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Priority Substances - Source Screening and
Measures SheetsTenth Meeting of Working Group E
on Chemical Aspects 24 June 2010
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Structure of the presentation
• Source screening sheets: methodology for revision and findings
• Measures sheets: methodology and overview of new legislation
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Source screening sheets – Methodology (I)
• Methodology as specified in the 2005 Concept Paper
• Up to date (since 2004) information sought from:– EU Sources
• REACH (Annex XV Dossiers)• EU RARs• Plant Protection Products Directive• Biocides Directive• Prior Informed Consent• E-PRTR
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– International Sources• OSPAR Background Documents & Report on Emissions,
Discharges and Losses• UNECE (Rotterdam Convention; CLRTAP; POPs)
– FP6 Projects• Score-PP (substance flow analysis for selected priority
pollutants in case cities)• SOCOPSE (source control of priority substances in Europe
– Other information• Pesticides Manual• Trade Association Web-sites• Other reputable studies identified via Google searches
Source screening sheets – Methodology (II)
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• Reductions can be seen in reported discharges from IPPC installations (data from E-PRTR)
• However, industrial emissions are still significant for some substances
• Use of some substances now banned (e.g. some pesticides) or restricted
Main conclusions
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• Pesticides not included in Annex I of Directive 91/414/EEC therefore use prohibited – Alachlor; Atrazine; Chlorfenvinphos; Endosulfan;
Hexachlorocyclohexane (Lindane); Pentachlorophenol; Simazine; TBT; Trifluralin
• Pesticides where use continues – Chlorpyrifos; Diuron; Isoproturon.
Conclusions - pesticides
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• Cadmium – industrial sources remain significant
• Lead – industrial sources remain significant. Also discharges as a result of the use of lead products. Emissions to air from use of leaded petrol significantly reduced.
• Mercury – use in chlor-alkali electrolysis industry significantly reduced but currently still important. Further reductions expected in coming years.
• Nickel – emissions have reduced, but most sources still significant.
Conclusions – metals
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• BDEs – believed not to be produced in EU. Use restricted and significantly reduced.
• C10-C13 chloroalkanes (SCCPs) – production and industrial use are significant sources.
• 1,2-dichloroethane (EDC) – production and industrial use are significant sources.
• Dichloromethane – domestic use prohibited, professional use restricted (to be prohibited in 2012), production and industrial use remain significant sources.
• Hexachlorobenzene – no longer used or manufactured in the EU. No significant sources.
Conclusions – organohalogens (I)
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• Hexachlorobutadiene – no longer used or manufactured in the EU. No significant sources.
• Pentachlorobenzene – no longer used or manufactured in the EU. Losses from historically contaminated sediments only significant source.
• Trichlorobenzenes – one manufacturer in EU, used as a chemical intermediate. Production and industrial use are significant sources.
• Trichloromethane (Chloroform) – use by public and in diffusive applications is prohibited. Industrial production and use are significant sources.
Conclusions – organohalogens (II)
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• Anthracene – industrial manufacture and use main significant sources. Creosote use restricted but leaching from historically treated wood and contaminated sediment significant sources.
• Benzene – use in certain applications prohibited. Industrial production and use are significant sources.
• DEHP – emissions as a result of product use are significant, together with industrial production and use.
• Fluoranthene – little information available on production and use in EU. Most sources result in emissions of PAH/fluoranthene
• Naphthalene – significant industrial emissions from combustion processes, basic organic chemicals and non-ferrous metal production. Atmospheric deposition not significant
Conclusions – other organic substances (I)
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• Nonylphenols – domestic use phased out. Reduction in industrial use but emissions still significant.
• Octyphenols – significance of emissions as a result of tyre wear disputed. Emissions from non-IPPC installations likely to be more significant than those from IPPC installations.
• PAH – significant reduction in emissions from IPPC installations observed, but most sources still significant.
Conclusions – other organic substances (II)
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Measure sheets – Methodology
• Objective: To identify changes in measures since 2004 including new measures
• Starting point: 2004 measures sheets • Up to date information sought from:
– EUR-lex – Commission website / CIRCA / ENDS– International (OSPAR etc.)
• Structured according to the 2004 measures sheets (source/pathways)
• Reference to Directive 2008/105 on EQS in sheets under discussion
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Source pathway
Cat 2004 2010 Measures foreseen as at May 2010
Key stepsofimplemen-tation (of existing measures)
Implemen-tation gaps
C S notes
Issues identified in measures sheets - columns
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• Losses to surface waters by diffuse sources • Discharges to surface waters by point sources • Losses from historically contaminated sediments
and soils • Emissions to atmosphere
Sources/pathways
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Proposed: additional S0 row for relevant measures that does not directly relate to source/pathway:
Regulation (EC) No 1907/2006 (REACH)
• Obligation for registration• Annex XIV: Candidate list
for substances of very high concern
• Annex XVII (former Directive 76/769)
Regulation (EC) No 850/2004 on persistent organic pollutants
• Annex I: Substances subject to prohibitions (IA and B)• Annex II: Substances subject to restrictions
Source/ PathwayS0 General
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Stockholm Convention on Persistent Organic Pollutants (POPS)
• Annex A: Elimination • Annex B: Restriction• Annex C: Unintentional production• Currently endosulfan proposed for listing under POP
Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures (CLP)
• Aligns existing EU legislation to the UN Global Harmonised System GHS
Regulation (EC) concerning the export No 689/2008 and import of dangerous chemicals (PIC)
• Annex I(1):Chemicals subject to export notification procedure• Annex I(2) Chemicals qualifying for PIC notification
Source/ PathwayS0 General
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Losses to surface water by diffuse sourcesS1 Atmospheric deposition on surface water
New: Directive 2008/50/EC on ambient air quality (CAFÉ Directive)
Directive 2004/107/EC relating to arsenic, cadmium, mercury, nickel and polycyclic aromatic hydrocarbons in ambient air
Still in force since 2004:
Directive 2001/81/EC on national emission ceilings
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Losses to surface water by diffuse sourcesS2 Drainage and deep groundwater
New:
Directive 2006/118/EC on the protection of groundwater against pollution and deterioration
• Lists active substances as pollutant • Applies to pesticides group
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Losses to surface water by diffuse sourcesS3 Agricultural activities (I)
2004 2010Directive 91/414/EEC concerning the placing of plant products on the market Regulation (EC) No
1107/2009 concerning the placing of plant protection products on the market
• Mainly: non-inclusion (pesticides group) in Annex I to 91/414/EC
Directive 79/117/EEC prohibiting the placing on the market and use of plant protection products containing certain active substances
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2010Decisions concerning non-inclusion of substances in Annex I to Directive 91/414/EEC
Decisions including substances to Annex I, IA or IB to Directive 98/8/EC (Biocides)
Regulation (EC) No 839/2008 amending Regulation (EC) No 396/2005 as regards Annexes II, III and IV on maximum residue levels of pesticides in or on certain products
Directive 2009/128/EC on the sustainable use of pesticides
Losses to surface water by diffuse sourcesS3 Agricultural activities (II)
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Losses to surface water by diffuse sourcesS5 Accidental spills
2004 and 2010
Directive 96/82/EC (SEVESO II)
• Management of accidents concerning hazardous substances• CLP classification
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Losses to surface water by point sourcesS8 Dischargers in sewage effluents from household use
New: Regulation 1223/2009 (cosmetic products)
• PS listed in substances prohibited
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– ->
Losses to surface water by point sourcesS9.2 Industrial Activity (IPPC)
2004 2010 In preparation
Directive 96/61/EC (IPPC)
Directive 2008/1/EC (IPPC)
Integrated pollution prevention control COM(2007)844)
Decision 2000/497/EC (EPER)
Regulation (EC) No 166/2006 (PRTR)
Regulation (EC) No 1907/2006 (Annex XVII to REACH)
• Annex I: Substances subject to prohibitions (IA and B)• Annex II: Substances subject to restrictions
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Losses to surface water by point sourcesS10 Solid waste treatment (1)
2004 2010
Directive 75/442/EEC on waste
Directive 91/689/EEC on hazardous waste
Directive 2006/12/EC (Waste Framework) (to be repealed by Directive 2008/98/EC in December 2010)
Directive 2008/98/EC (Waste Framework)
Directive 88/378 on the safety of toys
Directive 2009/48/EC on the safety of toys
Directive 91/157/EEC on waste batteries
Directive 2006/66/EC on waste batteries
Several measures establishing Eco-labelling (furniture, textile, computers etc)
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Still in force since 2004:
Directive 1999/31/EC on landfill of waste
Directive 2000/53/EC on end-of-life vehicles
Directive 2002/96/EC on waste electrical and electronic equipment (WEEE)
Directive 2002/95/EC on the restriction of the use of certain hazardous substances in electrical and electronic equipment (RoHS)
Losses to surface water by point sourcesS10 Solid waste treatment (2)
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Losses from historically contaminated sediment and soils
New: Directive 2006/118/EC (groundwater protection)
• Mainly applies to pesticides
Proposed measure:
Framework Directive on protection of soil (COM (2006)232)