Resources, Energy & Future - the ultimate drivers for ... · I Al-xMxC in large scale manufacturing...
Transcript of Resources, Energy & Future - the ultimate drivers for ... · I Al-xMxC in large scale manufacturing...
D 57482 Wenden Germany
Prof. Dr. Henning Zoz
Zoz Group, D-57482 Wenden, Germany
CIITEC-IPN, Instituto Politecnico Nacional, Mexico City, C.P. 02250 México, D.F.
Ritsumeikan University, Kusatsu, Shiga 525-8577, Japan
Resources, Energy & Future
- the ultimate drivers for Nanostructure and Nanotech -
Tech Transfer Forum, Energie und Nanotechnolgie
Zoz Group
hall 2, booth A55
D 57482 Wenden Germany
Resources, Energy & Future
- the ultimate drivers for
Nanostructure and Nanotech -
Tech Transfer Forum, Energie und Nanotechnolgie
D 57482 Wenden Germany
* UBA: Deutschland 2008 (TREMOD 2010)
Bayreuth,
29. & 30. Oktober 2011
D 57482 Wenden Germany
Hannover Fair, April 04-08, 2011 last year
D 57482 Wenden Germany
Description
This is the prototype of the globally first
ECONOMICAL hydrogen driven vehicle
demonstrating super safe Zoz-Hydrogen-
Technology. Zero emission is very nice
but only cost and performance do decide.
When
on-road approval expected:
for isigo® 1.0 within 2011
for H2Tank2Go® within 2011
for isigo® H2.0 as of 2012-07
technical data, dimensions & cost
isigo® H2.0 prototype commercial product
available yes 2012-07
max. speed ca. 35 km/h1)
range max. 60 km1) max. 120 km1)
drive-power 500 W
load capacity 100 kg
brakes disc brakes
fuel-cell PEM-FC, 320 W (24 V)
converter DC-DC (24V → 48V)
buffer micro-bat Li-ion, 48 V / 2,5 Ah
tank H2Tank2Go® (1x) H2Tank2Go® (2x)
operating pressure
(tank)
< 10 bar
(Hydrolium®, solid state absorption)
refueling time click`n`go (60s) click`n`go (10s)
pressure reducer 0,5 bar
dimensions 1085 × 285 × 460 mm
net weight [kg] 35 39
on-road approval no yes
net cost € 5.000,00 € 999,00
click ‘n’ go system H2Tank2Go®
isigo®, H2Tank2Go®
and Hydrolium® are
registered trademarks
of Zoz Group
isigo®H2.0 Technical data sheet
isigo® H2.0
prototype
Technical data & dimensions are subject to alteration.
D 57482 Wenden Germany
isigo®H2.0, semi-serial model, 20.04.2012
the worldwide and historically first economic…
Hannover Fair 2011 Hannover Fair 2012
fuel-cell PEMFC, H2-solidstate absorber tanks H2Tank2Go®
April 2011 April 2012 2011/2012
prototype vision semi-serial vehicle
H2-driven vehicle: Isigo® H2.0
D 57482 Wenden Germany
Hannover Fair, April 23-27, 2012 this year
D 57482 Wenden Germany
the revolution in refueling infrastructure
D 57482 Wenden Germany
worldwide locations & affiliation
Zoz Group
Maltoz®-Strasse
D-57482 Wenden
Tel.: +49 (0)2762 - 9756-0
Fax: +49 (0)2762 - 9756-7
www.zoz.de
• Siegen
• Düsseldorf
• Hamburg
• Bremen
• Hannover • Berlin
• Dresden • Olpe
• Cologne
• Frankfurt
• Stuttgart
• Munich
Wenden · Siegen · Olpe · Cupertino, CA · Berkeley, CA · Montreal · Tokyo · Kyoto · Seoul · Mexico City
Tsingtao · Taichung · Mumbai · Hyderabad · Nueva Esparta · Luxemburg · Uljanovsk
D 57482 Wenden Germany
Fli
eg
en
www.zoz.de
D 57482 Wenden Germany
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coming up
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world population vs. agricultural area
wo
rld
p
op
ula
tio
n in
mio
.
ag
ricu
ltu
ral are
a p
er
cap
ita
in
hecta
re
world population
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ref. Dr. Chien-Yung Ma, OZ10, Germany, proc. V4-S02
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earlier & yesterday
Makro- & Micromaterials
D 57482 Wenden Germany
today & tomorrow
NANOSTRUCTURE
D 57482 Wenden Germany
Simoloyer®, high kinetic processing device: 1-900 liters
www.zoz.de
D 57482 Wenden Germany
5 or 100 to of
nanostructure p.a. - processing time is the key -
CM 01
CM 08
CM 20
CM 100
CM 400
CM 900
dimensions
D 57482 Wenden Germany
I Al-xMxC in large scale manufacturing
II Recycling of Air Force bombs overspray
III Recycling of Electrical Arc Furnace Dust (EAF)
IV Tribochemistry with Oxides and Organic Solid State Synthesis
V High Performance Cements by refinement and activation
VI wood-plastic composites, CarboWood®
VII High Performance Lithium-Ion Battery ZoLiBat®
VIII H2-storage materials Hydrolium®
IX H2-Vehicle, H2Tank2Go®, ZE-power plant, future project
X Zentallium®, CNT`s in Aluminium at super high mechanical properties
D 57482 Wenden Germany
15.07.2010 at Prayon
D 57482 Wenden Germany
Al2O3-SiC nano-composite powder
data particle size analysis tap density Fe content
sizes D10 D50 D90 [kg/dm3] [wt. %]
(W20-20lm)
[µm] 0,48 0,76 11,20 1,18 < 0,02
200k x ZOOM200kV 13390
017 50 nm
SiC
applications: • plasma spraying
• HVOF spraying
• sputtering
• sintering
advantages: • superlative wear resistance
• superlative corrosion resistance
• nano-structured (grain size)
• cost competitive
typical PSD of Al2O3-SiC nano-composite Al2O3-SiC (10%) powder after 30 min. HKP
typical Al2O3-SiC nano-
composite powder, TEM
typical Al2O3-SiC nano-structured
plasma spray coating
SiC: • 5/10/15 wt. %
D 57482 Wenden Germany
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complete mineralization of
polychloro-dibenzo-p-dioxin
by tribochemical HKP
O
O Cl
Cl
Cl
Cl
TCDD , Seveso-Dioxin
similarly all other dioxins with one to eight chlorin atoms per molecule
+ tribomaterial (e.g. glass)
milling
graphite, H2O, and NaCl
mineralization
(NaCl from neutralization with glass constituents)
Mechanism: The tribomaterial forms extremely reactive fresh surfaces upon breakage that immediately react with the organic material (cf. 3000 year old ignition of fire by hitting flint)
Complete mineralization of polychloro-dibenzo-p-dioxins by tribochemical milling
the minerals formed are
HKP
forms
graphite, H2O & NaCl TCDD (Seveso-Dioxin)
similarly all other dioxins with one to
eight chlorine atoms per molecule (NaCl from neutralization with glass constituents)
mechanism: the tribomaterial forms extremely reactive “fresh” surfaces when collapse that
immediately react with the organic material no matter if solid, liquid or gas
complete decontamination of Dioxin
D 57482 Wenden Germany
„Futur Zement“ BMBF – project no. 03X0068A # 01.05.2009
Nanoskalige Aktivierung von Hüttensand und Portlandzement mittels eines innovativen Mahlverfahrens
zur Erzeugung von Hochleistungs- und Ultrahochleistungsbeton mit verbesserten Eigenschaften
(nanoscale activation of steel-mill sand and portland cement with an innovative grinding process for the
manufacturing of high performance and super high performance concrete with advanced properties)
Zoz Group
University of Siegen
Dyckerhoff, cement
Fuchs Lubritech, chemicals
Runkel, concrete prefabrication
High Performance Portland Cement by HEM
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High Performance Portland Cement by HEM
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„HEM-WPC“ co-operative project
ZIM KF2435402Kl9 # 01.05.2010
Innovative and Efficient Compound of wood and
plastics by High Energy Milling (HEM) for the
production of wood-polymer-composite
Zoz Group
University of Goettingen
University of Siegen
Wood Biology & Wood Products
University of Goettingen
Surface & Materials Technology
University of Siegen
D 57482 Wenden Germany
technical products, wire link chain storage & logistics, here: beverage crate
80 wt-% + 20 wt-% = 100 % WPC wood-powder waste plastic plastic-substitution
Zoz goes “green”
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CarboWood®
nature combined with technology
CarboWood ® is a Zoz-trademark and represents nanostructured and reinforced wood-base material
HighTech-WPC & CarboWood®
Zoz goes green
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ductile metal flakes
[Al], [Ni], [Cu], [Pd], [Ag], [Au], [Pb]
[Ti], [Fe], [Co], [Zn], [Mo]
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grain-size controlled aluminium utilizing CNTs
lighter than aluminium and as strong as steel (700 Mpa)
at half titanium-cost
CarbonNanoTubes
Baytubes®
light weight – less material for more structural application
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Zentallium®
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600 RC-Helicopter, Zentallium® shafts vs. steel shafts, first in flight 15.12.2011
mainrotor
shaft
spindle
shaft
length 195mm 110mm
diameter 10mm 8mm
borehole 5mm 5mm
weight steel HRC52 78,93g 37,40g
weight Zentallium® 31,36g 12,36g
weight reduction - 60,27% - 66,95%
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ZoLiBat® Technical data sheet
description
High efficient cost effective lithium-ion battery-
packs for electro kickboards/scooters isigo®1.0-
ZLB and longo®1.0-ZLB and other application.
dimensions, technical data & cost
dimensions (L x W x H) 175 x 130 x 60 mm
weight 3,25 kg
ambient temp. (charge) 0 – 45°C
ambient temp. (discharge) -20 – 60°C
nominal capacity 8 Ah
nominal voltage 48 V
internal impedance <10 mOhm
max. charge voltage 58,8 V
cut off voltage 39,2 V
charge mode CC/CV
max. charge current 12 A
max. discharge current 50 A
max. discharge current 120 A @ 10s (peak)
cycle life 350 times
net cost 450,00 € (value 06-2011)
safety tests
short circuit test
no fire or explosion all tests passed
drop test
overcharge test
impact test
nail penetration test
crush test
150°C high temp. test
test certificates coming soon
isigo®1.0-ZLB
(needs 1 ZoLiBat®-battery pack)
longo®1.0-ZLB
(needs 4 ZoLiBat®-battery packs)
ZoLiBat®-battery pack
(pack contains 14 single cells)
ZoLiBat®, isigo® and longo® are registered
trademarks of Zoz Group
Technical data & dimensions are subject to alteration.
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starting material
(Simoloyer® product)
coated foil
ZoLiBat® prototype cell electrochemical properties
next generation lithium batteries
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„H2Tank2Go®“ co-operative project
ZIM EP091640 # 25.09.2009
Entwicklung eines günstigen und somit marktfähigen
H2-Feststoff-Tanksystems
Development of a competitive and insofar marketable
Hydrogen Solid State Tank System
Zoz Group
GKSS Research Centre GmbH
D 57482 Wenden Germany
®
®
operating pressure ~ 1 MPa only !!
H2Tank2Go® powered by Hydrolium®
Zoz Hydrogen Technology, solid state absorber tank systems for zero emission future mobility
D 57482 Wenden Germany
H2Tank2Go® click‘n go system for Isigo® H2.0
Zoz Hydrogen Technology, solid state absorber tank systems for zero emission future mobility
D 57482 Wenden Germany
Rusnanotech 2010, November 1-3, 2010
D 57482 Wenden Germany
conclusions
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Light weight by Zentallium®
Battery Materials (ZoLiBat®)- Equipment
H2Tank2Go® & Hydrolium®
&
Test Field
the three answers for zero-emission future transportation
D 57482 Wenden Germany
Zoz Mobility Store Siegen
D 57482 Wenden Germany
Zoz Mobility Store Olpe
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Zoz Hydrogen Technology, solid state absorber tank systems for zero emission future mobility
M-E-NES *September 14, 2010
Modellstadt Elektromobilität Bad Neustadt a. d. Saale
source:
Röhm- und Saalepost
09.07.2011 Staatsminister Zeil, MdB Spatz, Dr. Zoz, NES, 07.10.2011
D 57482 Wenden Germany
create infrastructure, turn H2-mobility available, experience sustainability
• Zoz Mobility Stores (within 2011: selling the 1.000st electric vehicle)
• H2Tank2Go®-tank simply and
conveniently interchangeable → deposit
system (for example in one of the more than 2.500 property
markets in Germany or modified bottle machines)
• H2Tank2Go®-tank with MOT approval
anywhere in Germany available via
delivery service
blue – H2-range
red – battery-range
MOT approval
isigo® 1.0 2012
H2Tank2Go® 2012
isigo® H2.0 2012/13
D 57482 Wenden Germany
Comparison with Li-ion batteries
• Values for specific energy density from literature (also confirmed by Dow Chemical)
• 75 kWh needed for small passenger car at 300 km range
Li-ion Battery: ca. 160 Wh/kg; 300 Wh/L
→ 75 kWh / 0,16 kWh/kg = 468,75 kg
→ 75 kWh / 0,3 kWh/L = 250 L
Weight-estimate of fuel cell
US Department of Energy study:
→ 80 kW PEM-FC system: 115 kg
→ 25 kW system: ca. 50 kg
H2Tank2Go for 75 kWh + Fuel Cell:
• weight: 160 kg (tank) + 50 kg (FC) = 210 kg
• volume: 50 L (tank) + 40 L (FC) = 90 L
weight factor
volume factor 3
2
1
1
D 57482 Wenden Germany
…in the future…electric cars…hydrogen or battery ?
Approximation for 1000 cars:
• Li-ion batteries: 468 t; 250 m3
alternatively for pressured gas tanks you would find:
• 20.000 mechanical components designed to withstand ~1000 bar
D 57482 Wenden Germany
e-cars on the market (in Germany)
Mitsubishi i-MiEV
range: 150km
max. speed: 130 km/h
charging: 6 h
power: 47 Kw
~ € 35.000,00
VW Golf blue e-motion (2013)
range: 150km
max. speed: 135 km/h
charging: 7 h
power: 85kW
capacity: 26,5 kWh
€ 30.000,00 - € 40.000,00
Karabag 500 E
(based on Fiat 500 E)
range: 140km
max. speed: 110 km/h
charging: 2-6 h
capacity: 22 kWh
~ € 50.000,00
Porsche Boxster
188 kW
range 680 km
max. speed 263 km/h
~ € 45.000,00
D 57482 Wenden Germany
comparison of environmental impact – Li-ion battery vs. fuel cell + H2Tank2Go®
environmental impact Li-ion battery fuel cell + H2Tank2Go®
recyclable ? no
(but partly possible) yes
includes toxic elements ?
yes
no
guarantee 3 years 3 years
lifetime < 1.000 h ca. 4.000 h (PEM-FC);
> 10 years (tanks)
comparison: 10 years of driving Li-ion battery fuel cell + H2Tank2Go®
range (small passenger car)
ca. 150.000 km ca.150.000 km
number of consumed parts 3-4 batteries 1 fuel cell
(tank will not be consumed)
costs (fuel cell target price: 7.000 €)
ca. 60.000 – 80.000 € ca. 15.000 €
(tank + fuel cell)
D 57482 Wenden Germany
Proposal for a Zoz – hydrogen powered car
CORDOBA Trolley
40 x 26 x 60 cm
volume: 55 l
H2Tank2Go®
• volume: < 50 L
• weight: ca. 160 kg
• price: < 10.000 €
in the scale of :
3 diving bottles
volume: 45 l
15 l
D 57482 Wenden Germany
Zoz Hydrogen Technology, solid state absorber tank systems for zero emission future mobility
H2Tank2Go® powered by Hydrolium®
23 units
H2Tank2Go® could
give us as much as
2.3 kg Hydrogen
(~75 kWh)
D 57482 Wenden Germany
H2Tank2Go®: operating principle, multi-tank-system, cost
MOT approval
isigo® 1.0 2012
H2Tank2Go® 2012
isigo® H2.0 2012/13
patent situation
2- tank system
3- and more- tank system
nanostructured H2-storage-material Hydrolium® for fast sorption
kinetics and reversible storage
H2 H2
loading
unloading
a multi-tank-setup allows a precise and cost-
effective H2-level-indicator
quick change cartridges → easy to operate
operating pressure: < 10 bar → very safe
H2 capacity: 50 - 100 g → high performance storage
unlimited lifetime → no material consumption
price: € 175,00 → unbeatable in cost
D 57482 Wenden Germany
Costs and taxes: gasoline vs. hydrogen
Gasoline
• consumption: ca. 5 L / 100 km (→ 10.000 L for 200.000 km)
• cost of „super“-gasoline: ca. 1,40 € / L
(47,95 ct net fuel cost + 65,45 ct mineral oil tax + 26,6 ct value added tax)
Hydrogen
• tank-load: 2,25 kg H2 (range: approx. 300 km; 2,25 kg H2 contains 75 kWh of energy)
• consumption: 0,75 kg H2 / 100 km (→ 1.500 kg H2 for 200.000 km)
fuel price for 200.000 km range
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
Gasoline Hydrogen (electrolyser -
grid)
Hydrogen (electrolyser -
wind-power)
pri
ce
[€
] 7 € / 100 km 8,34 € / 100 km
4,58 € / 100 km
Gasoline prices expected
to increase in the future
windpower
feed-in compensation
(9,02 ct / kWh)
4795 €
net fuel cost
2660 €
value added tax
6545 €
mineral oil tax
14.000 €
16.685 €
9.160 €
Δcost = 4.480 €
contributes to tank cost
D 57482 Wenden Germany
Costs of PEM-FC
• cost of stack: ca. 1000 €/kW
• cost of complete 25 kW fuel cell system: ca. 70.000 € (~ 3.000 €/kW)
• There is no mass production of this kind of PEM-FC system yet!
→ target cost: 500 USD/kW complete → 25 kW PEM-FC < 10.000 €
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• Economic FuelCells (PEM) for
tomorrow:
Target Cost: 1.000 USD / kW
electrical power (small scale, air-cooled up to 2 kW)
• Goals & Requirements
– precious metal saving
– prefabricated C-layer
– high performance CCM (1W/cm²)
– cost effective most simplified BPS
– automatic manufacturing
– strategic market impact
• …this is formed at Wenden ! ref.: SGL Group, „Gas Diffusion Layers“, SGL Shanghai, September 2011
Zoz-xxx FuelCells
D 57482 Wenden Germany
Rusnanotech 2011, Moscow – German Area, October 26th-28th 2011
Henning Zoz and Anatoli Chubais, CEO Rusnano Alfik Valeev, Sergey Potapov, Henning Zoz and Deniz Yigit
Henning Zoz and Nikolay Morozov
Dr. Zoz, Vasiliy Grudev & Dr. Jean Botti, CTO EADS 1st Zoz-presentation in Russian language
D 57482 Wenden Germany
H2-E-Mobility for Zoz-Dars Center and Environment Protected Areas
Environment Protected Areas
Sochi 2014 Olympic Games
UNIVERSIADE 2013
FIFA World Cup 2018
D 57482 Wenden Germany
operating pressure ~ 1 MPa only !!
H2Tank2Go® powered by Hydrolium®
Zoz Hydrogen Technology, solid state absorber tank systems for zero emission future mobility
latest:
PCT-patent filing: June 5, 2012
on-road approval (MOT): September 2012
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the revolution in refueling infrastructure
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looking into
power generation
Dezentrales Emissionsfreies Kraftwerk (EFK) Decentral Zero Emission Power Plant (ZEPP)
Kopplung von Wind- und Solarkraft zur direkten Stromversorgung sowie Einspeisung in einen H2-Massenspeicher via Elektrolyseur mit
Stromrückgewinnung über Dampfturbine, Raketen- oder Otto-Motore oder Brennstoffzelle (reversibel?!)
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solar- and wind-power
ready for basic supply ?
D 57482 Wenden Germany
independent CO2-free hydrogen- / electric power-supply
• H2-driven vehicles
(100 cars)
• battery-driven vehicles
(100 cars)
• all day energy supply
(200 drivers at home)
? targets
decentral zero-emission power plant (ZEPP) - project
• H2-driven vehicles
(1.250 cars)
• battery-driven vehicles
(1.250 cars)
• all day energy supply
(city of Hünsborn)
(7 days supply in storage)
ME-NES (demonstration plant for 200 persons)
city of Hünsborn (plant for 3.273 citizens)
D 57482 Wenden Germany
renewable energy
(wind, solar)
electrolyser hydrogen storage
hydrogen-station
conversion
of H2 into
electricity
(fuel cell, H2-
engine,..)
electricity
100
H2-driven
cars
base load for power supply
(200 drivers at home)
100
battery-driven
cars
H2Tank2Go®
H2-kickboard
decentral zero-emission power plant (ZEPP) - project
D 57482 Wenden Germany
ZEPP: one year values – upscaling – city of Hünsborn
2.500 cars
(~ 37.500.000 km / year)
at 5L/100km consumption
→ 1.875.000 L gasoline needed
(16.500.000 kWh)
at 1,50 €/L price for gasoline
→ 2.812.500 €
city of Hünsborn
(~ 15.070.000 kWh / year)
at 0,25 €/kWh price for
household power supply
→ 3.767.500 €
mobility + base-load for Hünsborn per year cost → total: 6.580.000 €
city of Hünsborn
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ZEPP: comparison – investment for mobility + base load (McPhy vs. VAKO)
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ZEPP: comparison – investment for mobility + base load (McPhy vs. VAKO)
calculation disregarding gasoline-consumption for mobility
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Harry K. Voigtsberger,
Economic Minister, NRW
Dr. Thomas Gräbener,
President of AiF
Johannes Remmel,
Environmental Minister,
NRW
Peter Hintze,
Parliamentary
State Secretary
Sergei Iwanow, Deputy President of the
Russian Federation
Anatoly Chubais, CEO of RUSNANO
Dr. Aloízio Mercadante Oliva, Brasilian
Minister of Research & Technology
Prof. Dr. Annette Schavan, Federal Minister
for Education & Research
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latest news
16.09.2011 09.09.2011
02.10.2011
04.10.2011
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Parliamentary Evening “Hydrogen and FuelCell”, LV-BW, October 19th 2011, Berlin, Germany
discussion around hydrogen f.l.t.r.:
Prof. Dr. Henning Zoz, Zoz Group;
Franz Untersteller, Environment-Minister of Baden-Württemberg
Dr. Johannes Toepler, Chairman of the Board of the German Hydrogen Association
Dr. Christian Mohrdiek, Chief of Development Fuelcell & Battery-drive at Daimler AG
Moderator Franz Loogen, Managing Director of e-mobil BW GmbH
Prof. Dr. Wolfram Muench, Chief of Research and Innovation at EnBW Energy Baden-Württemberg AG
Dr. Klaus Bonhoff, Managing Director of the National Organization Hydrogen- and FuelCell-technology GmbH (NOW)
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Zoz-Hünsborn Energy ?
• cooperative basis ?
• all Huensborn citizen can become
shareholder ?
• or/and the municipal of Wenden ?
• ...
+
Zoz-Energie-Wende(n) ?
NPE-Schaufenster ?
ZHE 1 km²
D 57482 Wenden Germany
Projektantrag: Future Fuel System (FFS)
Kombinierte Strom- und Wasserstofftankstelle mit integrierter Energie-
Massenspeicherung zum direkten Anschluss an regenerative
Energieerzeugungsanlagen inklusive Hybrid-E-Vergleichsfahrzeugen
mit Range-Extender a) Verbrennungsmotor und b) PEM-FC & H2-
Feststoffspeicher-Schnellwechselkartuschen.
kurz:
Regenerative Energie speichern, bereitstellen und flexibel nutzen.
Future Fuel System (FFS)
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Ziele des Projekts – Teil 1
• Elektrolyseur wird mit regenerativer Energie direkt oder über Netzumleitung gespeist und
erzeugt Wasserstoff.
• H2-Massenspeicher wird durch Elektrolyseur beladen.
• Mobile H2-Kartuschen (H2Tank2Go®) werden am H2-Massenspeicher mittels Click‘n-Go-
Tauschautomat gewechselt, beladen und fakturiert.
• Schnellladestation mit Fakturierung (elektrochem. Energiespeicher) wird über regenerative
Energie direkt oder über Netzumleitung oder über H2-Rückverstromung gespeist.
H2 H2
Erneuerbare Energiequellen
(z. B. Windpark Rhön) Elektrolyseur H2-Speicher (ca. 1,2 m3)
mit 80 Kartuschenplätzen
H2Tank2Go®-Kartuschen (160 Stück im Umlauf)
Stromnetz
H2-Rückverstromung
über Brennstoffzelle(n)
H2
Schnelladestation für Batteriefahrzeuge
40 H2-Kartuschen 250 km
(40 l Tankbauvolumen)
z. B.: 20 l fossil 250 km
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Niederholzklau – Oberholzklau – Bühl - Projekt
in progress since July 2011, WEA set-up December 2013
power plant coming up !
• Grundlastfähige Stromversorgung für Niederholzklau, Oberholzklau & Bühl
• Energiespeicher für 7 Tage auf Basis von Wasserstoff
• zusätzliche Wasserstoff-Versorgung für Elektromobilität
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Niederholzklau – Oberholzklau – Bühl - Projekt
1. Aufbau einer
Windkraftanlage (kurzfristiges Ziel)
2. Installation von
Elektrolyseur & H2-
Massenspeicher (Transformation der
Überschussenergie in Wasserstoff
für späteren Gebrauch)
3. Integration einer H2-
Abfüllstation an das
Massenspeichersystem (H2 für mobile Zwecke)
4. Anschluss der
bestgeeigneten
Rückverstromungsvariante (Brennstoffzellen, BHKWs, H2-
Turbine,…)
• Aufbau einer Grundlastfähigen Energieversorgung für die Gemeinden:
Niederholzklau, Oberholzklau & Bühl
• Wasserstoff-basierter Energiespeicher ausreichend für 7 Tage andauernde
Flaute der erneuerbaren Energieversorgung
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Zoz Energy – Windkraft- Niederholzklau
E101
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Null-Emissions-Kraftwerk
erneuerbare Energien/
Stromerzeugung
Elektolyseur
(Wasserstoff-Produktion)
H2Tank2Go®-Verteilsystem
(Austausch leerer gegen voll-
beladene Kartuschen)
H2Tank2Go®-Kartuschen
H2 Elektrizität
(Rückverstromung via Brennstoffzellen,
BHKW, H2-Turbinen,..) Batterie-Ladestation
(für Elektrofahrzeuge) Stromnetz
isigo®H2.0 H2-betriebenes Auto
Elektroauto
H2-Massenspeicher &
-Abfüllstation
Stromversorgung der
Haushalte
D 57482 Wenden Germany
Niederholzklau – Oberholzklau – Bühl - Projekt
erste Berechnungen:
• Anzahl Einwohner: 1.169
• angenommener jährlicher energieverbrauch: 2.000 kWh pro Einwohner
• → 2.338.000 kWh pro Jahr→ ~ 45.000 kwh pro Woche
• Grundlast: ~ 270 kW
• Spitzenlast: ~ 3 x 270 kW = 810 kW
• falls Effizient der H2-Rückverstromung nur bei 50%: ~ 90.000 kWh in Form von Wasserstoff
werden für eine 7-Tage-Grundlastversorgung benötigt
→ das entspricht: ~ 30.000 Nm3 oder 2.697 kg Wasserstoff
• Anzahl McPhy-Tanks um diese Menge an H2 zu speichern: 45 (MCP-Serie); 5 (MGH-Serie)
• Produktionszeit des Wasserstoffs mit 60 Nm3/h Elektrolyse: ~ 21 Tage
• (Produktionszeit des Wasserstoffs mit 120 Nm3/h Elektrolyse: ~ 101/2 Tage)
• erforderliche Energie für die Elektrolyse: 150.000 kWh
• Leistung des 60 Nm3/h Elektrolyseurs: ~ 300 kW
• Leistung einer Enercon E101 bei 6 m/s Windgeschwindigkeit: 479 kW (→ Betrieb mehrerer Elektrolyseure nur bei stärkerem wind möglich)
• 21 Tage bei 6 m/s Windgeschwindigkeit : 500 h x 479 kW = 239.500 kWh
(mehr als genug Energie für die Elektrolyse)
D 57482 Wenden Germany
Niederholzklau – Oberholzklau – Bühl - Projekt
erste Investment-Kosteneinschätzung:
• Windkraftanlage: ~ 5.000.000 €
• McPhy-Tanks: ~ 4.725.000 € (alternativ: 7 VAKO-Tanks + Kompressor: 1.289.600 €)
• Elektrolyseur: ~ 1.000.000 €
• H2-Rückverstromung: ~ 4.420.000 € (hier auf Basis von13 Hydrogenics 50 kW Brennstoffzellen)
• Summe: ~ 15.145.000 € (→ ~ 13.000 € pro Einwohner)
jährliche Stromkosten der Einwohner von Niederholzklau, Oberholzklau & Bühl
(bei 25 ct/kWh): ~ 584.500 € (→ ~ 500 € pro Einwohner)
D 57482 Wenden Germany
two months later: will be nice to see you again !
OZ-workshop
D 57482 Wenden Germany
OZ-symposium
4 months later: will be nice to see you again !
D 57482 Wenden Germany
OZ-symposium
one year later: will be nice to see you again !
D 57482 Wenden Germany
Die blaue Energiewende – Westfalenpost am 24.04.2012 (Wirtschaft überregional)
D 57482 Wenden Germany
expanding horizons
high performance rudder-blade for CAT-16 made by Zoz in Wenden