Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... ·...

46
Progress in SECA Coal-Based Program 12 th Annual SECA Workshop Pittsburgh, PA July 26-28, 2011 Hossein Ghezel-Ayagh, FuelCell Energy, Inc.

Transcript of Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... ·...

Page 1: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Progress in SECA Coal-Based Program

12th Annual SECA Workshop

Pittsburgh, PA

July 26-28, 2011

Hossein Ghezel-Ayagh, FuelCell Energy, Inc.

Page 2: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Presentation Outline

Introduction

FCE SECA Program Team Members

SECA Coal-Based SOFC Program Overview

Progress in SOFC Technology

Cell Development and Manufacturing

Stack DevelopmentScale-up and Metric Tests

Proof-of-Concept Module (PCM) DevelopmentStack Module

Baseline System Design and Cost AnalysesIntegrated Gasification Fuel Cell (IGFC) System Configuration

Baseline Power Plant Cost Estimate

Conclusion and Future Plans

Page 3: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

FuelCell Energy (FCE)

Premier developer of stationary fuel cells with >40 years of experience

Headquarters and R&D in Danbury, CT (USA), with 65,000 ft2 manufacturing

facility in Torrington, CT (USA)

Delivering Direct FuelCell® (DFC®) power plants to commercial and industrial

customers

182 MW installed and in backlog

Over 80 plants generating power at more than 50 sites globally

Product sales and service backlog in excess of $200 million

Established commercial relationships with major distributors in the Americas,

Europe, and Asia

Developing large-scale coal-based power plants as well as natural gas

distributed generation (DG) systems utilizing planar SOFC

Multi- MW DFC-ERG in

Toronto, Canada

1.4 MW at a municipal building 2.4 MW plant owned by an IPP600 kW plant at a food processor11.2 MW plant owned by an IPP

Page 4: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Versa Power Systems (VPS)

• Privately held company

> Founded as joint venture of Solid Oxide Fuel Cell Consortium in 2001

> Headquartered in Littleton, Colorado, United States

> SOFC development facility in Calgary, Alberta, Canada

• Planar solid oxide fuel cell technology

> Achieved high electrical power densities and long life using low-cost materials

> Established manufacturing processes scalable to high volume production rates

• Current product effort focus on SECA stacks

> Developed and verified modular approach providing size flexibility

> Existing 32,000 ft2 facility has capacity for initial market production

Page 5: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

• Planar anode supported cells (up to 33 x 33 cm2)

• Capable of operating from 650 C to 800°C

• Ferritic stainless steel sheet metal interconnect

• Cross-flow gas delivery with manifolds integrated into the interconnect

but not through the cell

• Compressible ceramic gasket seals

• Standardized stack blocks configurable into stack towers for various

power applications

Anode

Cathode

Electrolyte

Anode

Cathode

Electrolyte

SOFC Cell and Stack Technology Background

Page 6: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Presentation Outline

Introduction

FCE SECA Program Team Members

SECA Coal-Based SOFC Program Overview

Progress in SOFC Technology

Cell Development and Manufacturing

Stack DevelopmentScale-up and Metric Tests

Proof-of-Concept Module (PCM) DevelopmentStack Module

Baseline System Design and Cost AnalysesIntegrated Gasification Fuel Cell (IGFC) System Configuration

Baseline Power Plant Cost Estimate

Conclusion and Future Plans

Page 7: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Program Technology Area

Program Goals

Development of large scale (>100 MWe) coal-based SOFC systems with:

At least 50% electrical efficiency from coal (higher heating value) Performance to meet DOE specified metrics for power output, degradation, availability, and reliability Fuel cell power island factory cost <$400/kW (2000 USD) More than 90% of carbon capture from coal syngas, as CO2 for sequestration Reduced water consumption as compared to the existing coal power plant technologies

FCE’s program focuses on the development of solid oxide fuel cell

(SOFC) cell and stack technology suitable for use in highly-efficient,

economically-competitive central generation power plant facilities

fueled by coal derived synthesis gas (syngas).

Page 8: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

10 kW Stack

1 kW

Stack

60 kW Stack Module

30 kW Stack Tower

Coal-Based SECA Program Status

2006

2008

2010

2012• FCE team successfully completed Phase II of the

Coal with Based SECA Program in April 2011 with

development of a new generation of low-cost high-

performance cell technology.

• SECA Phase III Project is to enhance stack

robustness and reliability for development of a

>50kW Stack Module.

Page 9: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Presentation Outline

Introduction

FCE SECA Program Team Members

SECA Coal-Based SOFC Program Overview

Progress in SOFC Technology

Cell Development and Manufacturing

Stack DevelopmentScale-up and Metric Tests

Proof-of-Concept Module (PCM) DevelopmentStack Module

Baseline System Design and Cost AnalysesIntegrated Gasification Fuel Cell (IGFC) System Configuration

Baseline Power Plant Cost Estimate

Conclusion and Future Plans

Page 10: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Anode DevelopmentReduced Cell Thickness

Enhanced Performance at Higher Fuel Utilization and at Lower Temperature

Enhanced Cell Mechanical Properties and Robustness

Phase I Phase IIIPhase II

Cathode development

Cell scale up

Anode development

Cell thickness reduction

2007 20112009

Cell robustness

TSC3 Cell-550

Cathode DevelopmentEnhanced Performance and Endurance

Reduced Operating Temperature

Increased Operating Window

Scale Up & Manufacturing Development

Scaled up from 121 cm2

550 cm21000 cm2

Established Manufacturing Processes for Baseline 550cm2 Cells

Completed Process Integration and Validation in Transitioning from TSC2 TSC3 technology

Cell Development Accomplishments

TSC2 Cell-550TSC2 Cell-121

Page 11: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

The Evolution of Cell Technology

Significant progress has been made toward enhancing cell

performance and endurance.

0.55

0.6

0.65

0.7

0.75

0.8

0.85

0.9

0 5000 10000 15000 20000 25000 30000 35000 40000

Elapsed Time (hours)

Ce

ll V

olt

ag

e (

V)

Cell active area = 81cm2

Fuel = hydrogen + 3% water

Oxidant = air

Uf = 50%

Uo = 25%

I = 0.5 to 0.55 A/cm2

2009 - present

2008 - present

2002 - 2005

Page 12: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

650 670 690 710 730 750 770 790

Temperature (°C)

AS

R (

oh

m.c

m2)

ASR (Area Specific Resistance) Reduction

and Performance Improvement

Baseline Cell

(TSC-2)

Cell Performance at 740 mA/cm2: TSC2 vs. TSC3

500

550

600

650

700

750

800

850

900

950

650°C 700°C 750°C 800°C

Temperatures

Vo

ltag

e (

mV

)

0%

2%

4%

6%

8%

10%

12%

14%

16%

18%

20%

Imp

rovem

en

t

TS

C-3

TS

C-2

Achieved significant ASR reduction below 700°C

Baseline Cell

(TSC-3)

Cathode

Design

Change

AFL (Anode

Functional Layer)

Modification

Page 13: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

0.5

0.6

0.7

0.8

0.9

1.0

1.1

1.2

0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80

Current Density (A/cm2)

Vo

lta

ge

(V

)

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

Po

we

r D

en

sit

y (

W/c

m2)

Single cell: 81 cm2 area

Fuel: H2 + 3% H2O

Oxidant: Air

Performance CurvesGlob _; (Cell Test Description) Oven #_, (Date)

0.50

0.60

0.70

0.80

0.90

1.00

1.10

1.20

0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80

Current Density (A/cm2)

Vo

ltag

e (

V)

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

Po

wer

De

ns

ity

(W

/cm

2)

800°C - V

750°C - V

700°C - V

650°C - V

800°C - P

750°C - P

700°C - P

650°C - P

Performance CurvesGlob _; (Cell Test Description) Oven #_, (Date)

0.50

0.60

0.70

0.80

0.90

1.00

1.10

1.20

0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80

Current Density (A/cm2)

Vo

lta

ge

(V

)

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

Po

wer

De

ns

ity

(W

/cm

2)

800°C - V

750°C - V

700°C - V

650°C - V

800°C - P

750°C - P

700°C - P

650°C - P

Voltage Power

Performance of Improved Cells

Cell voltage of >800 mV and power density of 400 mW/cm2 at 650 C were

achieved.

Page 14: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

0.7

0.8

0.9

1

1.1

23.50 24.50 25.50 26.50 27.50 28.50 29.50

Elapsed Time (hours)

Vo

lta

ge

(V

)

40%

50%

60%

70%

80%

90%

100%

Fu

el

Uti

liza

tio

n (

%)

Cell 01 Cell 02 Cell 03

Cell 04 Cell 05 Cell 06

Cell 07 Cell 08 Cell 09

Cell 10 Cell 11 Cell 12

Cell 13 Cell 14 Cell 15

Cell 16 uf

Cell Performance Enhancement in Stack

Uf (%) TSC 2 TSC 3 Gain

50 0.823 0.886 7.7%

60 0.817 0.879 7.6%

70 0.804 0.866 7.7%

80 0.785 0.847 7.9%

Test Stand Temperature: 700°C

Cell Active Area: 550 cm2

25% In-stack reforming

Current Density: 0.388 A/cm2

Scale-up TSC-3 cells with thin anodes have shown high performance at

high fuel utilizations in a 16-cell stack.

Page 15: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

0.000

0.200

0.400

0.600

0.800

1.000

1.200

0 2400 4800 7200 9600 12000 14400 16800 19200

Elapsed Time, hrs

Vo

ltag

e,

V

Overall:

47 mV over 16272 hrs

2.89 mV or 0.29% / 1000 hrs

Single Cell Stability Achievements (750 C)

Single Cell - 81 cm2 Active Area

Furnace Temperature: 750°C

Fuel: 55 H2:45 N2 + 3% H2O, Uf = 50%

Oxidant: Air, Ua = 25%

Current: 40.5 A (0.5 A/cm2)

Performance degradation rate of <0.3%/1000 h was achieved in 17,000 h of

operation using new generation TSC-3 cell technology and interconnect alloy.

Page 16: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Parametric Testing of Alloys

in a 32-cell Stack

Phase II research has identified a superior alloy, offering higher oxidation

resistance and a lower performance degradation rate.

GT057832-0001 TC0-TC1 - 30/Nov/09

32 cell Parametric; 61.5 Uf/13.5 Ua 213Amps 25% DIR Furn=700C

0.000

0.200

0.400

0.600

0.800

1.000

1.200

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000 11000 12000

Elapsed Time (hours)

Avera

ge C

ell V

olt

ag

e (

V)

0.0

50.0

100.0

150.0

200.0

250.0

Sta

ck C

urr

en

t (A

)

32 Cell Stack - 550 cm2 Active Area

Furnace Temperature: 700°C

Fuel: 63.2% H2, 11.7% N2, 5.2% CH4, 19.9% H2O

Uf = 61.5%

Oxidant: Air, Ua = 13.5%

Current: 213 A (0.39 A/cm2) to 9163 h

195 A (0.35 A/cm^2) since 9163 h

160 A (0.29 A/cm2) since 10160 h

Thermal Cycle Phase II Alloy Coated

1.06% / 1000 hours

Phase I Alloy

1.96% / 1000 hours

GT057832-0001 TC0-TC1 - 30/Nov/09

32 cell Parametric; 61.5 Uf/13.5 Ua 213Amps 25% DIR Furn=700C

0.000

0.200

0.400

0.600

0.800

1.000

1.200

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000 11000 12000

Elapsed Time (hours)

Av

era

ge

Ce

ll V

olt

ag

e (

V)

0.0

50.0

100.0

150.0

200.0

250.0

Sta

ck

Cu

rre

nt

(A)

32 Cell Stack - 550 cm2 Active Area

Furnace Temperature: 700°C

Fuel: 63.2% H2, 11.7% N2, 5.2% CH4, 19.9% H2O

Uf = 61.5%

Oxidant: Air, Ua = 13.5%

Current: 213 A (0.39 A/cm2) to 9163 h

195 A (0.35 A/cm^2) since 9163 h

160 A (0.29 A/cm2) since 10160 h

Thermal Cycle Phase II Alloy Coated

1.06% / 1000 hours

Phase I Alloy

1.96% / 1000 hours

GT057832-0001 TC0-TC1 - 30/Nov/09

32 cell Parametric; 61.5 Uf/13.5 Ua 213Amps 25% DIR Furn=700C

0.000

0.200

0.400

0.600

0.800

1.000

1.200

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000 11000 12000

Elapsed Time (hours)

Av

era

ge

Ce

ll V

olt

ag

e (

V)

0.0

50.0

100.0

150.0

200.0

250.0

Sta

ck

Cu

rre

nt

(A)

32 Cell Stack - 550 cm2 Active Area

Furnace Temperature: 700°C

Fuel: 63.2% H2, 11.7% N2, 5.2% CH4, 19.9% H2O

Uf = 61.5%

Oxidant: Air, Ua = 13.5%

Current: 213 A (0.39 A/cm2) to 9163 h

195 A (0.35 A/cm^2) since 9163 h

160 A (0.29 A/cm2) since 10160 h

Thermal Cycle Phase II Alloy Coated

1.06% / 1000 hours

Phase I Alloy

1.96% / 1000 hours

Page 17: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Recent Achievements in Cell Fabrication Process

Tape Casting

Screen Printing

Co-sintering

• Established fabrication process capabilities

for large area cells

> Cells up to 1000 cm2 (33 x 33 cm2) in

size were produced using TSC cell

manufacturing process

> Capital equipment for all major process

units was added in order to

accommodate increased cell size and

volume

• Developed and implemented the next

generation of cell fabrication processes

> Cell thickness was reduced by more

than 40%

• Fabricated > 5000 cells (25 x 25 cm2)

> Production volume of 500 kW (annual)

was established and yield greater than

95% was demonstrated

Page 18: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Presentation Outline

Introduction

FCE SECA Program Team Members

SECA Coal-Based SOFC Program Overview

Progress in SOFC Technology

Cell Development and Manufacturing

Stack DevelopmentScale-up and Metric Tests

Proof-of-Concept Module (PCM) DevelopmentStack Module

Baseline System Design and Cost AnalysesIntegrated Gasification Fuel Cell (IGFC) System Configuration

Baseline Power Plant Cost Estimate

Conclusion and Future Plans

Page 19: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Phase I Phase IIIPhase II

96 cells

X

550 cm2 (TSC3)

2007 20112009

S1 Stack Design

Metallic alloy and coating development

Contact and flow media development

S2 Stack Design S3 Stack Design

Improved stack performanceHigher power density

Higher fuel utilization

Higher direct internal reforming

Enhanced stack enduranceImproved stack thermal and flow management

Incorporated TSC3 cells

Incorporated advanced interconnect alloy, contact and flow media

Reduced stack cost

Stack Development Accomplishments

92 cells

X

550 cm2 (TSC3)

92 cells

X

550 cm2 (TSC2)

64 cells

X

550 cm2 (TSC2)

28 cells

X

121 cm2 (TSC2)

Cell Size 25 x 25 cm2

Active Area 550 cm2

Number of Cells 92

Page 20: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Stack Endurance Tests

Low performance degradation rate (~0.4% /1000 hr) is demonstrated in a

sub-scale stack with > 2 years of operation.

0.000

0.200

0.400

0.600

0.800

1.000

1.200

0 2000 4000 6000 8000 10000 12000 14000 16000 18000 20000

Elapsed Time (hours)

Ave

rag

e C

ell

Vo

ltag

e (

V)

Overall:

59.69 mV over 18,654 hrs

3.2 mV or 0.38% / 1000 hrs

Cell Count: 28

Cell Active Area: 121 cm2

Furnace Temperature: 670°C

Fuel: 55 H2:45 N2 + 3% H2O, Uf = 65%

Oxidant: Air, Ua = 40%

Current: 45 A (0.372 A/cm2)

Page 21: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

120-Cell Stack

24 inches

(61 cm)

Stack met Phase II metric test targets:

• Peak power rating of 25.2 kW

• >1,500 hours of operation

• Performance degradation rate < 1%/1000 h (surpassing 2%/1000 h DOE target)

120-Cell Stack Metric Test

GT058027-0001

120-Cell Stack

Cell Active Area: 550 cm2

0.0

0.2

0.4

0.6

0.8

1.0

1.2

0 250 500 750 1000 1250 1500 1750 2000

Test Duration (hours)

Av

era

ge

Ce

ll V

olt

ag

e (

V)

0

5

10

15

20

25

30

Sta

ck

Po

we

r (k

W)

Average Cell Voltage

Stack Power

Test stand repair

(full thermal cycle)

Normal Operating Conditions (NOC)

Furnace Temperature: 715°C

Fuel: 25.2% H2, 22.4% N2, 14.5% NG, 37.8% H2O

In-stack reforming = 70%, Uf = 68%

Oxidant: Air, Ua = 15%

Current: 200 A (0.364 A/cm2)

Stack conditioning

Peak power testing (24 h)

GT058027-0001

120-Cell Stack

Cell Active Area: 550 cm2

0.0

0.2

0.4

0.6

0.8

1.0

1.2

0 250 500 750 1000 1250 1500 1750 2000

Test Duration (hours)

Av

era

ge

Ce

ll V

olt

ag

e (

V)

0

5

10

15

20

25

30

Sta

ck

Po

we

r (k

W)

Average Cell Voltage

Stack Power

Test stand repair

(full thermal cycle)

Normal Operating Conditions (NOC)

Furnace Temperature: 715°C

Fuel: 25.2% H2, 22.4% N2, 14.5% NG, 37.8% H2O

In-stack reforming = 70%, Uf = 68%

Oxidant: Air, Ua = 15%

Current: 200 A (0.364 A/cm2)

Stack conditioning

Peak power testing (24 h)

Time Weighted Average Performance Degradation:

8.1 mV (0.98%)/khr over 1641 hours

Page 22: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

16 kW

96-Cell

(2011)

10 kW

64-Cell

(2008)

16 inches

(41 cm)

19 inches

(48 cm)

Next Generation 96-Cell Stack Block

Eliminated

instrumentation

plate

• Stack Instrumentation

> Eliminate instrumentation plates

> Reduce on-cell thermocouples

• Improve stack block flow management with enhanced manifold and flow medium designs

• Stack Manufacturing

> Develop production tooling

> Refine stack acceptance criteria

Page 23: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

• Thermally self-sustaining test environment (gas preheated only)

• Provisions for simulated anode gas representative of both syngas and

natural gas fueled systems

• Providing valuable lessons for future larger stack module designs

2009Q4 2010Q2

Stack Tower Testing

SO-30-1 Tower Assembly SO-30-3 Tower Assembly

3 x 64-cell stack tower 2 x 92-cell stack tower

20 inches

(51 cm)

2010Q3

SO-30-4 Tower Assembly

2 x 92-cell stack tower

Page 24: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Stack Tower (SO-30-4) Test

0

50

100

150

200

250

0 200 400 600 800 1000 1200 1400 1600 1800 2000

Runtime/ Hr

Sta

ck

Vo

lta

ge

/ V

0

5

10

15

20

25

30

35

40

45

50

Sta

ck

Po

we

r/ k

W

Voltage

Power

Confirmed Operation on Simulated Coal Syngas with High Methane Gas Composition from an

Advanced Catalytic Gasifier.

Peak Power Test

Brown-out

Trip

Diagnostic

Unload

Load bank

Trip

Failed

Thermocouple

Trip

Tower Operation: >1900 hours hot, >1400 hrs on load

Peak Power: 30.2 kWdc

Fuel: Simulated Syngas,

6.5% CH4, 24.0% H2, 45.3% CO2, 22.4% H2O, 1.8% N2

Uf 70%, Ua 13.5%, 185 A (336 mA/cm2)

Page 25: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Presentation Outline

Introduction

FCE SECA Program Team Members

SECA Coal-Based SOFC Program Overview

Progress in SOFC Technology

Cell Development and Manufacturing

Stack DevelopmentScale-up and Metric Tests

Proof-of-Concept Module (PCM) DevelopmentStack Module

Baseline System Design and Cost AnalysesIntegrated Gasification Fuel Cell (IGFC) System Configuration

Baseline Power Plant Cost Estimate

Conclusion and Future Plans

Page 26: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

SOFC Module Evolution

Phase II: 30 kW

2-Stack Tower

Phase III: 60 kW

1-Stack Tower X

4 Towers (1 Quad)

Phase III+: 125 kW

2-Stack Tower X

4 Towers (1 Quad)

Phase III+: 250 kW

2-Stack Tower X

8 Towers (2 Quads)

Rapid Module

Development:

Over 90% of the same parts used

each time the size doubles from 60-

125-250 kW.

Page 27: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

SubScale Testing & Modeling Scale-Up Design Detailed Modeling:

CFD & FEA

60 kW Module Development Cycle

Detailed Engineering Drawings,

RFQ’s, BOM, Procurement & Part

AccumulationValidation Test in FCE’s

400 kW Test FacilityBuild Module

Phase II

Phase III

Page 28: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Internal Radiator

Buss Bars

Stack Simulator

Conductive

Stack Gasket

60 kW Stack Module Hardware Fabrication

Compression Plate60 kW Vessel

High Temp. Flanges

Quad Base

Page 29: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

60 kW Module Hardware Assembly

SOFC Module Hardware Assembly is in Progress for Future Tests

Page 30: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

250 kW Module Design

Quad #1

Quad #2

Cathode Out

Implement lessons learned from FCE’s current commercial DFC product,

in the areas of: detailed design, manufacturing, value engineering, cost

reduction, serviceability, and shipping.

Page 31: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Electrical

Balance-of-Plant

(EBOP)

SOFC

Stack Module

Mechanical

Balance-of-Plant

(MBOP)

System Performance Summary:

Normal Operating Conditions

PCM System Performance

MDU system is designed to lay the foundation for market entry 250 kW SOFC

product operating on natural gas and biogas.

Fuel Cell

DC Power 277.2 kW

Inverter Loss 13.9 kW

SOFC Gross AC Power 263.3 kW

Fresh Air Blower 3.8 kW

Anode Recycle Blower 2.0 kW

Motor Loss 0.44 kW

I&C Parasitics 2.63 kW

AC Power 8.9 kW

Plant Net AC Output 254.4 kW

Efficiency (HHV) 55.5 %

Efficiency (LHV) 61.5 %

CONSUMED POWER

Net Generation

Fuel Cell

DC Power 277.2 kW

Inverter Loss 13.9 kW

SOFC Gross AC Power 263.3 kW

Fresh Air Blower 3.8 kW

Anode Recycle Blower 2.0 kW

Motor Loss 0.44 kW

I&C Parasitics 2.63 kW

AC Power 8.9 kW

Plant Net AC Output 254.4 kW

Efficiency (HHV) 55.5 %

Efficiency (LHV) 61.5 %

CONSUMED POWER

Net Generation

Page 32: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Presentation Outline

Introduction

FCE SECA Program Team Members

SECA Coal-Based SOFC Program Overview

Progress in SOFC Technology

Cell Development and Manufacturing

Stack DevelopmentScale-up and Metric Tests

Proof-of-Concept Module (PCM) DevelopmentStack Module

Baseline System Design and Cost AnalysesIntegrated Gasification Fuel Cell (IGFC) System Configuration

Baseline Power Plant Cost Estimate

Conclusion and Future Plans

Page 33: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Coal-Based SOFC System with Catalytic Gasification

POWER GENERATION SUMMARY kW % Q input % MW gross

Fuel Gas Expandors Gross Power @ 20 kV 49,750 7.04% 10.96%

Fuel Cell Inverter AC Gross Power @ 20 kV 362,134 51.28% 79.78%

WGCU Off Gas Expander Gross Power @ 20 kV 7,024 0.99% 1.55%

Steam Turbine Gross Power at Generator Terminals @ 20 kV, 35,019 4.96% 7.71%

Total Gross Power Generation @ 20 kV 453,927 64.27% 100.00%

ASU (including air and production compression) 11,977 1.70% 2.64%

Gasification: Coal Prep, Recycle Compressor 1,495 0.21% 0.33%

WGCU Blower & Compressor 902 0.13% 0.20%

WGCU Oxidant Compressor 7,505 1.06% 1.65%

FGD Pumps, Agitators, and Lime Handling 2,441 0.35% 0.54%

Cathode Air Blowers 9,059 1.28% 2.00%

Anode FG Recycle Blowers 1,873 0.27% 0.41%

Steam Turbine Cycle Auxiliaries (BFP, CT, CWP) 3,200 0.45% 0.70%

Miscellaneous Loads 74 0.01% 0.02%

Transformer Losses 817 0.12% 0.18%

Total Auxiliary Load 39,342 5.57% 8.67%

Net Power Output at 345 kV 414,585 58.70% 91.33%

Net Efficiency Excluding CO2 Compression & Thermal Input

Coal feed, lb/h 202,980

Coal HHV (AF), Btu/lb 11,872

Coal Thermal Input, kWth 706,255 100.00% 155.59%

Net Plant Efficiency (HHV) 58.70%

POWER GENERATION SUMMARY kW % Q input % MW gross

Fuel Gas Expandors Gross Power @ 20 kV 49,750 7.04% 10.96%

Fuel Cell Inverter AC Gross Power @ 20 kV 362,134 51.28% 79.78%

WGCU Off Gas Expander Gross Power @ 20 kV 7,024 0.99% 1.55%

Steam Turbine Gross Power at Generator Terminals @ 20 kV, 35,019 4.96% 7.71%

Total Gross Power Generation @ 20 kV 453,927 64.27% 100.00%

ASU (including air and production compression) 11,977 1.70% 2.64%

Gasification: Coal Prep, Recycle Compressor 1,495 0.21% 0.33%

WGCU Blower & Compressor 902 0.13% 0.20%

WGCU Oxidant Compressor 7,505 1.06% 1.65%

FGD Pumps, Agitators, and Lime Handling 2,441 0.35% 0.54%

Cathode Air Blowers 9,059 1.28% 2.00%

Anode FG Recycle Blowers 1,873 0.27% 0.41%

Steam Turbine Cycle Auxiliaries (BFP, CT, CWP) 3,200 0.45% 0.70%

Miscellaneous Loads 74 0.01% 0.02%

Transformer Losses 817 0.12% 0.18%

Total Auxiliary Load 39,342 5.57% 8.67%

Net Power Output at 345 kV 414,585 58.70% 91.33%

Net Efficiency Excluding CO2 Compression & Thermal Input

Coal feed, lb/h 202,980

Coal HHV (AF), Btu/lb 11,872

Coal Thermal Input, kWth 706,255 100.00% 155.59%

Net Plant Efficiency (HHV) 58.70%

Combined with high methane producing gasification, coal based atmospheric-

pressure SOFC systems are capable of achieving ~ 59% efficiency and 99+%

carbon capture.

Page 34: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

H2 Co-Generation System Concept

• 138 ton/day H2 Produced

• 48.2% Net Electrical Efficiency

• 67.4% Total Efficiency (Electrical + H2)

IGFC systems have the flexibility for hydrogen co-production at a very attractive overall

efficiency.

Page 35: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

SOFC MW Class Module

(scale: similar)

MW-class Module Development Approach

Use lessons learned in FCE DFC MW-scale commercialization to optimize

design for SOFC MW Class System.

FCE’s DFC MW Module

Page 36: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Baseline SOFC Power Island

SOFC power island includes:

> 8 Sections of 42 fuel cell stack modules

> Steam turbine

> Two syngas expanders

SOFC power island lay-out takes advantage of well-thought clustering

concept using repeated arrangements of grouped components.

Direct Contact Cooler

Heat Recovery Steam

Generation (HRSG)

Syngas

Expanders

Steam Turbine

Direct Contact Cooler

Heat Recovery Steam

Generation (HRSG)

Syngas

Expanders

Steam Turbine

42- SOFC Stack Module

Section

Page 37: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Layout of 42-Module SOFC Cluster

Air

Blower

Air Heater

& Exhaust

SOFC Stack

Module

Anode

Recycle

Blowers

DC-AC

Inverters

SOFC cluster design takes advantage of modularity of fuel cells.

Page 38: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

IGFC Site Layout

Lay-out of 670 MWac IGFC plant includes 336 SOFC stack

modules, two syngas expanders, and a steam bottoming cycle.

Coal Yard

Gasification,

Gas Cleanup

and CO2

Compression

Cooling Water

treatment

Air Separation

Unit (ASU)

Fuel Cell, Gas

Expanders, HRSG,

and Steam Turbine

Generator (STG)

Power Island

Flare

Electric Yard

Page 39: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Factory Equipment Cost Estimate

Phase I Factory Cost Estimate:

597 $/kW (2002 USD)

Phase II Factory Cost Estimate:

372 $/kW (2000 USD)

Phase I IGFC Factory Equipment Cost

Breakdown ($/kW)

Fuel Cell

Stacks

$197/kW,

33%

Balance-

of-Plant

(BOP)

$400/kW,

67%

Phase II IGFC Factory Equipment Cost Breakdown

(Y2000 $/kW)

Total = $372/kW

Balance-of-

Plant (BOP)

$287

77%

Fuel Cell

Stacks

$85

23%

Cost Reductions were achieved via:

Stack cost reductions and performance improvements

Integrated system performance optimizations

Value engineering of BOP components

Gasification IslandASU

Catalytic Gasifier

Gas Cleanup System

Coal Air (to ASU)

Clean

Syngas

Power IslandGas Expanders

SOFC Power System

HRSG / Steam Turbines

CO2/H2O

CO2 Separation &

CompressionDirect Contact Cooler

CO2 Compressors

Steam

Cost

Envelope

Product CO2

AC

Power

Page 40: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Stack Cost Reduction

Cost Reduction Focus Areas1. Stack Performance Increase

• Peak Power Increase

Resolved thermal management issues

2. Material Reduction:

• Thinner stack components

• Interconnect material reduction

• Reduced number of intermediate plates

3. Manufacturing Process Changes

• Improved material utilization

• Automation

• Elimination of process steps

• Interconnect manufacturing development

SOFC Stack Block Cost Reduction

$197

$119

$210

$153

$85

$108

$0

$50

$100

$150

$200

$250

Phase I Factory Cost

Est. (2002 USD)

2009 Interim

(2002 USD)

Phase II Factory

Cost Est. (2000 USD)

$/kW net AC

$/kW gross DC

The fuel cell stack cost have decreased substantially mainly due to

the R&D activities in the SECA Phase II project.

Page 41: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Balance-of-Plant Factory Equipment Cost Estimate

Costs were estimated by WorleyParsons, based on extensive in-house cost database in addition to budgetary vendor quotations

Cost estimation is based on two 670 MW nominal power plants manufactured per year (2000 USD).

Estimate includes Factory Equipment costs for the Power Island, exclusive of gasification, syngas cleanup, and CO2 separation/compression systems.

BOP Factory Cost Estimate:

287 $/kW (2000 USD)

Total BOP Cost (2000 USD) =

Electric Accessories

9 $/kW

3%

Instr. & Control

7 $/kW

2%

Site Improvements

2 $/kW

1%

BOP Water Systems

8 $/kW

3%

Steam Turbine

17 $/kW

6%

HRSG

64 $/kW

23%

Inverter

47 $/kW

16%

Heaters & Coolers

42 $/kW

14%

Expanders

38 $/kW

13%

Blowers

5 $/kW

2%

Fuel Cell Piping

33 $/kW

12%

Fuel Cell Enclosure

15 $/kW

5%

287 $/kW

`

Page 42: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Factory Cost Estimate Sensitivity Results

Mean = $390.8/kW, with a range of $348.8 to $440.2/kW

The range between the 10th and 90th percentiles is from $374.0 to $407.8 or within $17/kw from the mean

Cost Distribution Inputs

Est. “Most Likely” Cost

Est. Min (-10%)

Est. Max (+20%)

10% below Min

15% above Max

Monte Carlo Simulation was performed to predict Probability Distribution Function

(PDF) of Estimated System Cost.

SOFC Power Island Cost ($/kW)

10th percentile 90th percentile

Page 43: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Presentation Outline

Introduction

FCE SECA Program Team Members

SECA Coal-Based SOFC Program Overview

Progress in SOFC Technology

Cell Development and Manufacturing

Stack DevelopmentScale-up and Metric Tests

Proof-of-Concept Module (PCM) DevelopmentStack Module

Baseline System Design and Cost AnalysesIntegrated Gasification Fuel Cell (IGFC) System Configuration

Baseline Power Plant Cost Estimate

Conclusion and Future Plans

Page 44: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Summary Accomplishments

Modifications in cell materials have enhanced cell performance and reduced degradation rate to <0.3%/1000 h.Third generation manufacturing processes (TSC-3) were

developed for scaled-up 550 cm2 active area (25 cm x 25 cm) cells based on high-performance thin cell technology.Over 5000 cells of 25 cm x 25 cm cell size (550 cm2 active area)

have been fabricated in the pilot manufacturing facility, with >95% product yield. A 120-cell stack metric test successfully met DOE’s requirement

of completing 1500 h of testing before the end-of-Phase II, demonstrating a peak power of 25.2 kW and achieving a steady state average power degradation rate of 0.9%/1000 h (well below the Phase II DOE requirement of 2%/1000 h).

Stack tower concept suitable for large-scale SOFC modules was successfully demonstrated by achieving power output of >30 kWdc and operating on simulated coal-derived syngas. A Baseline IGFC System (~670 MW nominal) utilizing catalytic

gasification and capturing > 99% of carbon (as CO2) in the syngas was developed with an electrical efficiency of 58.7% (high heating value of coal). SOFC stack Factory Cost was estimated at $85/kW (Year 2000

dollars), meeting the Phase II target of ≤$100/kW. The Baseline Power Plant system Factory Cost Estimate,

audited by an independent party, achieved a cost of $372/kW (2000 USD) for the SOFC power island meeting the DOE metric of <$400/kW.

Page 45: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

MW-Scale

Demonstration

2008 2010 2012 2020

≥ 250 kW

Proof-of-

Concept

Unit

Phase IIIPhase IIPhase I

30 kW

Stack

Tower

10 kW

Stack

FCE’s Coal-Based SECA Program Plan

FCE’s long-term plan is development of SOFC power plants capable of

using a variety of fuels such as natural gas, biogas, and coal syngas.

2015

Coal-Based

58% LHV

System

Phase III+

60 kW

Stack

Module

Page 46: Progress in SECA Coal-Based Program 12th Annual SECA ... Library/Events/2011/seca/tue-pm... · Significant progress has been made toward enhancing cell ... 80 0.785 0.847 7.9% Test

Support for FCE’s SECA Coal Based Program provided

by the US Department of Energy (DOE) through the

co-operative agreement DE-FC26-04NT41837

Support and guidance by the management team at NETL

Acknowledgements

Thank You!