Pxy and Txy
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raoults law
Transcript of Pxy and Txy
Component A B C(1) o-xylene 14.0415 3358.79 212.041(2) water 16.3872 3885.7 230.17
X1 X2 Temp. P1* P2* P1 P2 Ptotal1 0 50 3.3997 12.4053 3.3997 0.0000 3.3997
0.9 0.1 50 3.3997 12.4053 3.0598 1.2405 4.30030.8 0.2 50 3.3997 12.4053 2.7198 2.4811 5.20080.7 0.3 50 3.3997 12.4053 2.3798 3.7216 6.10140.6 0.4 50 3.3997 12.4053 2.0398 4.9621 7.00190.5 0.5 50 3.3997 12.4053 1.6999 6.2026 7.90250.4 0.6 50 3.3997 12.4053 1.3599 7.4432 8.80300.3 0.7 50 3.3997 12.4053 1.0199 8.6837 9.70360.2 0.8 50 3.3997 12.4053 0.6799 9.9242 10.60420.1 0.9 50 3.3997 12.4053 0.3400 11.1647 11.5047
0 1 50 3.3997 12.4053 0.0000 12.4053 12.4053
X1 X2 Temp. P1* P2* P1 P2 Ptotal1 0 145.384 780.000 3151.396 780.000 0.000 780.000
0.9 0.1 135.700 600.397 2396.430 540.357 239.643 780.0000.8 0.2 128.549 490.198 1939.208 392.158 387.842 780.0000.7 0.3 122.911 415.215 1631.164 290.651 489.349 780.0000.6 0.4 118.274 360.696 1408.956 216.418 563.582 780.0000.5 0.5 114.348 319.173 1240.827 159.586 620.414 780.0000.4 0.6 110.952 286.441 1109.039 114.576 665.424 780.0000.3 0.7 107.965 259.946 1002.880 77.984 702.016 780.0000.2 0.8 105.304 238.041 915.490 47.608 732.392 780.0000.1 0.9 102.906 219.616 842.265 21.962 758.038 780.000
0 1 100.728 203.895 780.000 0.000 780.000 780.000
0 0.2 0.4 0.6 0.8 1 1.20.0000
2.0000
4.0000
6.0000
8.0000
10.0000
12.0000
14.0000 Pxy Diagram
BP LINEDP LINE
Mole Fraction O-XyleneT=50°C
Pres
sure
(KPa
)
0 0.2 0.4 0.6 0.8 1 1.20.0000
2.0000
4.0000
6.0000
8.0000
10.0000
12.0000
14.0000 Pxy Diagram
BP LINEDP LINE
Mole Fraction O-XyleneT=50°C
Pres
sure
(KPa
)
Y1 Y21.0000 0.00000.7115 0.28850.5230 0.47700.3900 0.61000.2913 0.70870.2151 0.78490.1545 0.84550.1051 0.89490.0641 0.93590.0296 0.97040.0000 1.0000
Y1 Y21.000 0.0000.693 0.3070.503 0.4970.373 0.6270.277 0.7230.205 0.7950.147 0.8530.100 0.9000.061 0.9390.028 0.9720.000 1.000
0 0.2 0.4 0.6 0.8 1 1.20.0000
2.0000
4.0000
6.0000
8.0000
10.0000
12.0000
14.0000 Pxy Diagram
BP LINEDP LINE
Mole Fraction O-XyleneT=50°C
Pres
sure
(KPa
)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10.000
20.000
40.000
60.000
80.000
100.000
120.000
140.000
160.000Txy Diagram
BP LINEDP LINE
Mole Fraction O-XyleneP= 780mmHg
Tem
pera
ture
(°C)
0 0.2 0.4 0.6 0.8 1 1.20.0000
2.0000
4.0000
6.0000
8.0000
10.0000
12.0000
14.0000
Pxy Diagram
BP LINEDP LINE
Mole Fraction WaterT=50°C
Pres
sure
(KPa
)
0 0.2 0.4 0.6 0.8 1 1.20.0000
2.0000
4.0000
6.0000
8.0000
10.0000
12.0000
14.0000 Pxy Diagram
BP LINEDP LINE
Mole Fraction O-XyleneT=50°C
Pres
sure
(KPa
)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10.000
20.000
40.000
60.000
80.000
100.000
120.000
140.000
160.000Txy Diagram
BP LINEDP LINE
Mole Fraction WaterP= 780mmHg
Tem
pera
ture
(°C)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10.000
20.000
40.000
60.000
80.000
100.000
120.000
140.000
160.000Txy Diagram
BP LINEDP LINE
Mole Fraction O-XyleneP= 780mmHg
Tem
pera
ture
(°C)
0 0.2 0.4 0.6 0.8 1 1.20.0000
2.0000
4.0000
6.0000
8.0000
10.0000
12.0000
14.0000
Pxy Diagram
BP LINEDP LINE
Mole Fraction WaterT=50°C
Pres
sure
(KPa
)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10.000
20.000
40.000
60.000
80.000
100.000
120.000
140.000
160.000Txy Diagram
BP LINEDP LINE
Mole Fraction WaterP= 780mmHg
Tem
pera
ture
(°C)
Component A B CAcetic Acid (A) 15.0717 3580.8 224.65Iso-Butane (B) 13.8254 2181.79 248.87
Xa1
0.90.80.70.60.50.40.30.20.1
0
TXY Diagram @ P=780 mmHg Xa Xb Temp. Pa* Pb* Pa Pb Ptotal
1 0 118.7533 780.001 20040.94 780.001 0 780.0010.9 0.1 62.65804 101.8404 6883.445 91.6564 688.3445 780.00090.8 0.2 38.03166 31.65754 3773.37 25.32603 754.6741 780.00010.7 0.3 24.17772 14.82041 2565.419 10.37429 769.6257 7800.6 0.4 14.90664 8.491556 1937.263 5.094934 774.9051 7800.5 0.5 8.069357 5.473465 1554.527 2.736733 777.2633 7800.4 0.6 2.713763 3.809408 1297.461 1.523763 778.4764 780.00010.3 0.7 -1.655472 2.797964 1113.087 0.839389 779.161 7800.2 0.8 -5.325749 2.138647 974.4664 0.427729 779.5732 780.00090.1 0.9 -8.477454 1.68563 866.4794 0.168563 779.8314 780
0 1 -11.2305 1.36133 780 0 780 780
PXY Diagram @ T=50 C
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-20
0
20
40
60
80
100
120
140Txy Diagram
BP Line
DP Line
Mole Fraction Acetic Acid
Tem
pera
ture
(°C)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-20
0
20
40
60
80
100
120
140Txy Diagram
BP Line
DP Line
Mole Fraction Acetic Acid
Tem
pera
ture
(°C)
Xb Temp. Pa* Pb* Pa Pb Ptotal Ya Yb0 50 57.34014 5116.648 57.34014 0 57.34014 1 0
0.1 50 57.34014 5116.648 51.60613 511.6648 563.2709 0.091619 0.9083810.2 50 57.34014 5116.648 45.87211 1023.33 1069.202 0.042903 0.9570970.3 50 57.34014 5116.648 40.1381 1534.994 1575.132 0.025482 0.9745180.4 50 57.34014 5116.648 34.40409 2046.659 2081.063 0.016532 0.9834680.5 50 57.34014 5116.648 28.67007 2558.324 2586.994 0.011082 0.9889180.6 50 57.34014 5116.648 22.93606 3069.989 3092.925 0.007416 0.9925840.7 50 57.34014 5116.648 17.20204 3581.653 3598.855 0.00478 0.995220.8 50 57.34014 5116.648 11.46803 4093.318 4104.786 0.002794 0.9972060.9 50 57.34014 5116.648 5.734014 4604.983 4610.717 0.001244 0.998756
1 50 57.34014 5116.648 0 5116.648 5116.648 0 1
TXY Diagram @ P=780 mmHg Ya Yb
1 00.117508 0.8824920.032469 0.967531
0.0133 0.98670.006532 0.9934680.003509 0.9964910.001954 0.9980460.001076 0.9989240.000548 0.9994520.000216 0.999784
0 1
PXY Diagram @ T=50 C
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-20
0
20
40
60
80
100
120
140Txy Diagram
BP Line
DP Line
Mole Fraction Acetic Acid
Tem
pera
ture
(°C)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1
-20
0
20
40
60
80
100
120
140Txy Diagram
BP LineDP Line
Mole Fraction Iso-Butane
Tem
pera
ture
(°C)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-20
0
20
40
60
80
100
120
140Txy Diagram
BP Line
DP Line
Mole Fraction Acetic Acid
Tem
pera
ture
(°C)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1
-20
0
20
40
60
80
100
120
140Txy Diagram
BP LineDP Line
Mole Fraction Iso-Butane
Tem
pera
ture
(°C)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10
1000
2000
3000
4000
5000
6000
Pxy Diagram
BP Line
DP Line
Mole Fraction Acetic Acid
Pres
sure
(mm
Hg)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1
-20
0
20
40
60
80
100
120
140Txy Diagram
BP LineDP Line
Mole Fraction Iso-Butane
Tem
pera
ture
(°C)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1
-20
0
20
40
60
80
100
120
140Txy Diagram
BP LineDP Line
Mole Fraction Iso-Butane
Tem
pera
ture
(°C)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10
1000
2000
3000
4000
5000
6000
Pxy Diagram
BP Line
DP Line
Mole Fraction Acetic Acid
Pres
sure
(mm
Hg)
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.10
1000
2000
3000
4000
5000
6000
Pxy Diagram
BP Line
DP Line
Mole Fraction Iso-Butane
Pres
sure
(mm
Hg)
