RIGHT SOLUTIONS | RIGHT PARTNERThe analyses for sample AA-01-031216 (P161301-001) were cancelled...

2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com

R I G H T S O L U T I O N S | R I G H T P A R T N E R

LABORATORY REPORT March 14, 2016 Glenn La Fevers Southern California Gas Company 12801 Tampa Ave Northridge, CA 91326-1045 RE: SOUTHERN CALIFORNIA GAS - ALISO CANYON STATION / 14424 Dear Glenn: Enclosed are the results of the samples submitted to our laboratory on March 13, 2016. For your reference, these analyses have been assigned our service request number P1601301. All analyses were performed according to our laboratory’s NELAP and DoD-ELAP-approved quality assurance program. The test results meet requirements of the current NELAP and DoD-ELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP and DoD-ELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. Results are intended to be considered in their entirety and apply only to the samples analyzed and reported herein. If you have any questions, please call me at (805) 526-7161. Respectfully submitted, ALS | Environmental Sue Anderson Project Manager

1 of 40

http://www.alsglobal.com/


sue.anderson

Sue



Client: Southern California Gas Company Service Request No: P1601301 Project: SOUTHERN CALIFORNIA GAS - ALISO CANYON STATION / 14424 _______________________________________________________________________________

CASE NARRATIVE

The samples were received intact under chain of custody on March 13, 2016 and were stored in accordance with the analytical method requirements. Please refer to the sample acceptance check form for additional information. The results reported herein are applicable only to the condition of the samples at the time of sample receipt. The analyses for sample AA-01-031216 (P161301-001) were cancelled because the sample came in at a positive pressure (received at +0.02 psig). Methane Analysis The samples were analyzed per modified EPA Method TO-3 for methane using a gas chromatograph equipped with a flame ionization detector (FID). This procedure is described in laboratory SOP VOA-TO3C1C6. This method is included on the laboratory’s DoD-ELAP scope of accreditation, however it is not part of the NELAP or AIHA-LAP accreditation. Sulfur Analysis The samples were also analyzed for ten sulfur compounds per ASTM D 5504-12 using a gas chromatograph equipped with a sulfur chemiluminescence detector (SCD). All compounds with the exception of hydrogen sulfide and carbonyl sulfide are quantitated against the initial calibration curve for methyl mercaptan. This method is included on the laboratory’s NELAP scope of accreditation, however it is not part of the DoD-ELAP or AIHA-LAP accreditation. Volatile Organic Compound Analysis The samples were also analyzed for volatile organic compounds in accordance with EPA Method TO-15 from the Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Second Edition (EPA/625/R-96/010b), January, 1999. This procedure is described in laboratory SOP VOA-TO15. The analytical system was comprised of a gas chromatograph / mass spectrometer (GC/MS) interfaced to a whole-air preconcentrator. This method is included on the laboratory’s NELAP and DoD-ELAP scope of accreditation, however it is not part of the AIHA-LAP accreditation. Any analytes flagged with an X are not included on the NELAP or DoD-ELAP accreditation. The canisters were cleaned, prior to sampling, down to the method reporting limit (MRL) reported for this project. Please note, projects which require reporting below the MRL could have results between the MRL and method detection limit (MDL) that are biased high. ______________________________________________________________________________________ The results of analyses are given in the attached laboratory report. All results are intended to be considered in their entirety, and ALS Environmental (ALS) is not responsible for utilization of less than the complete report. Use of ALS Environmental (ALS)’s Name. Client shall not use ALS’s name or trademark in any marketing or reporting materials, press releases or in any other manner (“Materials”) whatsoever and shall not attribute to ALS any test result, tolerance or specification derived from ALS’s data (“Attribution”) without ALS’s prior written consent, which may be withheld by ALS for any reason in its sole discretion. To request ALS’s consent, Client shall provide copies of the proposed Materials or Attribution and describe in writing Client’s proposed use of such Materials or Attribution. If ALS has not provided written approval of the Materials or Attribution within ten (10) days of receipt from Client, Client’s request to use ALS’s name or trademark in any Materials or Attribution shall be deemed denied. ALS may, in its discretion, reasonably charge Client for its time in reviewing Materials or Attribution requests. Client acknowledges and agrees that the unauthorized use of ALS’s name or trademark may cause ALS to incur irreparable harm for which the recovery of money damages will be inadequate. Accordingly, Client acknowledges and agrees that a violation shall justify preliminary injunctive relief. For questions contact the laboratory.

2 of 40




ALS Environmental – Simi Valley

CERTIFICATIONS, ACCREDITATIONS, AND REGISTRATIONS

Agency Web Site Number

AIHA http://www.aihaaccreditedlabs.org 101661

Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0694

DoD ELAP http://www.pjlabs.com/search-accredited-labs L15-398

Florida DOH (NELAP)

http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E871020

Maine DHHS http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

2014025

Minnesota DOH (NELAP)

http://www.health.state.mn.us/accreditation 977273

New Jersey DEP (NELAP)

http://www.nj.gov/dep/oqa/ CA009

New York DOH (NELAP)

http://www.wadsworth.org/labcert/elap/elap.html 11221

Oregon PHD (NELAP)

http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx

4068-001

Pennsylvania DEP http://www.depweb.state.pa.us/labs 68-03307

(Registration) Texas CEQ (NELAP)

http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704413-

15-6 Utah DOH (NELAP)

http://www.health.utah.gov/lab/labimp/certification/index.html CA01627201

5-5

Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C946

Analyses were performed according to our laboratory’s NELAP and DoD-ELAP approved quality assurance program. A complete listing of specific NELAP and DoD-ELAP certified analytes can be found in the certifications section at www.alsglobal.com, or at the accreditation body’s website. Each of the certifications listed above have an explicit Scope of Accreditation that applies to specific matrices/methods/analytes; therefore, please contact the laboratory for information corresponding to a particular certification.

3 of 40


http://www.aihaaccreditedlabs.org/

http://www.azdhs.gov/lab/license/env.htm

http://www.pjlabs.com/search-accredited-labs

http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm

http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

http://www.health.state.mn.us/accreditation

http://www.nj.gov/dep/oqa/

http://www.wadsworth.org/labcert/elap/elap.html



http://www.depweb.state.pa.us/labs

http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html

http://www.health.utah.gov/lab/labimp/certification/index.html

http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html


P1601301_Detail Summary_1603141133_RB.xls - DETAIL SUMMARY

Client: Southern California Gas Company Service Request: P1601301Project ID: SOUTHERN CALIFORNIA GAS - ALISO CANYON STATION / 14424

Date Received: 3/13/2016Time Received: 07:41

Client Sample ID Lab Code MatrixDate

CollectedTime

CollectedContainer

IDPi1

(psig)Pf1

(psig)

AA-02-031216 P1601301-002 Air 3/12/2016 00:48 AS01000 -2.07 1.00 X X XAA-03-031216 P1601301-003 Air 3/12/2016 00:38 AS00997 -5.30 1.15 X X XAA-04-031216 P1601301-004 Air 3/12/2016 00:22 AS00943 -5.64 1.04 X X XAA-05-031216 P1601301-005 Air 3/12/2016 00:12 AS00901 -6.79 1.19 X X XAA-06-031216 P1601301-006 Air 3/12/2016 00:06 AS00915 -5.05 1.30 X X XSS-3H-031216 P1601301-007 Air 3/12/2016 00:34 AS00968 -6.27 1.20 X X XSF-1-031216 P1601301-008 Air 3/12/2016 00:44 AS00376 -6.55 1.05 X X XSF-2/5-031216 P1601301-009 Air 3/12/2016 00:55 AS00999 -5.00 1.05 X X XCorbin-031216 P1601301-010 Air 3/12/2016 00:09 AS00913 -5.53 1.13 X X XPorterValley-031216 P1601301-011 Air 3/12/2016 00:00 AS00981 -4.46 1.15 X X XReseda-031216 P1601301-012 Air 3/12/2016 00:00 AS00932 -6.67 1.08 X X X031216-TB P1601301-013 Air 3/12/2016 00:00 AS00931 -14.47 1.06 X X X

ALS ENVIRONMENTAL

DETAIL SUMMARY REPORT

AST

M D

550

4-12

- Su

lfur C

an

TO-3

Mod

ified

- C

1C6+

Can

TO-1

5 - V

OC

Can

s

4 of 40

5 of 40

6 of 40

3/14/16 3:56 PMP1601301_Southern California Gas Company_SOUTHERN CALIFORNIA GAS - ALISO CANYON STATION _ 14424.xls - Page 1 of 1

ALS EnvironmentalSample Acceptance Check Form

Client: Southern California Gas Company Work order: P1601301Project: SOUTHERN CALIFORNIA GAS - ALISO CANYON STATION / 14424Sample(s) received on: 3/13/16 Date opened: 3/13/16 by: SANDERSON

Note: This form is used for all samples received by ALS. The use of this form for custody seals is strictly meant to indicate presence/absence and not as an indication of

compliance or nonconformity. Thermal preservation and pH will only be evaluated either at the request of the client and/or as required by the method/SOP.Yes No N/A

1 Were sample containers properly marked with client sample ID? 2 Did sample containers arrive in good condition? 3 Were chain-of-custody papers used and filled out? 4 Did sample container labels and/or tags agree with custody papers? 5 Was sample volume received adequate for analysis? 6 Are samples within specified holding times? 7 Was proper temperature (thermal preservation) of cooler at receipt adhered to?

8 Were custody seals on outside of cooler/Box/Container? Location of seal(s)? Sealing Lid?

Were signature and date included? Were seals intact?

9 Is there a client indication that the submitted samples are pH preserved? Were VOA vials checked for presence/absence of air bubbles?

10 Tubes: Are the tubes capped and intact? 11 Badges: Are the badges properly capped and intact?

Are dual bed badges separated and individually capped and intact?

Lab Sample ID Container Required Received Adjusted VOA HeadspaceDescription pH * pH pH (Presence/Absence) Comments

6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can6.0 L Silonite Can

RSK - MEEPP, HCL (pH<2); RSK - CO2, (pH 5-8); Sulfur (pH>4)

P1601301-005.01P1601301-006.01P1601301-007.01P1601301-008.01P1601301-009.01

Do containers have appropriate preservation, according to method/SOP or Client specified information?

Does the client/method/SOP require that the analyst check the sample pH and if necessary alter it?

Receipt / Preservation

P1601301-001.01P1601301-002.01P1601301-003.01P1601301-004.01

P1601301-010.01

Reference ID as 031216-TB

P1601301-011.01P1601301-012.01P1601301-013.01

Explain any discrepancies: (include lab sample ID numbers):

7 of 40

TO3_C1C6-SCGC.XLS - Page No.:P1601301_C1-C6_1603141022_SC.xls - TO-3

ALS ENVIRONMENTAL

RESULTS OF ANALYSISPage 1 of 1

Client: Southern California Gas CompanyClient Project ID: ALS Project ID: P1601301

Methane

Test Code: EPA TO-3 ModifiedInstrument ID: HP5890 II/GC8/FID Date(s) Collected: 3/12/16Analyst: Wade Henton Date Received: 3/13/16Sampling Media: 6.0 L Silonite Canister(s) Date Analyzed: 3/13/16Test Notes:

Canister Injection Client Sample ID ALS Sample ID Dilution Volume MRL Data

Factor ml(s) ppmV Qualifier

P1601301-002 1.24 1.0 2.6 0.62 P1601301-003 1.69 1.0 2.9 0.85 P1601301-004 1.74 1.0 2.5 0.87 P1601301-005 2.01 1.0 3.1 1.0 P1601301-006 1.66 1.0 2.5 0.83 P1601301-007 1.89 1.0 3.3 0.95 P1601301-008 1.93 1.0 3.1 0.97 P1601301-009 1.62 1.0 2.9 0.81 P1601301-010 1.73 1.0 2.9 0.87 P1601301-011 1.55 1.0 3.0 0.78 P1601301-012 1.97 1.0 2.9 0.99 P1601301-013 1.00 1.0 ND 0.50 P160313-MB 1.00 1.0 ND 0.50

ND = Compound was analyzed for, but not detected above the laboratory reporting limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.

031216-TB

AA-04-031216AA-05-031216AA-06-031216SS-3H-031216SF-1-031216

Method Blank

SF-2/5-031216Corbin-031216PorterValley-031216Reseda-031216

ResultppmV

SOUTHERN CALIFORNIA GAS - ALISO CANYON STATION / 14424

AA-02-031216AA-03-031216

8 of 40

TO3_C1C6-SCGC.XLS - Page No.:P1601301_C1-C6_1603141022_SC.xls - LCS

ALS ENVIRONMENTAL

LABORATORY CONTROL SAMPLE SUMMARYPage 1 of 1

Client: Southern California Gas CompanyClient Sample ID: Lab Control Sample ALS Project ID: P1601301Client Project ID: ALS Sample ID: P160313-LCS

Test Code: EPA TO-3 Modified Date Collected: NAInstrument ID: HP5890 II/GC8/FID Date Received: NAAnalyst: Wade Henton Date Analyzed: 3/13/16Sampling Media: 6.0 L Silonite Canister Volume(s) Analyzed: NA ml(s)Test Notes:

ALSCompound Data

Limits QualifierMethane 1,020 954 94 83-107


Spike AmountppmV

Acceptance% RecoveryResultppmV

9 of 40

SULFUR-SCGC.XLS - Page No.:P1601301_ASTM5504_1603141020_SC.xls - Sample (2)

ALS ENVIRONMENTAL


Client: Southern California Gas CompanyClient Sample ID: AA-02-031216 ALS Project ID: P1601301Client Project ID: ALS Sample ID: P1601301-002

Test Code: ASTM D 5504-12 Date Collected: 3/12/16Instrument ID: Agilent 6890A/GC13/SCD Time Collected: 00:48Analyst: Wade Henton Date Received: 3/13/16Sample Type: 6.0 L Silonite Canister Date Analyzed: 3/13/16Test Notes: Time Analyzed: 12:10 Volume(s) Analyzed: 1.0 ml(s)

Initial Pressure (psig): -2.07 Final Pressure (psig): 1.00

Canister Dilution Factor: 1.24

CAS # Compound Result MRL DatappbV ppbV Qualifier

7783-06-4 Hydrogen Sulfide ND 6.2 463-58-1 Carbonyl Sulfide ND 6.2 74-93-1 Methyl Mercaptan ND 3.1 75-08-1 Ethyl Mercaptan ND 3.1 75-18-3 Dimethyl Sulfide ND 3.1 75-15-0 Carbon Disulfide ND 3.1 75-33-2 Isopropyl Mercaptan ND 3.1 75-66-1 tert-Butyl Mercaptan ND 3.1 107-03-9 n-Propyl Mercaptan ND 3.1 110-01-0 Tetrahydrothiophene ND 3.1



10 of 40


ALS ENVIRONMENTAL










11 of 40


ALS ENVIRONMENTAL










12 of 40


ALS ENVIRONMENTAL







7783-06-4 Hydrogen Sulfide ND 10 463-58-1 Carbonyl Sulfide ND 10 74-93-1 Methyl Mercaptan ND 5.0 75-08-1 Ethyl Mercaptan ND 5.0 75-18-3 Dimethyl Sulfide ND 5.0 75-15-0 Carbon Disulfide ND 5.0 75-33-2 Isopropyl Mercaptan ND 5.0 75-66-1 tert-Butyl Mercaptan ND 5.0 107-03-9 n-Propyl Mercaptan ND 5.0 110-01-0 Tetrahydrothiophene ND 5.0



13 of 40


ALS ENVIRONMENTAL










14 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanyClient Sample ID: SS-3H-031216 ALS Project ID: P1601301Client Project ID: ALS Sample ID: P1601301-007








15 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanyClient Sample ID: SF-1-031216 ALS Project ID: P1601301Client Project ID: ALS Sample ID: P1601301-008








16 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanyClient Sample ID: SF-2/5-031216 ALS Project ID: P1601301Client Project ID: ALS Sample ID: P1601301-009








17 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanyClient Sample ID: Corbin-031216 ALS Project ID: P1601301Client Project ID: ALS Sample ID: P1601301-010








18 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanyClient Sample ID: PorterValley-031216 ALS Project ID: P1601301Client Project ID: ALS Sample ID: P1601301-011








19 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanyClient Sample ID: Reseda-031216 ALS Project ID: P1601301Client Project ID: ALS Sample ID: P1601301-012








20 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanyClient Sample ID: 031216-TB ALS Project ID: P1601301Client Project ID: ALS Sample ID: P1601301-013







21 of 40

SULFUR-SCGC.XLS - Page No.:P1601301_ASTM5504_1603141020_SC.xls - MBlank

ALS ENVIRONMENTAL


Client: Southern California Gas CompanyClient Sample ID: Method Blank ALS Project ID: P1601301Client Project ID: ALS Sample ID: P160313-MB

Test Code: ASTM D 5504-12 Date Collected: NAInstrument ID: Agilent 6890A/GC13/SCD Time Collected: NAAnalyst: Wade Henton Date Received: NASample Type: 6.0 L Silonite Canister Date Analyzed: 3/13/16Test Notes: Time Analyzed: 11:44 Volume(s) Analyzed: 1.0 ml(s)





22 of 40

SULFUR-SCGC.XLS - Page No.:P1601301_ASTM5504_1603141020_SC.xls - MBlank (2)

ALS ENVIRONMENTAL


Client: Southern California Gas CompanyClient Sample ID: Method Blank ALS Project ID: P1601301Client Project ID: ALS Sample ID: P160313-MB

Test Code: ASTM D 5504-12 Date Collected: NAInstrument ID: Agilent 7890A/GC22/SCD Time Collected: NAAnalyst: Wade Henton Date Received: NASample Type: 6.0 L Silonite Canister Date Analyzed: 3/13/16Test Notes: Time Analyzed: 12:56 Volume(s) Analyzed: 1.0 ml(s)





23 of 40

SULFUR-SCGC.XLS - Page No.:P1601301_ASTM5504_1603141020_SC.xls - LCS

ALS ENVIRONMENTAL



Test Code: ASTM D 5504-12 Date Collected: NAInstrument ID: Agilent 6890A/GC13/SCD Date Received: NAAnalyst: Wade Henton Date Analyzed: 3/13/16Sample Type: 6.0 L Silonite Canister Volume(s) Analyzed: NA ml(s)Test Notes:

ALS

CAS # Compound Spike Amount Result % Recovery Acceptance DatappbV ppbV Limits Qualifier

7783-06-4 Hydrogen Sulfide 2,000 2,330 117 65-138 463-58-1 Carbonyl Sulfide 2,000 2,440 122 60-135 74-93-1 Methyl Mercaptan 2,000 2,420 121 57-140


24 of 40

SULFUR-SCGC.XLS - Page No.:P1601301_ASTM5504_1603141020_SC.xls - LCS (2)

ALS ENVIRONMENTAL



Test Code: ASTM D 5504-12 Date Collected: NAInstrument ID: Agilent 7890A/GC22/SCD Date Received: NAAnalyst: Wade Henton Date Analyzed: 3/13/16Sample Type: 6.0 L Silonite Canister Volume(s) Analyzed: NA ml(s)Test Notes:

ALS

CAS # Compound Spike Amount Result % Recovery Acceptance DatappbV ppbV Limits Qualifier

7783-06-4 Hydrogen Sulfide 2,000 2,420 121 65-138 463-58-1 Carbonyl Sulfide 2,000 2,420 121 60-135 74-93-1 Methyl Mercaptan 2,000 2,420 121 57-140


25 of 40

TO15-SCGC.XLS - Page No.:P1601301_TO15_1603141045_SC.xls - Sample (2)

ALS ENVIRONMENTAL


Client: Southern California Gas CompanyAA-02-031216 ALS Project ID: P1601301

ALS Sample ID: P1601301-002

Test Code: EPA TO-15 Date Collected: 3/12/16Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: 3/13/16Analyst: Wida Ang Date Analyzed: 3/13/16Sample Type: 6.0 L Silonite Canister Volume(s) Analyzed: 1.00 Liter(s)Test Notes: Container ID: AS01000



CAS # Compound MRL DatappbV Qualifier

71-43-2 Benzene 0.21 0.039 108-88-3 Toluene 0.31 0.16 100-41-4 Ethylbenzene ND 0.14 179601-23-1 m,p-Xylenes 0.15 0.14 95-47-6 o-Xylene ND 0.14


ppbV

Client Sample ID:Client Project ID: SOUTHERN CALIFORNIA GAS - ALISO CANYON STATION / 14424

Result

26 of 40


ALS ENVIRONMENTAL








71-43-2 Benzene 0.13 0.053 108-88-3 Toluene ND 0.22 100-41-4 Ethylbenzene ND 0.19 179601-23-1 m,p-Xylenes ND 0.19 95-47-6 o-Xylene ND 0.19


ppbV


Result

27 of 40


ALS ENVIRONMENTAL










ppbV


Result

28 of 40


ALS ENVIRONMENTAL










ppbV


Result

29 of 40


ALS ENVIRONMENTAL








71-43-2 Benzene 0.17 0.052 108-88-3 Toluene 0.25 0.22 100-41-4 Ethylbenzene ND 0.19 179601-23-1 m,p-Xylenes ND 0.19 95-47-6 o-Xylene ND 0.19


ppbV


Result

30 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanySS-3H-031216 ALS Project ID: P1601301








ppbV


Result

31 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanySF-1-031216 ALS Project ID: P1601301








ppbV


Result

32 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanySF-2/5-031216 ALS Project ID: P1601301








ppbV


Result

33 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanyCorbin-031216 ALS Project ID: P1601301








ppbV


Result

34 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanyPorterValley-031216 ALS Project ID: P1601301






71-43-2 Benzene 0.22 0.049 108-88-3 Toluene 0.37 0.21 100-41-4 Ethylbenzene ND 0.18 179601-23-1 m,p-Xylenes 0.19 0.18 95-47-6 o-Xylene ND 0.18


ppbV


Result

35 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas CompanyReseda-031216 ALS Project ID: P1601301








ppbV


Result

36 of 40


ALS ENVIRONMENTAL


Client: Southern California Gas Company031216-TB ALS Project ID: P1601301





71-43-2 Benzene ND 0.031 108-88-3 Toluene ND 0.13 100-41-4 Ethylbenzene ND 0.12 179601-23-1 m,p-Xylenes ND 0.12 95-47-6 o-Xylene ND 0.12


ppbV


Result

37 of 40

TO15-SCGC.XLS - Page No.:P1601301_TO15_1603141045_SC.xls - MBlank

ALS ENVIRONMENTAL


Client: Southern California Gas CompanyMethod Blank ALS Project ID: P1601301

ALS Sample ID: P160313-MB Test Code: EPA TO-15 Date Collected: NAInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: NAAnalyst: Wida Ang Date Analyzed: 3/13/16Sample Type: 6.0 L Silonite Canister Volume(s) Analyzed: 1.00 Liter(s)Test Notes:



71-43-2 Benzene ND 0.031 108-88-3 Toluene ND 0.13 100-41-4 Ethylbenzene ND 0.12 179601-23-1 m,p-Xylenes ND 0.12 95-47-6 o-Xylene ND 0.12


ResultppbV


38 of 40

TO15-SCGC.XLS - Page No.:P1601301_TO15_1603141045_SC.xls - Surrogates

ALS ENVIRONMENTAL

SURROGATE SPIKE RECOVERY RESULTSPage 1 of 1

Client: Southern California Gas CompanyALS Project ID: P1601301

Test Code: EPA TO-15Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date(s) Collected: 3/12/16Analyst: Wida Ang Date(s) Received: 3/13/16Sample Type: 6.0 L Silonite Canister(s) Date(s) Analyzed: 3/13 - 3/14/16Test Notes:

Client Sample ID ALS Sample ID Acceptance DataLimits Qualifier

P160313-MB 70-130 P160313-LCS 70-130 P1601301-002 70-130 P1601301-003 70-130 P1601301-004 70-130 P1601301-005 70-130 P1601301-006 70-130 P1601301-007 70-130 P1601301-008 70-130 P1601301-009 70-130 P1601301-010 70-130 P1601301-011 70-130 P1601301-012 70-130 P1601301-013 70-130

Surrogate percent recovery is verified and accepted based on the on-column result.Reported results are shown in concentration units and as a result of the calculation, may vary slightly from the on-column percent recovery.

031216-TB

PorterValley-031216Reseda-031216

AA-05-031216

AA-03-031216AA-04-031216

AA-06-031216

Corbin-031216

88

87

88

Client Project ID:

SS-3H-031216SF-1-031216SF-2/5-031216

10985

86

85

87

87

8787

Recovered109109

AA-02-03121686

87

82 111105Lab Control Sample85

BromofluorobenzenePercentPercent

Method Blank

PercentRecoveredRecovered

Toluene-d81,2-Dichloroethane-d4

107

107

106

107

107107

106 108

109109

107109109

107

109

107


109

108108 109

108107 109

39 of 40

TO15-SCGC.XLS - Page No.:P1601301_TO15_1603141045_SC.xls - LCS

ALS ENVIRONMENTAL


Client: Southern California Gas CompanyLab Control Sample ALS Project ID: P1601301

ALS Sample ID: P160313-LCS

Test Code: EPA TO-15 Date Collected: NAInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: NAAnalyst: Wida Ang Date Analyzed: 3/13/16Sample Type: 6.0 L Silonite Canister Volume(s) Analyzed: 0.125 Liter(s)Test Notes:

CAS # Compound Data Qualifier

71-43-2 Benzene 86 61-110108-88-3 Toluene 106 67-117100-41-4 Ethylbenzene 115 69-123179601-23-1 m,p-Xylenes 112 67-12595-47-6 o-Xylene 112 67-124

Laboratory Control Sample percent recovery is verified and accepted based on the on-column result.Reported results are shown in concentration units and as a result of the calculation, may vary slightly.

Result


ppbV

61.557.9

ALSAcceptanceSpike Amount

Limits% Recovery

70.8 61.1ppbV

48.4 54.1

50.2 57.698.6 110

40 of 40

RIGHT SOLUTIONS | RIGHT PARTNERThe analyses for sample AA-01-031216 (P161301-001) were cancelled...

Documents

Transcript of RIGHT SOLUTIONS | RIGHT PARTNERThe analyses for sample AA-01-031216 (P161301-001) were cancelled...