Review laser ignition for aerospace propulsion · Review: laser ignition for aerospace propulsion...

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HOSTED BY ORIGINAL ARTICLE Review: laser ignition for aerospace propulsion Steven A. OBriant a , Sreenath B. Gupta b , Subith S. Vasu a,n a Department of Mechanical and Aerospace Engineering, Center for Advanced Turbomachinery and Energy Research, University of Central Florida, Orlando, FL, 32816, USA b Argonne National Laboratory, Argonne, IL, 60439, USA Received 13 November 2014; accepted 2 July 2015 Available online 23 February 2016 KEYWORDS Laser ignition; Ignition limit; Scramjet; Gas turbines; Rocket; Plasma ignition; Propulsion Abstract Renewed interest in the use of high-speed ramjets and scramjets and more efcient lean burning engines has led to many subsequent developments in the eld of laser ignition for aerospace use and application. Demands for newer, more advanced forms of ignition, are increasing as individuals strive to meet regulations that seek to reduce the level of pollutants in the atmosphere, such as CH x , NO x , and SO 2 . Many aviation gas turbine manufacturers are interested in increasing combustion efciency in engines, all the while reducing the aforementioned pollutants. There is also a desire for a new generation of aircraft and spacecraft, utilizing technologies such as scramjet propulsion, which will never realize their fullest potential without the use of advanced ignition processes. These scenarios are all limited by the use of conventional spark ignition methods, thus leading to the desire to nd new, alternative methods of ignition. This paper aims to provide the reader an overview of advanced ignition methods, with an emphasis on laser ignition and its applications to aerospace propulsion. A comprehensive review of advanced ignition systems in aerospace applications is performed. This includes studies on gas turbine applications, ramjet and scramjet systems, and space and rocket applications. A brief overview of ignition and laser ignition phenomena is also provided in earlier sections of the report. Throughout the reading, research papers, which were presented at the 2nd Laser Ignition Conference in April 2014, are mentioned to indicate the vast array of projects that are currently being pursued. & 2016 National Laboratory for Aeronautics and Astronautics. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). http://ppr.buaa.edu.cn/ www.sciencedirect.com Propulsion and Power Research 2212-540X & 2016 National Laboratory for Aeronautics and Astronautics. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). http://dx.doi.org/10.1016/j.jppr.2016.01.004 n Corresponding author. Tel.: þ1 407 823 3468. E-mail address: [email protected] (Subith S. Vasu). Peer review under responsibility of National Laboratory for Aeronautics and Astronautics, China. Propulsion and Power Research 2016;5(1):121

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Page 1: Review laser ignition for aerospace propulsion · Review: laser ignition for aerospace propulsion Steven A. O’Brianta, Sreenath B. Guptab, ... have suggested detonation as a form

http://ppr.buaa.edu.cn/

H O S T E D B Y

www.sciencedirect.com

Propulsion and Power Research

Propulsion and Power Research 2016;5(1):1–21

2212-540X & 2016 NaCC BY-NC-ND licens

http://dx.doi.org/10.10

nCorresponding auth

E-mail address: su

Peer review under r

ORIGINAL ARTICLE

Review: laser ignition for aerospace propulsion

Steven A. O’Brianta, Sreenath B. Guptab, Subith S. Vasua,n

aDepartment of Mechanical and Aerospace Engineering, Center for Advanced Turbomachinery and Energy Research,University of Central Florida, Orlando, FL, 32816, USAbArgonne National Laboratory, Argonne, IL, 60439, USA

Received 13 November 2014; accepted 2 July 2015Available online 23 February 2016

KEYWORDS

Laser ignition;Ignition limit;Scramjet;Gas turbines;Rocket;Plasma ignition;Propulsion

tional Laboratory foe (http://creativecom

16/j.jppr.2016.01.00

or. Tel.: þ1 407 82

[email protected] (Subit

esponsibility of Nat

Abstract Renewed interest in the use of high-speed ramjets and scramjets and more efficientlean burning engines has led to many subsequent developments in the field of laser ignition foraerospace use and application. Demands for newer, more advanced forms of ignition, areincreasing as individuals strive to meet regulations that seek to reduce the level of pollutants inthe atmosphere, such as CHx, NOx, and SO2. Many aviation gas turbine manufacturers areinterested in increasing combustion efficiency in engines, all the while reducing theaforementioned pollutants. There is also a desire for a new generation of aircraft andspacecraft, utilizing technologies such as scramjet propulsion, which will never realize theirfullest potential without the use of advanced ignition processes. These scenarios are all limitedby the use of conventional spark ignition methods, thus leading to the desire to find new,alternative methods of ignition.This paper aims to provide the reader an overview of advanced ignition methods, with anemphasis on laser ignition and its applications to aerospace propulsion. A comprehensivereview of advanced ignition systems in aerospace applications is performed. This includesstudies on gas turbine applications, ramjet and scramjet systems, and space and rocketapplications. A brief overview of ignition and laser ignition phenomena is also provided inearlier sections of the report. Throughout the reading, research papers, which were presented atthe 2nd Laser Ignition Conference in April 2014, are mentioned to indicate the vast array ofprojects that are currently being pursued.& 2016 National Laboratory for Aeronautics and Astronautics. Production and hosting by Elsevier B.V.

This is an open access article under the CC BY-NC-ND license

(http://creativecommons.org/licenses/by-nc-nd/4.0/).

r Aeronautics and Astronautics. Produmons.org/licenses/by-nc-nd/4.0/).

4

3 3468.

h S. Vasu).

ional Laboratory for Aeronautics and

ction and hosting by Elsevier B.V. This is an open access article under the

Astronautics, China.

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Steven A. O’Briant et al.2

1. Overview of laser ignition

Ignition is defined as the transformation process of acombustible material, from an unreactive state to a self-propagating state, where the ignition source can be removedwithout extinguishing the combustion process [1]. In thepast century, electrical sparks have been the predominantform of accomplishing this process. The desire to achieve amore advanced form of ignition stems from the need toacquire a more efficient ignition of combustible materials,while avoiding undesirable explosions during the process.According to Cardin et al, ignition can be summarized inthree successive stages [2]. First, the spark creates initialignition conditions for energy deposition. The initial break-down phase results in microsecond scale emissions, fol-lowed by a glow discharge phase which deposits most ofthe energy. The spark is then fully ionized and containsplasma with highly reactive chemical species. After break-down, the plasma grows and cools. High discontinuitiesexist between the spark and outer environment, such astemperature and pressure, which lead to the development ofa shock wave around the plasma. The shock wave isextremely energetic but cannot ignite the surroundingmixture due to a short propagation time. In the secondstage of ignition, the flame develops depending on theinitiation of the chemical reactions, which determineswhether or not the transition from a kernel of hot gas to aself-sustained flame kernel is possible. Radicals are vital tothe ignition process and must be produced in an appropriatequantity during the initiation of the chemical reaction topermit successful ignition of the flame kernel. The finalstage of ignition is flame kernel propagation, which leads toflame growth and wrinkling.According to classical combustion theory, two modes of

flame propagation exist, known as deflagrations and deto-nations [1,3,4]. Deflagrations are characterized by subsonicpropagation rates with approximately uniform pressureacross the front and reduced density behind the front.Deflagrations may be thought of as thermal conductionwaves sustained by a chemical heat release. As opposed todeflagrations, detonations have supersonic propagation ratesrelative to unburned material. There are substantial pressureincreases across the front with a slightly increased densitybehind it. Detonations may be represented by shock frontssustained by a chemical heat release. Deflagrations are theprimary form of flame propagation in practically allcombustion engines and systems. Though some papers [1]have suggested detonation as a form of propulsion foraircraft (such as a pulse detonation engine), detonation istypically an unwanted characteristic in aerospace applica-tions, and steps are usually taken to prevent deflagration-to-detonation transitions (DDT).Lewis and von Elbe [3] provide a phenomenological

description of deflagrations in premixed gases. If ignitionenergy is greater than the minimum ignition energy (MIE,Ef), at the time when peak temperature decays to theadiabatic flame temperature, Tf, heat is generated in the

kernel quicker than it is lost via conduction to the unburnedmixture. A steady, self-sustaining deflagration wave resultsfrom this ignition and consumes the remaining combustiblemixture. However, if the amount of energy is at a subcriticallevel, below the MIE, and is delivered to the combustiblemixture, the resulting flame kernel decays at a rapid rate.This is because the heat and radicals are lost, away from thesurface of the kernel, and dissociated species recombinefaster than they are regenerated. A realistic conclusion issuch that the MIE must be sufficient to raise a sphere of gas,whose radius is the characteristic flame thickness, δf, to theadiabatic flame temperature. Typical values of Ef are 0.4 mJfor stoichiometric CH4-air mixtures and 0.02 mJ for stoi-chiometric H2-air mixtures [3]. An estimation for the MIEof deflagration can be seen below in Eq. (1) [1,5], where ρfrefers to the density and cp is the specific heat at constantpressure.

Ef �4π3δ3f ρf cp Tf �T0

� � ð1Þ

Measurements by McNeill et al. [6] performed on combus-tion ignition processes by electrical and non-resonant lasersparks describe how spark formation and the subsequentflows (prior to combustion) contribute to minimum ignitionenergy values. The MIE for laser sparks is found to be higherthan electrical sparks, due to the higher energy cost ofcreating a laser spark and because of efficient removal ofthe energy absorbed in laser sparks to regions outside thenominal ignition kernel. However, before that study, therewere a wide range of MIE values being reported, with nopaper published relating the interrelated breakdown and shockphenomena as contributors to a system's ignitability. McNeillet al. found several factors that influence higher MIE's in laserspark ignition. First, additional energy is required for laserbreakdown to create a seed electron at the beam focus inorder to heat plasma. At threshold, the energy alone can behigher than the thermal MIE, but the breakdown energy couldbe reduced using a two wavelength system. The existingrelationship between laser breakdown energy and lens focallength suggests that with a very short focal length, the MIEfor laser spark ignition may approach that of an electricalspark ignition. Certain resonant laser ignition schemes, wherea laser is tuned to a transition of a fuel, allows photolysis ofcombustible fuel mixtures, lowering the required energy forignition. Secondly, laser sparks are more efficient at generat-ing shocks which propagate omnidirectionally. This is mainlydue to equilibration, a condition where a shock wavedevelops after energy delivered to the plasma electronstransfers to the ions. Denser laser spark plasmas makeequilibration more efficient than typical electrical sparks, thuscollisional processes prevail and radiative losses are lower.Thirdly, most of the stored laser energy is carried out of thenominal ignition-kernel volume by the shock, and no addi-tional heating occurs after the shock departs. Normally,supplemental heating occurs in the ignition-kernel volumefor electrical sparks, but this effect is absent for laser ignition,contributing to a higher MIE.

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Review: laser ignition for aerospace propulsion 3

1.1. Fundamentals of the laser ignition process

According to Ronney [1], laser ignition can be character-ized into four categories. Thermal initiation is the first ofthese types, where no electrical breakdown of gas occurs. Inthermal initiation, the laser source heats up a solid target orexcites vibrational/rotational modes of different gas mole-cules. The second type is non-resonant breakdown, which isconsidered by Tauer et al. [5] to be the most appropriatemechanism for ignition. In non-resonant breakdown, theelectrical field strength of a focused laser beam is enough tocause an electrical breakdown of a gas, and is most similarto standard electric spark discharges. A main differencebetween laser ignition and spark ignition is that smallamounts of vapor, dust, and microparticles can reduce thebreakdown field strength by orders of magnitude, whereaselectrical spark discharges are not usually affected by suchphenomena. The third type of laser ignition is resonantbreakdown, which is similar to non-resonant breakdown,but includes a non-resonant multiphoton photodissociationof a molecule, followed by a resonant photoionization ofatoms created by the previous photodissociation. The finaltype of laser ignition is photochemical ignition, in which asingle photon, typically in the UV range, undergoesdissociation after being absorbed by a molecule. Directheating of the gas may occur, but due to the species being inthermal non-equilibrium, they may recombine with them-selves or other molecules.

When applying the concept of laser ignition to actualapplication, laser-induced optical breakdown for the use ofigniting combustible gas mixtures may be done by usinglaser ablation ignition (LAI) or laser plasma ignition (LPI)[5]. In laser ablation ignition, a laser beam focuses on atarget, generating optical breakdown once the intensity inthe focal region exceeds a certain threshold. In laser plasmaignition, the concept is the same, but the laser beam istightly focused into the combustion chamber, and theplasma is formed in free space as opposed to a target inlaser ablation. Typically, this threshold for plasma forma-tion in LPI is one hundred times greater than target surfacesin LAI. Laser ablation is typically employed for use inrocket engines and spacecraft designs because, just as inchemical rockets, thrust is produced from the resultingreaction force. Plasma ignition on the other hand, istypically found in internal engines, since ignition of theplasma drives moving parts, such as in a cylinder. In eithercase, plasma formation is based on ionization of atoms andmolecules around the focal point followed by accelerationof ionized electrons. This causes collisions with moreneutral atoms of molecules.

1.2. Aerospace applications

Applying the concept of laser ignition to extreme flightregimes, such as supersonic and hypersonic flows, is one ofthe most challenging, yet fruitful pursuits in the field of

aviation. There are many benefits to all areas of aerospacestudy. Possibilities include multiple ignition positions intime and space, precise ignition timing, controllability ofinput energy and its duration, more stable combustion,ignition of leaner fuel mixtures, and ignition of highpressure mixtures [7]. Generation and maintenance of alaser is also much less than other forms of ignition, makingthe prospect of laser ignition promising from an economicstandpoint. In supersonic and hypersonic engines, such asscramjets, internal regions where combustion occurs canreceive energy instantaneously through laser igniters, with-out using electrodes, found in conventional ignition meth-ods. Since the laser ignition system is electrodeless, thereare no cooling effects associated with electrode use [8].Laser use also allows the laser radiation energy to focus itsintensity directly on the jet fuel, creating a spark [9,10].Laser ignition offers several advantages in internal combus-tion engines as well, such as the absence of electrodeswhich disturb the cylinder geometry (thus quenching aflame kernel), and variable ignition positions within thecombustion cylinder [7].

Using a laser ignition system with the aforementionedbenefits would allow for progress in the field of hypersonicaviation. An aircraft travelling at hypersonic speeds cancover immense ground in a short period of time. Forexample, a hypersonic aircraft travelling at Mach 5 cancover 7600 miles in roughly a 2 hour time frame. Con-sidering that the distance between Los Angeles and Tokyois approximately 5400 miles, a hypersonic flight carryingcommercial goods and/or passengers over the Pacific Oceancan be completed in almost 90 minutes; a huge improve-ment over the current average 11 hour flight. Thoughseveral commercial platforms have been proposed, suchas the Zero Emission Hyper Sonic Transport (ZEHST) andthe SpaceLiner, no company currently operates a supersonicor hypersonic transport vehicle for commercial purposes.Laser ignition offers to help advance technological cap-abilities in this field, which would enable for furthercommercial development.

The concept of laser ignition and propulsion may also beapplied to space travel. Multi-mode engines with built-inscramjet capabilities would allow for quick, cost-effectivetravel outside Earth's atmosphere. Small microsatellites,weighing between 1–10 kg, can also benefit by using onboardlaser propulsion, such as the laser-electrostatic hybrid accel-eration thruster [11], which is discussed later in this report.Ground-to-orbit launch vehicles are also proposed using laserpropulsion, which would allow rockets a high specificimpulse, higher thrust, and a lower propulsion weight.

A high-speed engine also has numerous military applica-tions. A scramjet engine can be utilized in next generationICBMs (Intercontinental Ballistic Missile) and militaryaircraft, which would be able to reach distant battlefieldsacross the globe in minutes, rather than hours. The UnitedStates Air Force (USAF) has experimented with theviability of air-breathing, high-speed scramjet propulsionin the form of the X-51A Waverider. During its final flight

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Figure 1 X-51A Waverider attached to B-52 mothership.(source: United States Air Force).

Steven A. O’Briant et al.4

in 2013, the X-51A was dropped via B-52 and used a solidrocket booster for its initial stage of flight, travelling over230 nautical miles in six minutes at Mach 5, setting a recordfor the longest hypersonic air-breathing flight ever. The X-51A can be seen in Figure 1, attached to its mothership, aB-52 Stratofortress. Though the X-51A does not utilizelaser ignition, it nonetheless demonstrates the importance offurther researching laser ignition, which will help perfectscramjet technology.The large range of flight conditions experienced by ramjets

and scramjets greatly affect how future high-speed aircrafts aredesigned. The conditions for safe flight may be defined as theflight envelope, with both an upper and lower limit. At higherMach numbers (M415), nonequilibrium flow in the regionfollowing leading shock waves can influence compressionramp flow, reducing fuel injection efficiency, as well asmixing and combustion efficiency [12]. This leads to largedecreases in engine performance and sets the upper limit of theflight envelope at a dynamic pressure of roughly 0.25–0.5 atm.At lower Mach numbers (Mo3), it is shown that ramjetoperation is insufficient due to poor compression ratios fromairflow deceleration. This, alongside thermal and structurallimitations, set the lower boundary of the flight envelope, andare limited by a dynamic pressure of 1 atm. Using laserigniters can extend the boundaries of the flight envelope, asplasma-assisted ignition can stabilize ultra-fast combustion athigher Mach regimes (M¼10–20) and higher altitudes,making it possible to reach regions of low dynamic pressures(0.05–0.2 atm) [12].

2. Advanced ignition in aerospace systems

Several categories of engines can benefit from laser ignition.Though all engines could potentially benefit from moreadvanced ignition methods, such as laser-induced plasmaignition, This section describes the following aeronautical andspace applications:

1. Gas turbines, including discussions on new laser “sparkplugs” and microwave assisted ignition and their effectson kernel formation.

2. Plasma-assisted ignition, using both conventional elec-trical spark ignition and laser-induced ignition.

3. Ramjet/scramjet applications and progress thus far,including sections on geometric variances and differentfuel characteristics.

4. Space applications, to include studies on laser ablation,applications in rocket design and satellite microthrusters.

2.1. Gas turbines and gas engines

Laser ignition may be used in various applicationsbesides high-speed, hypersonic aircraft. Examples includestandard internal combustion engines, such as in automo-biles and aircraft, as well as industrial combustion facilitieswhich generate large amounts power. There are severalpatents [13,14] which have already expressed possible usesfor their inventions in turbojet, turbofan, turboprop, and gasturbine applications. There are also studies, discussedbelow, that aim to develop a laser “spark plug” that isminiature in size and can fit directly on an internalcombustion engine. Pursuing laser ignition in gas turbinesystems helps to realize the added benefits of higher engineefficiency and lower pollutant levels in engines that arealready in wide scale use today. This section offers tosummarize the most current works in the above areas with afocus on gas turbines, gas engines, and methane-airmixtures.

In high-power gas engines, it is often desirable tominimize service effort and keep maintenance to a mini-mum. Lamp-pumped lasers employ short lifetime arc lampswhich are usually changed every 200 to 600 hours. Theiroptical alignment drifts over time as well, leading toincreases in downtime. Laser output usually suffers sincefrequent realignments are needed. Diode-pumped solid-statelasers offers to remedy these issues, as these lasers convertmost of their electrical input into laser light. Diode-pumpedlasers contain a higher electrical efficiency, require lesscooling water, operate from lower-voltage power supplies,are more compact, and provide many years of uninterruptedoperation. These advantages all serve to keep repair andmaintenance costs down.

Expanding on earlier work done in 2000 [15], Kopeceket al. [16] performed further experiments in a 2005 study onmethane-air mixtures at high pressures and high tempera-tures using solid-state lasers via non-resonant optical break-down. Since laser energy is deposited on the order ofnanoseconds, generated shock waves and asymmetricshapes of the flame kernel greatly influence combustion,leading to the desire to determine qualitative and quantita-tive properties of laser ignition using diagnostic methods.Very lean fuel mixtures with an air/fuel-equivalence ratio ofup to λ¼2.2 were successfully ignited with a Q-switchedNd:YAG (neodymium doped yttrium aluminum garnet)laser. However, only ratios below λ¼2.0 were found tobe of practical use (due to increases in ignition delay timeand lower peak pressures). This is considerably leaner than

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Figure 2 Averaged shapes of transmitted pulses based on inputenergy [16].

Figure 3 Shadowgraph of kernel growth rates, λ¼0.8 [17] (reprintedwith permission).

Review: laser ignition for aerospace propulsion 5

the limits imposed by ignition via conventional spark plugs(a limit of λ¼1.8 for commercial gas engines). A compactdiode-pumped laser could easily replace a conventionalspark plug and provide the required pulse energy (4 to6 mJ) for mixtures up to λ¼1.8. Time-resolved transmis-sion measurements were taken in the paper, giving anindication for the ideal pulse shape of future laser-ignitionsystems, as shown in Figure 2 below. This ideal pulse shapeshould have a very steep increase for effective plasmaformation, followed by a smooth descent to sustain theplasma as long as possible to heat up the flame kernel. Theminimum ignition energy was found to decrease as themean pressure increased. Kopecek et al. demonstrated theusefulness of laser ignition by combusting an air/fuelmixture in one cylinder of a 1 MW natural gas internalcombustion engine. A 5 ns pulsed Nd:YAG laser at1064 nm was used to ignite the mixture. The engine workedsuccessfully during a test period of 100 hours with nointerruption at a ratio of λ¼1.8. A minimum NOx emissionvalue was achieved at λ¼2.05 (where NOx¼0.22 g/kWh).

Studies conducted by Michael et al. [17], Wolk et al.[18], and Hayashi et al. [19] provide a possible alternativeprocess to methane-air combustion: laser-initiated micro-wave-enhanced ignition. There are several advantages byadding sequential microwave pulses following ignition,such as lower laser energy requirements, reduction in theignition delay time, and a large ignition volume. This typeof ignition is only limited by microwave wavelength andseed ionization profile (the placement of a seed laser, pulsedfor initial ionization). Adding sequential microwave pulsesafter ignition allows additional deposits of energy into theflame zone, increasing the kernel growth rate. Throughearly numerical simulations [17], energy densities depositedby the laser and microwave pulses estimate that microwavedeposition is several orders of magnitude stronger than laserenergy deposition. A preliminary investigation on the effectof rapid microwave pulse trains on ignition kernel forma-tion and growth show there is a considerable increase in

growth rate when the addition of energy takes place in thefirst few milliseconds after ignition. Wolk et al. theorize thatflame enhancement results from non-thermal chemicalkinetic enhancement from energy deposition to free elec-trons in the flame front, and induced flame wrinkling fromexcitation of plasma instability. It is shown from thesefindings that flame enhancement is negligible above aninitial pressure mixture of 3 bar (conducted in a constantvolume chamber). Hayashi et al. demonstrate that themicrowave-enhanced plasma technique extended plasmalife and lowered the minimum pulse energy for laserignition. This is true for a wide range of excess air ratios(0.6 to 1.54).

Findings from Michael et al. show two kernel growth ratesseen in Figure 3: (a) represents the kernel without additionalmicrowave pulses, while (b) has added microwave pulses at1 and 2 ms. Figure 4 shows kernel growth rates with nomicrowave pulses in the top row, and additional microwavepulses in the bottom row, at several millisecond intervals [18].In both figures, there is a significant increase in the diameter ofthe kernel in the bottom row of image, indicating the valuablepotential of microwave-enhanced ignition.

Knowledge of the minimum ignition energy is essentialto the application of laser ignition in the aforementionedmethane-air combustion studies. A recent study by Penget al. [20] tackles the issue of measuring the MIE in highpressure methane-air mixtures in premixed turbulent com-bustion conditions (similar to Kopecek et al.). A high-pressure, double-chamber (high-pressure outer chamber anda high-pressure fan stirred mixing chamber) explosionfacility, characterized by turbulent properties and

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Figure 4 Schlieren imaging of kernel growth rates, λ¼0.65, 0.75,0.85 [18] (reprinted with permission).

Steven A. O’Briant et al.6

controllable ignition, was used to measure the MIE andflame kernel formation. Findings indicate that MIEdecreases significantly with increasing pressure at any giventurbulence (agreeing with findings in Kopecek et al.), butincreases with increasing turbulence at a fixed pressure. Byvarying the turbulence in the system, three modes of flamekernel development are observed, similar to laminar,turbulent-flamelet, and distributed flames. The mechanismof flame kernel formation depends on the surface diffusivityratio between turbulence and the chemical reaction, repre-sented by the value Pe*. Pe* is the reaction zone Pécletnumber with pressure correction. The modified reactionzone Pe*, introduced in this paper, is shown below in Eq.(2), with p/p0 representing the ratio of test pressure toatmospheric pressure.

Pe� ¼ Pep

p0

� ��1=4

ð2Þ

The author recommends a model based on the balance oflocal ignition energy input and heat losses of ignitionkernels in high-pressure turbulent environment to predictMIE transitions at elevated pressures. This model, however,does not consider the unsteadiness of the full ignitionprocess.In contrast to performing combustion experiments in an

enclosed, double-chamber explosion facility, Cardin et al.[2] conducted a similar set of experiments meant to analyzethe ignition process of lean, highly turbulent, premixedmethane-air flows in a vertical open wind tunnel. Duringpreliminary studies, it was discovered that during plasmacooling, the net increase in radical emissions defined acharacteristic chemical time (corresponding to the initiationof chain-branching reactions), which increased significantlywith the equivalence ratio in ultra-lean mixtures. Based onthe evidence in this part of the experiment, it was concluded

that the time required to reach a self-sustaining chemicalreaction after breakdown is constant at equivalence ratiosλ40.7. In subsequent tests, the MIE values at differentequivalence ratios experienced a transition when the turbu-lence intensity was increased, thus leading to a much largeramount of energy being required to ignite the flow. This isthe same observation as experienced with the earlier studyby Peng et al. [20]. Before the transition, the smallest timescales of turbulence were larger than the time of initiation ofthe chain-branching reactions, indicating that the hot kerneland turbulence reaction occurred after the time of initiationof chemical reactions. Larger amounts of deposited energyare required to compensate for turbulent dissipation in orderto achieve a self-sustaining flame, due to the hot kernel/turbulent interaction during cooling. Turbulent diffusivityalso played an impact on the MIE/MIE0 ratio (MIE0

equaling the minimum energy in laminar flow), whichdramatically increased with increasing values of Pe* afterpassing the aforementioned transition. This led to signifi-cant heat losses, thus requiring more energy to ignite theflow at higher turbulent regimes.

Drawing from prior research in 2007 and 2008 [21–23],McIntyre et al. [24] present a study focusing on the ignitionand operation of a single cylinder research engine (filledwith either natural gas of hydrogen augmented natural gas)which utilizes a new laser diode end pumped, passively Q-switched laser. A commercial laser spark plug system issought to increase combustion efficiency at leaner mixtures,and the fiber optic coupled end pumped laser spark plugdeveloped by the researchers is stated as a significantadvanced toward producing this system. The work pre-sented extends research performed on a side pumped laserto the development of an end pumped laser system withgreatly improved operational characteristics. The new endpumped laser was packaged in such a fashion that the laserwas relatively insensitive to heat and vibration, allowing thesystem to be directly attached to the test engine. The endpumped laser spark plug was mounted directly to the engineand operated at 1800 rpm (as opposed to earlier works, inwhich the spark plug was detached from the engine andoperated at 600 rpm) for 10 hours. Engine emission datataken during the experiment showed that NOx concentrationincreased with increasing equivalence ratio due to increas-ing combustion temperatures. CO2 concentration levelsincreased and overall hydrocarbons decreased with increas-ing equivalence ratio as well, due to more complete ignitionand combustion. The researchers also added 20% hydrogen(by volume) to the natural gas, which produced results thatconcurred with the researcher's expectations. NOx concen-trations increased with an increasing equivalence ratio, CO2

concentrations reduced across all equivalence ratios (due tooverall availability of carbon in the fuel mix being dilutedby hydrogen), and total hydrocarbons decreased sincemethane was completely burned, and the remainingunburned hydrogen did not add to the concentration ofunburned hydrocarbons. These results were due only tostoichiometric variations in the trials. As far as advantages

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Figure 5 Spherical bomb configuration, situated in thermcraft XSB-12-12-18-1C 6 kW oven.

Review: laser ignition for aerospace propulsion 7

of utilizing the laser spark plug, the experiment showed thatthe laser-ignited engine performed just as well as conven-tional spark ignition, but with the added benefit of smootheroperation and an extension on the lean mixture limit in bothnatural gas and hydrogen augmented natural gas. Futureworks by the authors will include distribution of opticalpumping energy to laser plugs in multiple cylinders.

The main driver for achieving a laser ignition system thatis cost-effective and has a long lifespan is the pump laserbeing used. Schwarz et al. [25] compared two pumpingconcepts for laser ignition in their study for the use of laserspark plugs. The two main concepts studied by Schwarzet al. were edge emitters in combination with gas fibers andVCSELs (vertical cavity surface emitting lasers) in combi-nation with a pump lens. 806 nm edge emitters provedpromising at the start of their study; however, system costsproved to be too large and catastrophic optical damageoccurred. Using a VCSEL in laser ignition allowed theomission of glass fibers, which reduced cost and increasedlifetime value. This concept proved to be the more fruitfulof the two, as it did not fail and met their customer'srequirements of a long life span and relatively low cost.Groneborn et al. recently performed optimizations onVCSEL power arrays, improving the epitaxial design andthe geometrical array layout, reducing the required devicearea by 50%. A complete pump module that delivers a500 W pulse output is designed to fit into a 23 mmdiameter, small enough for an engine, allowing for lowcost, reliable systems as mentioned above.

In addition to different laser ignition systems, studiesperformed by Yamaguchi et al. [26] provide insight andexperimental data on two point laser ignition and conven-tional spark plug ignition in a single cylinder, lean burn gasengine. With an equivalence ratio of λ¼0.8, two-pointignition showed a more rapid rise in pressure as comparedto single point ignition. The widest stable operational rangeis achieved with two-point laser ignition (when comparedwith two point spark plug ignition), and yielded higherthermal efficiency and superior IMEP (indicated meaneffective pressure) stability. Further studies by Shionoet al. [27] investigate two-point laser-induced sparks fromthe perspective of flame kernel formation. During flamekernel formation, a third “lobe”, which is a geometricdescription of the flame kernel itself, may appear. This lobe,which is a characteristic behavior of laser ignition, is notobserved at a pressure of 1 MPa for focal point gaps of 0, 1,and 2 mm. Typically, the presence of a third lobe helps withinitial flame development. The growth of the flame kernelhowever, is clearly enhanced at 1 mm with a 1 MPapressure in the absence of the third lobe.

Saito et al. [28] recently performed tests with laser-inducedignition in an internal combustion engine using an inert gasdilution. In a previous study by the authors, it was found thatthe in-cylinder pressure and rate of heat release rose faster withlaser ignition over spark ignition, leading to a more stableoperation of the engine at high EGR (exhaust gas recirculation)fractions utilizing laser ignition. Confirming earlier studies, laser

ignition allowed for faster flame propagation, leading to ashorter ignition delay time. At high dilution rates, the operationof the gasoline engine was more stable with laser-inducedignition over conventional spark ignition, and had alarger IMEP.

An alternate method of studying fundamental laserignition is via a spherical bomb, as described by Vasuet al. [29]. The high-pressure (up to 140 atm), high-temperature spherical facility is optically accessible on4 sides for schlieren imaging and laser ignition, and wasinspired by studies conducted by Farrell et al. [30]. Thissetup can be seen in Figure 5 and similar apparatus arewidely used in literature. Gupta, Bihari and Sekar [31] useda laser ignition rail under lean-burn conditions in a6 cylinder natural gas engine. This engine was able to runin a lean-burn condition of λ¼1.76 using laser ignition, asopposed to λ¼1.6 allowed by conventional ignition. Pre-liminary results showed that laser ignited combustionallowed for a 60% reduction in NOx emissions with a0.8% increase in brake thermal efficiency. There areobservable increases in CO and UHC, but are easilyreduced with after-treatment systems. Other technologiesin conjunction with laser ignition may be needed to achievethe target thermal efficiency of 50%.

As stated earlier, the demand for alternative fuels hasincreased in recent years. A study by Rahman et al. [7]investigated the use of hydrous ethanol, an alternative liquidfuel, in internal combustion engines via laser ignition.Anhydrous ethanol, which is less than 1% water, is morecostly than gasoline, as there is a significant amount ofenergy required during distillation and dehydration process.Wet ethanol, or hydrous ethanol, may prove a promisingalternative to anhydrous ethanol (and possibly gasoline) asit improves the associated energy balance and may reducecosts. Laser ignition is utilized in the experiment due to theadvantages it offers, such as the ignition of leaner fuelmixtures, more stable combustion, and variable ignitionpositions within a combustion chamber. A Q-switched Nd:YAG laser with a 532-nm nanosecond pulse generated thespark in the transient ethanol fuel spray. It was observed

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that flame luminosity and development with subsequentpropagation became weaker and slower, with increases inignition delay times, at higher water content values. At 20%water content by volume, pressure rise and rate of heatrelease is practically similar to that of pure ethanol.Incomplete combustion occurred for stratified charge ofhydrous ethanol where laser ignition proved feasible up to30% water fraction volume. At 40% and 50% volumefraction, misfire occurred. This is different compared to acomparative study by Mack et al. [32] in which hydrousethanol was studied using conventional spark ignitionmethods in an homogenous charge compression ignition(HCCI) engine. According to Mack et al., stable operationoccurred at 40% water fraction, which is higher than thelimit of stable operation in laser ignition (30%). This leavesthis area of study open on the subject of laser ignition ofhydrous ethanol to match the higher performance ofconventional spark ignition methods.A more complex geometry pertaining to gas turbine

combustors is swirl flames. Some data from the previousdecade are available [33,34], but in all, little work has beendone on ignition studies in swirl configurations. As a studyaddressing innovative solutions for the development on newcombustors in aircraft engines, research performed in 2013 byCordier et al. [35] considered two swirl numbers and investi-gated their impact on the laser ignition process. The researchersdemonstrated that the efficiency of the ignition location (howsuccessful ignition is in various locations) is controlled by bothlocal flow properties and by the flame surface development,which are linked by typical kernel trajectories within thecombustion chamber. During long development times, theflame was observed to potentially cross into zones presentinghigh levels of turbulence, leading to partial or full extinction ofthe flame. Flame development and stabilization was largelycontrolled by the cold flow field (flow not ignited and withoutreaction), implying that location of ignition may be selectedbased on combustor cold flow. No correlation between localturbulent kinetic energy and ignition probability was observed,as opposed to the results found in the previous studiesperformed by Marchione and El-Rabii et al. [33,34].

Figure 6 Temperature field in the combustor. (a) Basic c

Though not entirely devoted to laser ignition, a studyperformed by Serbin et al. [36] investigated the possibilityof improving gas turbine performance through plasmaassisted combustion, and warrants discussion. Using com-putational fluid dynamics (CFD) and mathematical model-ing, a 25 MW gas turbine was investigated using a partiallypremixed lean gas-air mixture. The generated 3D computa-tional model for a basic gas turbine yielded severalinteresting results. The computational model generated fora modified, plasma assisted gas turbine combustor, gavesignificant improvements of the combustor's temperaturedistributions and ecological characteristics. Maximum tem-perature levels of the products in combustion decreased by190 degrees, resulting in decrease in NOx emissions from16 to 1 ppm. Secondary flow rate increases allowed deeperpenetration into the flame tube, and tangential variation inthe outlet cross section decreased. The total pressure lossalso decreased from 6.11% in the unmodified case to 5.72%in the improved design. The CFD results are shown andcompared in Figure 6 and Figure 7.

2.2. Supersonic and hypersonic flow systems

High-speed airbreathing engines are key to future super-sonic and hypersonic transportation vehicles. Two predo-minant strategies for tackling the challenges of designingthese future craft include conventional and laser plasma-assisted ignition. Plasma-assisted ignition shows promisewith both ignition methodologies, but further research isneeded, especially in the laser ignition field. The followingsections discuss experiments conducted in the past twodecades regarding advanced ignition studies related tosupersonic and hypersonic aerospace applications.

2.2.1. Plasma-assisted ignitionUltra-lean mixtures are desired for use at high initial and

average pressures (P�15–40 atm and V�10–70 m/s) ininternal combustion engines, while hypersonic aircraftengines operate at low pressures with high flow velocities

ase and (b) modified [36] (reprinted with permission).

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Figure 7 Temperature field of the combustor outlet cross section. (a) Basic gas turbine case and (b) modified gas turbine with plasma assistedcombustion [36] (reprinted with permission).

Review: laser ignition for aerospace propulsion 9

in combustion regions (P�100 Torr and M�2) [12]. In thecase of a lean-burn gas engine, the operational window isrestricted by conventional ignition methods. The aforemen-tioned limits can be increased through the use of plasmaassisted ignition technologies, described in detail in thissection.

Using nonequilibrium plasma for flame stabilization insubsonic and supersonic flows has been growing in interest,as nonequilibrium plasma discharges have a high propensityto produce reactive radical species. These radical speciesfacilitate combustion reactions and reduce ignition delaytimes. Do et al. [37,38] and Leonov et al. [39,40] recentlyintroduced a two-stage mechanism which can describeconventional plasma-assisted combustion flame stabiliza-tion (by electric discharge). In the case of hydrocarbonfueling and low temperature, flame stabilization can occurby using nonequilibrium plasma. In the first stage, theplasma induces active radical production and preflame (alsoknown as fuel reforming), which can be simplified as aproduction of H2, CH2O, and CO. The zone does notexperience a significant temperature and pressure increase.The preflame/cool flame appears as a source of activechemical species that initiates the second stage of normalcombustion, characterized by high temperature andpressure rise.

One of the following two conditions must exist forsustained deflagrative combustion in a supersonic stream:a continual source of ignition must exist, or conditions forautoignition should be maintained. Ignition behavior oflaser-induced plasma in thermal equilibrium applied tosonic, underexpanded jets injected into a hypersonic cross-flow, during which deflagrative combustion takes place,was investigated by Brieschenk, O’Byrne, and Kleine [41].H2 fuel was ionized before being injected into the cross-flow, without autoigniting the hypersonic flow. Previousstudies by the same authors [42] where laser-inducedplasma was generated in shear-layers showed that thismethod could promote the formation of hydroxyl and ignitea supersonic flow (these works are discussed in more detaillater). Latest work focuses on whether or not fuel-jet laser-

induced plasma ignition can outperform shear-layer igni-tion, in terms of laser energy requirements and ignitioneffectiveness. H2 fuel was diluted with Ar (serving as aplasma buffer gas, which extends plasma lifetimes), whichserves as the plasma buffer gas. It was discovered that fuel-jet laser-induced plasma ignition is less effective unless aplasma buffer gas is used to extend the lifetime of theplasma. Hydroxyl signals were increased with increasedlaser pulse energies, as fuel diluted with Ar was found toincrease the OH signal being observed. The hydroxylradicals are consumed during combustion, thus makingthe plasma buffer gas useful as it increased hydroxylformation. Enthalpy of the crossflow and the fuel plenumpressure did not significantly impact ignition effectiveness.The fuel-jet ignition technique was concluded to allow forlower laser energies to be used when compared to the shear-layer technique, but could only achieve similar OH den-sities with a plasma buffer gas.

Brieschenk, Kleine, and O’Byrne [43] continued theirwork on laser-induced ignition in hypersonic regimes withair-hydrogen fuel flow. Work was carried out at the T-ADFA hypersonic tunnel with a specific total enthalpy of2.5 MJ/kg and a freestream velocity of 2 km/s. Using acompression-ramp model with a port-hole injector, theauthors further investigated how laser-induced ignitioncan effectively produce hydroxyl. Time-resolved luminosityimaging indicated that laser-induced plasma rapidly grewwithin the first microsecond after initiation of the laser dueto a laser-driven shock wave. The luminosity separated intotwo regions, traveling along the shear layer behind theinjector bow shock. Turbulence of the flow at the injectionregion did not seem to affect the early evolution of theluminosity cloud. A calculated 54% of the laser energy wasabsorbed by the plasma, but was of secondary concern astechniques exist which decrease the energy requirement(such as using a plasma buffer gas in a fuel-jet ignition, asstated earlier). Blast wave theory was used in conjunctionwith an expansion wave model which yielded enthalpies onthe same order of magnitude as those predicted by NASACEA code.

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Further studies conducted on laser-induced plasma ignitionwere characterized by Tsuchiya et al. [8]. The effectivenessof laser irradiation focused at near fuel-jet boundary andrecirculation regions were investigated in supersonic air-streams. Other efforts included providing insight into ignitionaugmentation, wave propagation processes, and interactionsof the waves with a supersonic flow region. Propagationphenomena (such as wave interactions and plasma formation)of plasma-waves, flame-waves, and shock waves and asso-ciated recirculation zone formations are also studied. Using anumerical simulation, positions of the plasma kernelsinduced by laser irradiation affected ignition and flamestabilization characteristics and also the induction processof local turbulence augmenting local mixing. The authorswere able to characterize the laser ignition process into a fivestage time scale: 1 (10�9�10�8 s): Incident laser pulse isabsorbed. 2 (10�8�10�7 s): Plasma formation process. 3(10�6�10�4 s): Ignition. 4 (10�5): Shock flow interaction.5 (10�5): Convection/diffusion.In a follow-up study by Horisawa and Tsuchiya et al.

[44], additional CFD simulations, utilizing time-dependentNavier-Stokes equations, were conducted in supersonicairstreams with transverse hydrogen-fuel injection, in orderto study phenomena outlined earlier [8], for two specificcases. In the first case, where laser plasma was induced nearthe fuel injection port, it was observed that the initial phase(20–30 μs after laser pulse) proved effective, whereas anupstream part of the flame region, developed from theplasma kernel, was blocked by an oblique shock broughtupon from fuel injection. For the second case, in which aplasma kernel was induced downstream of the fuel injectionport, plasma effects became significant only after 40 μs,where the flame region expanded in both upstream anddownstream areas. In high pulse energy cases, a flamenucleus propagated with a shock wave. The propagatingshock wave induced recirculation zones and enhanced localmixing, particularly at near-wall regions with associatedflamelets. Active species from the flame nucleus weresupplied in a hydrogen/air mixing region via recirculatingzones formed by the shock wave. At each recirculation zonein the simulations tested, the flame region stabilized insupersonic regimes. In lower pulse energy cases, no shockwave structures induced by the plasma kernel could beobserved in the flow field. The propagating combustion wasinduced weak recirculation zones, but were smaller in sizecompared to the ones formed by the higher pulse energy.A study conducted over the course of five years by

Leonov [40], in conjunction with the Air Force Research

Table 1 Energetic thresholds at various conditions according to Ref.

Energetic threshold H2

T0¼30

Threshold of ignition in cavity and behind wallstep/kW 1Threshold of flameholding in shear layer over wallstep/kW o3Threshold of flameholding over plane wall/kW o3

Laboratory, sought to further study the phenomena ofplasma-induced ignition of air-fuel mixture at direct fuelinjection into separation zone downstream backwise wall-step and wall cavity by multi-electrode quasi-DC electricaldischarge at highs-speed flow. Both computational andexperimental data were developed for comparison andverification. The two-step mechanism for plasma assistedcombustion, mentioned previously [37,39], was analyzed aswell. The effect of transversal discharge on flameholdingwas conducted at Mach 2 in a cavity behind a backwisewall step, along a plane wall. Temperature was varied from300 to 750 K.

As can be seen in Table 1, the energetic threshold measuredfor ignition and flameholding can be compared amongstignition in a cavity behind a wallstep, threshold of flamehold-ing in shear layer over a wallstep, and threshold of flamehold-ing over a plane wall. Comparable power levels are observedfor flameholding with the wallstep or on the plane wall.Contrary to what is expected, the threshold for flameholdingdoes not decrease (improve) with a rise in static temperature.The author states that a hypothesis for this phenomena is thatan increase in temperature leads to intensification of gascirculation in the separation zone, thus a gas exchangebetween the separated zone and the core flow. From theexperimental data, two factors are considered for successfulfuel ignition and flameholding: discharge power and length ofdischarge filaments. Nonequilibrium power deposition into thegas lead to the creation of species which possess higherreactivity, when compared to those found at equilibrium. Itwas demonstrated that plasma should be generated in situ, atthe exact location of fuel-oxidizer interaction. This diminishesfast relaxation and mixing with the surrounding air.

Uniform mixing of injected fuel in high-speed flowsbecomes difficult with increasing Mach number, and theproblem of adequately spreading flame across the combus-tion chamber is not realized. Self-ignition delay time forhydrocarbon fuels exceed 10 ms at 1 atm and temperaturesof 600–1200 K, translating into a long ignition region.Several ideas are explored in a study by Macheret et al. [45]to help analyze energy and power requirements to shortenthe ignition delay time in hydrocarbon-fueled scramjetsusing nonequilibrium plasma generation. The first conceptis a multi-point, repetitively pulsed plasma ignition scheme,which is purposed to reduce the power budget by multipleorders of magnitude (from �100 MW/m2 to several MW/m2). This idea involves planting multiple ignition spotsseveral centimeters apart in the combustion chamber so thatflames being ignited by these spots will overlap in time.

[40].

C2H4 C2H4 C2H4

0 K T0¼300 K T0¼500 K T0¼650 K

2.5 4 �53.5 �5 �1044.5 45 48

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Review: laser ignition for aerospace propulsion 11

This is less costly energetically compared to volumetricignition. This concept relies on high flame propagationspeed; the higher the flame spreading speed is, the lower theenergy requirements on the igniters are. The second conceptexplored is electron-beam assisted fuel injection andatomization. Efficiency of high-speed systems, such asramjets and scramjets, depends strongly on how fuel andair are mixed before the ignition process. Fuel entering as avapor, in the form of microdroplets, would not penetrateinto dense, high-speed flow, and efficiency of ignitionwould be limited. A form of injection is proposed in whichfuel is injected into the core flow as a liquid jet, and low-power electron beams are used to electrostatically chargethe droplets, thus controlling droplet break-up, atomization,and mixing. This would allow the injection of fuel into ascramjet engine as a powerful liquid jet, allowing adequatepenetration into the flow, while simultaneously breaking upinto droplets, facilitated by Coulomb repulsion due to thenegative charge from high-energy electron beams. The finalproposed concept is multi-spot combustion ignition bysubcritical microwave discharge at the surface of fueldroplets. The subcritical microwave discharges, broughton by a local enhancement of electric field strength at thesurface of the droplets, would initiate combustion in multi-ple spots. This would assist in spreading the flame ignitionacross the combustor. Several advantages could be realizedfrom this concept; it would eliminate protruding metallicobjects in the airflow, be characterized by multi-spotignition across the combustor (equivalent to volumetricignition, solving the flame spread problem), save energy,and easily ignite in fuel-air mixtures that are lean in average(since combustion would occur easily at the droplet surface,where the local equivalence ratio is high).

Do, Cappelli, and Mungal [38] explored the concept ofigniting supersonic and sonic hydrogen jet flames insupersonic pure-oxygen crossflows, without the aid ofgeometric variances (such as cavities and wall steps).Nonequilibrium plasma was produced by 7 kV peak vol-tage, 20 ns pulsewidth, 50 kHz repetitive pulses. Upstreamsubsonic jets produced an oxygen-hydrogen mixture thatconvected toward the downstream main sonic jet whenactivated by the plasma. Interaction with the bow shock,formed by the jet, forms a combustion region that controlsthe formation of a jet flame. Ignition was observed to beconsiderably easier at higher Mach numbers as post-shockconditions played an important role in the autoignitionprocess.

Do, Cappelli, and Mungal [46] continued their work onplasma assisted combustion in another study focused oncavity flame ignition in supersonic airflow, with thegeometric variance being absent in their previous study.Using the same nonequilibrium plasma characteristics fromtheir previous study, the nanosecond pulsed plasma dis-charge, located within a wall cavity, was used to ignitehydrogen and ethylene jet flames in a crossflow. The use ofthe cavity resulted in flame ignition in the leeward side ofthe oblique hydrogen jet, and the cavity flame auto-ignited

when the enthalpy of the free-stream rose higher than 2 MJ/kg. A reduction in the ignition delay of the mixture withinthe cavity was observed. A parametric study indicated thateven higher pulse energy could lead to a higher reduction inignition delay. These benefits are seen as well in theethylene jet, suggesting that the combustion process in thisexperiment may be applicable to other hydrocarbons. Itshould be noted that the experiment in this particular studywas limited by the discharge power available for their pulsedischarge source.

Research was continued in a follow-up study in the sameyear by Do et al. [37], in which the authors used the sameplasma discharge source to ignite jet flames in supersoniccrossflows over the specific case of a flat wall, without the useof a cavity. Low power nonequilibrium nanosecond pulseddischarges for the stabilization of supersonic combustion hasnot been widely studied due to the low discharge energy perpulse, in comparison with the flow enthalpy over time betweensuccessive pulses. Hence a dual fuel jet injection configurationwas utilized to overcome these limitations by channeling plasmaenergy into activation of a subsonic fuel/oxygen mixture thatserves as a pilot flame. Two stages were found to represent thisplasma-enhanced supersonic combustion; the first stage divertsfuel towards an oblique subsonic injector, while in the secondstage, increased radical production (more than what would beachieved by plan discharge alone) ignites and sustains thecombustion in a majority of the fuel. This experimental setupwas easily integrated into a flat wall and did not require anygeometrical variations to induce flow recirculation.

2.2.2. Ramjet and scramjet applicationsAlthough the concept and configuration of scramjets is

relatively simple, there are many complicated physicalphenomena behind the operation of such an engine. Thescramjet engine utilizes forward motion to compress theincoming air (as opposed to a rotary compressor). An inletat the front end converges to the area of combustion (wherefuel is injected, mixed, and combusted), then diverges intothe nozzle. Thrust is produced by the expansion of theproducts of combustion through this nozzle. As opposed toramjets, scramjets contain a supersonic combustor, whileramjets contain subsonic flow in their combustion cham-bers. The difficulty in designing scramjets come from thephysical characteristics experienced during high-speedflight, and should allow for sufficient air compression,fuel-air mixing, combustion, and gas expansion. In Mach4–8, with a dynamic pressure of 1000–2000 psf (0.5–1 atm), combustor entrance conditions can be characterizedas follows: static pressure is 0.5–2 atm, static temperature is400–1000 K, and flow velocity is 1200–2400 m/s [45]. Thefollowing section details laser ignition applications inramjets and scramjets, but is not complete with severaladditional studies on fuels and geometric variances.

Due to the high speeds at which airbreathing scramjetengines travel (Figure 8), the time available for fuelinjection, fuel-air mixing, and combustion is very short,on the order of 1 ms. Flame holding, an important factor in

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Steven A. O’Briant et al.12

the design of an injection system, has the primary objectiveof reducing ignition delay time and to provide a continuoussource of radicals for chemical reaction to be established inthe shortest time possible. This can be achieved by threetechniques. The first is by creating a recirculation areawhere the fuel and air can mix at decreased velocities. Thesecond is via interaction of a shock wave with partially orfully mixed fuel and oxidizer. The final method is byformation of coherent structures containing unmixed fueland air, in which a diffusion flame occurs as the gases areconvected downstream. Several geometric surface altera-tions have been tested in order to help with the character-istics mentioned above, such as cavities [46–48], rampinjectors [49,50], wall steps, and angled combustor walls.The simplest approach to geometric variances is the

transverse injection of fuel from a wall orifice. As a fuel jetinteracts with a supersonic crossflow, a bow shock isformed. The upstream wall boundary layer thus separates,providing a region where the boundary layer and jet fluidsmix upstream at a subsonic velocity. Though there areconsiderable flame holding capabilities, there are stagnationpressure losses due to the strong three-dimensional bowshock formed by the jet penetration, which is increasinglyevident at higher velocities, such as in a scramjet. A step,followed by transverse injection, is another method ofachieving flame stabilization. The step creates a largerecirculation area with hot gases serving as a continuousignition source, but suffers the same disadvantage ofstagnation pressure losses and an increase in drag due tothe step. It is possible to angle the injection process at 301or 601, thus providing a weaker bow shock and reducingpressure losses. Due to the fuel jet's angle, the axialmomentum can actually contribute to the net thrust of theengine. Based on observations from various works [51,52],angled injection is likely to reduce autoignition andstabilization at flight speeds lower than Mach 10. Cavityflame holders, another type of geometric variance, has beenshown to significantly improve hydrocarbon combustionefficiency in a supersonic flow when placed after a rampinjector. Ben-Yakar and Hanson [47] provide an overviewof research (up until 2001) into cavity flame-holders. Somestudies [53] indicated autoignition within the cavity at Mach6.5, even without the use of spark ignition plugs. Smallinjector dimension and low combustor operation pressurereveals that without the cavity, ignition is unlikely. Similarstudies [54] also revealed that cavity length L and stepheight D significantly influence combustion sustainment.

Figure 8 Diagram of air-breathing scramjet system [12] (reprintedwith permission).

Ultimately, a cavity length to depth ratio between 1.7oL/Do2 showed sustained combustion in supersonic combus-tors utilizing solid fuels. Figure 9 details some of thetraditional injection methods described above.

An aeronautical injection system has been considered byZimmer, George, and Orain [55], which utilizes a stagedliquid fueled injector, injecting fuel through a centralpressurized atomizer while air is swirled. Laser ignitionwas used with dual Nd:YAG lasers with a 105 mJmaximum pulse. There are two recirculation zones: theinner and outer zones. In the inner recirculation zones, allsparks lead to a complete ignition of the chamber, regard-less of temperature variation. The probability of plasmaformation was strongly correlated with the temperature,however, and overall ignition probability was low fortemperatures below 150 1C. In the outer recirculation zone,not all plasma led to ignition of the chamber. Theresearchers determined that almost all sparks led to com-plete ignition above 170 1C, where the probability ofgetting any spark was almost zero below 135 1C. Futurework will include studies on the transition of success fromthe inner recirculation zone to the zone where spray hits thewall, which is of strong interest in aerospace applications.

Autoignition, an aforementioned characteristic of scram-jet flow, is the rapid spontaneous ignition and reaction ofthe fuel-air mixture, and is required to achieve efficientcombustion. A difficulty in developing scramjets includesthe slightly long ignition delay times of hydrocarbonsrelative to hydrogen. In addition to this, heat release ratesare affected by autoignition, and if these rates are too rapid,dynamic instabilities or choking may occur. Shock-tubeexperiments were conducted by Colket and Spadaccini [56]in 2001 to study and compare the ignition delay times ofseveral scramjet propulsion fuel candidates. Ethylene,heptane, and JP-10 were measured at specified conditions(1100–1500 K, pressures of 3–8 atm, and equivalence ratiosof 0.5–1.5). Using previous results published for heptaneand ethylene, new correlations were found from the twoexperimental data sets. Studies on hydrogen and methaneignition-delay times were also compared. A summary of theresults from the study can be seen in Table 2.

The ignition delay times from Table 2 can be expressedin descending order, with the longest ignition delay timelisted first: methane, JP-10, heptane, reformed fuel, ethy-lene, and hydrogen. The delays for the simulated reformedfuel in the experiment were calculated to be 50% to 70% ofheptane's delay time (heptane being the parent hydrocar-bon), supporting the argument that endothermic reactionproducts will ignite more readily. It was also found that theaddition of heptane to the simulated reformed fuel increasedignition delay, while hydrogen decreased the ignition delay;however small changes in concentrations of individualcomponent species are not usually likely to make dramaticchanges in the delay times. Moreover, the autoignition ofthe endothermic reaction product mixture was found to benot entirely driven by the individual constituent with thelowest ignition delay, such as ethylene and hydrogen.

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Figure 9 Flowfield schematics of various injection/flame-holding schemes in supersonic combustors [47] (reprinted with permission).(a) Underexpanded fuel injection normal to the crossflow, (b) injection behind a sudden expansion produced by a step, (c) fuel injection at anangle, and (d) open cavity flow at L/Do7-10.

Table 2 Ignition delay time comparison between fuels @ 7 atm(times in ms) [56]. Baseline fuel is a mixture of 0.3CH4/0.6C2H2/0.1H2.

Relative ignition delay times

Eq. ratio φ¼0.5 φ¼1.0Fuel 1300 K 1400 K 1300 K 1400 KMethane 16.8 14.6 15.1 13.1JP-10 1.33 1.2 1.33 1.2Heptane 1 1 1 180%heptane/20%baseline 0.96 0.72 0.86 0.73Baseline fuel 0.64 0.6 0.77 0.710%H2/90%baseline 0.58 0.49 0.66 0.51Ethylene 0.33 0.39 0.33 0.39Hydrogen 0.04 0.07 0.03 0.06

Review: laser ignition for aerospace propulsion 13

As stated earlier, the USAF has expressed interest inscramjet propulsion and its corresponding ignition processes.The Air Force plasma ignition program, introduced in a 2003study by Jacobsen et al. [57], aims to assess the possibility ofutilizing a plasma generating device for main-fuel ignition insupersonic flow regimes. Employing computational andexperimental methods, two plasma torch devices (one AC,one DC) were investigated, in addition to establishing baselineconditions of operation (such as required time to initiation acombustion shock train). Results indicated that the plasmaigniters produced hot pockets of excited gas with a 2 kW totalinput power and peak temperatures up to around 5000 K. InMach 2 supersonic flow, ethylene and JP-7 flames (with

substantial levels of OH) were produced at a total temperatureof 590 K and pressure of 5.4 atm. Further work conducted in2008 by Jacobsen et al. [58] with the Air Force ResearchLaboratory continues upon the studies conducted earlier in thedecade. The purpose of the work was to further expandknowledge in the understanding of the ignition process in asmall-scale scramjet duct. The flow physics of each igniter/fuel-injector/combustor system was studied to understand andcompare the potential of each plasma torch concept, andseveral plasma igniter locations and duct configurations wereanalyzed. A cavity flame holder was incorporated into the flowpath, as previous studies had recently discovered theirimportance in aiding the ignition process [47,48]. CFDsimulations completed by the team indicated that ignitioncan be accomplished in a few milliseconds, and the energyrequired for 10 ms of torch operation is roughly 10's of Joules,which is a reasonably small amount of energy compared tothat of a battery. Further work is being conducted to continueresearch into the design and development of new igniterconcepts. Additionally, a more fundamental understanding ofalternate starting methods (such as silane based or a gasgenerator) is being pursued, as these methods do not involvethe use of toxic chemicals and allows for restart attempts.

In 2011 and 2012, two plasma ignition methodologieswere investigated by Brieschenk, O’Byrne, and Kleine[42,43,59] (before their 2014 study mentioned earlier[41]): shear-layer laser induced plasma ignition and fuel-jet laser induced plasma ignition in the case of a 2D

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Steven A. O’Briant et al.14

scramjet inlet. Tests were conducted in the T-ADFA freepiston shock tunnel, with a specific total enthalpy of2.7 MJ/kg and a Mach 9 freestream. For shear-layer tests,laser induced plasma was formed immediately downstreamof four transverse injector ports, while the fuel-jet plasmawas formed inside the sonic throat of a single fuel injectorfor its respective runs. Diluting fuel with a plasma buffergas, in this case 8% Ar and 92% H2, was also investigatedto extend the life of the plasma. A schlieren image of flowfeatures in the experiment is shown in Figure 10, represent-ing the difference in intensity between an image takenbefore the experiment and an image taken with actual flow(local features are labeled as well).It is proposed that in the case of the shear-layer tests,

most hydroxyl is generated in an explosive fashion up to5 μs, and is then consumed by combustion thereafter,generating more heat. The recompression shock slightlyincreases hydroxyl concentration when laser inducedplasma regions pass through. For ignition of an entire flowfield, laser pulse frequencies of 100 kHz are recommended,but is stated as a possible overestimation. Relatively highlaser energies are needed (around 750 mJ) due to the highthreshold energy at lower gas densities, as a considerableportion of this energy is transmitted through the focalregion, and is unable to partake in the course of plasmaformation. In the fuel-jet tests, hydroxyl is produced at asignificantly lower rate when compared to shear-layerexperiments. This is due to rapid recombination of thehydrogen plasma at high pressures. No hydroxyl is found tobe generated in the boundary layer of the walls, insteadbeing located between the center and upper boundary of thejet. When diluted with argon, hydroxyl formation increasesby an order of magnitude. However, an 8% dilution ofargon results in a specific impulse loss in a scramjet by afactor of 2.5 when compared with pure, H2 fuel. Thoughboth techniques are found to be effective, they each comewith a set of disadvantages. Shear-layer ignition, thoughproducing high amounts of hydroxyl, requires high laserenergies when gas densities are low. Fuel-jet ignition allowsfor lower laser energies to be utilized, but requires a plasmabuffer gas in order to achieve the same hydroxyl

Figure 10 Flow field features on compressi

concentrations, thus reducing a scramjet's overall specificimpulse. Utilizing OH-PLIF (Planar laser induced fluores-cence), the OH radical can be seen in different delaytimings in Figure 11 for the shear-layer experiment.

Scramjet operational efficiency can be defined by theefficiency and extensiveness of the combustion process.Tests conducted on the 14-X scramjet engine in the T3Shock Tunnel, utilizing electric spark igniters, haveproven that electrical igniters are impractical in terms ofthe overall performance and efficiency of the test model[9]. This is due to the fact that the igniters are installed onthe inner walls of the combustor, restricting combustionreactions to the boundary layer established on the adjacentwall. This limits the igniters influence on the flow. Inaddition, the electrical power used to produce stableconditions for combustion, such as a continuous electric-arc or plasma torches, have similar orders of magnitude asthe produced scramjet engine thrust power, making theelectric igniters impractical. Laser ignition, as researchedat Universidade Federal do ABC in Brazil (in conjunctionwith IEAv) [9] offers to circumvent these issues andmay offer a way to manipulate shock waves by usinglaser beams to virtually shape the geometry of thecombustion chamber. Nascimento et al. [9] have shownthat through the Vaschy-Buckingham π Theorem ofdimensional analysis, a preliminary mathematical relation-ship can be developed which represents the theoreticalscramjet laser-induced supersonic combustion efficiency,or ηcs, shown below in Eq. (3).

ηcs ¼ φ f pΔtp;hfEp

;kfΔtpλ

Tf Ep;ρf λ

5

EpΔt2p

!ð3Þ

Laser parameters that influence supersonic combustionefficiency include Ep, which represents energy per pulse, λ,representing wavelength, Δtp, representing pulse duration,and fp, the repetition rate. Fluid parameters that influencesupersonic combustion efficiency include flow enthalpy, hf,flow density, ρf, flow temperature, Tf, and flow thermalconductivity, kf. Refinement of Eq. (3) is still requiredthrough experimental analyses.

on ramp [42] (reprinted with permission).

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Figure 11 Fluorescence of OH radical the in shear-layer ignition experiment [42] (reprinted with permission).

Review: laser ignition for aerospace propulsion 15

Preliminary results achieved from the analysis of a newlaser igniter for the 14-X scramjet have offered severalpossible interpretations as to the influence of laser para-meters on supersonic combustion. Shorter pulse durationscorrelated with higher pulse power, due to increases inphoton's temporal density on the pulse. This results in apossibly higher temperature reached by the fuel mixture.There is a greater probability of the formation of freeradicals, working as catalyzers for combustion. Laserrepetition rate was also found to influence the constantmaintenance of radicals formed after laser ignition, in orderto achieve stable and complete supersonic combustion. Itwas found that the repetition rate is essential to enablingmanipulation of virtual geometry in the scramjet combustor.Finally, laser wavelength influences the energy transferprocess and consequent generation of reactive radicals onthe supersonic flow [9].

2.3. Rocketry, satellites, & space

Progress has been made in the development of laserignition systems at NASA Marshall Space Flight Center.Past studies initially encountered issues with depositinglaser sparks inside a rocket chamber, thus limiting laserignition's potential utilization. Recent advances in fiberoptic technologies and multi-pulse laser formats haverenewed interest in using lasers for future rocket designs.In the study prepared by Osborne et al. [60], single and dualpulse laser sparks are characterized and analyzed for use inrocket ignition applications. Dual-pulse laser-induced spark,or DPLIS, ignition is performed using the followingprocess: a very short-duration, high-power pulse is fixatedat the combustible medium, which starts plasma formationthat preconditions the gas volume by maximizing absorp-tion of the second laser pulse. The second pulse providesadditional photon energy, extending plasma lifetime andaugmenting ignition conditions. Dual pulse laser sparks are

found to produce plasmas that absorb laser energy just asefficiently as a single pulse format, with the added benefit oflonger plasma lifetime. Using the same amount of energy asa single pulse system, a dual pulse laser format alsoproduced a spark that provided better ignition character-istics and sustained combustion of fuel-lean H2/air propel-lants. It is unclear in the study whether the benefits providedby the dual pulse format is correlated to longer plasmalifetimes, better coupling of the laser energy into theplasma, or longer spatial profile of the dual-pulse spark.

In order to stay in space, satellites must perform manysmall-scale maneuvers using small rocket engines. Theseengines are constantly being turned on and off as needed.Engines such as the Orbital and Maneuvering System forthe Hershel/Planck Satellites described by Manfletti andKroupa can have as many as 93, 130 engine cycles [61].Currently, the types of engines used for these low thrustoperations are liquid bipropellant engines using hypergolicfuels. Hypergolic fuels have the benefit of autoignition uponcontact with the oxidizer and can be stored for long periodsof time at room temperature. Unfortunately, these types offuels are toxic and highly destructive to the environment.As more people push towards greener and more efficientenergy the need for new methods for small-scale re-ignitable engines is being re-examined. The concept ofcontrolling satellite maneuvers with non-hypergolic fuelsposes other problems. Fuel such as cryogenic liquid oxygenpossess their own issues involving storage of the fuel andfeeding the system. However, these are engineering chal-lenges that can be overcome. As lasers move to beingsmaller and more powerful, ignition through lasers becomesa more feasible concept for satellites.

The development of small scale laser systems for theseapplications is one method for incorporating alternativefuels. Manfletti and Kroupa used a small-scale laser (Nd:YAG Laser), approximately the size of a computer mouse,as the ignition source. The experiments were focused ondetermining the minimum incident energy needed to ignite

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Steven A. O’Briant et al.16

mixtures of liquid oxygen and gaseous hydrogen. Theset-up described, which provided 30 mJ of energy, wassuccessful in igniting the fuel mixtures between 17% and33% of the time depending on the focal point. Another testof the set-up was reported later, adding data on liquidoxygen and gaseous methane mixtures [62]. The resultsshow that the methane mixtures require more energy tounite, making such a combination less feasible with currentlasers.As traveling to deep space and other planets becomes

more realistic, new technology is currently being developedfor faster space travel. One method currently being con-sidered is nuclear propulsion. Nuclear propulsion usinglasers to ignite the reaction has become a widely researchedtopic as of late. Similar to the concept of laser ablation,nuclear propulsion is possible by creating fusion reactionsthrough lasers. One research group has studied the fastignition of nuclear fuels using a picosecond terawatt laser[63,64]. Currently such studies are in their infancy withmuch more information needed but the concept showspotential for high thrust applications and minimal radiationallowing for implementation in space.

2.3.1. Laser ablation systems & solid propellantapplicationsLaser ablation propulsion has found numerous uses with

spacecraft and other objects associated with space. Laserablation involves a concentrated, intense laser beam strikinga condensed-matter surface, producing a jet of vapor orplasma. Thrust is produced from the resulting reactionthrust force, similar to chemical rockets. Only a fewapplications utilizing laser ablation are beyond the researchstage of development, but there are a wide array ofconditions that can benefit from this sort of propulsion.These include, but are not limited to, milliwatt-average-power satellite attitude-correction thrusters, kilowatt-average-power systems for reentering near-Earth spacedebris, and megawatt/gigawatt systems for ground launchinto low earth orbit (LEO). An extremely thorough litera-ture review, much more in depth than what is presentedhere, can be found by Phipps et al. [65].Various benefits can be realized from the use of a laser

ablation system. Variable specific impulse (Isp) is possibleby adjusting laser intensity on a target surface, changing thefocal-spot area, and switching the laser-pulse duration. Thiscauses the exhaust velocity to vary across ranges ofchemical reactions ( 500 soIspo5000 s). Thrust can alsobe controlled independently of the specific impulse throughvariations in the laser-pulse repetition rate. Efficiency ofenergy consumption is strongly improved by constant-momentum exhaust-velocity profiles, which require a vari-able Isp, and is difficult to obtain through conventionalchemical rockets. In a self-contained laser propulsionsystem, cryogenic or high-pressure fuel tanks, gas-driventurbopumps, and nozzle cooling structures, as well as othersystems, are merely replaced by lightweight diode or diode-pumped fiber lasers. The laser itself does not require

complicated cooling systems up to the kilowatt level, dueto large surface-to-volume ratios. Though chemical rocketsstill outperform laser ablation propulsion in terms of thrust,spacecraft using laser engines experience more agile feed-back. Laser ablation propulsion systems have also demon-strated thrust densities with a value of 800 kN/m2 [66], dueto the thrust originating from a spot with an area equal tothat of the laser focus. This is particularly important forsatellite applications as ion engines have a much largerthroat-area-to-thrust ratio. In systems intended to launchsatellites and other spacecraft into LEO (with a launchfrequency of five per day), the cost of operations is reducedto as little as $300/kg [67]. Many of the benefits statedabove arise from conceptual ideas, and many remain to bedemonstrated. However, the vast amount of potentialbenefits arising from this source of laser ignition is toogreat to be ignored.

A recent development in the field of laser ablationpropulsion is the research into a laser-electrostatic hybridacceleration thruster, studied by Osamura, Sakai, andHorisawa [68,69]. In these hybrid acceleration thrusters,there are three different acceleration regimes: electrostaticacceleration, electromagnetic acceleration, and electrother-mal acceleration. Optimization of a thruster which can adaptto all acceleration regimes is proposed through the use of anaugmented electrode configuration. In earlier studies by theauthors, laser-electromagnetic acceleration was the area offocus. Delays in phase changes were observed due to adifficulty in completing simultaneous phase change andelectromagnetic acceleration after the pulse discharge initia-tion. In order to improve thrust efficiency and reducedelayed ablation, laser-pulse irradiation was utilized. Itwas found that this irradiation induced a conductive plasmain short durations, allowing for shorter pulse switching ordischarge. Higher peak currents and improvements in thrustperformance can be expected due to shorter-pulsed plasma.In the current study, the laser-electrostatic hybrid accelera-tion thruster employs laser ablation plasma acceleratedthrough an electrostatic field. The process starts as anirradiated laser pulse is focused on a target surface, creatinglaser-induced plasma at the target region. Typically, in laserablation systems, electrons are emitted from the surface first,followed by ions, accelerated through ambipolar diffusion.The ions are accelerated further by using an additionalacceleration electrode. A high specific-impulse is expectedas the plasma is further accelerated through the electrostaticfield. Using a Faraday cup, the speed and number of ions inthe electrostatic hybrid thruster is estimated to determine anoptimum electrode geometry. For 10 mm diameter electrodesplaced 20 mm away from the laser target surface, the speedof ions was observed to increase with voltage. As theelectrode gap increased, the number of ions decreased. Ionspeeds, measured 80 mm away from the target, wereobserved at 16 km/s and 32 km/s for voltages of 0 and500 V, respectively, at an electrode gap of 20 mm.

Recent attention has been given to microthrusters forsmall satellites and spacecraft weighing less than 100 kg,

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Review: laser ignition for aerospace propulsion 17

which are believed to be more economical from a devel-opment and launching perspective [70,71]. The use of diodelasers have also been proposed for ignition of pyrotechnicmaterials and ablation of polymers in microthrusters. Otherresearchers have also proposed the use of diode lasers inmicrothrusters for maneuvering [72,73]. Diode lasers havethe advantages of being lightweight, requiring low voltagestypically lower than 5 V, and having convergent efficienciesover 40%, but suffer from lens fouling from jet plumes andrequire an advanced feeding system to deliver solidpropellants to the laser. In studies done by Koizumi et al.[71], a dual propulsive mode microthurster used a 1 Wmulti-mode diode laser for both laser ablation of polymersand laser ignition of pyrotechnics. The two modes, laserablation mode and laser ignition mode, were investigated.In laser ablation mode (no chemical reaction), the diodelaser irradiates the surface of the polymer propellant,generating low thrust. In laser ignition mode (energy releasewith chemical reaction), the laser irradiates and ignites thepyrotechnic (solid propellant) material, which is pre-loadedin small craters, resulting in higher thrust. These two modesare interchangeable by simply switching the surface beingirradiated by the laser beam. The advantage seen here byusing the dual mode microthruster is the fact that there is awider allowable thrust range. Impulses of 1–40 μN � s(achievable with varying pulse width) were observed inlaser ablation mode and 10 mN � s in laser ignition mode.This is a thrust range that spans over four orders ofmagnitude and can be installed in a 1–10 kg spacecraft.

In other studies done by Koizumi et al. [74], the followingpropellants were examined for laser ablation using a diodelaser: polyvinylchloride, acrylonitrile butadiene styrene poly-mer, polyoxy methylene, natural rubber, and polymethyl-methacrylate. Using polyvinylchloride as the ablativematerial yielded the best performance and thrust. More heavilycarbon doped polyvinylchloride yielded even better perfor-mance, leading to the conclusion that absorption length had alarge effect on performance. Intensity of the laser was variedduring the experiments, and had little effect on thrustcapability. Urech et al. [75,76] also investigated the use of3 polymers for the application of micro-laser plasma thrusters(utilizing laser ablation): polyvinylchloride, glycidyl azidepolymer and polyvinyl nitrate. Absorbers in the form ofcarbon nanoparticles and IR-dye were added to the polymersto promote IR absorption at wavelengths of 1064 nm.Glycidyl azide polymer doped with carbon was the mostefficient (368%, or 3.68 times thrust energy over depositedlaser pulse) material in their experiment and generated thehighest specific impulse, followed closely by the glycidylazide polymer doped with IR-dye (198%). Polyvinylchlorideyielded a lower ablation efficiency (50%) as only a smallamount of energy was gained from the decomposition of thispolymer. Polyvinyl nitrate contained the lowest efficiency(21%) and is most likely cause by the ejection of the moltenpolymer away from the ablation area.

Advanced ignition systems for solid propellants arerequired in order to increase the safety and effectiveness

of the ignition process. Solid propellants and energeticparticles are usually ignited by heating a pyrotechnicigniter, which in many cases comes from electrical drivensystems. Laser ignition systems offer increased stabilityover electrically heated systems by negating the possibilityof electrical errors in the heating circuit and chemicalinstability of the pyrotechnics [77]. Lasers also offer thepossible advantage of multipoint ignition in solid propel-lants, which can be utilized for combating low ignitionprobability in solid rockets [78,70].

The use of lasers for solid propellant ignition has beenstudied for over 10 years. Between 1993 and 1999 the UnitedStates Army Research Laboratory did extensive research onlaser ignition of solid propellants for the application ofadvanced munitions. The research done in this time framewas a part of the Laser Ignition in Guns, Howitzers andTanks (LIGHT) Program which focused on the creation oflaser ignition systems to replace the igniters in guns andartillery. The main motivation of this research was theefficiency of laser ignition systems if properly tuned to theabsorption of the propellant [79]. The LIGHT Program wasstimulated by the potential for reducing the vulnerabilityinherent of primers and igniters in the ignition train andallowing for ignition of insensitive munitions [79]. TheLIGHT Program used Nd:glass lasers based on their smallsize, low cost, and reliability to ignite a variety of propellantssuch as Black Power, JA2, M30, LKL, XM43, HELP2and HMX1 [78–81].Continuous wave CO2 lasers have beenused in studies of JA2 ignition [78]. Research done by Ulasand Kuo investigated the ignitability of 6 different solidpropellants using a 50 W CO2 laser as the ignition source;trials were done with 3 different laser heat fluxes, 30, 50 and100 W/cm2 as well as 2 different chamber pressures, 1 and69 atm [82].

Aluminum and boron are popular energetic metallic fuelsused in explosives and propellants. Energetic particles ofaluminum, boron, and magnesium samples have been ignitedvia CO2 laser in previous works [83–85]. Researchers at theNew Jersey Institute of Technology have used a CO2 laser toignite aluminum particles of diameter ranging from 1 to14 μm in attempts to determine particle burn times and flametemperature from aluminum combustion [86,83]. Experimentsconducted by Arkhipov and Korotkikh have addressed theinfluence of aluminum powder dispersity on the ignition timeand burning surface temperature of composite solid propel-lants using a multimode CO2 laser with a wavelength of10.6 μm and maximum power capacity of 100 W as theignition source [87]. Studies by Zhou et al. employed a CO2

laser to ignite boron powered particles of diameter between50 and 60 μm with oxide layer of thickness between 0 and1.384 μm to study the effects of the initial oxide layerthickness on the combustion of boron [84]. Magnesium hasalso been researched as an additive in aluminum and boronbased powders to promote ignition via CO2 laser [85,88]. Incases of high fluences acting on aluminum and molybdenumtrioxide ablation from thermal stress has been observedfollowing the ignition of the mixture [89].

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Figure 12 Laser-propelled flight experimental [91] vs. simulated data [90] (diamonds represent experimental data). (a) Altitude vs. time and(b) velocity vs. time.

Steven A. O’Briant et al.18

Laser propulsion may also be applied to rocket applications,allowing for the possibility of a higher specific impulse, higherthrust, and a lower propulsion weight, among other advan-tages. A simple propulsion system that can accomplish thistask is through the use of a solid propellant, where the surfaceis continuously vaporized by laser irradiation. Thermal laserpropulsive concepts are based on absorption in two mechan-isms: laser-supported combustion (LSC) waves or laser-supported detonation (LSD) waves. Based on thermodynamicconstraints, only a subsonic LSC wave can be used efficientlyin a converging-diverging nozzle section, while a supersonicLSD wave can only be made efficient in a diverging nozzleconfiguration. Numerical simulations are performed byResendes et al. [90] to study the flight mechanics of ascenttrajectories controlled by a laser propulsion system. COLVET,a launch vehicle simulation software program, is used tosimulate the motion of vehicles propelled by laser. Experi-mental data, obtained from an earlier laser-propelled flight byMyrabo [91], is used to reproduce the experiment usingCOLVET. A comparison of the two data sets is seen below inFigure 12. A lack of published data on the vehicle developedby Myrabo led the authors to estimate several parameters, butdata seems to have correlated nicely with the flight test results.Based on other results, the researchers concluded that the

most promising form of thermal laser propulsion is the LSDwave mechanism, using either an air breathing or rocket mode.A combination of short pulses (�10�9 s) and high repetitionrates (104–105 Hz) for pulse formatting is proposed to improvethruster performance. Uniform ignition is required in systemsutilizing the LSD concept, and can be achieved by using laserfocusing or by using low temperature ionization. Due toballistic considerations, there is a required minimum laserpower to launch a given mass. Preliminary simulations withCOLVET suggest that the minimal size of the vehicle is 3 kgwith an onboard 3 MW laser. It is also suggested that withcurrent laser power levels, on the order of 100 kW, a craft of200 g mass should theoretically launch to above 10 km inheight. It is proposed for future experiments to launch smallerscale vehicles to several kilometers in altitude, since a vertical

ascent trajectory is used to reach this height, and the presentstudy can be used to analyze such a case.

3. Summary and conclusions

Presented here is a review of laser ignition and itsapplication to both aero and space vehicles. With respectto gas turbines, research performed on microwave-enhancedlaser ignition yielded significantly evident kernel growthrates, with reductions in ignition delay times and largerignition volumes. MIE values and how they are affected indiffering circumstances were also investigated, indicatingthat MIE's decrease with increasing pressure at a giventurbulence but increase with increasing turbulence at a fixedpressure. The development of a laser ignition system isreviewed in both a single- and multi-cylinder system, withpossible benefits including a 60% reduction in NOx emis-sions and a 0.8% increase in thermal efficiency in the caseof a 6 cylinder preliminary study. Plasma assisted combus-tion in gas turbines was also detailed in the manuscript,using CFD modeling to demonstrate potentially coolertemperatures in the combustion chamber, as well as lowerNOx emissions.

Advanced ignition systems were examined in supersonicand hypersonic systems. An area of great interest is throughthe use of plasma-assisted technologies, using both con-ventional and laser ignition methods. Using conventionalignition methods, a two-stage mechanism was developed todescribe plasma-assisted combustion flame stabilization forhydrocarbon fueling and low temperature by nonequili-brium plasma. This includes active radical production andpreflame, followed by high temperature and pressure rise.Several studies are also reviewed regarding advancedignition in supersonic crossflows, which can lead toreductions in ignition delay time and may contribute tothe autoignition process. In terms of scramjet applications,several different geometric fuel injection variances wereanalyzed, including the advantages and disadvantages of

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Review: laser ignition for aerospace propulsion 19

cavities, ramp injectors, wall steps, and angled combustorwalls. Several laser-induced plasma ignition methodologieswere studied as well, such as shear-layer and fuel-jetignition. Laser ignition in the 14-X scramjet engine is alsoreported with respect to its efficiency.

Advanced ignition, particularly laser ablation, also has itsplace among future rocket and space designs. Laser abla-tion, especially with the advent of such technologies as fiberoptics, could allow for applications ranging from milliwatt-powered satellite correction thrusters to gigawatt systemsfor ground launch into orbit. Benefits from this type ofsystem include adjustable specific impulse, variable thrustby differing laser-pulse repetition rate, and a reduced cost ofoperation. From an economical standpoint, microthrusterson satellites which utilize diode lasers are proving to bemuch more efficient, not to mention lighter in weight andmore efficient. The aforementioned characteristics of laserignition and diagnostics are promising, and future researchon the subject may yield systems with a significant aero-space applications.

Acknowledgement

The authors thank Owen Pryor and Joseph Lopez ofUniversity of Central Florida for their assistance with thiseffort. SSV acknowledges funding received from theArgonne National Laboratory (under Contract No. 4F-31861) and the Department of Mechanical and AerospaceEngineering (UCF). SBG wish to acknowledge the financialsupport of the US Department of Energy.

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