Range of anionic and nonionic suRfactants - Clariant/media/Files/Corporate/Events/2015/ECS/... ·...

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TRADE NAME PRODUCT GROUP TYPE PURE ACRYLIC STYRENE- ACRYLIC VINYL ACETATE STYRENE- BUTADIENE E-PVC HLB VALUE APPEARANCE ACTIVE CONTENT APEO FREE LOW VOC (<1%) BIODEGRADABILITY US FDA 1 REGISTRATION, CHAPTER 21 CFR EUROPEAN REGISTRATION DIRECTIVE 10/2011 GERMAN BFR 2 AICS (AUSTRALIA) DSL (CANADA) EINECS (EUROPE) ENCS (JAPAN) IECSC (CHINA) KECI (KOREA) NECI (TAIWAN) NZIOC (NEW ZEALAND) PICCS (PHILIPPI- NES) TSCA (USA) COMPOSITION 5 LABEL SIGNAL WORD HAZARD STATEMENT 6 Dispersogen® LFA Phosphate Ester Tristyrl phenol ether phosphate n.a. Brownish, viscous liquid ca. 85% 3 3 - 3 3 3 3 3 3 3 3 Mixture - Warning H320 Emulsogen® APS 100 Sulfate ester Allyl polyalkylene glycol ether sulfate, ammonium salt n.a. Clear to cloudy yellowish liquid ca. 100% 3 - 46% (28d) OECD301B - - - 3 3 3 3 exempted 3 LVE 7 Substance label free label free label free Emulsogen® EPA 073 Sulfate ester Sodium alkyl ether sulfate n.a. Clear, colorless liquid ca. 30% 3 3 Readily biodegradable >80% (28d) OECD 301A § 175.105, 176.170, 176.180, 177.1210 3 BfR XIV, XXI, XXXIV 3 3 3 3 3 3 3 3 3 LVE 7 3 Mixture Irritant (Xi) R36 Emulsogen ® EPA 1954 Sulfate ester Sodium lauryl sulfate n.a. Clear, colorless to yellowish liquid ca. 30% 3 3 Readily biodegradable >60% OECD 301B 3 BfR XXI, XXXVI 3 3 3 3 3 3 3 3 3 3 Mixture Harmful (Xn), Irritant (Xi) R22, R38, R41 Emulsogen ® LA 083 Sulfate ester Ammonium alkyl ether sulfate n.a. Yellowish liquid ca. 30% 3 3 Readily biodegradable >93% (28d) OECD 301B 3 BfR XIV, XXI XXXIV 3 3 3 3 3 3 3 3 3 Mixture Irritant (Xi) R36/38 Emulsogen® LCA 213 Sulfate ester Allyl polyalkylene glycol ether sulfate, ammonium salt n.a. Clear yellowish liquid ca. 30% 3 - 3 3 3 3 3 3 Mixture Warning R36/41 Emulsogen® PF 20 S Sulfate ester Polyalkylene glycol ether sulfate, ammonium salt n.a. Yellowish brown liquid ca. 50% 3 3 - <10% OECD 302B 3 3 LVE 7 3 exempted Mixture label free label free label free Emulsogen® SF 8 Sulfosuccinate Dioctyl sulfosuccinate n.a. Colorless, clear to cloudy liquid ca. 50% 3 3 Readily biodegradable 78% (28d) OECD 301B § 175.105, 175.300, 175.320, 176.170, 176.180, 176.210, 177.1200, 177.2800, 178.3400 3 BfR II, XIV, XXXIV, XXXVI 3 3 3 3 3 3 3 3 3 3 Mixture Irritant (Xi) R36/38 Genapol ® LRO liquid Sulfonate Sodium lauryl ether sulfate n.a. Clear liquid ca. 27% 3 Readily biodegradable 95% (28d) OECD 301E § 176.210, 177.2800 3 BfR XIV, XXI, XXXIV 3 3 3 3 3 3 3 3 3 3 Mixture Irritant (Xi) R38, R41 Genapol® LRO paste Sulfonate Sodium lauryl ether sulfate n.a. Paste ca. 68-70% 3 Readily biodegradable 100% (28d) OECD 301B § 176.210, 177.2800 3 BfR XIV, XXI, XXXIV 3 3 3 3 3 3 3 3 3 3 Substance Danger H315, H318, H412 Hostapal® BV conc. Sulfate ester Sodium alkyl aryl ether sulfate n.a. Clear, colorless to yellowish liquid ca. 50% 3 - <10% OECD 302B BfR XIV 3 3 3 3 3 3 3 3 3 3 Mixture Irritant (Xi), Dangerous for the environment (N) R41, R52/53 Hostapal ® BVQ 9 Sulfate ester Sodium nonyl phenol polyglycol ether sulphate n.a. Yellow liquid ca. 40% - 9% (28d) OECD301D - - - 3 3 3 3 3 3 3 3 3 Mixture label free label free label free Hostapal® BVQ 25 Sulfate ester Sodium nonyl phenol polyglycol ether sulphate n.a. Clear yellowish liquid ca. 30% - 23% (21d) OECD301D 3 3 3 3 3 3 3 3 3 Mixture Warning H315, H411 Hostaphat® 1306 Phosphate ester Alkyl ether phosphate n.a. Clear, yellowih liquid ca. 100% 3 - 44% (28d) OECD 301B § 178.3400 3 3 3 3 3 3 3 3 3 Substance Danger H315, H318, H411 Hostapur® OS liquid Sulfonate Sodium olefin sulfonate n.a. Yellowish clear liquid ca. 40% 3 3 Readily biodegradable >80% (28d) OECD 301B § 175.105, 178.3400 3 3 3 3 3 3 3 3 3 3 Mixture Irritant (Xi) R38, R41 Hostapur® SAS 30 Sulfonate Sodium alkyl sulfonate n.a. Clear, slightly yellowish liquid ca. 30% 3 3 Readily biodegradable >89% (28d) OECD 301E § 176.170, 176.180, 178.3400 3 BfR XIV, XXXVI 3 3 3 3 3 3 3 3 3 3 Mixture Irritant (Xi) R38, R41 Hostapur® SAS 60 Sulfonate Sodium alkyl sulfonate n.a. Yellowish soft paste ca. 60% 3 3 Readily biodegradable >89% (28d) OECD 301E § 176.170, 176.180, 178.3130, 178.3400 3 BfR II, V, VI, XIV, XV, XXI, XXXIV, XXXVI 3 3 3 3 3 3 3 3 3 3 Mixture Irritant (Xi) R38, R41 Hostapur ® SAS 93 Sulfonate Sodium alkyl sulfonate n.a. Yellowish tablets ca. 93% 3 3 Readily biodegradable >89% (28d) OECD 301E § 176.170, 176.180, 178.3400 3 BfR XIV, XXXVI 3 3 3 3 3 3 3 3 3 3 Substance Danger H302, H315, H318, H412 Range of anionic emulsifiers 1 Product listed in chapter 21 CFR of the US Food and Drug Administration 2 The product meets the requirements of the Bundesamt für Riskikobewertung (German authority of risk assessment) 3 Hazardous labeling according to the Globally Harmonized System 4 Hazardous labeling according to the European Dangerous Substance Directive (EU Annex I Directive 67/548/EEC) 5 (GHS) is an internationally agreed upon system set to use worldwide unified standards for classification of chemicals as well as safety data sheets under the roof of the United Nations. The European Commission approved GHS in the “Regulation on classification, labeling and packaging of substances and mixtures “ on 16.12.08 (EU regulation 1272/2008). According the EU regulation, the classification and labteling has to be done until: - 01.12.2010 for substances - 01.06.2015 for mixtures (i.e. chemical preparations)“ 6 Risk phrases: R22: Harmful if swallowed R36: Irritating to eyes R38: Irritating to skin: R36/38: Irritating to eyes and skin R41: Risk of serious damage to eyes R52: Harmful to aquatic organisms R53: May cause long-term adverse effects in the aquatic environment R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment n.a. Not applicable APPLICATION PROPERTIES FOOD CONTACT REGULATION INVENTORY REGISTRATION STATUS HAZARDOUS LABELING ACCORDING TO GHS 3 OR DANGEROUS SUSBSTANCE DIRECTIVE 4 6 Hazard Statements: H302: Harmful if swallowed H315: Causes skin irritation H318: Causes serious eye damage H411: Toxic to aquatic life with long lasting effects H412: Harmful to aquatic life with long lasting effects 7 LVE = Low volume exempt RANGE OF ANIONIC AND NONIONIC SURFACTANTS Emulsion Polymerization

Transcript of Range of anionic and nonionic suRfactants - Clariant/media/Files/Corporate/Events/2015/ECS/... ·...

Page 1: Range of anionic and nonionic suRfactants - Clariant/media/Files/Corporate/Events/2015/ECS/... · >80% (28d) OECD 301B § 175.105, 178.3400 3 3 3 3 3 3 3 3 3 3 Mixture ... Genapol®

Trade name ProducT grouP

TyPe Pure acrylic

STyrene-acrylic

Vinyl aceTaTe

STyrene-buTadiene

e-PVc Hlb Value

aPPearance acTiVe conTenT

aPeo free

low Voc (<1%)

biodegradabiliTy uS fda1 regiSTraTion, cHaPTer 21 cfr

euroPean regiSTraTion direcTiVe 10/2011

german bfr2

aicS (auSTralia)

dSl (canada)

einecS (euroPe)

encS (JaPan)

iecSc (cHina)

Keci (Korea)

neci (Taiwan)

nZioc (new Zealand)

PiccS (PHiliPPi-neS)

TSca (uSa)

comPoSiTion5 label Signal word HaZard STaTemenT6

Dispersogen® LFA Phosphate Ester

Tristyrl phenol ether phosphate

● n.a. Brownish, viscous liquid

ca. 85% 3 3 - 3 3 3 3 3 3 3 3 Mixture - Warning H320

Emulsogen® APS 100 Sulfate ester Allyl polyalkylene glycol ether sulfate, ammonium salt

● ● n.a. Clear to cloudy yellowish liquid

ca. 100% 3 - 46% (28d)OECD301B

- - - 3 3 3 3 exempted 3 LVE7 Substance label free label free label free

Emulsogen® EPA 073 Sulfate ester Sodium alkyl ether sulfate ● ● ● n.a. Clear, colorless liquid ca. 30% 3 3 Readily biodegradable

>80% (28d)OECD 301A

§ 175.105, 176.170,176.180, 177.1210

3 BfR XIV,XXI, XXXIV

3 3 3 3 3 3 3 3 3 LVE7 3 Mixture ✖ Irritant (Xi) R36

Emulsogen® EPA 1954 Sulfate ester Sodium lauryl sulfate ● ● ● n.a. Clear, colorless to yellowish liquid

ca. 30% 3 3 Readily biodegradable

>60% OECD301B

3 BfR XXI,XXXVI

3 3 3 3 3 3 3 3 3 3 Mixture✖

Harmful (Xn),Irritant (Xi)

R22, R38, R41

Emulsogen® LA 083 Sulfate ester Ammonium alkyl ether sulfate

● ● n.a. Yellowish liquid ca. 30% 3 3 Readily biodegradable

>93% (28d)OECD 301B

3 BfR XIV, XXI XXXIV

3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R36/38

Emulsogen® LCA 213 Sulfate ester Allyl polyalkylene glycol ether sulfate, ammonium salt

● ● ● n.a. Clear yellowish liquid ca. 30% 3 - 3 3 3 3 3 3 Mixture Warning R36/41

Emulsogen® PF 20 S Sulfate ester Polyalkylene glycol ether sulfate, ammonium salt

● ● n.a. Yellowish brown liquid ca. 50% 3 3 - <10% OECD302B

3 3 LVE7 3 exempted Mixture label free label free label free

Emulsogen® SF 8 Sulfosuccinate Dioctyl sulfosuccinate ● n.a. Colorless, clear tocloudy liquid

ca. 50% 3 3 Readily biodegradable

78% (28d)OECD 301B

§ 175.105, 175.300,175.320, 176.170,176.180, 176.210,177.1200, 177.2800,178.3400

3 BfR II, XIV,XXXIV,XXXVI

3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R36/38

Genapol® LRO liquid Sulfonate Sodium lauryl ether sulfate ● ● ● ● n.a. Clear liquid ca. 27% 3 Readily biodegradable

95% (28d)OECD 301E

§ 176.210, 177.2800 3 BfR XIV, XXI,XXXIV

3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R38, R41

Genapol® LRO paste Sulfonate Sodium lauryl ether sulfate ● ● ● ● n.a. Paste ca. 68-70% 3 Readily biodegradable

100% (28d)OECD 301B

§ 176.210, 177.2800 3 BfR XIV, XXI,XXXIV

3 3 3 3 3 3 3 3 3 3 Substance Danger H315, H318, H412

Hostapal® BV conc. Sulfate ester Sodium alkyl aryl ether sulfate

● ● ● n.a. Clear, colorless to yellowish liquid

ca. 50% 3 - <10% OECD302B

BfR XIV 3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi),Dangerous for theenvironment (N)

R41, R52/53

Hostapal® BVQ 9 Sulfate ester Sodium nonyl phenol polyglycol ether sulphate

● ● ● n.a. Yellow liquid ca. 40% - 9% (28d)OECD301D

- - - 3 3 3 3 3 3 3 3 3 Mixture label free label free label free

Hostapal® BVQ 25 Sulfate ester Sodium nonyl phenol polyglycol ether sulphate

● ● ● n.a. Clear yellowish liquid ca. 30% - 23% (21d)OECD301D

3 3 3 3 3 3 3 3 3 Mixture Warning H315, H411

Hostaphat® 1306 Phosphate ester

Alkyl ether phosphate ● ● ● n.a. Clear, yellowih liquid ca. 100% 3 - 44% (28d)OECD 301B

§ 178.3400 3 3 3 3 3 3 3 3 3 Substance

Danger H315, H318, H411

Hostapur® OS liquid Sulfonate Sodium olefin sulfonate ● ● ● ● n.a. Yellowish clear liquid ca. 40% 3 3 Readily biodegradable

>80% (28d)OECD 301B

§ 175.105, 178.3400 3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R38, R41

Hostapur® SAS 30 Sulfonate Sodium alkyl sulfonate ● ● ● ● ● n.a. Clear, slightly yellowish liquid

ca. 30% 3 3 Readily biodegradable

>89% (28d)OECD 301E

§ 176.170, 176.180,178.3400

3 BfR XIV,XXXVI

3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R38, R41

Hostapur® SAS 60 Sulfonate Sodium alkyl sulfonate ● ● ● ● ● n.a. Yellowish soft paste ca. 60% 3 3 Readily biodegradable

>89% (28d)OECD 301E

§ 176.170, 176.180,178.3130, 178.3400

3 BfR II, V,VI, XIV, XV,XXI, XXXIV,XXXVI

3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R38, R41

Hostapur® SAS 93 Sulfonate Sodium alkyl sulfonate ● ● ● ● ● n.a. Yellowish tablets ca. 93% 3 3 Readily biodegradable

>89% (28d)OECD 301E

§ 176.170, 176.180,178.3400

3 BfR XIV,XXXVI

3 3 3 3 3 3 3 3 3 3 Substance

Danger H302, H315, H318, H412

Range of anionic emulsifiers

1 Product listed in chapter 21 CFR of the US Food and Drug Administration 2 The product meets the requirements of the Bundesamt für Riskikobewertung (German authority of risk assessment) 3 Hazardous labeling according to the Globally Harmonized System 4 Hazardous labeling according to the European Dangerous Substance Directive (EU Annex I Directive 67/548/EEC) 5 (GHS) is an internationally agreed upon system set to use worldwide unified standards for classification of chemicals as well as safety data sheets under the roof of the United Nations. The European Commission approved GHS in the “Regulation on classification, labeling and packaging of substances and mixtures “ on 16.12.08 (EU regulation 1272/2008). According the EU regulation, the classification and labteling has to be done until: - 01.12.2010 for substances - 01.06.2015 for mixtures (i.e. chemical preparations)“

6 risk phrases: R22: Harmful if swallowed R36: Irritating to eyes R38: Irritating to skin: R36/38: Irritating to eyes and skin R41: Risk of serious damage to eyes R52: Harmful to aquatic organisms R53: May cause long-term adverse effects in the aquatic environment R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment n.a. Not applicable

aPPlicaTion ProPerTieS food conTacT regulaTion inVenTory regiSTraTion STaTuS HaZardouS labeling according To gHS3 or dangerouS SuSbSTance direcTiVe4

6 Hazard Statements: H302: Harmful if swallowed H315: Causes skin irritation H318: Causes serious eye damage H411: Toxic to aquatic life with long lasting effects H412: Harmful to aquatic life with long lasting effects

7 LVE = Low volume exempt

Range of anionic and nonionic suRfactants

Emulsion Polymerization

Page 2: Range of anionic and nonionic suRfactants - Clariant/media/Files/Corporate/Events/2015/ECS/... · >80% (28d) OECD 301B § 175.105, 178.3400 3 3 3 3 3 3 3 3 3 3 Mixture ... Genapol®

Range of nonionic emulsifiers

Trade name ProducT grouP

TyPe Pure acrylic

STyrene-acrylic

Vinyl aceTaTe

STyrene-buTadiene

e-PVc Hlb Value

aPPearance acTiVe conTenT

aPeo free

low Voc (<1%)

biodegradabiliTy uS fda1

regiSTraTion, cHaPTer 21 cfr

euroPean regiSTraTion direcTiVe 10/2011

german bfr2

aicS (auSTralia)

dSl (canada)

einecS (euroPe)

encS (JaPan)

iecSc (cHina)

Keci (Korea)

neci (Taiwan)

nZioc (new Zealand)

PiccS (PHiliPPi-neS)

TSca (uSa)

comPoSiTion5 label Signal word HaZard STaTemenT6

Emulsogen® 4084 EO/PO block copolymers

60% EO, 40% PO ● ● ● 18 Pale yellow wax ca. 100% 3 3 - <10% (28d)OECD302B

§ 175.105, 176.180,176.200, 176.210,177.1200, 177.1680

3 BfR XIV, XLVIII, LIII

3 3 3 3 3 3 3 3 3 3 Substance label free label free label free

Emulsogen® EPN 118 Fatty alcohol polyglycol ether

C11 oxo alcohol, ethoxylated with 11 moles EO

● ● ● ● 15 Clear colorless liquid ca. 80% 3 3 Inherentlybiodegradable

> 80 % OECD302 B

§ 175.105, 176.170,176.180, 181.30

3 BfR XIV, XXI,XXXIV,XXXVI

3 3 3 3 3 3 3 3 3 3 Mixture ✖ Harmful (Xn),Irritant (Xi)

R22, R41

Emulsogen® EPN 217 Fatty alcohol polyglycol ether

C11 oxo alcohol, ethoxylated with 21 moles EO

● ● ● ● 17 Clear colorless liquid ca. 70% 3 3 Inherentlybiodegradable

> 80 % OECD302 B

§ 176.170, 176.180,181.30

3 BfR XIV, XXI,XXXIV

3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free

Emulsogen® EPN 287 Fatty alcohol polyglycol ether

C11 oxo alcohol, ethoxylated with 28 moles EO

● ● ● ● 17,5 Clear colorless liquid ca. 70% 3 3 Inherentlybiodegradable

> 80 % OECD302 B

§ 175.105, 176.170,176.180, 181.30

3 BfR XIV, XXI,XXXIV,XXXVI

3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free

Emulsogen® EPN 407 Fatty alcohol polyglycol ether

C11 oxo alcohol, ethoxylated with 40 moles EO

● ● ● ● 18 Clear colorless liquid ca. 70% 3 3 Inherentlybiodegradable

> 80 % OECD302 B

§ 175.105, 176.170,176.180, 181.30

3 BfR XIV, XXI,XXXIV

3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free

Emulsogen® LCN 070 Fatty alcohol ethoxylate

C11 oxo alcohol, ethoxylated with 7 moles EO

● ● ● 13 Clear to cloudy liquid ca. 100% 3 3 Readily biodegradable

>80% (28d)OECD301E

§ 175.105, 176.170,176.180, 181.30

3 BfR XIV, XXI,XXXIV,XXXVI

3 3 3 3 3 3 3 3 Substance

Danger H302, H318

Emulsogen® LCN 088 Fatty alcohol ethoxylate

C11 oxo alcohol, ethoxylated with 8 moles EO

● 13,5 Clear liquid ca. 80% 3 3 Readily biodegradable

>61% (28d)OECD301B

§ 175.105, 176.170,176.180, 181.30

3 BfR XIV, XXI,XXXIV,XXXVI

3 3 3 3 3 3 3 3 Mixture ✖ Harmful (Xn),Irritant (Xi)

R22, R41

Emulsogen® LCN 118 Fatty alcohol ethoxylate

C11 oxo alcohol, ethoxylated with 11 moles EO

● ● ● ● 14 Clear liquid ca. 80% 3 3 Readily biodegradable

>61% (28d)OECD301B

§ 175.105, 176.170,176.180, 181.30

3 BfR XIV, XXI,XXXIV,XXXVI

3 3 3 3 3 3 3 3 Mixture ✖ Harmful (Xn),Irritant (Xi)

R22, R41

Emulsogen® LCN 158 Fatty alcohol ethoxylate

C11 oxo alcohol, ethoxylated with 15 moles EO

● ● ● ● 16 Clear liquid ca. 80% 3 3 Readily biodegradable

>75% (28d) OECD301B

§ 175.105, 176.170,176.180, 181.30

3 BfR XIV, XXI,XXXIV

3 3 3 3 3 3 3 3 Mixture ✖ Harmful (Xn),Irritant (Xi)

R22, R41

Emulsogen® LCN 217 Fatty alcohol ethoxylate

C11 oxo alcohol, ethoxylated with 21 moles EO

● ● ● ● 17 Clear liquid ca. 70% 3 3 Readily biodegradable

>75% (28d)OECD301B

§ 175.105, 176.170,176.180, 181.30

3 BfR XIV, XXI,XXXIV,XXXVI

3 3 3 3 3 3 3 3 Mixture label free label free label free

Emulsogen® LCN 287 Fatty alcohol ethoxylate

C11 oxo alcohol, ethoxylated with 28 moles EO

● ● ● ● 17,5 Clear liquid ca. 70% 3 3 Readily biodegradable

>75% (28d)OECD301B

§ 175.105, 176.170,176.180, 181.30

3 BfR XIV, XXI,XXXIV

3 3 3 3 3 3 3 3 Mixture label free label free label free

Emulsogen® LCN 407 Fatty alcohol ethoxylate

C11 oxo alcohol, ethoxylated with 40 moles EO

● ● ● 18 Clear liquid ca. 70% 3 3 Inherently biodegradable

> 80 % OECD302B

§ 175.105, 176.170,176.180, 181.30

3 BfR XIV, XXI,XXXIV

3 3 3 3 3 3 3 3 Mixture label free label free label free

Emulsogen® TS 200 Tristyryl ethoxylate

Tristyryl ethoxylated with 20 moles EO

● ● ● 14 Yellowish brown liquid ca. 100% 3 3 - 10-35% OECD302B

BfR XIV, XXI,XXXIV

3 3 3 3 3 3 3 3 3 Substance label free label free label free

Genapol® PF 10 EO/PO block copolymers

10% EO, 90% PO ● ● ● 13 Clear colorless liquid ca. 100% 3 3 Readily biodegradable

100% (28d)OECD 301B

§ 175.105, 176.180,176.200, 176.210,

3 BfR V, VI,XIV, XXXVI

3 3 3 3 3 3 3 3 3 3 Substance label free label free label free

Genapol® PF 20 EO/PO block copolymers

20% EO, 80% PO ● ● ● 14 Slightly cloudy, colorless liquid

ca. 100% 3 3 Readily biodegradable

99% (28d)OECD 301F

§ 175.105, 176.180,176.200, 176.210,

3 BfR V, VI,XIV, XXXVI

3 3 3 3 3 3 3 3 3 3 Substance label free label free label free

Genapol® PF 40 EO/PO block copolymers

40% EO, 60% PO ● ● ● 16 Slightly cloudy, colorless liquid

ca. 100% 3 3 Readily biodegradable

61% (28d)OECD 301F

§ 175.105, 176.180,176.200, 176.210,

3 BfR V, VI,XIV, XXXVI

3 3 3 3 3 3 3 3 3 3 Substance label free label free label free

Genapol® PF 80 EO/PO blockcopolymers

80% EO, 20% PO ● ● ● ● 19 Wax ca. 100% 3 3 - <10% (28d)OECD302B

§ 175.105, 176.180,176.200, 176.210,

3 BfR XIV,XLVIII, LIII

3 3 3 3 3 3 3 3 3 3 Substance label free label free label free

Genapol® X 080 Fatty alcohol ethoxylate

C13 oxo alcohol, ethoxylated with 8 moles EO

● ● ● ● ● 12 Slightly cloudy, colorless liquid

ca. 100% 3 3 Readily biodegradable

60% (28d)OECD 301F

§ 175.105, 176.170,176.180, 176.200,176.210, 181.30

3 BfR V, VI,XIV, XV, XXI,XXXIV, XXXVI, LI, LII

3 3 3 3 3 3 3 3 3 3 Substance

Danger H302, H318

Genapol® X 307 Fatty alcohol ethoxylate

C13 oxo alcohol, ethoxylated with 30 moles EO

● ● ● ● 18 Clear colorless liquid ca. 70% 3 3 Readily biodegradable

100% (25d)OECD 301B

§ 176.170, 176.180,176.200, 181.30

3 BfR V, VI,XIV, XV, XXI,XXXIV

3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free

Genapol® X 407 Fatty alcohol ethoxylate

C13 oxo alcohol, ethoxylated with 40 moles EO

● ● ● 18 Clear colorless liquid ca. 70% 3 3 Readily biodegradable

100% (25d)OECD 301B

§ 176.170, 176.180,176.200, 181.30

3 BfR V, VI,XIV, XV, XXI,XXXIV

3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free

Genapol® X 1003 Fatty alcohol ethoxylate

C13 oxo alcohol, ethoxylated with 100 moles EO

● ● ● 19 Clear colorless liquid ca. 35% 3 3 - 50-60% OECD301B

§ 176.170, 176.180,176.200, 181.30

3 BfR V, VI,XIV, XV, XXI,XXXIV

3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free

Genapol® X 1005 Fatty alcohol ethoxylate

C13 oxo alcohol, ethoxylated with 100 moles EO

● ● ● 19 Clear colorless liquid ca. 50% 3 3 Readily biodegradable

>95% (25d)OECD 301B

§ 176.170, 176.180,176.200, 181.30

3 BfR V, VI,XIV, XV, XXI,XXXIV

3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free

aPPlicaTion ProPerTieS food conTacT regulaTion inVenTory regiSTraTion STaTuS HaZardouS labeling according To gHS3

or dangerouS SuSbSTance direcTiVe4

1 Product listed in chapter 21 CFR of the US Food and Drug Administration 2 The product meets the requirements of the Bundesamt für Riskikobewertung (German authority of risk assessment) 3 Hazardous labeling according to the Globally Harmonized System 4 Hazardous labeling according to the European Dangerous Substance Directive (EU Annex I Directive 67/548/EEC) 5 (GHS) is an internationally agreed upon system set to use worldwide unified standards for classification of chemicals as well as safety data sheets under the roof of the United Nations. The European Commission approved GHS in the “Regulation on classification, labeling and packaging of substances and mixtures “ on 16.12.08 (EU regulation 1272/2008). According the EU regulation, the classification and labteling has to be done until: - 01.12.2010 for substances - 01.06.2015 for mixtures (i.e. chemical preparations)“ 6 risk phrases: R22: Harmful if swallowed R36: Irritating to eyes R38: Irritating to skin: R36/38: Irritating to eyes and skin R41: Risk of serious damage to eyes R52: Harmful to aquatic organisms R53: May cause long-term adverse effects in the aquatic environment R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

6 Hazard Statements: H302: Harmful if swallowed H315: Causes skin irritation H318: Causes serious eye damage H411: Toxic to aquatic life with long lasting effects H412: Harmful to aquatic life with long lasting effects