SAFETY DATA SHEET CARPLAN DEMON COOL

Revision date: 14/10/2018 Revision: 1

SAFETY DATA SHEETCARPLAN DEMON COOL

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name CARPLAN DEMON COOL

Product number DCO101, DCO000

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Antifreeze liquid.

1.3. Details of the supplier of the safety data sheet

Supplier TETROSYL LIMITEDBuryLancashireEnglandBL9 7NY0161 764 59810161 797 [email protected]

Manufacturer TETROSYL LIMITEDBuryLancashireEnglandBL9 7NY0161 764 59810161 797 [email protected]

1.4. Emergency telephone number

Emergency telephone +44 (0)161 764 5981

SECTION 2: Hazards identification

2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Not Classified

Health hazards Acute Tox. 4 - H302

Environmental hazards Not Classified

2.2. Label elements

Pictogram

Signal word Warning

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CARPLAN DEMON COOL

Hazard statements H302 Harmful if swallowed.

Precautionary statements P101 If medical advice is needed, have product container or label at hand.P102 Keep out of reach of children.P264 Wash contaminated skin thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P501 Dispose of contents/ container in accordance with local regulations.

Contains ETHANEDIOL

Supplementary precautionarystatements

P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.P330 Rinse mouth.P501 Dispose of contents/ container to …

2.3. Other hazards

This product contains substances classified as PBT.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

ETHANEDIOL 60-100%

CAS number: 107-21-1 EC number: 203-473-3 REACH registration number: 01-2119456816-28-0000

ClassificationAcute Tox. 4 - H302STOT RE 2 - H373

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Effects may be delayed. Keep affected person under observation. For breathing difficulties,oxygen may be necessary. If breathing stops, provide artificial respiration. Get medicalattention. Remove affected person from source of contamination. Place unconscious personon the side in the recovery position and ensure breathing can take place. Never give anythingby mouth to an unconscious person.

Inhalation Remove affected person from source of contamination. Get medical attention if any discomfortcontinues. For breathing difficulties, oxygen may be necessary. If breathing stops, provideartificial respiration. If spray/mist has been inhaled, proceed as follows. Move affected personto fresh air and keep warm and at rest in a position comfortable for breathing. If throat irritationor coughing persists, proceed as follows. Get medical attention. Show this Safety Data Sheetto the medical personnel.

Ingestion Get medical attention immediately. Never give anything by mouth to an unconscious person.Try to induce vomiting. If vomiting occurs, the head should be kept low so that vomit does notenter the lungs. Rinse mouth thoroughly with water. Give plenty of water to drink. Get medicalattention if a large quantity has been ingested. Show this Safety Data Sheet to the medicalpersonnel.

Skin contact Remove contaminated clothing and rinse skin thoroughly with water. Get medical attention ifany discomfort continues.

Eye contact Do not rub eye. Rinse immediately with plenty of water. Remove any contact lenses and openeyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention if irritationpersists after washing. Show this Safety Data Sheet to the medical personnel.

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CARPLAN DEMON COOL

4.2. Most important symptoms and effects, both acute and delayed

General information The severity of the symptoms described will vary dependent on the concentration and thelength of exposure. Effects may be delayed. Keep affected person under observation.

Inhalation Irritation of nose, throat and airway.

Ingestion May cause discomfort if swallowed. May cause unconsciousness, blindness and possiblydeath. Central nervous system depression.

Skin contact Prolonged skin contact may cause redness and irritation.

Eye contact Irritation, burning, lachrymation, blurred vision after liquid splash.

4.3. Indication of any immediate medical attention and special treatment needed

Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with the following media: Alcohol-resistant foam. Water spray, fog or mist. Carbondioxide (CO2). Dry chemicals.

Unsuitable extinguishingmedia

Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards No unusual fire or explosion hazards noted.

Hazardous combustionproducts

Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides andother toxic gases or vapours.

5.3. Advice for firefighters

Protective actions duringfirefighting

No specific firefighting precautions known.

Special protective equipmentfor firefighters

Leave danger zone immediately. Use protective equipment appropriate for surroundingmaterials.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalationof spray mist and contact with skin and eyes. In case of spills, beware of slippery floors andsurfaces.

6.2. Environmental precautions

Environmental precautions Collect and dispose of spillage as indicated in Section 13. Avoid release to the environment.Avoid discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Stop leak if possible without risk. Eliminate all sources of ignition. No smoking, sparks, flamesor other sources of ignition near spillage. Provide adequate ventilation. Provide adequateventilation. Contain spillage with sand, earth or other suitable non-combustible material. Avoidthe spillage or runoff entering drains, sewers or watercourses. Absorb spillage with non-combustible, absorbent material.

6.4. Reference to other sections

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CARPLAN DEMON COOL

Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. For wastedisposal, see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Read and follow manufacturer's recommendations. Keep away from heat, sparks and openflame. Wear suitable protective equipment for prolonged exposure and/or high concentrationsof vapours, spray or mist. Good personal hygiene procedures should be implemented. Washhands and any other contaminated areas of the body with soap and water before leaving thework site. Do not eat, drink or smoke when using the product. Avoid inhalation ofvapours/spray and contact with skin and eyes. Avoid the formation of mists. Observe anyoccupational exposure limits for the product or ingredients. Avoid inhalation of vapours andspray/mists. Pregnant or breastfeeding women should not work with this product if there isany risk of exposure. Pregnant or breastfeeding women should not work with this product ifthere is any risk of exposure.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Keep away from heat, sparks and open flame. Keep container tightly closed. Keep containersupright. Keep only in the original container. Avoid contact with oxidising agents.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parametersOccupational exposure limitsNo exposure limits known for ingredient(s).

ETHANEDIOL

Long-term exposure limit (8-hour TWA): WEL 20 ppm 52 mg/m³ vapourShort-term exposure limit (15-minute): WEL 40 ppm 104 mg/m³ vapourSkLong-term exposure limit (8-hour TWA): WEL 10 mg/m³ particulateSkWEL = Workplace Exposure LimitSk = Can be absorbed through the skin.

8.2. Exposure controls

Protective equipment

Appropriate engineeringcontrols

Avoid inhalation of vapours. Observe any occupational exposure limits for the product oringredients. Provide adequate ventilation.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicateseye contact is possible. Unless the assessment indicates a higher degree of protection isrequired, the following protection should be worn: Tight-fitting safety glasses.

Hand protection It is recommended that gloves are made of the following material: Nitrile rubber. Chemical-resistant, impervious gloves complying with an approved standard should be worn if a riskassessment indicates skin contact is possible.

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CARPLAN DEMON COOL

Other skin and bodyprotection

Wear suitable protective clothing as protection against splashing or contamination.

Hygiene measures Provide eyewash station. Wash contaminated clothing before reuse. Wash at the end of eachwork shift and before eating, smoking and using the toilet. Wash promptly if skin becomescontaminated. Promptly remove any clothing that becomes contaminated. When using do noteat, drink or smoke.

Respiratory protection No specific recommendations. Respiratory protection must be used if the airbornecontamination exceeds the recommended occupational exposure limit.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Coloured liquid.

Colour Colourless.

Odour Odourless.

pH pH (diluted solution): 6-7.5 100 g/l

Melting point Not determined.

Initial boiling point and range 100-195°C @ 760 mm Hg

Flash point Not applicable.

Evaporation rate Not determined.

Upper/lower flammability orexplosive limits

Not determined.

Vapour pressure Not determined.

Vapour density Not determined.

Relative density 1.05 @ 15°C

Solubility(ies) Miscible with water. Miscible with the following materials: acetone Alcohols.

Partition coefficient : -1.36

Auto-ignition temperature Not determined.

Decomposition Temperature Not determined.

9.2. Other information

Other information None.

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity The following materials may react with the product: Oxidising materials.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

Possibility of hazardousreactions

Not determined.

10.4. Conditions to avoid

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CARPLAN DEMON COOL

Conditions to avoid Avoid contact with the following materials: Oxidising materials.

10.5. Incompatible materials

Materials to avoid Strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decompositionproducts


SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects No information available.

Acute toxicity - oralATE oral (mg/kg) 833.33

Specific target organ toxicity - single exposureTarget organs Central nervous system Heart and cardiovascular system Kidneys

Inhalation May cause respiratory system irritation.

Ingestion Harmful if swallowed. May cause irritation. Symptoms following overexposure may include thefollowing: Stomach pain. Nausea, vomiting. Diarrhoea. May cause nausea, headache,dizziness and intoxication.

Skin contact Slightly irritating.

Eye contact Irritating to eyes.

Acute and chronic healthhazards

This chemical can be hazardous when inhaled and/or touched. A single exposure may causethe following adverse effects: Central nervous system depression.

Route of exposure Ingestion.

Target organs Kidneys Liver

Medical symptoms Allergic rash. Delayed, often serious, breathing problems. Tachycardia (excessively rapidheart beat, including rapid and weak pulse). Unconsciousness, possibly death.

SECTION 12: Ecological information

Ecotoxicity The product components are not classified as environmentally hazardous. However, large orfrequent spills may have hazardous effects on the environment.

12.1. ToxicityAcute aquatic toxicityAcute toxicity - fish

LC₅₀, 96 hours: 72860mg/l mg/l, Fish

Acute toxicity - aquaticinvertebrates

EC₅₀, 48 hours: 46300 mg/l, Daphnia magna

Acute toxicity - aquatic plants IC₅₀, 72 hours: >6500mg/l mg/l, Algae

12.2. Persistence and degradability

Persistence and degradability The product is biodegradable.

12.3. Bioaccumulative potential

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CARPLAN DEMON COOL

Bioaccumulative potential The product is not bioaccumulating.

Partition coefficient : -1.36

12.4. Mobility in soil

Adsorption/desorptioncoefficient

Not available.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvBassessment

This substance is not classified as PBT or vPvB according to current EU criteria.

12.6. Other adverse effects

Other adverse effects Not applicable.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Waste is classified as hazardous waste. Dispose of waste to licensed waste disposal site inaccordance with the requirements of the local Waste Disposal Authority.

Disposal methods Confirm disposal procedures with environmental engineer and local regulations.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods(IMDG, IATA, ADR/RID).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Transport labelsNo transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutantNo.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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CARPLAN DEMON COOL

National regulations EH40/2005 Workplace exposure limits.

EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18December 2006 concerning the Registration, Evaluation, Authorisation and Restriction ofChemicals (REACH) (as amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Issued by Health & Safety Department

Revision date 14/10/2018

Revision 1

SDS number 32808

SDS status Approved.

Hazard statements in full H302 Harmful if swallowed.H373 May cause damage to organs (Kidneys) through prolonged or repeated exposure.

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Revision date: 16/08/2018 Revision: 1 Supersedes date: 27/07/2018

SAFETY DATA SHEETDEMON SHOT



Product name DEMON SHOT

Product number DSW050, DSW051


Identified uses Glass cleaner.







2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Flam. Liq. 2 - H225

Health hazards Eye Irrit. 2 - H319


2.2. Label elements

Pictogram

Signal word Danger

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DEMON SHOT

Hazard statements H225 Highly flammable liquid and vapour.H319 Causes serious eye irritation.EUH208 Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.

Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Nosmoking.P233 Keep container tightly closed.P243 Take action to prevent static discharges.P264 Wash contaminated skin thoroughly after handling.P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.Rinse skin with water or shower.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.P337+P313 If eye irritation persists: Get medical advice/ attention.P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.P403+P235 Store in a well-ventilated place. Keep cool.P501 Dispose of contents/ container in accordance with national regulations.P101 If medical advice is needed, have product container or label at hand.P102 Keep out of reach of children.

Detergent labelling < 5% anionic surfactants, < 5% perfumes, Contains BENZISOTHIAZOLINONE,METHYLISOTHIAZOLINONE


P240 Ground and bond container and receiving equipment.P241 Use explosion-proof electrical equipment.P242 Use non-sparking tools.

2.3. Other hazards

Not applicable.


3.2. Mixtures

ETHANOL 60-100%


ClassificationFlam. Liq. 2 - H225Eye Irrit. 2 - H319

IPA 2.5-<5.0%


ClassificationFlam. Liq. 2 - H225Eye Irrit. 2 - H319STOT SE 3 - H336

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DEMON SHOT

1,2-BENZISOTHIAZOL-3(2H)-ONE 0.001 - <0.1%

CAS number: 2634-33-5 EC number: 220-120-9

M factor (Acute) = 1

ClassificationAcute Tox. 4 - H302Skin Irrit. 2 - H315Eye Dam. 1 - H318Skin Sens. 1 - H317Aquatic Acute 1 - H400

ETHANOL 0.001 - <0.1%


ClassificationFlam. Liq. 2 - H225

ETHYL ACETATE 0.001 - <0.1%






General information Get medical attention if any discomfort continues. Remove affected person from source ofcontamination. Effects may be delayed. Keep affected person under observation.

Inhalation Remove affected person from source of contamination. Get medical attention if any discomfortcontinues. For breathing difficulties, oxygen may be necessary. If breathing stops, provideartificial respiration.

Ingestion Get medical attention if any discomfort continues. Rinse mouth thoroughly with water. Giveplenty of water to drink. Get medical attention if a large quantity has been ingested. Show thisSafety Data Sheet to the medical personnel.





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DEMON SHOT

Inhalation Vapours in high concentrations are anaesthetic. Symptoms following overexposure mayinclude the following: Headache. Fatigue. Dizziness. Central nervous system depression.Irritation of nose, throat and airway.

Ingestion May cause discomfort if swallowed. May cause stomach pain or vomiting. Ingestion of largeamounts may cause unconsciousness. May cause nausea, headache, dizziness andintoxication. Burning sensation in mouth.

Skin contact Prolonged skin contact may cause redness and irritation. Mild dermatitis, allergic skin rash.

Eye contact Irritation of eyes and mucous membranes.





Suitable extinguishing media Extinguish with the following media: Foam, carbon dioxide or dry powder. Water. Use fire-extinguishing media suitable for the surrounding fire.




Specific hazards Vapours may form explosive mixtures with air. May form explosive mixture with air at veryhigh concentration.







Leave danger zone immediately. Wear positive-pressure self-contained breathing apparatus(SCBA) and appropriate protective clothing.



Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No smoking,sparks, flames or other sources of ignition near spillage. Avoid inhalation of spray mist andcontact with skin and eyes. In case of spills, beware of slippery floors and surfaces.


Environmental precautions Do not discharge into drains or watercourses or onto the ground. Collect and dispose ofspillage as indicated in Section 13.




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DEMON SHOT




Usage precautions Read and follow manufacturer's recommendations. Keep away from heat, sparks and openflame. Wear suitable protective equipment for prolonged exposure and/or high concentrationsof vapours, spray or mist. Good personal hygiene procedures should be implemented. Washhands and any other contaminated areas of the body with soap and water before leaving thework site. Do not eat, drink or smoke when using the product. Avoid inhalation ofvapours/spray and contact with skin and eyes. Avoid the formation of mists. Observe anyoccupational exposure limits for the product or ingredients. Avoid inhalation of vapours andspray/mists.


Storage precautions Keep away from heat, sparks and open flame. Keep container tightly closed. Keep containersupright. Keep only in the original container. Store away from the following materials: Acids.Oxidising materials.



SECTION 8: Exposure controls/Personal protection


IPA

Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m³Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m³

ETHANOL

Long-term exposure limit (8-hour TWA): WEL 1000 ppm 1920 mg/m³Short-term exposure limit (15-minute): WEL

ETHYL ACETATE

Long-term exposure limit (8-hour TWA): WEL 200 ppmShort-term exposure limit (15-minute): WEL 400 ppmWEL = Workplace Exposure Limit






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DEMON SHOT

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn ifa risk assessment indicates skin contact is possible. It should be noted that liquid maypenetrate the gloves. Frequent changes are recommended. It is recommended that glovesare made of the following material: Nitrile rubber. It is recommended that gloves are made ofthe following material: Polyvinyl chloride (PVC). Rubber (natural, latex).


Provide eyewash station.

Hygiene measures Wash contaminated clothing before reuse. Wash at the end of each work shift and beforeeating, smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptlyremove any clothing that becomes contaminated. When using do not eat, drink or smoke.


SECTION 9: Physical and chemical properties


Appearance Clear liquid.

Colour Red.

Odour Slight alcoholic.

pH pH (concentrated solution): 9.00


Initial boiling point and range 82°C @ 1.013 hPa

Flash point 12°C



Not determined.



Relative density 0.830g/cm³ @ 20°C

Solubility(ies) Miscible with water.

Partition coefficient Not determined.



Viscosity <10 mm²/s @ 20°C

Explosive properties Not considered to be explosive.

Explosive under the influenceof a flame

Not considered to be explosive.

Oxidising properties Does not meet the criteria for classification as oxidising.




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DEMON SHOT

10.1. Reactivity

Reactivity The following materials may react with the product: Acids. Aldehydes. Isocyanates. Strongoxidising agents.





Not determined.


Conditions to avoid Avoid contact with strong oxidising agents. Avoid heat, flames and other sources of ignition.Avoid contact with acids. Avoid contact with the following materials: Acids. Oxidising agents.The following materials may react violently with the product: Earth metals such as sodium,potassium and barium.


Materials to avoid Strong acids. Strong oxidising agents. Alkali metals. Metal oxides. Aldehydes. Isocyanates.



Does not decompose when used and stored as recommended.



Inhalation No specific health hazards known.

Ingestion May cause discomfort if swallowed.

Skin contact Prolonged and frequent contact may cause redness and irritation.

Eye contact Irritating to eyes.

SECTION 12: Ecological information


12.1. ToxicityAcute aquatic toxicity12.2. Persistence and degradability

Persistence and degradability There are no data on the degradability of this product.


Bioaccumulative potential No data available on bioaccumulation.



Mobility The product is miscible with water and may spread in water systems.


Not available.

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DEMON SHOT





Other adverse effects Not available.






14.1. UN number

UN No. (ADR/RID) 1993

UN No. (IMDG) 1993

UN No. (ICAO) 1993

UN No. (ADN) 1993


Proper shipping name(ADR/RID)

FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, ISOPROPANOL)

Proper shipping name (IMDG) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, ISOPROPANOL)

Proper shipping name (ICAO) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, ISOPROPANOL)

Proper shipping name (ADN) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, ISOPROPANOL)


ADR/RID class 3

ADR/RID classification code F1

ADR/RID label 3

IMDG class 3

ICAO class/division 3

ADN class 3

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ICAO packing group II

ADN packing group II

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DEMON SHOT




EmS F-E, S-E

ADR transport category 2

Emergency Action Code •3YE

Hazard Identification Number(ADR/RID)

33

Tunnel restriction code (D/E)



Not applicable.



National regulations EH40/2005 Workplace exposure limits






Issued by Health & Safety Department


Revision 1

Supersedes date 27/07/2018

SDS number 32775


Hazard statements in full H225 Highly flammable liquid and vapour.H302 Harmful if swallowed.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H319 Causes serious eye irritation.H336 May cause drowsiness or dizziness.H400 Very toxic to aquatic life.EUH208 Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.

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SAFETY DATA SHEETDEMON ICE



Product name DEMON ICE

Product number CDI001, CDI002, CDI096


Identified uses Antifreeze liquid.







2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Flam. Liq. 3 - H226

Health hazards STOT RE 2 - H373


2.2. Label elements

Pictogram

Signal word Warning

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DEMON ICE

Hazard statements H226 Flammable liquid and vapour.H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements P101 If medical advice is needed, have product container or label at hand.P102 Keep out of reach of children.P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Nosmoking.P233 Keep container tightly closed.P243 Take precautionary measures against static discharge.P260 Do not breathe vapour/ spray.P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.Rinse skin with water/ shower.P314 Get medical advice/ attention if you feel unwell.P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.P403+P235 Store in a well-ventilated place. Keep cool.P501 Dispose of contents/ container in accordance with national regulations.

Contains ETHANEDIOL

Detergent labelling < 5% perfumes


P240 Ground/ bond container and receiving equipment.P241 Use explosion-proof electrical equipment.P242 Use only non-sparking tools.

2.3. Other hazards


3.2. Mixtures

ETHANEDIOL 10-<30%


ClassificationAcute Tox. 4 - H302STOT RE 2 - H373

ETHANOL 10-<30%


ClassificationFlam. Liq. 2 - H225

IPA 2.5-<5.0%



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DEMON ICE

METHANOL 0.5-<1%


ClassificationFlam. Liq. 2 - H225Acute Tox. 3 - H301Acute Tox. 3 - H311Acute Tox. 3 - H331STOT SE 1 - H370

DIETHANOLAMINE 0.001 - <0.1%


ClassificationAcute Tox. 4 - H302Skin Irrit. 2 - H315Eye Dam. 1 - H318STOT RE 2 - H373

ETHYL ACETATE 0.001 - <0.1%



CYCLOHEXANE 0.001 - <0.1%


M factor (Acute) = 1 M factor (Chronic) = 1

ClassificationFlam. Liq. 2 - H225Skin Irrit. 2 - H315STOT SE 3 - H336Asp. Tox. 1 - H304Aquatic Acute 1 - H400Aquatic Chronic 1 - H410




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DEMON ICE

General information Get medical attention if any discomfort continues. Remove affected person from source ofcontamination. Effects may be delayed. Keep affected person under observation. Whenbreathing is difficult, properly trained personnel may assist affected person by administeringoxygen. For breathing difficulties, oxygen may be necessary. If breathing stops, provideartificial respiration.

Inhalation Remove affected person from source of contamination. Get medical attention if any discomfortcontinues. For breathing difficulties, oxygen may be necessary. If breathing stops, provideartificial respiration.

Ingestion Get medical attention if any discomfort continues. Rinse mouth thoroughly with water. Giveplenty of water to drink. Get medical attention if a large quantity has been ingested. Show thisSafety Data Sheet to the medical personnel. Get medical attention immediately.





Inhalation Vapours in high concentrations are anaesthetic. Symptoms following overexposure mayinclude the following: Headache. Fatigue. Dizziness. Central nervous system depression.Irritation of nose, throat and airway.

Ingestion May cause discomfort if swallowed. May cause stomach pain or vomiting. Ingestion of largeamounts may cause unconsciousness. May cause nausea, headache, dizziness andintoxication. Burning sensation in mouth. May cause unconsciousness, blindness and possiblydeath.

Skin contact Prolonged skin contact may cause redness and irritation. Mild dermatitis, allergic skin rash.

Eye contact Irritation of eyes and mucous membranes. Irritation, burning, lachrymation, blurred vision afterliquid splash.





Suitable extinguishing media Extinguish with the following media: Foam, carbon dioxide or dry powder. Water. Use fire-extinguishing media suitable for the surrounding fire.




Specific hazards Vapours may form explosive mixtures with air. May form explosive mixture with air at veryhigh concentration.




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DEMON ICE




Leave danger zone immediately. Wear positive-pressure self-contained breathing apparatus(SCBA) and appropriate protective clothing.



Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No smoking,sparks, flames or other sources of ignition near spillage. Avoid inhalation of spray mist andcontact with skin and eyes. In case of spills, beware of slippery floors and surfaces.


Environmental precautions Do not discharge into drains or watercourses or onto the ground. Collect and dispose ofspillage as indicated in Section 13.







Usage precautions Read and follow manufacturer's recommendations. Keep away from heat, sparks and openflame. Wear suitable protective equipment for prolonged exposure and/or high concentrationsof vapours, spray or mist. Good personal hygiene procedures should be implemented. Washhands and any other contaminated areas of the body with soap and water before leaving thework site. Do not eat, drink or smoke when using the product. Avoid inhalation ofvapours/spray and contact with skin and eyes. Avoid the formation of mists. Observe anyoccupational exposure limits for the product or ingredients. Avoid inhalation of vapours andspray/mists.


Storage precautions Keep away from heat, sparks and open flame. Keep container tightly closed. Keep containersupright. Keep only in the original container. Store away from the following materials: Acids.Oxidising materials.



SECTION 8: Exposure Controls/personal protection


ETHANEDIOL

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DEMON ICE

Long-term exposure limit (8-hour TWA): WEL 20 ppm 52 mg/m³ vapourShort-term exposure limit (15-minute): WEL 40 ppm 104 mg/m³ vapourSkLong-term exposure limit (8-hour TWA): WEL 10 mg/m³ particulateSk

ETHANOL

Long-term exposure limit (8-hour TWA): WEL 1000 ppm 1920 mg/m³Short-term exposure limit (15-minute): WEL

IPA

Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m³Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m³

METHANOL

Long-term exposure limit (8-hour TWA): WEL 200 ppm 266 mg/m³Short-term exposure limit (15-minute): WEL 250 ppm 333 mg/m³Sk

DIETHANOLAMINE

Long-term exposure limit (8-hour TWA): OES 3 ppm 15 mg/m³Short-term exposure limit (15-minute): OES

ETHYL ACETATE

Long-term exposure limit (8-hour TWA): WEL 200 ppmShort-term exposure limit (15-minute): WEL 400 ppm

CYCLOHEXANE

Long-term exposure limit (8-hour TWA): WEL 100 ppm 350 mg/m³Short-term exposure limit (15-minute): WEL 300 ppm 1050 mg/m³WEL = Workplace Exposure Limit

Sk = Can be absorbed through the skin.






Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn ifa risk assessment indicates skin contact is possible. It should be noted that liquid maypenetrate the gloves. Frequent changes are recommended. It is recommended that glovesare made of the following material: Nitrile rubber. It is recommended that gloves are made ofthe following material: Polyvinyl chloride (PVC). Rubber (natural, latex).


Provide eyewash station.

Hygiene measures Wash contaminated clothing before reuse. Wash at the end of each work shift and beforeeating, smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptlyremove any clothing that becomes contaminated. When using do not eat, drink or smoke.

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SECTION 9: Physical and Chemical Properties


Appearance Clear liquid.

Colour Blue.

Odour Slight alcoholic.

pH pH (concentrated solution): 6.5 - 7.5


Initial boiling point and range ~100°C @ 1.013 hPa

Flash point 30.5°C



Not determined.



Relative density 1.02g/cm³ @ 20°C

Solubility(ies) Soluble in water.




Viscosity 200 - 400 cP @ 20°C

Explosive properties Not considered to be explosive.

Explosive under the influenceof a flame

Not considered to be explosive.

Oxidising properties Does not meet the criteria for classification as oxidising.




10.1. Reactivity

Reactivity The following materials may react with the product: Acids. Aldehydes. Isocyanates. Strongoxidising agents.





Not determined.

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Conditions to avoid Avoid contact with strong oxidising agents. Avoid heat, flames and other sources of ignition.Avoid contact with the following materials: Acids. Oxidising agents. The following materialsmay react violently with the product: Earth metals such as sodium, potassium and barium.


Materials to avoid Strong acids. Strong oxidising agents. Alkali metals. Metal oxides. Aldehydes. Isocyanates.



Does not decompose when used and stored as recommended.



Toxicological effects No information available.

Acute toxicity - oralATE oral (mg/kg) 2,232.14

Acute toxicity - dermalATE dermal (mg/kg) 51,724.14

Acute toxicity - inhalationATE inhalation (vapours mg/l) 517.24

Inhalation May cause drowsiness or dizziness. High concentrations of vapours may irritate respiratorysystem and lead to headache, fatigue, nausea and vomiting.

Ingestion May cause stomach pain or vomiting.

Skin contact Prolonged and frequent contact may cause redness and irritation.

Eye contact May cause temporary eye irritation.

Acute and chronic healthhazards

May cause damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological Information


12.1. Toxicity

Acute toxicity - fish Not available.

Acute toxicity - aquaticinvertebrates

Not available.

12.2. Persistence and degradability

Persistence and degradability There are no data on the degradability of this product.


Bioaccumulative potential No data available on bioaccumulation.



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Mobility The product is soluble in water.


Not available.





Other adverse effects Not available.






14.1. UN number

UN No. (ADR/RID) 1993

UN No. (IMDG) 1993

UN No. (ICAO) 1993

UN No. (ADN) 1993


Proper shipping name(ADR/RID)

FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, Isopropanol)

Proper shipping name (IMDG) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, Isopropanol)

Proper shipping name (ICAO) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, Isopropanol)

Proper shipping name (ADN) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, Isopropanol)


ADR/RID class 3

ADR/RID classification code F1

ADR/RID label 3

IMDG class 3

ICAO class/division 3

ADN class 3

Transport labels

14.4. Packing group

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ADR/RID packing group III

IMDG packing group III

ADN packing group III

ICAO packing group III




EmS F-E, S-E

ADR transport category 3

Emergency Action Code •3Y

Hazard Identification Number(ADR/RID)

30

Tunnel restriction code (D/E)



Not applicable.



National regulations EH40/2005 Workplace exposure limits







Revision 3

Supersedes date 19/07/2017

SDS number 32442


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Hazard statements in full H225 Highly flammable liquid and vapour.H226 Flammable liquid and vapour.H301 Toxic if swallowed.H302 Harmful if swallowed.H304 May be fatal if swallowed and enters airways.H311 Toxic in contact with skin.H315 Causes skin irritation.H318 Causes serious eye damage.H319 Causes serious eye irritation.H331 Toxic if inhaled.H336 May cause drowsiness or dizziness.H370 Causes damage to organs .H373 May cause damage to organs through prolonged or repeated exposure.H373 May cause damage to organs (Kidneys) through prolonged or repeated exposure.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.

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SAFETY DATA SHEET CARPLAN DEMON COOL

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