RP 1162 Requirements -...

36
2012-2013 Edition

Transcript of RP 1162 Requirements -...

2012-2013 Edition

2012-2013 Edition

The information contained within is intended for use by

professional first responders.

For Natural Gas Emergencies Call Toll Free

1-877-TECO-911

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Table of Contents

Introduction .............................................................................................................. 4 Pipeline Purpose and Reliability ................................................................................... 4 Safety and Security .................................................................................................... 4 Communities Served by TECO Peoples Gas .................................................................. 6 Hazard Awareness and Suggested Prevention Measures ................................................ 8 Natural Gas Operations Only ....................................................................................... 9 TECO Peoples Gas Safety Policy for Employees Responding to Natural Gas Emergencies .. 9 Public Awareness Programs ...................................................................................... 10 Educating the Public ................................................................................................ 10 Educating Excavators ............................................................................................... 10 Additional Public Awareness Information .................................................................... 12 Integrity Management Programs at TECO Peoples Gas ................................................ 13 Pipeline Marker Information ...................................................................................... 14 First Responder Training .......................................................................................... 15 Safety Advisor Assistance ......................................................................................... 15 Natural Gas Fire Training Centers .............................................................................. 16 Emergency Preparedness Communications ................................................................. 17 Number of Gas Emergencies ..................................................................................... 17 Emergency Contact Information ................................................................................ 17 TECO Peoples Gas Local Non-Emergency Contacts ..................................................... 18 Appendix A MATERIAL SAFETY DATA SHEET ......................................................... 21 Appendix B Eight Step Process Considerations........................................................ 24 Appendix C Control of Natural Gas in Emergencies ................................................. 25

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Introduction TECO Peoples Gas’ family of companies began distributing manufactured gas products in Florida in 1865. Approximately one hundred years later, modern natural gas pipelines replaced these manufactured gas plants with a sophisticated network of interstate and intrastate pipelines. Today Peoples Gas serves over 340,000 customers, including residential, commercial and industrial, through a network of more than 11,000 miles of gas main. This represents approximately one-half of the natural gas customers in the state of Florida.

Pipeline Purpose and Reliability From natural gas wells in the Gulf of Mexico, gas is gathered through a system of interstate pipelines running from Texas, Louisiana, Mississippi, Alabama and Florida. One pipeline crosses the Gulf of Mexico from Mobile Bay to Tampa Bay, providing an alternate supply to Florida residents. Peoples Gas accepts delivery of this gas supply and distributes it to a diverse group of customers within the state, providing an efficient, reliable and domestically-produced energy source.

Safety and Security The natural gas industry invests time and money in its pipeline system to ensure safety and reliability. Natural gas pipelines have an outstanding safety record, especially when compared to other modes of transportation. According to National Transportation Safety Board Council 2009 statistics, 33,808 transportation fatalities occurred on the highways, while aviation, boating and railroads accounted for another 2,106 fatalities. In contrast, the number of fatalities associated with natural gas pipelines was 14.

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Communities Served by TECO Peoples Gas Baker County Macclenny Bay County Callaway Lynn Haven Panama City Panama City Beach Parker Springfield Tyndall Air Force Base Broward County Coconut Creek Cooper City Coral Springs Dania Beach Davie Deerfield Beach Ft. Lauderdale Hallandale Beach Hollywood Lauderdale-By-the-Sea Lauderdale Lakes Lauderhill Lighthouse Point Margate Melrose Park North Lauderdale Oakland Park Parkland Pembroke Park Pembroke Pines Plantation Pompano Beach Sea Ranch Lakes Tamarac Weston Wilton Manors Charlotte County Charlotte Harbor Englewood Port Charlotte Punta Gorda Clay County

Orange Park

Collier County

Bonita Shores Golden Gate Naples Pelican Bay Vanderbilt Vanderbilt Beach Fiddler’s Creek Columbia County

Lake City Dade County Aventura Bar Harbour Village Bay Harbor Islands Biscayne Gardens Biscayne Park El Portal Golden Beach Indian Creek Village Miami Miami Beach Miami Gardens Miami Shores North Bay Village North Miami North Miami Beach Sunny Isles Beach Surfside Duval County Atlantic Beach Baldwin Jacksonville Jacksonville Beach Neptune Beach Gilchrist County Hernando County Brooksville Spring Hill Highlands County Avon Park Hillsborough County

Apollo Beach

Balm Brandon Dover Gibsonton Lithia Lutz Port Sutton Port Tampa Riverview Ruskin Seffner Sun City Tampa Temple Terrace Thonotosassa Valrico Wimauma Lafayette County Lake County Cassia Clermont Dona Vista Eustis Forest Hills Grand Island Howey-in-the-Hills Leesburg Lisbon Mascret Mount Dora Sorrento Tangerine Tavares The Villages Umatilla Webster Zellwood Lee County

Bonita Bay Bonita Beach Bonita Springs Cape Coral Estero Fort Myers Fort Myers Beach Lehigh Acres

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North Fort Myers Miromar Lakes Punta Gorda San Carlos Park Levy County Romeo Liberty County Manatee County Bradenton Bradenton Beach Ellenton Holmes Beach Lakewood Ranch Oneco Palmetto Parrish Tallevast University Park Marion County Belleview Chandler Lowell Ocala Oklawaha Silver Springs Silver Springs Shores The Villages Summerfield Martin County Stuart Nassau County

Bryceville Orange County Apopka Belle Isle Casselberry Golden Rod Lake Buena Vista Maitland Orlando Winter Park

Osceola County Celebration City Kissimmee Poinciana Palm Beach County Juno Beach Jupiter Lake Park North Palm Beach Palm Beach Gardens Pasco County Crystal Springs Dade City Holiday Hudson Land of Lakes New Port Richey Ozona Port Richey St. Leo San Antonio Spring Hill Wesley Chapel Zephyrhills Pinellas County Bay Pines Belleair Beach Clearwater Dunedin Elfers Gulfport Homosassa Indian Beach Kenneth City Largo Madeira Beach North Redington Beach Palm Harbor Passa Grille Pinellas Park Redington Beach Redington Shores St. Pete Beach St. Petersburg Seminole South Pasadena Treasure Island

Weeki Wachee Williston Polk County Frostproof Kathleen Lakeland St. Johns County

St. Augustine Sarasota County Englewood Longboat Key Nokomis North Port Osprey Sarasota Venice Seminole County Altamonte Springs Apopka Casselberry Fern Park Longwood Maitland Oviedo Sanford Winter Park Winter Springs Sumter County

Lady Lake Oxford The Villages Union County Volusia County Daytona Beach Dayton Beach Shores Holly Hill Ormond Beach Port Orange South Daytona Wakulla County

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Hazard Awareness and Suggested Prevention Measures The following table is a suggested mutual assistance plan to minimize the hazards to life or property. When responding to pipeline emergencies, all company actions are to make safe any actual or potential hazards to life or property.

Pipeline Emergencies Suggested Minimum Fire

Dept. Emergency Response First Responder Notification

By TECO Peoples Gas

Carbon monoxide incidents

Respond immediately and don SCBA upon arrival; and/or follow local First Responder SOPs.

Notification when the incidents involve personal injury or exposure to the public.

Gas detected inside or near building

Follow 2004 Emergency Response Guidebook using Guide No.:115

Notification when gas migration cannot be controlled. Any scenario where an unsafe atmosphere is discovered in a confined space.

Broken gas line with/without ignition

Follow 2004 Emergency Response Guidebook using Guide No.:115

Notification when company first responder will be delayed or where emergency support is needed.

Transmission incidents

Exercise Extreme Caution and follow 2004 Emergency Response Guidebook using Guide No.:115

Notification when company first responder will be delayed or where emergency support is needed.

Intentional gas leaks, acts of sabotage

Follow local SOPs. The company will notify fire departments for assistance in the investigation.

Explosion occurring near or directly involving a pipeline facility

Follow 2004 Emergency Response Guidebook using Guide No.:115

The company will notify the fire department immediately.

Natural disasters Emergency response may vary depending on the scope of the natural disaster.

Coordinated through Local EOC

Asphyxiation Follow local SOPs. The company will notify the fire department immediately.

Over-pressurization Follow local SOPs.

The company will notify the fire department immediately and inform them of the scope of area (neighborhoods) that will be affected.

Odorization incidents Follow local SOPs

The company will notify the fire department when mechanical failures lead to over-odorization, mercaptan spills and other similar events.

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A copy of our Material Safety Data Sheet is included in Appendix A for your reference. Also, Appendix C contains a typical emergency response plan for natural gas emergencies. In the event of a gas emergency the company may seek to establish flow control measures. Flow control, pressure reduction or pipeline shutdown may take place remotely from the incident scene. Occasionally, pipeline shutdown is facilitated at the incident scene using a pipeline squeeze-off tool. The application of flow control is dependent on system design. It is not always possible or feasible to stop the flow of escaping gas. Each incident is unique and must be evaluated. Because natural gas is very compressible, even when a pipeline is shut down, it may take a long time before all the gas has escaped and the incident is safe.

Natural Gas Operations Only Peoples Gas delivers only natural gas to its customers. It is no longer in the propane market and does not operate any propane facilities or delivery services. As such, Peoples Gas personnel are not trained in emergency propane response, and the company does not have emergency response equipment suitable to mitigate propane emergencies.

TECO Peoples Gas Safety Policy for Employees Responding to Natural Gas Emergencies At TECO Energy, safety is our first core value. We emphasize a safe work environment and a culture of looking out for the safety and well-being of each other, our customers and our community. We believe the safety of life outweighs all other considerations. No employee (or company contractor) is permitted to enter an engulfing flammable atmosphere unless these conditions have been met:

1.) All tactical strategies to effect repair, including pressure reduction and flow control, have been taken first;

2.) Donning complete thermal protection (company bunker gear) and SCBA;

3.) Supporting attendants are available to monitor site conditions, man lifelines (if needed), and fire extinguishers;

4.) Entrants have free access and egress from the exclusion zone.

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Public Awareness Programs TECO Peoples Gas operates a continuing education program to make the public, excavators, and governmental organizations aware of the possible hazards associated with the unintended release of natural gas. Each interest group is targeted with a special outreach program. These outreach programs are conducted using bi-lingual promotional materials to reach the widest demographic audience.

Educating the Public Newspaper advertisement reaches a wide public audience. In 2011 over 2 million Florida residences received this important message from TECO Peoples Gas through 19 different newspapers.

Educating Excavators The majority of pipeline leaks statewide are the result of excavation damages. These damages have the potential for serious consequences within the neighborhoods where they occur. Most often, these types of excavation damages are preventable. This equates to approximately 1,600-1,700 excavation damages each year. TECO Peoples Gas targets professional excavators with educational materials in a unique outreach using direct mailers. More than 46,000 bi-lingual safety brochures were sent during calendar year 2011 to educate excavators. State Law, § 556, requires excavators to notify Sunshine State One-Call of Florida, the state utility notification

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center, two full business days prior to excavating. This advanced warning allows underground facility owners like TECO Peoples Gas an opportunity to visit the job site and mark the estimated horizontal route of any pipelines at the dig site. Last year Peoples Gas received approximately 268,000 requests to mark facilities from Sunshine State One-Call of Florida. TECO Peoples Gas is a founding member of Sunshine State One-Call.

Sunshine State One-Call has a comprehensive outreach program creating awareness of the hazards of excavation for all underground facility owners. On line excavator training programs are available to assist any damage prevention stakeholder in the basic requirements of state law and industry best practices. This award- winning program distinguishes Sunshine’s public awareness programs among other states. Likewise, Sunshine holds many forums and seminars around the state each year as well as private training workshops all focusing on damage prevention. In accordance with recently enacted federal regulations (FCC), Sunshine State One-Call has begun operating the new national 3-digit toll free access number - 811 - within the state of Florida. Excavators can connect to the utility notification center and provide excavation information by dialing the toll free number. There has been some concern that the 811 dialing code is too close to the emergency number, 911. However, there is little that can be done to eliminate miss-dialing. Moreover, since this is a national effort mandated by the federal government there is little that can be done to change it.

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Additional Public Awareness Information Additional safety information can be obtained by accessing the TECO Peoples Gas website at peoplesgas.com/safety.

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Integrity Management Programs at TECO Peoples Gas In accordance with recently enacted federal regulations, some segments of our transmission pipelines have been designated as High Consequence Areas (HCAs). An HCA generally means that transmission pipelines traverse neighborhoods that have buildings which house 20 or more people. These pipeline facilities have undergone a supplemental hazard assessment and prevention program called Integrity Management Programs. To learn more about the location of gas transmission facilities and other pipelines, Emergency Officials are encouraged to visit the National Pipeline Mapping System at npms.phmsa.dot.gov, where TECO Peoples Gas has placed facility records showing their location. Building and zoning officials should consider land use practices along the routes of these transmission corridors. If they have safety concerns, they should contact the local operating center nearest the transmission corridor for additional information.

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Pipeline Marker Information

TECO Peoples Gas uses pipeline markers to designate underground corridors of all transmission pipelines and certain distribution pipelines. These pipeline markers are not intended to represent the exact location of the underground facility, but are placed to alert the public, especially excavators, to the presence of a pipeline facility. Pipeline markers are frequently placed in areas of new construction, where excavation activities are likely to follow. Moreover, pipeline markers serve to protect the facility while permanent records are being updated, and pipeline protection teams are educated about their presence. Excavators working in the area of a pipeline marker will quickly identify the pipelines and take precautionary measures. Marker posts provide an on-site warning to everyone, and therefore are a key element in the company’s damage prevention program.

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First Responder Training Emergency responders who understand the properties and characteristics of natural gas and the procedures for responding to gas-related emergency situations are better prepared to protect their own lives and the lives of those they serve. TECO Peoples Gas is committed to fostering good working relationships with our First Responder partners by providing comprehensive free training for natural gas emergencies and related situations. To participate in this free training online, go to peoplesgas.com/safetytraining.

Safety Advisor Assistance Peoples Gas has Regional Safety Advisors who can help your training officers develop skills they need to facilitate this training. Their contact information is listed below. [Please note that you should not call them for a gas leak situation. Call 1-877-TECO-911 for gas emergencies.]

North Florida Region West Florida Region South Florida Region Safety Advisor Safety Advisor Safety Advisor Bill Clayton – Jacksonville Robert Buckel – Tampa Gary Martin - Ft. Lauderdale 4040 Philips Highway 1400 Channelside Dr. 5101 NW 21st Ave. Jacksonville , FL 32207 Tampa, FL 44605 Ft. Lauderdale, FL 33309 Office: 904 739-4889 Office: 813 275-3736 Office: 954 453-0815

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Natural Gas Fire Training Centers

Location Address Phone Number

400 9th St. S. St. Pete, FL 33701

116 S. 34th St. Tampa, FL 33605

2709 E. Hanna Tampa, FL 33610

Marion Co. Fire Rescue3230 SE Maricamp Rd. Ocala,

FL 34471 352-291-8000

410 NE 3rd St. Ocala, FL 34470

2700 Firefighters Memorial

DriveJacksonville, FL 32246

400.N BenevaSarasota, FL

Lucaya Ave. &

Pinebrook Rd.Venice, FL

Pasco County Fire Dept.15900 Little Ranch Road

Brooksville, FL 34610 727-861-3007

Natural Gas Fire Training Centers

St. Pete Training Division727-893-7713

Tampa Fire Rescue813-242-5410

Hillsborough County Fire

Rescue813-272-6600

City of Ocala FD

352-629-8306Jacksonville Fire and

Rescue Department,

Training Division 904-645-0124

Sarasota County Fire Dept

941-861-2182.

City of Venice Fire Dept.

941-480-3030

Natural gas fire schools are used to bridge theoretical information with hands-on practical experience. The schools listed in this table may be contacted to schedule training classes for your first responders. Regional Safety Advisors can also assist with this training.

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Emergency Preparedness Communications TECO Peoples Gas operates a Customer Service and Emergency Response Center 24 hours a day, 7 days a week, all year long. Emergency Officials and Emergency Operations Centers have been provided a special toll-free telephone number to report emergencies. Any caller using this number will reach a trained emergency dispatcher without going into a telephone queue, or other call routing system. That number is 1-877-TECO-911.

Number of Gas Emergencies Every gas leak received from the public is considered a grade one leak, or a gas emergency, until it has been investigated by a trained gas technician. Statewide, in 2011 we responded to approximately 17,187 emergency leak calls. Peoples Gas averaged a 30 minute response time, and 97.6 percent of these emergencies were reached within 30 minutes.

Each year the 24-hour operations center receives approximately 1,000 emergency calls from emergency operations centers and fire departments calling our Toll Free Hotline: 1-877-TECO–911. This is an unpublished emergency number specifically installed for First Responders.

Emergency Contact Information

For Natural Gas Emergencies

Call Toll Free 1-877-TECO-911

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TECO Peoples Gas Local Non-Emergency Contacts (Use the voice activated directory – 813-228-4111.)

West Region

Avon Park - Operation Office Only 1085 W. Main Street Avon Park, FL 33825 Division Manager: Brent Lipham Fort Myers - Operation Office Only 5901 Enterprise Parkway Fort Myers, FL 33905 Division Manager: Charles Byrd Lakeland - Operation Office Only 445 Kathleen Rd. Lakeland, FL 33815 Division Manager: Brent Lipham Tampa - Operation and Regional Operations Administrative Office 1400 Channelside Dr. Tampa, FL 33605 Director: Keith Martin

Division Manager: Brent Lipham Regional Operations Manager: Hugh Macfarlane

St. Petersburg - Operation Office Only 1920 9th Avenue N. St. Petersburg, FL 33713 Division Manager: Leroy McLeod Sarasota - Operation Office Only 8261 Vico Court Sarasota, FL 34240 Division Manager: Steve Patterson

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TECO Peoples Gas Local Non-Emergency Contacts - continued

East Region

Ft. Lauderdale - Regional Operations Administrative Office 5101 NW 21st Ave. Ft. Lauderdale, FL 33309 Director: Rick Wall Regional Operations Manager: Angel Quant Dade Broward - Operation Office Only 15779 West Dixie Highway North Miami Beach, FL 33162 Division Manager: Jesus Vega Jacksonville - Operation Office Only 4040 Philips Highway Jacksonville, FL 32207

Division Manager: Chris Barrington Jupiter - Operation Office Only 1363 Jupiter Park Drive Jupiter, FL 33458 Division Manager: Tulio Montesano Ocala - Operation Office Only 316 SW 33rd Avenue Ocala, FL 34474 Division Manager: Steve Pinkowski Orlando - Operation Office Only 600 W. Robinson Street Orlando, FL Division Manager: Mike Hannweber Panama City - Operation Office Only 3706 W. 23rd St. Panama City, FL 32405 Division Manager: Michael McGuire

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TECO Peoples Gas Local Non-Emergency Contacts - continued

East Region - continued

Daytona - Operation Office Only 1722 Ridgewood Avenue Holly Hill, FL 32117 Division Manager: Cheri Sattelmeier Eustis - Operation Office Only 1724 Kurt Street Eustis, FL 32726 Division Manager: Cheri Sattelmeier

Corporate Office

TECO Peoples Gas 702 N. Franklin St. Tampa, FL 33602 Director of Engineering & Safety: Mark Haney

Senior Manager, Damage Prevention: Lance Horton Supervisor, Damage Prevention & Recovery: Sandra Panos

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Appendix A MATERIAL SAFETY DATA SHEET (3 pages)

Natural Gas

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Natural Gas Last Revised: 19 February 2007

SYNONYMS: Methane, Marsh Gas

CAS No: 74-82-8

DISTRIBUTOR: TECO Peoples Gas

ADDRESS: 702 N. Franklin St., Tampa, FL 33602

EMERGENCY PHONE: (877) 832-6747

CHEMICAL NAME: Methane

CHEMICAL FAMILY: Hydrocarbon

CHEMICAL FORMULA: CH4-C2H6 C3 H8

SECTION 2: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS CAS No. % VOL Toxicity Data

Predominantly Methane 74-82-8 ~95% Non-toxic. Simple asphyxiant

Ethane 74-84-0 0-5% Non-toxic. Simple asphyxiant

Butane 106-97-8 0-1% Non-toxic. Simple asphyxiant

Trace Hydrocarbons 0-1% Non-toxic. Simple asphyxiant

SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Flammable, high-pressure gas. May form explosive mixture with air. Can cause rapid

suffocation. May cause dizziness and drowsiness. Self-contained breathing apparatus may be required by rescue workers.

ROUTES OF ENTRY: Inhalation. Eye contact.

POTENTIAL HEALTH EFFECTS

EYES: Possible irritation.

SKIN: Not known as an irritant. Secondary injuries possible (abrasions, burns).

INHALATION: Asphyxiant. Effects are due to lack of oxygen. Moderate concentrations may cause headaches, drowsiness, dizziness, excitation, excess salivation, vomiting and unconciousness. Lack of oxygen can kill.

ACUTE HEALTH HAZARDS: Asphyxiation.

CHRONIC HEALTH HAZARDS: None known.

CARCINOGENICITY: Not listed as a carcinogen by OSHA, ACGIH, NTP, IARC.

Hazard Rating*

1 Health

4 Flammability

0 Reactivity

0 Least 3 High

1 Slight 4 Extreme

2 Moderate * NFPA 704

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SECTION 4: FIRST AID MEASURES EYES: Flush with water for 15 minutes. Seek medical attention if problem or irritation persists.

SKIN: For abrasions – clean with soap and water then bandage. For burns – seek medical attention.

INHALATION: Remove victim to fresh air. Restore breathing if necessary. Have trained person administer oxygen if breathing difficulties persist. Seek medical attention.

INGESTION: Unlikely under normal atmospheric conditions.

SECTION 5: FIRE-FIGHTING MEASURES FLAMMABLE LIMITS IN AIR (% BY VOLUME)

UPPER: 15%

LOWER: 5%

FLASH POINT: -306° F (-187.8°C)

AUTOIGNITION TEMPERATURE: 899.6°F (482°C)

NFPA HAZARD CLASSIFICATION: HEALTH: 1 (Slight) FLAMMABILITY: 4 (Extreme) REACTIVITY: 0 (Least)

HMIS HAZARD CLASSIFICATION: HEALTH: 1 (Slight) FLAMMABILITY: 4 (Extreme) REACTIVITY: 0 (Least)

PROTECTION: K (K = Air line hood or mask, gloves, full chemical suit, boots)

EXTINGUISHING MEDIA: CO2, Dry chemical, Wet fog

SPECIAL FIRE FIGHTING PROCEDURES: Let fire burn, shut off gas supply. Water should be used to keep fire-exposed containers cool and to protect personnel effecting shutoff. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop leak.

UNUSUAL FIRE AND EXPLOSION HAZARDS: A hazard of reignition or explosion exists if flame is extinguished without stopping flow of gas.

SECTION 6: ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES: Natural gas is lighter than air and freely dissipates if ignition does not occur.

Forms explosive mixtures with air. Immediately evacaute all personnel from danger area. Use self-contained breathing apparatus where needed. Remove all sources of ignition if without risk.

SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE: Do not cut, puncture or weld pipeline or containers without appropriate procedures.

Ground and bond all lines and equipment. Keep away from heat, sparks, open flames and other sources of ignition. Rapid escape of gas may generate static charge. Use of explosion proof electrical equipment is required.

SECTION 8: EXPOSURE CONTROL / PERSONAL PROTECTION ENGINEERING CONTROLS: Provide adequate ventilation to control exposure below recommended levels.

VENTILATION: Provide adequate ventilation to control exposure below recommended levels.

RESPIRATORY PROTECTION: Use supplied air respiratory protection (SCBA) where gas has displaced O2 content of air below 19.5%.

EYE PROTECTION: Safety glasses, goggles.

SKIN PROTECTION: Gloves, fire resistant coveralls.

WORK HYGIENIC PRACTICES: Provide adequate ventilation. Remove all potential sources of ignition.

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Colorless, Odorless (without odorant), Tasteless

ODOR: Mercaptan odorant (rotten eggs)

PHYSICAL STATE: Gas

BOILING POINT: -259°F (-162°C)

MELTING POINT: -323°F (-182.5°C)

FREEZING POINT: -324°F (-182.6°C)

VAPOR PRESSURE (mmHg): > 1000 at 68°F (20°C) @ 760 mm Hg (1 atm)

VAPOR DENSITY (AIR = 1): 0.615 at 68°F (20°C) @ 760 mm Hg (1 atm)

SPECIFIC GRAVITY (H2O = 1): Gas

EVAPORATION RATE: > 1

SOLUBILITY IN WATER: Very slightly soluble in cold water.

PERCENT VOLATILE: 100%

MOLECULAR WEIGHT: 17.66 g/mole

SECTION 10: STABILITY AND REACTIVITY STABILITY: Stable

CONDITIONS TO AVOID (STABILITY): Heat or fame.

INCOMPATIBILITY (MATERIAL TO AVOID): Heat or flame, oxidizing agents, halogens, interhalogens. Will ignite spontaneously with chlorine dioxide.

HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Carbon monoxide, carbon dioxide and possible trace amounts of sulphur dioxide and oxides of nitrogen.

HAZARDOUS POLYMERIZATION: Will not occur.

SECTION 11: TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Non-toxic.

SECTION 12: ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: n/a

SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Product is non-toxic and will dissipate in air if ignition does not occur.

SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION

PROPER SHIPPING NAME: Natural Gas

HAZARD CLASS: Flammable Gas

ID NUMBER: UN 1971

LABEL STATEMENT: Flammable Gas

SECTION 15: REGULATORY INFORMATION Not Determined.

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Appendix B Eight Step Process Considerations 1.) Site Management and Control

Proportion – What type of pipeline facility is involved?

Location – Where is the location of the emergency? o Rural o Residential o Business

2.) Identifying the Problem and Materials Involved

What type of Natural Gas emergency is it? o CO Incidents o Gas detected inside or near a building o Broken gas line with/without ignition o Transmission pipeline problems o Intentional Gas leaks/Acts of sabotage o Explosions involving a pipeline facility o Natural Disasters o Asphyxiations o Over/Under Pressurization

3.) Evaluating the Hazards and Risks

Life and Property Priorities.

Use electronic Combustible Gas Indicators or other similar devices to identify the percent gas in air, and then monitor site conditions.

4.) Selecting Protective Clothing and Equipment

SCBA and Bunker gear whenever a gas in air condition exists. 5.) Developing a Plan of Operation and Coordinating Resources

If local operating company is not present, contact them immediately. 6.) Implementing the Responses Objectives

Follow SOP’s for the emergency identified.

Always monitor site conditions for changes. 7.) Handling Decontamination and Clean-up

Releases of natural gas do not result in environmental contamination. 8.) Implementing Termination Activities

Monitor surrounding buildings and underground points of collection before allowing public to enter to safety zone.

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Appendix C Control of Natural Gas in Emergencies Factual Information About Natural Gas 1. Natural gas is neither toxic nor poisonous. Tests show that concentrations of 25 percent natural gas mixed with air produce no ill effects. However, if natural gas displaces the air in an enclosed space, suffocation can occur because of the lack of oxygen. 2. Natural gas is lighter than air, and it will rise and diffuse rapidly when it escapes in an open area. When confined in a closed room, the gas will rise to ceiling level. The air in the room will be displaced from the top downward. Remember this when you ventilate a room. Open windows from the top and bottom. Lighter-than-air natural gas should not be confused with liquefied petroleum gas. This gas is more commonly called L.P., bottle gas, propane, butane, and various other trade names. Liquefied petroleum gases are all heavier than air and collect in low places when not confined. 3. Most natural gas is odorless in its natural state; therefore, an odorant is usually added to give it a distinctive odor of rotten eggs. 4. Burning natural gas produces a high radiant heat. Combustibles must be wetted down to prevent their ignition by this radiated heat. 5. The ignition point of natural gas is 1,100 – 1,200 degrees Fahrenheit. This temperature is reached by pilot lights, flint sparks, matches, or sparks from electrical switches or motors. Procedures During Emergencies The gas company employee, the firefighter, and other emergency personnel have the same goals when they are brought together in an emergency situation involving natural gas. Firefighters, by supplementing their overall knowledge of emergency measures with helpful information provided by gas company employees, can more effectively protect the public they serve. The main purpose of this booklet is to provide emergency personnel with general information about emergency procedures involving natural gas. It also includes several examples of specific information provided by the gas company employee "at the scene" that can be beneficial in controlling an emergency. These emergencies will involve one or more of five basic situations:

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1) Gas Escaping Outside 2) Gas Burning Outside 3) Gas Escaping Inside 4) Gas Burning Inside 5) Function of Relief Valves

Upon the first indication that gas is involved, CALL THE GAS COMPANY at 1-

877-TECO-911. This may be immediately after the call is received at the fire station or when the firefighter arrives at the scene, but whenever and wherever natural gas is involved, immediately call the gas company. Gas company personnel are instructed to report their presence upon arrival to the fire officer in charge. 1. Gas Escaping Outside If natural gas is escaping from the ground, an excavation, an open pipe, a manhole, a sewer or a vault, clear a safe area around the location and barricade or rope it off. If possible, police and firefighters should check with the gas company employee before advising the public in the immediate vicinity of the emergency what measures, if any, should be taken. The special knowledge of the gas company employee may help avoid causing undue alarm and unnecessary action by the public in adjacent or removed locations. In most instances the gas company employee will cut off the gas to adjoining properties and advise the customers of safety precautions to be taken, such as extinguishing all open flames, prohibiting smoking and making certain that electrical switches or similar possible ignition sources are not operated. Gas company employees will also check for gas in surrounding buildings, particularly in basements. It may be necessary to restrict or reroute all traffic until the gas flow is brought under control. Manholes or vaults can usually be vented by temporarily removing their covers. 2. Gas Burning Outside If natural gas is burning outside, the firefighter should make no attempt to extinguish the fire. Burning gas will not explode, but it may ignite surrounding combustibles. Clear the danger area and barricade or rope it off. DO NOT OPERATE GAS VALVES IN THE STREET - HAVE THE GAS COMPANY EMPLOYEE DO IT. Turning the wrong valve could create another emergency.

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Gas company employees, with their special knowledge and information, can avoid this. Spray water mist on any surrounding combustibles if they are in danger of igniting. Do not use water on burning natural gas at its point of escape. If this point is in an excavation, the hole will be filled with mud, making the repair slower and more hazardous. 3. Gas Escaping Inside If natural gas is escaping inside a building, ventilate the area starting where the gas concentration is strongest. If gas is escaping in quantity, clear the building of its occupants. Shut off open flame devices by operating manual controls, but do not operate electrical switches. The fire officer in charge may determine that it is necessary to shut off the gas to the building at the service valve. The necessity of this action should be weighed against the fact that turning off the gas in commercial or industrial areas might seriously interrupt important production processes and possibly create further hazards. Again, your gas company employee can give you specific information to help evaluate the situation. If a firefighter or other emergency personnel turns off a valve, leave it off, then immediately tell the gas company employee. After a valve has been shut off, only gas company employees should turn it on again, because they have the experience and training necessary to evaluate the conditions and determine when this action is advisable. 4. Gas Burning Inside If natural gas is burning inside a building, shut off the gas at the meter, or, when available, at an outside valve. If the gas supply cannot be safely shut off, keep the surrounding combustibles wetted with spray stream until the gas company emergency crews can control the flowing gas. If it appears that inside piping or meter installations are going to be endangered by a non-gas fire in a building, the fire officer in charge can determine if it is necessary to turn off the gas. Again, the gas company employee can help evaluate the situation. If a fire is caused by a gas appliance that is burning out of control, it is usually enough to shut off the gas at the appliance's valve. When this is not practical, or the valve cannot be located, shut off the gas at the meter supplying the appliance. 5. Function of Relief Valves in Distribution Systems A relief valve protects gas systems from accidental over-pressuring. Gas company control points with relief valves are sometimes referred to as district regulating

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stations, city gate stations or town border stations. Each pressure reducing regulating station has a gas regulator set to maintain a fixed down-stream pressure. If for any reason there is a malfunction and the regulator fails to properly limit downstream pressure, the relief valve will open to protect the system. When this occurs, gas is vented into the atmosphere, usually accompanied by a loud, high-pitched noise. Natural gas, which is much lighter than air, diffuses upward into the atmosphere. A RELIEF VALVE VENTING GAS INTO THE ATMOSPHERE IS PERFORMING ITS PROPER FUNCTION. IT SHOULD NEVER BE CUT OFF OR RESTRICTED UNTIL A GAS COMPANY EMPLOYEE ARRIVES AND MAKES CORRECTIONS. Anyone who sees or hears a relief valve venting gas to the atmosphere should call the gas company at once, but take no action which would keep the relief valve from venting gas into the atmosphere.

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Example 1 shows a typical relief valve installation. The relief valve may be recognized as one connected to a discharge pipe extending upward, usually with a rain cap on the end. Most companies install a standard cutoff valve below the relief valve with a lock to keep it in an open position. The lock is to keep unauthorized persons from closing the valve and rendering the relief valve ineffective.

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Example 2 is a typical meter facility on a utilization pressure system which has operating pressures in the piping on both sides of the meter at about one-quarter pound per square inch. This application is sometimes used for commercial buildings, regulator stations and city gate stations.

The typical cutoff valve can be operated (open or closed) by turning it one-quarter turn, 90 degrees. Example 2 is a typical meter facility on a low or utilization pressure system. Note: There is no regulator upstream of the meter.

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Example 3 is a typical meter facility on a medium pressure system. This installation differs from Example 2 in that a regulator is included to reduce the pressure of the incoming gas from pounds per square inch to utilization pressure of about one-quarter pound per square inch.

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Example 4 shows meter facilities for multiple-dwelling buildings. There is a master control valve which shuts off the gas to all the meters in the manifold, and there is also a valve on the inlet side of each individual meter. This makes it possible to shut off gas to an apartment where an emergency situation exists without interrupting service to units in other parts of the building. The number of the apartment served appears on the front of or on a tag attached to the particular meter.

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The meter facilities shown in Example 5a and 5b are used for large industrial and commercial gas users and are located outside the building, inside the building, or in their own separate buildings.

Example 5a

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5a

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Gas Detection Odors sometimes mistaken for natural gas can come from many sources such as petroleum products (especially gasoline), marsh gas, sewer gas, industrial gases and even some batteries being charged are typical examples. There are many types of gas detection instruments, and since the gas company employee is trained in their use, he will be glad to assist you. Natural gas has its odor regulated by the gas company in order to give it a sufficiently distinctive and recognizable odor. It is suggested that emergency personnel familiarize themselves with the odor of the gas distributed in their area. Press Relations and Publicity In an emergency involving natural gas, refer inquiries from press representatives and other interested parties to a gas company representative if available. The gas company representative will be able to clarify technicalities and provide other information necessary for complete and accurate reporting of the emergency. Proper identification of the type of "gas" is of vital importance. If the emergency involves natural gas, be sure to identify it as "natural gas." If gasoline, chlorine gas, sewer gas, propane, etc., is involved, always carefully identify the type. The gas company's objective in working with press, TV, and radio representatives during an emergency is the same as that of emergency personnel - to be helpful and cooperative in determining the cause of an emergency and to accurately report the cause to the public.

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