SAFETY AND POLLUTION HAZARDS OF CHEMICALS AND …...GESAMP Hazard Profiles amended since the...

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SUB-COMMITTEE ON POLLUTION PREVENTION AND RESPONSE 7th session Agenda item 3

PPR 7/INF.17

13 December 2019 ENGLISH ONLY

Pre-session public release: ☒

SAFETY AND POLLUTION HAZARDS OF CHEMICALS AND PREPARATION OF

CONSEQUENTIAL AMENDMENTS TO THE IBC CODE

Information supporting a review of the products listed in the MEPC.2/Circular

Note by the Secretariat

SUMMARY

Executive summary: This document contains an overview of products that have had their GESAMP Hazard Profiles amended since the adoption of the 2004 amendments to the IBC Code (resolutions MEPC.119(52) and MSC.176(79)), products that currently only have a pollution (P) hazard rating in chapter 17 of the IBC Code, but have been assigned an additional safety (S) hazard rating in the 2019 amendments to the IBC Code, and products assigned to List 2 of the MEPC.2/Circular that have a component with a safety hazard in the contains name

Strategic direction, if applicable:

6

Output: 6.3

Action to be taken: Paragraph 5

Related documents: PPR 1/Circ.6, PPR 7/3 and MEPC.2/Circ.25

Introduction

1 The 2019 amendments to the IBC Code were adopted as resolutions MEPC.318(74) and MSC.460(101) and are expected to enter into force 1 January 2021. These amendments include a complete revision of the carriage requirements for all products listed in chapters 17 and 18 of the IBC Code, following their assessment in accordance with chapter 21 of the IBC Code.

PPR 7/INF.17


2 During the twenty-fifth session of the PPR Working Group on the Evaluation of Safety and Pollution Hazards of Chemicals (ESPH 25), the Working Group discussed how to review the products in Lists 2 and 3 of the MEPC.2/Circular (PPR 7/3, paragraphs 6.1 to 6.8) in order to ensure that the carriage requirements are assigned using the most up-to-date GESAMP Hazard Profiles and the revised Criteria for assigning carriage requirements for products subject to the IBC Code (chapter 21 of the IBC Code). 3 In this context, the Group noted it was important to shorten the Lists of products in the MEPC.2/Circular and discussed possible approaches on how to achieve that. As a way forward, in order to identify products that should have had their carriage requirements updated since they were included in the MEPC.2/Circular, the Group requested the Secretariat to submit to PPR 7 or ESPH 26 an overview of the GESAMP Hazard Profiles that have been amended since the 2004 amendments to the IBC Code and a list of the products that currently only have a pollution (P) hazard rating but have been assigned an additional safety (S) hazard rating in the 2019 amendments to the IBC Code. 4 To that end, the following information is provided in the annexes to this document:

.1 in annex 1 there is a list of products that have had their GESAMP Hazard Profiles amended since the 2004 amendments to the IBC Code (resolutions MEPC.119(52) and MSC.176(79));

.2 in annex 2 there is a list of the products that currently have a pollution (P)

only hazard rating in chapter 17 or 18 of the IBC Code or are "Other Substances" (OS) in chapter 18 of the IBC Code, but have been assigned an additional safety (S) hazard rating in the 2019 amendments to the IBC Code; and

.3 in annex 3 there is a list of products in list 2 (pollution hazards only) of the

MEPC.2/Circular that have a component with a safety hazard in the contains name.

Action requested of the Sub-Committee

5 The Sub-Committee is invited to note the information contained in this document and take action as appropriate.

***

PPR 7/INF.17 Annex 1, page 1


ANNEX 1

GESAMP HAZARD PROFILES THAT HAVE BEEN AMENDED SINCE THE ADOPTION OF THE 2004 AMENDMENTS TO THE IBC CODE

TRN Name EHS Name

Tetrachloroethane 1,1,2,2-Tetrachloroethane

Propylene glycol 1,2-Propylene glycol

1,2,3-Trichloropropan 1,2,3-Trichloropropan

1,2-Butylene oxide 1,2-Butylene oxide

1,2-Dichloropropane 1,2-Dichloropropane

1,3-Cyclopentadiene dimer (molten) 1,3-Cyclopentadiene dimer (molten)

1,3-Pentadiene 1,3-Pentadiene

Glutaraldehyde solutions (50% or less) 1,5-Pentanedial solution, (5-50%)

1,5,9-Cyclododecatriene 1,5,9-Cyclododecatriene

1,6-Dichlorohexane 1,6-Dichlorohexane

1,6-Hexanediol, distillation overheads 1,6-Hexanediol, distillation overheads

1-Dodecene 1-Dodecene

1-Heptanol 1-Heptanol

1-Nitropropane 1-Nitropropane

2,2,4-Trimethyl-1,3-pentanediol diisobutyrate


2,4-Dichlorophenol 2,4-Dichlorophenol

2,4-Dichlorophenoxyacetic acid, triisopropanolamine salt solution

2,4-Dichlorophenoxyacetic acid, triisopropanolamine salt soln.

2,4-Dichlorophenoxyacetic acid, diethanolamine salt solution

2,4-Dichlorophenoxyacetic acid, diethanolamine salt, solution

Toluenediamine 2,4-Tolylenediamine

2,6-Diaminohexanoic acid phosphonate mixed salts solution

2,6-Diaminohexanoic acid phosphonate mixed salts solution

2-Ethyl-3-propylacrolein 2-Ethyl-3-propylacrolein

2-Ethylhexanoic acid 2-Ethylhexanoic acid

tert-Amyl alcohol 2-Methyl-2-butanol

2-Methyl-5-ethyl pyridine 2-Methyl-5-ethylpyridine

2-Nitropropane 2-Nitropropane

2-Propene-1-aminium, N,N-dimethyl-N-2-propenyl-, chloride, homopolymer

2-Propene-1-aminium, N,N-dimethyl-N-2-propenyl-, chloride, homopolymer (aqueous solution)

2-Propenoic acid polymer with furandione (65% in 2-butoxyethanol)

2-Propenoic acid polymer with furandione (65% in 2-butoxyethanol)

3-(methylthio)propionaldehyde 3-(Methylthio) propionaldehyde

4-Methylpyridine 4-Methylpyridine

Acrylic acid / dimethyldiallylammonium chloride copolymer, partial sodium salt (MWt 1500-4000, aqueous solution)

Acrylic acid / dimethyldiallylammonium chloride copolymer, partial sodium salt (MWt 1500-4000, aqueous solution)

Acrylic acid/ethenesulphonic acid copolymer with phosphonate groups, sodium salt solution

Acrylic acid/ethenesulphonic acid copolymer with phosphonate groups, sodium salt (aqueous solution)

Acrylonitrile Acrylonitrile

Alkyl (C10-C15, C12 rich) phenol poly(4-12)ethoxylate

Alkyl (C10-C15, C12 rich) phenol poly(4-12)ethoxylate

Alkyl (C12+) dimethylamine Dodecyl-, Tetradecyl-, Hexadecyl-dimethylamine mixture



TRN Name EHS Name

Alkyl (C7-C9) nitrates Alkyl (C7-C9) nitrates

Alkyl(C8+)amine, Alkenyl (C12+) acid ester mixture

Alkyl amine, alkenyl acid ester, mixture

Alkylbenzenes mixture (containing less than 1% naphthalene)

Alkylbenzenes mixture (containing less than 1% naphthalene)

Alkylbenzenes mixtures (containing naphthalene)

Alkylbenzenes mixtures (containing naphthalene)

Allyl alcohol Allyl alcohol

Alpha-Pinene Alpha-Pinene

Aluminium chloride (30% or less)/hydrochloric acid (20% or less) solution

Aluminium chloride/hydrogen chloride solution

Ammonium hydrogen phosphate solution Diammonium hydrogen phosphate

Ammonium polyphosphate solution Ammonium polyphosphate solution

Benzene sulphonyl chloride Benzene sulphonyl chloride

Beta-Pinene Beta-Pinene

Butyl acetate (all isomers) Butyl acetate

Butyl benzyl phthalate Butyl benzyl phthalate

Butyl butyrate (all isomers) Butyl butyrate

Butyl octyl phthalate Butyl octyl phthalate

Butyl stearate Butyl stearate

3-Methoxy-1-butanol Butylene glycol monomethyl ether

Butyric acid Butyric acid

Drilling brines (containing calcium bromide Calcium bromide (solutions)

Calcium carbonate slurry Calcium carbonate slurry

Calcium hydroxide slurry Calcium hydroxide

Calcium hypochlorite solution (15% or less) Calcium hypochlorite solutions containing less than 15% but more than 1.5% Ca(OCl)2

Calcium hypochlorite solution (more than 15%)

Calcium hypochlorite solutions containing 15% Ca(Ocl)2 or more

epsilon-Caprolactam (molten or aqueous solutions)

Caprolactam

Carbon disulphide Carbon disulphide

Cashew nut shell oil (untreated) Cashew nut shell oil (untreated)

Castor oil Castor oil (containing less than 10% free fatty acids)

Chlorobenzene Chlorobenzene

Chlorosulphonic acid Chlorosulphonic acid

Coal tar pitch (molten) Coal tar pitch (molten)

Coconut oil Coconut oil

Coconut oil fatty acid Coconut oil fatty acid

Cotton seed oil Cotton seed oil

Creosote (coal tar) Creosote (coal tar)

Cresols (all isomers) Cresols (mixed isomers)

Crotonaldehyde Crotonaldehyde

Cyclohexanone Cyclohexanone

Cyclopentene Cyclopentene

Decahydronaphthalen Decahydronaphthalen

Decyl acrylate Decyl acrylate

Di-(2-ethylhexyl) phthalate Di-(2-ethylhexyl) phthalate

Di-(2-ethylbutyl) phthalate Di-(2-ethylbutyl) phthalate

Di-(2-ethylhexyl) phthalate Di-(2-ethylhexyl) phthalate



TRN Name EHS Name

Dialkyl phthalates C9-C13 Dialkyl (C7-C13) phthalates

Dialkyl (C9 – C10) phthalates Dialkyl (C9 – C10) phthalates

Dibromomethane Dibromomethane

Di-n-butyl phthalate Dibutyl phthalate

Dichloropropene/Dichloropropane mixture Dichloropropane and dichloropropene, mixtur

Diethyl phthalate Diethyl phthalate

Diethyl sulphate Diethyl sulphate

Diethylene glycol diethyl ether Diethylene glycol diethyl ether

Diheptyl phthalate Diheptyl phthalate

Dihexyl phthalate Di-hexyl phthalate

Diisobutyl phthalate Diisobutyl phthalate

Diisobutylamine Diisobutylamine

Diisodecyl phthalate Diisodecyl phthalate

Diisoheptyl phthalate Diisoheptyl phthalate

Diisononyl phthalate Diisononyl phthalate

Diisooctyl phthalate Diisooctyl phthalate

Isopropyl ether Diisopropyl ether

Dimethyl adipate Dimethyl adipate

Dimethyl glutarate Dimethyl glutarate

Dimethyl phthalate Dimethyl phthalate

Dinonyl phthalate Dinonyl phthalate

Di-n-propyl phthalate Di-n-propyl phthalate

Dioctyl phthalate Di-n-octyl phthalat

Diphenyl Diphenyl

Diphenylmethane diisocyanate Diphenylmethane-4,4'-diisocyanate

Dipropylene glycol Dipropylene glycol

Dipropylene glycol dibenzoate Dipropylene glycol dibenzoate

Ditridecyl phthalate Ditridecyl phthalate

Diundecyl phthalate Diundecyl phthalate

Dodecene (all isomers) Dodecene (all isomers)

Dodecyl phenol Dodecyl phenol

Dodecylamine/tetradecylamine mixture Dodecylamine/tetradecylamine mixture

1,3,5-Hexahydrotriethanol-1,3,5-triazine solution

Ethanoltriazine (aqueous solution)

Ethoxylated long chain (C16+) alkyloxyalkylamine

Ethoxylated long chain (>C16)alkyloxyalkanamine (LOA)

Ethoxylated tallow amine (>95%) Ethoxylated tallow amine (>95%)

Ethyl 3-ethoxypropionate Ethyl 3-ethoxypropionate

Ethyl acrylate Ethyl acrylate

Ethyl tert-butyl ether Ethyl tert-butyl ether

Ethylbenzene Ethylbenzene

Ethylcyclohexane Ethyl cyclohexane

Ethylene glycol Ethylene glycol

Ethylene glycol (>75%)/Sodium alkyl carboxylates/borax mixture

Ethylene glycol (>75%)/Sodium alkyl carboxylates/borax mixture #)

Ethylene glycol (>85%)/Sodium alkyl carboxylates mixture

Ethylene glycol (>85%)/Sodium alkyl carboxylates mixture

Ethylene glycol butyl ether acetate Ethylene glycol butyl ether acetate

2-Ethoxyethyl acetate Ethylene glycol ethyl ether acetate

Ethylene glycol methyl ether acetate Ethylene glycol methyl ether acetate



TRN Name EHS Name

Ethylene glycol acetate Ethylene glycol monoacetate

2-Ethoxyethanol Ethylene glycol monoethyl ether

Ethylene glycol phenyl ether Ethylene glycol phenyl ether

Ethylene vinyl acetate copolymer (emulsion) Ethylene vinyl acetate copolymer (emulsion)

Fatty acids, (C8-C10) Fatty acids saturated, C8-C10

Fatty acids, (C12+) Fatty acids, linear C12+ saturated with C12+ unsaturated

Fatty acids, linear, C8-C18 saturated with C18 unsaturated

Fatty acids, (C8-C18)

Fish by-products (fresh) Fish by-products (fresh)

Fish oil Fish oil (containing less than 10% free fatty acids)

Fish silage (containing 3% or less formic acid with antioxidant)

Fish silage (containing 3% or less formic acid with antioxidant

Fish silage protein concentrate (containing 4% or less formic acid)

Fish silage protein concentrate (containing 4% or less formic acid)

Fluorosilicic acid solution (20-30%) Fluorosilicic acid solution (20-30%)

Fumaric adduct of Rosin, water dispersion Fumaric adduct of rosin (water dispersion)

Furfuryl alcohol Furfuryl alcohol

Glucitol/glycerol blend propoxylated (containing 10% or more amines)

Glucitol/glycerol blend propoxylated (containing 10% or more amines)

Glycerol ethoxylated Glycerol ethoxylated

Glycerol monooleate Glycerol monooleate

Groundnut oil Groundnut oil

n-Heptanoic acid Heptanoic acid

Heptyl acetate Heptyl acetate

Hexamethyleneimine Hexamethyleneimine

Waxes (Hydrocarbon waxes)1 Hydrocarbon wax

Iso-and cyclo-alkanes (C12+) Iso-and cyclo-alkanes (C12+)

Isophorone diisocyanate Isophorone diisocyanate

Isoprene Isoprene

Lactonitrile solution (80% or less) Lactonitrile solution (80% or less)

Lard Lard (containing less than 10% free fatty acids)

Latex, ammonia (1% or less)- inhibited Latex, ammonia inhibited

Dodecyl methacrylate Lauryl methacrylate

Alkyl(C12-C16) propoxyamine ethoxylate Linear alkyl (C12-16) propoxyamine ethoxylate

Linseed oil Linseed oil (containing less than 4% free fatty acids)

Maltitol solution Maltitol Syrup

m-Chlorotoluene m-Chlorotoluene

Metam sodium solution Metam-sodium (ISO)

Methacrylonitrile Methacrylonitrile

Methyl alcohol Methanol

Methyl acrylate Methyl acrylate

Methyl butyl ketone Methyl butyl ketone

Methyl propyl ketone Methyl propyl ketone

Methyl salicylate Methyl salicylate

1 This product has been renamed and the new TRN name is included in brackets. EHS name correspond to

the renamed product.



TRN Name EHS Name

2-Methyl-2-hydroxy-3-butyne Methylbutynol

Methylene bisthiocyanate Methylene dithiocyanate

Microsilica slurry Silica slurry

N,N-Dimethyldodecylamine N,N-Dimethyldodecylamine

n-Alkanes (C9-C11) n-Alkanes (C9-C11)

Nitric acid (less than 70%) Nitric acid (90% or less)

Nitric acid (70% and over) Nitric acid (90% or less)

Nonane (all isomers) Nonane

Nonylphenol Nonyl phenol

Chlorotoluenes (mixed isomers) o-Chlorotoluene

Olefins (C13+, all isomers) Olefins C13 and above, all isomers

Olive oil Olive oil

Palm kernel acid oil Palm nut oil fatty acid

Palm kernel fatty acid distillate Palm kernel fatty acid distillate

Palm kernel oil Palm nut oil

Palm oil Palm oil (containing less than 15% free fatty acids)

Palm olein Palm olein

Palm stearin Palm stearin

Paraffin wax (Paraffin wax, highly-refined)2 Paraffin wax, highly-refined

p-Chlorotoluene p-Chlorotoluene

Petrolatum (Paraffin wax, semi-refined)2 Paraffin wax, semi-refined

Phosphoric acid Phosphoric acid

Poly(tetramethylene ether) glycol (mw 600-3000)

Poly(tetramethylene ether) glycol (mw 600-3000)

Polyalkyl (C18-C22) acrylate in xylene Poly(C18-C22)alkyl acrylate in xylene

Polyether (molecular weight 1350+) Polyether (molecular weight 2000+) (LOA)

Polyethylene polyamines (more than 50% C5 -C20 paraffin oil)

Polyethylene amines / paraffin mixtures

Polyethylene polyamines Polyethylene polyamines

olefin amide alkeneamine polyol Polyolefin amide alkylene amine polyol

Poly(20)oxyethylene sorbitan monooleate Polyoxyethylene sorbitan monooleate

Propylene oxide Propylene oxide

Pyridine Pyridine

Rapeseed oil Rapeseed oil (high erucic acid; containing less than 4% free fatty acids)

Sodium aluminate solution Sodium aluminate (solution)

Sodium carbonate solution Sodium carbonate

Sodium dichromate solution (70% or less) Sodium dichromate solution

Sodium hydrogen sulphide (6% or less)/sodium carbonate (3% or less) solution

Sodium hydrogen sulphide (6% or less)/sodium carbonate (3% or less)

Sodium hydrosulphide solution (45% or less) Sodium hydrogen sulphide, solutions

Sodium hydrosulphide/Ammonium sulphide solution

Sodium hydrogen sulphide/Ammonium sulphide(mixture)

No registered TRN Name Sodium hydroxide (30% or less)/Sodium aluminate (25% or less) solution

Soyabean oil Soyabean oil (containing less than 4% free fatty acids)

Sulphuric acid Sulphuric acid





TRN Name EHS Name

Sunflower seed oil Sunflower oil

Dichloroethyl ether sym-Dichlorodiethyl ether

Tall oil (crude and distilled) Tall oil, crude and distilled

Tall oil crude Crude Tall Oil

Tall oil fatty acid (resin acids less than 20%) Tall oil fatty acid (resin acids less than 20%)

Tall oil pitch Tall oil pitch

Tallow Tallow

tert-Amyl methyl ether tert-Amyl methyl ether

Tert-Dodecanethiol Tert-Dodecanethiol

Titanium dioxide (64 – 77% solution in water) Titanium dioxide slurry

Toluene diisocyanate Toluene diisocyanate

Triethylene glycol Triethylene glycol

Trimethylacetic acid Trimethylacetic acid

Tripropylene glycol Tripropylene glycol

Trixylyl phosphate Trixylenyl phosphate

Tung oil Tung oil

Urea/Ammonium nitrate solution Urea/Ammonium nitrate solution (containing < 1% aq. Ammonia)

Vegetable protein solution (hydrolysed) Vegetable protein solution,hydrolyzed

Vinyl ethyl ether Vinyl ethyl ether

Waxes (Hydrocarbon wax)3 Hydrocarbon wax

Xylenol Xylenols (mixtures)

***



PPR 7/INF.17

Annex 2, page 1


ANNEX 2

PRODUCTS THAT HAVE CHANGED FROM "P" TO "S/P" IN COLUMN D OF THE 2019 AMENDMENTS TO THE IBC CODE (RESOLUTIONS MEPC.318(74) AND MSC.460(101))

Product name in the IBC Code:

Acetochlor

Alcohol (C9-C11) poly (2.5-9) ethoxylate

Alcohol (C6-C17) (secondary) poly(3-6) ethoxylates

Alcohol (C6-C17) (secondary) poly(7-12) ethoxylates

Alcohol (C12-C16) poly(1-6) ethoxylates

Alcohol (C12-C16) poly(20+) ethoxylates

Alcohol (C12-C16) poly(7-19) ethoxylates

Alkanes (C6-C9)

Iso- and cyclo-alkanes (C10-C11)

Iso- and cyclo-alkanes (C12+)

Alkaryl polyethers (C9-C20)

Alkenyl (C11+) amide

Alkyl acrylate/vinylpyridine copolymer in toluene

Alkyl (C3-C4) benzenes

Alkyl (C5-C8) benzenes

Alkyl (C9+)benzenes

Alkyl (C11-C17) benzene sulphonic acid

Alkyl (C8-C10)/(C12-C14):(40% or less/60% or more) polyglucoside solution (55% or less)

Alkyl (C8-C10)/(C12-C14):(60% or more/40% or less) polyglucoside solution(55% or less)

Alkyl (C7-C11)phenol poly(4-12) ethoxylate

Alkyl (C8-C40) phenol sulphide

Alkyl (C8-C9) phenylamine in aromatic solvents

Alkyl (C9-C15) phenyl propoxylate

Alkyl (C8-C10) polyglucoside solution (65% or less)

Alkyl (C8-C10)/(C12-C14):(50%/50%) polyglucoside solution (55% or less)

Alkyl (C12-C14) polyglucoside solution (55% or less)

Aluminium sulphate solution

2-Amino-2-methyl-1-propanol

Ammonium thiosulphate solution (60% or less)

Amyl acetate (all isomers)

n-Amyl alcohol

Amyl alcohol, primary

sec-Amyl alcohol

tert-Amyl alcohol

tert-Amyl methyl ether

Aviation alkylates (C8 paraffins and iso-paraffins BPT 95 - 120°C)

Benzenetricarboxylic acid, trioctyl ester

Benzyl acetate

Benzyl alcohol

Butylbenzene (all isomers)

Butyl benzyl phthalate

Butyl butyrate (all isomers)

Butylene glycol

gamma-Butyrolactone




Calcium hydroxide slurry

Calcium lignosulphonate solutions

Calcium long-chain alkyl (C11-C40) phenate

Calcium long-chain alkyl salicylate (C13+)

Calcium nitrate solutions (50% or less)

Calcium nitrate/Magnesium nitrate/Potassium chloride solution

epsilon-Caprolactam (molten or aqueous solutions)

Chlorinated paraffins (C10-C13)

Chlorinated paraffins (C14-C17) (with 50% chlorine or more, and less than 1% C13 or shorter chains)

4-Chloro-2-methylphenoxyacetic acid, dimethylamine salt solution

1-(4-Chlorophenyl)-4,4- dimethyl-pentan-3-one

Citric acid (70% or less)

Cycloheptane

Cyclohexane

Cyclohexyl acetate

1,3-Cyclopentadiene dimer (molten)

Cyclopentene

p-Cymene

Decahydronaphthalene

Decanoic acid

Diacetone alcohol

Dialkyl (C7-C13) phthalates

Dibutyl hydrogen phosphonate

2,6-Di-tert-butylphenol

Dibutyl phthalate

Diethylbenzene

Diethylene glycol

Diethylene glycol diethyl ether

Diethylene glycol phthalate

Di-(2-ethylhexyl) adipate

Diethyl phthalate

Diglycidyl ether of bisphenol A

Diglycidyl ether of bisphenol F

Diheptyl phthalate

Di-n-hexyl adipate

Dihexyl phthalate

Diisobutyl ketone

Diisobutyl phthalate

Diisononyl adipate

Diisooctyl phthalate

Diisopropylbenzene (all isomers)

Diisopropylnaphthalene

Dimethyl glutarate

Dimethyl octanoic acid

Dimethyl phthalate

Dinonyl phthalate

Dioctyl phthalate

Dipentene

Diphenyl

Diphenylamine (molten)

PPR 7/INF.17

Annex 2, page 3



Diphenylamines, alkylated

Diphenyl/Diphenyl ether mixtures

Diphenylol propane-epichlorohydrin resins

Dithiocarbamate ester (C7-C35)

Diundecyl phthalate

Dodecane (all isomers)

Dodecene (all isomers)

Dodecyl alcohol

Dodecylbenzene

Dodecyl phenol

Dodecyl Xylene

Drilling brines (containing calcium bromide)

Drilling brines (containing zinc chloride)

2-Ethoxyethyl acetate

Ethyl acetate

Ethyl acetoacetate

Ethyl amyl ketone

Ethylbenzene

Ethyl tert-butyl ether

Ethyl butyrate

Ethylcyclohexane

S-Ethyl dipropylthiocarbamate

Ethylene carbonate

Ethylene glycol

Ethylene glycol acetate

Ethylene glycol butyl ether acetate

Ethylene glycol diacetate

Ethylene glycol methyl ether acetate

Ethylene glycol phenyl ether

Ethylene glycol phenyl ether/Diethylene glycol phenyl ether mixture

Ethylene-vinyl acetate copolymer (emulsion)

2-Ethylhexanoic acid

Ethyl propionate

Fatty acid (saturated C13+)

Fatty acids, essentially linear (C6-C18) 2-ethylhexyl ester

Formamide

Furfuryl alcohol

Glycerine

Glycerol monooleate

Glyceryl triacetate

Glycidyl ester of C10 trialkylacetic acid

Glycine, sodium salt solution

Glyoxal solution (40% or less)

Glyphosate solution (not containing surfactant)

n-Heptanoic acid

Heptanol (all isomers) (d)

Heptyl acetate

1-Hexadecylnaphthalene / 1,4-bis(hexadecyl)naphthalene mixture

Hexamethylene glycol

Hexamethylenetetramine solutions




Hexane (all isomers)

1,6-Hexanediol, distillation overheads

Hexanoic acid

Hexanol

Hexene (all isomers)

Hexyl acetate

Hexyl acetate

Hexylene glycol

N-(Hydroxyethyl)ethylenediaminetriacetic acid, trisodium salt solution

2-Hydroxy-4-(methylthio)butanoic acid

Isoamyl alcohol

Isobutyl alcohol

Isobutyl methacrylate

Lactic acid

Latex: Carboxylated styrene-Butadiene copolymer; Styrene-Butadiene rubber

Lauric acid

Long-chain alkaryl polyether (C11-C20)

Long-chain alkaryl sulphonic acid (C16-C60)

Long-chain alkylphenate/Phenol sulphide mixture

Magnesium hydroxide slurry

Magnesium long-chain alkaryl sulphonate (C11-C50)

Magnesium long-chain alkyl salicylate (C11+)

3-Methoxy-1-butanol

3-Methoxybutyl acetate

N-(2-Methoxy-1-methyl ethyl)-2-ethyl-6-methyl chloroacetanilide

Methyl acetoacetate

Methyl alcohol

Methylamyl alcohol

Methyl amyl ketone

Methylbutenol

Methyl butyl ketone

Methylbutynol

Methyl butyrate

Methylcyclohexane

Methylcyclopentadiene dimer

Methyl ethyl ketone

Methyl isobutyl ketone

N-Methylglucamine solution (70% or less)

3-Methyl-3-methoxybutanol

Methyl propyl ketone

N-Methyl-2-pyrrolidone

Methyl salicylate

Myrcene

Naphthalenesulphonic acid-Formaldehyde copolymer, sodium salt solution

Neodecanoic acid

Nitrilotriacetic acid, trisodium salt solution

Nonane (all isomers)

Nonanoic acid (all isomers)

Nonyl methacrylate monomer

Nonylphenol

Nonylphenol poly(4+)ethoxylate

PPR 7/INF.17

Annex 2, page 5



Octamethylcyclotetrasiloxane

Octanoic acid (all isomers)

Octanol (all isomers)

n-Octyl acetate

Octyl aldehydes

Octyl decyl adipate

Olefin mixtures (C5-C7)

Olefin mixtures (C5-C15)

alpha-Olefins (C6-C18) mixtures

Oleic acid

Pentanoic acid

n-Pentyl propionate

1-Phenyl-1-xylyl ethane

Phosphate esters, alkyl (C12-C14) amine

alpha-Pinene

beta-Pinene

Pine oil

Polyalkyl (C18-C22) acrylate in xylene

Polyaluminium chloride solution

Poly(2+)cyclic aromatics

Polyethylene glycol dimethyl ether

Polyisobutenamine in aliphatic (C10-C14) solvent

Polyisobutenyl anhydride adduct

Polyglycerin, sodium salt solution (containing less than 3% sodium hydroxide)

Polyolefin amide alkeneamine (C17+)

Polyolefinamine (C28-C250)

Polyolefinamine in alkyl (C2-C4) benzenes

Polyolefinamine in aromatic solvent

Polyolefin aminoester salts (molecular weight 2000+)

Polyolefin anhydride

Polyolefin phenolic amine (C28-C250)

Potassium oleate

Potassium formate solutions

Potassium thiosulphate (50% or less)

n-Propyl alcohol

Propylene carbonate

Propylene glycol phenyl ether

Propylene tetramer

Propylene trimer

Rape seed oil fatty acid methyl esters

Rosin

Sodium alkyl (C14-C17) sulphonates (60-65% solution)

Sodium benzoate

Sodium carbonate solution

Sodium hydrogen sulphide (6% or less)/Sodium carbonate (3% or less) solution

Sodium poly(4+)acrylate solutions

Sodium silicate solution

Sodium sulphate solutions

Sodium sulphite solution (25% or less)

Sodium thiocyanate solution (56% or less)




Sulpholane

Sulphurized fat (C14-C20)

Tetrahydronaphthalene

Tetramethylbenzene (all isomers)

Toluene

Tributyl phosphate

Tridecane

Tridecanoic acid

Tridecyl acetate

Triethylbenzene

Triethyl phosphate

Triisopropanolamine

Trimethylbenzene (all isomers)


Trixylyl phosphate

Turpentine

Undecanoic acid

1-Undecene

Undecyl alcohol

Urea/Ammonium phosphate solution

Urea solution

White spirit, low (15-20%) aromatic

Xylenes/ethylbenzene (10% or more) mixture

Zinc alkenyl carboxamide

***

PPR 7/INF.17

Annex 3, page 1


ANNEX 3

PRODUCTS IN LIST 2 OF THE MEPC.2/CIRCULAR THAT HAVE A COMPONENT WITH A SAFETY HAZARD IN THE CONTAINS NAME

Trade name Component with a safety hazard Representative country and company

Anglamol 99 Oleylamine USA (Lubrizol)

ASH 1925 ISO- AND CYCLO-ALKANES (C12+)

ZAF (PetroSA)

ASH 2636 ISO- AND CYCLO-ALKANES (C12+)

ZAF (PetroSA)

ASH-H ISO- AND CYCLO-ALKANES (C12+)

ZAF (PetroSA)

ASH-M ISO- AND CYCLO-ALKANES (C12+)

ZAF (PetroSA)

9/C10 AROMATICS Trimethylbenzene (all isomers) GBR (SABIC (UK))

CAN 17 Ammonium nitrate solution (93% or less)

NOR (Yara International S. A.)

CELANESE MAM BLEND

Dodecyl alcohol USA (Celanese)

CF 2000 Iso- and cyclo-alkanes (C10-C11) BEL (ExxonMobil)

CF 2100 ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

CFX 2000 ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

CFX 2100 Iso- and cyclo-alkanes (C10-C11) BEL (ExxonMobil)

CN9 Ammonium nitrate solution (93% or less)

NOR (Yara International S. A.)

EC6359A [[(2-hydroxyethyl)imino]dimethylene]bisphosphonic acid, sodium salt

USA (Nalco)

COROL 24 Dodecyl alcohol JPN (Ecogreen)

EPF S20 Alkanes (C6-C9) SGP (ExxonMobil)

Epikote TN 1001-X-75

Diphenylol propane-epichlorohydrin resins

NDL (Hexion Spec. Ch. BV)

Escaid 100 Alkyl (C5-C8) benzenes BEL (ExxonMobil)

Escaid 110 ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

Escaid 110 Special Fluid

ISO- AND CYCLO-ALKANES (C12+)

SGP (ExxonMobil)

Escaid 120 ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

Escaid 120ULA ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

Escaid 120ULA (H) ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

Exxal 7 Alcohol Heptanol (all isomers) USA (ExxonMobil)

Exxal 8 Alcohol Octanol (all isomers) USA (ExxonMobil)

Exxal 9 Alcohol Nonyl alcohol (all isomers) NDL (ExxonMobil)

Exxal 12 Alcohol Undecyl alcohol USA (ExxonMobil)

Exxal L9 Alcohol Nonyl alcohol (all isomers) USA (ExxonMobil)




Exx-Print M 75 A ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

EXX-Print M74 A-S ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

Exx-Print M79D ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

Exx-Print T 76 A ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

Exx-Print T 82A ISO- AND CYCLO-ALKANES (C12+)

BEL (ExxonMobil)

Exxsol D 30 Alkanes (C6-C9) BEL (ExxonMobil)

Exxsol D 40 Alkanes (C6-C9) BEL (ExxonMobil)

Exxsol D 60 Iso- and Cyclo- Alkanes (C10-C11) BEL (ExxonMobil)

Exxsol D 80 Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)


Exxsol D 130 Fluid Iso- and Cyclo- Alkanes (C12+) SGP (ExxonMobil)


Exxsol D 180/200 SP

Iso- and Cyclo- Alkanes (C10-C11) BEL (ExxonMobil)

Exxsol D 220/230 Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)

Exxsol D60(S) Iso- and Cyclo- Alkanes (C12+) SGP (ExxonMobil)

Exxsol D95 Iso- and Cyclo- Alkanes (C12+) SGP (ExxonMobil)

Exxsol D100 Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)

Exxsol D100 ULA (formerly Exxsol D100 S)

Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)

Exxsol D110 Alkyl (C5-C8) benzenes SGP (ExxonMobil)

Exxsol DSP 60/95 S Alkanes (C6-C9) BEL (ExxonMobil)

Exxsol DSP 60/95 SH

Alkanes (C6-C9) BEL (ExxonMobil)

Exxsol DSP 145/160

Alkanes (C6-C9) BEL (ExxonMobil)

FORSA™ SCW88003 SCALE INHIBITOR

[[(Phosphonomethyl)imino]bis [ethylenenitrilobis(methylene)]] tetrakisphosphonic acid, ammonium salt solution (60% or less)

GBR (Baker Hughes)

HAN 8070 Alkyl (C5-C8) benzenes BEL (ExxonMobil)

HAN 8572 Poly(2+)cyclic aromatics BEL (ExxonMobil)

HITEC 6561 Dodecene (all isomers) USA (Afton)

Isopar G Iso- and Cyclo- Alkanes (C10-C11) BEL (ExxonMobil)

Isopar H Iso- and Cyclo- Alkanes (C10-C11) BEL (ExxonMobil)

Isopar L Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)

Isopar L (E) Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)

ISOPAR L AP Iso- and Cyclo- Alkanes (C12+) SGP (ExxonMobil Chemical)

Isopar M Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)

Isopar N Iso- and Cyclo- Alkanes (C12+) GBR) ExxonMobil

KALCOL 1260 Dodecyl alcohol MYS (Fatty Chemical (MYS))

KALCOL 2465 Dodecyl alcohol USA (Fatty Chemical (MYS))

KALCOL 2470 Dodecyl alcohol USA (Fatty Chemical (MYS))

PPR 7/INF.17

Annex 3, page 3



KemSweep NLP 5000

Iso- and Cyclo- Alkanes (C12+) GBR (Kemira)

LINEVOL 911 Undecyl alcohol USA (Shell)

Lubrizol 3700D Alkenyl (C11+) amide USA (Lubrizol)

Lubrizol 6950J Alkenyl (C11+) amide USA (Lubrizol)

Lubrizol 9222K Calcium long-chain alkyl phenate sulphide (C8-C40)

USA (Lubrizol)

Lubrizol 9297 Calcium long-chain alkyl phenate sulphide (C8-C40)

USA (Lubrizol)

Lubrizol 9297J Calcium long-chain alkyl phenate sulphide (C8-C40)

USA (Lubrizol)

Lubrizol 9827R Alkenyl (C11+) amide USA (Lubrizol)

Lubrizol 16012 Alkenyl (C11+) amide USA (Lubrizol)






Lubrizol 79023 Calcium long-chain alkyl phenate sulphide (C8-C40)

USA (Lubrizol)

Lubrizol A99 Oleylamine USA (Lubrizol)

Lubrizol PV1127 Alkenyl (C11+) amide USA (Lubrizol)

MISC16443A Methanol USA (NALCO Champion)

MOSSPAR 1925 Iso- and Cyclo- Alkanes (C12+) ZAF (PetroSA)

MOSSPAR 2636 Iso- and Cyclo- Alkanes (C12+) ZAF (PetroSA)

MOSSPAR H Iso- and Cyclo- Alkanes (C12+) ZAF (PetroSA)

MOSSPAR M Iso- and Cyclo- Alkanes (C12+) ZAF (PetroSA)

MOSSTANOL 120 n-Propyl alcohol ZAF (PetroSA)

MOSSTANOL P Cyclopentanol4 ZAF (PetroSA)

Nappar 10 Alkanes (C6-C9) BEL (ExxonMobil)

Neodol 24 Dodecyl alcohol USA (Shell)

Neodol 25 Dodecyl alcohol USA (Shell)

Neodol 91 Undecyl alcohol USA (Shell)

Neodol 135 Undecyl alcohol USA (Shell)

NESSOL 40 White spirit, low (15-20%) aromatic FIN (Neste)

NESSOL 60 White spirit, low (15-20%) aromatic FIN (Neste)

NESSOL D40 Iso- and Cyclo- Alkanes (C10-C11) FIN (Neste)



NESSOL D100 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)

NESSOL D100+ Iso- and Cyclo- Alkanes (C12+) FIN (Neste)

NEXBASE 3015 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)

NEXBASE®3020 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)






4 Does not have a GESAMP Hazard Profile.




NExTAME Olefin mixtures (C5-C15) FIN (Neste)

Octimise G2003 Solvent naphtha2 BEL (Innospec)

Octimise G2048 Alkyl (C3-C4) benzenes BEL (Innospec)

OLOA 219M Calcium long-chain alkyl phenate sulphide (C8-C40)

USA (Chevron Oronite)

OLOA 219U Calcium long-chain alkyl phenate sulphide (C8-C40)

USA (Chevron Oronite)

OrePrep F-597 Frother

1,6-Hexanediol, distillation overheads

USA (CYTEC)

Petrinex T9 Naphthalene GBR (SABIC (UK))

PHASETREAT 7623

Ethylene glycol monoalkyl ethers NOR (Clariant Oil Services Scandinavia AS)

PROP BH n-Propyl alcohol ZAF (SASOL)

R097671A lkenyl (C11+) amide USA (Lubrizol)

R-50428 Ethylene glycol USA (North American Shipbuilding)

RM 50141 Propylene tetramer USA (Chevron Oronite)

RM 100D Polyolefin amide alkeneamine (C17+)

USA (Lubrizol)




SABUTOL n-Propyl alcohol ZAF (SASOL)

SBP 60-95 Hexane (all isomers) ISR (Gadiv)

SCAL16475A Diethylenetriamine pentaacetic acid, pentapotassium salt (40% solution)5

GBR (ChampionX)

L16660A Diethylenetriamine pentamethylene phosphonic acid, pentasodium salt solution

GBR (ChampionX)

SCALETREAT 13850

Ethylene glycol NOR (Clariant Oil Services Scandinavia AS)

SCW85902KCL

[[(Phosphonomethyl)imino]bis[ethylenenitrilobis (methylene)]] tetrakisphosphonic acid, ammonium salt solution (60% or less)

GBR (Baker Hughes)

SELEXOL SOLVENT

Polyethylene glycol dimethyl ether USA (Dow)

SOLGAD 100 Alkyl (C3-C4) benzenes ISR (Gadiv)

SOLGAD 150 Alkyl (C5-C8) benzenes ISR (Gadiv)

SOLGAD 150ULN Alkyl (C3-C4) benzenes ISR (Gadiv)

SOLGAD 200 Methyl naphtalene (molten)3 ISR (Gadiv)

SOLGAD 200ULN Methyl naphtalene (molten) ISR (Gadiv)

SOLTROL 130 Iso- and Cyclo- Alkanes (C10-C11) USA (Chevron Phillips)

Solvesso 100 Alkyl (C3-C4) benzenes BEL (ExxonMobile)

Somentor 32 Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobile)

Somentor 32 S Iso- and Cyclo- Alkanes (C12+) SGP (ExxonMobil Asia Pacific Pte Ltd)

5 Does not have complete GESAMP Hazard Profile.

PPR 7/INF.17

Annex 3, page 5



Somentor 34 Iso- and Cyclo- Alkanes (C12+) NLD (ExxonMobile)

Varsol 30 Alkanes (C6-C9) BEL (ExxonMobile)

Varsol 40 Alkyl (C3-C4) benzenes BEL (ExxonMobile)




Varsol 140 Alkyl (C9+) benzenes BEL (ExxonMobile)

WAXTREAT 3553 Alkyl (C3-C4) benzenes NOR (Clariant Oil Services Scandinavia AS)

Xylenes Concentrates

Ethylbenzene GBR (ExxonMobile)

__________

SAFETY AND POLLUTION HAZARDS OF CHEMICALS AND …...GESAMP Hazard Profiles amended since the...

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