Room Temperature So No Chemical Initiation of Thiol-Ene Reactions

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    ChemComm

    www.rsc.org/chemcomm

    ISSN1359-7345

    Chemical Communications

    www.rsc.org/chemcomm Volume 46 | Number32 | 28 August2010 | Pages58135976

    1359-7345(2010)46:32;1-H

    COMMUNICATION

    J.FraserStoddart etal.Directedself-assembly of aring-in-ring complex

    FEATUREARTICLE

    Wenbin Lin etal.Hybridnanomaterialsforbiomedicalapplications

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    R+

    HS R'R

    S R'

    Ultrasound initiates thiol-ene 'click' reactions at room temperature in

    toluene and water, giving quantitative yields for aqueous reactions in air.

    Ultrasound

    20 kHz, 17 W cm-2

    Room temp.

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