METROPOLITAN WATER RECL..AJ-.AATION DiSTRICT OF GREATER CHICAGOPRIORITY POLLUTANTS

tv'ONTHlY REPORTING FORM

RO-202INSTRUCTIONS

The analysis and rf'!porting of priority pollutants as required by the Metropolitan Waler ReclamationDistrict of Greater Chicago (District) shall be conducted in accordance with the following requirements:

I. Analylical Methodology

United States Environmental Protection Agency (USEPA) methodologies are to beemployed. These methodologies are published in the Federal Register. Volume 49,October 1984.

A., Volatile Organics (Qr purgeables) -USEPA Methodology 624 for analysis by purge and trap with Gas

Chr~malo~raphy I Mass Spectrometer (GC/MS),

B. Semivolatiles (or aci9'base/neulral extraclables)­USEPA Methodology 6'25 for analysis by GC/MS.

C. Pesticides and PCBs -USEPA Methodology 608 for analysis by GC with electron capture'detector.

D. Inorqanics •40 CFR Part t36, Volume 49, No. 209, October 1989.

All analysis of pesticides and PCBs must achieve the Method Detection Limits (MOL)specified by the District Analysis for volatile organics -and semivolatile organics mustachieve the Quantitation Limits (Ol) specified by the District. A copy of the MOL and Olcan be obtained by contacting the District at (312) 751-3044. Analysis for inorganicsmust achieve the ~ontract Required Detection Limits (CROL) specified in Item 1.0.above.

11. Mandalol)' Reporting Requirements

A. '. Representative grab samples shall be collected' on a monthly basis frol!\.., eachsanitary sewer discharge. A composite of four grabs is required.

B. ~amples specified in Item A shall be submitted to an independent laboratory forpriority pollutant analysis. All 124 compounds listed on this monthly reportingform must be analyzed and repor1ed on this form (one form for each discharge).

C. ' . Monthly reponing forms shall be submilted to the District no later than the20th day of the following month.

III. Reporting' Instances Where MOL or Ql are Not Allainable

In some instances, the samples may contain high levels of the compound under analysisor interfering compounds which may overload the GC column, detector and/or massspectrometer and a dilution may be required. In such instances, the information on thefollowing page must be supplied. in addition to the monthly reporting form.

Me I MV....U I.. I I M.l'l VVI" I en nt:.......LJ\MA IIUN UI~ I HICT OF GREATER CHICAGOPRIORfTY POll.LrrANTS

MONTH....Y REPCHTlNG FORM

HD-202INSTRUCTIONS (Continued)

II I. ReportinQ Instances Where MOL or QL are Not Atlajnable(Conljnuedl

A. The reason for the dilution and the dawee of dilution. Explanation formsfor high MDL's or QL's supplied by the DIstrict must be used by theanalytical laboratory. This explanation form must ba signed by theanalytical chemist of the contract laboratory. '

B. For volatile and semivolatila compounds, the following must be provided:

1. Total ion chromatogram of the sample.

2. Mass spectrum backg'round, corrected.

3. Mass spectrum background. uflaltered.4_ Reference standard spectrum.

5. Ion profile of the two major peaks.

G. For pesticides and PCBs, the following must be provided:

1. Chromatogram of sample.

2. Chromatogram of reference standard.

Company NaITJe: For Offico Uua Only

Reporting Period;MOI1th Year

Sampling PoInt:Sampling Dale:

Indude the 5 highest compounds not listed above.

Analytical QlNo. CASNJ. Purgeables Results Attained

uQ/l (1) uQ/L (2)1 74-B7v 3 Chtoroffiethane2 74-83·9 Bromometh ane3 75-01-4 Vinyl Chloride4 . 75-00-3 Chloroethane5 75-09~2 Methylene Chloride6 107-02-8 Acrolein7 107-13-1 AcrylonitrileB 75-35-4 1.1-Dlchloroethene9 75-34-3 l,l·Dlchloroethane

10 156-60-5 trans-1 ,2-D1chloroelh ane11 67-66-3 Chloroform12 107-06-2 l,2·Dlchloroethane -- ,-

13 71·55-6 1,1,1-Trichloroethane14 56-23-5 Carbon Tetrachloride15 75-27-4 Bromodlchloromethane16 78-87-5 l,2-Dlchloropropane17 542-75-6 1.3v Dlchloropropene18 79-01-6 Trichloroethane19 1240048-1 Dlbromochloromethane20 79-00-5 1,l,2-Trlchloroethane21 71-43-2 Benzeoe22 110-75-8 2-Chloroethylvinyl-Ether23 75-25-2 Bromoform24 127-18-4 Tetrachloroethane25 79-34-5 1,l.2.2-Tefrachloroethane·26 108-88-3 Toluene27 106-90-7 Chlorobenzene28 100-41-4 Ethylbenzene29 *30 ·31 •32 •33 •.

METROF'OLITAN WATER REClAMATION DISTRICT OF GREATER CHICAGOPRIORITY POllUTANTS

MONTH...YFE~ FORM

RO-202

Include the 5 highest compounds n01 IIs1ed above•

Analytical oLNo. CAS No. Base/NeutralJAcid Extr actable Resuhs Attained

LJQ/l (1') uQ/l (2)34 62-75-9 N-Nilrosodimethylamine35 108-95-2 Phenol36 111-44-4 bis (Z-Chloro ethyl)elher37 95-57-8 Z-Chloro.phenol38 541-73-1 1.3-Dichlorobenzeoe39 106-46-7 l,4-Dichlorobanzene40 95:50-1 1.2-Dichlorobenzeno41 108-60-1 bi s (2·Chloro IsoprapyI) 9thar42 621-64-7 N-Nltroso-di -n-propylam ina43 67-72-1 Hexachloroethane44 98-95-3 Nitrobenzene45 78-59-1 Isophorona46 88-75-5 2-Nitrophenol47 105-67-9 2,4 -0 im ethylphenot48 111-91-1 b is (2-Ch (oro othoxyJm8thana49 120-83-2 2.4-0Ichh>Tophsnol50 120-82-1 , .2.4-TrJchloroben.zenll51 91-20-3 Naphthalene52 8.7-68-3 Hexachlorobtltadlen 9

53 59-50-7 4-Chioro-3 -M 9th yl phenol54 77-47-4 Haxacnlorocyclopenfadlene55 88-06-2 2,4,6-Trlchlorophenol56 91-58-7 2-Chloronaphthal ens57 13'-11·3 Dimethyl phthalate58 208-96-8 AcenaphthyJene59' 606-20-2 2,6-Dinltrotoluene60 83-32-9 Acenaphthene61 51-28-5 2,4-DlnJtrophsnol62 100-02-7 4-Nllropheool63 121-14-2 2.4-Dlnitrotolueoe64 84-66-2 Dlethyl phthalate-65 7005-72-3 4-Chlorophenyl phenyl ether66 86-73-7. Fhmrene67 534-52-1 4.6-Dlnnro-o-cresol68 86-30-6 N -Ni tro sodiphenylamlne69 122-66-7 l,2*Dipheoylhydrazine70 101-55-3 4-Bromophenyl phenyl ether71 118-74-1 Hexachlorobenzene72 87-86-5 Pentachlorophenol73 85-01-8 Phenanthrene74 120-12-7 Anthracene75 84-74-2 Di-o-butyl phthalatB76 2Q6-44-0 Fluoranth en e77 92-87-5 Benzidine78 129-00-0 Pyrena79 85-68-7 Butyl banzyl phthalate80 91-94-1 3,3-D1chlorobenzldine81 56-55-3 Benzo(a)anttuBcene82 218-01-9 Chrysene83 117-81-7 bl s f2-EthyIhexyl)phthalate84 117-84-0 Di·n-octylphtha'ate85 205-99-2 Benzo(bl fluoranth ena86 207-08-9 Benzo(k)fluoranthene87 50-32-8 Bonzo(a)pyrene88 193-39-5 IndenD (1 ,2.3-c.d)pyren e89 53-70-3 Dibenzo(a.h)anthracene90 191-24-2 Benzo(Qh1)perv!ene91 ·92 ·93 ·94 ·95 ·.

Me I nUrULI 11-\1-' V'l1-\ I eM HI:l-LAMA IIUN UIS JHIt; I UI- GHEATEA CHICAGOPRIORfTY POLLUTANTS

MONTI-iLY REPOATlN3 FORM

HO-202

Analytical MDlNo. CAS No. Pesticides and PCBs Results Attained

ug/L (1) uq/L (21"96 319·64-6 Alpha-BHC97 319-65-7 Bela-SHe98 319-66-8 Gamma-BHe (Lindane) ""

99 58-89-9 Delta-BHC100 76-44-8 Heptachlor101 309-00-2 Aldrin102 1024-57-3 Heptachlor epoxide103 959-98-8 Endosullan J104 60-57-1 Dieldrin105 72-55-9 4,4'-ODE106 72-20-8 Endrin10] 33213-65-9 Endosullan IIlOB 7421-93-4 Endrin aldehyde109 72-54-8 4,4'-000110 1031-07-8 Endosulfan sulfate111 50-29-3 4,4'-DDT112 57-74-9 Chlordane113 8001-35-2 Toxaphene114 53469-21-9 Aroclo[-1242115 11097-69-1 Aroclor-1254116 11104-28-2 Aroclor-1221117 11141'16-5 Aroclor-1232118 12.672-29- 6 Aroclor-1248119 11096-82-5 Aroclor-1260120 12674-11-2 Aroclor-l016121 ·122 ·123 ·124 ·125 ·

AnalyticalNo. Inorganics Results

uQ/L (-1)126 Antimony1-27 Arsenic128 Beryllium129 Cadmium130 Chromium131 Copper132 Cyanide133 Lead134 Mercury135 Nickel136 Selenium137 Sliver138 Thallium139 Zinc . M •

(1) Enter the analytIcal resul;s for each of the above listed compounds or -ND If the compoundwas not detected or below the OL or MOL reported by your consulting lat;loratory. Submit thecertified laboralory report with this form.

(2) Enter the QL or MDL anained by your consulting laboratory. All cases in which the Ol or MDLreported by your consulting laboratory exceeded the prescribed OL or MOL must be documented.as indicated in the instructions on this form.

Company Representative: Title;

Signature: Date;

Mail forms to:

5/91

Metropolitan Water Reclamation Districtof Greater Chicago

Enforcement SectionP_ O. Box 10654Chicago, Illinois 605"10