Prof M Wills1 Year 1 M Wills test 3 for first year 22nd November 2010. Write your answers on a piece...

4
Prof M Wills 1 Year 1 M Wills test 3 for first year 22nd November 2010. Write your answers on a piece of paper. Write your name at the top of the paper. Hand it in at the end of the lecture. It will be marked and returned to you later. ) Add arrows to the following mechanism: Ph H H Br Ph H Ph H Ph H E-alkene. Base: ct the product formed in the reaction below, and show a mechanism for its for R Br 2 R + Br Br R R Br Br R R Br Br R R Br Br or 3 marks 4 marks
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Transcript of Prof M Wills1 Year 1 M Wills test 3 for first year 22nd November 2010. Write your answers on a piece...

Page 1: Prof M Wills1 Year 1 M Wills test 3 for first year 22nd November 2010. Write your answers on a piece of paper. Write your name at the top of the paper.

Prof M Wills 1

Year 1 M Wills test 3 for first year 22nd November 2010.

Write your answers on a piece of paper. Write your name at the top of the paper. Hand it in at the end of the lecture. It will be marked and returned to you later.

1) Add arrows to the following mechanism:

PhH

H

Br

PhH

PhH

Ph H

E- alkene.

Base:

2) Predict the product formed in the reaction below, and show a mechanism for its formation:

RBr2R +

BrBr

RR

Br

Br

RR

Br

Br

RR

Br

Bror

3 marks

4 marks

Page 2: Prof M Wills1 Year 1 M Wills test 3 for first year 22nd November 2010. Write your answers on a piece of paper. Write your name at the top of the paper.

Prof M Wills 2

3) Predict the product formed in the reaction below, and show a mechanism for its formation:

RHBrR +

H

RR

H

Br

RR

H

Br

3 marks

Page 3: Prof M Wills1 Year 1 M Wills test 3 for first year 22nd November 2010. Write your answers on a piece of paper. Write your name at the top of the paper.

A very goodanswer:

Page 4: Prof M Wills1 Year 1 M Wills test 3 for first year 22nd November 2010. Write your answers on a piece of paper. Write your name at the top of the paper.

A surprisingly common error – remember that the H and the brAre removed from ADJACENT carbons, not the same one.

A relatively minor error – antiperiplanar H is best one aligned for removal.