Safety Data Sheet According to 1907/2006/EC, Article 31 · Trade name: PU-D20 B component 1.2...

Page: 1/10 Safety Data Sheet

According to 1907/2006/EC, Article 31 Revision: 01-12-2016 1. Identification of the substance/ preparation and of the company undertaking 1.1 Product details: Trade name: PU-D20 B component 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance/ the preparation: Adhesives. 1.3 Details of the supplier of the safety data sheet Manufacturer/ supplier: DMS A/S Randersvej 126700 EsbjergDenmark Tel.: 0045 – 7023 4343 Fax: 0045 – 7023 4342 E-Mail [email protected] Further information obtainable from: Tel.: 0045 – 7023 43431.4 Emergency telephone number: Tel.: 0045 – 2844 4937 2. Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008

GHS08 health hazard

Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.

GHS07

Acute Tox. 4 H332 Harmful if inhaled. Skin. Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. Skin sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation.

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According to 1907/2006/EC, Article 31 Revision: 01-12-2016 Trade name: PU-D20 B component 2.2 Label elements Labelling according to Regulation (EU) No 1272/2008: The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS07 GHS08

GHS07 GHS08 · Signal word Danger · Hazard-determining components of labelling: diphenylmethanediisocyanate,isomeres and homologues · Hazard statements H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. Precautionary statements P280 Wear protective gloves / eye protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P402+P404 Store in a dry place. Store in a closed container. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Additional information: Contains isocyanates. May produce an allergic reaction. Restricted to professional users.

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According to 1907/2006/EC, Article 31 Revision: 01-12-2016 Trade name: PU-D20 B component 2.3 Other hazards Results of PBT and vPvB assessment. PBT: Not applicable. vPvB: Not applicable. 3. Composition/ information on ingredients

3.2 Mixtures Description: Mixture of substances listed below with non-hazardous additions Dangerous components: CAS: 9016-87-9 Polymer

diphenylmethanediisocyanate, isomers and homologues

50-100% Resp. Sens. 1, H334; Carc. 2, H351; STOT RE2, H373;

Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335

Additional information: For the wording of the listed risk phrases refer to section 16.

4. First-aid measures

4.1 Description of first aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. Remove contaminated clothing. If symptoms persist or in cases of doubt seek medical advice.

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According to 1907/2006/EC, Article 31 Revision: 01-12-2016 Trade name: PU-D20 B component After inhalation: Supply fresh air and be sure to call for a doctor. In case of unconsciousness place patient stable in side position for transportation. In the casualty is not breathing: perform mouth-to-mouth or mouth-to-nose resuscitation, notify emergency physician immediately. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse the opened eye for several minutes under water. If symptoms persist, consult a doctor. After swallowing: Rinse mouth with water. If symptoms persist consult a doctor. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. 5. Fire-fighting measures: 5.1 Extinguishing media Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions. For safety reasons unsuitable extinguishing agents: Water with full jet. 5.2 Special hazards arising from the substance or mixture Under certain fire conditions, traces of other gases cannot be excluded, e.g.: Carbon Monoxide (CO). 5.3 Advise for fire-fighters Protective equipment: Mount respiratory protective device. Wear self-contained respiratory protective device. Wear fully protective suit. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Not required 6.2 Environmental precautions No special measures required. 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

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According to 1907/2006/EC, Article 31 Revision: 01-12-2016 Trade name: PU-D20 B component 7. Handling and storage 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about fire- and explosion protection: No special measures required. 7.2 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep container tightly sealed. 7.3 Specific end use(s) No further relevant information available. 8. Exposure controls/ personal protection Additional information about design of technical facilities: No further data: see item 7. 8.1 Control parameters Ingredients with limit values that require monitoring at the workplace: 9016-87-9 diphenylmethanediisocyanate, isomers and homologues (50 - 100%) WEL Short-term value: 0.07 mg/m3

Long-term value: 0.02 mg/m3 Sen; as -NCO Additional information: The lists valid during the making were used as basis. 8.2 Exposure controls: Personal protective equipment: General protective and hygienic measures: Wear high-quality protective equipment during operations such as grinding, drilling and/or sawing. Dust mask FFP3 (Filtering Facepiece Partikel) (EN149:2001). Gloves (grinding) (EN388 (4.1.3.1)) Safety glasses (EN166-168,170). Hearing protection (EN352-2). Vacuum clean contaminated clothing. Do not blow or brush off contamination. Store protective clothing separately. The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Do not inhale gases/fumes/aerosols. Avoid contact with the eyes and skin. Do not carry product impregnated cleaning cloths in trousers pockets. Respiratory protection: In exceptional situations (e.g. accidental release of the substanc) wearing of respiratory protection is required. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

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According to 1907/2006/EC, Article 31 Revision: 01-12-2016 Trade name: PU-D20 B component Protection of hands:

Protective gloves

Nitrile rubber gloves (EN374, EN388:4101). Permeation EN374-3: 2003 (minutes) >480 minutes. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. While wearing protective gloves cotton single-use under gloves are recommendable. However these under gloves must be discarded after each use to avoid potential exposure to absorbed product. Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. Penetration time of the glove material: the exact break time has to be found out by the manufacturer of the protective gloves and has to be observed. For the permanent contact gloves made of the following materials are suitable: Nitrile rubber, NBR. For contact of maximum 15 minutes gloves made of the following materials are suitable: Nitrile rubber, NBR. Eye protection:

Tightly sealed goggles.

Safety glasses (EN166). Body protection: Protective work clothing. (EN340, 463, 468, 943-1, 943-2) 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties General information Appearance: Form: Fluid Colour: Light brown Odour: Characteristic pH-value: Not applicable Change in condition

Melting point/ melting range: < 10oC Boiling point/ boiling range: Undetermined Flash point: > 200oC Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard.

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According to 1907/2006/EC, Article 31 Revision: 01-12-2016 Trade name: PU-D20 B component Explosion limits: Lower: Not determined

Upper: Not determined Vapour pressure at 25oC: < 0.01 hPa Density at 20oC: 1.235 g/cm3 Solubility in/ miscibility with water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water) Not determined. Viscosity: Dynamic at 20oC: 150 mPas Solvent content: Organic solvents: 0.0% Solid content: 100.0% 9.2 Other information No further relevant information available. 10. Stability and reactivity 10.1 Reactivity 10.2 Chemical stability Thermal decomposition/ conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions No dangerous reactions known. 10.4 Conditions to avoid: No further relevant information available. 10.5 Incompatible materials: Oxidizing agents. 10.6 Hazardous decomposition products: No dangerous decomposition products known. 11. Toxicological information 11.1 Information on toxicological effects The product has not been tested. The statements undernaeth have been derived from the properties of the individual components. Acute toxicity: LD/LC 50 values relevant for classification: 9016-87-9 diphenylmethanediisocyanate, isomers and homologues Oral LD50 49000 mg/kg (Rat) Referenz: National Technical Information Service Vol. OTS0516728, Dermal LD50 9400 mg/kg (Rabbit) Referenz: Office of Toxic Substances Report Vol. OTS0517028 LD50, OECD 402 >9400 mg/kg (Rabbit) Inhalative LC50, 4h 0.49 mg/l (Rat) Referenz: National Technical Information Service Vol. OTS0555284 Primary irritant effect: On the skin: Irritant to skin and mucous membranes. On the eye: Irritating effect. Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact.

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According to 1907/2006/EC, Article 31 Revision: 01-12-2016 Trade name: PU-D20 B component Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Harmful Irritant Acute effects (acute toxicity, irritation and corrosivity 9016-87-9 diphenylmethanediisocyanate, isomers and homologues OECD 405, mucosal irritation non-irritant (Rabbit) Toxicological study of a comparable product 12. Ecological information 12.1 Toxicity Aquatic toxicity: 9016-87-9 diphenylmethanediisocyanate, isomers and homologues EC50, 24h > 1000 mg/l (Daphnia magna) EC50, 24h OECD 202 > 1000 mg/l (Daphnia magna) EC50, 3h > 100 mg/l (Activated sludge) EC50, 72h OECD201 > 1640 mg/l (Scenedesmus subspicatus) LC0, 96h > 1000 mg/l (Zebrabärbling) LC50, 96h, OECD203 > 1000 mg/l (Brachydanio rerio (Zebra vis) 12.2 Persistence and degradability: No further relevant information available. 12.3 Bioaccumulative potential: No further relevant information available. 12.4 Mobility in soil: No further relevant information available. Ecotoxical effects: Other information: Ecotoxicological data have not been determined specifically for this product. Information given is based on knowledge of the components and the ecotoxicology of similar products. Additional ecological information: General notes: Not known to be hazardous to water 12.5 Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. 12.6 Other adverse effects No further relevant information available. 13. Disposal considerations 13.1 Waste treatment methods Recommendation: Must not be disposed together with household garbage. Do not allow product to reach sewage system. European waste catalogue Please contact your waste disposer for the exact waste code. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations.

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According to 1907/2006/EC, Article 31 Revision: 01-12-2016Trade name: PU-D20 B component 14. Transport information 14.1 UN-Number ADR, ADN, IMDG, IATA Void 14.2 UN proper shipping name ADR, ADN, IMDG, IATA Void 14.3 Transport hazard class(es) ADR, ADN, IMDG, IATA Class Void 14.4 Packing group ADR, IMDG, IATA Void 14.5 Environmental hazards Marine pollutant: no 14.6 Special precautions for user Not applicable 14.7 Transport in bulk according to Annex II of Marpol73/78 and IBC Code Not applicable UN “Model Regulation”: - 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations: Technical instructions (air):

Class Share in % 1 50 - 100.0

15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16. Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

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According to 1907/2006/EC, Article 31 Revision: 01-12-2016 Trade name: PU-D20 B component Relevant phrases H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organization ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Resp. Sens. 1: Sensitisation - Respirat., Hazard Category 1 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 Carc. 2: Carcinogenicity, Hazard Category 2 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2 Sources Classification corresponds to the current lists of the EEC, is supplemented with data from publications and data from the company. · * Data compared to the previous version altered. DISCLAIMER: Information and details given in this document, particularly any recommendations for application and use of our products are based on careful laboratory tests and prevailing practical experience and are believed to be correct at time of publication. The information is not binding, which is also generally true for our practical customer service, given verbally, in writing and by tests. Due to (possibly varying) conditions of transport, storage, process, substrate use or product application (which are beyond our knowledge and control), we strongly recommend to carry out sufficient tests in order to ensure that our products are suitable for the intended processes and applications. Further, it is the user's obligation to utilize this material with due care, in accordance with the information in the Material Safety Datasheet (and with the information given in any other way by ANR) and in full compliance with health, safety and environmental regulations. Whilst proper care has been taken in the preparation of this document, no liability for damage or injury resulting from its use is accepted, other than the limited liability which may arise towards a contractual party on the basis of ANR’s conditions of sale (a copy of these conditions is available on request). ANR’s acceptance of any orders for this product is expressly conditional upon purchaser’s assent to these conditions of sale. No information contained in this document (nor any information given verbally, in writing and by tests) is to be construed as permission, recommendation or inducement by ANR or its officers, employees or affiliates, to use any product or process so as to infringe upon or conflict with any patent. ANR does not attest or guarantee that the use of its products or processes will not infringe upon any patent; user is responsible for verifying its freedom to operate in any jurisdiction.

Safety Data Sheet According to 1907/2006/EC, Article 31 · Trade name: PU-D20 B component 1.2...

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