RECYCLING AND REUSE, Mehmet أ‡AKMAKCI Tأ¼rkiye Fehiman أ‡ؤ°NER Tأ¼rkiye Emine UBAY...

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  • RECYCLING AND REUSE, 2016

    3rd INTERNATIONAL CONFERENCE

    ON

    RECYCLING AND REUSE

    FULL TEXT PROCEEDINGS

    Editors

    Dr. Sinan GÜNEYSU

    Dr. Cemal Emre GÖKÇE

    İstanbul / TÜRKİYE

    September 28-30, 2016

  • Fulltext Book of the 3rd International Conference on Recycling and Reuse

    September 28-30, 2016 - Istanbul / TÜRKİYE

    ii

    3rd International Conference on Recycling and Reuse, R&R 2016 (İstanbul, Türkiye)

    İstanbul : İstanbul University Environmental Engineering Department

    Namik Kemal University Environmental Engineering Department

    ISBN 978-605-07-0605-5

    All rights reserved © 2016

    No subject or language corrections were done on abstracts by editors.

    Authors are individually responsible for their papers.

  • Fulltext Book of the 3rd International Conference on Recycling and Reuse

    September 28-30, 2016 - Istanbul / TÜRKİYE

    iii

    PREFACE

    International Conference on Recycling and Reuse (R&R, 2016) organized by two leading

    universities of Turkiye; Istanbul University and Namik Kemal University, was held in

    Istanbul, 28-30 September, 2016. The conference brought together engineers, scientists,

    practitioners and other environmental professionals from many countries all over the world

    to exchange emerging ideas and to investigate key issues such as: integrated waste

    management; novel applications for reuse and recycling; renewable energy sources and

    green technologies. Over 250 oral and poster presentations as well as eight plenary lectures

    and six invited talks from eminent researchers have been scheduled in an intensive three-

    day program. Most importantly, over 40 young master and doctoral students participated in

    the conference. The participation of about 20 young researchers was subsidized by R&R,

    2016 organization through fee remission.

    The organizers would like to express their thanks to the keynote speakers for their excellent

    presentations. Special thanks should also be addressed to the members of the Scientific

    Committee. Moreover, we are very grateful to the members of the Organizing Committee

    as well as to our Sponsors who made the R&R, 2016 Conference a great success. It is also

    worth to mention that presented contributions, both oral and posters, could be submitted as

    full research papers to the journals; Desalination and Water Treatment, Water Science and

    Technology, Water Science and Technology: Water Supply, Water Practice and Technology

    which provided special efforts to publish the selected conference papers. Finally, we thank

    all participants without whom the R&R, 2016 Conference would not have been possible.

    We would like to welcome you at the forthcoming 4th International Conference on

    Recycling and Reuse (R&R, 2018).

    September 2016, Istanbul

    Prof. Dr. Hüseyin Selçuk Prof. Dr. Süreyya Meriç

    http://wst.iwaponline.com/ http://wst.iwaponline.com/ http://ws.iwaponline.com/ http://wpt.iwaponline.com/

  • Fulltext Book of the 3rd International Conference on Recycling and Reuse

    September 28-30, 2016 - Istanbul / TÜRKİYE

    iv

    COMMITTEES

    Scientific Committee

    Ömer AKGİRAY Türkiye

    Levent ALTAŞ Türkiye

    İdil ARSLAN ALATON Türkiye

    Osman Atilla ARIKAN Türkiye

    Bülent ARMAĞAN Türkiye

    Önder AYYILDIZ Türkiye

    Yaşar AVŞAR Türkiye

    Miriam BALABAN USA

    Nilgün BALKAYA Türkiye

    Bilsen Beler BAYKAL Türkiye

    Vincenzo BELGIORNO Italy

    Giorgio BERTANZA Italy

    Mehmet BİLGİN Türkiye

    Nadim COPTY Türkiye

    Barış ÇALLI Türkiye

    Mehmet ÇAKMAKCI Türkiye

    Fehiman ÇİNER Türkiye

    Emine UBAY ÇOKGÖR Türkiye

    Ahmet DEMİR Türkiye

    Erhan DEMİRBAŞ Türkiye

    Ibrahim DINCER Canada

    Dionysios D. DIONYSIOU USA

    Patrick DUNLOP England

    Şükrü DURSUN Türkiye

    Ebru DÜLEKGÜRGEN Türkiye

    Güleda ENGİN Türkiye

    S. Birgül TANTEKİN ERSOLMAZ Türkiye

    Santiago ESPLUGAS Spain

  • Fulltext Book of the 3rd International Conference on Recycling and Reuse

    September 28-30, 2016 - Istanbul / TÜRKİYE

    v

    Francesco FATONE Italy

    Pilar FERNÁNDEZ-IBÁÑEZ Spain

    Emre Burcu GÜNGÖR Türkiye

    Mehmet Ali GÜRKAYNAK Türkiye

    Mustafa IŞIK Türkiye

    İsmail İNCİ Türkiye

    Güçlü İNSEL Türkiye

    Gülen İSKENDER Türkiye

    Nalan KABAY Türkiye

    Ralph KAEGI Switzerland

    Bülent KESKİNLER Türkiye

    Mehmet KİTİŞ Türkiye

    Mehmet KOBYA Türkiye

    Ali Savaş KOPARAL Türkiye

    Norbert KREUZINGER Austria

    Kerstin KUCHTA Germany

    Dimitra LAMBROPOULOU Greece

    Alette LANGENHOFF Netherlands

    Gianluca LiPUMA England

    Sixto MALATO Spain

    Elif PEHLİVANOĞLU MANTAŞ Türkiye

    Dionissious MANTZAVINOS Greece

    Giuseppe MASCOLO Italy

    Javier MARUGÁN Spain

    Sureyya MERİC Türkiye

    Bülent MERTOĞLU Türkiye

    Habip MUHAMMETOĞLU Türkiye

    Rosa M. QUINTA-FERREIRA Portugal

    Yaşar NUHOĞLU Türkiye

    Ayşegül PALA Türkiye

  • Fulltext Book of the 3rd International Conference on Recycling and Reuse

    September 28-30, 2016 - Istanbul / TÜRKİYE

    vi

    Suresh PILLAI Ireland

    Luigi RIZZO Italy

    Motasem Naief SAIDAN Jordan

    Selim SANİN Türkiye

    Meltem SARIOĞLU CEBECİ Türkiye

    Delia Teresa SPONZA Türkiye

    Sami SAYADI Tunisia

    Jens Ejbye SCHMIDT Denmark

    Huseyin SELCUK Türkiye

    Adrián M.T. SILVA Portugal

    Seval Kutlu AKAL SOLMAZ Türkiye

    Seval SÖZEN Türkiye

    Victor STAROV England

    Ayşegül TANIK Türkiye

    Yücel TAŞDEMİR Türkiye

    Lokman Hakan TECER Türkiye

    Turgut ONAY Türkiye

    Yalçın A. ÖKTEM Türkiye

    Özlem KARAHAN ÖZGÜN Türkiye

    Cengiz ÖZMETİN Türkiye

    Danae VANIERI Greece

    Vitor VILAR Portugal

    Orhan YENİGÜN Türkiye

    Ülkü YETİŞ Türkiye

    Levent YILMAZ Türkiye

  • Fulltext Book of the 3rd International Conference on Recycling and Reuse

    September 28-30, 2016 - Istanbul / TÜRKİYE

    vii

    Organization Committee

    Organizing Chairs

     Hüseyin SELÇUK

     Süreyya MERİÇ

    Editorial Chiefs

     Nilgün BALKAYA

     Luigi RIZZO

    Organizing Committee Members

     Semih NEMLİOĞLU

     H. Kurtuluş ÖZCAN

     Ülkü ALVER ŞAHİN

     Burcu ONAT

     Serdar AYDIN

     Emine ELMASLAR ÖZBAŞ

     Atakan ÖNGEN

     Deniz İZLEN ÇİFÇİ

     M. İberia AYDIN

     Burak YÜZER

     Selda YİĞİT HUNCE

     V. Zülal KİREMİTCİ

     C. Emre GÖKÇE

     Sinan GÜNEYSU

     Naim SEZGİN

     Can Burak ÖZKAL

  • 1

    Ozonation for the Removal of Bisphenol-A from Aqueous Solutions

    M. Mutseyekwaa, Ş. Doğanb*, S. Pirgalıoğluc

    aInstitute of Graduate Studies and Research, Cyprus International University, Haspolat, Lefkoşa, North Cyprus, Mersin 10

    TURKEY. b*Environmental Engineering Department, Cyprus International University, Haspolat, Lefkoşa, North Cyprus, Mersin 10

    TURKEY (sdogan@ciu.edu.tr). cChemical Engineering Program, Middle East Technical University, Northern Cyprus Campus,Kalkanlı, Güzelyurt, Mersin

    10 TURKEY.

    Keywords: Degradation kinetics, by-product formation, pH effect, ozonation, Bisphenol A.

    Abstract

    100 mg.L-1 Bisphenol A (BPA) containing synthetic water samples have been exposed to ozone

    process for 90 minutes. Three different pH conditions (pH 3, 7 and 10) were tested to achive an

    effective treatment of BPA by monitoring the concentration and mineralization simultaneously.

    5.3 mg.min-1 gaseous ozone was supplied into the aqueous solution of BPA where its removal

    was best fitted to pseudo-first order kinetics. Alkaline conditions promoted the fastest removal

    showing the highest observed reaction rate constant which was calculated as 0.15 min-1. Under

    optimum conditions (pH 10) 30 minutes satisfied the complete removal of BPA however, 40%

    mineralization was achieved after 90 minutes and remain constant. Commonly ring structured

    byproducts were observed under pH 3 and 7 conditions indicating the lower degree of

    mineralization.

    1. Introduction

    Bisphenol A (BPA) is produced over 2.7 billion kilogram worldwide every year (Vandenberg

    et al, 2007). 99.9 % of BPA that is produced is used for the production of polycarbonate plastic,

    epoxy resin and other plastic products (Staples et al, 1998). It is consumed in a wide range of

    products for different purposes that include; optical lenses, thermal paper, protective coating,

    automotive lenses, electrical parts, building materials, compact disks, and flame retard