Proceedings MR2009 23 JMountford

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    Titanium

    A Viable Alternative in Todays World for Marine & Naval Applications

    Milton R. ScaturroConsultant

    Scaturro & Associates31 Alviso Drive, Camarillo, CA 93010-8476

    John A. Mountford Jr.Consultant

    Tico Titanium, Inc.30150 South Wixom Road, Wixom, MI 48393

    [5961 West Shore Drive NW, Canton, OH 44718]

    NORFOLK MARRIOTT WATERSIDE

    NORFOLK, VA JUNE 8 12, 2009

    Fried A. Kriedt P.E., D.Sc.Materials Engineer LPD-17 ProgramComputer Sciences Corp.560 Lynnmeade RoadGretna, LA 70056

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    ELEMENT GR 1 GR 2 GR 3 GR 5 GR 7 GR 9 GR 12 GR 23 GR 32

    Nitrogen (max.) 0.03 0.03 0.05 0.05 0.03 0.03 0.03 0.03 0.03

    Carbon (max.) 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08

    Hydrogen (max.) 0.015 0.015 0.015 0.015 0.015 0.015 0.015 0.0125 0.015Iron (max.) 0.20 0.30 0.30 0.40 0.30 0.25 0.30 0.25 0.25

    Oxygen (max.) 0.18 0.25 0.35 0.20 0.25 0.15 0.25 0.13 0.11

    Aluminum *** *** *** 5.5 - 6.75 *** 2.5 - 3.5 ***5.5 -

    6.75 4.5 - 5.5

    Vanadium *** *** *** 3.5 - 4.5 *** 2.0 - 3.0 *** 3.5 - 4.5 ***

    Palladium *** *** *** *** 0.12-0.25 *** *** *** ***

    Molybdenum *** *** *** *** *** *** 0.2 - 0.4 *** 0.6 - 1.2

    Nickel *** *** *** *** *** *** 0.6 - 0.9 *** ***

    Silicon *** *** *** *** *** *** *** *** 0.06 - 0.14

    Tin *** *** *** *** 0.6 - 1.4 *** *** *** 0.6 - 1.4

    Zirconium *** *** *** *** *** *** *** *** 0.6 - 1.4

    Residual ea. (max.) 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1

    Residual Total

    (max.) 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4

    TITANIUM Bal Bal Bal Bal Bal Bal Bal Bal Bal

    6Al-4V Gr 2+Pd 3Al-2.5V 6Al-4V 5111

    Chemistry (Weight %)

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    MECHANICAL PROPERTIES

    Grade UTS Yield Elongation Red Area a Elastic Modulus

    min. min. max. min. min. Tension Shear ksi ksi ksi % % x106 psi x106 psi

    1 35 20 45 24 30 14.9 5.51

    2 50 40 65 20 30 15.0 5.51

    3 65 55 80 18 30 15.0 5.66

    4 80 70 95 15 25 15.2 5.66

    5 (6-4) 130 120 -- 10 25 16.5 6.38

    7 50 40 65 20 30 15.0 5.51

    9 (3-2.5) 90 70 -- 15 25 14.9 6.35

    12 70 50 -- 18 25 15.2 5.51

    32 (5111) 100 85 -- 18 30 16.0

    a = Bar/Billet Forging

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    PHYSICAL PROPERTIESThermal Coefficient

    Grade Elastic Modulus Density Conductivity Expansion

    Elect.

    Resist. Weld Hard

    Tension Shear RB

    x106 psi x106 psi lbs/in3 g/cm3 BTU/hr-ft-0F x10-6 in/in-0F x10-6 ohm-in [ RC ]

    1 14.9 5.51 0.163 4.51 12.7 4.8 18 E 70

    2 15.0 5.51 0.163 4.51 12.6 4.8 21 E 80-85

    3 15.0 5.66 0.163 4.51 12.6 4.8 21 VG 90

    4 15.2 5.66 0.163 4.51 10.0 4.8 24 G 100

    5 (6-4) 16.5 6.38 0.160 4.43 3.8 5.0 66 VG [ 36 ]

    7 15.0 5.51 0.163 4.51 12.6 4.8 21 E 80-85

    9 (3-2.5) 14.9 6.35 0.162 4.48 4.8 5.3 50 VG [25]

    12 15.2 5.51 0.163 4.51 11.0 4.8 21 E [ 11 ]

    32 (5111) 16.0 0.160 4.43 4.3 4.6 60

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    Immune:

    Sea Water Brackish Water Polluted WaterMIC [Microbiologically Induced Corrosion]

    Fully Resistant:

    Stress Corrosion CrackingCavitation

    Pitting & Crevice Corrosion < 800 C (1750 F)

    Resistant:

    Gases - SO2 CO2 CO NH4 H2S N2

    H2 Embrittlement < 800

    C (1750

    F)

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    Attributes

    Corrosion Immunity (Seawater, Polluted, MIC)

    Strength Higher Mechanicals than Cu-Ni

    Hardness Higher than Cu-Ni

    Light Weight / Low Density 1/2 Cu-Ni

    Excellent Erosion Resistance to 20x Cu-Ni

    Compatible with Composites

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    Attributes contd.

    Low Thermal Expansion

    Non-Magnetic

    Superior Ballistic Properties

    High Shock Resistance

    High Melting Point [ 3020 0F / 1660 0C]

    Non Radioactive

    Environmentally Friendly (Non Toxic)

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    Benefits

    Corrosion Free Service - Life of the Ship

    Maintenance Eliminated/ Reduced

    Life of Ship Durability - No Replacement

    Increased Compartment Space (Volume)

    Design Efficiencies Smaller/ Thinner

    Support Loads Lessened

    Weight Reduction (Topside/Overall)

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    Benefits contd.

    Free up Manpower & Crew Manning

    Reduced Fuel Consumption

    Life Cycle Cost Savings

    Reduced Operating Costs

    Increased Storage & Payload Capacity

    No Painting ; No Solvents/ Supplies

    Better Compartment Accessibility

    No EPA or Environmental Issues

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    Heat Exchangers

    Coolers

    Lube Oil

    Engine Jacket

    Phalanx

    Radar Electronics

    Engine Piston Water

    Fresh Water

    Turbine Generators

    Thruster Engines

    Gear Lube Oil

    Discharge

    Other

    Distillation Unit Condensers

    Distillation Unit Brine Heaters

    Steam Condensers

    Refrigeration Condensers

    Air Conditioning Condensers

    Preheat Seawater Freshwater

    Jacket Water Heating

    Air/Gas Compressors (LP & HP)

    Fuel Oil Heating

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    Titanium Reduced Pipe Sizes PIPE Weight

    Ti Sch 10 Cu-Ni Class 200

    PT

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    Titanium Reduced Pipe Sizes WATER Weight

    Ti Sch 10 Cu-Ni Class 200

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    PIPE Weight Savings (lbs./ 100 ft.) ( Percent )

    Titanium Sch 10 - vs. - Cu-Ni Class 200

    Titanium Cu-Ni Weight Savings

    Size lbs/100 ft Size lbs/100 ft lbs/100 ft Percent

    2" Sch 10 152 3" class 200 391 239 61

    3" Sch 10 249 4" class 200 583 334 57

    4" Sch 10 323 6" Class 200 1,058 735 69

    6" Sch 10 534 8" Class 200 1,528 994 65

    8" Sch 10 771 10" Class 200 2,405 1,634 68

    10" Sch 10 1,073 12" Class 200 3,805 2,732 72

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    WATER Weight Savings (lbs./ 100 ft.) ( Percent )

    Titanium Sch 10 - vs. - Cu-Ni Class 200

    Titanium Cu-Ni Weight Savings

    Size lbs/100 ft Size lbs/100 ft lbs/100 ft Percent

    2" Sch 10 158 3" class 200 373 215 58

    3" Sch 10 362 4" class 200 624 262 42

    4" Sch 10 618 6" Class 200 1376 758 55

    6" Sch 10 1,376 8" Class 200 2,362 986 42

    8" Sch 10 2,362 10" Class 200 3,665 1,303 36

    10" Sch 10 3,697 12" Class 200 5,109 1,412 28

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    Weight Savings Totals (lbs./ 100 ft.)

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    Titanium Reduced Pipe Sizes VOLUME

    Titanium Sch 10 - vs. - Cu-Ni Class 200

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    Titanium Reduced Pipe Sizes % Volume SavedTitanium Sch 10 - vs. - Cu-Ni Class 200

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    Seawater Service and Firemain Systems

    Firemain Systems Pipe, Flanges & Fittings

    Fire Pumps (Grades 2 and 5)

    Hydrants

    Valves

    Butterfly / Globe / Ball

    Nozzles & Deluge Valving

    Input Service Water Piping

    Bilges

    Sprinkler Heads

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    Structures

    Exhaust Uptakes / Liners

    Cargo Doors

    Vertical Launch Systems

    Torpedo Bay Doors

    Stanchions

    Electrical Boxes

    Ballast Tanks Well Deck HVAC Vent Ducting

    Emergency Doors

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    Structures contd.

    Radar Structures

    Hanger Doors

    Jet Blast Deflectors

    Masts

    Weather Deck Light Boxes

    Emergency Stop Switch Boxes

    Seawater & Freshwater Tanks Under Insulation Ducting

    Compartment Doors

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    Summary

    Why Titanium

    Corrosion Immunity (Life of Ship)

    High Erosion Resistance

    High Strength

    Light Weight (Wgt. Reduction in tons)

    High Shock Resistance / Survivability

    Performance / Low Maintenance

    Durable

    Green Environmentally Clean