PLASTICS - Verbundzentrale des GBV of Thermoplastic ... Ultrasonic Welding of Regrind Plastics ......

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San Francisco May 1-5 1994 PLASTICS Gateway to The Future VOLUME II—MATERIALS 1994 f UNIVEnSil I IA TTC INFORM ; .'I * %

Transcript of PLASTICS - Verbundzentrale des GBV of Thermoplastic ... Ultrasonic Welding of Regrind Plastics ......

San Francisco May 1-5 1994

PLASTICSGateway to The Future

VOLUME II—MATERIALS1994

f UNIVEnSilI IA

TTCINFORM

; . ' I

* %

Application of Thermoplastic Resistance Welding Techniques to Thermoset Composites 1295R. C. Don, S. H. McKnight, E. D. Wetzel, J. W. Gillespie, Jr., University of DelawareEffect of a Strain Relief Insert on the Buckling Strength of a Composite Plate 1300P. Herrington, University of New OrleansProcess Optimisation in Ultrasonic Welding of the AWS-Test Sample D06H. Potente, D. Harming, E. Moritzer, University of PaderbornAmplitude Control in Ultrasonic Welding of Thermoplastics 1311D. A. Grewell, J. L. Frantz, Branson Ultrasonics Corporation, USAUltrasonic Welding of Regrind Plastics 1317B. Infantino, Eastman Kodak CompanyThe Effects of Moisture on the Vibration Welding of Polyamide 1320H. Potente, M. Uebbing, Universitdt-GH PaderbornThe Hot-Tool Welding of Acrylonitrile-Butadiene-Styrene 1327V. K. Stokes, GE Corporate Research and DevelopmentApplication of an Integrated Process Model for Fusion Bonding ofThermoplastic Composites 1334S. T. Holmes, R. C. Don, J. W. Gillespie, Jr., University of DelawareA Feasibility Study of Radio Frequency Joining of HDPE Using ConductivePolymeric Composite 1341C. F. Faisst, Jr., Eastman Kodak Co.A. Benatar, The Ohio State UniversityJoining of Short Fiber Glass Reinforced Polypropylene Using ResistanceHeated Fusion Bonding 1347M. G. McBride, S. H. McKnight, J. W. Gillespie, Jr., University of DelawareElectromagnetic Welding of Thermoplastics and Specific Design Criteriawith Emphasis on Polypropylene D52S. M. Chookazian, Ashland Chemical Inc.Joining Thermoplastic Lined Steel Pipe 1356N. S. Taylor, TWIHigh Speed Welding of Plastics Using Lasers 1360I. A. Jones, N. S. Taylor, TWI

VOLUME II—MATERIALSELECTRICAL & ELECTRONIC DIVISION

The Attributes of Functionalized Polybutadiene Resins in Electrical Encapsulations 1366R. H. Boutier, Elf Atochem North America, Inc.Flow Visualization for Thermoset Transfer Molding 1371L. T. Manzione, J. D. Weld, AT&T Bell LaboratoriesMeasurement and Modeling of Solvent Removal from Thin Polymer Films 1375J. Gu, G. A. Campbell, Clarkson UniversityCrosslinking Techniques for Electrical Jacketing Materials 1379B. Thorburn, Nissin High Voltage America, Co., Ltd.Total Value Analysis of Plastic Electronic Components 1386F. C. Jaarsma, J. Carrizales, Hoechst-Celanese CorporationElectrical Percolation in Short Fiber Composites: Continuum SpaceMonte Carlo Simulations and Experimental Results 1392A. A. Dani, A. A. Ogale, Clemson UniversityPermanent EMI Shielding of Plastics Using Copper Fibers 1396M. V. Murthy, Doss Plastics Inc.The Effect of Extrusion Parameters on the Physical and ElectricalProperties of Static Dissipative Polymer Blends 1401R. J. Coots, T. E. Fahey, A. Giovannitti-Jensen, The BFGoodrich CompanyThin-Film Polymer Batteries for Electric Vehicles 1406S. J. Visco, M. M. Doeff, L. C. De Jonghe, Lawrence Berkeley Laboratory

XX/ANTEC '94

Constant Gauge Length Testing of Polymeric Fibers 1412C. Daley, Kimberly-Clark Inc.K. Menard, The Perkin Elmer Corporation

ENGINEERING PROPERTIES & STRUCTURE DIVISION

Quantitative Real-Time Orientation Measurement of Semicrystalline Polymers—Part II 1416R. E. Pepper, Amoco Fabrics and Fibers CorporationR. J. Samuels, Georgia Institute of TechnologyOrientation, Mechanical and Thermal Characterization of Drawn PET 1421A. Ajji, J. Guevremont, K. C. Cole, M. M. Dumoulin, Industrial Materials InstituteHigh Modulus Polypropylene: Effect of Polymer and Processing Variableson Morphology and Physical Properties 1425R. Phillips, G. Hebert, J. News, M. Wolkowicz, Himont USA Inc.New Rules: Shrink Properties of Substantially Linear PolyolefinPlastomer Based Blown Films 1430K. L. Walton, R. M. Patel, Dow Chemical North AmericaThe Effect of Lamellar Injection Molding on Properties of PC/ABS Composites 1433K. Nichols, J. Sole, M. Barger, D. Pawlowski, J. Bicerano, The Dow Chemical Company

* A New Approach to Reactive Compounding 1440D. J. van der Wai, L. P. B. M. Janssen, University of Groningen

•Preparation of Starch Derivatives by Reactive Extrusion 1444M. E. Carr, National Center for Agricultural Utilization Research

•Reactive Extrusion of PP-g-AA with Alkyl Amines 1449X. C. Wang, C. Tzoganakis, G. L. Rempel, University of Waterloo

*Poly(isoprene-g-styrene) by Reactive Extrusion 1456W. Michaeli, W. Frings, A. Ortmann, Institut fur KunststoffverarbeitungH. Hocker, Deutsches WollforschungsinstitutCrystallinity and Order Development in Oriented Polyvinylchloride, PVC 1464S. A. Jabarin, The University of ToledoCrystal Structure Investigations of LARC-CPI Semicrystalline Polyimide 1469M. V. Brillhart, J. Teverovsky, J. Friler, P. Cebe, Massachusetts Institute of TechnologyStudy of the Preferential Crystallization of Polypropylene on the Surface of Wood Fibers 1474G. Wang, I. R. Harrison, The Pennsylvania State UniversityCrosslinking of Homogeneous Polyethylenes 1476P. J. Phillips, P. Sajkiewicz, University of TennesseeMaster Curve Approach to Polymer Crystallization Kinetics 1480T. W. Chan, G. D. Shyu, A. I. Isayev, University of AkronA Method of Studying Nonisothermal Crystallization of Polymers atVery High Cooling Rates 1485Z. Ding, J. E. Spruiell, University of TennesseePreliminary Report of Spherulite Deformation after Drawingof Poly(phenylene sulfide) Films 1491P. Cebe, P. Kang, I. Kwan, Massachusetts Institute of TechnologyOn-Line Monitoring of Reactive Compatibilization 1496M. Xanthos, J. Grenci, C. Jacob, S. S. Dagli, Polymer Processing InstituteH. K. Kotlar, Petrochemicals and PlasticsResidence Time Distribution of a Twin-Screw Extruder 1500J. P. Puaux, A. Ainser, Universite Jean-MonnetProgresses in Melt Reaction in Polymer Blends 1504R. Legras, P. Marechal, J. M. Dekoninck, Exxon Chemical International Inc.Some Structural Factors in the Reactive Blending of Polyamides 1509M. K. Akkapeddi, B. Van Buskirk, G. J. Dege, Allied Signal Inc.Modification of Nylon 66 by Reactive Extrusion 1514W. J. Lin, W. B. Yuo, L. G. Lin, Industrial Technology Research Institute

•Present in a joint session.

ANTEC '94/XXi

Influence of Some Molecular Parameters of the Interfacial Modifier onthe Emulsification of Polystyrene/Ethylene-Propylene Rubber Blends 1517M. Matos, P. Lomellini, B. D. Favis, Ecole Polytechnique de Montreal

*Melt Grafting of a Basic Monomer onto Polyethylene in a Twin Screw Extruder 1524K. E. Oliphant, W. E. Baker, Queen's University

•The Grafting of Polystyrene on Starch in a Twin-Screw Extruder 1530R. A. de Graaf, L. P. B. M. Janssen, University of Groningen

•Continuous Polymerization in a Back-Mixed Drag Flow Reactor 1535Y. Lu, J. A. Biesenberger, D. B. Todd, Stevens Institute of Technology

* Continuous Polymerization of Caprolactam in a Twin Screw Extruder On-LineBlending and Melt Spinning to Form Blend Fibers 1536H. Kye, J. L. White, The University of Akron

* Non-Homogeneous Mixing Rates and Conversion 1545C. Maier, General Electric Corporate Research & DevelopmentM. Lambla, EAHP-ULPD. Bigio, University of Maryland

•Evaluation of Chemically Modified Polypropylene with Various Glass Fiber Types,for Performance Enhancement in Glass Filled Polypropylene 1549R. C. Constable, BP Chemicals Inc.

*Transesterification of Ethylene Vinyl Acetate Copolymer in a Modular IntermeshingCorotating Twin Screw Extruder with Different Screw Configurations 1553P. J. Kim, J. L. White, University of Akron

•Molecular Weight Dependence of Polystyrene-Poly (methyl methacrylate) InterfacialTension via the Imbedded Fiber Retraction Technique 1564P. C. Ellingson, D. A. Strand, A. Cohen, R. L. Sammler, C. J. Carriere,

The Dow Chemical Company•Multilayer Rheology: Comparison of Experimental Data with Modeling

of Multilayer Shear Flow 1567C. J. Carriere, D. L. Headley, R. G. Gravel, R. Ramanathan, The Dow Chemical Company

•Tensile Properties of Starch/Polyethylene Blends: A Composite Theory Analysis 1572J. L. Willett, R. P. Westhoff, National Center for Agricultural Utilization Research

•Analysis of Dry Sliding Wear and Friction Data of Internally Lubricated Composites 1577A. Bolvari, LNP Engineering Plastics Inc.

•Tensile Dilatometry of Injection Molded HDPE/PA6 Blends 1584S. Fellahi, B. D. Favis, B. Fisa, Ecole Polytechnique de MontrealInterfacial Tension of a Blend Containing Liquid CrystallinePolymer and Polycarbonate 1590S. Kenig, Israel Plastics and Rubber CenterMicrocomposites Based on Thermoplastics and ThermotropicLiquid Crystalline Polymers 1594A. A. Handlos, E. A. Sabol, D. G. Baird, Virginia Polytechnic Institute and State UniversityStructure Development and Mechanical Properties of in situ ThermoplasticComposites Subject to Shearfree Deformation 1599J. P. de Souza, D. G. Baird, Virginia Polytechnic Institute and State UniversityThe Effect of Injection Molding Conditions on the Mechanical Properties of an in situComposite: Polypropylene and a LCP Based on HBA/HNA 1606H. J. O'Donnell, D. G. Baird, Virginia Polytechnic Institute and State University

•Miscibility Characterization of High Tg Polyester and Polycarbonate Blends 1614H. E. Yang, Eastman Chemical Company

•Crystallinities in Blends of Branched Fractions of Polyethylene 1619P. J. Phillips, K. Monar, The University of Tennessee

* Structure/Property Relationships in Flame Retarded Polycarbonate 1622S. R. Seibel, E. Papazoglou, FMC Corporation

•Experimental Determination of Process Optimizations When CompoundingFiberglass Reinforced, Flame Retarded PBT on the Co-Rotating Twin Screw Extruder 1626E. Beecher, J. Grillo, Werner & Pfleiderer CorporationE. Papazoglou, S. Seibel, FMC Corporation

*Present in a joint session.

XXU/ANTEC '94

•Positively Charged Polyethersulfone Microporous Membrane 1632H. Hu, Gelman Sciences Incorporated

•Pore and Permeability of Various Filter Media 1635K.-J. Choi, Fleetguard, Inc.

•Polymeric Filtration System for Viscous Polymer Solutions 1638C. B. Wang, Eastman Chemical CompanyPolyvinyl Alcohol-Polyethylene Polyblends through Reactive Processing 1646N. G. Gay lord, H. Ender, L. R. David, Jr., Gaylord Research InstituteInterpenetrating Polymer Network of Polyurethane and FurfurylAlcohol I. Mechanical Properties 1649C.-C. M. Ma, D. Y. Goang, National Tsing Hua UniversityJ. L. Han, K. H. Hsieh, National Taiwan UniversityNovel Reaction Injection Moulding Processing of Polyurethanes: In Shot RatioVariation and Twin Mixhead Injection 1654P. D. Coates, N. Tucker, S. S. F. Wong, A. F. Johnson, University of BradfordOrganic Fibre Reinforced Polymer Matrix Composites Produced by SRIM 1659P. D. Coates, S. D. Long, A. F. Johnson, N. Tucker, S. Wong, University of BradfordCuring Characteristics of a Zinc-Catalyzed Cyanate Ester Resin System 1664Y. Deng, G. C. Martin, Syracuse UniversitySynthesis and Characterization of a Poly Alkyl-Aryl by Friedel-Crafts Alkylation 1669R. M. Jimenez-Amezcua, I. Reyes-Gonzalez, V. M. Gonzalez-Romero,

H. H. Ramirez, V. N. Caro, Universidad de GuadalajaraEffect of pH on the Mechanical Properties of Functionalized PolymersPrepared by Emulsion Polymerization 1672P. J. Hernandez, E. Mendizabal, J. E. Puig, Universidad de GuadalajaraM. Hidalgo, Industrias Resistol S.A.I. Katime, Universidad del Pais VascoSimplified Database on Plastic Properties, Processes, and Products 1676D. V. Rosato, Rhode Island School of DesignScanning Electron Microscopy of Porosity in "Porosity Free" andTraditional Acetals 1681R. W. Campbell, The Polymer CorporationEffects of Annealing on the Dynamic Mechanical Behavior of Poly(phenylene sulfide) 1686J. J. Scobbo, Jr., C. R. Hwang, GE PlasticsDynamic Mechanical Relaxations of Polyethylene Copolymers 1691L. Woo, M. T. K. Ling, S. P. Westphal, Baxter HealthcareComparison of Intermeshing and Separated Rotor Internal Mixers 1694P. S. Kim, J. L. White, The University of Akron

•Variation of Failure Properties in Injection Molded Plaques 1700H. G. deLorenzi, J. T. Woods, J. F. Birnby, General Electric

•Fracture Toughness of Weldline Region in Injection Molded Articles 1705K. Tomari, T. Harada, Osaka Municipal Technical Research InstituteM. Iwamoto, Z. Maekawa, H. Hamada, Kyoto Institute of Technology

•Impact Behavior of Composites of PolypropyleneFilled with Hybrid [CaCO3/Mica] Filler 1710J. Jancar, A. T. DiBenedetto, University of Connecticut

•Delamination in Polycarbonate/Polyethylene Terephthalate Blends—A Model System Approach for Predictions 1713H. T. Pham, K. Sehanobish, E. G. Rightor, The Dow Chemical Company

• A New Technique for Studying Toughening by Inclusions 1717E. Ivanova, S. Wu, R. Li, A. Chudnovsky, University of Illinois at ChicagoK. Sehanobish, C. P. Bosnyak, The Dow Chemical Company

•Effect of Plasticizer on the Fracture Toughness of Unsaturated Polyester Resins 1724M. Bakar, F. Djaider, A. Feghouli, Algerian Petroleum Institute

•Effects of Molding Conditions on Properties and TougheningMechanism of Polycarbonate 1728J. Y. J. Chung, N. R. Lazear, Miles Inc.

•Present in a joint session.

ANTEC '94 /XXiii

•Experimental Evaluation of Lead Encapsulation by Encapsulant Coating 1733F. S. Lai, J. C. Hwang, T. Ngwa, University of Massachusetts at Lowell

•Surface Embrittlement of Polyacetals in Chlorinated Water 1737L. J. Broutman, G. W. Kamykowski, L. J. Broutman & Associates, Inc.

•Estimating Pipe Burst Properties of VDF Based Resins 1741J. Holton, M. Bolmer, Elf Atochem North America, Inc.B. Schlinquer, Elf Atochem S.A.

•Fracture Toughness of Nylon 6/Nylon 6IcoT Blends 1746Y. Liu, J. A. Donovan, University of Massachusetts

•Novel Elastic-Deformation Grinding Process for Commingled Plastic Waste Recovery 1752K. Khait, Northwestern University

•Amorphous High-Heat Polycarbonates for Advanced Lighting Applications 1759W. G. Paul, P. N. Bier, Miles Inc.

•Value Added Blends and Composites from Recycled Plastic Fishing Gear 1763S. S. Dagli, S. K. Dey, R. Tupil, M. Xanthos, Polymer Processing Institute

•Ecoprofiles for Disposal Processes 1767C. Molgaard, L. Alting, Technical University of Denmark

• Thermoplastic Elastomers —A Major Recycling Opportunity 1772C. P. Rader, R. C. Wegelin, Advanced Elastomer Systems, L.P

•Life Cycles of Plastics 1778C. L. Beatty, University of Florida

•Rheomolding—A New Process to Mold Polymeric Materials. Part I: Principle 1780J. P. Ibar, Solomat Rheomolding Division

•An Approach Towards Molding Parts with Constant Properties on Addition of Regrind 1783N. Dontula, G. A. Campbell, Clarkson UniversityJ. J. Wenskus, Eastman Kodak Company

•Easy and Quick Method for the Measurement of Fibre Orientation 1790W. Michaeli, M. Heber, Institut fur Kunststojfverarbeitung

•Calculation of Fibre Orientation for Complex SMC Parts 1794W. Michaeli, M. Heber, Institut fiir Kunststojfverarbeitung

•Evaluation of the Influence of the Geometrical Parameters on the MechanicalProperties of Thermoplastic Flanges Using FEA 1798W. Michaeli, G. Aengenheyster, D. Jurss, Institut fur Kunststojfverarbeitung

•Describing Poisson's Ratio of Thermoplastics as a Non-Linear ViscoelasticMaterial Parameter 1804W Michaeli, J. Dassow, Institut fur Kunststoffverarbeitung

•Impact Characterization of RIM Composites Based on Key ParametersDerived from Automotive Exterior Applications 1808K. J. Wang, H.-J. Sue, J. W. Berg, The Dow Chemical CompanyDow Rheology Index (DRI) For Insite Technology Polyolefins (ITP):Unique Structure-Processing Relationships 1814S. Lai, T. A. Plumley, T. I. Butler, G. W. Knight, C. I. Kao, The Dow Chemical CompanyExperimental Factors in Measurement of Elongational ViscosityUsing Lubricated Squeezing 1816T. C. Hsu, I. R. Harrison, The Pennsylvania State UniversityPolymer Melt Lubricated Flow Elongational Rheometry 1819A. Pendse, J. R. Collier, H. C. Kim, Y. W. Lo, Louisiana State UniversityMaterial Characterization Relevant to the Numerical Simulation of BlowMolding and Thermoforming 1824M. E. Ryan, A. Garcia-Rejon, State University of New York at BuffaloPressure, Volume and Temperature (PvT) Apparatus forComputer Simulations in Injection Molding 1831S. M. Bhatt, S. P. McCarthy, University of Massachusetts at LowellAn Inverse Model for Thermal Residual Stresses in Injectionand Compression Molding 1834Y. Farhoudi, M. R. Kamal, McGill University

*Present in a joint session.

XXiY/ANTEC '94

Biofibers as Reinforcing Fillers in Thermoplastic Composites 1840J. P. Schneider, G. E. Myers, C. M. Clemons, B. W. English, USDA Forest ServiceWear/Abrasion Behavior of Recycled Plastic Lumber 1846M. A. El-Rahman, W. Lee, R. Cannaday, C. L. Beatty, University of FloridaTSC of S/B Block and Random Copolymers with Ground Rubber Tire Particles 1850D. M. Bennett, Z. Li, C. L. Beatty, University of FloridaFlexural Fatigue Study of Commingled Recycled Plastics 1852S. G. Yang, D. Bennett, C. L. Beatty, University of FloridaFlexural Fatigue Resistance of Recycled HDPE 1855S. G. Yang, D. Bennett, C. Beatty, University of FloridaWear/Abrasion Studies of Styrene-Butadiene Block CopolymerContaining Recycled Rubber 1858Z. Li, M. El-Rahman, C. L. Beatty, University of FloridaApplication of Fractography to Recycled Plastic Post Failure 1863Z. Chen, J. J. Mecholsky, D. K. Jones, C. L. Beatty, University of FloridaThe Kinetics of the Swelling of Ground Rubber Tire Particles 1865T. M. Joseph, Z. Li, C. L. Beatty, University of FloridaThe Measurement of Thermal Diffusivity in Recycled Plastic Lumberthrough the Utilization of Liquid Crystal Laminates 1867T. M. Joseph, C. L. Beatty, University of FloridaRheomolding—A New Process to Mold Polymeric Materials. Part H: Applications 1869J. P. Ibar, Solomat Rheomolding DivisionCharacterization of Recycled Commingled Plastic Lumber 1870A. J. Hill, M. D. Zipper, Monash UniversityT. J. Bastow, CSIROC. L. Beatty, University of FloridaRecycled Plastic Panels and Perforated Scrap Zinc Sheets for CorrosionProtection of Steel Reinforcing Bars in Marine Concrete Structures 1875R. G. Powers, I. R. Lasa, R. J. Kessler, Florida Department of Transportation

THERMOPLASTIC MATERIALS & FOAMS DIVISION

•Maximizing Weld Strength Utilizing a Reversible Transient Flow 1880W. H. Walker, The Pennsylvania State University-Erie, The Behrend College

•Die Swell of Viscoelastic Polymers 1885P. Santelices, University of Massachusetts at Lowell

•Phase Behavior of Triblock Terpolymers Possessing the Lamellar Morphology 1888L. Kane, North Carolina State University

•Rheological Properties of Unconventional Thermoplastic Engineering Alloys 1891W. P. Benoit II, The University of Massachusetts at Lowell

•The Effect of Molecular Weight on Melt Index 1895K. S. Shick, The Pennsylvania State University-Erie, The Behrend College

•The Effects of Colorants on the Shrinkage of Polyester 1904C. J. Neubert, The Pennsylvania State University-Erie, The Behrend College

•The Effects of Drying Time on Hydroscopic Polymers 1908J. Dunham, University of Massachusetts at Lowell

•The Application of the Hartmann Equation of State to Polymer Liquid Crystals 1911K. Wolyniec, University of North Texas

•Examining the Properties of Recycled 46 Polyamide 1914R. E. Hieber, The Pennsylvania State University-Erie, The Behrend College

•Investigation of the Effects of Molding Pressure onCompression Molded PTFE Parts 1918J. M. Barboza, The University of Massachusetts at Lowell

•Evaluation of the Transverse Flexure Test for Studying Interfacial BondStrength in Thermoplastic Composites 1922M. Vassy, Clemson University

*Present in a joint session.

ANTEC '94/XX\

•Incremental Properties of Reinforced Elastomers 1924A. R. Bhogesara, The University of Massachusetts at Lowell

•Cold Effects on the Impact Sensitivity of Polyethylene 1928T. R. Clyburn, The Pennsylvania State University-Erie, The Behrend CollegePerspectives on Cellular Materials; from Synthetic FoamCushions to the Human Lungs 1934L. C. Rubens, Michigan Molecular InstituteComputer Simulation of Polyurethane Foam Reactions Using Material andEnergy Balance Calculations 1941N. S. Ramesh, N. Malwitz, Sealed Air CorporationAn Approximate Cell-to-Cell Diffusion Model for Polyethylene Foam 1946D. Kundu, C. Princell, IMCOAA. Haji-Sheikh, University of Texas at ArlingtonA Comparison of the Microcellular Processing of Semi-Crystalline andAmorphous Poly(ethylene terephthalate) 1951D. F. Baldwin, N. P. Suh, Massachusetts Institute of TechnologyC. B. Park, University of TorontoManufacturing of Polybutylene Insulation Foam 1959D. Kundu, C. Princell, IMCOAC. C. Hwo, C-Y. Ma, S. A. Nulf, Shell Development CompanyInert Gases as Alternative Blowing Agents for Extruded Low-DensityPolystyrene Foam 1964C. Jacob, S. K. Dey, Polymer Processing InstituteEthylene Methyl Acrylate Copolv mers for Flexible Packaging Applications 1968L. K. Johnson, Quantum Chemical CompanyEffect of CO2 Saturation and Desorption on the NotchSensitivity of Polycarbonate Fatigue 1972K. A. Seeler, Lafayette CollegeV. Kumar, University of WashingtonPropylene-Butene Random Copolymers for Film Application 1977A. M. Chatterjee, R. N. Campbell, Shell Development CompanyMicroscopic Structure of Recycled EPS Foam 1984L. Hornberger, T. Pirie, N. Mohareb, T. Hight, Santa Clara UniversityHydrolysis Resistant Thermoplastic Polyesters 1988R. R. Gallucci, D. G. Hamilton, GE PlasticsMore Experiments on Thermoplastic Foam Nucleation 1992S.-T. Lee, Sealed Air CorporationProperties and Applications of Polyurethane-Series Shape Memory Polymer 1998S. Hayashi, S. Kondo, C. Giordano, Mitsubishi Heavy Industries, Ltd.Preparation of Epoxy-Modified Polyethylene and Its Application inPolyphenylene Sulflde Alloys 2002C. M. Chen, H. R. Lee, S. Y. Wu, C. P. Chen, H. C. Kao, Union Chemical Laboratories, ITRIPPS/Functionalized SEBS Blends: Effect of Compatibility andViscosity on Morphology 2007C. P. Chen, H. R. Lee, C. M. Chen, W. J. Chen, H. C. Kao,

Industrial Technology Research InstituteA Study of the Kinetics of the Decomposition of2,5-Dimethyl-2,5-DI(t-butylperoxy)Hexane in Polyolefins 2011J. D. McCullough, Jr., M. S. Rodriguez, Shell Development CompanyRecent Advances in the Processing and Applications of High Nitrile Resins 2019P. R. Lund, BP Chemicals

PLASTICS ANALYSIS DIVISION

Chromatography of Plastics Additives 2024R. Miller, Eastman Chemical Company

*Present in a joint session.

XXVl/ANTEC '94

The Use of Advanced Characterization Techniques in Evaluating theFitness-for-Use of Long-Glass Fiber Thermoplastics 2029M. P. Sepe, Dickten & Masch Mfg. Co.Thermo-Optical Apparatus for Characterizing Phase Transitions inPolymer Solutions and Blends 2038D. J. Moonay, R.-J. Wu, M. T. Shaw, University of ConnecticutCharacterization of Controlled-Degradation Polypropylene 2041C. Chen, B. Sanschagrin, Ecole Polytechnique de MontrealK. T. Nguyen, L. Piche, Industrial Materials InstituteA Method for the Measurement of Internal Stresses in LaminatedComposites: The Successive Grooving Technique 2045W. J. Yu, P. Sunderland, J.-A. E. Manson, Ecole Polytechnique Federate de LausanneApplication of a Nonlinear Viscoelastic Model to the Constitutive Behaviorof Glassy Polymers 2052R. A. Crook, A. Letton, Texas A&M UniversityThe Effect of Die Surface Characteristics on Processing Additive Performance 2059D. E. Priester, E. I. du Pont de Nemours and CompanyPhysical Aging of Nylon 66 2063I. Spinu, G. B. McKenna, National Institute of Standards and TechnologyThe Effect of Endgroups and Molecular Weight on the ThermalAging of Polycarbonate Resins 2067D. G. LeGrand, B. McKinley, P. McCloskey, D. Dardaris, J. Caraher, General ElectricS. Morgan, K. Snow, P. Sybert, GE PlasticsProbing Aging and Rejuvenation in the Nonlinear Viscoelastic Range 2071W. K. Waldron, Jr., G. B. McKenna, National Institute of Standards and TechnologyM. M. Santore, Lehigh UniversityConformational Changes and Physical Aging in Bisphenol-A Polycarbonate:Origins of Mechanical Properties 2077V. Stolarski, A. Letton, E. Nour, J. Laane, Texas A&M UniversityMolecular Modeling of Polymer Melts and Alloys 2082J. G. Curro, Sandia National LaboratoriesThermodynamic Properties of Semi-Flexible Polymer Blends from Simulation 2087J. D. Weinhold, S. K. Kumar, The Pennsylvania State UniversitySpecific Interactions Which Stabilize Polymer Blends: Insights fromMolecular Modeling 2092S. Fitzwater, Rohm and Haas CompanyAggregation in Polymer Brushes 2097D. Gersappe, M. Fasolka, A. C. Balazs, University of PittsburghS. H. Jacobson, Hoechst-Celanese CorporationPhase Behavior of Polymer Fluids in Bulk and Constrained Environments 2101I. Szleifer, H. Tang, Purdue UniversityS. Kumar, The Pennsylvania State UniversityModeling of the Transport of Carbon Dioxide through Polymers 2105J. Bicerano, D. J. Moll, The Dow Chemical CompanyA. R. K. Ralston, University of Wisconsin-MadisonMiscibility Behavior of Rubber Blends 2110K. Ding, B. Williams, N. S. Murthy, Allied Signal Inc.A Micro-Mechanical Model of Dimensional Recovery in a Composite Layer 2116M. Y. M. Chiang, G. B. McKenna, National Institute of Standards and TechnologyJ. Yuan, AT&T Bell LaboratoriesFluorine-Containing High Performance Polymers for Membrane-Based Gas Separations 2122W. J. Koros, The University of TexasOrgano-Soluble Segmented Rigid-Rod Polyimide Films: AnisotropicStructure and Properties 2124F. E. Arnold, Jr., D. Shen, F. W. Harris, S. Z. D. Cheng, The University of AkronInfluence of CF3-Groups on the Thermal Stability of 5-MemberedHeteroaromatic Units in Aromatic Polyethers 2129G. Maier, R. Hecht, J. M. Schneider, O. Nuyken, Technische Universitat Munchen

ANTEC '94 /xxvi i

Fluoropolymers in Gas Sensing Devices 2134C. Feger, IBM-T. J. Watson Research CenterM. Osterfeld, H. Franke, Universitat Duisburg

•Characterization of Linear Low Density Polyethylene by TemperatureRising Elution Fractionation and by Differential Scanning Calorimetry 2138J. J. Mara, Chevron Chemical CompanyK. P. Menard, Perkin-Elmer Corporation

•Creep Data for Gapex™ Polypropylene Products via DMA Method 2142A. D. McMaster, Ferro CorporationD. Chundury, Ferro Corporation

•Determination of the Effects of Moisture on Nylon 2146W. J. Sichina, A. Bizet, Seiko Instruments Inc.

•Prediction of Heat Stabilizer Consumption in PE, PP, PS and PVC byFluorescence Reflectometry 2151P. Breant, Elf Atochem/CerdatoC. H. Stapfer, Metrastat PSD

•Thermal Conductivity of Polymers, Glasses & Ceramics by Modulated DSC 2156J. A. Foreman, S. M. Marcus, R. L. Blaine, TA InstrumentsFluorinated Aromatic Polyesters 2162P. E. Cassidy, J. W. Fitch, V. S. Reddy, B. Lunceford, D. Person,

Southwest Texas State UniversityA High Performance Photosensitive Polyimide Based on aBPDA/PDA/6FDAm Copolymer 2165M. Angelopoulos, J. Gelorme, IBM—T. J. Watson Research CenterS. Swanson, J. Labadie, IBM—Almaden Research CenterRefractive Index in Aromatic Polyimides 2170D. C. Rich, P. Cebe, Massachusetts Institute of TechnologyA. K. St. Clair, NASA Langley Research CenterMultilayered Structures with Metal Cations Based on LB Films ofIon-Exchange Perfluorinated Polymer 2174B. V. Mislavsky, R. G. Yusupov, Russian Academy of SciencesN. S. Maslova, Y. N. Moiseev, S. V. Savinov, Moscow State UniversityD. A. Znamensky, A. Y. Rozhkov, Center of Surface and Vacuum PropertiesInteraction of Organic Solvents with Fluoropolymers 2178T. M. Aminabhavi, H. T. S. Phayde, Kamatak UniversityApproaches to Improve the Toughness of IP 960 Polyimide Thermoset. A Comparative Study 2184T. Pascal, F. Bertholio, M. Senneron, B. Laguitton, B. Sillion, UMR 102 CNRS-IFPApplication of Thermosetting Cure Diagrams 2192S. L. Simon, J. K. Gillham, Princeton UniversityEffect of Physical Blowing Agents on Crystallization Temperatureof Polymer Melts 2197S. K. Dey, C. Jacob, J. A. Biesenberger, Polymer Processing InstituteAnalysis of Butyl Acrylate Diffusion in a Polystyrene Matrix in the GradientPolymer Formation Region 2199C. F. Jasso-Gastinel, J. Valdez-Ortiz, J. H. Perez-Lopez, Universidad de GuadalajaraO. Laguna-Castellanos, Instituto de Ciencia y Tecnologia de PohmerosChanges of Mechanical Properties for Loose Tubes underVarious Strains after Thermal Aging 2203H.-F. Lin, C.-H. Hsieh, S.-I. Wang, H.-P. Hsu, K.-Y. Chen, Telecommunication LabsMaterial Wear Resistance Quantification 2208J. E. Hoge, R. Eadara, D. Dahl, Ciba-Geigy CorporationRecent Developments in On-Line Analytical TechniquesApplicable to the Polymer Industry 2214S. H. Patel, D. B. Todd, M. Xanthos, Polymer Processing InstituteIn-Line Monitoring of Molten Polymers NIR Spectroscopy, Robust Probesand Rapid Data Analysis 2220M. G. Hansen, A. Khettry, University of Tennessee

*Present in a joint session.

xwiii/ANTEC '94

Quantitative Near-Infrared Monitoring of Polyethylene-PolypropyleneMelt Blending 2227M. Bains, R. Reshadat, R. Lew, W. R. Cluett, S. T. Balke, University of TorontoJ. W. Hall, NIRSystems, Inc.In-Line Monitoring of Titanium Dioxide Content in Polyethylene Terephthalate Extrusion 2232J. Batra, M. G. Hansen, The University of TennesseeUltrasonic Measurement of Polymer Material Properties during Injection Molding 2236C. L. Thomas, A. O. Adebo, Drexel UniversityA. J. Bur, National Institute of Standards and TechnologyMeasuring Thermal Conductivity under High Pressures 2240F. Oehmke, T. Wiegmann, SWO Polymertechnik GmbHThe Effect of Pressure on the Crystallization Kinetics of Poly(ethylene terephthalate) 2243A. Y. Provost, B. Sanschagrin, Ecole Polytechnique de MontrealK. T. Nguyen, R. Connolly, Industrial Materials InstituteMeasuring PVT Curves at High Cooling Rates 2247F. Oehmke, T. Wiegmann, SWO Polymertechnik GmbHCharacterization of Blown Film Morphology 2252H. Fruitwala, P. Shirodkar, Mobil Chemical CompanyThe Use of a Five Color Scale to Quantify Distributive Mixing in a Miscible System 2257W. Bairn, D. Bigio, University of MarylandCombined Thermal, Rheological, Optical and Mechanical Analysisof Ethylene Copolymers 2261L. Woo, T. K. Ling, S. P. Westphal, Baxter HealthcareEffect of Thermomechanical History in the Melt on the CrystallizationKinetics of Isotactic Polypropylene 2266J. C. Michel, Montefina S.A.A Novel Technique for Measuring Strains in Thin Films under Biaxial Conditions 2272M. A. Said, Wallops Flight FacilityUse of DMA and DSC to Optimize the Processing of ElectronicEncapsulation Materials 2276H. Mallela, Teccor Electronics Inc.M. Davis, K. Menard, The Perkin-Elmer CorporationAnalysis of Polyolefin Blends by Differential Scanning Calorimetry:Detectability of Polypropylene in High Density Polyethylene-Polypropylene Blends 2281T. Weeks, M. Zoriu, J. D. McCoy, New Mexico Institute of Mining and TechnologyJ. Deporter, Phillips Petroleum CompanyJ. Curro, Sandia National LabsFiller-Matrix Debonding Monitored by Tensile Test 2284A. Meddad, S. Fellahi, M. Pinard, B. Fisa, Ecole Polytechnique de MontrealEffect of Aging on the Enthalpic Relaxation of Amorphous PET 2289S. R. Sauerbrunn, R. L. Blaine, J. A. Foreman, TA Instruments, Inc.

ADVANCED POLYMER COMPOSITES DIVISION

Mechanical Properties of Long-Fiber Filled Injection-MoldedThermoplastic Composites 2294V. K. Stokes, L. P. Inzinna, G. G. Trantina, E. W Liang, J. T. Woods,

General Electric Corporate Research and DevelopmentFunctional Feature-Based Approximate Structural Analysis for InjectionMolded LFRTP Part 2300T. Xu, C. Chassapis, Stevens Institute of TechnologyThe Effect of Fiber Length on the Mechanical Performance of InjectionMoldable, Long Glass Reinforced Polypropylene 2306D. A. Grove, D. E. Miller, LNP Engineering Plastics Inc.Optimizing Injection Molding Parameters to Maximize Impact Strengthof Long Fiber Thermoplastics 2311E. V. Lee, L. J. Pitzner, T. A. Regan, Polymer Composites, Inc.Three-Dimensional Fiber Orientation Distributions in Injection-Molded,Short Fiber-Reinforced Thermoplastics 2316B. Lian, J. Ladewig, J. M. Wille, J. J. McGrath, Michigan State University

ANTEC '94/XXix

In situ FDEMS Sensing and Model Verification of Resin Position, Viscosity andDegree of Cure for Resin Transfer Molding of Textile Preforms 2322A. C. Loss, V. H. Hammond, Virginia Polytechnic Institute and State UniversityD. E. Kranbuehl, D. Hood, S. Mahoney, W. Limburg, College of William and MaryG. H. Hasko, Lockheed Engineering and Sciences CompanyDeposition Model for Electrostatic Fluidized Bed Powder Coating 2329M. A. DeBenedictis, J. D. Muzzy, Georgia Institute of TechnologyPMR-15 Composites Produced from Powder-Coated Towpreg 2333J. A. Dugger, D. E. Hirt, Clemson UniversityFabric Reinforced Thermoplastics—Towards a Simulationof the Forming Process 2337W Michaeli, A. Biswas, Institut fur KunststoffverarbeitungThe Composite Disc—A Slide Rule for Laminate Predimensioning 2342W. Michaeli, M. Wegener, D. Huybrechts, Institut fur KunststoffverarbeitungKnowledge- and Case-Based Computer Support for the Design of Composite Parts 2347W. Michaeli, A. Biswas, Institut fur KunststoffverarbeitungImpact Responses of Gradient Designed Textile Structural Compositesunder Low and High Impact Velocities 2352J. Z. Yu, C. Lei, F. K. Ko, Drexel UniversityA Study of Polyacrylonitrile-Based Quasi-Carbon Fibers and Their Composites 2358L. R. Zhao, J. L. Zhou, B. Z. Jang, Auburn UniversityPseudo-Laminate Analysis of Long Fiber Composites 2362A. Farouk, T. Davidson, The Stevens Institute of TechnologyA Novel Approach to Visualization of Acousto-Ultrasonic Data 2366D. L. Fecko, K. V. Steiner, J. W. Gillespie, University of DelawareEffect of Tensile Deformation on the Electrical Resistivity of CarbonWhisker Reinforced Thermoplastic Elastomer Composites 2371V. Chellappa, Z. W. Chiou, B. Z. Jang, Auburn UniversityThe Effects of Crosslink Density on Microcracking in High-TemperatureLaRC RP46T Composites 2376B. D. Potter, F. G. Yuan, North Carolina State UniversityR. H. Pater, NASA Langley Research CenterHygrothermal Stability of Graphite Fiber/Epoxy Interface 2382D. W. Sohn, Q. Zhou, N.-H. Sung, Tufts UniversityPlasma Treatment of Glass Fibres for Fibre Reinforced Plastics 2386W. Michaeli, M. Stollenwerk, F. Steinkamp, Institut fur KunststoffverarbeitungMorphological Aspects of the Beta Transcrystalline Interphase inGlass Reinforced Polypropylene 2390A. Lustiger, C. N. Marzinsky, R. R. Mueller, H. D. Wagner, Exxon Research and Engineering CompanyDurability of Glass Fiber/Polymer Composites 2394C. L. Schutte, M. McAuliffe, National Institute of Standards and TechnologyFatigue Behavior of Quasi-Isotropic Laminate of Carbon Fiber ReinforcedPolyetheretherketone (PEEK) Composites. (I) Residual Strength underTension-Tension Loading 2398C.-C. M. Ma, N.-H. Tai, S. H. Wu, S. H. Lin, J. F. Wu, National Tsing Hua UniversityC. L. Ong, Y. C. Wu, M. F. Sheu, Chung Shan Institute of Science & TechnologyCreep Behavior of [ ± 45]4S Laminated Carbon Fiber ReinforcedPolyetheretherketone (PEEK) Composites (I) 2405C.-C. M. Ma, N.-H. Tai, S. H. Wu, S. H. Lin, F. J. Wu, National Tsing Hua UniversityC. L. Ong, I. C. Wu, M. F. Sheu, Chung Shan Institute of Science & TechnologyThe Influence of Carbon Fiber Surface Treatment on the Mechanical Propertiesof Unidirectional Carbon/Carbon Composites 2411C.-C. M. Ma, N.-H. Tai, W.-C. Chang, C.-K. Fang, H.-T. Chao, National Tsing Hua University

ALLOYS & BLENDS SPECIAL INTEREST GROUP

Structure-Properties Relationships in PP/LLDPE Blends 2418A. J. Muller, C. Latorre, G. Mendez, J. Rotino, J. L. Rojas, Grupo de Polimeros USBBlends of LLDPE and Polystyrene for Film Applications 2423K. Sato, R. Saetre, J. Taylor, D. L. Cooke, Novacor Chemicals Ltd.

xxx/ANTEC '94

Melt Blending of Linear Low Density Polyethylene and Polystyrene—Effectsof Processing Conditions, Composition, and Compatibilizers upon Morphology Development 2428L. Y. Yang, T. G. Smith, D. Bigio, University of MarylandMixing Effect in Liquid Crystal Polymer Reinforced PolyethyleneBlends for Thin Film Application 2433T. C. Hsu, K. Meechumnarn, I. R. Harrison, The Pennsylvania State UniversityPolyblends of High-Density Polyethylene with Butyl Rubber 2436R. D. Deanin, R. K. Datta, University of Massachusetts at LowellImpact Modification of Polypropylenes with EXACT™ Plastomers 2439T. C. Yu, Exxon Chemical Company

•Characterization of Linear Low Density Polyethylene by TemperatureRising Elution Fractionation and by Differential Scanning Calorimetry 2138J. J. Mara, Chevron Chemical CompanyK. P. Menard, Perkin-EImer Corporation

•Creep Data for Gapex™ Polypropylene Products via DMA Method 2142A. D. McMaster, Ferro CorporationD. Chundury, Ferro Corporation

•Determination of the Effects of Moisture on Nylon 2146W. J. Sichina, A. Bizet, Seiko Instruments Inc.

•Prediction of Heat Stabilizer Consumption in PE, PP, PS and PVC byFluorescence Reflectometry 2151P. Breant, Elf Atochem/CerdatoC. H. Stapfer, Metrastat PSD

•Thermal Conductivity of Polymers, Glasses & Ceramics by Modulated DSC 2156J. A. Foreman, S. M. Marcus, R. L. Blaine, TA Instruments

•Miscibility Characterization of High Tg Polyester and Polycarbonate Blends 1614H. E. Yang, Eastman Chemical Company

•Crystallinities in Blends of Branched Fractions of Polyethylene 1619P. J. Phillips, K. Monar, The University of Tennessee

•Structure/Property Relationships in Flame Retarded Polycarbonate 1622S. R. Seibel, E. Papazoglou, FMC Corporation

•Experimental Determination of Process Optimizations When CompoundingFiberglass Reinforced, Flame Retarded PBT on the Co-Rotating Twin Screw Extruder 1626E. Beecher, J. Grillo, Werner & Pfleiderer CorporationE. Papazoglou, S. Seibel, FMC Corporation

•Positively Charged Polyethersulfone Microporous Membrane 1632H. Hu, Gelman Sciences Incorporated

•Pore and Permeability of Various Filter Media 1635K.-J. Choi, Fleetguard, Inc.

•Polymeric Filtration System for Viscous Polymer Solutions 1638C. B. Wang, Eastman Chemical CompanyVisualization of Morphology Development in Polymer Blends 2448U. Sundararaj, Y. Dori, C. W. Macosko, University of Minnesota—Twin CitiesUltrasonic Behavior of Polymer Blends 2452R. Gendron, J. Tatibouet, J. Guevremont, M. M. Dumoulin, L. Piche, Industrial Materials InstituteRheology and Morphology of High Density Polyethylene and Nylon-11 Blends 2457U. Patel, S. N. Bhattacharya, R. A. Shanks, RMIT UniversityPercolation Model for Modulus of Nylon 6/Nylon 6IcoT Blends 2461Y. Liu, J. A. Donovan, University of MassachusettsTransparent Polycarbonate Polyethylene Terephthalate Blends 2466J. P. Mason, Miles Inc.Effect of Compatibilizer on Fatigue Properties of PC/PS Blends 2469K. Mimura, H. Hristov, A. F. Yee, The University of MichiganCompatibilization of Aromatic Liquid Crystal Polymers and Their Blendswith Thermoplastics 2472M. J. Stachowski, A. T. DiBenedetto, University of Connecticut

'Present in a joint session.

ANTEC '94/xxxi

A Miscibility Study of Innovative High Heat Acrylic (HHA) with Standard Acrylic 2477A. P. W. Clelland, J. J. Shen, ICI Acrylics Inc.Fully and Semi-Interpenetrating Polymer Networks Based on Epoxy and Acrylics 2481M.-S. Lin, S.-T. Lee, National Chiaoo-Tung UniversityEffects of Component Behavior and Concentration on Filled Thermoplastics Properties 2488G. Z.-H. Shi, C. Nedea, DOMCO Industries LimitedBeneficial Effects of Fiber Glass in PP/PS Alloys 2494M. Huang, D. Done, C. Wei-Berk, HimontFracture Resistance of Unreinforced and Glass Fiber Reinforced Nylon/ABS Alloys 2499S. C. Wong, S. V. Nair, L. H. Vestergaard, University of MassachusettsL. A. Goettler, L. A. Gustafson, Monsanto CompanyRole of Rubber Particles and Internal Interfaces on the Fracture Resistance ofUnreinforced and Glass Fiber Reinforced PC/ABS Blends 2503L. H. Vestergaard, S. V. Nair, M. L. Shiao, University of MassachusettsL. A. Goettler, L. A. Gustafson, Monsanto Company

VOLUME III—SPECIAL AREASCOLOR & APPEARANCE DIVISION

Coloring of a Novel Polypropylene/Polystyrene Alloy 2508K. T. Okamoto, M. C. T. Huang, P. A. McGrath, Himont U.S.A., Inc.R. M. Harris, PMS ConsolidatedThe Performance of Titanium Dioxide Pigments in Masterbatch Applications 2514C. L. Watson, Tioxide Group PicG. Decelles, Tioxide Canada Inc.Measurement of Gloss and Reflection Properties of Surfaces 2518G. Kigle-Boeckler, BYK-Gardner, Inc.The Effect of Carbon Black Morphology on the Viscosity andLetdown Performance of the Carbon Black Masterbatch 2524M. C. Yu, J. Menashi, D. J. Kaul, Cabot CorporationCadmium Free Colored Engineering Plastics for the Automotive Industry 2529B. M. Mulholland, Hoechst-Celanese CorporationKnit Lines in Aesthetic Outdoor Acrylonitrile-Styrene-Acrylate Applications 2537J. McGuire, C. Azzopardi, BASF Corporation Plastic MaterialsCadmium, Lead, Mercury and Hexavalent Chromium Free Color forMPFP (Melt Processable Fluoropolymers) 2542S. Parikh, L. Creed, ICI FluoropolymersChemiluminescence in Evaluating the Thermal Oxidative Stability ofABS and ABS/Polycarbonate Blends 2546S. S. Parikh, Monsanto Chemical CompanyL. Zlatkevich, Custom Scientific Instrument

AUTOMOTIVE DIVISION

Aging of Glass Fiber Reinforced Nylon 6,6 in Automobile Underhood Parts 2552D. M. Bigg, BattelleV. Kanellopoulos, Battelle EuropePermeability Comparisons of Fabrics Used in Airbag Construction 2556R. Keshavaraj, R. W. Tock, Texas Tech UniversityG. Nusholtz, Chrysler MotorsDurability of Multilayer Coated Thermoplastic Olefins in thePresence of Steep Temperature Gradients 2560S. Shah, S. Srinivasan, E. Szczepaniak, D&S Plastics InternationalR. A. Ryntz, Ford Motor CompanyThe Effect of Gate Location on Stiffness of Automotive Accelerator Pedal 2565B. A. Mathew, Nylon Corporation of AmericaG. Crippa, STP Tecnopolimeri SpaG. Molina, Centro Ricerche Fiat

xxxii/ANTEC '94