PRODUCT NAME Caterpillar AR11C107C Old Cat Yellow (Aerosol)williamadamsshop.com.au/files/MSDS/MSDS...

Caterpillar AR11C107C Old Cat Yellow (Aerosol)

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 25-Jan-2013 CHEMWATCH 5010-76X9317SP Version No:

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Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAMECaterpillar AR11C107C Old Cat Yellow (Aerosol)

SYNONYMS"aerosol spray touch up paint enamel"

PROPER SHIPPING NAMEAEROSOLS

PRODUCT USEYellow touch up enamel paint.Application is by spray atomisation from a hand held aerosol pack.The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing.

SUPPLIERCompany: Caterpillar LtdAddress:1 Caterpillar DriveTullamarineVIC, 3043AustraliaTelephone: +61 3 9953 9333Fax: +61 3 9335 3366

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.

CHEMWATCH HAZARD RATINGS

Flammability Toxicity

Body Contact Reactivity

Chronic

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

RISK SAFETY■ Extremely flammable. • Keep locked up.■ Harmful by inhalation and if swallowed. • Keep away from sources of ignition. No smoking.■ Danger of cumulative effects. • Do not breathe gas/fumes/vapour/spray.■ Irritating to eyes and skin. • Avoid contact with skin.■ Limited evidence of a carcinogenic effect. • Avoid contact with eyes.■ May cause SENSITISATION by skin contact. • Wear suitable protective clothing.■ Risk of explosion if heated under • In case of insufficient ventilation, wearconfinement. suitable respiratory equipment.■ Toxic to aquatic organisms, may cause long- • Wear suitable gloves.term adverse effects in the aquaticenvironment.

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of 13Section 2 - HAZARDS IDENTIFICATION

■ May impair fertility. • Wear eye/face protection.■ May cause harm to the unborn child. • Use only in well ventilated areas.■ Repeated exposure may cause skin dryness and • Keep container in a well ventilated place.cracking.■ Vapours may cause drowsiness and dizziness. • Avoid exposure - obtain special instructions

before use.■ Skin contact may produce health damage*. • Do not empty into drains.■ May produce discomfort of the respiratory • To clean the floor and all objects contaminatedsystem*. by this material, use water and detergent.■ Possible respiratory sensitiser*. • Keep container tightly closed.* (limited evidence). • This material and its container must be disposed

of in a safe way.• Keep away from food, drink and animal feedingstuffs.• In case of contact with eyes, rinse with plentyof water and contact Doctor or Poisons InformationCentre.• Use appropriate container to avoid environmentalcontamination.• Avoid release to the environment. Refer tospecial instructions/Safety data sheets.• This material and its container must be disposedof as hazardous waste.• In case of accident by inhalation: removecasualty to fresh air and keep at rest.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %acetone 67-64-1 35toluene 108-88-3 5solvent naphtha petroleum, light aliphatic 64742-89-8. <52- ethoxyethyl acetate 111-15-9 <5white spirit 8052-41-3. 15lead sulfochromate 1344-37-2 5petroleum ether 8032-32-4. <5aerosol propellants includepropane 74-98-6 20

Section 4 - FIRST AID MEASURES

SWALLOWED■ Rinse mouth out with plenty of water.If poisoning occurs, contact a doctor or Poisons Information Centre.• If swallowed do NOT induce vomiting.• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.• Observe the patient carefully.• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.

EYE■ If this product comes in contact with the eyes:• Immediately hold eyelids apart and flush the eye continuously with running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.• Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.• Transport to hospital or doctor without delay.

SKIN■ If solids or aerosol mists are deposited upon the skin:• Flush skin and hair with running water (and soap if available).

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of 13Section 4 - FIRST AID MEASURES

• Remove any adhering solids with industrial skin cleansing cream.• DO NOT use solvents.• Seek medical attention in the event of irritation.

INHALED• If fumes or combustion products are inhaled remove from contaminated area.• Lay patient down. Keep warm and rested.• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.

NOTES TO PHYSICIANFor acute or short term repeated exposures to petroleum distillates or related hydrocarbons:• Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.• Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction,

obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should beintubated.

• Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury hasbeen reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungsexcrete inhaled solvents, so that hyperventilation improves clearance.

• A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detectthe presence of pneumothorax.

• Gastric acids solubilise lead and its salts and lead absorption occurs in the small bowel.• Particles of less than 1 um diameter are substantially absorbed by the alveoli following inhalation.• Lead is distributed to the red blood cells and has a half-life of 35 days. It is subsequently redistributed to soft tissue &

bone-stores or eliminated. The kidney accounts for 75% of daily lead loss; integumentary and alimentary losses account for theremainder.

• Neurasthenic symptoms are the most common symptoms of intoxication. Lead toxicity produces a classic motor neuropathy. Acuteencephalopathy appears infrequently in adults. Diazepam is the best drug for seizures.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA• Alcohol stable foam.• Dry chemical powder.• Carbon dioxide.• Water spray or fog - Large fires only.

FIRE FIGHTING• Alert Fire Brigade and tell them location and nature of hazard.• May be violently or explosively reactive.• Wear breathing apparatus plus protective gloves.• Prevent, by any means available, spillage from entering drains or water course.

FIRE/EXPLOSION HAZARD• Liquid and vapour are highly flammable.• Severe fire hazard when exposed to heat or flame.• Vapour forms an explosive mixture with air.• Severe explosion hazard, in the form of vapour, when exposed to flame or spark.Other combustion products include: carbon dioxide (CO2) metal oxides, i.e lead.

FIRE INCOMPATIBILITY■ Avoid contamination with strong oxidising agents as ignition may result.

HAZCHEM2YE

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Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Wear protective clothing, impervious gloves and safety glasses.• Shut off all possible sources of ignition and increase ventilation.

MAJOR SPILLS• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• May be violently or explosively reactive.• Wear breathing apparatus plus protective gloves.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Prevent concentration in hollows and sumps.DO NOT spray directly on humans, exposed food or food utensils.

SUITABLE CONTAINER• Aerosol dispenser.• Check that containers are clearly labelled.

STORAGE INCOMPATIBILITYAvoid storage with oxidisers, strong acids and strong alkalis.

STORAGE REQUIREMENTS• Store in original containers in approved flammable liquid storage area.• DO NOT store in pits, depressions, basements or areas where vapours may be trapped.• No smoking, naked lights, heat or ignition sources.• Keep containers securely sealed. Contents under pressure.• Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLSSource Material TWA TWA STEL STEL Peak Peak TWA Notes

ppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC__________ __________ ______ ______ ______ ______ ______ ______ ______ ______Australia acetone 500 1185 1000 2375Exposure (Acetone)StandardsAustralia toluene 50 191 150 574Exposure (Toluene)StandardsAustralia solvent naphtha 900 (see Chapter 16)Exposure petroleum, lightStandards aliphatic

(Petrol(gasoline))

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of 13Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Source Material TWA TWA STEL STEL Peak Peak TWA Notesppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC

__________ __________ ______ ______ ______ ______ ______ ______ ______ ______

Australia 2- ethoxyethyl 5 27Exposure acetate (2-Standards Ethoxyethyl

acetate)Australia white spirit 790 (see Chapter 16)Exposure (White spirits)Standards

The following materials had no OELs on our records• lead sulfochromate: CAS:1344- 37- 2• petroleum ether: CAS:8032- 32- 4

ODOUR SAFETY FACTOR (OSF)OSF=0.042 (solvent naphtha petroleum, light aliphatic)■ Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure Standard is being exceeded.

Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.

The Odour Safety Factor (OSF) is defined as:

OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm

Classification into classes follows:

Class OSF DescriptionA 550 Over 90% of exposed individuals are aware by smell that

the Exposure Standard (TLV- TWA for example) is beingreached, even when distracted by working activities

B 26- 550 As " A" for 50- 90% of persons being distractedC 1- 26 As " A" for less than 50% of persons being distractedD 0.18- 1 10- 50% of persons aware of being tested perceive by

smell that the Exposure Standard is being reachedE <0.18 As " D" for less than 10% of persons aware of being

tested

.

MATERIAL DATAPETROLEUM ETHER:SOLVENT NAPHTHA PETROLEUM, LIGHT ALIPHATIC:

For n-hexane:Odour Threshold Value: 65 ppmNOTE: Detector tubes for n-hexane, measuring in excess of 100 ppm, are available commercially.Occupational polyneuropathy may result from exposures as low as 500 ppm (as hexane), whilst nearly continuous exposures of 250

ppm have caused neurotoxic effects in animals.Concurrent exposure to chemicals (including MEK) and drugs which induce hepatic liver oxidative metabolism can reduce the time

for neuropathy to appear.

SOLVENT NAPHTHA PETROLEUM, LIGHT ALIPHATIC:TOLUENE:

For toluene:Odour Threshold Value: 0.16-6.7 (detection), 1.9-69 (recognition)NOTE: Detector tubes measuring in excess of 5 ppm, are available.High concentrations of toluene in the air produce depression of the central nervous system (CNS) in humans.

2-ETHOXYETHYL ACETATE:ACETONE:

Exposed individuals are reasonably expected to be warned, by smell, that the Exposure Standard is being exceeded.Odour Safety Factor (OSF) is determined to fall into either Class A or B.The Odour Safety Factor (OSF) is defined as:

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OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppmClassification into classes follows:

Class OSF DescriptionA 550 Over 90% of exposed individuals

are aware by smell that theExposure Standard (TLV- TWA forexample) is being reached, evenwhen distracted by workingactivities

B 26- 550 As " A" for 50- 90% of personsbeing distracted

C 1- 26 As " A" for less than 50% ofpersons being distracted

D 0.18- 1 10- 50% of persons aware ofbeing tested perceive by smellthat the Exposure Standard isbeing reached

E <0.18 As " D" for less than 10% ofpersons aware of being tested

.

CATERPILLAR AR11C107C OLD CAT YELLOW (AEROSOL):None assigned. Refer to individual constituents.

ACETONE:Odour Threshold Value: 3.6 ppm (detection), 699 ppm (recognition)Saturation vapour concentration: 237000 ppm @ 20 CNOTE: Detector tubes measuring in excess of 40 ppm, are available.Exposure at or below the recommended TLV-TWA is thought to protect the worker against mild irritation associated with brief

exposures and the bioaccumulation, chronic irritation of the respiratory tract and headaches associated with long-term acetoneexposures.

TOLUENE:Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed through intact skin. Absorption by skin

may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the same as for inhalation. Contact with eyes andmucous membranes may also contribute to overall exposure and may also invalidate the exposure standard.

SOLVENT NAPHTHA PETROLEUM, LIGHT ALIPHATIC:for benzeneOdour Threshold Value: 34 ppm (detection), 97 ppm (recognition)NOTE: Detector tubes for benzene, measuring in excess of 0.5 ppm, are commercially available. The relative quality of

epidemiological data and quantitative health risk assessments related to documented and theoretical leukaemic deaths constitutethe basis of the TLV-recommendation.<</>.

Odour threshold: 0.25 ppm.The TLV-TWA is protective against ocular and upper respiratory tract irritation and is recommended for bulk handling of

gasoline based on calculations of hydrocarbon content of gasoline vapour.for ethyl benzene:Odour Threshold Value: 0.46-0.60 ppmNOTE: Detector tubes for ethylbenzene, measuring in excess of 30 ppm, are commercially available.Ethyl benzene produces irritation of the skin and mucous membranes and appears to produce acute and chronic effects on the

central nervous system.CEL TWA: 200 ppm, 800 mg/m3 [SHELL]

2-ETHOXYETHYL ACETATE:

Odour Threshold Value: 0.06 ppm (detection), 0.13 ppm (recognition) This substance is readily hydrolysed inthe body yieldingethylene glycol monoethyl ether which is a putative reproductive toxin. The TLV-TWA is thought to be protective againsttesticular effects.

WHITE SPIRIT:For white spirit:Low and high odour thresholds of 5.25 and 157.5 mg/m3, respectively, were considered to provide a rather useful index of odour

as a warning property.The TLV-TWA is calculated from data on the toxicities of the major ingredients and is intended to minimise the potential for

irritative and narcotic effects, polyneuropathy and kidney damage produced by vapours.<</>.

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LEAD SULFOCHROMATE:The lead concentration in air is to be maintained so that the lead concentration in workers' blood remains below 0.060 mg/100

g of whole blood. The recommended TLV-TWA has been derived following a review of reports of adverse effects on reproduction,blood-pressure and other end-points of toxicity.

for insoluble chrome(VI)-containing substances:There is little environmental data regarding exposures and possible links to increased respiratory cancers. The recommended

TLV is thought to provide an adequate margin of safety pending a review of the complexities involved in the scientific issuesrelated to chromate carcinogenicity.

• demography, occupational and medical history and health advice.WARNING: This substance is classified by the NOHSC as Category 2 Probable Human Carcinogen.WARNING: This substance has been classified by the ACGIH as A2 Suspected Human Carcinogen.

PETROLEUM ETHER:For cyclohexane:Odour Threshold Value: 784 ppm (detection)NOTE: Detector tubes for cyclohexane, measuring in excess of 100 ppm are commercially available.The recommended TLV-TWA represents the borderline of irritation but takes into account the practical difficulties of achieving

lower values in the workplace.for heptane (all isomers)The TLV-TWA is protective against narcotic and irritant effects which are greater than those of pentane or n-hexane but less

than those of octane. The TLV-TWA applies to all isomers.<</>.Naphthas of this type produce central nervous system depression and are mild irritants of the eyes and upper respiratory

tract. The carcinogenic potential of middle petroleum distillates is recognised and is related to the content of polynucleararomatic hydrocarbons

(PAHs).CAUTION: This substance has been classified by the ACGIH as A3Animal carcinogen (at relatively high doses).

PROPANE:For propaneOdour Safety Factor(OSF)OSF=0.16 (PROPANE).

PERSONAL PROTECTION

RESPIRATOR•Type AX-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

EYE• Safety glasses with side shields; or as required,• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,

describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].

HANDS/FEET■ Wear chemical protective gloves. e.g. PVC gloves with barrier cream Wear safety footwear.

OTHER■ None required when handling small quantities.• Overalls.• Eyewash unit.

ENGINEERING CONTROLS■ Use in a well-ventilated area.Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineeringcontrols can be highly effective in protecting workers and will typically be independent of worker interactions to provide this

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high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work environment.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCEYellow highly flammable liquid with a solvent odour; does not mix with water.Supplied as an aerosol pack. Contents under PRESSURE.

PHYSICAL PROPERTIESLiquid.Gas.Does not mix with water.

State Liquid Molecular Weight Not applicableMelting Range (°C) Not available Boiling Range (°C) Not availableSolubility in water (g/L) Immiscible Flash Point (°C) <- 7pH (1% solution) Not applicable Decomposition Temp (°C) Not availablepH (as supplied) Not applicable Autoignition Temp (°C) Not availableVapour Pressure (kPa) Not available Upper Explosive Limit (%) Not availableSpecific Gravity (water=1) Not available Lower Explosive Limit (%) Not availableRelative Vapour Density >1 Volatile Component (%vol) 0.80(air=1)Evaporation Rate >1 Ether=1

Section 10 - STABILITY AND REACTIVITY

CONDITIONS CONTRIBUTING TO INSTABILITY• Elevated temperatures.• Presence of open flame.• Product is considered stable.• Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED■ Not a likely route of entry into the body in commercial or industrial environments. The liquid may produce considerablegastrointestinal discomfort and be harmful or toxic if swallowed. Ingestion may cause nausea, pain and vomiting. Vomit enteringthe lungs by aspiration can cause inflammation of the lungs, which can lead to death.

EYE■ The liquid produces a high level of eye discomfort and is capable of causing pain and severe conjunctivitis. Corneal injury maydevelop, with possible permanent impairment of vision, if not promptly and adequately treated.The vapour is discomforting to the eyes.The vapour when concentrated has pronounced eye irritation effects and this gives some warning of high vapour concentrations. Ifeye irritation occurs seek to reduce exposure with available control measures, or evacuate area.The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure toirritants may produce conjunctivitis.

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SKIN■ The liquid is mildly discomforting to the skin if exposure is prolonged and is capable of causing skin reactions which may leadto dermatitis.Toxic effects may result from skin absorption.The material may accentuate any pre-existing dermatitis condition.The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling,the production of vesicles, scaling and thickening of the skin.

INHALED■ The vapour is discomforting to the upper respiratory tract and lungs.Inhalation hazard is increased at higher temperatures.Acute effects from inhalation of high vapour concentrations may be chest and nasal irritation with coughing, sneezing, headacheand even nausea.If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma andpossible death.Inhalation of vapour may aggravate a pre-existing respiratory condition such as asthma, bronchitis, emphysema.WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.

CHRONIC HEALTH EFFECTS■ Principal routes of exposure are usually by skin contact with the material and inhalation of vapour/spray mist.Lead can cross the placenta, and cause miscarriage, stillbirths and birth defects. Exposure before birth can cause mentalretardation, behavioural disorders and infant death. Lead can also cause reduced sex drive, impotence, sterility and damage thesperm of males, increasing the potential for birth defects. Periods in women can also be affected.Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS].Prolonged or continuous skin contact with the liquid may cause defatting with drying, cracking, irritation and dermatitisfollowing.Toxic effects are increased by consumption of alcohol.As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; oringestion in any form, should be avoided by observing good occupational work practice.One ingredient of the product has caused skin sensitisation reactions, shown as localised reddening and hives, or may producerespiratory sensitisation characterised by asthma-like symptoms and runny nose.

TOXICITY AND IRRITATION■ Not available. Refer to individual constituents.

CARCINOGENtoluene International Agency for Group 3 Not classifiable as

Research on Cancer (IARC) - to itsAgents Reviewed by the IARC carcinogenicity toMonographs humans

white spirit International Agency for Group 3 Not classifiable asResearch on Cancer (IARC) - to itsAgents Reviewed by the IARC carcinogenicity toMonographs humans

SKINacetone GESAMP/EHS Composite D1: skin 1

List - GESAMP Hazard irritation/corrosionProfiles

toluene Australia Exposure Notes SkStandards - Skin

toluene GESAMP/EHS Composite D1: skin 2List - GESAMP Hazard irritation/corrosionProfiles

toluene GESAMP/EHS Composite D1: skin 1List - GESAMP Hazard irritation/corrosionProfiles

2- ethoxyethyl acetate Australia Exposure Notes SkStandards - Skin

2- ethoxyethyl acetate GESAMP/EHS Composite D1: skin 1List - GESAMP Hazard irritation/corrosionProfiles

white spirit GESAMP/EHS Composite D1: skin 1List - GESAMP Hazard irritation/corrosionProfiles

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Section 12 - ECOLOGICAL INFORMATION

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.This material and its container must be disposed of as hazardous waste.Avoid release to the environment.Refer to special instructions/ safety data sheets.

EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation Mobility

Water/Soilacetone LOW HIGH LOW HIGHtoluene LOW MED LOW MEDsolvent naphtha petroleum, light No Data No Data No Data No Dataaliphatic Available Available Available Available2- ethoxyethyl acetate LOW No Data LOW HIGH

Availablewhite spirit No Data No Data No Data No Data

Available Available Available Availablelead sulfochromate No Data No Data No Data No Data

Available Available Available Availablepetroleum ether No Data No Data No Data No Data

Available Available Available Availablepropane LOW No Data LOW HIGH

Available

Section 13 - DISPOSAL CONSIDERATIONS

• Consult State Land Waste Management Authority for disposal.• Discharge contents of damaged aerosol cans at an approved site.• Allow small quantities to evaporate.• DO NOT incinerate or puncture aerosol cans.

Section 14 - TRANSPORTATION INFORMATION

Labels Required: FLAMMABLE GAS

HAZCHEM: 2YE (ADG7)

ADG7:Class or Division 2.1 Subsidiary Risk: NoneUN No.: 1950 Packing Group: NoneSpecial Provision: 63 190 277 Limited Quantity: See SP 277

327Portable Tanks & Bulk None Portable Tanks & Bulk NoneContainers - Instruction: Containers - Special

Provision:Packagings & IBCs - Packing P003 LP02 Packagings & IBCs - Special PP17 PP87Instruction: Packing Provision: L2Name and Description: AEROSOLS

Air Transport IATA:ICAO/IATA Class 2.1 ICAO/IATA Subrisk: NoneUN/ID Number: 1950 Packing Group: -

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of 13Section 14 - TRANSPORTATION INFORMATION

Special provisions: A145Cargo OnlyPacking Instructions: 203 Maximum Qty/Pack: 150 kgPassenger and Cargo Passenger and CargoPacking Instructions: 203 Maximum Qty/Pack: 75 kgPassenger and Cargo Limited Quantity Passenger and Cargo Limited QuantityPacking Instructions: Y203 Maximum Qty/Pack: 30 kg G

Shipping name:AEROSOLS

Maritime Transport IMDG:IMDG Class 2.1 IMDG Subrisk: SP63UN Number: 1950 Packing Group: NoneEMS Number: F-D,S-U Special provisions: 63 190 277 327 344 959Limited Quantities: See SP277 Marine Pollutant: YesShipping name:AEROSOLS

Section 15 - REGULATORY INFORMATION

Indications of Danger:F+ Extremely flammableN Dangerous for the environmentT Toxic

POISONS SCHEDULENone

REGULATIONS

Regulations for ingredients

acetone (CAS: 67-64-1) is found on the following regulatory lists;"Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 2", "Australia Customs (Prohibited Exports) Regulations 1958 - Schedule 9 Precursor substances - Part 2", "Australia Exposure Standards", "Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions", "Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Illicit Drug Reagents/Essential Chemicals - Category III", "Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "FEMA Generally Recognized as Safe (GRAS) Flavoring Substances 23 - Examples of FEMA GRAS Substances with Non-Flavor Functions", "FisherTransport Information", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO IBC Code Chapter 18: List of products to which the Code does not apply", "IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances", "International Fragrance Association (IFRA) Survey: Transparency List", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR National List of Candidates for Substitution – Norway", "Sigma-AldrichTransport Information", "United Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments", "United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II", "United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International Control (Red List) - Table II"

toluene (CAS: 108-88-3) is found on the following regulatory lists;"Acros Transport Information", "Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (AQUA/1 to 6 - non-pesticide anthropogenic organics)", "Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - organic compounds)", "Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm - Domestic water supply quality", "Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm (Aquatic habitat)", "Australia Customs (Prohibited Exports) Regulations 1958 - Schedule 9 Precursor substances - Part 2", "Australia Drinking Water Guideline Values For Physical and Chemical Characteristics", "Australia Exposure Standards", "Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions", "Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Illicit Drug Reagents/Essential Chemicals - Category III", "Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)",

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of 13Section 15 - REGULATORY INFORMATION

"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix I", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 7", "FisherTransport Information", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk", "IMO Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures containing at least 99% by weight of components already assessed by IMO, presenting safety hazards", "International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs", "International Fragrance Association (IFRA) Standards Prohibited", "International Fragrance Association (IFRA) Survey: Transparency List", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR List of Chemicals for Priority Action", "Sigma-AldrichTransport Information", "United Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments", "United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II", "United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International Control (Red List) - Table II", "WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water"

solvent naphtha petroleum, light aliphatic (CAS: 64742-89-8) is found on the following regulatory lists;"Acros Transport Information", "Australia Exposure Standards", "Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions", "Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures containing at least 99% by weight of components already assessed by IMO, presenting safety hazards", "International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs", "International Air Transport Association (IATA) Dangerous Goods Regulations", "International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and Cargo Aircraft", "International Council of Chemical Associations (ICCA) - High Production Volume List", "International Fragrance Association (IFRA) Survey: Transparency List", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR List of Chemicals for Priority Action", "OSPAR National List of Candidates for Substitution – Norway", "Sigma-AldrichTransport Information"

2-ethoxyethyl acetate (CAS: 111-15-9) is found on the following regulatory lists;"Australia Exposure Standards", "Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions", "Australia Hazardous Substances", "Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix I", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6", "FisherTransport Information", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk", "IMO Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures containing at least 99% by weight of components already assessed by IMO, presenting safety hazards", "International Chemical Secretariat (ChemSec) SIN List (*Substitute It Now!)", "International Fragrance Association (IFRA) Standards Prohibited", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR National List of Candidates for Substitution – Norway", "Sigma-AldrichTransport Information"

white spirit (CAS: 8052-41-3) is found on the following regulatory lists;"Acros Transport Information", "Australia Exposure Standards", "Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions", "Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines", "FisherTransport Information", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk", "IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances", "IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO", "International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs", "International Air Transport Association (IATA) Dangerous Goods Regulations", "International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and Cargo Aircraft", "International Council of Chemical Associations (ICCA) - High Production Volume List", "International Fragrance Association (IFRA) Survey: Transparency List", "International Numbering System for Food Additives", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR List of Chemicals for Priority Action", "OSPAR National List of Candidates for Substitution – Norway", "Sigma-AldrichTransport Information", "United Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments"

lead sulfochromate (CAS: 1344-37-2) is found on the following regulatory lists;"Australia - New South Wales - Work Health and Safety Regulation 2011 Restricted hazardous chemicals", "Australia - Queensland Work Health and Safety Regulation - Restricted hazardous chemicals", "Australia - South Australia - Work Health and Safety Regulations 2012 - Restricted hazardous chemicals", "Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions", "Australia Hazardous Substances", "Australia Hazardous Substances Requiring Health Surveillance", "Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for the

continued...



of 13Section 15 - REGULATORY INFORMATION

Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix C", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix I", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6", "Australia Work Health and Safety Regulations 2011 - Restricted hazardous chemicals", "International Chemical Secretariat (ChemSec) SIN List (*Substitute It Now!)", "International Council of Chemical Associations (ICCA) - High Production Volume List", "OECD List of High Production Volume (HPV) Chemicals", "United Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments"

petroleum ether (CAS: 8032-32-4) is found on the following regulatory lists;"Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions", "Australia Hazardous Substances", "Australia Inventory of Chemical Substances (AICS)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "FisherTransport Information", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances", "IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO", "International Council of Chemical Associations (ICCA) - High Production Volume List", "International Fragrance Association (IFRA) Survey: Transparency List", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR National List of Candidates for Substitution – Norway", "Sigma-AldrichTransport Information"

propane (CAS: 74-98-6) is found on the following regulatory lists;"Australia Exposure Standards", "Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions", "Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP", "International Council of Chemical Associations (ICCA) - High Production Volume List", "International Fragrance Association (IFRA) Survey: Transparency List", "International Numbering System for Food Additives", "OECD List of High Production Volume (HPV) Chemicals", "Sigma-AldrichTransport Information"

No data for Caterpillar AR11C107C Old Cat Yellow (Aerosol) (CW: 5010-76)

Section 16 - OTHER INFORMATION

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 25-Jan-2013Print Date: 6-Jun-2013

This is the end of the MSDS.

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