RESTRICTED SUBSTANCES LIST IMPS & ELFS · 2017. 10. 2. · Imps & Elfs has committed itself to...

RESTRICTEDSUBSTANCESLISTIMPS&ELFS

("RSL")3.0

OCTOBER.2017

IMPS&ELFS2017

INTRODUCTION3.0

Page2

INTRODUCTION

The production of apparel from raw materials to finished products is a long process. It starts with fibres via spinning, weaving or knitting, bleaching, dyeing, printing, washing, cutting and sewing to a garment. The processes are not only mechanical but they can be considered as chemical intensive and complex.

Imps & Elfs has committed itself to develop responsible chemical management procedures for all products, including accessories attached to garments, prints and packaging materials. Imps & Elfs expects the same commitment from its suppliers and have therefore developed a Restricted Substances List (Imps & Elfs RSL 3.0) to inform all suppliers on all chemicals that are banned or restricted in Imps & Elfs production processes and finished products. The purpose of a Restricted Substances List (RSL) is to reduce the use of hazardous¹ substances in the textile and apparel supply chain.

Our RSL includes; 1. The strictest legal requirements both inside and outside the EU2. Substances under investigation with no specific legal basis yet3. Other attention points in requirements from Eco label organisations or are mentioned by NGO’s, like Greenpeace .

A valid OEKO-TEX® Standard 100 product certificate issued by the OEKO-TEX® Association (www.oeko-tex.com) covers most of requirements of this RSL. The new OEKO-TEX® certification is called Sustainable Textile Production (STeP) (replacement of OEKO-TEX® Standard 1000) and has a wider scope: it covers also environmental aspects on the production site. Certification according to Oeko-Tex ® Standard 100 or STeP can be more cost effective than single tests. Input Stream Management of the bluesign® system (www.bluesign.com), for unsustainable substances to be eliminated first or meeting the EU Ecolabel (www.ecolabel.eu) requirements is also a cost effective way to fulfil obligations of this RSL. Above that, who participate in the Global Organic Textile Standard (GOTS) certification program (www.global-standard.org), with completion of GOTS certification, use only GOTS accepted chemical inputs such as dyestuffs, prints and auxiliary agents and therefore meet the requirements of this RSL. GOTS is the worldwide leading textile processing standard for organic fibres, including ecological and social criteria, backed up by independent certification of the entire textile supply chain.

Please be prepared that your contact person could request a signature for each order to declare that the specific order complies with our RSL requirements. Also it can be possible that one of your styles will be selected for pre-delivery testing at a certified laboratory.

As matter of general principle, Imps & Elfs reserves the right to select styles to be (counter) tested upon arrival in our warehouse. If this post-test is a “FAIL”, all the cost incurred in this testing procedure shall be borne by the supplier, including all additional cost for non-marketable styles.

As a result of a dynamic process this RSL will be updated on a regular basis in order to assist in the development of responsible entrepreneurship and they can be used as a basis for the development of Quality Management Systems.

In case of any question you can contact:

Smita Mahajan Manager Buying & Production mailto:[email protected]

TABLEOFCONTENT3.0

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GENERAL PAGE RESTRICTEDSUBSTANCESLIST3.0 PAGE

INTRODUCTION 2 PHTHALATES 16

TABLEOFCONTENT 3 POLYCYCLICAROMATICHYDROCARBONS(PAH’S) 17

RESTRICTEDSUBSTANCESDECLARATION 4 PVC 17

RESTRICTIONONPACKAGING 18

MATRIX PAGE SOLVENTS 18

GENRALRISKMATRIX 5 OTHERATTENTIONPOINTS 19

RESTRICTEDSUBSTANCESLIST3.0 PAGE REACHREGULATION1907/2006 PAGE

ALKYLPHENOLS(AP)ANDALKYLPHENOLETHOXYLATES(APEO) 6 REACHCANDIDATELIST 20-26

AZODYESWHICHBYREDUCTIVECLEAVAGEMAYRELEASEONEORMOREAROMATICARYLAMINES

6

BIOCIDES 7 ADDITIONALINFORMATION PAGE

CHLOROBENZENESANDCHLOROTOLUENES 7 EXPLANATIONONTHEACTIONOFSUBSTANCES 27-28

CHLORINATEDPARAFFINS 8 EXPLANATIONOFABBREVIATIONS 29

CHLOROPHENOLS 8

DISPERSEDYESWHICHARECLASSIFIEDTOBEALLERGENIC 9

DYESWHICHARECLASSIFIEDTOBECARCINOGENIC 9

DYESWITHENVIRONMENTALPROBLEMS 10

FLAMERETARDENTS 10

FORMALDEHYDE 10

HEAVYMETALS,EXTRACTABLETEXTILESANDTRIMS 11

HEAVYMETALS,SOLUBLEAPPLICABLEFORGARMENTCOMPONENTS 11

HEAVYMETALS,TOTALCONTENT 11

HEAVYMETALS,RELEASABLENICKEL 12

ORGANOTINCOMPOUNDS 12

PERFLUORINATEDCHEMICALS 13

PESTICIDES 14-15

RESTRICTEDSUBSTANCESLISTDECLARATION3.0

4

RESTRICTED SUBSTANCES LIST DECLARATION

Amsterdam, October 2017

Dear Supplier,

Subject: Restricted Substances List declaration

Imps & Elfs has recently updated the new Restricted Substances List 3.0 and shared with you about all chemicals that are banned or restricted in Imps & Elfs production processes and in finished products.

By this agreement we would like you to ensure us, that all products, fabrics and accessories will be produced in compliance with the List of Restricted Chemicals in products and additional requirements. This list gets updated every year and we will inform you the updated list, as and when have the information.

In addition to the information in the list relating to the chemicals and their residues, it is necessary that you collect, display and keep all the safety and security sheets concerning the chemicals used on our products, fabrics and accessories during - but not restricted to - production, finishing and/or transport.

You will hereby acknowledges: . • the receipt and content of the List of Restricted Chemicals (Imps & Elfs RSL 3.0 & RSL Introduction letter) sent to you in mail;• the commitment to fully and unconditionally comply with the List of restricted chemicals and additional requirements;• If required Imps & Elfs will ask you to conduct and present test report in some of the products.

Kind Regards,

Fons CohenImps & Elfs BV

Signed and agreed:

Name:

Date:

RiskMatrix3.0

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CHEMICALNATURALFIBERS

BLENDEDFIBERS

SYNTHETICFIBERS

ARTIFICIALLEATHER(WITHFIBERBACKING)

NATURALLEATHER

COATINGANDPRINTS

NATURALMATERIALS

POLYMERS,PLASTICS,FOAMS,

NATURAL&SYNTHETICRUBBER

METALFEATHER&DOWN

GLUE

ALKYLPHENOLSANDALKYPHENOLETHOXYLATES

●●● ●●● ●●● ●●● ●●● ●●● ●●● ●●● ● ●●●

AZODYES ●●● ●●● ●●● ●●● ●●● ●●● ●●● ●●●

BIOCIDES ● ● ● ● ● ● ●CHLOROBENZENESANDCHLOROTOLUENES

●● ●● ●

CHLORINATEDPARAFFINS ● ● ● ● ●●● ●● ●●

CHLORINATEDPHENOLSPCP&TECP ● ● ● ● ● ●

ALLERGENICDISPERSEDYES ●● ●● ●● ●●

CARCINOGENICDYES ●● ●● ●● ●● ●●

FLAMERETARDENTS ● ● ● ● ● ● ● ●● ●●

FORMALDEHYDE ●●● ●●● ●●● ●●● ●●● ●●● ●●● ●●●

HEAVYMETALSEXTRACTABLEANDSOLUBLE

●● ●● ●● ●● ●● ●● ●●

CHROMIUMVI ● ●●●

HEAVYMETALSTOTALCONTENTLEAD&CADMIUM

● ● ● ●

HEAVYMETALS,RELEASABLENICKLE ●●●

ORGANOTINCOMPOUNDS ● ● ● ● ● ● ● ●PERFLUORINATEDCHEMICALSPFOS&

PFOA●●

PHTHALATES ●●● ●●● ●●● ●●●

POLYCLICAROMATICHYDROCARBONS ●●● ●●● ●●● ●●●

PVC ●● ●●SOLVENTSHALOGENATEDANDOTHERS-VOLATILEORGANICCOMPOUNDS

●● ●● ●● ●● ●● ●● ●● ●●

pH ●● ●● ●● ●● ●●

●●(Ifwater-orstain-repellantfinishisapplied)

●●●indicatethatachemicalhasbeeninwidespreaduseand/orfrequentlydetectedinaparticularmaterial.●●indicatethatachemicalhasbeendeliberatelyusedand/ordetectedinaparticularmaterialoccasionally.●indicatesthereisaverylowbuttheoreticalchancethatachemicalcouldbeusedand/ordetected.Nodotindicatesthatwebelievethereisanalmostnegligibleriskofachemicalbeingusedand/ordetected.

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SUBSTANCE CASNUMBER TESTMETHOD IMPS&ELFSRESTRICTEDLIMIT RELEVANCEOFRESTRICTION

Nonylphenols(NP)

104-40-511066-49-225154-52-384852-15-390481-04-2

Octylphenols(OP)140-66-91806-26-427193-28-8

Nonylphenolethoxylates(NPEO)

9016-45-926027-38-337205-87-168412-54-4127087-87-0

Octylphenolethoxylates(OPEO)9002-93-19036-19-568987-90-6

4-Aminobiphenyl 92-67-1Benzidine 92-87-54-Chloro-o-toluidine 95-69-22-Naphtylamine 91-59-8o-Aminoazotoluene 97-56-35-Nitro-o-toluidine 99-55-84-Chloroaniline 106-47-82,4-Diaminoanisole 615-05-44,4'-Diaminodiphenylmethane(4,4'-MDA) 101-77-93,3'-Dichlorobenzidine 91-94-13,3'-Dimethoxybenzidine 119-90-43,3'-Dimethylbenzidine 119-93-74,4'-Methylenedi-o-toluidine 838-88-0p-Cresidine 120-71-84,4’-Methylene-bis(2-chloraniline) 101-14-44,4'-Oxydianiline 101-80-44,4'-Thiodianiline 139-65-1o-Toluidine 95-53-42,4-Toluenediamine(2,4-TDA) 95-80-72,4,5-Trimethylaniline 137-17-7o-Anisidine(2-Methoxyaniline) 90-04-04-Aminoazobenzene(4-AAB) 60-09-32,4-Xylidine 95-68-12,6-Xylidine 87-62-7

ALKYLPHENOLS(AP)ANDALKYLPHENOLETHOXYLATES(APEO)


Textiles:ISO18254-1:2016.

Leather:ISO18218-1:2015

<10mg/kg

APEOsarewidelyusedindetergents,scouringagents,wettingagents,softeners,leatherfinishing,de-gummingforsilk,Polyesterpaddingandmanyotheruses.APEO'scaneasilydegradetoAP's

whichareconsideredtobetoxic,persistenttotheenvironmentandbioaccumulative.

<100mg/kg

Textiles:EN14362-1:2017

Leather:ENISO17234-1:2015

TestMethodforconfirmationof4-Aminoazobenzene(4AAB)

Textiles(EU):EN14362-3:2017Leather(EU):ENISO17234-2:2011

Notused<20mg/kg

AZODyesmayreleaseoneormorearylamines.Thelistedarylaminesareconsideredtobecarcinogenic.

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Dimethylfumarate 624-49-7 ISO16186:2012Extraction,GC-MSNotdetected

Detectionlimit:0.1mg/kg

Dimethylfumarate(DMFu)isafungicideusedtopreventmouldinleatherandtextiles.DMFucancauseacutedermatitis,eczema,andgeneralfatiguetothepersonswhohavebeenincontactwiththis

substance.CanalsobeusedasPesticide

o-Phenylphenol(OPP) 90-43-7 ISO13365:2011Extraction,GC-MS <50mg/kg

o-Phenylphenolcanbeusedforitspreservativepropertiesinleatherorasacarrierindyeingprocesses.Canirritatetheskinandcausein

contactwitheyesevereirritationandburnswithpossibleeyedamage.

Pentachlorobenzenes(PCB) 608-93-5Hexachlorobenzene(HCB) 118-741Trichlorobenzenes:1,2,3-TriCB1,2,4-TriCB1,3,5-TriCB

87-61-6120-82-1108-70-3

Tetrachlorobenzenes:1,2,3,4-TeCB1,2,3,5-TeCB1,2,4,5-TeCB

634-66-2634-90-295-94-3

Chlorobenzene 108-90-7Dichlorobenzenes:1,2-DiCB1,3-DiCB1-4-DiCB

95-50-1541-73-1106-46-7

Monochlorotoluenes:2-CT3-CT4-CT

95-49-8108-41-8106-43-4

Dichlorotoluenes:2,3-DiCT2,4-DiCT2,5-DiCT2,6-DiCT3,4-DiCT3,5-DiCT

32768-54-095-73-8

19398-61-9118-69-495-75-0

25186-47-4

Trichlorotoluenes:2,3,6-TRiCT2,4,5-TRiCTα,α,α,-TriCT

98-07-72077-46-56639-30-1

Tetrachlorotoluenes:α,α,α,4-TetraCTα,α,α,2-TetraCT2,6,α,α-TetraCT

5216-25-181-19-6

2136-89-2

Pentachlorotoluenes 877-11-2

BIOCIDES

CHLOROBENZENESANDCHLOROTOLUENES

DIN54232:2010followedbyGC-MS <1mg/kg(total).

Thesecarriersareusedindyeingpolyesterandblendsofwoolandpolyesteraswoolcannotbedyedatthehightemperatures(130°C)

requiredfordyeingpolyester.Mostofthesecarriersaretoxictohumansandaquaticorganisms,

andsomeareevencarcinogenic.

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Short-chainchlorinatedparaffins(SCCP) 85535-84-8 ENISO18219:2015 <1000mg/kgSCCP’s:usedasflameretardants,inplasticizers,paintsand

adhesives.Alsousedforfatliquoringofleather.SCCP’smaycauselong-termadverseeffectsintheaquaticenvironment.

Pentachlorophenol(PCP) 87-86-5

2,3,5,6-Tetrachlorophenol(TeCP) 935-95-5

2,3,4,6-Tetrachlorphenol(TeCP) 58-90-2

2,3,4,5-Tetrachlorphenol(TeCP) 4901-51-3

2,3,4-Trichlorophenol(TrCP) 15950-66-0






2,3-Dichlorophenol(DCP) 576-24-9






2-Chlorophenol(MCP) 95-57-8



CHLORINATEDPARAFFINS

CHLOROPHENOLS

ExtractionwithKOHfollowedbyGC-MS*.

*Incaseofresultsclosetolimitvalue(+/-10%)re-testwithreferencemethod:§64LFGBBVLB82.02-

8(2001)(fortextiles)orISO17070(2015)(forleather)

PCPandTeCP’sarepolychlorinatedcompoundsusedtopreservewood,leather,andtextiles.PCPandTeCP’sareirritatantstotheskin,eyesandmouthandcancauseharmfuleffectstotheliver,kidneys,bloodandlungsandareprobablehumancarcinogens

<0.05mg/kg

<0.2mg/kg

<0.5mg/kg

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C.I.DisperseBlue1 2475-45-8C.I.DisperseBlue35 12222-75-2C.I.DisperseBlue106 12223-01-7C.I.DisperseBlue124 61951-51-7C.I.DisperseOrange3 730-40-5

C.I.DisperseOrange37/59/7612223-33-513301-61-6

C.I.DisperseRed1 2872-52-8C.I.DisperseYellow3 2832-40-8C.I.DisperseBlue3 2475-46-9C.I.DisperseBlue7 3179-90-6C.I.DisperseBlue26 3860-63-7C.I.DisperseBlue102 12222-97-8C.I.DisperseBrown1 23355-64-8C.I.DisperseOrange1 2581-69-3C.I.DisperseOrange149 85136-74-9C.I.DisperseRed11 2872-48-2C.I.DisperseRed17 3179-89-3C.I.DisperseYellow1 119-15-3C.I.DisperseYellow9 6373-73-5C.I.DisperseYellow23 6250-23-3C.I.DisperseYellow39 12236-29-2C.I.DisperseYellow49 54824-37-2

C.I.AcidRed26 3761-53-3C.I.BasicRed9 569-61-9C.I.BasicBlue26(with≥0.1%Michler'sketoneorbase) 2580-56-5

C.I.BasicGreen4(oxalate,chlorideorfree)2437-29-8,569-64-2,10309-95-2

C.I.BasicViolet3(with≥0.1%Michler'sketoneorbase) 548-62-9C.I.BasicViolet14 632-99-5C.I.DirectBlack38 1937-37-7C.I.DirectBlue6 2602-46-2DirectBrown95 16071-86-6C.I.DirectRed28 573-58-0C.I.DisperseBlue1 2475-45-8C.I.DisperseOrange11 82-28-0C.I.DisperseYellow3 2832-40-8C.I.Disperseorange11 82-28-0C.I.PigmentRed104 12656-85-8C.I.PigmentYellow34 1344-37-2

AccordingtotheCommissionDecisionthesedyestuffsarenotallowedinproductsbearingtheEUEco-labelbecausetheyare

consideredtobecarcinogenic.

DISPERSEDYESWHICHARECLASSIFIEDTOBEALLERGENIC

DIN54231:2005§64LFGBB82.02-10

Notused<3mg/l(=appr.50mg/kg)

Dispersedyesaremainlyusedfordyeingpolyester,nylonandcelluloseacetate.Somedispersedyeshaveanallergenouspotentialtothehumanskinandareapossiblethreattohealth,especiallyifthedyesarenotcolourfasttoperspiration.AnumberofdispersedyesarelegallyrestrictedoutsidetheEU.Mostofthemappearin

RSL'sofinternationalretailers.

DYESWHICHARECLASSIFIEDTOBECARCINOGENIC

DIN54231:2005§64LFGBB82.02-10


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NavyBlueisamixtureof:disodium(6-(4-anisidino)-3-sulfonato-2-(3,5-dinitro-2-oxidophenylazo)-1-naphtholato)(1-(5-chloro-2-oxidophenylazo)-2-naphtholato)chromate(1-);trisodiumbis(6-(4-anisidino)-3-sulfonato-2-(3,5-dinitro-2-oxidophenylazo)-1-naphtholato)-chromate(1-)

Component1:118685-33-9

Component2:Notallocated

DIN54231:2005§64LFGBB82.02-10


Navy blue 018112 has a high aquatic toxicity and is harmful to the environment. Carcinogenic.

Heptabromodiphenylether446255-22-7207122-16-5

Hexabromodiphenylether 36483-60-0Tetrabromodiphenylether 5436-43-12,2-bis(bromomethyl)-1,3-propanediol(BBMP) 3296-90-0Bis-(2,3-dibromopropyl)phosphate(BIS) 5412-25-9

Boricacid10043-35-311113-50-1

Diborontrioxide 1303-86-2

Disodiumtetraborate,anhydrous1303-96-41330-43-4

Pentabromodiphenylether(PentaBDE)32534-81-960348-60-9

Tetraborondisodiumheptaoxide,hydrate 12267-73-1TetrabromobisphenolA 79-94-7Tris-(2,3-dibromopropyl)-phosphate(TRIS) 126-72-7Tris-(aziridinyl)-phosphineoxide(TEPA) 545-55-1Trixylylphosphate(TXP) 25155-23-1Polybrominatedbiphenyls(PBBs) 59536-65-1Octabromodiphenylether(octaBDE) 32536-52-0DecabromodiphenylEther(DecaBDE) 1163-19-5

Hexabromocyclododecane(HBCDD)

25637-99-43194-55-6

134237-50-6134237-51-7134237-52-8

Tris-(2-chloroethyl)-phosphate(TCEP) 115-96-8

Tris(1,3-dichloro-2-propyl)phosphate(TDCPP) 13674-87-8

Formaldehyde 50-00-0ISO14184-1:2011(Textiles)

.ISO17226-2:2008(Leather)

NotdetectedDetectionlimit:16mg/kg

Formaldehyde:usedinanti-creasing,anti-shrinking,easy-ironingandwaterrepellencefinishing.Formaldehydeisatoxicchemicalwhich

caninduceirritationtoeyesandnoseandevencausecancer.

FORMALDEHYDE

FLAMERETARDENTS

DYESWITHENVIRONMENTALPROBLEMS

SolventextractionandanalysisbyGC-MSorLC-MSNotdetected

Detectionlimit:5mg/kg

Thesetypesofflameretardentsaretoxicandaresuspectedtobecarcinogenic.Theypersistintheenvironmentandfoodchain,and

arelikelytopassupthefoodchain.

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Arsenic(As) 7440-38-2 <0.2mg/kg

Chromium(Cr) 7440-47-3 <1.0mg/kg

Cobalt(Co) 7440-48-4 <1.0mg/kg

Copper(Cu) 7440-50-8 <25.0mg/kg**

Lead(Pb) 7439-92-1 <0.2mg/kg

Nickel(Ni) 7440-02--0 <1.0mg/kg

Antimony(Sb) 7440-36-0 <30mg/kg

Cadmium(Cd) 7440-43-9 <0.1mg/kg

Mercury(Hg) 7439-97-6 <0.02mg/kg

ChromiumVI(CrVI) 18540-29-9

ENISO17075-1:2017afteraging,agingconditions:24H/80degreesC./5%humidity.

.§64LFGB82.02-11(2008)

NotdetectedDetectionLimit:

3mg/kg

Manyheavymetalsarebioaccumulativewhenabsorbedbythehumanbodythroughperspirationandgivecauseforconcernin

healthtermssuchaschronictoxicity,allergenicreactionsandcancer

Antimony(Sb) 7440-36-0 <60mg/kgArsenic(As) 7440-38-2 <25mg/kgBarium 7440-39-3 <1000mg/kgCadmium(Cd) 7440-43-9 <75mg/kgChromium(Cr) 7440-47-3 <60mg/kgLead(Pb) 7439-92-1 <90mg/kgMercury(Hg) 7439-97-6 <60mg/kgSelenium(SE) 7782-49-2 <500mg/kg

Cadmiumanditscompounds 7440-43-9

EN1122:2001.

Formetalparts:digestionwithaquaregia,determinationusingICP.

<40mg/kg

Leadanditscompounds 7439-92-1

TotalDigestion(industrypractice-notspecifiedbytheregulation)

.Formetalpartsdigestionwithaquaregia,

determinationusingICP.

<90mg/kg

HEAVYMETALS,SOLUBLEAPPLICABLEFORGARMENTCOMPONENTS

Extractionwithsimulatedgastricsolutionacc.toEN71-3:1995



APPLICABLEFORLEATHERANDWOOLITEMS



ExtractableContent:Extractionwithacidperspirationaccordingto

ENISO105-E04:2013.

**Norequirementforaccessoriesandyarnsmadefrominorganicmaterials,respectingthe

requirementsregardingbiologicalactiveproducts



HEAVYMETALS,EXTRACTABLETEXTILESANDTRIMS

HEAVYMETALS,TOTALCONTENT

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Nickel 7440-02-0

NickelreleaseEN1811:2011+A1:2015

andAbrasionofcoateditemsEN12472:2005+A1:2009

Consumergoodssuchasjewellery,snapfasteners,pressbuttons,zipfasteners,etc.,whichcancomeintocontactwiththehumanskinforalongerperiodmustnot

releasemorethan0.5µgnickelpercm²perweek(<0.88μg/cm²/week

isdeemedcompliant)

Nickelcancauseextremeallergies.

Tributyltin(TBT) 56573-85-4

Triphenyltin(TPhT) 668-34-8

Dibutyltin(DBT) 14488-53-0

Dioctyltin(DOT)15231-44-43542-36-7

Monooctyltin(MOT) 3091-25-6

Monomethyltin(MMT) 23001-26-5

Monophenyltin(MPhT) 2406-68-0

Diphenyltin(DPhT) 1011-95-6

Dimethyltin(DMT) 753-73-1

Dipropyltin(DPT) Several

Monobutyltin(MBT) 78763-54-9

Tricyclohexyltin(TCyHT) 3091-32-5

Trioctyltin(TOT) 2587-76-0

Tripropyltin(TPT) 2279-76-7

Trimethyltin(TMT) 1066-45-1

Tetrabutyltin(TebT) 1461-25-2

Tetraethyltin(TeET) Several

HEAVYMETALS,RELEASABLENICKEL

ORGANOTINCOMPOUNDS

ENISO/TS16179:2012followedbyGC-MS

Organotincompoundsareusedasbiocides(antibacterials),and/orheatstabilizersinplastics,inks,paints,andheattransfermaterial.Itisalsousedtopreventunpleasantodours.Damagetoliver,kidneys,bloodformingprocessesanddisruptionoftheenzymesystemare

possible,particularlytochildren.

<0.5mg/kg

<1mg/kg

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Perfluoroctanesulfonates(PFOS) Various

Perfluoroctaneacids(PFOA) Various

Perfluorooctanesulfonamide(PFOSA) 754-91-6

Perfluorooctanesulfonfluoride(PFOSF/POSF) 307-35-7

N-Methylperfluorooctanesulfonamide(N-Me-FOSA) 31506-32-8

N-Ethylperfluorooctanesulfonamide(N-Et-FOSA) 4151-50-2N-Methylperfluorooctanesulfonamideethanol(N-Me-FOSE)

24448-09-7

N-Ethylperfluorooctanesulfonamideethanol(N-Et-FOSE)

1691-99-2

Perfluoroheptanoicacid(PFHpA) Various

Perfluorononanoicacid(PFNA) Various

Perfluorodecanoicacid(PFDA) Various

Henicosafluoroundecanoicacid(PFUdA) 2058-94-8

Tricosafluorododecanoicacid(PFDoA) 307-55-1

Pentacosafluorotridecanoicacid(PFTrDA) 72629-94-8

Heptacosafluorotetradecanoicacid(PFTeDA) 376-06-7

Perfluorinatedcarbonicacids:PFBAPFPeAPFHxAPF-3,7-DMOA

375-22-42706-90-3307-24-4

172155-07-6

Perfluorinatedsulfonicacids:PFBSPFHxSPFHpSPFDS

375-73-559933-66-3355-46-4375-92-8335-77-3

Partiallyfluorinatedcarbonic/sulfonicacids:7HPFHpA4HPFUnA1H,1H,2H,2H-PFOS

1546-95-834598-33-927619-97-2

Estersoffluorinatedalcoholswithacrylicacid:6:2FTA8:2FTA10:2FTA

17527-29-627905-45-917741-60-5

Partiallyfluorinatedlinearalcohols:4:2FTOH6:2FTOH8:2FTOH10:2FTOH

2043-47-2647-42-7678-39-7865-86-1

PERFLUORINATEDCHEMICALSANDHERCOMPOUNDS

Solventextraction,LC-MSCEN/TS15968:2010

PFOScanbeusedasimpregnationagentsandcleaningproducts.PFOSispersistent,bioaccumulative,poisonousandpossibly

carcinogenic.PFOAismainlyusedasasurfactantandhavethesameriskprofileas

PFOS.

UsagebanDetectionlimit:1μg/m²

<0.05mg/kg

RSL3.0

Page14


2,4,5-T 93-76-52,4-D 94-75-7

Acetamiprid135410-20-7160430-64-8

Aldicarb 116-06-3Aldrine 309-00-2

Azinophosethyl 2642-71-9

Azinophosmethyl 86-50-0

Bromophos-ethyl 4824-78-6

Captafol 01-06-25

Carbaryl 63-25-2

Chlorbenzilate 510-15-6

Chlordane 57-74-9

Chlordimeform 6164-98-3

Chlorfenvinphos 470-90-6

Clothianidin 210880-92-5

Coumaphos 56-72-4

Cyfluthrin 68359-37-5

Cyhalothrin 91465-08-6

Cypermethrin 52315-07-8

DEF 78-48-8

Deltamethrin 52918-63-5

DDD53-19-072-54-8

DDE3424-82-672-55-9

DDT�� 50-29-3

Diazinon 333-41-5

Dichlorprop 120-36-2

Dicrotophos 141-66-2

Dieldrine 60-57-1

Dimethoate 60-51-5

Dinosebandsalts 88-85-7

Dinotefuran 165252-70-0

Endosulfan,α- 959-98-8

Endosulfan,β- 33213-65-9

Endrine 72-20-8

Esfenvalerate 66230-04-4

PESTICIDES

ASEorSoxhletExtractionwithAcetone/Hexane//GC-MSorLC-MC

Sum0.5mg/kg

Apesticidemaybeachemicalsubstance,biologicalagent(suchasavirusorbacteria),antimicrobial,disinfectantordeviceusedagainst

anypest.

Pesticidesalsohavedrawbacks:potentialtoxicitytohumansandanimals.

Intextilesandapparel,thesepesticidesmaybefoundinnaturalfibres,primarilycotton.

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Page15


Fenvalerate 51630-58-1

Heptachlorine 76-44-8

Heptachloroepoxide 1024-57-3

Hexachlorobenzene 118-74-1

Hexachlorcyclohexane,α- 319-84-6

Hexachlorcyclohexane,β- 319-85-7

Hexachlorcyclohexane,δ- 319-86-8

Imidacloprid105827-78-9,138261-41-3

Isodrine 465-73-6

Kelevane 4234-79-1

Kepone 143-50-0

Lindane 58-89-9

Malathion 121-75-5

MCPA 94-74-6

MCPB 94-81-5

Mecoprop 93-65-2

Metamidophos 10265-92-6

Methoxychlor 72-43-5

Mirex 2385-85-5

Monocrotophos 6923-22-4

Nitenpyram150824-47-8120738-89-8

Parathion 56-38-2

Parathion-methyl 298-00-0

Perthane 72-56-0

Phosdrin/Mevinphos 7786-34-7

Phosphamidone 13171-21-6

Propethamphos 31218-83-4

Profenophos 41198-08-7

Strobane 8001-50-1

Quinalphos 13593-03-8

Telodrine 297-78-9

Thiacloprid 111988-49-9

Thiamethoxam 153719-23-4

Toxaphene 8001-35-2

Trifluralin 1582-09-8

Apesticidemaybeachemicalsubstance,biologicalagent(suchasavirusorbacteria),antimicrobial,disinfectantordeviceusedagainst

anypest.

PESTICIDESCONTINUED

ASEorSoxhletExtractionwithAcetone/Hexane//GC-MSorLC-MC

Sum0.5mg/kg

RSL3.0

Page16


Bis(2-ethylhexyl)phthalate(DEHP) 117-81-7

Dibutylphthalate(DBP) 84-74-2

Butylbenzylphthalate(BBP) 85-68-7

Di-“isononyl”phthalate(DINP)28553-12-068515-48-0

Di-“isodecylphthalate(DIDP)26761-40-068515-49-1

Di-n-octylphthalate(DNOP) 117-84-0

Di-isobutylphthalate(DIBP) 84-69-51,2-Benzenedicarboxylicacid,dipentylester,branchedandlinear

84777-06-0

1,2-Benzenedicarboxylicacid,di-C6-8-branchedalkylesters,C7-rich(DIHP)*

71888-89-6

Di-isopentylphthalate(DIPP) 605-50-5

Dipentylphthalate(DPP) 131-18-0

Bis(2-methoxyethyl)phthalate(DMEP) 117-82-8

Di-n-hexylphthalate(DnHP) 84-75-3

1,2-Benzenedicarboxylicacid,di-C7-11-branchedandlinearalkylesters(DHNUP)

68515-42-4

N-pentyl-isopentylphthalate(NPIPP) 776297-69-9

1,2-Benzenedicarboxylicacid.Dihexylester.Branchedandlinear(DHxP)

68515-50-4

1,2-benzenedicarboxylicacid,di-C6-10-alkylesters;1,2-benzenedicarboxylicacid,mixeddecylandhexylandoctyldiesterswith≥0.3%ofdihexylphthalate(ECNo.201-559-5)

68515-51-568648-93-1

Di-iso-hexylphthalate(DIHxP) 71850-09-4

Di-cyclohexylphthalate(DCHP) 84-61-7

Diethylphthalate(DEP) 84-66-2

Di-n-propylphthalate(DPrP) 131-16-8

Dimethylphthalate(DMP) 131-11-3

Di-iso-octylphthalate(DIOP) 27554-26-3

Di-n-nonylphthalate(DNP) 84-76-4

PHTHALATES

ISO14389:2014ThesumofallPhthalates

<500mg/kg

Phthalatesareaddedtoplasticstoincreaseflexibility.Intextilesandapparel,phthalatescanbefoundincoatedtextiles,plastic

components,trimsandplastisolprints.Phthalatesarereprotoxicandcancausebirthdefectsandchangesinhormonelevels.AcompletebanofPhthalatesisrecommendedbyNGO'sandmanyretailers.

RSL3.0

Page17


Benzo(a)pyrene[BaP] 50-32-8

Benzo(a)anthracene 56-55-3

Chrysene 218-01-9

Benzo(b)fluoranthene 205-99-2

Benzo(k)fluoranthene 207-08-9

Dibenzo(ah)anthracene 53-70-3

Benzo(e)pyrene 192-97-2

Benzo(j)fluoranthene 205-82-3

Acenaphthene 83-32-9

Acenaphthylene 208-96-8

Antracene 120-12-7

Benzo(ghi)perylene 191-24-2

Fluoranthene 206-44-0

Fluorene 86-73-7

Indeno(1,2,3-cd)pyrene 193-39-5

Naphthalene 91-20-3

Phenanthrene 85-01-8

Pyrene 129-00-0

Cyclopenta[c,d]pyrene 27208-37-3

Dibenzo[a,e]pyrene 192-65-4

Dibenzo[a,h]pyrene 189-64-0

Dibenzo[a,i]pyrene 189-55-9

Dibenzo[a,l]pyrene 191-30-0

1-Methylpyrene 2381-21-7

Polyvinylchloride 9002-86-2 Beilsteintest/InfraredSpectroscopy(FTIR) UsagebanTheuseofPVCisvoluntarilyrestrictedbecauseitisclaimedthatdioxinsareproducedasabyproductofvinylchloridemanufactureandfromburningofwastePVC

POLYCYCLICAROMATICHYDROCARBONS(PAH’S)

PVC

AfPSGS2014:01PAH

<0.5mg/kgeach

Rubberorplasticcomponentsthatcomeintodirectandprolongedcontactwiththehumanskinortheoralcavitycancausesevere

allergenicreactions.

Thesumof24PAH's≤5mg/kg

RSL3.0

Page18


Cadmium(Cd)

Lead(Pb)

Chromium(Cr6+)—hexavalent

Mercury(Hg)

1,2-Dichloroethane 107-06-21,2,3-Trichloropropane 96-18-4Bis-(2-methoxyethyl)ether 111-96-6Formamide 75-12-71-Methyl-2pyrrolidone 872-50-42-Ethoxyethylacetate 111-15-9DMAC(N,N-dimethylacetamide) 127-19-5DMFa(N,NDimethylformamide) 68-12-2 300mg/kgMEK(Methyl-Ethyl-Ketone) 78-93-3 100mg/kgCyclohexanone 108-94-1 100mg/kg2-Ethoxyethanol 110-80-5 50mg/kg2-Ethoxyethylacetate 111-15-9 50mg/kg1,2-Dimethoxyethane(DME) 110-71-4 50mg/kg2-Methoxyethanol 109-86-4 50mg/kg2-Methoxyethylacetate 110-49-6 50mg/kg2-Methoxypropylacetate 70657-70-4 50mg/kgTriethyleneglycoldimethylether 112-49-2 50mg/kgTrichloroethylene 79-01-6 40mg/kgXylene 1330-20-7 20mg/kgEthylbenzene 100-41-4 20mg/kgOrthoxylene 95-47-6 20mg/kgMetaxylene 108-38-3 20mg/kgParaxylene 106-42-3 20mg/kgo-Cresol 95-48-7 20mg/kgp-Cresol 106-44-5 20mg/kgm-Cresol 108-39-4 20mg/kgAcetophenone 98-86-2 20mg/kg2-Phenyl-2-propanole 617-94-7 20mg/kgStyrene 100-42-5 10mg/kgNaphthalene 91-20-3 10mg/kgToluene 108-88-3 5mg/kgTetrachloroethylene 127-18-4 5mg/kgMethylenechloride 75-09-2 5mg/kgBenzene 71-43-2 1mg/kg

HeadspaceGC-MSVOC’sareorganicchemicalcompoundsthatvaporizeundernormal

conditionsandentertheatmosphere.CommonartificialVOCsincludethinnersanddrycleaningsolvents

1000mg/kg

SOLVENTS-VOLATILEORGANICCOMPOUNDS

RESTRICTIONONPACKAGING

VariousCEN/TR13695-1

AciddigestionwithICPanalysis

Thesumofconcentrationlevelsoflead,cadmium,mercuryand

hexavalentchromiumpresentinpackagingorpackaging

componentsshallnotexceed100mg/kg

Packagingmeanstransportationpackagingaswellasproductpackaging,i.e.,anymaterialusedforthecontainment,protection,handling,delivery,andpresentationoffinishedgoods(article).

RSL3.0

Page19


pHvaluefortextiles ISO3071:2005 4.0–7.5

pHisameasureoftheacidityorbasicityofasolution.AsolutionwithpHis7isneutral.pHvaluesthatdonotfallwithin

thespecifiedlimitscancauseskinirritation

Odour SNV195651:1968Noabnormalodourallowed.Ifodourrating>3,VOCtesttobe

performed

OTHERATTENTIONPOINTS

REACHCANDIDATELIST3.0

Page20

REACHANNEX:ECHA’SCANDIDATELISTOFSUBSTANCESOFVERYHIGHCONCERNLASTUPDATE07-07-2017NUMBEROFSUBSTANCESONTHECANDIDATELIST:174

Substances,preparationsandarticleswillbeassessedontheirrisksforhealthandenvironmentalaspects

AnyproducerorimporterofImps&ElfsarticlesshallsubmitanotificationtoImps&Elfsforanysubstancecontainedinthosearticles,ifthefollowingconditionismet:

CandidateListofSubstancesofVeryHighConcernforauthorisationTheidentificationofasubstanceasSubstanceofVeryHighConcern(SVHC)anditsinclusionintheCandidateLististhefirststepoftheauthorisationprocedure.Companiesmayhaveimmediatelegalobligationsfollowingsuchinclusionwhicharelinkedtothelistedsubstanceonitsown,inpreparationsandarticles.

No. SubstanceName CasNumber Dateofinclusion Reasonforinclusion

1Perfluorohexane-1-sulphonicacidanditssaltsPFHxS

- .2017/07/07 vPvB(Article57e)

24,4'-isopropylidenediphenolBisphenolA;BPA

80-05-7 .2017/01/12 Toxicforreproduction(Article57c)

3

4-heptylphenol,branchedandlinearsubstanceswithalinearand/orbranchedalkylchainwithacarbonnumberof7covalentlyboundpredominantlyinposition4tophenol,coveringalsoUVCB-andwell-definedsubstanceswhichincludeanyoftheindividualisomersoracombinationthereof

- .2017/01/12Equivalentlevelofconcernhavingprobableseriouseffectstotheenvironment(Article57f)

4 Nonadecafluorodecanoicacid(PFDA)anditssodiumandammoniumsalts3830-45-33108-42-7335-76-2

.2017/01/12 Toxicforreproduction(Article57c)PBT(Article57d)

5 p-(1,1-dimethylpropyl)phenol 80-46-6 .2017/01/12Equivalentlevelofconcernhavingprobableseriouseffectstotheenvironment(Article57f)

6 Benzo{def}chrysene 50-32-8 .2016/20/06Carcinogenic(Article57a):Mutagenic(Article57b);Toxicforreproduction(Article57c);PBT(Article57d);vPvB(Article57e)

7 1,3-propanesultone 1120-71-4 .2015/12/15 Carcinogenic(Article57a);8 2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)phenol(UV-327) 3864-99-1 .2015/12/15 vPvB(Article57e)9 2-(2H-benzotriazol-2-yl)-4-(tert-butyl)-6-(sec-butyl)phenol(UV-350) 36437-37-3 .2015/12/15 vPvB(Article57e)10 Nitrobenzene 98-95-3 .2015/12/15 Toxicforreproduction(Article57c)

11 Perfluorononan-1-oic-acidanditssodiumandammoniumsalts375-95-121049-39-84149-60-4

.2015/12/15 Toxicforreproduction(Article57c);PBT(Article57d)

121,2-benzenedicarboxylicacid,di-C6-10-alkylesters;1,2-benzenedicarboxylicacid,mixeddecylandhexylandoctyldiesterswith≥0.3%ofdihexylphthalate(ECNo.201-559-5)

68515-51-568648-93-1

.2015/06/15 Toxicforreproduction(Article57c)

Note:TheECnumberincludesbothanhydrousandhydratedformsofasubstanceandconsequentlytheentriescoverboththeseforms.TheCASnumberincludedmaybefortheanhydrousformonly,andthereforetheCASnumbershowndoesnotalwaysdescribetheentryaccurately.

Asubstanceofthecandidatelistispresentintheimported/producedarticleswithover0.1%w/w(>1000mg/kg).(EuropeanCourtofJusticejudgementof10-09-2015caseC-106/14referringtoeveryconstituentpartofthearticle)

FurtherdocumentationormoredetailedinformationontheidentificationprocessofSubstancesofVeryHighConcerncanbefoundonthewebpagesofECHA'sMemberStateCommittee.


Page21


135-sec-butyl-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane[1],5-sec-butyl-2-(4,6-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane[2][coveringanyoftheindividualstereoisomersof[1]and[2]oranycombinationthereof]

- .2015/06/15 vPvB(Article57e)

14 Bis(2-ethylhexyl)phthalate(DEHP) 117-81-72014/12/17;2008/10/28

Equivalentlevelofconcernhavingprobableseriouseffectstotheenvironment(Article57f);Toxicforreproduction(article57c)

15 2-ethylhexyl10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate(DOTE) 15571-58-1 .2014/12/17 Toxicforreproduction(Article57c)16 2-benzotriazol-2-yl-4,6-di-tert-butylphenol(UV-320) 3846-71-7 .2014/12/17 PBT(Article57d);vPvB(Article57e)

17reactionmassof2-ethylhexyl10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoateand2-ethylhexyl10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4-octyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate(reactionmassofDOTEandMOTE)

- .2014/12/17 Toxicforreproduction(Article57c)

18 Cadmiumfluoride 7790-79-6 .2014/12/17Carcinogenic(Article57a);Mutagenic(Article57b);Toxicforreproduction(Article57c);Equivalentlevelofconcernhavingprobableseriouseffectstohumanhealth(Article57f)

19 Cadmiumsulphate10124-36-431119-53-6

.2014/12/17Carcinogenic(Article57a);Mutagenic(Article57b);Toxicforreproduction(Article57c);Equivalentlevelofconcernhavingprobableseriouseffectstohumanhealth(Article57f)

20 2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol(UV-328) 25973-55-1 .2014/12/17 PBT(Article57d);vPvB(Article57e)

21 Cadmiumchloride 10108-64-2 2014/06/16

Carcinogenic(Article57a);Mutagenic(Article57b);Toxicforreproduction(Article57c);Equivalentlevelofconcernhavingprobableseriouseffectstohumanhealth(Article57f)

22 Sodiumperoxometaborate .7632-04-4 2014/06/16 Toxicforreproduction(Article57c)23 1,2-Benzenedicarboxylicacid,dihexylester,branchedandlinear 68515-50-4 2014/06/16 Toxicforreproduction(Article57c)24 Sodiumperborate;perboricacid,sodiumsalt - 2014/06/16 Toxicforreproduction(Article57c)25 Trixylylphosphate 25155-23-1 2013/12/16 Toxicforreproduction(Article57c);26 Leaddi(acetate) 301-04-2 2013/12/16 Toxicforreproduction(Article57c);27 Imidazolidine-2-thione;(2-imidazoline-2-thiol) 96-45-7 2013/12/16 Toxicforreproduction(Article57c);

28Disodium3,3'-[[1,1'-biphenyl]-4,4'-diylbis(azo)]bis(4-aminonaphthalene-1-sulphonate)(C.I.DirectRed28)

573-58-0 2013/12/16 Carcinogenic(Article57a);

29 Cadmiumsulphide 1306-23-6 2013/12/16 Carcinogenic(Article57a);

30Disodium4-amino-3-[[4'-[(2,4-diaminophenyl)azo][1,1'-biphenyl]-4-yl]azo]-5-hydroxy-6-(phenylazo)naphthalene-2,7-disulphonate(C.I.DirectBlack38)

1937-37-7 2013/12/16 Carcinogenic(Article57a);

31 Dihexylphthalate 84-75-3 2013/12/16 Toxicforreproduction(Article57c);32 Ammoniumpentadecafluorooctanoate(APFO) 3825-26-1 2013/06/20 Toxicforreproduction(Article57c);

33

4-Nonylphenol,branchedandlinear,ethoxylated[substanceswithalinearand/orbranchedalkylchainwithacarbonnumberof9covalentlyboundinposition4tophenol,ethoxylatedcoveringUVCB-andwell-definedsubstances,polymersandhomologues,whichincludeanyoftheindividualisomersand/orcombinationsthereof]

- 2013/06/20Equivalentlevelofconcernhavingprobableseriouseffectstotheenvironment(Article57f)

34 Pentadecafluorooctanoicacid(PFOA) 335-67-1 2013/06/20 Toxicforreproduction(Article57c);35 Dipentylphthalate(DPP) 131-18-0 2013/06/20 Toxicforreproduction(Article57c);

36 Cadmium 7440-43-9 2013/06/20Carcinogenic(Article57a);Equivalentlevelofconcernhavingprobableseriouseffectstohumanhealth(Article57f)


Page22


37 Cadmiumoxide 1306-19-0 2013/06/20Carcinogenic(Article57a);Equivalentlevelofconcernhavingprobableseriouseffectstohumanhealth(Article57f)

38 4,4'-methylenedi-o-toluidine 838-88-0 2012/12/19 Carcinogenic(Article57a)39 N-pentyl-isopentylphthalate 776297-69-9 2012/12/19 Toxicforreproduction(Article57c)40 4-Aminoazobenzene 60-09-3 2012/12/19 Carcinogenic(Article57a)41 Orangelead(leadtetroxide) 1314-41-6 2012/12/19 Toxicforreproduction(Article57c)42 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine 143860-04-2 2012/12/19 Toxicforreproduction(Article57c)43 Dimethylsulphate 77-78-1 2012/12/19 Carcinogenic(Article57a)44 Heptacosafluorotetradecanoicacid 376-06-7 2012/12/19 vPvB(Article57e)45 Leadtitaniumzirconiumoxide 12626-81-2 2012/12/19 Toxicforreproduction(Article57c)

464-(1,1,3,3-tetramethylbutyl)phenol,ethoxylated[coveringwell-definedsubstancesandUVCBsubstances,polymersandhomologues]


47 6-methoxy-m-toluidine(p-cresidine) 120-71-8 2012/12/19 Carcinogenic(Article57a)48 Dinoseb(6-sec-butyl-2,4-dinitrophenol) 88-85-7 2012/12/19 Toxicforreproduction(Article57c)49 1,2-Diethoxyethane 629-14-1 2012/12/19 Toxicforreproduction(Article57c)50 Sulfurousacid,leadsalt,dibasic 62229-08-7 2012/12/19 Toxicforreproduction(Article57c)51 1-bromopropane(n-propylbromide) 106-94-5 2012/12/19 Toxicforreproduction(Article57c)52 Bis(pentabromophenyl)ether(decabromodiphenylether;DecaBDE) 1163-19-5 2012/12/19 PBT(Article57d);vPvB(Article57e)53 Biphenyl-4-ylamine 92-67-1 2012/12/19 Carcinogenic(Article57a)54 Pentaleadtetraoxidesulphate 12065-90-6 2012/12/19 Toxicforreproduction(Article57c)55 Silicicacid,leadsalt 11120-22-2 2012/12/19 Toxicforreproduction(Article57c)56 o-Toluidine 95-53-4 2012/12/19 Carcinogenic(Article57a)57 Aceticacid,leadsalt,basic 51404-69-4 2012/12/19 Toxicforreproduction(Article57c)58 Dioxobis(stearato)trilead 12578-12-0 2012/12/19 Toxicforreproduction(Article57c)59 Leadbis(tetrafluoroborate) 13814-96-5 2012/12/19 Toxicforreproduction(Article57c)60 Leaddinitrate 10099-74-8 2012/12/19 Toxicforreproduction(Article57c)

61

Silicicacid(H2Si2O5),bariumsalt(1:1),lead-doped[withlead(Pb)contentabovetheapplicablegenericconcentrationlimitfor’toxicityforreproduction’Repr.1A(CLP)orcategory1(DSD);thesubstanceisamemberofthegroupentryofleadcompounds,withindexnumber082-001-00-6inRegulation(EC)No1272/2008]

68784-75-8 2012/12/19 Toxicforreproduction(Article57c)

62

Cyclohexane-1,2-dicarboxylicanhydride[1],cis-cyclohexane-1,2-dicarboxylicanhydride[2],trans-cyclohexane-1,2-dicarboxylicanhydride[3][Theindividualcis-[2]andtrans-[3]isomersubstancesandallpossiblecombinationsofthecis-andtrans-isomers[1]arecoveredbythisentry]

85-42-7,13149-00-3,14166-21-3

2012/12/19Equivalentlevelofconcernhavingprobableseriouseffectstohumanhealth(Article57f)

63 N-methylacetamide 79-16-3 2012/12/19 Toxicforreproduction(Article57c)64 Pyrochlore,antimonyleadyellow 8012-00-8 2012/12/19 Toxicforreproduction(Article57c)65 Leadmonoxide(leadoxide) 1317-36-8 2012/12/19 Toxicforreproduction(Article57c)66 Tetraleadtrioxidesulphate 12202-17-4 2012/12/19 Toxicforreproduction(Article57c)67 Trileadbis(carbonate)dihydroxide 1319-46-6 2012/12/19 Toxicforreproduction(Article57c)

68 Diazene-1,2-dicarboxamide(C,C'-azodi(formamide)) 123-77-3 2012/12/19Equivalentlevelofconcernhavingprobableseriouseffectstohumanhealth(Article57f)

69 1,2-Benzenedicarboxylicacid,dipentylester,branchedandlinear 84777-06-0 2012/12/19 Toxicforreproduction(Article57c)


Page23


70 N,N-dimethylformamide 68-12-2 2012/12/19 Toxicforreproduction(Article57c)71 Tetraethyllead 78-00-2 2012/12/19 Toxicforreproduction(Article57c)72 Methyloxirane(Propyleneoxide) 75-56-9 2012/12/19 Carcinogenic(Article57a);Mutagenic(Article57b)

734-Nonylphenol,branchedandlinear[substanceswithalinearand/orbranchedalkylchainwithacarbonnumberof9covalentlyboundinposition4tophenol,coveringalsoUVCB-andwell-definedsubstanceswhichincludeanyoftheindividualisomersoracombinationthereof]


74 Fattyacids,C16-18,leadsalts 91031-62-8 2012/12/19 Toxicforreproduction(Article57c)75 Trileaddioxidephosphonate 12141-20-7 2012/12/19 Toxicforreproduction(Article57c)76 o-aminoazotoluene 97-56-3 2012/12/19 Carcinogenic(Article57a)77 [Phthalato(2-)]dioxotrilead 69011-06-9 2012/12/19 Toxicforreproduction(Article57c)78 Tricosafluorododecanoicacid 307-55-1 2012/12/19 vPvB(Article57e)79 Leadoxidesulfate 12036-76-9 2012/12/19 Toxicforreproduction(Article57c)80 Methoxyaceticacid 625-45-6 2012/12/19 Toxicforreproduction(Article57c)81 Diisopentylphthalate 605-50-5 2012/12/19 Toxicforreproduction(Article57c)82 Leadcyanamidate 20837-86-9 2012/12/19 Toxicforreproduction(Article57c)83 4,4'-oxydianilineanditssalts 101-80-4 2012/12/19 Carcinogenic(Article57a);Mutagenic(Article57b)84 4-methyl-m-phenylenediamine(toluene-2,4-diamine) 95-80-7 2012/12/19 Carcinogenic(Article57a)85 Henicosafluoroundecanoicacid 2058-94-8 2012/12/19 vPvB(Article57e)86 Furan 110-00-9 2012/12/19 Carcinogenic(Article57a)87 Pentacosafluorotridecanoicacid 72629-94-8 2012/12/19 vPvB(Article57e)88 Diethylsulphate 64-67-5 2012/12/19 Carcinogenic(Article57a);Mutagenic(Article57b)

89

Hexahydromethylphthalicanhydride[1],Hexahydro-4-methylphthalicanhydride[2],Hexahydro-1-methylphthalicanhydride[3],Hexahydro-3-methylphthalicanhydride[4][Theindividualisomers[2],[3]and[4](includingtheircis-andtrans-stereoisomericforms)andallpossiblecombinationsoftheisomers[1]arecoveredbythisentry]

25550-51-0,19438-60-9,48122-14-1,57110-29-9

2012/12/19Equivalentlevelofconcernhavingprobableseriouseffectstohumanhealth(Article57f)

90 Dibutyltindichloride(DBTC) 683-18-1 2012/12/19 Toxicforreproduction(Article57c)91 Leadtitaniumtrioxide 12060-00-3 2012/12/19 Toxicforreproduction(Article57c)92 Formamide 75-12-7 2012/06/18 Toxicforreproduction(Article57c)

93[4-[[4-anilino-1-naphthyl][4-(dimethylamino)phenyl]methylene]cyclohexa-2,5-dien-1-ylidene]dimethylammoniumchloride(C.I.BasicBlue26)[with≥0.1%ofMichler'sketone(ECNo.202-027-5)orMichler'sbase(ECNo.202-959-2)]

2580-56-5 2012/06/18 Carcinogenic(Article57a)

94 Diborontrioxide 1303-86-2 2012/06/18 Toxicforreproduction(Article57c)95 4,4'-bis(dimethylamino)benzophenone(Michler’sketone) 90-94-8 2012/06/18 Carcinogenic(Article57a)96 1,2-dimethoxyethane;ethyleneglycoldimethylether(EGDME) 110-71-4 2012/06/18 Toxicforreproduction(Article57c)97 Lead(II)bis(methanesulfonate) 17570-76-2 2012/06/18 Toxicforreproduction(Article57c)

98α,α-Bis[4-(dimethylamino)phenyl]-4(phenylamino)naphthalene-1-methanol(C.I.SolventBlue4)[with≥0.1%ofMichler'sketone(ECNo.202-027-5)orMichler'sbase(ECNo.202-959-2)]


99 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione(TGIC) 2451-62-9 2012/06/18 Mutagenic(Article57b)


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1004-[4,4'-bis(dimethylamino)benzhydrylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammoniumchloride(C.I.BasicViolet3)[with≥0.1%ofMichler'sketone(ECNo.202-027-5)orMichler'sbase(ECNo.202-959-2)]


1014,4'-bis(dimethylamino)-4''-(methylamino)tritylalcohol[with≥0.1%ofMichler'sketone(ECNo.202-027-5)orMichler'sbase(ECNo.202-959-2)]


102 N,N,N',N'-tetramethyl-4,4'-methylenedianiline(Michler’sbase) 101-61-1 2012/06/18 Carcinogenic(Article57a)103 1,3,5-tris[(2Sand2R)-2,3-epoxypropyl]-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione(β-TGIC) 59653-74-6 2012/06/18 Mutagenic(Article57b)104 1,2-bis(2-methoxyethoxy)ethane(TEGDME;triglyme) 112-49-2 2012/06/18 Toxicforreproduction(Article57c)105 Leadstyphnate 15245-44-0 2011/12/19 Toxicforreproduction(article57c)106 Calciumarsenate 7778-44-1 2011/12/19 Carcinogenic(article57a)107 Bis(2-methoxyethyl)ether 111-96-6 2011/12/19 Toxicforreproduction(article57c)108 Phenolphthalein 77-09-8 2011/12/19 Carcinogenic(article57a)109 Arsenicacid 7778-39-4 2011/12/19 Carcinogenic(article57a)110 2-Methoxyaniline;o-Anisidine 90-04-0 2011/12/19 Carcinogenic(article57a)111 Potassiumhydroxyoctaoxodizincatedichromate 11103-86-9 2011/12/19 Carcinogenic(article57a)112 Bis(2-methoxyethyl)phthalate 117-82-8 2011/12/19 Toxicforreproduction(article57c)

113 4-(1,1,3,3-tetramethylbutyl)phenol 140-66-9 2011/12/19Equivalentlevelofconcernhavingprobableseriouseffectstotheenvironment(article57f)

114 Dichromiumtris(chromate) 24613-89-6 2011/12/19 Carcinogenic(article57a)115 Pentazincchromateoctahydroxide 49663-84-5 2011/12/19 Carcinogenic(article57a)

116

AluminosilicateRefractoryCeramicFibresarefibrescoveredbyindexnumber650-017-00-8inAnnexVI,part3,table3.1ofRegulation(EC)No1272/2008oftheEuropeanParliamentandoftheCouncilof16December2008onclassification,labellingandpackagingofsubstancesandmixtures,andfulfilthethreefollowingconditions:a)oxidesofaluminiumandsiliconarethemaincomponentspresent(inthefibres)withinvariableconcentrationrangesb)fibreshavealengthweightedgeometricmeandiameterlesstwostandardgeometricerrorsof6orlessmicrometres(µm)c)alkalineoxideandalkaliearthoxide(Na2O+K2O+CaO+MgO+BaO)contentlessorequalto18%byweight

- 2011/12/19 Carcinogenic(article57a)

117 Leaddipicrate 6477-64-1 2011/12/19 Toxicforreproduction(article57c)118 N,N-dimethylacetamide 127-19-5 2011/12/19 Toxicforreproduction(article57c)119 1,2-dichloroethane 107-06-2 2011/12/19 Carcinogenic(article57a)120 2,2'-dichloro-4,4'-methylenedianiline 101-14-4 2011/12/19 Carcinogenic(article57a)121 Trileaddiarsenate 3687-31-8 2011/12/19 Carcinogenicandtoxicforreproduction(articles57aand57c)122 Formaldehyde,oligomericreactionproductswithaniline 25214-70-4 2011/12/19 Carcinogenic(article57a)123 Leaddiazide,Leadazide 13424-46-9 2011/12/19 Toxicforreproduction(article57c),


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124

ZirconiaAluminosilicateRefractoryCeramicFibresarefibrescoveredbyindexnumber650-017-00-8inAnnexVI,part3,table3.1ofRegulation(EC)No1272/2008oftheEuropeanParliamentandoftheCouncilof16December2008onclassification,labellingandpackagingofsubstancesandmixtures,andfulfilthethreefollowingconditions:a)oxidesofaluminium,siliconandzirconiumarethemaincomponentspresent(inthefibres)withinvariableconcentrationrangesb)fibreshavealengthweightedgeometricmeandiameterlesstwostandardgeometricerrorsof6orlessmicrometres(µm).c)alkalineoxideandalkaliearthoxide(Na2O+K2O+CaO+MgO+BaO)contentlessorequalto18%byweight

2011/12/19 Carcinogenic(article57a)

125 Cobaltdichloride 7646-79-92011/06/20-2008/10/28

Carcinogenicandtoxicforreproduction(articles57aand57c)

126 1-Methyl-2-pyrrolidone 872-50-4 2011/06/20 Toxicforreproduction(article57c)127 1,2-Benzenedicarboxylicacid,di-C7-11-branchedandlinearalkylesters 68515-42-4 2011/06/20 Toxicforreproduction(article57c)128 Hydrazine 302-01-2,7803-57-8 2011/06/20 Carcinogenic(article57a)129 1,2,3-Trichloropropane 96-18-4 2011/06/20 Carcinogenicandtoxicforreproduction(articles57aand57c)130 1,2-Benzenedicarboxylicacid,di-C6-8-branchedalkylesters,C7-rich 71888-89-6 2011/06/20 Toxicforreproduction(article57c)131 Strontiumchromate 7789-06-2 2011/06/20 Carcinogenic(article57a)132 2-Ethoxyethylacetate 111-15-9 2011/06/20 Toxicforreproduction(article57c)133 2-Ethoxyethanol 110-80-5 2010/12/15 Toxicforreproduction(article57c)134 Cobalt(II)diacetate 71-48-7 2010/12/15 Carcinogenicandtoxicforreproduction(articles57aand57c)135 Cobalt(II)carbonate 513-79-1 2010/12/15 Carcinogenicandtoxicforreproduction(articles57aand57c)136 Cobalt(II)sulphate 10124-43-3 2010/12/15 Carcinogenicandtoxicforreproduction(articles57aand57c)

137Acidsgeneratedfromchromiumtrioxideandtheiroligomers.Namesoftheacidsandtheiroligomers:Chromicacid,Dichromicacid,Oligomersofchromicacidanddichromicacid.

7738-94-5,13530-68-2 2010/12/15 Carcinogenic(article57a)

138 Cobalt(II)dinitrate 10141-05-6 2010/12/15 Carcinogenicandtoxicforreproduction(articles57aand57c)139 Chromiumtrioxide 1333-82-0 2010/12/15 Carcinogenicandmutagenic(articles57aand57b)140 2-Methoxyethanol 109-86-4 2010/12/15 Toxicforreproduction(article57c)141 Trichloroethylene 79-01-6 2010/06/18 Carcinogenic(article57a)

142 Sodiumchromate 7775-11-3 2010/06/18Carcinogenic,mutagenicandtoxicforreproduction(articles57a,57band57c)

143 Boricacid 10043-35-3,11113-50-1 2010/06/18 Toxicforreproduction(article57c)144 Potassiumchromate 7789-00-6 2010/06/18 Carcinogenicandmutagenic(articles57aand57b).145 Tetraborondisodiumheptaoxide,hydrate 12267-73-1 2010/06/18 Toxicforreproduction(article57c)

146 Potassiumdichromate 7778-50-9 2010/06/18Carcinogenic,mutagenicandtoxicforreproduction(articles57a,57band57c)

147 Disodiumtetraborate,anhydrous1303-96-4,1330-43-4,12179-04-3

2010/06/18 Toxicforreproduction(article57c)

148 Ammoniumdichromate 7789-09-5 2010/06/18Carcinogenic,mutagenicandtoxicforreproduction(articles57a,57band57c)

149 Acrylamide 79-06-1 2010/03/30 Carcinogenicandmutagenic(articles57aand57b)150 2,4-Dinitrotoluene 121-14-2 2010/01/13 Carcinogenic(article57a)151 Leadchromatemolybdatesulphatered(C.I.PigmentRed104) 12656-85-8 2010/01/13 Carcinogenicandtoxicforreproduction(articles57aand57c)

152 Anthraceneoil,anthracene-low 90640-82-7 2010/01/13Carcinogenic2,mutagenic3,PBTandvPvB(articles57a,57b,57dand57e)

153 Pitch,coaltar,hightemp. 65996-93-2 2010/01/13 Carcinogenic,PBTandvPvB(articles57a,57dand57e)


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154 Anthraceneoil,anthracenepaste 90640-81-6 2010/01/13Carcinogenic2,mutagenic3,PBTandvPvB(articles57a,57b,57dand57e)

155 Leadsulfochromateyellow(C.I.PigmentYellow34) 1344-37-2 2010/01/13 Carcinogenicandtoxicforreproduction(articles57aand57c))156 Leadchromate 7758-97-6 2010/01/13 Carcinogenicandtoxicforreproduction(articles57aand57c)157 Anthraceneoil 90640-80-5 2010/01/13 Carcinogenic1,PBTandvPvB(articles57a,57dand57e)158 Diisobutylphthalate 84-69-5 2010/01/13 Toxicforreproduction(article57c)159 Tris(2-chloroethyl)phosphate 115-96-8 2010/01/13 Toxicforreproduction(article57c)

160 Anthraceneoil,anthracenepaste,anthracenefraction 91995-15-2 2010/01/13Carcinogenic2,mutagenic3,PBTandvPvB(articles57a,57b,57dand57e)

161 Anthraceneoil,anthracenepaste,distn.lights 91995-17-4 2010/01/13Carcinogenic2,mutagenic3,PBTandvPvB(articles57a,57b,57dand57e)

162 4,4'-Diaminodiphenylmethane(MDA) 101-77-9 2008/10/28 Carcinogenic(article57a)163 Triethylarsenate 15606-95-8 2008/10/28 Carcinogenic(article57a)164 5-tert-butyl-2,4,6-trinitro-m-xylene(muskxylene) 81-15-2 2008/10/28 vPvB(article57e)165 Benzylbutylphthalate(BBP) 85-68-7 2008/10/28 Toxicforreproduction(article57c)

166 Sodiumdichromate 7789-12-0,10588-01-9 2008/10/28Carcinogenic,mutagenicandtoxicforreproduction(articles57a,57band57c)

167 Alkanes,C10-13,chloro(ShortChainChlorinatedParaffins) 85535-84-8 2008/10/28 PBTandvPvB(articles57dand57e)

168Hexabromocyclododecane(HBCDD)andallmajordiastereoisomersidentified:Alpha-hexabromocyclododecaneBeta-hexabromocyclododecaneGamma-hexabromocyclododecane

25637-99-4,3194-55-6(134237-50-6)(134237-51-7)(134237-52-8)

2008/10/28 PBT(article57d)

169 Anthracene 120-12-7 2008/10/28 PBT(article57d)170 Dibutylphthalate(DBP) 84-74-2 2008/10/28 Toxicforreproduction(article57c)171 Leadhydrogenarsenate 7784-40-9 2008/10/28 Carcinogenicandtoxicforreproduction(articles57aand57c)172 Diarsenictrioxide 1327-53-3 2008/10/28 Carcinogenic(article57a)173 Diarsenicpentaoxide 1303-28-2 2008/10/28 Carcinogenic(article57a)174 Bis(tributyltin)oxide(TBTO) 56-35-9 2008/10/28 PBT(article57d)

EXPLANATIONSUBSTANCES3.0

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ALKYLPHENOLS(AP)ANDALKYLPHENOLETHOXYLATES(APEO)

NPEs/OPEsareincludedinthegroupofnon-ionicsurfactantscalledalkylphenolethoxylates(APEOs).NPEsandOPEscandegradetoNPandOPrespectively.APEOsareusedindetergents,scouringagents,wettingagents,softeners,emulsifier/dispersingagentsfordyesandprints,impregnatingagentsandasdegreasingagentsInleathertanning,APEOisusedinde-greasing,finishingetc.Insilkproductionforde-gumming.APEOcouldalsobepresentindyesandpigmentpreparations.Polyesterpaddinganddown/featherfillingsareriskyforAPEO.Thesechemicalsareliabletobetoxic,persistentandtobioaccumulate.IfNPEOsandOPEOsarereleasedtotheenvironment,theycanbedegradedbacktoNPsandOPs,whicharetoxictoaquaticlife,persistentintheenvironmentandcanbioaccumulatedinbodytissue.Theyaresimilartonaturaloestrogenhormonesandcandisruptsexualdevelopmentinsomeorganismse.g.causingfeminisationoffish.


whichbyreductivecleavagemayreleaseoneofmorearomaticarylaminesincorporateoneorseveralazogroups(N=N)boundwitharomaticcompounds.Thousandsofazodyesexist,however,onlythosewhichcandegradetoformthelistedaminesareconsideredtobecarcinogenicandarethereforerestrictedintextiles,leather,apparelandtoys.

BIOCIDESDIMETHYLFUMARATE isusedbyproducersasabiocidetokillmouldsthatmaycausefurnitureorshoeleathertodeteriorateduringstorageandtransportationinahumidclimate.Dimethylfumarate(DMF)isafungicidethatmanufacturersuseformaritimetransportandthestorageofconsumergoods.DMFcancauseacutedermatitis,eczema,andgeneralfatiguetothepersonswhohavebeenincontactwiththissubstance.

BIOCIDESGENERAL arebiologicallyactivesubstances,andtheirtoxicandbiocidalnatureenablesthemtokillorharmlivingthings.Sincebiocidesbynatureareusedtohavedetrimentaleffectsonbiologicalorganisms,theyareatthesametimeaseriousthreattolivingorganismsthatwerenotintendedtobecontrolled.Biocideshaveadverseeffectsonthenervoussystemwhenenteringintothehumanbody.Theymayirritateeyes,skin,andtherespiratorysystem.

CHLOROBENZESANDCHLOROTOLUENES areusedinbatchdyeingofsyntheticfibres,particularlypolyesterfibres,topromotetheabsorptionanddiffusionofdispersedyesintothefibreatrelativelowtemperatures.Carriersareimportantfordyeingblendsofwoolandpolyesteraswoolcannotbedyedathighertemperaturesthanboiling.Thereisariskthatthecarrierswillremainonthetextilematerialorpartiallyevaporateduringsubsequentprocesses.Mostofthesecarriersaretoxictohumansandaquaticorganisms,andsomeareevencarcinogenic.

CHLORINATEDPARAFFINS arepolychlorinatedalkanesandtheyaredividedintothreecategoriesdependingonthelengthofthecarbonchain,short(C10-C13),medium(C14-C17),andlong(C20-C30).Shortchainchlorinatedparaffinsareusedasflameretardantsforplastics.Theyarealsousedasaplasticizerinrubber,paints,andadhesives.ShortChainChlorinatedParaffinsareclassifiedasdangeroustotheenvironmentbecausetheyareverytoxictoaquaticorganisms,andmaycauselong-termadverseeffectsintheaquaticenvironment.

CHLOROPHENOLS arepolychlorinatedcompoundsusedasapreservativetowood,leather,andtextiles.PCPandTeCPhavebeenusedasanantifungalinwoodproducts,textiles,andleather.PCPandTeCPareirritatantstotheskin,eyesandmouthandcancauseharmfuleffectstotheliver,kidneys,bloodandlungsandareprobablehumancarcinogens.

DISPERSEDYESWHICHARECLASSIFIEDTOBEALLERGENIC aregenerallywater-insolublecolourantsthataremainlyusedfordyingpolyester,nylonandcelluloseacetate.Somedispersedyeshaveanallergenous(sensitizing)potentialtothehumanskinandcanbeconsideredasapossiblethreattohealth,especiallyifthedyesexhibitpoorcolourfastnesstoperspirationfastness.

DYESWHICHARECLASSIFIEDTOBECARCINOGENIC Fromthelisteddyestuffsitisproventhattheyarecarcinogenic.DYESWITHENVIRONMENTALPROBLEMS Ithasbeenassessedthatthisbluecolourantharmstheenvironmentasithasahighaquatictoxicity,isnoteasilydegradableandreachestheenvironmentviawaste

water.FLAMERETARDENTS arechemicalcompoundsthatcanbeincorporatedintotextilesorappliedbyspraystopreventburning.Brominatedflameretardantsareusedinawiderangeof

productslikeautomobiles,electronicsandtextilesbecauseoftheirstabilityandheatresistance.SomeflameretardentsareastoxicasPCB’sandDDTandaresuspectedtobecarcinogenic.Theypersistoncetheyentertheenvironmentandfoodchain,andarelikelytopassupthefoodchain.

FORMALDEHYDE isavolatileorganiccompoundwhosechemicalpropertiesmakeitsuitabletobeusedforcross-linkingamongstothersinanti-creasing,anti-shrinking,andwaterrepellencefinishing,etc.tofabrics.Itcanbemixedwithphenolandureatoformpolymericresins.Intextilesandapparel,formaldehydemaybefoundinstiffenedandpermanentpressedfabric.Formaldehydeisatoxicchemicalwhichcaninduceirritationtomucousmembraneandissuspectedtocausecancer.

EXPLANATIONONTHEACTIONOFSUBSTANCES

EXPLANATIONSUBSTANCES3.0

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EXPLANATIONONTHEACTIONOFSUBSTANCES

HEAVYMETALS(GENERAL) arefoundindyestuffsandusedasdye-fixingagents.Theyalsooccurinnaturalfibreslikecotton.Manyheavymetalsarebioaccumulativewhenabsorbedbythehumanbodythroughperspirationandgivecauseforconcerninhealthtermssuchaschronictoxicity,allergenicreactionsandcancers.

HEAVYMETALSCHROMIUMVI Intextilesandapparels,ChromiumVIisusuallyassociatedwithchrometannedleather.ChromiumVIcancauseskinirritationandisconsideredtobecarcinogenic.HEAVYMETALSANTIMONY isusedinflame-proofing,paints,ceramics,enamels,awidevarietyofalloys,electronics,andrubber.Theflame-retardantapplicationscanincludechildren'sclothing,

toys,aircraftandautomobileseatcovers.HEAVYMETALSARSENIC isanotoriouslypoisonousmetalloid.Thetoxicityofarsenictoinsects,bacteriaandfungimakesitanidealcomponentforthepreservationofwood.HEAVYMETALSCADMIUM isanaturallyoccurringmetal.Intextilesandapparels,cadmiumisusuallyusedaspigments,coatings,stabilizersinplastics,dyes,paints,inksandmetalaccessories.

CadmiumisalsoawellknownstabilizerforthemanufacturingofpolymerslikePVC.Cadmiumanditsderivativesaresuspectedtobecarcinogenic.HEAVYMETALSCOBALT isahard,lustrous,greymetal.Cobaltcompoundshavebeenusedforcenturiestoimpartarichbluecolortoglass,glazes,andceramics.Afternickelandchromium,

cobaltisamajorcauseofcontactdermatitis.AthigherlevelsofexposurecobaltshowsmutagenicandcarcinogeniceffectsHEAVYMETALSCOPPER isametalwithveryhighthermalandelectricalconductivity.Copperisanessentialtracenutrienttoallhighplantandanimallife.Inanimals,includinghumansitisfound

primarilyinthebloodstream,asaco-factorinvariousenzymesandincopper-basedpigments.However,insufficientamounts,coppercanbepoisonousandevenfataltoorganisms.

HEAVYMETALSLEAD isasoft,metal,alsoconsideredtobeoneoftheheavymetals.Leadisapoisonousmetalthatcandamagenervousconnections(especiallyinyoungchildren)andcausebloodandbraindisorders.Intextilesandapparel,leadcanbefoundinplastics,paints,inks,pigments,andmetalcomponents.

HEAVYMETALSMERCURY alsocalledquicksilverisaheavymetal.Mercuryisliquidatornearroomtemperatureandpressure.Mercuryexposureathighlevelscanharmthebrain,heart,kidneys,lungsandimmunesystem.

HEAVYMETALSNICKEL Nickelismetaloftencombinedwithothermetalstocreatealloyswithincreasedhardnessandresistancetocorrosion.Intextilesandapparel,nickelismainlyfoundinaccessoriesfortextilesandclothing,paints,inks,trims,plastics,andmetalcomponents.Nickelcancauseextremeallergies.

ORGANOTINCOMPOUNDS areaclassofchemicalscombiningtinandorganicssuchasbutylandphenylgroups.Organotinarepredominantlyfoundintheenvironmentasantifoulantsinmarinepaints,buttheycanalsobeusedasbiocides(antibacterials),and/orheatstabilizersinplastics.Intextilesandapparel,organotinsmaybeusedinplastics,inks,paints,andheattransfermaterial.Itisalsousedtopreventunpleasantodours.

PERFLUORINATEDCHEMICALS areorganofluorinecompoundsandareoftenusedassurfactants.Likeotherfluorocarbonsitrepelswater.PFOSisthemainingredientinmanystainrepellentfinishes.Alsousedas:binderinnon-wovenfabricstoenhancedyeing;wettingagentstoimprovecoverageandpenetrationofsubstances;achievefinish-on-yarnuniformity;waterresistance;oilresistantcoatingsontextiles,leather,andothermaterials.Thesechemicalsarepersistent,bioaccumulativeandpoisonoustomammals.

PESTICIDES pesticidesaresubstancesormixturesofsubstancesusedtokillapest.Apesticidemaybeachemicalsubstance,biologicalagent(suchasavirusorbacteria),antimicrobial,disinfectantordeviceusedagainstanypest.Althoughtherearebenefitstotheuseofpesticides,therearealsodrawbacks,suchaspotentialtoxicitytohumansandanimals.Intextilesandapparel,thesepesticidesmaybefoundinnaturalfibres,primarilycotton.

PHTHALATES areaclassoforganiccompoundsaddedtoplasticstoincreaseflexibility.Intextilesandapparel,phthalatescanbeassociatedwithflexibleplasticcomponents,trims,screenandplastisolprints.Phthalatesarereprotoxicandcancausebirthdefectsandchangesinhormonelevels.

POLYCYCLICAROMATICHYDROCARBONS(PAH’S) areoneofthemostwidespreadorganicpollutants.Inadditiontotheirpresenceinfossilfuelstheyarealsoformedbyincompletecombustionofcarbon-containingfuelssuchaswood,coal,diesel,fat,tobacco,orincensePAHcontaminationshavebeenfoundinrubberbutalsoinvariousplastics.

POLYVINYLCHLORIDE(PVC) isawidelyusedthermoplasticpolymer.Itcanbemadesofterandmoreflexiblebytheadditionofplasticizers,themostwidely-usedbeingphthalates.Inthisform,itisusedinclothingandupholsteryItiscommonlyusedincoats,jackets,apronsandbags.Theglobalphase-outofPVCisadvocatedbecauseitisclaimedthatdioxinisproducedasabyproductofvinylchloridemanufactureandfromincinerationofwastePVCindomesticgarbage.

SOLVENTS-VOLATILEORGANICCOMPOUNDS areorganicchemicalcompoundsthatvaporizeundernormalconditionsandentertheatmosphere.CommonartificialVOCsincludethinnersanddrycleaningsolvents.

SOLVENT-DI-METHYLFORMAMIDE Theprimaryuseofdimethylformamideisasasolventwithlowevaporationrate.Dimethylformamideisusedintheproductionofacrylicandaramidfibersandplastics.DMFhasbeenlinkedtocancerinhumans,anditisthoughttocausebirthdefects.InsomesectorsofindustrywomenarebannedfromworkingwithDMF

OTHERATTENTIONPOINTS-pHVALUE pHisameasureoftheacidityorbasicityofasolution.AsolutionwhosepHis7issaidtobeneutral,whichmeansthatitisneitheracidicnorbasic.pHvaluesthatdonotfallwithinthespecifiedlimitscancauseskinirritation.

EXPLANATIONABBREVIATIONS3.0

29

ASE AcceleratedSolventExtraction

CAS ChemicalAbstractServiceNumber

DIN StandardeditedbytheDeutschesInstitutfürNormung(GermanInstituteforStandardization)

EC EuropeanCommission

ECHA EuropeanChemicalAgency

EN EuropeanStandardeditedbytheEuropeanCommitteeforStandardization

EU EuropeanUnion

GCGaschromatography:atechniqueforthequalitativeorquantitativeseparationofthecomponentsofmixturesofcompounds;characterisedbytheuseofthemobilephasegasmovingrelativetoastationaryphase(liquidorsolid)

GC-ECD Gaschromatography,ElectronCaptureDetector

HPLC HighPerformanceLiquidChromatography

IR InfraredSpectrometry

ISO InternationalStandardeditedbytheInternationalOrganizationforStandardization

ISO/TS TechnicalSpecification:anormativedocumentrepresentingthetechnicalconsensuswithinanISOcommittee

KOH Potassiumhydroxide

LC-MSLiquidchromatography-massspectrometry(LC-MS)isananalyticalchemistrytechniquethatcombinesthephysicalseparationcapabilitiesofliquidchromatographywiththemassanalysiscapabilitiesofmassspectrometry

LFGB Lebensmittel-,Bedarfsgegenstände-,undFuttermittelgesetzbuch

mg/kg milligramperkilogram,seealsoppm

mg/l milligramperlitre

MS MassSpectrometry:ananalyticaltechniquethatmeasuresthemass/chargeratiooftheionsformedwhenamoleculeoratomisionized,vaporizedandintroducedintoavacuum

n.d. notdetectable

PBT Persistent,Bioaccumulative,Toxic

ppm PartsPerMillion:Aunitdescribingconcentrationsofchemicalsubstances.1ppmcanalsobenotatedas1milligramperkilogram(mg/kg)or1μg/g(microgrampergram)

REACH Registration,Evaluation,AuthorisationandRestrictionofChemicals

RSL RestrictedSubstancesList

SVHC SubstancesofVeryHighConcern

TLC ThinLayerChromatographyisachromatographytechniqueusedtoseparatechemicalcompounds

VOC VolatileOrganicCompounds

vPvB VeryPersistent,veryBioaccumulative

µg microgram

EXPLANATIONOFABBREVIATIONS

RESTRICTED SUBSTANCES LIST IMPS & ELFS · 2017. 10. 2. · Imps & Elfs has committed itself to...

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