefficientn-octanol / water Not Available
Odour threshold Not Available Auto-ignition temperature(°C) Not Available
pH (as supplied) Not Available Decompositiontemperature Not Available
Melting point / freezingpoint (°C) Not Available Viscosity (cSt) Not Available
Initial boiling point andboiling range (°C) Not Available Molecular weight (g/mol) Not Applicable
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm ormN/m) Not Available
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Partly Miscible pH as a solution (1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability
Elevated temperatures. Presence of open flame. Product is considered stable. Hazardous polymerisation will not occur.
Possibility of hazardousreactions See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decompositionproducts See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Inhalation hazard is increased at higher temperatures.Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness,slowing of reflexes, fatigue and inco-ordination.WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
Ingestion Not normally a hazard due to physical form of product.Considered an unlikely route of entry in commercial/industrial environments Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact Not considered an irritant through normal use.
Eye Spray mist may produce discomfortThe material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.
Chronic
Principal routes of exposure are by accidental skin and eye contact and by inhalation of vapours especially at higher temperatures.As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should beavoided by observing good occupational work practice.WARNING: Aerosol containers may present pressure related hazards.
ELEVEN GIVE ME CLEANHAIR DRY SHAMPOO
TOXICITY IRRITATION
Not Available Not Available
ethanol
TOXICITY IRRITATION
Dermal (rabbit) LD50: 17100 mg/kg[1] Eye (rabbit): 500 mg SEVERE
Inhalation (rat) LC50: 64000 ppm/4h[2] Eye (rabbit):100mg/24hr-moderate
Oral (rat) LD50: >1187-2769 mg/kg[1] Skin (rabbit):20 mg/24hr-moderate
Skin (rabbit):400 mg (open)-mild
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Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification
isohexanes
TOXICITY IRRITATION
Dermal (rabbit) LD50: >5000 mg/kg[1] Not Available
Dermal (rabbit) LD50: >5000 mg/kg[1]
dermal (rat) LD50: >=4000 mg/kg[1]
Oral (rat) LD50: >25000 mg/kg[1]
Oral (rat) LD50: >25000 mg/kg[1]
Oral (rat) LD50: >8000 mg/kg[1]
hydrocarbon propellant
TOXICITY IRRITATION
Inhalation (mouse) LC50: >15.6-<17.9 mm/l2 h mm/l2="">[1] Not Available
Inhalation (mouse) LC50: >15.6-<17.9 mm/l2 h mm/l2="">[1]
Inhalation (mouse) LC50: 410000 ppm2 h[1]
Inhalation (mouse) LC50: 410000 ppm2 h[1]
Inhalation (rat) LC50: >800000 ppm15 min[1]
Inhalation (rat) LC50: >800000 ppm15 min[1]
Inhalation (rat) LC50: 1354.944 mg/L15 min[1]
Inhalation (rat) LC50: 1355 mg/l15 min[1]
Inhalation (rat) LC50: 1442.738 mg/L15 min[1]
Inhalation (rat) LC50: 1442.738 mg/L15 min[1]
Inhalation (rat) LC50: 1443 mg/l15 min[1]
Inhalation (rat) LC50: 1443 mg/l15 min[1]
Inhalation (rat) LC50: 570000 ppm15 min[1]
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified dataextracted from RTECS - Register of Toxic Effect of chemical Substances
ETHANOL The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,scaling and thickening of the skin.
ISOHEXANES No significant acute toxicological data identified in literature search.
HYDROCARBONPROPELLANT
No significant acute toxicological data identified in literature search. inhalation of the gas
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious EyeDamage/Irritation STOT - Single Exposure
Respiratory or Skinsensitisation STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
Ingredient Endpoint Test Duration (hr) Species Value Source
ethanol EC50 24 Algae or other aquatic plants 0.0129024mg/L 4
ethanol EC50 48 Crustacea 2mg/L 4
ethanol LC50 96 Fish 42mg/L 4
ethanol NOEC 2016 Fish 0.000375mg/L 4
ethanol EC50 72 Algae or other aquatic plants 275mg/L 2
isohexanes EC50 384 Crustacea 0.240mg/L 3
isohexanes EC50 96 Algae or other aquatic plants 1.526mg/L 3
isohexanes LC50 96 Fish 0.961mg/L 3
hydrocarbon propellant LC50 96 Fish 24.11mg/L 2
hydrocarbon propellant EC50 96 Algae or other aquatic plants 7.71mg/L 2
hydrocarbon propellant EC50 96 Algae or other aquatic plants 8.57mg/L 2
hydrocarbon propellant LC50 96 Fish 24.11mg/L 2
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hydrocarbon propellant EC50 96 Algae or other aquatic plants 7.71mg/L 2
hydrocarbon propellant EC50 96 Algae or other aquatic plants 8.57mg/L 2
Legend:Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 -Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
ethanol LOW (Half-life = 2.17 days) LOW (Half-life = 5.08 days)
isohexanes LOW LOW
Bioaccumulative potential
Ingredient Bioaccumulation
ethanol LOW (LogKOW = -0.31)
isohexanes LOW (LogKOW = 3.7056)
Mobility in soil
Ingredient Mobility
ethanol HIGH (KOC = 1)
isohexanes LOW (KOC = 230.3)
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packagingdisposal
Consult State Land Waste Management Authority for disposal. Discharge contents of damaged aerosol cans at an approved site. Allow small quantities to evaporate. DO NOT incinerate or puncture aerosol cans. Bury residues and emptied aerosol cans at an approved site.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (ADG)
UN number 1950
Packing group Not Applicable
UN proper shipping name AEROSOLS
Environmental hazard Not Applicable
Transport hazard class(es)Class 2.1
Subrisk Not Applicable
Special precautions for userSpecial provisions 63 190 277 327 344
Limited quantity 1000ml
Air transport (ICAO-IATA / DGR)
UN number 1950
Packing group Not Applicable
UN proper shipping name Aerosols
Environmental hazard Not Applicable
Transport hazard class(es)
ICAO/IATA Class 2.1
ICAO / IATA Subrisk Not Applicable
ERG Code 10L
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Special precautions for user
Special provisions A145A167A802; A1A145A167A802
Cargo Only Packing Instructions 203
Cargo Only Maximum Qty / Pack 150 kg
Passenger and Cargo Packing Instructions 203; Forbidden
Passenger and Cargo Maximum Qty / Pack 75 kg; Forbidden
Passenger and Cargo Limited Quantity Packing Instructions Y203; Forbidden
Passenger and Cargo Limited Maximum Qty / Pack 30 kg G; Forbidden
Sea transport (IMDG-Code / GGVSee)
UN number 1950
Packing group Not Applicable
UN proper shipping name AEROSOLS
Environmental hazard Not Applicable
Transport hazard class(es)IMDG Class 2.1
IMDG Subrisk Not Applicable
Special precautions for user
EMS Number F-D, S-U
Special provisions 63 190 277 327 344 959
Limited Quantities 1000ml
Transport in bulk according to Annex II of MARPOL and the IBC codeNot Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
ETHANOL(64-17-5) IS FOUND ON THE FOLLOWING REGULATORY LISTSAustralia Exposure StandardsAustralia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
ISOHEXANES(73513-42-5) IS FOUND ON THE FOLLOWING REGULATORY LISTSAustralia Exposure Standards Australia Inventory of Chemical Substances (AICS)
HYDROCARBON PROPELLANT(68476-85-7.) IS FOUND ON THE FOLLOWING REGULATORY LISTSAustralia Exposure StandardsAustralia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited ListPassenger and Cargo Aircraft
National Inventory Status
Australia - AICS Y
Canada - DSL N (isohexanes)
Canada - NDSL N (isohexanes; ethanol; hydrocarbon propellant)
China - IECSC Y
Europe - EINEC / ELINCS /NLP Y
Japan - ENCS N (hydrocarbon propellant)
Korea - KECI N (isohexanes)
New Zealand - NZIoC Y
Philippines - PICCS Y
USA - TSCA N (isohexanes)
Legend: Y = All ingredients are on the inventoryN = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
SECTION 16 OTHER INFORMATION
Other information
Ingredients with multiple cas numbers
Name CAS No
isohexanes 73513-42-5, 93924-36-8
hydrocarbon propellant 68476-85-7., 68476-86-8.
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee usingavailable literature references.A list of reference resources used to assist the committee may be found at:
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www.chemwatch.net
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or othersettings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
Definitions and abbreviationsPC䠉TWA: Permissible Concentration-Time Weighted AveragePC䠉STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit䚹IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index
This document is copyright.Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH.TEL (+61 3) 9572 4700.
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Page 1 of 6 Quality manufacturers of bath & body care products – made in Australia
SAFETY DATA SHEET
According to Regulation (EC) no. 1907/2006 SECTION 1: Identification of the substance/mixture & of the Company/ Undertaking of the substance/mixture and of the
company/undertaking 1.1 Product Name: Eleven Extra Hold Styling Clay 1.2 Application of the substance/mixture: Hair styling product. For external use only. 1.3 Details of the Manufacturer / Distributor:
Natural Beauty Care Pty Ltd 8 Teton Court, Highett, Victoria 3190, Australia.
Eleven Australia Pty Ltd 7 Endeavour Way, Sunshine West, Victoria 3020, Australia.
1.4 Emergency telephone number: +61 3 9553 0733 Facsimile Number: +61 3 9553 4988 1.5 POISON INFORMATION CENTRE: 13 11 26 (Australia)
SECTION 2: Hazard Identification
Not classified as Dangerous goods by the criteria of the Australian Dangerous goods code (ADG) for Transport and Rail. NON-DANGEROUS GOODS.
This material is a personal care product that is safe for consumers with intended and foreseeable use. This product is non- hazardous according to Work Safe Australia.
Classification of the substance or mixture (Classification according to Regulation (EC) No 1272/2008): Nil Classification according to the Directive 67/548/EEC or Directive 1999/45/EC: Not regulated
Signal word: Not relevant
Hazard statements:
Not relevant Precautionary statements:
P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P103 Read label before use
Page 2 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 3: Composition/formulation on ingredients
SECTION 4: First Aid Measures
4.1 Description of first aid measures
General information: No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Name of Chemical CAS Number Percentage
w/w
Petrolatum 8009-03-8 < 25 Beeswax (Cera Alba) 8012-89-3 < 25 Water (Aqua) 7732-18-5 < 20 Oleth-5 9004-98-2 < 20 Paraffin 8002-74-2 < 10 Kaolin 1332-58-7 < 10 Bentonite 1302-78-9 < 10 Mineral Oil (Paraffinum Liquidum) 8012-95-1 < 5 Ceteareth-20 68439-49-6 < 5 Fragrance (Parfum) - < 1 Phenoxyethanol 122-99-6 < 1 Citric Acid 77-92-9 < 0.5 Copernicia Cerifera (Carnauba) Wax 8015-86-9 < 0.5 Potassium Sorbate 24634-61-5 < 0.5 Ethylhexylglycerin 70445-33-9 < 0.5 Sodium Benzoate 532-32-1 < 0.5
HEALTH EFFECTS: Acute - Swallowed May be harmful if large amounts are swallowed Acute - Eye Full strength material may be irritating to eyes Acute - Skin Not considered an irritant through normal use. Full strength material in repeated
or prolonged contact with skin may be irritating and cause allergic reactions in sensitive individuals
Acute - Inhaled Full strength material should not cause any irritation to the mucous membrane and upper airways
FIRST AID: Swallowed Do not induce vomiting, Give plenty of water and seek medical advice Eye Flush eye with copious amounts of water for 15 minutes including under eyelid. If
discomfit persists, obtain medical advice. Skin Remove contaminated clothing. Wash affected areas with warm soapy water
Inhaled Remove to fresh uncontaminated air, lay patient on back until breathing returns to normal
Page 3 of 6 Quality manufacturers of bath & body care products – made in Australia
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting Measures
5.1 Suitable Extinguishing media: Carbon dioxide, Foam, Dry Chemical 5.2 Special hazards arising from the substance or mixture:
No further relevant information available. 5.3 Advice for firefighters:
Wear Protective equipment. Do not inhale explosion gases or combustion gases. Hazchem Code: Not applicable.
SECTION 6: Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures: Remove all sources of ignition. Increase ventilation. Evacuate all personnel. Wear sufficient respiratory protection and full protective clothing to minimise skin and eye exposure. If possible contain the spill. 6.2 Environmental precautions: No special measures required. 6.3 Methods and material for containment and cleaning up: Slippery when spilt. Clean up immediately. Wear protective equipment to avoid eye contact. Contain – prevent run off into drains and waterways. Use absorbent material. Collect and seal on properly labelled containers for disposal. If large quantities of this material enter the waterways, contact the Environmental Protection Authority or you local Waste Management Authority. 6.4 Reference to other sections: See Section 7 for information on safe handling.
SECTION 7: Handling & Storage
7.1 Precautions for safe handling
None required when handling small quantities. Avoid contact with eyes. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing.
Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities: Store below 30C if in original containers. Store in a cool dry well ventilated area. Store away from Incompatible materials. 7.3 Specific end use(s) No further relevant information available.
Page 4 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 8: Exposure Controls /Personal Protection:
Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters: No value assigned for this specific material
8.2 Appropriate engineering controls:
Non-required 8.3 Personal Protection:
None required when handling small quantities. Avoid contact with eyes. Do not ingest. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing. Some sensitive individuals may develop an allergic response.
National Exposure Standards: No exposure standards have been established for this material by Work Safe Australia. Biological Limit Values: No biological limit allowed.
SECTION 9: Physical & Chemical Properties
Appearance: Thick Waxy Balm Colour: Grey Odour: Cool Melon Odour threshold: Not determined. pH: 5.0-5.5 Flash point: Not available Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined. Danger of explosion: Product does not present an explosion hazard. Self-igniting: Product is not self - igniting. Solubility in / Miscibility with water: Soluble. Density at 20 °C: 0.90-1.04 g/cm³ Vapour density Not applicable. Vapour pressure: Not applicable.
SECTION 10: Stability & Reactivity
10.1 Reactivity: No further relevant information available. 10.2 Chemical stability: Stable under normal handling and storage conditions.
Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions No dangerous reactions known. 10.4 Conditions to avoid No further relevant information available. 10.5 Incompatible materials: No further relevant information available. 10.6 Hazardous decomposition products: None under normal conditions of storage and use.
SECTION 11: Toxicology Information
11.1 Information on toxicological effects:
No adverse health effects expected if the product is handled in accordance with this safety data sheet and the product label. Product is safe for its intended use based on the formulation, testing results and the history of safe consumer use.
Acute toxicity: No LD50 data available for this product
Primary irritant effect:
On the skin: No irritant effect On the eye: No irritating effect
Page 5 of 6 Quality manufacturers of bath & body care products – made in Australia
Carcinogen Classification: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed carcinogen by IARC
SECTION 12: Ecological Information
12.1 Ecotoxicity: Avoid contaminating waterways 12.2 Persistence/degradability: No tested data available on this product. 12.3 Bioaccumulative potential: This product shows a low bioaccumulation potential 12.4 Mobility: Prevent contamination of soil, ground and surface water.
Section 13: Disposals Consideration
Disposal Methods:
Refer to Waste Management Authority. Dispose of contents/containers in accordance with local/regional/national/international regulations.
SECTION 14: Transport Information
ADG 7.3 Land Transport of Dangerous Goods
Labels required: No special requirements
UN Number: N/A
Proper Shipping Name: N/A
DG Class: N/A
Subsidiary Risk: None
Packing Group: N/A
HAZCHEM Code: N/A
Special Provision: N/A
MARITIME TRANSPORTATION AIR TRANSPORTATION
IMCD IATA Dangerous Goods Regulations (DGR) 56th
Edition 2015
IMCD: N/A ICAO/IATA Class: N/A
Label: N/A Label: N/A
UN Number: N/A UN Number: N/A
Packaging Group: Not allocated Packaging Group: N/A
EMS Number: N/A
Marine Pollutant: Not allocated
Proper Shipping Name: As above Proper Shipping Name: As above Special Provisions; N/A Special Provisions; N/A
Page 6 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 15: Regulatory Information
POISONS SCHEDULE (SUSMP):
Not subject to labelling
AICS:
All ingredients in this product are compliant with NICNAS regulations
SECTION 16: OTHER INFORMATION
The information herein is accurate to the best of our knowledge. However, it is meant to describe safety requirements of our products, thus this shall not constitute a guarantee for any specific product features and shall not establish a legally valid
contractual relationship. No warranty is expressed or made as to this document’s accuracy, reliability or completeness. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated.
Relevant phrases
Non relevant Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) AICS: Australian Inventory of Chemical substances NICNAS: National Industrial Chemical Notification & Assessment Scheme IARC: International Agency for Research Cancer
MSDS prepared by: Natural Beauty Care Pty. Ltd. Issue Date: 14/06/2016 Revision Number: 1
END OF MSDS
Ozdare Business Services Chemwatch Hazard Alert Code: 4
ELEVEN GIVE ME HOLD FLEXIBLE HAIR SPRAY
Chemwatch: 33-4542Version No: 2.1.1.1Safety Data Sheet according to WHS and ADG requirements
Issue Date: 01/01/2013Print Date: 23/05/2016
Initial Date: Not AvailableS.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name ELEVEN GIVE ME HOLD FLEXIBLE HAIR SPRAY
Synonyms Not Available
Proper shipping name AEROSOLS
Other means ofidentification Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified usesSDS are intended for use in the workplace. For domestic-use products, refer to consumer labels.Application is by spray atomisation from a hand held aerosol packHair styling product.
Details of the supplier of the safety data sheet
Registered company name Ozdare Business Services
Address 7 Endeavour Way Sunshine West VIC 3020 Australia
Telephone +61 3 9314 9099
Fax +61 3 9314 9211
Website Not Available
Email Not Available
Emergency telephone number
Association / Organisation Not Available
Emergency telephonenumbers Not Available
Other emergency telephonenumbers Not Available
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGSMaxMin
Flammability 4 Toxicity 0Body Contact 2 Reactivity 1 Chronic 0
0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme
Poisons Schedule Not Applicable
Classification [1] Aerosols Category 1, Eye Irritation Category 2A
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD DANGER
Hazard statement(s)
H222 Extremely flammable aerosol.
Continued...
H319 Causes serious eye irritation.
AUH044 Risk of explosion if heated under confinement
Precautionary statement(s) Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
Precautionary statement(s) Storage
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Precautionary statement(s) DisposalNot Applicable
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
SubstancesSee section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
64-17-5 >60
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If aerosols come in contact with the eyes: Immediately hold the eyelids apart and flush the eye continuously for at least 15 minutes with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact Wipe off excess with absorbent tissue or towel.Wash with soap and water.
Inhalation
If aerosols, fumes or combustion products are inhaled:Remove to fresh air. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag-valve mask device, orpocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor.
Ingestion Not considered a normal route of entry.
Indication of any immediate medical attention and special treatment neededTreat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing mediaSMALL FIRE:
Water spray, dry chemical or CO2 LARGE FIRE:
Water spray or fog.
Special hazards arising from the substrate or mixture
Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. If safe, switch off electrical equipment until vapour fire hazard removed. Use water delivered as a fine spray to control fire and cool adjacent area.
ethanol
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DO NOT approach containers suspected to be hot.
Fire/Explosion Hazard
Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat or flame. Vapour forms an explosive mixture with air. Severe explosion hazard, in the form of vapour, when exposed to flame or spark. Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition with violent container rupture. Aerosol cans may explode on exposure to naked flames.
Other combustion products include:, carbon dioxide (CO2), other pyrolysis products typical of burning organic material
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Wear protective clothing, impervious gloves and safety glasses. Shut off all possible sources of ignition and increase ventilation. Wipe up. If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated. Undamaged cans should be gathered and stowed safely.
Major Spills
Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
None required when handling small quantities.OTHERWISE:
Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials.
Other information
Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can Store in original containers in approved flammable liquid storage area. DO NOT store in pits, depressions, basements or areas where vapours may be trapped. No smoking, naked lights, heat or ignition sources. Keep containers securely sealed. Contents under pressure. Store away from incompatible materials. Store in a cool, dry, well ventilated area.
Conditions for safe storage, including any incompatibilities
Suitable container Aerosol dispenser. Check that containers are clearly labelled.
Storage incompatibility Avoid storage with oxidisers
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
Australia Exposure Standards ethanol Ethyl alcohol 1880 mg/m3 / 1000 ppm Not Available Not Available Not Available
EMERGENCY LIMITS
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
ethanol Ethyl alcohol; (Ethanol) Not Available Not Available Not Available
Ingredient Original IDLH Revised IDLH
ethanol 15,000 ppm 3,300 [LEL] ppm
Exposure controls
Appropriate engineeringcontrols
None required when handling small quantities.OTHERWISE:Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly
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effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and"removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must matchthe particular process and chemical or contaminant in use.Employers may need to use multiple types of controls to prevent employee overexposure.
Personal protection
Eye and face protection
No special equipment for minor exposure i.e. when handling small quantities.OTHERWISE:
Safety glasses with side shields.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing oflenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class ofchemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should bereadily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable.
Skin protection See Hand protection below
Hands/feet protection
No special equipment needed when handling small quantities. OTHERWISE: For potentially moderate exposures: Wear general protective gloves, eg. light weight rubber gloves. For potentially heavy exposures: Wear chemical protective gloves, eg. PVC. and safety footwear.
Body protection See Other protection below
Other protection
No special equipment needed when handling small quantities.OTHERWISE:
Overalls. Skin cleansing cream. Eyewash unit. Do not spray on hot surfaces.
Thermal hazards Not Available
Recommended material(s)GLOVE SELECTION INDEXGlove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: ELEVEN GIVE ME HOLD FLEXIBLE HAIR SPRAY
Material CPI
BUTYL C
NATURAL RUBBER C
NATURAL+NEOPRENE C
NEOPRENE C
NITRILE C
NITRILE+PVC C
PE/EVAL/PE C
PVC C
* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of the glove, a finalselection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequent basis, factors such as"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwisebe unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
Respiratory protectionType AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSIZ88 or national equivalent)
Selection of the Class and Type of respirator will depend upon the level of breathing zonecontaminant and the chemical nature of the contaminant. Protection Factors (defined as theratio of contaminant outside and inside the mask) may also be important.
Requiredminimumprotection factor
Maximum gas/vapourconcentration present in airp.p.m. (by volume)
Half-faceRespirator
Full-FaceRespirator
up to 10 1000 AX-AUS /Class1
-
up to 50 1000 - AX-AUS /Class 1
up to 50 5000 Airline * -
up to 100 5000 - AX-2
up to 100 10000 - AX-3
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demandA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogencyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance 22aer Cloudy liquid spray with a perfumed odour; partly mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available Partition coefficientn-octanol / water Not Available
Odour threshold Not Available Auto-ignition temperature(°C) Not Available
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pH (as supplied) Not Applicable Decompositiontemperature Not Available
Melting point / freezingpoint (°C) Not Available Viscosity (cSt) Not Available
Initial boiling point andboiling range (°C) Not Available Molecular weight (g/mol) Not Applicable
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm ormN/m) Not Available
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Partly Miscible pH as a solution (1%) Not Applicable
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability
Elevated temperatures. Presence of open flame. Product is considered stable. Hazardous polymerisation will not occur.
Possibility of hazardousreactions See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decompositionproducts See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Inhalation hazard is increased at higher temperatures.Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness,slowing of reflexes, fatigue and inco-ordination.WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
Ingestion Not normally a hazard due to physical form of product.Considered an unlikely route of entry in commercial/industrial environments Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin ContactNot considered an irritant through normal use.The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,scaling and thickening of the skin.
EyeSpray mist may produce discomfortThe material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produceconjunctivitis.
Chronic
Principal routes of exposure are by accidental skin and eye contact and by inhalation of vapours especially at higher temperatures.As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should beavoided by observing good occupational work practice.WARNING: Aerosol containers may present pressure related hazards.
ELEVEN GIVE ME HOLDFLEXIBLE HAIR SPRAY
TOXICITY IRRITATION
Not Available Not Available
ethanol
TOXICITY IRRITATION
Dermal (rabbit) LD50: 17100 mg/kg[1] Eye (rabbit): 500 mg SEVERE
Inhalation (rat) LC50: 64000 ppm/4h[2] Eye (rabbit):100mg/24hr-moderate
Oral (rat) LD50: >1187-2769 mg/kg[1] Skin (rabbit):20 mg/24hr-moderate
Skin (rabbit):400 mg (open)-mild
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified dataextracted from RTECS - Register of Toxic Effect of chemical Substances
ETHANOL The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,scaling and thickening of the skin.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
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Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification
Serious EyeDamage/Irritation STOT - Single Exposure
Respiratory or Skinsensitisation STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
Ingredient Endpoint Test Duration (hr) Species Value Source
ethanol EC50 24 Algae or other aquatic plants 0.0129024mg/L 4
ethanol EC50 48 Crustacea 2mg/L 4
ethanol LC50 96 Fish 42mg/L 4
ethanol NOEC 2016 Fish 0.000375mg/L 4
ethanol EC50 72 Algae or other aquatic plants 275mg/L 2
Legend:Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 -Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
ethanol LOW (Half-life = 2.17 days) LOW (Half-life = 5.08 days)
Bioaccumulative potential
Ingredient Bioaccumulation
ethanol LOW (LogKOW = -0.31)
Mobility in soil
Ingredient Mobility
ethanol HIGH (KOC = 1)
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packagingdisposal
Consult State Land Waste Management Authority for disposal. Discharge contents of damaged aerosol cans at an approved site. Allow small quantities to evaporate. DO NOT incinerate or puncture aerosol cans. Bury residues and emptied aerosol cans at an approved site.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (ADG)
UN number 1950
Packing group Not Applicable
UN proper shipping name AEROSOLS
Environmental hazard Not Applicable
Transport hazard class(es)Class 2.1
Subrisk Not Applicable
Special precautions for userSpecial provisions 63 190 277 327 344
Limited quantity 1000ml
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Air transport (ICAO-IATA / DGR)
UN number 1950
Packing group Not Applicable
UN proper shipping name Aerosols
Environmental hazard Not Applicable
Transport hazard class(es)
ICAO/IATA Class 2.1
ICAO / IATA Subrisk Not Applicable
ERG Code 10L
Special precautions for user
Special provisions A145A167A802; A1A145A167A802
Cargo Only Packing Instructions 203
Cargo Only Maximum Qty / Pack 150 kg
Passenger and Cargo Packing Instructions 203; Forbidden
Passenger and Cargo Maximum Qty / Pack 75 kg; Forbidden
Passenger and Cargo Limited Quantity Packing Instructions Y203; Forbidden
Passenger and Cargo Limited Maximum Qty / Pack 30 kg G; Forbidden
Sea transport (IMDG-Code / GGVSee)
UN number 1950
Packing group Not Applicable
UN proper shipping name AEROSOLS
Environmental hazard Not Applicable
Transport hazard class(es)IMDG Class 2.1
IMDG Subrisk Not Applicable
Special precautions for user
EMS Number F-D, S-U
Special provisions 63 190 277 327 344 959
Limited Quantities 1000ml
Transport in bulk according to Annex II of MARPOL and the IBC codeNot Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
ETHANOL(64-17-5) IS FOUND ON THE FOLLOWING REGULATORY LISTSAustralia Exposure StandardsAustralia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
National Inventory Status
Australia - AICS Y
Canada - DSL Y
Canada - NDSL N (ethanol)
China - IECSC Y
Europe - EINEC / ELINCS /NLP Y
Japan - ENCS Y
Korea - KECI Y
New Zealand - NZIoC Y
Philippines - PICCS Y
USA - TSCA Y
Legend: Y = All ingredients are on the inventoryN = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
SECTION 16 OTHER INFORMATION
Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee usingavailable literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
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settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
Definitions and abbreviationsPC䠉TWA: Permissible Concentration-Time Weighted AveragePC䠉STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit䚹IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index
This document is copyright.Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH.TEL (+61 3) 9572 4700.
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end of SDS
Page 1 of 6 Quality manufacturers of bath & body care products – made in Australia
SAFETY DATA SHEET
According to Regulation (EC) no. 1907/2006
SECTION 1: Identification of the substance/mixture & of the Company/ Undertaking of the substance/mixture and of the
company/undertaking 1.1 Product Name: Eleven Frizz Control Shaping Cream 1.2 Application of the substance/mixture: Hair styling product. For external use only. 1.3 Details of the Manufacturer / Distributor:
Natural Beauty Care Pty Ltd 8 Teton Court, Highett, Victoria 3190, Australia.
Eleven Australia Pty Ltd 7 Endeavour Way, Sunshine West, Victoria 3020, Australia.
1.4 Emergency telephone number: +61 3 9553 0733 Facsimile Number: +61 3 9553 4988 1.5 POISON INFORMATION CENTRE: 13 11 26 (Australia)
SECTION 2: Hazard Identification
Not classified as Dangerous goods by the criteria of the Australian Dangerous goods code (ADG) for Transport and Rail. NON-DANGEROUS GOODS.
This material is a personal care product that is safe for consumers with intended and foreseeable use. This product is non-
hazardous according to Work Safe Australia.
Classification of the substance or mixture (Classification according to Regulation (EC) No 1272/2008): Nil Classification according to the Directive 67/548/EEC or Directive 1999/45/EC: Not regulated
Signal word: Not relevant
Hazard statements:
Not relevant Precautionary statements:
P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P103 Read label before use
Page 2 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 3: Composition/formulation on ingredients
SECTION 4: First Aid Measures
4.1 Description of first aid measures
General information: No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Name of Chemical CAS Number Percentage w/w
Water (Aqua) 7732-18-5 < 70-80 Cetearyl Alcohol 67762-27-0 < 10 Glycerin 56-81-5 < 10 Petrolatum 8009-03-8 < 5 Ceteareth-20 68439-49-6 < 5 Propylene Glycol 57-55-6 < 5 PEG-75 Lanolin 61790-81-6 < 5 Paraffin 8002-74-2 < 5 PVP 9003-39-8 < 5 Cyclopentasiloxane 541-02-6 < 1 Phenoxyethanol 122-99-6 < 1 Cyclohexasiloxane 540-97-6 < 0.5 Carbomer 9003-01-4 < 0.5 Fragrance (Parfum) - < 0.5 Benzyl Alcohol 100-51-6 < 0.5 Triethanolamine 102-71-6 < 0.5
HEALTH EFFECTS: Acute - Swallowed May be harmful if large amounts are swallowed Acute - Eye Full strength material may be irritating to eyes Acute - Skin Not considered an irritant through normal use. Full strength material in repeated
or prolonged contact with skin may be irritating and cause allergic reactions in sensitive individuals
Acute - Inhaled Full strength material should not cause any irritation to the mucous membrane and upper airways
FIRST AID: Swallowed Do not induce vomiting, Give plenty of water and seek medical advice Eye Flush eye with copious amounts of water for 15 minutes including under eyelid. If
discomfit persists, obtain medical advice.
Skin Remove contaminated clothing. Wash affected areas with warm soapy water
Inhaled Remove to fresh uncontaminated air, lay patient on back until breathing returns to normal
Page 3 of 6 Quality manufacturers of bath & body care products – made in Australia
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting Measures
5.1 Suitable Extinguishing media: Carbon dioxide, Foam, Dry Chemical 5.2 Special hazards arising from the substance or mixture:
No further relevant information available. 5.3 Advice for firefighters:
Wear Protective equipment. Do not inhale explosion gases or combustion gases. Hazchem Code: Not applicable.
SECTION 6: Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures: Remove all sources of ignition. Increase
ventilation. Evacuate all personnel. Wear sufficient respiratory protection and full protective clothing to minimise skin and
eye exposure. If possible contain the spill.
6.2 Environmental precautions: No special measures required. 6.3 Methods and material for containment and cleaning up: Slippery when spilt. Clean up immediately. Wear protective equipment to avoid eye contact. Contain – prevent run off into drains and waterways. Use absorbent material. Collect and seal on properly labelled containers for disposal. If large quantities of this material enter the waterways, contact the Environmental Protection Authority or you local Waste Management Authority. 6.4 Reference to other sections: See Section 7 for information on safe handling.
SECTION 7: Handling & Storage
7.1 Precautions for safe handling
None required when handling small quantities. Avoid contact with eyes. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing.
Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities: Store below 30C if in original containers. Store in a cool dry well ventilated area. Store away from Incompatible materials. 7.3 Specific end use(s) No further relevant information available.
Page 4 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 8: Exposure Controls /Personal Protection:
Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters: No value assigned for this specific material
8.2 Appropriate engineering controls:
Non-required 8.3 Personal Protection:
None required when handling small quantities. Avoid contact with eyes. Do not ingest. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing. Some sensitive individuals may develop an allergic response.
National Exposure Standards: No exposure standards have been established for this material by Work Safe Australia.
Biological Limit Values: No biological limit allowed.
SECTION 9: Physical & Chemical Properties
Appearance: Thick Waxy Balm Colour: White/ Off White
Odour: Pomegranate Odour threshold: Not determined. pH: 6.0-6.5 Flash point: Not available Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined. Danger of explosion: Product does not present an explosion hazard. Self-igniting: Product is not self - igniting. Solubility in / Miscibility with water: Soluble. Density at 20 °C: 0.90-1.04 g/cm³ Vapour density Not applicable. Vapour pressure: Not applicable.
SECTION 10: Stability & Reactivity
10.1 Reactivity: No further relevant information available. 10.2 Chemical stability: Stable under normal handling and storage conditions.
Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions No dangerous reactions known. 10.4 Conditions to avoid No further relevant information available. 10.5 Incompatible materials: No further relevant information available. 10.6 Hazardous decomposition products: None under normal conditions of storage and use.
SECTION 11: Toxicology Information
11.1 Information on toxicological effects:
No adverse health effects expected if the product is handled in accordance with this safety data sheet and the product label. Product is safe for its intended use based on the formulation, testing results and the history of safe consumer use.
Acute toxicity: No LD50 data available for this product
Primary irritant effect:
On the skin: No irritant effect
On the eye: No irritating effect
Page 5 of 6 Quality manufacturers of bath & body care products – made in Australia
Carcinogen Classification: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed carcinogen by IARC
SECTION 12: Ecological Information
12.1 Ecotoxicity: Avoid contaminating waterways 12.2 Persistence/degradability: No tested data available on this product. 12.3 Bioaccumulative potential: This product shows a low bioaccumulation potential 12.4 Mobility: Prevent contamination of soil, ground and surface water.
Section 13: Disposals Consideration
Disposal Methods:
Refer to Waste Management Authority. Dispose of contents/containers in accordance with local/regional/national/international regulations.
SECTION 14: Transport Information
ADG 7.3 Land Transport of Dangerous Goods
Labels required: No special requirements
UN Number: N/A
Proper Shipping Name: N/A
DG Class: N/A
Subsidiary Risk: None
Packing Group: N/A
HAZCHEM Code: N/A
Special Provision: N/A
MARITIME TRANSPORTATION AIR TRANSPORTATION
IMCD IATA Dangerous Goods Regulations (DGR) 56th
Edition 2015
IMCD: N/A ICAO/IATA Class: N/A
Label: N/A Label: N/A
UN Number: N/A UN Number: N/A
Packaging Group: Not allocated Packaging Group: N/A
EMS Number: N/A
Marine Pollutant: Not allocated
Proper Shipping Name: As above Proper Shipping Name: As above Special Provisions; N/A Special Provisions; N/A
Page 6 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 15: Regulatory Information
POISONS SCHEDULE (SUSMP):
Not subject to labelling
AICS:
All ingredients in this product are compliant with NICNAS regulations
SECTION 16: OTHER INFORMATION
The information herein is accurate to the best of our knowledge. However, it is meant to describe safety requirements of our
products, thus this shall not constitute a guarantee for any specific product features and shall not establish a legally valid
contractual relationship. No warranty is expressed or made as to this document’s accuracy, reliability or completeness. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated.
Relevant phrases
Non relevant Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) AICS: Australian Inventory of Chemical substances NICNAS: National Industrial Chemical Notification & Assessment Scheme IARC: International Agency for Research Cancer
MSDS prepared by: Natural Beauty Care Pty. Ltd. Issue Date: 14/06/2016
Revision Number: 1
END OF MSDS
Eleven Australia Pty Ltd Chemwatch Hazard Alert Code: 4
Eleven Give Me Hold Strong Hairspray
Chemwatch: 46-2405Version No: 2.1.1.1Safety Data Sheet according to WHS and ADG requirements
Issue Date: 11/12/2014Print Date: 23/05/2016
Initial Date: Not AvailableS.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Eleven Give Me Hold Strong Hairspray
Synonyms Not Available
Proper shipping name AEROSOLS
Other means ofidentification Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified usesSDS are intended for use in the workplace. For domestic-use products, refer to consumer labels.Application is by spray atomisation from a hand held aerosol packHair styling product.
Details of the supplier of the safety data sheet
Registered company name Eleven Australia Pty Ltd
Address 7 Endeavour Way Sunshine West VIC 3020 Australia
Telephone 1800 104 204
Fax +61 3 9314 9211
Website Not Available
Email Not Available
Emergency telephone number
Association / Organisation Not Available
Emergency telephonenumbers Not Available
Other emergency telephonenumbers Not Available
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGSMaxMin
Flammability 4 Toxicity 0Body Contact 2 Reactivity 1 Chronic 0
0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme
Poisons Schedule Not Applicable
Classification [1] Aerosols Category 1, Eye Irritation Category 2A
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD DANGER
Continued...
Hazard statement(s)
H222 Extremely flammable aerosol.
H319 Causes serious eye irritation.
AUH044 Risk of explosion if heated under confinement
Precautionary statement(s) Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
Precautionary statement(s) Storage
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Precautionary statement(s) DisposalNot Applicable
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
SubstancesSee section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
64-17-5 50-60
68476-85-7. 30-40
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If aerosols come in contact with the eyes: Immediately hold the eyelids apart and flush the eye continuously for at least 15 minutes with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact Wipe off excess with absorbent tissue or towel.Wash with soap and water.
Inhalation
If aerosols, fumes or combustion products are inhaled:Remove to fresh air. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag-valve mask device, orpocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor.
Ingestion Not considered a normal route of entry.
Indication of any immediate medical attention and special treatment neededTreat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing mediaSMALL FIRE:
Water spray, dry chemical or CO2 LARGE FIRE:
Water spray or fog.
Special hazards arising from the substrate or mixture
Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course.
ethanol
hydrocarbon propellant
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If safe, switch off electrical equipment until vapour fire hazard removed. Use water delivered as a fine spray to control fire and cool adjacent area. DO NOT approach containers suspected to be hot.
Fire/Explosion Hazard
Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat or flame. Vapour forms an explosive mixture with air. Severe explosion hazard, in the form of vapour, when exposed to flame or spark. Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition with violent container rupture. Aerosol cans may explode on exposure to naked flames.
Other combustion products include:, carbon dioxide (CO2), other pyrolysis products typical of burning organic material
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Wear protective clothing, impervious gloves and safety glasses. Shut off all possible sources of ignition and increase ventilation. Wipe up. If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated. Undamaged cans should be gathered and stowed safely.
Major Spills
Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
None required when handling small quantities.OTHERWISE:
Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials.
Other information
Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can Store in original containers in approved flammable liquid storage area. DO NOT store in pits, depressions, basements or areas where vapours may be trapped. No smoking, naked lights, heat or ignition sources. Keep containers securely sealed. Contents under pressure. Store away from incompatible materials. Store in a cool, dry, well ventilated area.
Conditions for safe storage, including any incompatibilities
Suitable container Aerosol dispenser. Check that containers are clearly labelled.
Storage incompatibility Avoid storage with oxidisers
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
Australia Exposure Standards ethanol Ethyl alcohol 1880 mg/m3 / 1000 ppm Not Available Not Available Not Available
Australia Exposure Standards hydrocarbon propellant LPG (liquified petroleum gas) 1800 mg/m3 / 1000 ppm Not Available Not Available Not Available
EMERGENCY LIMITS
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
ethanol Ethyl alcohol; (Ethanol) Not Available Not Available Not Available
hydrocarbon propellant Liquified petroleum gas; (L.P.G.) 3,000 ppm 3200 ppm 19000 ppm
Ingredient Original IDLH Revised IDLH
ethanol 15,000 ppm 3,300 [LEL] ppm
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hydrocarbon propellant 19,000 [LEL] ppm 2,000 [LEL] ppm
Exposure controls
Appropriate engineeringcontrols
None required when handling small quantities.OTHERWISE:Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highlyeffective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and"removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must matchthe particular process and chemical or contaminant in use.Employers may need to use multiple types of controls to prevent employee overexposure.
Personal protection
Eye and face protection
No special equipment for minor exposure i.e. when handling small quantities.OTHERWISE:
Safety glasses with side shields.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing oflenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class ofchemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should bereadily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable.
Skin protection See Hand protection below
Hands/feet protection
No special equipment needed when handling small quantities. OTHERWISE: For potentially moderate exposures: Wear general protective gloves, eg. light weight rubber gloves. For potentially heavy exposures: Wear chemical protective gloves, eg. PVC. and safety footwear.
Body protection See Other protection below
Other protection
No special equipment needed when handling small quantities.OTHERWISE:
Overalls. Skin cleansing cream. Eyewash unit. Do not spray on hot surfaces.
Thermal hazards Not Available
Recommended material(s)GLOVE SELECTION INDEXGlove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: Eleven Give Me Hold Strong Hairspray
Material CPI
BUTYL C
NATURAL RUBBER C
NATURAL+NEOPRENE C
NEOPRENE C
NITRILE C
NITRILE+PVC C
PE/EVAL/PE C
PVC C
* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of the glove, a finalselection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequent basis, factors such as"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwisebe unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
Respiratory protectionType AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSIZ88 or national equivalent)
Selection of the Class and Type of respirator will depend upon the level of breathing zonecontaminant and the chemical nature of the contaminant. Protection Factors (defined as theratio of contaminant outside and inside the mask) may also be important.
Requiredminimumprotection factor
Maximum gas/vapourconcentration present in airp.p.m. (by volume)
Half-faceRespirator
Full-FaceRespirator
up to 10 1000 AX-AUS /Class1
-
up to 50 1000 - AX-AUS /Class 1
up to 50 5000 Airline * -
up to 100 5000 - AX-2
up to 100 10000 - AX-3
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demandA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogencyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance 22aer Clear spray with a pleasant odour; does not mix with water.
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Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available Partition coefficientn-octanol / water Not Available
Odour threshold Not Available Auto-ignition temperature(°C) Not Available
pH (as supplied) Not Applicable Decompositiontemperature Not Available
Melting point / freezingpoint (°C) Not Available Viscosity (cSt) Not Available
Initial boiling point andboiling range (°C) Not Available Molecular weight (g/mol) Not Applicable
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm ormN/m) Not Available
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Immiscible pH as a solution (1%) Not Applicable
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability
Elevated temperatures. Presence of open flame. Product is considered stable. Hazardous polymerisation will not occur.
Possibility of hazardousreactions See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decompositionproducts See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Inhalation hazard is increased at higher temperatures.Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness,slowing of reflexes, fatigue and inco-ordination.WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
Ingestion Not normally a hazard due to physical form of product.Considered an unlikely route of entry in commercial/industrial environments Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin ContactNot considered an irritant through normal use.The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,scaling and thickening of the skin.
EyeSpray mist may produce discomfortThe material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produceconjunctivitis.
Chronic
Principal routes of exposure are by accidental skin and eye contact and by inhalation of vapours especially at higher temperatures.As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should beavoided by observing good occupational work practice.WARNING: Aerosol containers may present pressure related hazards.
Eleven Give Me HoldStrong Hairspray
TOXICITY IRRITATION
Not Available Not Available
ethanol
TOXICITY IRRITATION
Dermal (rabbit) LD50: 17100 mg/kg[1] Eye (rabbit): 500 mg SEVERE
Inhalation (rat) LC50: 64000 ppm/4h[2] Eye (rabbit):100mg/24hr-moderate
Oral (rat) LD50: >1187-2769 mg/kg[1] Skin (rabbit):20 mg/24hr-moderate
Skin (rabbit):400 mg (open)-mild
hydrocarbon propellant
TOXICITY IRRITATION
Inhalation (mouse) LC50: >15.6-<17.9 mm/l2 h mm/l2="">[1] Not Available
Inhalation (mouse) LC50: >15.6-<17.9 mm/l2 h mm/l2="">[1]
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Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification
Inhalation (mouse) LC50: 410000 ppm2 h[1]
Inhalation (mouse) LC50: 410000 ppm2 h[1]
Inhalation (rat) LC50: >800000 ppm15 min[1]
Inhalation (rat) LC50: >800000 ppm15 min[1]
Inhalation (rat) LC50: 1354.944 mg/L15 min[1]
Inhalation (rat) LC50: 1355 mg/l15 min[1]
Inhalation (rat) LC50: 1442.738 mg/L15 min[1]
Inhalation (rat) LC50: 1442.738 mg/L15 min[1]
Inhalation (rat) LC50: 1443 mg/l15 min[1]
Inhalation (rat) LC50: 1443 mg/l15 min[1]
Inhalation (rat) LC50: 570000 ppm15 min[1]
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified dataextracted from RTECS - Register of Toxic Effect of chemical Substances
ETHANOL The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,scaling and thickening of the skin.
HYDROCARBONPROPELLANT
No significant acute toxicological data identified in literature search. inhalation of the gas
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious EyeDamage/Irritation STOT - Single Exposure
Respiratory or Skinsensitisation STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
Ingredient Endpoint Test Duration (hr) Species Value Source
ethanol EC50 24 Algae or other aquatic plants 0.0129024mg/L 4
ethanol EC50 48 Crustacea 2mg/L 4
ethanol LC50 96 Fish 42mg/L 4
ethanol NOEC 2016 Fish 0.000375mg/L 4
ethanol EC50 72 Algae or other aquatic plants 275mg/L 2
hydrocarbon propellant LC50 96 Fish 24.11mg/L 2
hydrocarbon propellant EC50 96 Algae or other aquatic plants 7.71mg/L 2
hydrocarbon propellant EC50 96 Algae or other aquatic plants 8.57mg/L 2
hydrocarbon propellant LC50 96 Fish 24.11mg/L 2
hydrocarbon propellant EC50 96 Algae or other aquatic plants 7.71mg/L 2
hydrocarbon propellant EC50 96 Algae or other aquatic plants 8.57mg/L 2
Legend:Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 -Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
ethanol LOW (Half-life = 2.17 days) LOW (Half-life = 5.08 days)
Bioaccumulative potential
Ingredient Bioaccumulation
ethanol LOW (LogKOW = -0.31)
Mobility in soil
Ingredient Mobility
ethanol HIGH (KOC = 1)
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SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packagingdisposal
Consult State Land Waste Management Authority for disposal. Discharge contents of damaged aerosol cans at an approved site. Allow small quantities to evaporate. DO NOT incinerate or puncture aerosol cans. Bury residues and emptied aerosol cans at an approved site.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (ADG)
UN number 1950
Packing group Not Applicable
UN proper shipping name AEROSOLS
Environmental hazard Not Applicable
Transport hazard class(es)Class 2.1
Subrisk Not Applicable
Special precautions for userSpecial provisions 63 190 277 327 344
Limited quantity 1000ml
Air transport (ICAO-IATA / DGR)
UN number 1950
Packing group Not Applicable
UN proper shipping name Aerosols
Environmental hazard Not Applicable
Transport hazard class(es)
ICAO/IATA Class 2.1
ICAO / IATA Subrisk Not Applicable
ERG Code 10L
Special precautions for user
Special provisions A145A167A802; A1A145A167A802
Cargo Only Packing Instructions 203
Cargo Only Maximum Qty / Pack 150 kg
Passenger and Cargo Packing Instructions 203; Forbidden
Passenger and Cargo Maximum Qty / Pack 75 kg; Forbidden
Passenger and Cargo Limited Quantity Packing Instructions Y203; Forbidden
Passenger and Cargo Limited Maximum Qty / Pack 30 kg G; Forbidden
Sea transport (IMDG-Code / GGVSee)
UN number 1950
Packing group Not Applicable
UN proper shipping name AEROSOLS
Environmental hazard Not Applicable
Transport hazard class(es)IMDG Class 2.1
IMDG Subrisk Not Applicable
Special precautions for user
EMS Number F-D, S-U
Special provisions 63 190 277 327 344 959
Limited Quantities 1000ml
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Transport in bulk according to Annex II of MARPOL and the IBC codeNot Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
ETHANOL(64-17-5) IS FOUND ON THE FOLLOWING REGULATORY LISTSAustralia Exposure StandardsAustralia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
HYDROCARBON PROPELLANT(68476-85-7.) IS FOUND ON THE FOLLOWING REGULATORY LISTSAustralia Exposure StandardsAustralia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited ListPassenger and Cargo Aircraft
National Inventory Status
Australia - AICS Y
Canada - DSL Y
Canada - NDSL N (ethanol; hydrocarbon propellant)
China - IECSC Y
Europe - EINEC / ELINCS /NLP Y
Japan - ENCS N (hydrocarbon propellant)
Korea - KECI Y
New Zealand - NZIoC Y
Philippines - PICCS Y
USA - TSCA Y
Legend: Y = All ingredients are on the inventoryN = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
SECTION 16 OTHER INFORMATION
Other information
Ingredients with multiple cas numbers
Name CAS No
hydrocarbon propellant 68476-85-7., 68476-86-8.
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee usingavailable literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or othersettings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
Definitions and abbreviationsPC䠉TWA: Permissible Concentration-Time Weighted AveragePC䠉STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit䚹IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index
This document is copyright.Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH.TEL (+61 3) 9572 4700.
Chemwatch: 46-2405Version No: 2.1.1.1
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end of SDS
Page 1 of 6 Quality manufacturers of bath & body care products – made in Australia
SAFETY DATA SHEET
According to Regulation (EC) no. 1907/2006 SECTION 1: Identification of the substance/mixture & of the Company/ Undertaking of the substance/mixture and of the
company/undertaking 1.1 Product Name: Hand and Body Lotion 1.2 Application of the substance/mixture: Hand and Body Lotion. For external use only. 1.3 Details of the Manufacturer / Distributor:
Natural Beauty Care Pty Ltd 8 Teton Court, Highett, Victoria 3190, Australia.
Eleven Australia Pty Ltd 7 Endeavour Way, Sunshine West, Victoria 3020, Australia.
1.4 Emergency telephone number: +61 3 9553 0733 Facsimile Number: +61 3 9553 4988 1.5 POISON INFORMATION CENTRE: 13 11 26 (Australia)
SECTION 2: Hazard Identification
Not classified as Dangerous goods by the criteria of the Australian Dangerous goods code (ADG) for Transport and Rail. NON-DANGEROUS GOODS.
This material is a personal care product that is safe for consumers with intended and foreseeable use. This product is non- hazardous according to Work Safe Australia.
Classification of the substance or mixture (Classification according to Regulation (EC) No 1272/2008): Nil Classification according to the Directive 67/548/EEC or Directive 1999/45/EC: Not regulated
Signal word: Not relevant
Hazard statements:
Not relevant Precautionary statements:
P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P103 Read label before use
Page 2 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 3: Composition/formulation on ingredients
SECTION 4: First Aid Measures
4.1 Description of first aid measures
General information: No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Name of Chemical CAS Number Percentage
w/w
Water (Aqua) 7732-18-5 > 80-90 Isopropyl Myristate 110-27-0 < 10 Glycerin 56-81-5 < 5 Glyceryl Stearate SE 11099-07-3 < 5 Cetearyl Alcohol 67762-27-0 < 5 Dimethicone 9006-65-9 < 5 Natural oils and extracts - < 5 Stearic Acid 57-11-4 < 5 Fragrance (Parfum) - < 1 Phenoxyethanol 122-99-6 < 1 Ethylhexylglycerin 70445-33-9 < 0.5 Citric Acid 5949-29-1 < 0.5 Triethanolamine 102-71-6 < 0.5 Acrylates/C10-30 Alkyl Acrylate Crosspolymer - < 0.5 Tocopheryl Acetate 7695-91-2 < 0.5 Benzyl Alcohol 100-51-6 < 0.5 Disodium EDTA 139-33-3 < 0.5
HEALTH EFFECTS: Acute - Swallowed May be harmful if large amounts are swallowed Acute - Eye Full strength material may be irritating to eyes Acute - Skin Not considered an irritant through normal use. Full strength material in repeated
or prolonged contact with skin may be irritating and cause allergic reactions in sensitive individuals
Acute - Inhaled Full strength material should not cause any irritation to the mucous membrane and upper airways
Page 3 of 6 Quality manufacturers of bath & body care products – made in Australia
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting Measures
5.1 Suitable Extinguishing media: Carbon dioxide, Foam, Dry Chemical 5.2 Special hazards arising from the substance or mixture:
No further relevant information available. 5.3 Advice for firefighters:
Wear Protective equipment. Do not inhale explosion gases or combustion gases. Hazchem Code: Not applicable.
SECTION 6: Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures: Remove all sources of ignition. Increase ventilation. Evacuate all personnel. Wear sufficient respiratory protection and full protective clothing to minimise skin and eye exposure. If possible contain the spill. 6.2 Environmental precautions: No special measures required. 6.3 Methods and material for containment and cleaning up: Slippery when spilt. Clean up immediately. Wear protective equipment to avoid eye contact. Contain – prevent run off into drains and waterways. Use absorbent material. Collect and seal on properly labelled containers for disposal. If large quantities of this material enter the waterways, contact the Environmental Protection Authority or you local Waste Management Authority. 6.4 Reference to other sections: See Section 7 for information on safe handling.
FIRST AID: Swallowed Do not induce vomiting, Give plenty of water and seek medical advice Eye Flush eye with copious amounts of water for 15 minutes including under eyelid. If
discomfit persists, obtain medical advice. Skin Remove contaminated clothing. Wash affected areas with warm soapy water
Inhaled Remove to fresh uncontaminated air, lay patient on back until breathing returns to normal
Page 4 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 7: Handling & Storage
7.1 Precautions for safe handling
None required when handling small quantities. Avoid contact with eyes. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing.
Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities: Store below 30C if in original containers. Store in a cool dry well ventilated area. Store away from Incompatible materials. 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure Controls /Personal Protection:
Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters: No value assigned for this specific material
8.2 Appropriate engineering controls:
Non-required 8.3 Personal Protection:
None required when handling small quantities. Avoid contact with eyes. Do not ingest. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing. Some sensitive individuals may develop an allergic response.
National Exposure Standards: No exposure standards have been established for this material by Work Safe Australia. Biological Limit Values: No biological limit allowed.
SECTION 9: Physical & Chemical Properties
Appearance: Thick smooth cream Colour: White Odour: Characteristic aroma of aloe & cucumber Odour threshold: Not determined. pH: 5.5 -6.0 Flash point: Not available Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined. Danger of explosion: Product does not present an explosion hazard. Self-igniting: Product is not self - igniting. Solubility in / Miscibility with water: Soluble. Density at 20 °C: 0.90-1.04 g/cm³ Vapour density Not applicable. Vapour pressure: Not applicable.
SECTION 10: Stability & Reactivity
10.1 Reactivity: No further relevant information available. 10.2 Chemical stability: Stable under normal handling and storage conditions.
Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions No dangerous reactions known. 10.4 Conditions to avoid No further relevant information available.
Page 5 of 6 Quality manufacturers of bath & body care products – made in Australia
10.5 Incompatible materials: No further relevant information available. 10.6 Hazardous decomposition products: None under normal conditions of storage and use.
SECTION 11: Toxicology Information
11.1 Information on toxicological effects:
No adverse health effects expected if the product is handled in accordance with this safety data sheet and the product label. Product is safe for its intended use based on the formulation, testing results and the history of safe consumer use.
Acute toxicity: No LD50 data available for this product
Primary irritant effect:
On the skin: No irritant effect On the eye: No irritating effect Carcinogen Classification: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed carcinogen by IARC
SECTION 12: Ecological Information
12.1 Ecotoxicity: Avoid contaminating waterways 12.2 Persistence/degradability: No tested data available on this product. 12.3 Bioaccumulative potential: This product shows a low bioaccumulation potential 12.4 Mobility: Prevent contamination of soil, ground and surface water.
Section 13: Disposals Consideration
Disposal Methods:
Refer to Waste Management Authority. Dispose of contents/containers in accordance with local/regional/national/international regulations.
SECTION 14: Transport Information
ADG 7.3 Land Transport of Dangerous Goods
Labels required: No special requirements
UN Number: N/A
Proper Shipping Name: N/A
DG Class: N/A
Subsidiary Risk: None
Packing Group: N/A
HAZCHEM Code: N/A
Special Provision: N/A
Page 6 of 6 Quality manufacturers of bath & body care products – made in Australia
MARITIME TRANSPORTATION AIR TRANSPORTATION
IMCD IATA Dangerous Goods Regulations (DGR) 56th
Edition 2015
IMCD: N/A ICAO/IATA Class: N/A
Label: N/A Label: N/A
UN Number: N/A UN Number: N/A
Packaging Group: Not allocated Packaging Group: N/A
EMS Number: N/A
Marine Pollutant: Not allocated
Proper Shipping Name: As above Proper Shipping Name: As above Special Provisions; N/A Special Provisions; N/A
SECTION 15: Regulatory Information
POISONS SCHEDULE (SUSMP):
Not subject to labelling
AICS:
All ingredients in this product are compliant with NICNAS regulations
SECTION 16: OTHER INFORMATION
The information herein is accurate to the best of our knowledge. However, it is meant to describe safety requirements of our products, thus this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. No warranty is expressed or made as to this document’s accuracy, reliability or completeness. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated. Relevant phrases
Non relevant Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) AICS: Australian Inventory of Chemical substances NICNAS: National Industrial Chemical Notification & Assessment Scheme IARC: International Agency for Research Cancer
MSDS prepared by: Natural Beauty Care Pty. Ltd. Issue Date: 14/06/2016 Revision Number: 1
END OF MSDS
Page 1 of 6 Quality manufacturers of bath & body care products – made in Australia
SAFETY DATA SHEET
According to Regulation (EC) no. 1907/2006 SECTION 1: Identification of the substance/mixture & of the Company/ Undertaking of the substance/mixture and of the
company/undertaking 1.1 Product Name: Wash Me All Over Hand and Body Wash 1.2 Application of the substance/mixture: Hand and Body Wash. For external use only. 1.3 Details of the Manufacturer / Distributor:
Natural Beauty Care Pty Ltd 8 Teton Court, Highett, Victoria 3190, Australia.
Eleven Australia Pty Ltd 7 Endeavour Way, Sunshine West, Victoria 3020, Australia.
1.4 Emergency telephone number: +61 3 9553 0733 Facsimile Number: +61 3 9553 4988 1.5 POISON INFORMATION CENTRE: 13 11 26 (Australia)
SECTION 2: Hazard Identification
Not classified as Dangerous goods by the criteria of the Australian Dangerous goods code (ADG) for Transport and Rail. NON-DANGEROUS GOODS.
This material is a personal care product that is safe for consumers with intended and foreseeable use. This product is non- hazardous according to Work Safe Australia.
Classification of the substance or mixture (Classification according to Regulation (EC) No 1272/2008): Nil Classification according to the Directive 67/548/EEC or Directive 1999/45/EC: Not regulated
Signal word: Not relevant
Hazard statements:
Not relevant Precautionary statements:
P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P103 Read label before use
Page 2 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 3: Composition/formulation on ingredients
SECTION 4: First Aid Measures
4.1 Description of first aid measures
General information: No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Name of Chemical CAS Number Percentage
w/w
Water (Aqua) 7732-18-5 > 60-70 Ammonium Lauryl Sulfate 2235-54-3 < 10 Cocamide DEA 68603-42-9 < 5 Cocamidopropyl Betaine 61789-40-0 < 5 Natural oils and extracts - < 1 Citric Acid 77-92-9 < 0.5 Potassium Sorbate 24634-61-5 < 0.5 Phenoxyethanol 122-99-6 < 0.5 Sodium Chloride 7647-14-5 < 0.5 Ascorbic Acid 50-81-7 < 0.5
HEALTH EFFECTS: Acute - Swallowed May be harmful if large amounts are swallowed Acute - Eye Full strength material may be irritating to eyes Acute - Skin Not considered an irritant through normal use. Full strength material in repeated
or prolonged contact with skin may be irritating and cause allergic reactions in sensitive individuals
Acute - Inhaled Full strength material should not cause any irritation to the mucous membrane and upper airways
FIRST AID: Swallowed Do not induce vomiting, Give plenty of water and seek medical advice Eye Flush eye with copious amounts of water for 15 minutes including under eyelid. If
discomfit persists, obtain medical advice. Skin Remove contaminated clothing. Wash affected areas with warm soapy water
Inhaled Remove to fresh uncontaminated air, lay patient on back until breathing returns to normal
Page 3 of 6 Quality manufacturers of bath & body care products – made in Australia
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting Measures
5.1 Suitable Extinguishing media: Carbon dioxide, Foam, Dry Chemical 5.2 Special hazards arising from the substance or mixture:
No further relevant information available. 5.3 Advice for firefighters:
Wear Protective equipment. Do not inhale explosion gases or combustion gases. Hazchem Code: Not applicable.
SECTION 6: Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures: Remove all sources of ignition. Increase ventilation. Evacuate all personnel. Wear sufficient respiratory protection and full protective clothing to minimise skin and eye exposure. If possible contain the spill. 6.2 Environmental precautions: No special measures required. 6.3 Methods and material for containment and cleaning up: Slippery when spilt. Clean up immediately. Wear protective equipment to avoid eye contact. Contain – prevent run off into drains and waterways. Use absorbent material. Collect and seal on properly labelled containers for disposal. If large quantities of this material enter the waterways, contact the Environmental Protection Authority or you local Waste Management Authority. 6.4 Reference to other sections: See Section 7 for information on safe handling.
SECTION 7: Handling & Storage
7.1 Precautions for safe handling
None required when handling small quantities. Avoid contact with eyes. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing.
Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities: Store below 30C if in original containers. Store in a cool dry well ventilated area. Store away from Incompatible materials. 7.3 Specific end use(s) No further relevant information available.
Page 4 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 8: Exposure Controls /Personal Protection:
Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters: No value assigned for this specific material
8.2 Appropriate engineering controls:
Non-required 8.3 Personal Protection:
None required when handling small quantities. Avoid contact with eyes. Do not ingest. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing. Some sensitive individuals may develop an allergic response.
National Exposure Standards: No exposure standards have been established for this material by Work Safe Australia. Biological Limit Values: No biological limit allowed.
SECTION 9: Physical & Chemical Properties
Appearance: Thick smooth Gel Colour: Clear Colourless Odour: Characteristic Odour threshold: Not determined. pH: 4.2-4.9 Flash point: Not available Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined. Danger of explosion: Product does not present an explosion hazard. Self-igniting: Product is not self - igniting. Solubility in / Miscibility with water: Soluble. Density at 20 °C: 0.90-1.04 g/cm³ Vapour density Not applicable. Vapour pressure: Not applicable.
SECTION 10: Stability & Reactivity
10.1 Reactivity: No further relevant information available. 10.2 Chemical stability: Stable under normal handling and storage conditions.
Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions No dangerous reactions known. 10.4 Conditions to avoid No further relevant information available. 10.5 Incompatible materials: No further relevant information available. 10.6 Hazardous decomposition products: None under normal conditions of storage and use.
SECTION 11: Toxicology Information
11.1 Information on toxicological effects:
No adverse health effects expected if the product is handled in accordance with this safety data sheet and the product label. Product is safe for its intended use based on the formulation, testing results and the history of safe consumer use.
Acute toxicity: No LD50 data available for this product
Primary irritant effect:
On the skin: No irritant effect On the eye: No irritating effect
Page 5 of 6 Quality manufacturers of bath & body care products – made in Australia
Carcinogen Classification: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed carcinogen by IARC
SECTION 12: Ecological Information
12.1 Ecotoxicity: Avoid contaminating waterways 12.2 Persistence/degradability: No tested data available on this product. 12.3 Bioaccumulative potential: This product shows a low bioaccumulation potential 12.4 Mobility: Prevent contamination of soil, ground and surface water.
Section 13: Disposals Consideration
Disposal Methods:
Refer to Waste Management Authority. Dispose of contents/containers in accordance with local/regional/national/international regulations.
SECTION 14: Transport Information
ADG 7.3 Land Transport of Dangerous Goods
Labels required: No special requirements
UN Number: N/A
Proper Shipping Name: N/A
DG Class: N/A
Subsidiary Risk: None
Packing Group: N/A
HAZCHEM Code: N/A
Special Provision: N/A
MARITIME TRANSPORTATION AIR TRANSPORTATION
IMCD IATA Dangerous Goods Regulations (DGR) 56th
Edition 2015
IMCD: N/A ICAO/IATA Class: N/A
Label: N/A Label: N/A
UN Number: N/A UN Number: N/A
Packaging Group: Not allocated Packaging Group: N/A
EMS Number: N/A
Marine Pollutant: Not allocated
Proper Shipping Name: As above Proper Shipping Name: As above Special Provisions; N/A Special Provisions; N/A
Page 6 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 15: Regulatory Information
POISONS SCHEDULE (SUSMP):
Not subject to labelling
AICS:
All ingredients in this product are compliant with NICNAS regulations
SECTION 16: OTHER INFORMATION
The information herein is accurate to the best of our knowledge. However, it is meant to describe safety requirements of our products, thus this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. No warranty is expressed or made as to this document’s accuracy, reliability or completeness. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated. Relevant phrases
Non relevant Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) AICS: Australian Inventory of Chemical substances NICNAS: National Industrial Chemical Notification & Assessment Scheme IARC: International Agency for Research Cancer
MSDS prepared by: Natural Beauty Care Pty. Ltd. Issue Date: 14/06/2016 Revision Number: 1
END OF MSDS
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare Hydrate My Hair Moisture Conditioner Other Name: Conditioner Product Use: To condition and beautify hair after cleansing, or before or after other hair treatments. Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Certrimonium Chloride 112-02-7 <2.5 Behentrimonium Chloride 17301-53-0 <1.50 Cyclomethicone 69430-24-6 <2.50 Other ingredients to 100
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures
Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: White opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 0.95 – 1.00 Water Solubility: Completely soluble in water. pH: 3.00 – 4.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity
Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare Hydrate my Hair Moisture Shampoo Other Name: Shampoo Product Use: To cleanse the hair Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Sodium Lauryl Sulphate 151-21-3 <10 Cocamido Propyl Betain 80438-79-1 <10 Other ingredients to 100 The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures
Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: White opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 1.01 – 1.03 Water Solubility: Completely soluble in water. pH: 5.50 – 6.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity
Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare I want Body Volume Conditioner Other Name: Conditioner Product Use: To condition and beautify hair after cleansing, or before or after other hair treatments. Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Certrimonium Chloride 112-02-7 <2.5 Behentrimonium Chloride 17301-53-0 <1.50 Cyclomethicone 69430-24-6 <2.50 Other ingredients to 100
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures
Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: White opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 0.95 – 1.00 Water Solubility: Completely soluble in water. pH: 3.00 – 4.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity
Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Section 1 - Identification
Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare Instant Body Volume Foam Other Name: Styling Product Product Use: To style the hair Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour : Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort.
Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Cocamidopropyl Betain 80438-79-1 <1% Certrimonium Chloride 112-02-7 <2% Other ingredients to 100% The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards : There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn.
Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715 , Protective Gloves: AS 2161 , Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337 , Occupational Protective Footwear: AS/NZS2210 . SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour : Clear liquid
Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 1.00 – 1.01 Water Solubility: Completely soluble in water. pH: 6.00 – 7.50 Viscosity: <500cps spindle 3, 12rpm @20c
Section 10 - Stability and Reactivity Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable
HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms: ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Section 1 - Identification
Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare I Want Volume Powder Other Name: Styling Product Product Use: To style the hair Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour : Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort.
Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Silica Silylate 112926-00-8 <40.00 Other ingredients to 100
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards : There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn.
Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715 , Protective Gloves: AS 2161 , Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337 , Occupational Protective Footwear: AS/NZS2210 . SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour : white powder
Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: N/A Water Solubility: N/A . pH: N/A Viscosity: N/A.
Section 10 - Stability and Reactivity Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable
HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms: ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare I want Body Volume Shampoo Other Name: Shampoo Product Use: To cleanse the hair Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Sodium Lauryl Sulphate 151-21-3 <10 Cocamido Propyl Betain 80438-79-1 <10 Other ingredients to 100 The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures
Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: White opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 1.01 – 1.03 Water Solubility: Completely soluble in water. pH: 5.50 – 6.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity
Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Material Safety Data Sheet
1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY / UNDERTAKING Product name Hair Shake
Catalog code
Use of the product Personal hair care product
Company Guangzhou Beaver Cosmetics Co., Ltd Add: No.5 Zhen Xing Rd., High-tech Industrial Park, Tai ping Development Zone, Cong Hua Dist., Guangzhou City, China Telephone Tel: 86-20-37940773; 37940775; 37940779; Fax: 86-20-37940773-7210; Email: [email protected]
Date 18/12/2015
2. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredients: WATER(AQUA,EAU), ALCOHOL DENAT, PEG-32, SILICA, PEG-8, PROPYLENE GLYCOL, DIAZOLIDINYL UREA, SODIUM LAURYL SULFATE, BENTONITE, SODIUM METHYL COCOYL TAURATE, MAGNESIUM ALUMINUM SILICATE, CITRIC ACID, AMINOMETHYL PROPANOL, PARFUM, COCODIMONIUM HYDROXYPROPYL HYDROLYZED KERATIN, HYDROLYZED KERATIN, HYDROLYZED WHEAT PROTEIN, HYDROLYZED CORN PROTEIN, HYDROLYZED SOY PROTEIN
3. HAZARDS IDENTIFICATION
Specific Hazards : Possible fire hazard by product vapors ignition (additional information is given under section 7)
Potential Health effects : Please refer to section 11.
4. FIRST AID MEASURES
Eye contact : Make sure to remove contact lenses from the eyes before rinsing. Flush eyes immediately with plenty of water while occasionally lifting and lowering eyelids, for at least 15 minutes. Seek medical attention from a specialist if irritation persists.
Inhalation : Remove to fresh air.
Ingestion : Never make an unconscious person vomit or drink fluids!
Rinse mouth thoroughly.
Seek medical advice and show the label when possible.
Skin Contact : Rinse skin with water and mild soap. Consult a physician if irritation persists.
5. FIRE-FIGHTING MEASURES
Flash Point : Not determined.
Autoignition Temperature : Not determined.
Flammability Limits in air : Not determined.
Extinguishing media : On large fires use dry chemical, foam or water
spray. On small fires use carbon dioxide (CO2) dry chemical or water spray. Water can be used to cool fire exposed containers.
Fire Fighting Measures : Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Use water spray to keep fire exposed containers cool. Determine the need to evacuate or isolate the area according to your local emergency plan.
Specific hazards : Fire or high temperatures may create carbon
oxides and traces of incompletely burned carbon compounds. Formaldehyde.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Wear proper protective equipment. Observe all personal
Protection equipment recommendations described in sections 8.
Environmental precautions : Prevent from spreading or entering into drains,
ditches or waterways by using sand, earth or other appropriate barriers.
Clean up methods : Determine the need to evacuate or isolate the area
according to your local emergency plan. Eliminate all possible sources of ignition. Very large spills should be contained by embanking, etc... procedures. Avoid sparks, flames, heat and smoking. Ventilate. Mop, wipe or soak up with absorbent material and place in appropriate container. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbent or cleaning materials appropriately, since spontaneous heating may occur.
Further information : The spilled product produces an extremely slippery
surface, take precautions.
7. HANDLING AND STORAGE
Handling : Use with adequate ventilation. Avoid eye contact. Avoid inhalation of vapors. Avoid all unnecessary exposure. Keep away from food, drink and animal dishes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking.
Storage : Keep only in the original glass bottles in a cool, well
ventilated dry area and protect from light. Keep containers tightly closed when not in use.
Precautions : Static electricity will accumulate and may ignite vapors.
Prevent a possible fire hazard by taking precautionary measures against static discharges. Keep container closed and away from heat, sparks and flame.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection Respiratory protection : In case of inadequate ventilation use suitable respirator.
Hand protection : No specific hand protection noted, but gloves may still be
advisable. Eye protection : Wear approved safety goggles.
Hygiene measures : Exercise good hygiene practice. Wash after handling, especially
before eating, drinking or smoking. When using, do not eat, drink
or smoke.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance - 5 - 67
.
Colour : 67
pH value at 25oC :
Solubility in water : yes
Specific gravity at 25oC : app. 0.95 0.05
10. STABILITY AND REACTIVITY
Stability : Stable under normal temperature conditions and recommended use.
Materials to avoid : Strong oxidizing substances.
Hazardous decomposition Products : Thermal breakdown of this product during fire or
very high heat conditions may evolve the following decomposition
products: Carbon oxides and traces of incompletely burned carbon compounds. Formaldehyde.
11. TOXICOLOGICAL INFORMATION
Potential Health effects
Inhalation : Inhalation is an unlikely route of exposure
under normal temperature conditions and recommended use. Accidental inhalation of the product spray, is unlikely to cause irritation of the nose and upper respiratory tract.
Skin contact : May cause skin irritation.
Repeated exposure to the product is unlikely to produce allergy by skin contact. Exposure to this product is unlikely to result in phototoxic effects.
Eye contact : Accidental exposure of the eye to the product
may result in eye irritation.
Ingestion : Accidental ingestion of the product may cause irritation to the mouth and upper digestive tract.
Toxicological tests : No data is available regarding the finished product.
Additional information : Toxicological assessment of the finished product is available and
will be sent upon request.
12. ECOLOGICAL INFORMATION
Environmental fate and distribution : Specific data regarding the finished product is not available.
Complete information regarding the product ingredients is not yet available.
Environmental effects : No data is available regarding the finished product.
Complete information regarding the product ingredients is not yet available.
Fate and effects in waste water Treatment plants : No data is available regarding the finished product.
Complete information regarding the product ingredients is not yet available.
13. DISPOSAL CONSIDERATIONS
Avoid releasing into the environment. Dispose of waste and residues in a safe manner, in accordance with local and national regulations.
14. TRANSPORT INFORMATION
General information
The product is not classified as dangerous goods for transport, according to the international regulation of the transport of dangerous goods (ADR/RID, IMDG and IATA-DGR)
Transportation by road or railway according to ADR and RID
Remarks : Not classified as dangerous goods according to ADR.
Transportation by vessels according to IMDG
Remarks : Not classified as dangerous goods according to IMDG.
Transportation by airplane according to IATA-DRG
Remarks : Not classified as dangerous goods according to IATA-DGR.
15. Regulatory information
Risk phrases :
NC
not classified.
Safety phrases :
S25 S51
Avoid contact with eyes. Use only in well-ventilated areas.
16. OTHER INFORMATION
Further information : None. This MSDS is intended to provide a brief summary of our knowledge and Guidance regarding the
use of this material. The information contained here has been compiled from sources considered to be
dependable and is accurate to the best of the company’s knowledge .It is not meant to be an all-inclusive document
on worldwide hazard communication regulations. This information is furnished upon condition that the
person receiving it shall make his own determination of the suitability of the material for his particular
purpose.
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare Blonde Shampoo Other Name: Shampoo Product Use: To cleanse the hair Creation Date: April 2016 This version issued: April 2016
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour : Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion:
Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Sodium Lauryl Sulphate 151-21-3 <10 Cocamido Propyl Betain 80438-79-1 <10 Other ingredients to 100 The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards : There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade.
Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715 , Protective Gloves: AS 2161 , Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337 , Occupational Protective Footwear: AS/NZS2210 . SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties:
Physical Description & colour : White opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 1.01 – 1.03 Water Solubility: Completely soluble in water. pH: 5.50 – 6.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable
PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms: ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare Keep me Blonde Treatment Other Name: Treatment Product Use: To condition and beautify hair after cleansing, or before or after other hair treatments. Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Certrimonium Chloride 112-02-7 <2.5 Behentrimonium Chloride 17301-53-0 <1.50 Isopropyl Myristate 110-27-0 <2.00 Other ingredients to 100
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures
Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: Purple opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 0.95 – 1.00 Water Solubility: Completely soluble in water. pH: 3.00 – 4.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity
Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare Keep My Curl Defining Cream Other Name: Styling Product Product Use: To condition and style the hair Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Certrimonium Chloride 112-02-7 <1.00 Cyclomethicone 69430-24-6 <10.00 Other ingredients to 100
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up,
wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: White opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 0.95 – 1.00 Water Solubility: Completely soluble in water. pH: 5.00 – 7.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms: ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Ozdare Business Services Chemwatch Hazard Alert Code: 4
ELEVEN MAKE ME SHINE SPRAY GLOSS
Chemwatch: 33-4543Version No: 2.1.1.1Safety Data Sheet according to WHS and ADG requirements
Issue Date: 01/01/2013Print Date: 07/06/2016
Initial Date: Not AvailableS.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name ELEVEN MAKE ME SHINE SPRAY GLOSS
Proper shipping name AEROSOLS
Other means ofidentification Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified usesSDS are intended for use in the workplace. For domestic-use products, refer to consumer labels.Application is by spray atomisation from a hand held aerosol packHair styling product.
Details of the supplier of the safety data sheet
Registered company name Ozdare Business Services
Address 7 Endeavour Way Sunshine West VIC 3020 Australia
Telephone +61 3 9314 9099
Fax +61 3 9314 9211
Website Not Available
Email Not Available
Emergency telephone number
Association / Organisation Not Available
Emergency telephonenumbers Not Available
Other emergency telephonenumbers Not Available
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGSMaxMin
Flammability 4 Toxicity 0Body Contact 2 Reactivity 1 Chronic 0
0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme
Poisons Schedule Not Applicable
Classification [1] Aerosols Category 1, Eye Irritation Category 2A
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD DANGER
Hazard statement(s)
Continued...
H222 Extremely flammable aerosol.
H319 Causes serious eye irritation.
AUH044 Risk of explosion if heated under confinement
Precautionary statement(s) Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) Response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
Precautionary statement(s) Storage
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Precautionary statement(s) DisposalNot Applicable
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
SubstancesSee section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
64-17-5 30-60
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If aerosols come in contact with the eyes: Immediately hold the eyelids apart and flush the eye continuously for at least 15 minutes with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact Wipe off excess with absorbent tissue or towel.Wash with soap and water.
Inhalation
If aerosols, fumes or combustion products are inhaled:Remove to fresh air. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag-valve mask device, orpocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor.
Ingestion Not considered a normal route of entry.
Indication of any immediate medical attention and special treatment neededTreat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing mediaSMALL FIRE:
Water spray, dry chemical or CO2 LARGE FIRE:
Water spray or fog.
Special hazards arising from the substrate or mixture
Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course.
ethanol
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If safe, switch off electrical equipment until vapour fire hazard removed. Use water delivered as a fine spray to control fire and cool adjacent area. DO NOT approach containers suspected to be hot.
Fire/Explosion Hazard
Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat or flame. Vapour forms an explosive mixture with air. Severe explosion hazard, in the form of vapour, when exposed to flame or spark. Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition with violent container rupture. Aerosol cans may explode on exposure to naked flames.
Other combustion products include:, carbon dioxide (CO2), other pyrolysis products typical of burning organic material
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Wear protective clothing, impervious gloves and safety glasses. Shut off all possible sources of ignition and increase ventilation. Wipe up. If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated. Undamaged cans should be gathered and stowed safely.
Major Spills
Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
None required when handling small quantities.OTHERWISE:
Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials.
Other information
Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can Store in original containers in approved flammable liquid storage area. DO NOT store in pits, depressions, basements or areas where vapours may be trapped. No smoking, naked lights, heat or ignition sources. Keep containers securely sealed. Contents under pressure. Store away from incompatible materials. Store in a cool, dry, well ventilated area.
Conditions for safe storage, including any incompatibilities
Suitable container Aerosol dispenser. Check that containers are clearly labelled.
Storage incompatibility Avoid storage with oxidisers
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
Australia Exposure Standards ethanol Ethyl alcohol 1880 mg/m3 / 1000 ppm Not Available Not Available Not Available
EMERGENCY LIMITS
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
ethanol Ethyl alcohol; (Ethanol) Not Available Not Available Not Available
Ingredient Original IDLH Revised IDLH
ethanol 15,000 ppm 3,300 [LEL] ppm
Exposure controls
Appropriate engineering None required when handling small quantities.
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controls
OTHERWISE:Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highlyeffective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and"removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must matchthe particular process and chemical or contaminant in use.Employers may need to use multiple types of controls to prevent employee overexposure.
Personal protection
Eye and face protection
No special equipment for minor exposure i.e. when handling small quantities.OTHERWISE:
Safety glasses with side shields.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing oflenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class ofchemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should bereadily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable.
Skin protection See Hand protection below
Hands/feet protection
No special equipment needed when handling small quantities. OTHERWISE: For potentially moderate exposures: Wear general protective gloves, eg. light weight rubber gloves. For potentially heavy exposures: Wear chemical protective gloves, eg. PVC. and safety footwear.
Body protection See Other protection below
Other protection
No special equipment needed when handling small quantities.OTHERWISE:
Overalls. Skin cleansing cream. Eyewash unit. Do not spray on hot surfaces.
Thermal hazards Not Available
Recommended material(s)GLOVE SELECTION INDEXGlove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: ELEVEN MAKE ME SHINE SPRAY GLOSS
Material CPI
BUTYL C
NATURAL RUBBER C
NATURAL+NEOPRENE C
NEOPRENE C
NITRILE C
NITRILE+PVC C
PE/EVAL/PE C
PVC C
* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of the glove, a finalselection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequent basis, factors such as"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwisebe unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
Respiratory protectionType AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSIZ88 or national equivalent)
Selection of the Class and Type of respirator will depend upon the level of breathing zonecontaminant and the chemical nature of the contaminant. Protection Factors (defined as theratio of contaminant outside and inside the mask) may also be important.
Requiredminimumprotection factor
Maximum gas/vapourconcentration present in airp.p.m. (by volume)
Half-faceRespirator
Full-FaceRespirator
up to 10 1000 AX-AUS /Class1
-
up to 50 1000 - AX-AUS /Class 1
up to 50 5000 Airline * -
up to 100 5000 - AX-2
up to 100 10000 - AX-3
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demandA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogencyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance 22aer Cloudy liquid spray with a perfumed odour; partly mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available Partition coefficientn-octanol / water Not Available
Odour threshold Not Available Auto-ignition temperature(°C) Not Available
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pH (as supplied) Not Available Decompositiontemperature Not Available
Melting point / freezingpoint (°C) Not Available Viscosity (cSt) Not Available
Initial boiling point andboiling range (°C) Not Available Molecular weight (g/mol) Not Applicable
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm ormN/m) Not Available
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Partly Miscible pH as a solution (1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability
Elevated temperatures. Presence of open flame. Product is considered stable. Hazardous polymerisation will not occur.
Possibility of hazardousreactions See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decompositionproducts See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Inhalation hazard is increased at higher temperatures.Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness,slowing of reflexes, fatigue and inco-ordination.WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
Ingestion Not normally a hazard due to physical form of product.Considered an unlikely route of entry in commercial/industrial environments Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin ContactNot considered an irritant through normal use.The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,scaling and thickening of the skin.
EyeSpray mist may produce discomfortThe material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produceconjunctivitis.
Chronic
Principal routes of exposure are by accidental skin and eye contact and by inhalation of vapours especially at higher temperatures.As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should beavoided by observing good occupational work practice.WARNING: Aerosol containers may present pressure related hazards.
ELEVEN MAKE ME SHINESPRAY GLOSS
TOXICITY IRRITATION
Not Available Not Available
ethanol
TOXICITY IRRITATION
Dermal (rabbit) LD50: 17100 mg/kg[1] Eye (rabbit): 500 mg SEVERE
Inhalation (rat) LC50: 64000 ppm/4h[2] Eye (rabbit):100mg/24hr-moderate
Oral (rat) LD50: >1187-2769 mg/kg[1] Skin (rabbit):20 mg/24hr-moderate
Skin (rabbit):400 mg (open)-mild
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified dataextracted from RTECS - Register of Toxic Effect of chemical Substances
ETHANOL The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,scaling and thickening of the skin.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
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Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification
Serious EyeDamage/Irritation STOT - Single Exposure
Respiratory or Skinsensitisation STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
Ingredient Endpoint Test Duration (hr) Species Value Source
ethanol EC50 24 Algae or other aquatic plants 0.0129024mg/L 4
ethanol EC50 48 Crustacea 2mg/L 4
ethanol LC50 96 Fish 42mg/L 4
ethanol NOEC 2016 Fish 0.000375mg/L 4
ethanol EC50 72 Algae or other aquatic plants 275mg/L 2
Legend:Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 -Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
ethanol LOW (Half-life = 2.17 days) LOW (Half-life = 5.08 days)
Bioaccumulative potential
Ingredient Bioaccumulation
ethanol LOW (LogKOW = -0.31)
Mobility in soil
Ingredient Mobility
ethanol HIGH (KOC = 1)
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packagingdisposal
Consult State Land Waste Management Authority for disposal. Discharge contents of damaged aerosol cans at an approved site. Allow small quantities to evaporate. DO NOT incinerate or puncture aerosol cans. Bury residues and emptied aerosol cans at an approved site.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (ADG)
UN number 1950
Packing group Not Applicable
UN proper shipping name AEROSOLS
Environmental hazard Not Applicable
Transport hazard class(es)Class 2.1
Subrisk Not Applicable
Special precautions for userSpecial provisions 63 190 277 327 344
Limited quantity 1000ml
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Air transport (ICAO-IATA / DGR)
UN number 1950
Packing group Not Applicable
UN proper shipping name Aerosols
Environmental hazard Not Applicable
Transport hazard class(es)
ICAO/IATA Class 2.1
ICAO / IATA Subrisk Not Applicable
ERG Code 10L
Special precautions for user
Special provisions A145A167A802; A1A145A167A802
Cargo Only Packing Instructions 203
Cargo Only Maximum Qty / Pack 150 kg
Passenger and Cargo Packing Instructions 203; Forbidden
Passenger and Cargo Maximum Qty / Pack 75 kg; Forbidden
Passenger and Cargo Limited Quantity Packing Instructions Y203; Forbidden
Passenger and Cargo Limited Maximum Qty / Pack 30 kg G; Forbidden
Sea transport (IMDG-Code / GGVSee)
UN number 1950
Packing group Not Applicable
UN proper shipping name AEROSOLS
Environmental hazard Not Applicable
Transport hazard class(es)IMDG Class 2.1
IMDG Subrisk Not Applicable
Special precautions for user
EMS Number F-D, S-U
Special provisions 63 190 277 327 344 959
Limited Quantities 1000ml
Transport in bulk according to Annex II of MARPOL and the IBC codeNot Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
ETHANOL(64-17-5) IS FOUND ON THE FOLLOWING REGULATORY LISTSAustralia Exposure StandardsAustralia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
National Inventory Status
Australia - AICS Y
Canada - DSL Y
Canada - NDSL N (ethanol)
China - IECSC Y
Europe - EINEC / ELINCS /NLP Y
Japan - ENCS Y
Korea - KECI Y
New Zealand - NZIoC Y
Philippines - PICCS Y
USA - TSCA Y
Legend: Y = All ingredients are on the inventoryN = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
SECTION 16 OTHER INFORMATION
Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee usingavailable literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
Chemwatch: 33-4543Version No: 2.1.1.1
Page 7 of 8
ELEVEN MAKE ME SHINE SPRAY GLOSS
Issue Date: 01/01/2013Print Date: 07/06/2016
Continued...
settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
Definitions and abbreviationsPC䠉TWA: Permissible Concentration-Time Weighted AveragePC䠉STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit䚹IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index
This document is copyright.Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH.TEL (+61 3) 9572 4700.
Chemwatch: 33-4543Version No: 2.1.1.1
Page 8 of 8
ELEVEN MAKE ME SHINE SPRAY GLOSS
Issue Date: 01/01/2013Print Date: 07/06/2016
end of SDS
Page 1 of 6 Quality manufacturers of bath & body care products – made in Australia
SAFETY DATA SHEET
According to Regulation (EC) no. 1907/2006 SECTION 1: Identification of the substance/mixture & of the Company/ Undertaking of the substance/mixture and of the
company/undertaking 1.1 Product Name: Eleven Matte Texture Styling Paste 1.2 Application of the substance/mixture: Hair styling product. For external use only. 1.3 Details of the Manufacturer / Distributor:
Natural Beauty Care Pty Ltd 8 Teton Court, Highett, Victoria 3190, Australia.
Eleven Australia Pty Ltd 7 Endeavour Way, Sunshine West, Victoria 3020, Australia.
1.4 Emergency telephone number: +61 3 9553 0733 Facsimile Number: +61 3 9553 4988 1.5 POISON INFORMATION CENTRE: 13 11 26 (Australia)
SECTION 2: Hazard Identification
Not classified as Dangerous goods by the criteria of the Australian Dangerous goods code (ADG) for Transport and Rail. NON-DANGEROUS GOODS.
This material is a personal care product that is safe for consumers with intended and foreseeable use. This product is non- hazardous according to Work Safe Australia.
Classification of the substance or mixture (Classification according to Regulation (EC) No 1272/2008): Nil Classification according to the Directive 67/548/EEC or Directive 1999/45/EC: Not regulated
Signal word: Not relevant
Hazard statements:
Not relevant
Precautionary statements:
P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P103 Read label before use
Page 2 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 3: Composition/formulation on ingredients
SECTION 4: First Aid Measures
4.1 Description of first aid measures
General information: No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Name of Chemical CAS Number Percentage w/w
Water (Aqua) 7732-18-5 < 50-60 Cetearyl Alcohol 67762-27-0 < 10 Lanolin Cera 68201-49-0 < 10 Beeswax (Cera Alba) 8012-89-3 < 10 Stearyl Stearate 2778-96-3 < 10 Glycerin 56-81-5 < 5 Propylene Glycol 57-55-6 < 5 PEG-8 Beeswax - < 5 Oleth-30 9004-98-2 < 5 Oleth-5 9004-98-2 < 5 Microcrystalline Wax (Cera Microcrystallina) 63231-60-7 < 5 PVP 9003-39-8 < 5 Octyldodecanol 5333-42-6 < 1 Ricinus Communis (Castor) Seed Oil 8001-79-4 < 1 Dimethicone 9006-65-9 < 1 Phenoxyethanol 122-99-6 < 1 Benzyl Alcohol 100-51-6 < 1
Acrylates/C10-30 Alkyl Acrylate Crosspolymer -
< 0.5 Fragrance (Parfum) - < 0.5 Triethanolamine 102-71-6 < 0.5 Yellow 5 (CI 19140) 12225-21-7 < 0.5 Caramel 8028-89-5 < 0.5
HEALTH EFFECTS: Acute - Swallowed May be harmful if large amounts are swallowed Acute - Eye Full strength material may be irritating to eyes Acute - Skin Not considered an irritant through normal use. Full strength material in repeated
or prolonged contact with skin may be irritating and cause allergic reactions in sensitive individuals
Acute - Inhaled Full strength material should not cause any irritation to the mucous membrane and upper airways
Page 3 of 6 Quality manufacturers of bath & body care products – made in Australia
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting Measures
5.1 Suitable Extinguishing media: Carbon dioxide, Foam, Dry Chemical
5.2 Special hazards arising from the substance or mixture:
No further relevant information available.
5.3 Advice for firefighters:
Wear Protective equipment. Do not inhale explosion gases or combustion gases. Hazchem Code: Not applicable.
SECTION 6: Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures: Remove all sources of ignition. Increase ventilation. Evacuate all personnel. Wear sufficient respiratory protection and full protective clothing to minimise skin and eye exposure. If possible contain the spill.
6.2 Environmental precautions: No special measures required.
6.3 Methods and material for containment and cleaning up: Slippery when spilt. Clean up immediately. Wear protective
equipment to avoid eye contact. Contain – prevent run off into drains and waterways. Use absorbent material. Collect and
seal on properly labelled containers for disposal. If large quantities of this material enter the waterways, contact the
Environmental Protection Authority or you local Waste Management Authority.
6.4 Reference to other sections: See Section 7 for information on safe handling.
SECTION 7: Handling & Storage
7.1 Precautions for safe handling
None required when handling small quantities. Avoid contact with eyes. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing.
FIRST AID: Swallowed Do not induce vomiting, Give plenty of water and seek medical advice Eye Flush eye with copious amounts of water for 15 minutes including under eyelid. If
discomfit persists, obtain medical advice. Skin Remove contaminated clothing. Wash affected areas with warm soapy water
Inhaled Remove to fresh uncontaminated air, lay patient on back until breathing returns to normal
Page 4 of 6 Quality manufacturers of bath & body care products – made in Australia
Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities: Store below 30C if in original containers. Store in a cool dry well ventilated area. Store away from Incompatible materials. 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure Controls /Personal Protection:
Additional information about design of technical facilities: No further data; see item 7.
8.1 Control parameters: No value assigned for this specific material
8.2 Appropriate engineering controls:
Non-required 8.3 Personal Protection:
None required when handling small quantities. Avoid contact with eyes. Do not ingest. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing. Some sensitive individuals may develop an allergic response.
National Exposure Standards: No exposure standards have been established for this material by Work Safe Australia. Biological Limit Values: No biological limit allowed.
SECTION 9: Physical & Chemical Properties
Appearance: Thick Waxy Balm Colour: White/ Off White Odour: Vanilla Odour threshold: Not determined.
pH: 6.0-6.5 Flash point: Not available
Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined.
Danger of explosion: Product does not present an explosion hazard. Self-igniting: Product is not self - igniting.
Solubility in / Miscibility with water: Soluble. Density at 20 °C: 0.90-1.04 g/cm³
Vapour density Not applicable. Vapour pressure: Not applicable.
SECTION 10: Stability & Reactivity
10.1 Reactivity: No further relevant information available.
10.2 Chemical stability: Stable under normal handling and storage conditions.
Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials: No further relevant information available.
10.6 Hazardous decomposition products: None under normal conditions of storage and use.
Page 5 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 11: Toxicology Information
11.1 Information on toxicological effects:
No adverse health effects expected if the product is handled in accordance with this safety data sheet and the product label. Product is safe for its intended use based on the formulation, testing results and the history of safe consumer use.
Acute toxicity: No LD50 data available for this product
Primary irritant effect:
On the skin: No irritant effect On the eye: No irritating effect Carcinogen Classification: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed carcinogen by IARC
SECTION 12: Ecological Information
12.1 Ecotoxicity: Avoid contaminating waterways 12.2 Persistence/degradability: No tested data available on this product. 12.3 Bioaccumulative potential: This product shows a low bioaccumulation potential 12.4 Mobility: Prevent contamination of soil, ground and surface water.
Section 13: Disposals Consideration
Disposal Methods:
Refer to Waste Management Authority. Dispose of contents/containers in accordance with local/regional/national/international regulations.
SECTION 14: Transport Information
ADG 7.3 Land Transport of Dangerous Goods
Labels required: No special requirements
UN Number: N/A
Proper Shipping Name: N/A
DG Class: N/A
Subsidiary Risk: None
Packing Group: N/A
HAZCHEM Code: N/A
Special Provision: N/A
Page 6 of 6 Quality manufacturers of bath & body care products – made in Australia
MARITIME TRANSPORTATION AIR TRANSPORTATION
IMCD IATA Dangerous Goods Regulations (DGR) 56th
Edition 2015
IMCD: N/A ICAO/IATA Class: N/A
Label: N/A Label: N/A
UN Number: N/A UN Number: N/A
Packaging Group: Not allocated Packaging Group: N/A
EMS Number: N/A
Marine Pollutant: Not allocated
Proper Shipping Name: As above Proper Shipping Name: As above Special Provisions; N/A Special Provisions; N/A
SECTION 15: Regulatory Information
POISONS SCHEDULE (SUSMP):
Not subject to labelling
AICS:
All ingredients in this product are compliant with NICNAS regulations
SECTION 16: OTHER INFORMATION
The information herein is accurate to the best of our knowledge. However, it is meant to describe safety requirements of our
products, thus this shall not constitute a guarantee for any specific product features and shall not establish a legally valid
contractual relationship. No warranty is expressed or made as to this document’s accuracy, reliability or completeness. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated.
Relevant phrases
Non relevant Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
AICS: Australian Inventory of Chemical substances
NICNAS: National Industrial Chemical Notification & Assessment Scheme
IARC: International Agency for Research Cancer
MSDS prepared by: Natural Beauty Care Pty. Ltd. Issue Date: 14/06/2016 Revision Number: 1
END OF MSDS
Page 1 of 6 Quality manufacturers of bath & body care products – made in Australia
SAFETY DATA SHEET
According to Regulation (EC) no. 1907/2006 SECTION 1: Identification of the substance/mixture & of the Company/ Undertaking of the substance/mixture and of the
company/undertaking 1.1 Product Name: Eleven Medium Hold Styling Paste 1.2 Application of the substance/mixture: Hair styling product. For external use only. 1.3 Details of the Manufacturer / Distributor:
Natural Beauty Care Pty Ltd 8 Teton Court, Highett, Victoria 3190, Australia.
Eleven Australia Pty Ltd 7 Endeavour Way, Sunshine West, Victoria 3020, Australia.
1.4 Emergency telephone number: +61 3 9553 0733 Facsimile Number: +61 3 9553 4988 1.5 POISON INFORMATION CENTRE: 13 11 26 (Australia)
SECTION 2: Hazard Identification
Not classified as Dangerous goods by the criteria of the Australian Dangerous goods code (ADG) for Transport and Rail. NON-DANGEROUS GOODS.
This material is a personal care product that is safe for consumers with intended and foreseeable use. This product is non- hazardous according to Work Safe Australia.
Classification of the substance or mixture (Classification according to Regulation (EC) No 1272/2008): Nil Classification according to the Directive 67/548/EEC or Directive 1999/45/EC: Not regulated
Signal word: Not relevant
Hazard statements:
Not relevant Precautionary statements:
P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P103 Read label before use
Page 2 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 3: Composition/formulation on ingredients
SECTION 4: First Aid Measures
4.1 Description of first aid measures
General information: No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Name of Chemical CAS Number Percentage w/w
Water (Aqua) 7732-18-5 >60 Lanolin Cera 68201-49-0 < 20 Oleth-30 9004-98-2 < 10 Cetearyl Alcohol 67762-27-0 < 5 Petrolatum 8009-03-8 < 5 PVP 9003-39-8 < 5 PEG-7 Glyceryl Cocoate 68553-03-7 < 5 Copernicia Cerifera (Carnauba) Wax 8015-86-9 < 5 VP/VA Copolymer 25086-89-9 < 1 Mineral Oil (Paraffinum Liquidum) 8042-47-5 < 1 Benzyl Alcohol 100-51-6 < 1 Phenoxyethanol 122-99-6 < 1 Dehydroacetic Acid 520-45-6 < 0.5 Ethylhexylglycerin 70445-33-9 < 0.5 Fragrance (Parfum) - < 0.5 Acrylates/C10-30 Alkyl Acrylate Crosspolymer - < 0.5 Triethanolamine 102-71-6 < 0.5
HEALTH EFFECTS: Acute - Swallowed May be harmful if large amounts are swallowed Acute - Eye Full strength material may be irritating to eyes Acute - Skin Not considered an irritant through normal use. Full strength material in repeated
or prolonged contact with skin may be irritating and cause allergic reactions in sensitive individuals
Acute - Inhaled Full strength material should not cause any irritation to the mucous membrane and upper airways
Page 3 of 6 Quality manufacturers of bath & body care products – made in Australia
4.2 Most important symptoms and effects, both acute and delayed: No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed: No further relevant information available.
SECTION 5: Firefighting Measures
5.1 Suitable Extinguishing media: Carbon dioxide, Foam, Dry Chemical 5.2 Special hazards arising from the substance or mixture: No further relevant information available. 5.3 Advice for firefighters: Wear Protective equipment. Do not inhale explosion gases or combustion gases.
Hazchem Code: Not applicable.
SECTION 6: Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures: Remove all sources of ignition. Increase ventilation. Evacuate all personnel. Wear sufficient respiratory protection and full protective clothing to minimise skin and eye exposure. If possible contain the spill. 6.2 Environmental precautions: No special measures required. 6.3 Methods and material for containment and cleaning up: Slippery when spilt. Clean up immediately. Wear protective equipment to avoid eye contact. Contain – prevent run off into drains and waterways. Use absorbent material. Collect and seal on properly labelled containers for disposal. If large quantities of this material enter the waterways, contact the Environmental Protection Authority or you local Waste Management Authority. 6.4 Reference to other sections: See Section 7 for information on safe handling.
SECTION 7: Handling & Storage
7.1 Precautions for safe handling
None required when handling small quantities. Avoid contact with eyes. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing.
Information about fire - and explosion protection: No special measures required.
FIRST AID: Swallowed Do not induce vomiting, Give plenty of water and seek medical advice Eye Flush eye with copious amounts of water for 15 minutes including under eyelid. If
discomfit persists, obtain medical advice. Skin Remove contaminated clothing. Wash affected areas with warm soapy water
Inhaled Remove to fresh uncontaminated air, lay patient on back until breathing returns to normal
Page 4 of 6 Quality manufacturers of bath & body care products – made in Australia
7.2 Conditions for safe storage, including any incompatibilities: Store below 30°C if in original containers. Store in a cool dry well ventilated area. Store away from incompatible materials.
7.3 Specific end use(s): No further relevant information available.
SECTION 8: Exposure Controls /Personal Protection:
Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters: No value assigned for this specific material.
8.2 Appropriate engineering controls: Not required. 8.3 Personal Protection: None required when handling small quantities. Avoid contact with eyes. Do not ingest. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing. Some sensitive individuals may develop an allergic response.
National Exposure Standards: No exposure standards have been established for this material by Work Safe Australia. Biological Limit Values: No biological limit allowed.
SECTION 9: Physical & Chemical Properties
Appearance: Thick Waxy Balm Colour: Off White/ Yellow tinge Odour: Toasted Coconut Odour threshold: Not determined. pH: 6.0 – 6.5 Flash point: Not available. Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined. Danger of explosion: Product does not present an explosion hazard. Self-igniting: Product is not self - igniting. Solubility in / Miscibility with water: Soluble. Density at 20 °C: 0.90 – 1.04 g/cm³ Vapour density: Not applicable. Vapour pressure: Not applicable.
SECTION 10: Stability & Reactivity
10.1 Reactivity: No further relevant information available. 10.2 Chemical stability: Stable under normal handling and storage conditions.
Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions: No dangerous reactions known. 10.4 Conditions to avoid: No further relevant information available. 10.5 Incompatible materials: No further relevant information available. 10.6 Hazardous decomposition products: None under normal conditions of storage and use.
SECTION 11: Toxicology Information
11.1 Information on toxicological effects:
No adverse health effects expected if the product is handled in accordance with this safety data sheet and the product label. Product is safe for its intended use based on the formulation, testing results and the history of safe consumer use. Acute toxicity: No LD50 data available for this product.
Page 5 of 6 Quality manufacturers of bath & body care products – made in Australia
Primary irritant effect:
On the skin: No irritant effect. On the eye: No irritating effect. Carcinogen Classification: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed carcinogen by IARC.
SECTION 12: Ecological Information
12.1 Ecotoxicity: Avoid contaminating waterways. 12.2 Persistence/degradability: No tested data available on this product. 12.3 Bioaccumulative potential: This product shows a low bioaccumulation potential. 12.4 Mobility: Prevent contamination of soil, ground and surface water.
Section 13: Disposals Consideration
Disposal Methods:
Refer to Waste Management Authority. Dispose of contents/containers in accordance with local/regional/national/international regulations.
SECTION 14: Transport Information
ADG 7.3 Land Transport of Dangerous Goods
Labels required: No special requirements
UN Number: N/A
Proper Shipping Name: N/A
DG Class: N/A
Subsidiary Risk: None
Packing Group: N/A
HAZCHEM Code: N/A
Special Provision: N/A
MARITIME TRANSPORTATION AIR TRANSPORTATION
IMCD IATA Dangerous Goods Regulations (DGR) 56th
Edition 2015
IMCD: N/A ICAO/IATA Class: N/A
Label: N/A Label: N/A
UN Number: N/A UN Number: N/A
Packaging Group: Not allocated Packaging Group: N/A
EMS Number: N/A
Marine Pollutant: Not allocated
Proper Shipping Name: As above Proper Shipping Name: As above Special Provisions; N/A Special Provisions; N/A
Page 6 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 15: Regulatory Information
POISONS SCHEDULE (SUSMP):
Not subject to labelling
AICS:
All ingredients in this product are compliant with NICNAS regulations
SECTION 16: OTHER INFORMATION
The information herein is accurate to the best of our knowledge. However, it is meant to describe safety requirements of our products, thus this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. No warranty is expressed or made as to this document’s accuracy, reliability or completeness. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated. Relevant phrases:
Not relevant. Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) AICS: Australian Inventory of Chemical substances NICNAS: National Industrial Chemical Notification & Assessment Scheme IARC: International Agency for Research Cancer
MSDS prepared by: Natural Beauty Care Pty. Ltd. Issue Date: 13/10/2016 Revision Number: 2
END OF MSDS
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare Eleven Miracle Treatment Other Name: Treatment Product Use: To condition and beautify hair after cleansing, or before or after other hair treatments. Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Behentrimonium Chloride 17301-53-0 <1.50 Cyclomethicone 69430-24-6 <2.50 Isopropyl Myristate 110-27-0 <2.00 Other ingredients to 100
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures
Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: white opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 0.95 – 1.00 Water Solubility: Completely soluble in water. pH: 3.00 – 4.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity
Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of salt and other minor ingredients. Trade Name: Ozdare Sea Salt Spray Other Name: Styling Product Product Use: To style the hair Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Clear liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Alcohol 64-17-5 <4.50 Other ingredients to 100 The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up,
wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: White opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 1.035 – 1.040 Water Solubility: Completely soluble in water. pH: 6.00 – 7.00 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms: ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC
CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Section 1 - Identification Company Name: Eleven Australia Pty Ltd
7 Endeavour Way
Sunshine West VIC 3020
Manufacture: RAUXEL PTY LTD
40 Beaumont Rd
Mt Kuring-Gai 2080
Phone: (02) 9457 9330
Fax: (02) 9457 9391
Chemical nature: Silicone based product. Trade Name: Ozdare Shine Serum Other Name: Hair Styling Products Product Use: Styling Product Creation Date: May, 2015 This version issued: May, 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure to some products may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids, waxes and pastes of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Repeated exposure to some products may cause skin dryness or cracking. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion:
Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)
Cyclomethicone 69430-24-6 <90.00 not set not set
Dimethiconol 31692-79-2 <2.00 not set not set
Other ingredients to 100
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn.
Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: Clear Liquid Odour: coconut fragrance Freezing/Melting Point: Approximately 0°C. Specific Gravity: 0.95-0.99 Water Solubility: Not soluble in water.
Section 10 - Stability and Reactivity Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable
DANGEROUS GOODS CLASS: Not Applicable
SUBSIDIARY RISK: Not Applicable
PACKAGING GROUP No: Not Applicable
HAZCHEM CODE: Not Applicable
POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous
Finished packages product by vessel (IMDG); Non Hazardous
Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms: ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Page 1/6SAFETY DATA SHEETAccording to Safe Work Australia
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1 . IDENTIFICATION: PRODUCT IDENTIFIER AND CHEMICAL IDENTITYProduct Name: SLICK HOLD POMADEOther Means of Identification: Mixture
Recommended Use of the Chemical and Restriction on Use: Hair styling product
Details of Manufacturer or Importer:Health Focus Manufacturers6 Huntington StreetClontarf QLD 4019
Phone Number: +61 7 3883 1355
Emergency telephone number: +61 438 756 977
2 . HAZARDS IDENTIFICATIONHazardous Nature:Not classified as Hazardous according to the Globally Harmonised System of Classification and Labelling ofChemicals (GHS) and Safe Work Australia criteria.Not classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods byRoad and Rail. (7th edition)
environment
Aquatic Acute 1 H400 Very toxic to aquatic life.Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.
Signal Word Warning
Hazard StatementsH410 Very toxic to aquatic life with long lasting effects.
Precautionary StatementsP273 Avoid release to the environment.P391 Collect spillage.P501 Dispose of contents/container in accordance with local/regional/national regulations.
3 . COMPOSITION AND INFORMATION ON INGREDIENTSChemical Characterization: MixturesDescription: Mixture of substances listed below with nonhazardous additions.Hazardous Components:56-81-5 1,2,3-Propanetriol 5%57-55-6 1,2-Propanediol 5%
4 . FIRST AID MEASURESInhalation: If inhaled, remove to fresh air. Seek medical attention if breathing problems develop.
Skin Contact:In case of skin irritation wash affected areas with water and soap and discontinue use. Seek medical attention ifsymptoms persist.
(Contd. on page 2)
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Product Name: SLICK HOLD POMADE
(Contd. of page 1)
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Eye Contact:In case of eye irritation, hold eyelids open and rinse with water. Seek medical attention if symptoms persist.
Ingestion:If swallowed, do not induce vomiting. Rinse mouth with water. Never give anything by mouth to an unconsciousperson. Seek medical attention if large amounts are ingested.
Symptoms Caused by Exposure:Eye Contact: May cause slight eye irritation.Ingestion: May cause gastrointestinal irritation.
5 . FIRE FIGHTING MEASURESSuitable Extinguishing Media: Water spray or fog, foam, dry chemical powder or carbon dioxide.
Specific Hazards Arising from the Chemical:Hazardous combustion products include oxides of carbon and nitrogen.Product is not flammable.
Special Protective Equipment and Precautions for Fire Fighters:When fighting a major fire wear self-contained breathing apparatus and protective equipment.
6 . ACCIDENTAL RELEASE MEASURESPersonal Precautions, Protective Equipment and Emergency Procedures:Wear appropriate protective clothing. Ensure adequate ventilation.
Environmental Precautions: In the event of a major spill, prevent spillage from entering drains or water courses.
Methods and Materials for Containment and Cleaning Up:Scoop up spill and place in suitable container for subsequent disposal. Provide adequate ventilation. Spilt productmay be slippery. Clean the spill area with water.
7 . HANDLING AND STORAGEPrecautions for Safe Handling:Use of safe work practices are recommended to avoid eye contact and inhalation of product.Food, beverages and tobacco products should not be stored or consumed where this material is in use.
Conditions for Safe Storage:Store in a cool, dry and well ventilated area. Keep in original container tightly closed when not in use.
8 . EXPOSURE CONTROLS AND PERSONAL PROTECTIONExposure Standards:56-81-5 1,2,3-PropanetriolNES TWA: 10 mg/m³57-55-6 1,2-PropanediolNES TWA: 474* 10** mg/m³, 150* ppm
*vapour&particluates;**particulates only
Engineering Controls:Maintain air concentration below occupational exposure standards, providing adequate ventilation.
(Contd. on page 3)
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Product Name: SLICK HOLD POMADE
(Contd. of page 2)
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Respiratory Protection: Respiratory protection is not required under normal use conditions.
Skin Protection: Skin protection is not required under normal use conditions.
Eye and Face Protection: Eye protection is not required under normal use conditions.
9 . PHYSICAL AND CHEMICAL PROPERTIESAppearance:
Form: Waxy solidColour: YellowOdour: Fragrant odour
Odour Threshold: No information availablepH-Value: No information availableMelting point/Melting range: No information availableInitial Boiling Point/Boiling Range: <100 °CFlash Point: Not applicableFlammability: Product is not flammable.Auto-ignition Temperature: No information availableDecomposition Temperature: No information availableExplosion Limits:
Lower: Not applicableUpper: Not applicable
Vapour Pressure: No information availableRelative Density at 20 °C: 1.0Vapour Density: No information availableEvaporation Rate: No information availableSolubility in Water: SolublePartition Coefficient (n-octanol/water): No information available
10 . STABILITY AND REACTIVITYPossibility of Hazardous Reactions: Hazardous polymerisation will not occur.
Chemical Stability: Stable at ambient temperature and under normal conditions of use.
Conditions to Avoid: No further relevant information available.
Incompatible Materials: No further relevant information available.
Hazardous Decomposition Products: Oxides of carbon and nitrogen.
11 . TOXICOLOGICAL INFORMATIONToxicity:LD₅₀/LC₅₀ Values Relevant for Classification:56-81-5 1,2,3-PropanetriolOral LD₅₀ 12600 mg/kg (rat)57-55-6 1,2-PropanediolOral LD₅₀ 2000 mg/kg (rat)Dermal LD₅₀ 20800 mg/kg (rabbit)
(Contd. on page 4)
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Product Name: SLICK HOLD POMADE
(Contd. of page 3)
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122-99-6 2-PhenoxyethanolOral LD₅₀ 1260 mg/kg (rat)Dermal LD₅₀ 5000 mg/kg (rabbit)55406-53-6 3-Iodo-2-propynylbutylcarbamateOral LD₅₀ 1470 mg/kg (rat)Dermal LD₅₀ >2000 mg/kg (rat)Inhalation LC₅₀/4 h >6.89 mg/l (rat)2783-94-0 disodium 6-hydroxy-5-[(4-sulphonatophenyl)azo]naphthalene-2-sulphonateOral LD₅₀ >10000 mg/kg (rat)
Acute Health EffectsInhalation: No adverse health effects expected.Skin: No adverse health effects expected.Eye: May cause slight eye irritation.Ingestion: May cause gastrointestinal irritation.
Skin Corrosion / Irritation: Based on classification principles, the classification criteria are not met.
Serious Eye Damage / Irritation: Based on classification principles, the classification criteria are not met.
Respiratory or Skin Sensitisation: Based on classification principles, the classification criteria are not met.
Germ Cell Mutagenicity: Based on classification principles, the classification criteria are not met.
Carcinogenicity:Polyvinyl pyrrolidone and Sunset Yellow FCF are classified by IARC as Group 3 - Not classifiable as to itscarcinogenicity to humans.
Reproductive Toxicity: Based on classification principles, the classification criteria are not met.
Specific Target Organ Toxicity (STOT) - Single Exposure:Based on classification principles, the classification criteria are not met.
Specific Target Organ Toxicity (STOT) - Repeated Exposure:Based on classification principles, the classification criteria are not met.
Aspiration Hazard: Based on classification principles, the classification criteria are not met.
Chronic Health Effects: No information available
Existing Conditions Aggravated by Exposure: No information available
Additional toxicological information: No information available
12 . ECOLOGICAL INFORMATIONEcotoxicity: No information available
Aquatic toxicity: Very toxic to aquatic life with long lasting effects.
Persistence and Degradability: No information available
Bioaccumulative Potential: No information available
Mobility in Soil: No information available(Contd. on page 5)
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(Contd. of page 4)
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Other adverse effects: No information available
13 . DISPOSAL CONSIDERATIONSDisposal Methods and Containers: Dispose according to applicable local and state government regulations.
Special Precautions for Landfill or Incineration:Please consult your state Land Waste Management Authority for more information.
14 . TRANSPORT INFORMATIONUN NumberADG Not regulatedIMDG, IATA UN3077
Proper Shipping NameADG Not regulatedIMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Alcohols, C16-18,
ethoxylated, Glycols, 1.2-, C12-16, ethoxylated propoxylated), MARINE POLLUTANTIATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Alcohols, C16-18,
ethoxylated, Glycols, 1.2-, C12-16, ethoxylated propoxylated)
Dangerous Goods ClassADG Class: Not regulatedIMDG Class: 9 Miscellaneous dangerous substances and articles.
Packing Group:ADG Not regulatedIMDG, IATA III
Marine pollutant: YesSymbol (fish and tree)
EMS Number: F-A,S-F
Hazchem Code: 2Z
Limited Quantities: 5 kg
15 . REGULATORY INFORMATIONAustralian Inventory of Chemical Substances:56-81-5 1,2,3-Propanetriol57-55-6 1,2-Propanediol
Standard for the Uniform Scheduling of Drugs and Poisons (SUSMP) - Poison Schedule:Poisons Schedule: 5
16 . OTHER INFORMATIONDate of Preparation or Last Revision: 14.07.2016
Prepared by: MSDS.COM.AU Pty Ltd www.msds.com.au
Abbreviations and acronyms:ADG: Australian Dangerous GoodsIMDG: International Maritime Code for Dangerous Goods
(Contd. on page 6)
Page 6/6SAFETY DATA SHEETAccording to Safe Work Australia
Printing date 14.07.2016 Revision: 14.07.2016
Product Name: SLICK HOLD POMADE
(Contd. of page 5)
42.0
IATA: International Air Transport AssociationGHS: Globally Harmonised System of Classification and Labelling of ChemicalsCAS: Chemical Abstracts Service (division of the American Chemical Society)LC₅₀: Lethal concentration, 50 percentLD₅₀: Lethal dose, 50 percentIARC: International Agency for Research on CancerSTEL: Short Term Exposure LimitTWA: Time Weighted AverageNES: National Exposure Standard (Safe Work Australia - Workplace Exposure Standards For Airborne Contaminants)Aquatic Acute 1: Hazardous to the aquatic environment, short-term (Acute). Category 1Aquatic Chronic 1: Hazardous to the aquatic environment, long-term (Chronic). Category 1
DisclaimerThis SDS is prepared in accord with the Safe Work Australia document “Code of Practice for the Preparation ofSafety Data Sheets for Hazardous Chemicals - December 2011”The information contained in this safety data sheet is provided in good faith and is believed to be accurate at thedate of issuance. Health Focus Manufacturers makes no representation of the accuracy or comprehensiveness ofthe information and to the full extent allowed by law excludes all liability for any loss or damage related to thesupply or use of the information in this material safety data sheet. MSDS.COM.AU Pty Ltd is not in a position towarrant the accuracy of the data herein. The user is cautioned to make their own determinations as to thesuitability of the information provided to the particular circumstances in which the product is used.
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare Smooth Me Now Antifrizz Conditioner Other Name: Conditioner Product Use: To condition and beautify hair after cleansing, or before or after other hair treatments. Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Certrimonium Chloride 112-02-7 <2.5 Behentrimonium Chloride 17301-53-0 <1.50 Cyclomethicone 69430-24-6 <2.50 Other ingredients to 100
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures
Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: White opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 0.95 – 1.00 Water Solubility: Completely soluble in water. pH: 3.00 – 4.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity
Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Section 1 - Identification Company Name: Eleven Australia Pty Ltd 7 Endeavour Way
Sunshine West VIC 3020 Manufacture: RAUXEL PTY LTD
40 Beaumont Rd Mt Kuring-Gai 2080 Phone: (02) 9457 9330 Fax: (02) 9457 9391 Chemical nature: Water solution of surfactants and other minor ingredients. Trade Name: Ozdare Smooth Me Now Antifrizz Shampoo Other Name: Shampoo Product Use: To cleanse the hair Creation Date: September 2015 This version issued: September 2015
Section 2 - Hazards Identification Statement of Hazardous Nature These products are classified as: Not classified as hazardous according to the criteria of SWA. Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R66. Repeated exposure may cause skin dryness or cracking. Safety Phrases: S24/25. Avoid contact with skin and eyes. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
Emergency Overview Physical Description & Colour: Viscous liquids of various colours and degrees of opacity. Odour: Various fragrances. Major Health Hazards: no significant risk factors have been found for these products.
Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that these products are not harmful. In addition product is unlikely to cause any discomfort or irritation. Skin Contact: Short Term Exposure: Available data indicates that these products are not harmful. It should present no hazards or discomfort in normal use. Eye Contact: Short Term Exposure: These products are believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3) Sodium Lauryl Sulphate 151-21-3 <10 Cocamido Propyl Betain 80438-79-1 <10 Other ingredients to 100 The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until product is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of these products are involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures
Accidental release: Absorb onto suitable absorbent material like vermiculite, sand or kitty litter. Sweep up and shovel or collect recoverable product, and dispose of promptly. After sweeping up, wash area with water. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. Storage: Store in a cool, well ventilated area, out of direct sunlight. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. SWA Exposure Limits TWA (mg/m3) STEL (mg/m3) Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. The use of exhaust fans is strongly recommended. Eye Protection: Eye protection is recommended when these products are being used. You are strongly encouraged to wear protective glasses or goggles. Skin Protection: We suggest that routine unprotected and long term contact with these products should be avoided and that suitable gloves should be worn during use. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product.
Section 9 - Physical and Chemical Properties: Physical Description & colour: White opaque liquid Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Specific Gravity: 1.01 – 1.03 Water Solubility: Completely soluble in water. pH: 5.50 – 6.50 Viscosity: Varies from product to product.
Section 10 - Stability and Reactivity
Reactivity: These products are unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulphur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information Local Effects: Target Organs: none known Classification of Hazardous Ingredients Ingredient Risk Phrases No ingredient mentioned in the HSIS Database is present in these products at hazardous concentrations.
Section 12 - Ecological Information This product range is biodegradable. It is not likely to accumulate in the soil or water or cause long term problems.
Section 13 - Disposal Considerations Disposal: Small quantities as used in a salon may safely be flushed down the sink. However, if you have old or redundant stock, call your local council, or your supplier for disposal advice.
Section 14 - Transport Information
UN NUMBER: Not Applicable DANGEROUS GOODS CLASS: Not Applicable SUBSIDIARY RISK: Not Applicable PACKAGING GROUP No: Not Applicable HAZCHEM CODE: Not Applicable POISON SCHEDULE: Not Applicable
Finished packages product by ground (DOT); Non Hazardous Finished packages product by vessel (IMDG); Non Hazardous Finished packages product by air (IATA); Non Hazardous
Section 15 - Regulatory Information AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature. Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AICS Australian Inventory of Chemical Substances SWA Safe Work Australia, formerly ASCC and NOHSC CAS Number Chemical Abstracts Service Registry Number Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC International Agency for Research on Cancer NOS Not otherwise specified NTP National Toxicology Program (USA) R-Phrase Risk Phrase SUSMP Standard for the Uniform Scheduling of Medicines & Poisons UN Number United Nations Number THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Page 1 of 6 Quality manufacturers of bath & body care products – made in Australia
SAFETY DATA SHEET
According to Regulation (EC) no. 1907/2006 SECTION 1: Identification of the substance/mixture & of the Company/ Undertaking of the substance/mixture and of the
company/undertaking 1.1 Product Name: Eleven Strong Hold Styling Paste 1.2 Application of the substance/mixture: Hair styling product. For external use only. 1.3 Details of the Manufacturer / Distributor:
Natural Beauty Care Pty Ltd 8 Teton Court, Highett, Victoria 3190, Australia.
Eleven Australia Pty Ltd 7 Endeavour Way, Sunshine West, Victoria 3020, Australia.
1.4 Emergency telephone number: +61 3 9553 0733 Facsimile Number: +61 3 9553 4988 1.5 POISON INFORMATION CENTRE: 13 11 26 (Australia)
SECTION 2: Hazard Identification
Not classified as Dangerous goods by the criteria of the Australian Dangerous goods code (ADG) for Transport and Rail. NON-DANGEROUS GOODS.
This material is a personal care product that is safe for consumers with intended and foreseeable use. This product is non- hazardous according to Work Safe Australia.
Classification of the substance or mixture (Classification according to Regulation (EC) No 1272/2008): Nil Classification according to the Directive 67/548/EEC or Directive 1999/45/EC: Not regulated
Signal word: Not relevant
Hazard statements:
Not relevant
Precautionary statements:
P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P103 Read label before use
Page 2 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 3: Composition/formulation on ingredients
SECTION 4: First Aid Measures
4.1 Description of first aid measures
General information: No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Name of Chemical CAS Number Percentage w/w
Water (Aqua) 7732-18-5 < 50-60 Lanolin Cera 68201-49-0 < 20 Beeswax (Cera Alba) 8012-89-3 < 20 Cetearyl Alcohol 67762-27-0 < 10 Stearyl Stearate 2778-96-3 < 10 Glycerin 56-81-5 < 5 Propylene Glycol 57-55-6 < 5 PEG-8 Beeswax - < 5 Oleth-30 9004-98-2 < 5 Oleth-5 9004-98-2 < 5 Microcrystalline Wax (Cera Microcrystallina) 63231-60-7 < 5 PVP 9003-39-8 < 5 Octyldodecanol 5333-42-6 < 1 Ricinus Communis (Castor) Seed Oil 8001-79-4 < 1 Dimethicone 9006-65-9 < 1 Phenoxyethanol 122-99-6 < 1 Benzyl Alcohol 100-51-6 < 1
Acrylates/C10-30 Alkyl Acrylate Crosspolymer -
< 0.5 Fragrance (Parfum) - < 0.5 Triethanolamine 102-71-6 < 0.5 Yellow 5 (CI 19140) 12225-21-7 < 0.5 Caramel 8028-89-5 < 0.5
HEALTH EFFECTS: Acute - Swallowed May be harmful if large amounts are swallowed Acute - Eye Full strength material may be irritating to eyes Acute - Skin Not considered an irritant through normal use. Full strength material in repeated
or prolonged contact with skin may be irritating and cause allergic reactions in sensitive individuals
Acute - Inhaled Full strength material should not cause any irritation to the mucous membrane and upper airways
Page 3 of 6 Quality manufacturers of bath & body care products – made in Australia
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting Measures
5.1 Suitable Extinguishing media: Carbon dioxide, Foam, Dry Chemical
5.2 Special hazards arising from the substance or mixture:
No further relevant information available.
5.3 Advice for firefighters:
Wear Protective equipment. Do not inhale explosion gases or combustion gases. Hazchem Code: Not applicable.
SECTION 6: Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures: Remove all sources of ignition. Increase ventilation. Evacuate all personnel. Wear sufficient respiratory protection and full protective clothing to minimise skin and eye exposure. If possible contain the spill.
6.2 Environmental precautions: No special measures required.
6.3 Methods and material for containment and cleaning up: Slippery when spilt. Clean up immediately. Wear protective
equipment to avoid eye contact. Contain – prevent run off into drains and waterways. Use absorbent material. Collect and
seal on properly labelled containers for disposal. If large quantities of this material enter the waterways, contact the
Environmental Protection Authority or you local Waste Management Authority.
6.4 Reference to other sections: See Section 7 for information on safe handling.
FIRST AID: Swallowed Do not induce vomiting, Give plenty of water and seek medical advice Eye Flush eye with copious amounts of water for 15 minutes including under eyelid. If
discomfit persists, obtain medical advice. Skin Remove contaminated clothing. Wash affected areas with warm soapy water
Inhaled Remove to fresh uncontaminated air, lay patient on back until breathing returns to normal
Page 4 of 6 Quality manufacturers of bath & body care products – made in Australia
SECTION 7: Handling & Storage
7.1 Precautions for safe handling
None required when handling small quantities. Avoid contact with eyes. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing.
Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities: Store below 30C if in original containers. Store in a cool dry well ventilated area. Store away from Incompatible materials. 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure Controls /Personal Protection:
Additional information about design of technical facilities: No further data; see item 7.
8.1 Control parameters: No value assigned for this specific material
8.2 Appropriate engineering controls:
Non-required 8.3 Personal Protection:
None required when handling small quantities. Avoid contact with eyes. Do not ingest. Good personal hygiene practices should be used ie. Wash hands after contact otherwise wear protective clothing. Some sensitive individuals may develop an allergic response.
National Exposure Standards: No exposure standards have been established for this material by Work Safe Australia. Biological Limit Values: No biological limit allowed.
SECTION 9: Physical & Chemical Properties
Appearance: Thick Waxy Balm Colour: White/ Off White Odour: Vanilla Odour threshold: Not determined.
pH: 6.0-6.5 Flash point: Not available
Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined.
Danger of explosion: Product does not present an explosion hazard. Self-igniting: Product is not self - igniting.
Solubility in / Miscibility with water: Soluble. Density at 20 °C: 0.90-1.04 g/cm³
Vapour density Not applicable. Vapour pressure: Not applicable.
SECTION 10: Stability & Reactivity
10.1 Reactivity: No further relevant information available.
10.2 Chemical stability: Stable under normal handling and storage conditions.
Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials: No further relevant information available.
Page 5 of 6 Quality manufacturers of bath & body care products – made in Australia
10.6 Hazardous decomposition products: None under normal conditions of storage and use.
SECTION 11: Toxicology Information
11.1 Information on toxicological effects:
No adverse health effects expected if the product is handled in accordance with this safety data sheet and the product label. Product is safe for its intended use based on the formulation, testing results and the history of safe consumer use.
Acute toxicity: No LD50 data available for this product
Primary irritant effect:
On the skin: No irritant effect On the eye: No irritating effect Carcinogen Classification: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed carcinogen by IARC
SECTION 12: Ecological Information
12.1 Ecotoxicity: Avoid contaminating waterways 12.2 Persistence/degradability: No tested data available on this product. 12.3 Bioaccumulative potential: This product shows a low bioaccumulation potential 12.4 Mobility: Prevent contamination of soil, ground and surface water.
Section 13: Disposals Consideration
Disposal Methods:
Refer to Waste Management Authority. Dispose of contents/containers in accordance with local/regional/national/international regulations.
SECTION 14: Transport Information
ADG 7.3 Land Transport of Dangerous Goods
Labels required: No special requirements
UN Number: N/A
Proper Shipping Name: N/A
DG Class: N/A
Subsidiary Risk: None
Packing Group: N/A
HAZCHEM Code: N/A
Special Provision: N/A
Page 6 of 6 Quality manufacturers of bath & body care products – made in Australia
MARITIME TRANSPORTATION AIR TRANSPORTATION
IMCD IATA Dangerous Goods Regulations (DGR) 56th
Edition 2015
IMCD: N/A ICAO/IATA Class: N/A
Label: N/A Label: N/A
UN Number: N/A UN Number: N/A
Packaging Group: Not allocated Packaging Group: N/A
EMS Number: N/A
Marine Pollutant: Not allocated
Proper Shipping Name: As above Proper Shipping Name: As above Special Provisions; N/A Special Provisions; N/A
SECTION 15: Regulatory Information
POISONS SCHEDULE (SUSMP):
Not subject to labelling
AICS:
All ingredients in this product are compliant with NICNAS regulations
SECTION 16: OTHER INFORMATION
The information herein is accurate to the best of our knowledge. However, it is meant to describe safety requirements of our
products, thus this shall not constitute a guarantee for any specific product features and shall not establish a legally valid
contractual relationship. No warranty is expressed or made as to this document’s accuracy, reliability or completeness. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated.
Relevant phrases
Non relevant Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
AICS: Australian Inventory of Chemical substances
NICNAS: National Industrial Chemical Notification & Assessment Scheme
IARC: International Agency for Research Cancer
MSDS prepared by: Natural Beauty Care Pty. Ltd. Issue Date: 14/06/2016 Revision Number: 1
END OF MSDS
WPS-CHI-011 Eleven Revision Date 1/10/2018
Appearance Physical State
< 15
Clear Aerosol
Precautionary StatementsOdor Odor Fragranced
• Wear eye/face protection.• Avoid breating dust/fune/gas/mist/vapors/spray.• Use only outdoors or in a well-ventilated area.• Keep away from heat/sparks/open flames/hot surfaces - No smoking.• Do not spray on an open flam or other ignition source.
Prevention• Obtain special instructions before use.• Do not handle until all safety precautions have been read and understood.• Use personal protective equipment as required.• Wash face, hands and any exposed skin thoroughly after handling.
Eyes• IF IN EYES: Rinse cautionsly with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• If eye irritation persists: Get medical advice/attention.
• Pressurized container: Do no pierce or burn, even after use.
General Advice• If exposed or concerned: Get medical attention/advice
• Dispose of contents/container to an approved waste disposal plant.
Hazzard Not Otherwise Classifed (HNOC)Rapid evaporation of the liquid may cause frostbite.
Other informationMay be harmful if inhaled. Intentional misuse by deliberately concentrating and
inhaling contents may be harmful or fatal.
75-28-5
74-98-6
Inhalation• IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Storage• Store locked up.• Store in a well-ventilated place. Keep container tightly closed.• Protect from sunlight. Do no expose to temperatures exceeding 50°C/122°F
Disposal
CAS-No
< 75
Weight %
< 20
3. COMPOSITION/INFORMATION ON INGREDIENTS
64-17-5
Trade Secret
*
*
*
Chemical NameEthyl Alcohol
Propane
Isobutane
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WPS-CHI-011 Eleven Revision Date 1/10/2018
Notes to Physician
Unsuitable Extinguishing Media
Thermal decomposition can lead to release of irritating and
toxic gases and vapors: Carbon oxides. Nitrogen oxides (NOx).
Hazardous Combustion Products
Sensitivity to Mechanical ImpactSensitivity to Static Discharge
Explosion DataYes
Yes
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Personal precautions, protective equipment and emergency procedures
Contents under pressure. Remove all sources of ignition. Do not puncture or incinerate cans.
Avoid contact with skin, eyes and clothing. Do not touch damaged containers or spilled
material
Environmental Precautions
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed, if necessary
Suitable Extinguishing MediaCarbon dioxide (CO 2 ). Dry chemical. Alcohol-resistant foam. Water fog.
No information available.
Specific Hazards Arising from the ChemicalNo information available.
Personal Precautions
Most Important Symptoms/Effects
Environmental Precautions
4. FIRST AID MEASURES
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get
medical attention immediately if irritation persists.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Eye irritation/reactions. Frostbite. Drowsiness. Dizziness. Simple asphyxiant.
Description of necessary first-aid measures
See Section 12 for additional Ecological Information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
6. ACCIDENTAL RELEASE MEASURES
Clean mouth with water and afterwards drink plenty of water. Do NOT induce vomiting. Never
give anything by mouth to an unconscious person. Get medical attention.
Ingestion
Eye Contact
Skin Contact
Inhalation
Wash off with warm water and soap. In case of contact with liquefied gas, thaw frosted parts
with lukewarm water. Get medical attention if symptoms occur.
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WPS-CHI-011 Eleven Revision Date 1/10/2018
Strong oxidizing agents.
Individual protection measures, such as personal protective equipment
Respiratory Protection
Information on basic physical and chemical properties
Exposure Guidelines
Chemical Name ACGIH TLV NIOSH IDLHOSHA PEL
Pick up and transfer to properly labeled containers. Cover liquid spill with sand, earth or other
noncombustible absorbent material. Clean contaminated surface thoroughly.
Methods for Cleaning Up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods and materials for containment and cleaning up
7. HANDLING AND STORAGE
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
9. PHYSICAL AND CHEMICAL PROPERTIES
Contents under pressure. Keep away from open flames, hot surfaces and sources of ignition.
Avoid contact with skin, eyes and clothing.
Precautions for safe handling
Handling
Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other
chemicals.
Storage
Control parameters
Appropriate engineering controls
Conditions for safe storage, including any incompatibilities
Incompatible Products
TWA: 1000 ppm TWA: 1000 ppm TWA: 1000 ppmEthyl Alcohol
Ethyl Alcohol 64-17-5
Engineering Measures Showers
Eyewash stations
Ventilation systems
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, approved respiratory protection should be worn.
No protective equipment is needed under normal use conditions. Lightweight protective
clothing. Protective gloves. Please observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the gloves. Also take into
consideration the specific local conditions under which the product is used, such as the danger
of cuts, abrasion.
No protective equipment is needed under normal use conditions. Risk of contact, wear: Safety
glasses with side-shields.
Eye/Face Protection
Skin and Body Protection
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WPS-CHI-011 Eleven Revision Date 1/10/2018
Heat, flames and sparks.
ReactivityNot reactive under normal conditions.
Conditions to avoid
Hazardous polymerization does not occur.
Hazardous Polymerization
None under normal processing.
Possibility of hazardous reactions
Stable under recommended storage conditions.
Chemical stability
11. TOXICOLOGICAL INFORMATION
Carbon oxides. Nitrogen oxides (NOx).
Hazardous decomposition products
Strong oxidizing agents
Incompatible materials
Property
Clear
No information available
Flammable Properties
Aerosol
Fragranced
Appearance
Odor Threshold
Physical State
Odor
Enter here
ValuesNo data available
No data available
79.4 ºC / 175 ºF
18.3C/ 65F
> 1
Remarks/ - MethodEnter here
Enter here
for concentrate
Open cup ( for pure ethanol)
No data available
No data available
No data available
No data available
pHMelting Point/RangeBoiling Point/Boiling RangeFlash PointEvaporation rate
water = 1
Enter here
Enter here
Enter here
Enter here
Enter here
45-55 psig @ 70 F
No data available
1.02
No data available
No data available
Enter here
Flammability (solid, gas)Flammability Limits in Air
upper flammability limitlower flammability limit
Vapor PressureVapor DensitySpecific GravityWater SolubilitySolubility in other solventsPartition coefficient: n-octanol/waterAutoignition TemperatureDecomposition TemperatureViscosity
No data available
No data available
No data available
No data available
Enter here
Enter here
Enter here
Enter here
Enter here
Enter here
10. STABILITY AND REACTIVITY
Not Flammable
No data available
No data available
Enter here
Enter here
Enter here
Explosive PropertiesOxidizing Properties
Other informationVOC Content (%) 92%
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WPS-CHI-011 Eleven Revision Date 1/10/2018
Chemical Name ACGIH IARC NTP OSHAEthyl Alcohol A3 Group 1 Known X
No information available.
Ethanol has been shown to be carcinogenic in long-term studies only when consumed and
abused as an alcoholic beverage. Vinyl acetate is identified by IARC and ACGIH as a potential
carcinogen based on data in animal studies. Lifetime exposure to high vapor concentrations
(600 ppm) of Vinyl acetate caused malignant and benign tumors of the respiratory tract of
rats, but not in mice: this response possibly being associated with the irritant effect. Vinyl
acetate has been tested for carcinogenic potential in rats in two separate drinking water
studies. In one study, in which animals were exposed to concentrations up to 0.5% in water,
there was no evidence of carcinogenicity. In the second study, conducted at higher
concentrations (up to 1% in water), evidence of cancer in the stomach and oral cavities was
observed. There is no evidence that vinyl acetate causes cancer in humans.
Carcinogenicity
Reproductive Toxicity No information available.
May cause irritation of respiratory tract. May cause drowsiness and dizziness.
Intentional misuse by deliberately concentrating and inhaling contents may be
harmful or fatal.Contact with eyes may cause serious eye irritation based on the components present
within the product.
Contact with product may cause frostbite.
Eye Contact
Inhalation
Skin Contact
Information on likely routes of exposure
Product Information
LC50 InhalationEthyl Alcohol 7060 mg/kg (Rat) - 124.7 mg/L ( Rat) 4 h
Ingestion May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea.
Chemical Name LD50 Oral LD50 Dermal
Symptoms related to the physical, chemical and toxicological characteristics
Mutagenic Effects
Eye contact with liquid may cause irritation including stinging, burning, tearing, or reddening
of the eyes. Avoid skin contact with leaking liquid (danger of frostbite).
Symptoms
Sensitization No information available.
Delayed and immediate effects and also chronic effects from short and long term exposure
STOT - single exposureSTOT - repeated exposureAspiration Hazard
May cause respiratory irritation. May cause drowsiness or dizziness.
No information available.
No information available.
Numerical measures of toxicity - Product
The following values are calculated based on chapter 3.1 of the GHS document:
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WPS-CHI-011 Eleven Revision Date 1/10/2018
Do not re-use empty containers.
Dispose of in accordance with federal, state, and local regulations.Waste Disposal Methods
Contaminated Packaging
Log Pow-0.32
Chemical NameEthyl alcohol
No information available.
Other Adverse Effects
No information available.
No information available.Bioaccumulation
Persistence and Degradability
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to MicroorganismsDaphnia Magna (Water
Flea)Ethyl Alcohol LC50 96 h: 12.0-16.0mL/L EC50=34634 mg?L 30 min LC50 48h: 9268-14221
mg/L
23700 mg/kg; Acute toxicity estimate
mg/L; Acute toxicity estimate
134.2 mg/L; Acute toxicity estimate
The environmental impact of this product has not been fully investigated.
Ecotoxicity
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
14. TRANSPORT INFORMATION
LD50 OralLD50 DermalInhalation Vapor
8538 mg/kg; Acute toxicity estimate
Proper shipping name Hazard Class Description Emergency Response Guide Number
DOT
TDG
MEX
Consumer commodity
126
Consumer commodity, ORM-D
ORM-D
UN1950
UN-Number Proper Shipping Name Hazard Class Description
UN-Number Proper Shipping Name
UN1950, Aerosols, 2.1
2.1
Aerosols
UN1950
Aerosols
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WPS-CHI-011 Eleven Revision Date 1/10/2018
15. REGULATORY INFORMATION
ICAO
IATA
Hazard Class Description
ERG Code Hazard Class Proper Shipping Name UN-Number
Description Hazard Class Proper Shipping Name UN-Number
9L
9
Consumer commodity
ID8000
ID8000, Consumer commodity, 9
9
Consumer commodity
ID8000
UN1950, Aerosols, 2.1
2.1
UN1950, Aerosols, 2.1 (18.3°C o.c.)
F-D, S-U
2
Aerosols
UN1950
ID8000, Consumer commodity, 9
Description EmS No. Hazard Class Proper Shipping Name UN-Number
Description
IMDG/IMO
International Inventories
DSLTSCA All components of this product are either listed or are exempt on the TSCA inventory.
Substances comply or are exempt
LegendTSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
Chemical Name CAS-No Weight % SARA 313 - Threshold Values %
SARA 311/312 Hazard Categories
Clean Water Act
Chemical NameCWA - Reportable
QuantitiesCWA - Toxic Pollutants CWA - Priority Pollutants
CWA - Hazardous Substances
Reactive Hazard Sudden Release of Pressure Hazard Fire Hazard Chronic Health Hazard Acute Health Hazard
No
Yes
Yes
Yes
Yes
CERCLA
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WPS-CHI-011 Eleven Revision Date 1/10/2018
New Jersey IllinoisX -
NFPA
HMIS
16. OTHER INFORMATION
RQHazardous Substances RQsChemical Name Extremely Hazardous Substances RQs
X
U.S. State Regulations
California Proposition 65
Ethyl alcohol is only considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage.
Developmental
California Prop. 65CAS-No64-17-5
Chemical NameEthyl alcohol
Not applicableEPA Pesticide Registration Number
U.S. EPA Label Information
U.S. State Right-to-Know Regulations
Physical and Chemical HazardsHealth Hazard 2
Health Hazard 2* Personal Protection X
Instability 0
Physical Hazard 0Flammability 4
Flammability 4
Rhode IslandPennsylvaniaMassachusettsEthyl alcohol
Chemical NameX
General DisclaimerThe information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any other material or in any
process, unless specified in the text
Prepared By
*Indicates a chronic health hazard.
End of Safety Data Sheeet
Initial Release.
21-Apr-15
21-Apr-15
1-800-572-6501
Coal City, IL 60416
1300 North St
Chicago Aerosol
Revision NoteRevision DateIssuing Date
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