Resources, Energy & Future - the ultimate drivers for ... · I Al-xMxC in large scale manufacturing...

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D 57482 Wenden Germany Prof. Dr. Henning Zoz Zoz Group, D-57482 Wenden, Germany CIITEC-IPN, Instituto Politecnico Nacional, Mexico City, C.P. 02250 México, D.F. Ritsumeikan University, Kusatsu, Shiga 525-8577, Japan Resources, Energy & Future - the ultimate drivers for Nanostructure and Nanotech - Tech Transfer Forum, Energie und Nanotechnolgie Zoz Group hall 2, booth A55

Transcript of Resources, Energy & Future - the ultimate drivers for ... · I Al-xMxC in large scale manufacturing...

Page 1: Resources, Energy & Future - the ultimate drivers for ... · I Al-xMxC in large scale manufacturing II Recycling of Air Force bombs overspray III Recycling of Electrical Arc Furnace

D 57482 Wenden Germany

Prof. Dr. Henning Zoz

Zoz Group, D-57482 Wenden, Germany

CIITEC-IPN, Instituto Politecnico Nacional, Mexico City, C.P. 02250 México, D.F.

Ritsumeikan University, Kusatsu, Shiga 525-8577, Japan

Resources, Energy & Future

- the ultimate drivers for Nanostructure and Nanotech -

Tech Transfer Forum, Energie und Nanotechnolgie

Zoz Group

hall 2, booth A55

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Resources, Energy & Future

- the ultimate drivers for

Nanostructure and Nanotech -

Tech Transfer Forum, Energie und Nanotechnolgie

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* UBA: Deutschland 2008 (TREMOD 2010)

Bayreuth,

29. & 30. Oktober 2011

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Hannover Fair, April 04-08, 2011 last year

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Description

This is the prototype of the globally first

ECONOMICAL hydrogen driven vehicle

demonstrating super safe Zoz-Hydrogen-

Technology. Zero emission is very nice

but only cost and performance do decide.

When

on-road approval expected:

for isigo® 1.0 within 2011

for H2Tank2Go® within 2011

for isigo® H2.0 as of 2012-07

technical data, dimensions & cost

isigo® H2.0 prototype commercial product

available yes 2012-07

max. speed ca. 35 km/h1)

range max. 60 km1) max. 120 km1)

drive-power 500 W

load capacity 100 kg

brakes disc brakes

fuel-cell PEM-FC, 320 W (24 V)

converter DC-DC (24V → 48V)

buffer micro-bat Li-ion, 48 V / 2,5 Ah

tank H2Tank2Go® (1x) H2Tank2Go® (2x)

operating pressure

(tank)

< 10 bar

(Hydrolium®, solid state absorption)

refueling time click`n`go (60s) click`n`go (10s)

pressure reducer 0,5 bar

dimensions 1085 × 285 × 460 mm

net weight [kg] 35 39

on-road approval no yes

net cost € 5.000,00 € 999,00

click ‘n’ go system H2Tank2Go®

isigo®, H2Tank2Go®

and Hydrolium® are

registered trademarks

of Zoz Group

isigo®H2.0 Technical data sheet

isigo® H2.0

prototype

Technical data & dimensions are subject to alteration.

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isigo®H2.0, semi-serial model, 20.04.2012

the worldwide and historically first economic…

Hannover Fair 2011 Hannover Fair 2012

fuel-cell PEMFC, H2-solidstate absorber tanks H2Tank2Go®

April 2011 April 2012 2011/2012

prototype vision semi-serial vehicle

H2-driven vehicle: Isigo® H2.0

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Hannover Fair, April 23-27, 2012 this year

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the revolution in refueling infrastructure

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worldwide locations & affiliation

Zoz Group

Maltoz®-Strasse

D-57482 Wenden

Tel.: +49 (0)2762 - 9756-0

Fax: +49 (0)2762 - 9756-7

www.zoz.de

• Siegen

• Düsseldorf

• Hamburg

• Bremen

• Hannover • Berlin

• Dresden • Olpe

• Cologne

• Frankfurt

• Stuttgart

• Munich

Wenden · Siegen · Olpe · Cupertino, CA · Berkeley, CA · Montreal · Tokyo · Kyoto · Seoul · Mexico City

Tsingtao · Taichung · Mumbai · Hyderabad · Nueva Esparta · Luxemburg · Uljanovsk

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Fli

eg

en

www.zoz.de

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coming up

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world population vs. agricultural area

wo

rld

p

op

ula

tio

n in

mio

.

ag

ricu

ltu

ral are

a p

er

cap

ita

in

hecta

re

world population

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ref. Dr. Chien-Yung Ma, OZ10, Germany, proc. V4-S02

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earlier & yesterday

Makro- & Micromaterials

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today & tomorrow

NANOSTRUCTURE

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Simoloyer®, high kinetic processing device: 1-900 liters

www.zoz.de

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5 or 100 to of

nanostructure p.a. - processing time is the key -

CM 01

CM 08

CM 20

CM 100

CM 400

CM 900

dimensions

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I Al-xMxC in large scale manufacturing

II Recycling of Air Force bombs overspray

III Recycling of Electrical Arc Furnace Dust (EAF)

IV Tribochemistry with Oxides and Organic Solid State Synthesis

V High Performance Cements by refinement and activation

VI wood-plastic composites, CarboWood®

VII High Performance Lithium-Ion Battery ZoLiBat®

VIII H2-storage materials Hydrolium®

IX H2-Vehicle, H2Tank2Go®, ZE-power plant, future project

X Zentallium®, CNT`s in Aluminium at super high mechanical properties

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15.07.2010 at Prayon

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Al2O3-SiC nano-composite powder

data particle size analysis tap density Fe content

sizes D10 D50 D90 [kg/dm3] [wt. %]

(W20-20lm)

[µm] 0,48 0,76 11,20 1,18 < 0,02

200k x ZOOM200kV 13390

017 50 nm

SiC

applications: • plasma spraying

• HVOF spraying

• sputtering

• sintering

advantages: • superlative wear resistance

• superlative corrosion resistance

• nano-structured (grain size)

• cost competitive

typical PSD of Al2O3-SiC nano-composite Al2O3-SiC (10%) powder after 30 min. HKP

typical Al2O3-SiC nano-

composite powder, TEM

typical Al2O3-SiC nano-structured

plasma spray coating

SiC: • 5/10/15 wt. %

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complete mineralization of

polychloro-dibenzo-p-dioxin

by tribochemical HKP

O

O Cl

Cl

Cl

Cl

TCDD , Seveso-Dioxin

similarly all other dioxins with one to eight chlorin atoms per molecule

+ tribomaterial (e.g. glass)

milling

graphite, H2O, and NaCl

mineralization

(NaCl from neutralization with glass constituents)

Mechanism: The tribomaterial forms extremely reactive fresh surfaces upon breakage that immediately react with the organic material (cf. 3000 year old ignition of fire by hitting flint)

Complete mineralization of polychloro-dibenzo-p-dioxins by tribochemical milling

the minerals formed are

HKP

forms

graphite, H2O & NaCl TCDD (Seveso-Dioxin)

similarly all other dioxins with one to

eight chlorine atoms per molecule (NaCl from neutralization with glass constituents)

mechanism: the tribomaterial forms extremely reactive “fresh” surfaces when collapse that

immediately react with the organic material no matter if solid, liquid or gas

complete decontamination of Dioxin

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„Futur Zement“ BMBF – project no. 03X0068A # 01.05.2009

Nanoskalige Aktivierung von Hüttensand und Portlandzement mittels eines innovativen Mahlverfahrens

zur Erzeugung von Hochleistungs- und Ultrahochleistungsbeton mit verbesserten Eigenschaften

(nanoscale activation of steel-mill sand and portland cement with an innovative grinding process for the

manufacturing of high performance and super high performance concrete with advanced properties)

Zoz Group

University of Siegen

Dyckerhoff, cement

Fuchs Lubritech, chemicals

Runkel, concrete prefabrication

High Performance Portland Cement by HEM

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High Performance Portland Cement by HEM

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„HEM-WPC“ co-operative project

ZIM KF2435402Kl9 # 01.05.2010

Innovative and Efficient Compound of wood and

plastics by High Energy Milling (HEM) for the

production of wood-polymer-composite

Zoz Group

University of Goettingen

University of Siegen

Wood Biology & Wood Products

University of Goettingen

Surface & Materials Technology

University of Siegen

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technical products, wire link chain storage & logistics, here: beverage crate

80 wt-% + 20 wt-% = 100 % WPC wood-powder waste plastic plastic-substitution

Zoz goes “green”

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CarboWood®

nature combined with technology

CarboWood ® is a Zoz-trademark and represents nanostructured and reinforced wood-base material

HighTech-WPC & CarboWood®

Zoz goes green

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ductile metal flakes

[Al], [Ni], [Cu], [Pd], [Ag], [Au], [Pb]

[Ti], [Fe], [Co], [Zn], [Mo]

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grain-size controlled aluminium utilizing CNTs

lighter than aluminium and as strong as steel (700 Mpa)

at half titanium-cost

CarbonNanoTubes

Baytubes®

light weight – less material for more structural application

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Zentallium®

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600 RC-Helicopter, Zentallium® shafts vs. steel shafts, first in flight 15.12.2011

mainrotor

shaft

spindle

shaft

length 195mm 110mm

diameter 10mm 8mm

borehole 5mm 5mm

weight steel HRC52 78,93g 37,40g

weight Zentallium® 31,36g 12,36g

weight reduction - 60,27% - 66,95%

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ZoLiBat® Technical data sheet

description

High efficient cost effective lithium-ion battery-

packs for electro kickboards/scooters isigo®1.0-

ZLB and longo®1.0-ZLB and other application.

dimensions, technical data & cost

dimensions (L x W x H) 175 x 130 x 60 mm

weight 3,25 kg

ambient temp. (charge) 0 – 45°C

ambient temp. (discharge) -20 – 60°C

nominal capacity 8 Ah

nominal voltage 48 V

internal impedance <10 mOhm

max. charge voltage 58,8 V

cut off voltage 39,2 V

charge mode CC/CV

max. charge current 12 A

max. discharge current 50 A

max. discharge current 120 A @ 10s (peak)

cycle life 350 times

net cost 450,00 € (value 06-2011)

safety tests

short circuit test

no fire or explosion all tests passed

drop test

overcharge test

impact test

nail penetration test

crush test

150°C high temp. test

test certificates coming soon

isigo®1.0-ZLB

(needs 1 ZoLiBat®-battery pack)

longo®1.0-ZLB

(needs 4 ZoLiBat®-battery packs)

ZoLiBat®-battery pack

(pack contains 14 single cells)

ZoLiBat®, isigo® and longo® are registered

trademarks of Zoz Group

Technical data & dimensions are subject to alteration.

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starting material

(Simoloyer® product)

coated foil

ZoLiBat® prototype cell electrochemical properties

next generation lithium batteries

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„H2Tank2Go®“ co-operative project

ZIM EP091640 # 25.09.2009

Entwicklung eines günstigen und somit marktfähigen

H2-Feststoff-Tanksystems

Development of a competitive and insofar marketable

Hydrogen Solid State Tank System

Zoz Group

GKSS Research Centre GmbH

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®

®

operating pressure ~ 1 MPa only !!

H2Tank2Go® powered by Hydrolium®

Zoz Hydrogen Technology, solid state absorber tank systems for zero emission future mobility

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H2Tank2Go® click‘n go system for Isigo® H2.0

Zoz Hydrogen Technology, solid state absorber tank systems for zero emission future mobility

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Rusnanotech 2010, November 1-3, 2010

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conclusions

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Light weight by Zentallium®

Battery Materials (ZoLiBat®)- Equipment

H2Tank2Go® & Hydrolium®

&

Test Field

the three answers for zero-emission future transportation

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Zoz Mobility Store Siegen

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Zoz Mobility Store Olpe

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Zoz Hydrogen Technology, solid state absorber tank systems for zero emission future mobility

M-E-NES *September 14, 2010

Modellstadt Elektromobilität Bad Neustadt a. d. Saale

source:

Röhm- und Saalepost

09.07.2011 Staatsminister Zeil, MdB Spatz, Dr. Zoz, NES, 07.10.2011

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create infrastructure, turn H2-mobility available, experience sustainability

• Zoz Mobility Stores (within 2011: selling the 1.000st electric vehicle)

• H2Tank2Go®-tank simply and

conveniently interchangeable → deposit

system (for example in one of the more than 2.500 property

markets in Germany or modified bottle machines)

• H2Tank2Go®-tank with MOT approval

anywhere in Germany available via

delivery service

blue – H2-range

red – battery-range

MOT approval

isigo® 1.0 2012

H2Tank2Go® 2012

isigo® H2.0 2012/13

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Comparison with Li-ion batteries

• Values for specific energy density from literature (also confirmed by Dow Chemical)

• 75 kWh needed for small passenger car at 300 km range

Li-ion Battery: ca. 160 Wh/kg; 300 Wh/L

→ 75 kWh / 0,16 kWh/kg = 468,75 kg

→ 75 kWh / 0,3 kWh/L = 250 L

Weight-estimate of fuel cell

US Department of Energy study:

→ 80 kW PEM-FC system: 115 kg

→ 25 kW system: ca. 50 kg

H2Tank2Go for 75 kWh + Fuel Cell:

• weight: 160 kg (tank) + 50 kg (FC) = 210 kg

• volume: 50 L (tank) + 40 L (FC) = 90 L

weight factor

volume factor 3

2

1

1

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…in the future…electric cars…hydrogen or battery ?

Approximation for 1000 cars:

• Li-ion batteries: 468 t; 250 m3

alternatively for pressured gas tanks you would find:

• 20.000 mechanical components designed to withstand ~1000 bar

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e-cars on the market (in Germany)

Mitsubishi i-MiEV

range: 150km

max. speed: 130 km/h

charging: 6 h

power: 47 Kw

~ € 35.000,00

VW Golf blue e-motion (2013)

range: 150km

max. speed: 135 km/h

charging: 7 h

power: 85kW

capacity: 26,5 kWh

€ 30.000,00 - € 40.000,00

Karabag 500 E

(based on Fiat 500 E)

range: 140km

max. speed: 110 km/h

charging: 2-6 h

capacity: 22 kWh

~ € 50.000,00

Porsche Boxster

188 kW

range 680 km

max. speed 263 km/h

~ € 45.000,00

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comparison of environmental impact – Li-ion battery vs. fuel cell + H2Tank2Go®

environmental impact Li-ion battery fuel cell + H2Tank2Go®

recyclable ? no

(but partly possible) yes

includes toxic elements ?

yes

no

guarantee 3 years 3 years

lifetime < 1.000 h ca. 4.000 h (PEM-FC);

> 10 years (tanks)

comparison: 10 years of driving Li-ion battery fuel cell + H2Tank2Go®

range (small passenger car)

ca. 150.000 km ca.150.000 km

number of consumed parts 3-4 batteries 1 fuel cell

(tank will not be consumed)

costs (fuel cell target price: 7.000 €)

ca. 60.000 – 80.000 € ca. 15.000 €

(tank + fuel cell)

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Proposal for a Zoz – hydrogen powered car

CORDOBA Trolley

40 x 26 x 60 cm

volume: 55 l

H2Tank2Go®

• volume: < 50 L

• weight: ca. 160 kg

• price: < 10.000 €

in the scale of :

3 diving bottles

volume: 45 l

15 l

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Zoz Hydrogen Technology, solid state absorber tank systems for zero emission future mobility

H2Tank2Go® powered by Hydrolium®

23 units

H2Tank2Go® could

give us as much as

2.3 kg Hydrogen

(~75 kWh)

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H2Tank2Go®: operating principle, multi-tank-system, cost

MOT approval

isigo® 1.0 2012

H2Tank2Go® 2012

isigo® H2.0 2012/13

patent situation

2- tank system

3- and more- tank system

nanostructured H2-storage-material Hydrolium® for fast sorption

kinetics and reversible storage

H2 H2

loading

unloading

a multi-tank-setup allows a precise and cost-

effective H2-level-indicator

quick change cartridges → easy to operate

operating pressure: < 10 bar → very safe

H2 capacity: 50 - 100 g → high performance storage

unlimited lifetime → no material consumption

price: € 175,00 → unbeatable in cost

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Costs and taxes: gasoline vs. hydrogen

Gasoline

• consumption: ca. 5 L / 100 km (→ 10.000 L for 200.000 km)

• cost of „super“-gasoline: ca. 1,40 € / L

(47,95 ct net fuel cost + 65,45 ct mineral oil tax + 26,6 ct value added tax)

Hydrogen

• tank-load: 2,25 kg H2 (range: approx. 300 km; 2,25 kg H2 contains 75 kWh of energy)

• consumption: 0,75 kg H2 / 100 km (→ 1.500 kg H2 for 200.000 km)

fuel price for 200.000 km range

0

2000

4000

6000

8000

10000

12000

14000

16000

18000

Gasoline Hydrogen (electrolyser -

grid)

Hydrogen (electrolyser -

wind-power)

pri

ce

[€

] 7 € / 100 km 8,34 € / 100 km

4,58 € / 100 km

Gasoline prices expected

to increase in the future

windpower

feed-in compensation

(9,02 ct / kWh)

4795 €

net fuel cost

2660 €

value added tax

6545 €

mineral oil tax

14.000 €

16.685 €

9.160 €

Δcost = 4.480 €

contributes to tank cost

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Costs of PEM-FC

• cost of stack: ca. 1000 €/kW

• cost of complete 25 kW fuel cell system: ca. 70.000 € (~ 3.000 €/kW)

• There is no mass production of this kind of PEM-FC system yet!

→ target cost: 500 USD/kW complete → 25 kW PEM-FC < 10.000 €

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• Economic FuelCells (PEM) for

tomorrow:

Target Cost: 1.000 USD / kW

electrical power (small scale, air-cooled up to 2 kW)

• Goals & Requirements

– precious metal saving

– prefabricated C-layer

– high performance CCM (1W/cm²)

– cost effective most simplified BPS

– automatic manufacturing

– strategic market impact

• …this is formed at Wenden ! ref.: SGL Group, „Gas Diffusion Layers“, SGL Shanghai, September 2011

Zoz-xxx FuelCells

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Rusnanotech 2011, Moscow – German Area, October 26th-28th 2011

Henning Zoz and Anatoli Chubais, CEO Rusnano Alfik Valeev, Sergey Potapov, Henning Zoz and Deniz Yigit

Henning Zoz and Nikolay Morozov

Dr. Zoz, Vasiliy Grudev & Dr. Jean Botti, CTO EADS 1st Zoz-presentation in Russian language

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H2-E-Mobility for Zoz-Dars Center and Environment Protected Areas

Environment Protected Areas

Sochi 2014 Olympic Games

UNIVERSIADE 2013

FIFA World Cup 2018

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operating pressure ~ 1 MPa only !!

H2Tank2Go® powered by Hydrolium®

Zoz Hydrogen Technology, solid state absorber tank systems for zero emission future mobility

latest:

PCT-patent filing: June 5, 2012

on-road approval (MOT): September 2012

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the revolution in refueling infrastructure

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looking into

power generation

Dezentrales Emissionsfreies Kraftwerk (EFK) Decentral Zero Emission Power Plant (ZEPP)

Kopplung von Wind- und Solarkraft zur direkten Stromversorgung sowie Einspeisung in einen H2-Massenspeicher via Elektrolyseur mit

Stromrückgewinnung über Dampfturbine, Raketen- oder Otto-Motore oder Brennstoffzelle (reversibel?!)

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solar- and wind-power

ready for basic supply ?

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independent CO2-free hydrogen- / electric power-supply

• H2-driven vehicles

(100 cars)

• battery-driven vehicles

(100 cars)

• all day energy supply

(200 drivers at home)

? targets

decentral zero-emission power plant (ZEPP) - project

• H2-driven vehicles

(1.250 cars)

• battery-driven vehicles

(1.250 cars)

• all day energy supply

(city of Hünsborn)

(7 days supply in storage)

ME-NES (demonstration plant for 200 persons)

city of Hünsborn (plant for 3.273 citizens)

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renewable energy

(wind, solar)

electrolyser hydrogen storage

hydrogen-station

conversion

of H2 into

electricity

(fuel cell, H2-

engine,..)

electricity

100

H2-driven

cars

base load for power supply

(200 drivers at home)

100

battery-driven

cars

H2Tank2Go®

H2-kickboard

decentral zero-emission power plant (ZEPP) - project

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ZEPP: one year values – upscaling – city of Hünsborn

2.500 cars

(~ 37.500.000 km / year)

at 5L/100km consumption

→ 1.875.000 L gasoline needed

(16.500.000 kWh)

at 1,50 €/L price for gasoline

→ 2.812.500 €

city of Hünsborn

(~ 15.070.000 kWh / year)

at 0,25 €/kWh price for

household power supply

→ 3.767.500 €

mobility + base-load for Hünsborn per year cost → total: 6.580.000 €

city of Hünsborn

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ZEPP: comparison – investment for mobility + base load (McPhy vs. VAKO)

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ZEPP: comparison – investment for mobility + base load (McPhy vs. VAKO)

calculation disregarding gasoline-consumption for mobility

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Harry K. Voigtsberger,

Economic Minister, NRW

Dr. Thomas Gräbener,

President of AiF

Johannes Remmel,

Environmental Minister,

NRW

Peter Hintze,

Parliamentary

State Secretary

Sergei Iwanow, Deputy President of the

Russian Federation

Anatoly Chubais, CEO of RUSNANO

Dr. Aloízio Mercadante Oliva, Brasilian

Minister of Research & Technology

Prof. Dr. Annette Schavan, Federal Minister

for Education & Research

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latest news

16.09.2011 09.09.2011

02.10.2011

04.10.2011

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Parliamentary Evening “Hydrogen and FuelCell”, LV-BW, October 19th 2011, Berlin, Germany

discussion around hydrogen f.l.t.r.:

Prof. Dr. Henning Zoz, Zoz Group;

Franz Untersteller, Environment-Minister of Baden-Württemberg

Dr. Johannes Toepler, Chairman of the Board of the German Hydrogen Association

Dr. Christian Mohrdiek, Chief of Development Fuelcell & Battery-drive at Daimler AG

Moderator Franz Loogen, Managing Director of e-mobil BW GmbH

Prof. Dr. Wolfram Muench, Chief of Research and Innovation at EnBW Energy Baden-Württemberg AG

Dr. Klaus Bonhoff, Managing Director of the National Organization Hydrogen- and FuelCell-technology GmbH (NOW)

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Zoz-Hünsborn Energy ?

• cooperative basis ?

• all Huensborn citizen can become

shareholder ?

• or/and the municipal of Wenden ?

• ...

+

Zoz-Energie-Wende(n) ?

NPE-Schaufenster ?

ZHE 1 km²

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Projektantrag: Future Fuel System (FFS)

Kombinierte Strom- und Wasserstofftankstelle mit integrierter Energie-

Massenspeicherung zum direkten Anschluss an regenerative

Energieerzeugungsanlagen inklusive Hybrid-E-Vergleichsfahrzeugen

mit Range-Extender a) Verbrennungsmotor und b) PEM-FC & H2-

Feststoffspeicher-Schnellwechselkartuschen.

kurz:

Regenerative Energie speichern, bereitstellen und flexibel nutzen.

Future Fuel System (FFS)

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Ziele des Projekts – Teil 1

• Elektrolyseur wird mit regenerativer Energie direkt oder über Netzumleitung gespeist und

erzeugt Wasserstoff.

• H2-Massenspeicher wird durch Elektrolyseur beladen.

• Mobile H2-Kartuschen (H2Tank2Go®) werden am H2-Massenspeicher mittels Click‘n-Go-

Tauschautomat gewechselt, beladen und fakturiert.

• Schnellladestation mit Fakturierung (elektrochem. Energiespeicher) wird über regenerative

Energie direkt oder über Netzumleitung oder über H2-Rückverstromung gespeist.

H2 H2

Erneuerbare Energiequellen

(z. B. Windpark Rhön) Elektrolyseur H2-Speicher (ca. 1,2 m3)

mit 80 Kartuschenplätzen

H2Tank2Go®-Kartuschen (160 Stück im Umlauf)

Stromnetz

H2-Rückverstromung

über Brennstoffzelle(n)

H2

Schnelladestation für Batteriefahrzeuge

40 H2-Kartuschen 250 km

(40 l Tankbauvolumen)

z. B.: 20 l fossil 250 km

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Niederholzklau – Oberholzklau – Bühl - Projekt

in progress since July 2011, WEA set-up December 2013

power plant coming up !

• Grundlastfähige Stromversorgung für Niederholzklau, Oberholzklau & Bühl

• Energiespeicher für 7 Tage auf Basis von Wasserstoff

• zusätzliche Wasserstoff-Versorgung für Elektromobilität

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Niederholzklau – Oberholzklau – Bühl - Projekt

1. Aufbau einer

Windkraftanlage (kurzfristiges Ziel)

2. Installation von

Elektrolyseur & H2-

Massenspeicher (Transformation der

Überschussenergie in Wasserstoff

für späteren Gebrauch)

3. Integration einer H2-

Abfüllstation an das

Massenspeichersystem (H2 für mobile Zwecke)

4. Anschluss der

bestgeeigneten

Rückverstromungsvariante (Brennstoffzellen, BHKWs, H2-

Turbine,…)

• Aufbau einer Grundlastfähigen Energieversorgung für die Gemeinden:

Niederholzklau, Oberholzklau & Bühl

• Wasserstoff-basierter Energiespeicher ausreichend für 7 Tage andauernde

Flaute der erneuerbaren Energieversorgung

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Zoz Energy – Windkraft- Niederholzklau

E101

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Null-Emissions-Kraftwerk

erneuerbare Energien/

Stromerzeugung

Elektolyseur

(Wasserstoff-Produktion)

H2Tank2Go®-Verteilsystem

(Austausch leerer gegen voll-

beladene Kartuschen)

H2Tank2Go®-Kartuschen

H2 Elektrizität

(Rückverstromung via Brennstoffzellen,

BHKW, H2-Turbinen,..) Batterie-Ladestation

(für Elektrofahrzeuge) Stromnetz

isigo®H2.0 H2-betriebenes Auto

Elektroauto

H2-Massenspeicher &

-Abfüllstation

Stromversorgung der

Haushalte

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Niederholzklau – Oberholzklau – Bühl - Projekt

erste Berechnungen:

• Anzahl Einwohner: 1.169

• angenommener jährlicher energieverbrauch: 2.000 kWh pro Einwohner

• → 2.338.000 kWh pro Jahr→ ~ 45.000 kwh pro Woche

• Grundlast: ~ 270 kW

• Spitzenlast: ~ 3 x 270 kW = 810 kW

• falls Effizient der H2-Rückverstromung nur bei 50%: ~ 90.000 kWh in Form von Wasserstoff

werden für eine 7-Tage-Grundlastversorgung benötigt

→ das entspricht: ~ 30.000 Nm3 oder 2.697 kg Wasserstoff

• Anzahl McPhy-Tanks um diese Menge an H2 zu speichern: 45 (MCP-Serie); 5 (MGH-Serie)

• Produktionszeit des Wasserstoffs mit 60 Nm3/h Elektrolyse: ~ 21 Tage

• (Produktionszeit des Wasserstoffs mit 120 Nm3/h Elektrolyse: ~ 101/2 Tage)

• erforderliche Energie für die Elektrolyse: 150.000 kWh

• Leistung des 60 Nm3/h Elektrolyseurs: ~ 300 kW

• Leistung einer Enercon E101 bei 6 m/s Windgeschwindigkeit: 479 kW (→ Betrieb mehrerer Elektrolyseure nur bei stärkerem wind möglich)

• 21 Tage bei 6 m/s Windgeschwindigkeit : 500 h x 479 kW = 239.500 kWh

(mehr als genug Energie für die Elektrolyse)

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Niederholzklau – Oberholzklau – Bühl - Projekt

erste Investment-Kosteneinschätzung:

• Windkraftanlage: ~ 5.000.000 €

• McPhy-Tanks: ~ 4.725.000 € (alternativ: 7 VAKO-Tanks + Kompressor: 1.289.600 €)

• Elektrolyseur: ~ 1.000.000 €

• H2-Rückverstromung: ~ 4.420.000 € (hier auf Basis von13 Hydrogenics 50 kW Brennstoffzellen)

• Summe: ~ 15.145.000 € (→ ~ 13.000 € pro Einwohner)

jährliche Stromkosten der Einwohner von Niederholzklau, Oberholzklau & Bühl

(bei 25 ct/kWh): ~ 584.500 € (→ ~ 500 € pro Einwohner)

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two months later: will be nice to see you again !

OZ-workshop

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D 57482 Wenden Germany

OZ-symposium

4 months later: will be nice to see you again !

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D 57482 Wenden Germany

OZ-symposium

one year later: will be nice to see you again !

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Die blaue Energiewende – Westfalenpost am 24.04.2012 (Wirtschaft überregional)

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D 57482 Wenden Germany

expanding horizons

high performance rudder-blade for CAT-16 made by Zoz in Wenden