Prepreg excellence days - Presentation
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Advanced Materials
DECEMBER, 2014
ADVANCED CHEMISTRIES RAISING PERFORMANCE
Advanced Materials
2
Advanced Materials
FOCUSED INDUSTRIES
ADVANCED CHEMISTRIES RAISING PERFORMANCE
3
Advanced Materials
OUR HISTORY
ADVANCED CHEMISTRIES RAISING PERFORMANCE
1758
1884 1971
1996
1997
2000
2003
2005
2011
J.R. Geigy AG begins trading in chemicals and dyes
Chemical Industry Basel (CIBA) is formed
Ciba merges with J.R. Geigy to form Ciba-Geigy
Ciba-Geigy merges with Sandoz to form Novartis
Ciba Specialty Chemicals independent of Novartis
Vantico is formed for Performance Polymers
Vantico is acquired by Huntsman and becomes AdMat division
Huntsman becomes a public company
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Advanced Materials
2,300 employees, 80 countries, more than 1,500 products, over 2000 customers
GLOBAL PRESENCE
ADVANCED CHEMISTRIES RAISING PERFORMANCE
Americas: 527
APAC: 448
São Paulo Taboão da Serra
McIntosh
East Lansing
Spartan
Singapore
Hong Kong
Shanghai
Mumbai Chennai
Dubai
Cairo Sadat City
Istanbul
Moscow
Madrid
Pamplona
Duxford
Vienna
Bergkamen
Buenos Aires
Tokyo Kobe
Bad Säckingen
Panyu
Monthey Seoul
Taipeh
Deer Park
3 regional headquarters 13 manufacturing sites 10 sales offices IMT: 188
Europe: 1,135
Los Angeles
The Woodlands
Basel
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Advanced Materials
INNOVATION
ADVANCED CHEMISTRIES RAISING PERFORMANCE
Innovation comes from more than just new molecules It incorporates both new building blocks as well as a way of working together along the value chain.
6
Advanced Materials
1930 1940 1950 1960 1970 1980 1990 2000 2010 2020
- - - - - - - - -
Lab / pilot scale availability
Internal evaluation
Customer evaluation
Commercial scale availability
Qualification 1st application
Technical drivers
MILESTONES IN EPOXIES
ADVANCED CHEMISTRIES RAISING PERFORMANCE
CIBA
CIBA
Aerospace Marine Electronics
BISHENOL A EPOXIES
OO
OO
Araldite® GY 250 Araldite® LY 556 Araldite® MY 790 …
Superior mechanical performances to polyester and phenolics
CIBA
CIBA
Aerospace Marine Electronics
DOW
CIBA
DOW
Electronics Structural Composites
CIBA
n
CH2
O
O
CH2
O
O
O
O
EPN / ECN
DOW
DOW
Electronics Structural Composites
Thermal resistance superior to Bisphenol A epoxies
Araldite® EPN 1138 Araldite® EPN 1139 Araldite® ECN 1273 Araldite® ECN 1299 …
CIBA
Structural composites
CIBA
ON
O ON
O
O
O
O
N
OTGMDA / TGPAP
Araldite® MY720 Araldite® MY0500
Thermal resistance Mechanical performance TP tougheners Compatibility Processability
UNION CARBIDE
CIBA
Structural composites
CIBA
Structural composites
CIBA
CIBA
Araldite® MY720 Araldite® 9655, 9512, 9634… Araldite® M721 Araldite® MY0500 Araldite® MY0510
Processability
Structural composites
CIBA
CIBA
Structural composites
HUNTSMAN
CIBA
TGMAP
OO
N
O
O
SUMITOMO
CIBA
Structural composites
Araldite® MY0600 Araldite® MY0610
Modulus improvement Similar other performances
HUNTSMAN
SHELL
FLUORENE
O O
OO
DIC
NAPHTHALENE
O
O
O
O
HUNTSMAN
N
HUNTSMAN
HUNTSMAN
HUNTSMAN
HUNTSMAN
Toughness and thermal resistance via reduction of cross linking density
Araldite® MY 0816
HUNTSMAN CoE
NEXT GENERATION EPOXIES
HUNTSMAN CoE
“20% UP”
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Advanced Materials
1960 1970 1980 1990 2000 2010 2020
- - - - - -
Lab / pilot scale availability
Internal evaluation
Customer evaluation
Commercial scale availability
Qualification 1st application
Technical drivers
?
?
Electronics Structural composites
BMI MDA
Higher thermal resistance to epoxies
?
?
Electronics Structural composites
CIBA
Structural composites Electronics
CIBA
NN CH2
O
O O
O
Me
Me
OHOH
CIBA
BMI MDA FREE
Structural composites Electronics
CIBA
Lower toxicity Processability
Matrimid® 5292 A/B
LONZA CIBA (R.P.)
R.P. DOW
R.P. DOW
Structural composites Electronics
CYANATE ESTERS
LONZA CIBA (R.P.)
R.P. DOW
R.P. DOW
Structural composites Electronics
Niche between epoxies and BMIs
AroCy® range
GURIT ESSEX
CIBA
Electronics
HUNTSMAN
HUNTSMAN CoE
ADVANCED CHEMISTRIES RAISING PERFORMANCE
MILESTONES IN OTHER HIGH PERFORMANCE THERMOSETS
NEXT GENERATION BENZOXAZINES
HUNTSMAN
HUNTSMAN CoE
BENZOXAZINES BISPHENOL A / F
GURIT ESSEX
FST / X-Free Thermal and mechanical performance Dielectric properties
Processing Low toxicity FST / X-Free
Interiors Structural composites
Processing Thermal and mechanical performance Araldite® LZ 8280 N 75
XU 8282-1 Araldite® MT 35600 Araldite® MT 35700
CIBA
Electronics
HUNTSMAN
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Advanced Materials
Registration, Evaluation, Authorization and Restriction
REACH FOR CHEMICALS
ADVANCED CHEMISTRIES RAISING PERFORMANCE
We are spending several millions euros each year in order to maintain current supply
Introduction of new molecules into the EU market may be commercially risky and expensive In worse case, more than 2 millions euros
Large financial and resource impact on the chemical components suppliers due to number of substances Analytical & toxicity studies, dossier preparation, chemical safety report, personal costs…
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Advanced Materials
Evolution in Europe for chemistries used in composite applications
REGULATORY / LEGISLATION
ADVANCED CHEMISTRIES RAISING PERFORMANCE
Statement Phenolics Epoxy with resins formerly "R68” & currently "H341" labelled
Epoxy with resins "Others"
Bis-Maleimides
Cyanate Ester
Benzoxazines Isocyanate
NO ISSUE with REACH registration
NO USAGE LIMITATION for composite application (prepregs or direct closed processes)
Unknown
ADDITIONAL PROTECTIVE MEASURES (not mandatory today) could be required at the working place
(1) TGMDA (2) Naphthalene epoxy
(4)
TGPAP, TGMAP Subject to test programs results (3)
(1) Formaldehyde is today under consultation for "Proposal for Harmonised Classification and Labelling" and it will be classified as Carc. 1A (2) Latest tests for REACH dossier allow removal from Mutagenic and Reprotoxic classification lists : "R68"/"H341" phrases to be removed by end 2013 (3) Mutagenic and reprotoxic tests running: Tests results expected between 2014 (MUT) and 2016 (REPRO) (4) REACH registration 2018 Remark: The above table represents Huntsman’s view based on current knowlegde at the date of the presentation and are subject to changes in regulation
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Advanced Materials
WHAT YOU SHOULD EXPECT FOR INNOVATION
ADVANCED CHEMISTRIES RAISING PERFORMANCE
CONTSRUCT BUILDING BLOCKS
MANAGE CHANGE
PROVIDE FOCUS
SPECIALTY COMPONENTS PARTNER (e.g. Huntsman)
ROLE IN INNOVATION
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Advanced Materials
CONSTRUCT BUILDING BLOCKS
ADVANCED CHEMISTRIES RAISING PERFORMANCE
FOCUS
BUILDING BLOCKS CHANGE
SP
E. C
OM
P. P
AR
TNE
R PREPREGGER
DDS
TGMDA
M5218
DICY
BIS-A
EPN
IPDA
ECN
BIS-F
Optimize Customize Synthesize
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Advanced Materials
MANAGE CHANGE
ADVANCED CHEMISTRIES RAISING PERFORMANCE
CHANGE
FOCUS
BUILDING BLOCKS
MITIGATIONS § Processes that cover both
internal and external stake holders along the value chain
§ Product stewardship § Apply predictive approach § Communication of risks § Process safety management
CHANGES REGULATORY RAW MATERIAL VARIABILITY SUPPLY CHAIN
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Advanced Materials
PROVIDE FOCUS
ADVANCED CHEMISTRIES RAISING PERFORMANCE
FOCUS
CHANGE BUILDING BLOCKS
0
20
40
60
80
100
MARKET FOCUS
MC supplier SC supplier Prepregger Tier 1 OEM
OEM TIER 1
PREPREGGER SPE. COMP. PARTNER
MASS COMMODITY
SUPPLIER
MASS COMMODITY
SUPPLIER
MASS COMMODITY
SUPPLIER
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Advanced Materials
TAMING THE WILD
ADVANCED CHEMISTRIES RAISING PERFORMANCE
FOCUS
CHANGE BUILDING BLOCKS THE COMMODITY WILDERNESS
§ General specifications with little regard to historical equivalence or customers
§ Inconsistency or fluctuation of quality § Change management that meets internal
needs (mainly for safety) and not customer focused
§ Reluctant to create “specialty” or “unique” materials
§ “Here is our offering, take it or leave it”
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Advanced Materials
CREATING FOCUS
ADVANCED CHEMISTRIES RAISING PERFORMANCE
FOCUS
CHANGE BUILDING BLOCKS
THE PREPREGGER CIVILIZATION § Focused needs § Well defined specifications based on
statistical equivalence rather than just a specification range
§ Sensitive to change (effects on quality and processing time, potential breaching of approvals)
§ Change management that incorporates value chain
§ Values uniqueness
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Advanced Materials
A common blueprint along the value chain evolves into a new civilization of value.
WORKING TOGETHER TO DRIVE INNOVATION
ADVANCED CHEMISTRIES RAISING PERFORMANCE
17
Advanced Materials
Araldite® is a registered trademark of Huntsman Corporation or an affiliate thereof in one or more, but not all, countries. Sales of the product described herein (“Product”) are subject to the general terms and conditions of sale of either Huntsman Advanced Materials LLC, or its appropriate affiliate including without limitation Huntsman Advanced Materials (Europe) BVBA, Huntsman Advanced Materials Americas Inc., or Huntsman Advanced Materials (Hong Kong) Ltd. or Huntsman Advanced Materials (Guangdong) Ltd. (“Huntsman”). The following supercedes Buyer’s documents. While the information and re-com-mendations included in this publication are, to the best of Huntsman’s knowledge, accurate as of the date of publication, NOTHING CONTAINED HEREIN IS TO BE CONSTRUED AS A REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, NONINFRINGEMENT OF ANY INTELLEC-TUAL PROPERTY RIGHTS, OR WARRANTIES AS TO QUALITY OR CORRESPONDENCE WITH PRIOR DESCRIPTION OR SAMPLE, AND THE BUYER ASSUMES ALL RISK AND LIABILITY WHATSOEVER RESULTING FROM THE USE OF SUCH PRODUCT, WHETHER USED SINGLY OR IN COMBINATION WITH OTHER SUBSTANCES. No statements or recommendations made herein are to be construed as a representation about the suitability of any Product for the particular application of Buyer or user or as an inducement to infringe any patent or other intellectual property right. Data and results are based on controlled conditions and/or lab work. Buyer is responsible to determine the applicability of such information and recommendations and the suitability of any Product for its own particular purpose, and to ensure that its intended use of the Product does not infringe any intellectual property rights. The Product may be or become hazardous. Buyer should (i) obtain Material Safety Data Sheets and Technical Data Sheets from Huntsman containing detailed information on Product hazards and toxicity, together with proper shipping, handling and storage pro-cedures for the Prod-uct, (ii) take all steps necessary to adequately inform, warn and familiarize its employees, agents, direct and in-direct customers and contractors who may handle or be exposed to the Product of all hazards pertaining to and proper procedures for safe handling, use, storage, transportation and disposal of and exposure to the Product and (iii) comply with and ensure that its employees, agents, direct and indirect customers and contractors who may handle or be exposed to the Product comply with all safety information contained in the applicable Material Safety Data Sheets, Technical Data Sheets or other instructions provided by Huntsman and all applicable laws, regulations and standards relating to the handling, use, storage, distribution and disposal of and exposure to the Product. Please note that products may differ from country to country. If you have any queries, kindly contact your local Huntsman representative. © 2013 Huntsman Corporation. All rights reserved. Ref. No. Prepreg Excellence Days 12.13 _EN_EU
LEGAL INFORMATION
ADVANCED CHEMISTRIES RAISING PERFORMANCE