Production of Licella bio-crude oil as a platform for bio-chemicals, … · 2020. 5. 13. ·...

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Production of Licella bio-crude oil as a platform for bio-chemicals, marine & aviation fuels

Transcript of Production of Licella bio-crude oil as a platform for bio-chemicals, … · 2020. 5. 13. ·...

Page 1: Production of Licella bio-crude oil as a platform for bio-chemicals, … · 2020. 5. 13. · Production of Licella bio-crude oil as a platform for bio-chemicals, marine & aviation

Production of Licella bio-crude oil as

a platform for bio-chemicals, marine

& aviation fuels

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2009

Describes Licella’s technology as “potentially “Revolutionary and disruptive” due to its capacity to: ….create fungible fuels, enabling the use of the existing distribution infrastructure. These technologies would remove the distribution infrastructure constraints.

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Why does bio-crude make so much sense?

• Where will low carbon, high energy density liquid fuels and chemical feedstocks come from?

• Lignocellulose represents the largest basket of sustainable biomass available and the only source of volumes comparable with fossil deposits

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Biomass challenges

Challenges

• Nature has:– Aggregated feedstock for free– Converted feedstock to crude for

free

• Multinationals/Governments have invested trillions of $ in refining infrastructure

• Biomass has:– High oxygen content– High water content

• Customers want:– Price parity – or cheaper– Sustainable production

• Electric & Fuel Cell vehicles being deployed

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Biomass opportunities

Challenges

• Nature has:– Aggregated feedstock for free– Converted feedstock to crude for

free

• Multinationals/Governments have invested trillions of $ in refining infrastructure

• Biomass has:– High oxygen content– High water content

• Customers want:– Price parity – or cheaper– Sustainable production

• Electric & Fuel Cell vehicles being deployed

Opportunities

• Energy security

• Customers:– Using “Bio” as competitive

advantage

• Biomass typically low in sulphur

• Aviation still requires high density fuels

• Paris:– Carbon pricing is coming & with

it national schemes to reduce GHG’s

• Biomass processing industries looking to expand into fuels & Chemicals

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Revised Mandates Under the RFS2

Finalised RFS2 schedule in November 2015, 2008-2022 (bn gallons per year)

Source: Bloomberg New Energy Finance, Nawitka

9.010.5

12.0 12.6 13.2 13.8 13.6 14.1 14.5 15.0 15.0 15.0 15.0 15.0 15.0

5.57.0

8.510.5

13.516.0

0.2 0.2 0.5

2.53.0

3.5

3.5

3.5

4.0

0.00.5

0.70.8

1.01.0

1.6 1.71.9

1.0

1.0

1.0

1.0

1.0

1.0

0

5

10

15

20

25

30

35

40

2008 2010 2012 2014 2016 2018 2020 2022

Biomass-baseddiesel

Other advanced

Cellulosicbiofuels

Renewable fuel(corn ethanol)

The final rule pushed up total volumes 3% from the May 2015 proposal, a victory for biofuels

Strong uncertainty as to how post-2016RVOs will be set

• The original RVO for Cellulosic Biofuel in 2017 is 5.5 bn gallons. However, we expect the EPA will reduce this amount to better reflect the installed capacity.

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Source Nawitka Capital

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Revised Mandates Under the RFS2

Finalised RFS2 schedule in November 2015, 2008-2022 (bn gallons per year)

Source: Bloomberg New Energy Finance, Nawitka

9.010.5

12.0 12.6 13.2 13.8 13.6 14.1 14.5 15.0 15.0 15.0 15.0 15.0 15.0

5.57.0

8.510.5

13.516.0

0.2 0.2 0.5

2.53.0

3.5

3.5

3.5

4.0

0.00.5

0.70.8

1.01.0

1.6 1.71.9

1.0

1.0

1.0

1.0

1.0

1.0

0

5

10

15

20

25

30

35

40

2008 2010 2012 2014 2016 2018 2020 2022

Biomass-baseddiesel

Other advanced

Cellulosicbiofuels

Renewable fuel(corn ethanol)

The final rule pushed up total volumes 3% from the May 2015 proposal, a victory for biofuels

Strong uncertainty as to how post-2016RVOs will be set

• In late 2015 the EPA

slashed the Cellulosic

Biofuel mandate for

2016 from 4.2 bn to 0.2

bn gallons – a 95%

reduction due to the

lack of supply.

• The original RVO for Cellulosic Biofuel in 2017 is 5.5 bn gallons. However, we expect the EPA will reduce this amount to better reflect the installed capacity.

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Costs of production will reduce, but it will take time

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16% of the barrel delivers

47% of the value

Source Bloomberg New Energy Finance, US EIA, American Chemical Council

Critical to capture the full value

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What we do

Biomass e.g. Wood residues~17 MJ/kg dry ~40% Oxygen

Licella Biocrude~35 MJ/kg ~13 % Oxygen

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Lignocellulosic Biomass• Use all the resource

• Significant quantities of wood residues e.g. sawmill residue, hog fuel, can be aggregated:

– Low in sulphur, ash and metals

– High moisture content (10-60%)

– Low bulk density and energy density

– Complex biopolymers plus fatty acids and resins

• Also bagasse, stover, energy grasses, macroalgae, microalgae ...

Source: Xu et al., Chem. Soc. Rev., 2014, 43, 7485-7500

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Technology Scale Up

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Reactor Progression Plant Construction

Reactor diameter scale up

Capacity scale up

1st Generation Small Pilot 2009 - -

2nd Generation Large Pilot 2011 x 2 x10

3rd Generation Large Pilot 2013 x 3 x100

Gen 1 Gen 2 Gen 3

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Licella’s Cat-HTR

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Algae

Wood wastePine/ Eucalypt

Sugar WasteBagasse

Agricultural waste

Wheat Straw

Palm WastePalm Bunches

Energy CropsBana Grass

Examples of feedstocks tested

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• Low sulphur• Renewable• Distillable• Much more stable than pyrolysis oils• Oxygen content comparable to plant oils

~11-14%• Made by a process instead of extracted –

many parameters can be altered or varied

Licella Biocrude overview

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removalof residual oxygen at refinery

Licella’s Bio-crude

(~36 MJ/kg & 12% O2)

biomass

(dry)

diesel

jet fuel

Ethanol

Pyrolysis

Oils

Relationship of Oxygen Content to Energy Density

Percentage oxygen in wt%C

alo

rifi

c V

alu

e in

MJ

/kg More Oxygen =

Less Energy

Removal of oxygen with hydrogen is

expensive

Less hydrogen = cheaper process

It’s all about the Oxygen....and Hydrogen!

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Typical Properties of Radiata Pine Biocrude (dry basis)

Property

Gross Calorific Value (MJ/Kg) 34-36

Oxygen (mass %) 10-14

Carbon (mass %) 79-82

Hydrogen (mass %) 6-8

Sulphur (mass %) 0.01

Nitrogen (mass %) 0.1-0.2

• Water-insoluble, soluble in many organic solvents• Can be distilled• Denser than water at ambient temperatures

• 1H nmr suggests minimum aromatic:aliphatic proton ratio about 1:5, so aromatic:aliphatic carbon ratio about 1:2.5

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Using Biocrudes without Further Upgrading

• 20% Blend of non hydrotreatedbiocrude (diesel fraction) showed no significant changes in brake power and indicated power, compared to diesel alone in modern automotive engine

0

10

20

30

40

50

60

70

0 25 50 75 100

BP

(k

W);

IP

(k

W)

Engine load (% of full load)

R0 (BP) R5 (BP) R10 (BP) R20 (BP)

R0 (IP) R5 (IP) R10 (IP) R20 (IP)

• Results very promising for use of biocrudes in

stationary and marine engines without

upgrading in refinery

Nabi, Rahman, Islam, Hossain, Brooks, Rowlands, Tulloch, Ristovski & Brown, ‘Fuel characterisation, engine performance, combustion and

exhaust emissions with a new renewable Licella biofuel,’ Energy Conversion and Management, 96, 588–598 (2015).

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High Energy Content (34-

36MJ/Kg) = Less Hydrogen

12-14% Oxygen

No specialty catalysts

required

Brownfield sites

“drops in” to existing

petroleum infrastructure

Higher yields

We use all the biomass 30 –

40% yield

2+ bbls per odt feedstock

No drying required

Able to use wet feedstocks

Lowest possible Opex

Highest possible yields

Don’t create a char

No pre-treatment required Lowest possible Capex

Ability to Maximise Revenue

>70% reduction in GHG

Chemicals as well as fuels

Licella’s Bio-Crude Oil

Fuels Low in Sulphur

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Aviation Fuels – “Green Diesel” very prospective

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Meet Errol

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• Sustainable Aviation Fuel must be:

– A “drop-in” replacement that meets the same technical standards as fossil derived fuel

– Fulfill internationally recognised sustainability criteria

– Competitively priced compared with fossil Jet-A

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51% more for selling product

that’s easier/cheaper to make

Why would you make Jet?

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What are all the existing airline taxes for ?

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Marine Opportunities

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Significant changes

happening with Marine

fuel requirements

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Licella – Biochemicals

Volume (MT) p.a. from 200k odt facility

Price

$/T

COMMODITY

SPECIALTY

$10,000

$2,000

$700

6,5002,300 60,000

Cyclo/AliphaticsPhenols, Cresols

Vanillin, Guaiacol etc

Bio-Crude

Ref: C. Begley for Generic Value/ Volume curve

Additives, Monomers,

Solvents

Fine chemicals, Drug precursors, Pesticides, Dyes, Food additives and Flavours ,

Stabilisers

Solvents, Monomers, Stabilisers

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16% of the barrel delivers

47% of the value

Source Bloomberg New Energy Finance, US EIA, American Chemical Council

Critical to capture the full value

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Policy certainty required

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Pulp Mills

1 Intercontinental

2 Northwood

3 Prince George

4 Taylor

5 Canfor Pulp Ltd. Head Office

6 Canfor Pulp Innovation

CANFOR PULP INNOVATION (CPI)

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Search and Apply

NOT

Research and

Development

“NATURALLY REFINED SOLUTION”

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Biofuels-Bio Chemicals Joint Venture Established

• Global Application to Kraft, Mechanical Pulpmills and Extracted Lignin

• The Worlds Largest Bio-Refinery Base Integrated into Canfor Pulp’s Kraft Mill in Prince George, British Columbia, Canada

• Initial Project – 400,000 - 500,000 bbls of Biocrude Per Annum

• Advanced Biofuel Product Which Meets Highest Standards in Low Carbon Fuel Standards

• The Process will Enhance Existing Pulp Industry Value Proposition

“THE WONDER from DOWN UNDER”

LICELLA KRAFT“NATURALLY REFINED SOLUTION”

Jim Lane – Biofuels Digest

CANFOR PULP

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Northwood

Prince George

Intercontinental

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Licella’s Bio-crude is a true replacement producing fuels and chemicals

Simple Process

Importance of having significant strategic partners with shared vision

This is a long journey but will deliver significant rewards

Importance of long term, stable, bipartisan policy

Summary

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Not for wimps!

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Acknowledgments

Licella would like to thank the Australian Government particularly ARENA and Accelerating Commercialisation for their support

Thank you for listening

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Questions

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Contact details

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Steve Rogers

[email protected]

Mobile +61 428 274 910

www.Licella.com.au