PICKLINOX G2 - market.varjenje.net · Romania Regulatory reference Legea 319/2006 privind...

PICKLINOX G2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Date of issue: 24/07/2009 Revision date: 13/07/2018 Supersedes: 24/04/2018 Version: 4.0

17/07/2018 EN (English) SDS Ref.: WL-0039 1/12

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Mixture

Product name : PICKLINOX G2

Product code : WL-0039

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified uses

Main use category : Metal surface treatment products, including galvanic and electroplating products

Industrial/Professional use spec : For professional use only Industrial

Function or use category : Welding and soldering agents

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

Lincoln Electric Europe S.L. Calle Balmes, 89 8th floor, 2a 08008 Barcelona - SPAIN T +34 93 492 20 00 [email protected] - www.lincolnelectric.eu

1.4. Emergency telephone number

Emergency number : +33 1 45 42 59 59 (INRS)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II)

Acute toxicity (oral), Category 4 H302

Acute toxicity (inhalation:dust,mist) Category 4

H332

Skin corrosion/irritation, Category 1A H314

Serious eye damage/eye irritation, Category 1

H318

Full text of H statements : see section 16

Adverse physicochemical, human health and environmental effects


2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display

Hazard pictograms (CLP) :

GHS05

GHS07

Signal word (CLP) : Danger

Hazardous ingredients : ammonium bifluoride; nitric acid ... %

Hazard statements (CLP) : H302+H332 - Harmful if swallowed or if inhaled H314 - Causes severe skin burns and eye damage.

Precautionary statements (CLP) : P260 - Do not breathe dust, fume, gas, spray, vapours. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P314 - Get medical advice/attention if you feel unwell. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

mailto:[email protected]

www.lincolnelectric.eu




2.3. Other hazards


SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable

3.2. Mixtures

Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]

nitric acid ... %

(CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1 (REACH-no) 01-2119487297-23-XXXX

13,75 - 20 Ox. Liq. 3, H272 Met. Corr. 1, H290 Acute Tox. 3 (Inhalation:vapour), H331 Skin Corr. 1A, H314

ammonium bifluoride


6,5 - 9,5 Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314

Specific concentration limits:

Name Product identifier Specific concentration limits

nitric acid ... % (CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1 (REACH-no) 01-2119487297-23-XXXX

( 5 =<C < 20) Skin Corr. 1B, H314 (C >= 20) Skin Corr. 1A, H314 ( 65 =<C < 99) Ox. Liq. 3, H272 (C >= 99) Ox. Liq. 2, H272

ammonium bifluoride (CAS-No.) 1341-49-7 (EC-No.) 215-676-4 (EC Index-No.) 009-009-00-4 (REACH-no) 01-2119489180-38-XXXX

( 0,1 =<C < 1) Eye Irrit. 2, H319 ( 0,1 =<C < 1) Skin Irrit. 2, H315 (C >= 1) Skin Corr. 1B, H314

Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Get immediate medical advice/attention.

First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse immediately with plenty of water for 15 minutes. Get immediate medical advice/attention.

First-aid measures after eye contact : Rinse immediately with plenty of water. Get immediate medical advice/attention.

First-aid measures after ingestion : Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/effects : Causes severe burns.

Symptoms/effects after skin contact : Causes severe burns.

Symptoms/effects after eye contact : Causes serious eye damage.

Symptoms/effects after ingestion : May be harmful if swallowed.

4.3. Indication of any immediate medical attention and special treatment needed


SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Carbon dioxide. Dry powder. Water spray.

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition products in case of fire

: May release hazardous fumes. Hydrogen fluoride.

5.3. Advice for firefighters

Firefighting instructions : Cool closed containers exposed to fire with water spray. Do not enter fire area without proper protective equipment, including respiratory protection.

Protection during firefighting : Wear recommended personal protective equipment.

Other information : Do not remove damaged packages. Move only undamaged packages out of fire zone.




SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Safety glasses with face shield. Gloves. Use self-contained breathing apparatus and chemically protective clothing.

6.1.1. For non-emergency personnel

Emergency procedures : Ventilate spillage area. Do not touch or walk on the spilled product.

6.1.2. For emergency responders


6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

For containment : Stop leak without risks if possible. Place in a suitable container for disposal in accordance with the waste regulations (see Section 13).

Methods for cleaning up : Neutralize with : Bases. Bicarbonate. Collect spills and put it into appropriated container. Do not use : Sand.

6.4. Reference to other sections

See Heading 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Additional hazards when processed : May be corrosive to metals. Provide local exhaust or general room ventilation.

Precautions for safe handling : Avoid contact with skin, eyes and clothing. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not breathe vapours.

Hygiene measures : Do not eat, drink or smoke when using this product.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Keep container closed when not in use. Keep container in well ventilated place. Keep only in the original container in a cool, well ventilated place away from : Heat sources.

Incompatible materials : Metals.

Storage area : Store in a well-ventilated place. Store away from heat.

Special rules on packaging : Keep only in original container.

7.3. Specific end use(s)

Not applicable.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

PICKLINOX G2

EU Local name Nitric acid

EU IOELV STEL (mg/m³) 2,6 mg/m³

EU IOELV STEL (ppm) 1 ppm

EU Regulatory reference COMMISSION DIRECTIVE 2006/15/EC

Czech Republic Local name Kyselina dusičná

Czech Republic Expoziční limity (PEL) (mg/m³) 1 mg/m³

Czech Republic Expoziční limity (PEL) (ppm) 0,39 ppm

Czech Republic Expoziční limity (NPK-P) (mg/m³) 2,5 mg/m³

Czech Republic Expoziční limity (NPK-P) (ppm) 1 ppm

Czech Republic Remark (CZ) I (dráždí sliznice (oči, dýchací cesty) resp. kůži)

Czech Republic Regulatory reference Nařízení vlády č. 361/2007 Sb. (zapracovány změny č. 93/2012 Sb., 9/2013 Sb.)

France Local name Acide nitrique

France VLE (mg/m³) 2,6 mg/m³

France VLE (ppm) 1 ppm

France Note (FR) Valeurs règlementaires indicatives

France Regulatory reference Arrêté du 30 juin 2004 modifié (réf.: INRS ED 984, 2016)

Germany Local name Salpetersäure

Germany TRGS 900 Occupational exposure limit value (mg/m³) 2,6 mg/m³




PICKLINOX G2

Germany TRGS 900 Occupational exposure limit value (ppm) 1 ppm

Germany Remark (TRGS 900) EU;13;16

Germany Regulatory reference (TRGS900) TRGS900

Italy Local name Acido nitrico

Italy OEL STEL (mg/m³) 2,6 mg/m³

Italy OEL STEL (ppm) 1 ppm

Italy Regulatory reference Allegato XXXVIII del D.Lgs. 9 aprile 2008, n. 81 e s.m.i.

Netherlands Local name Salpeterzuur

Netherlands Grenswaarde TGG 15MIN (mg/m³) 1,3 mg/m³

Netherlands Regulatory reference Arbeidsomstandighedenregeling 2017

Poland Local name Kwas azotowy(V)

Poland NDS (mg/m³) 1,4 mg/m³

Poland NDSCh (mg/m³) 2,6 mg/m³

Poland Regulatory reference Dz. U. 2017 poz. 1348

Portugal Local name Ácido nítrico

Portugal OEL TWA (ppm) 2 ppm

Portugal OEL STEL (ppm) 4 ppm

Portugal Regulatory reference Norma Portuguesa NP 1796:2014

Romania Local name Acid nitric

Romania OEL STEL (mg/m³) 2,6 mg/m³

Romania OEL STEL (ppm) 1 ppm

Romania Regulatory reference Legea 319/2006 privind Securitatea şi sănătatea în muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006

Slovakia Local name Kyselina dusičná

Slovakia OEL STEL (mg/m³) 2,6 mg/m³

Slovakia OEL STEL (ppm) 1 ppm

Slovakia Regulatory reference Nariadenie vlády č. 355/2006 Z. z. (Zmena: 300/2007 Z.z.; Zmena: 471/2011 Z.z.)

Spain Local name Ácido nítrico

Spain VLA-EC (mg/m³) 2,6 mg/m³

Spain VLA-EC (ppm) 1 ppm

Spain Notes VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo).

Spain Regulatory reference Límites de Exposición Profesional para Agentes Químicos en España 2018. INSHT

United Kingdom Local name Nitric acid

United Kingdom WEL STEL (mg/m³) 2,6 mg/m³

United Kingdom WEL STEL (ppm) 1 ppm

United Kingdom Regulatory reference EH40. HSE

USA - ACGIH Local name Nitric acid

USA - ACGIH ACGIH TWA (ppm) 2 ppm

USA - ACGIH ACGIH STEL (ppm) 4 ppm

USA - ACGIH Remark (ACGIH) URT & eye irr; dental erosion

USA - ACGIH Regulatory reference ACGIH 2018

USA - OSHA Local name Nitric acid

USA - OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³

USA - OSHA OSHA PEL (TWA) (ppm) 2 ppm

nitric acid ... % (7697-37-2)


EU IOELV STEL (mg/m³) 2,6 mg/m³ 2.6 (EU)


EU Notes MIS DANS LES PAYS MANUELLEMENT






nitric acid ... % (7697-37-2)


















Italy OEL TWA (mg/m³) 2,6 mg/m³

































nitric acid ... % (7697-37-2)











ammonium bifluoride (1341-49-7)


France VME (mg/m³) 2,5 mg/m³ Fluorure F-

Germany TRGS 900 Occupational exposure limit value (mg/m³) 2,5 mg/m³ F-

Netherlands Grenswaarde TGG 8H (mg/m³) 2 mg/m³

USA - ACGIH ACGIH TWA (mg/m³) 2,5 mg/m³ F-

8.2. Exposure controls

Materials for protective clothing:

Wear suitable protective clothing. EN ISO 20344

Hand protection:

Chemical resistant PVC gloves (to European standard EN 374 or equivalent). Category III

Eye protection:

Chemical goggles or face shield. Use eye protection according to EN 166, designed to protect against liquid splashes.

Skin and body protection:

Chemical resistant safety shoes. Long sleeved protective clothing. EN ISO 20344

Respiratory protection:

Do not exceed the occupational exposure limits (OEL). If these are not sufficient or impracticable, then also use a half-mask, selected in accordance with EN529. Standard EN 137 - Self-contained open-circuit compressed air breathing apparatus with full face mask. EN 138

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Appearance : Paste.

Colour : Translucent.

Odour : Pungent.

Odour threshold : No data available

pH : ≈ 1

Relative evaporation rate (butylacetate=1) : No data available

Melting point : Not applicable.

Freezing point : Not available

Boiling point : Not available

Flash point : Not applicable

Critical temperature : Not applicable

Auto-ignition temperature : <= Not applicable

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapour pressure : Not available

Relative vapour density at 20 °C : No data available

Relative density : ≈ 1,53

Solubility : No data available

Log Pow : No data available




Viscosity, kinematic : Not available

Viscosity, dynamic : No data available

Explosive properties : Not applicable.

Oxidising properties : Not available.

Explosive limits : No data available

9.2. Other information

VOC content : 0

SECTION 10: Stability and reactivity

10.1. Reactivity

Decomposes. Risk of ignition.

10.2. Chemical stability


10.3. Possibility of hazardous reactions

Reacts violently with water. May react violently with acids.

10.4. Conditions to avoid

Overheating. Protect from moisture. alcohol.

10.5. Incompatible materials

May be corrosive to metals. Strong bases. Acetone. alcohol. Reducing agent.

10.6. Hazardous decomposition products

Nitric acid. Fluorine (F). Hydrogen fluoride. ammonia. Nitrogen oxides.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Oral: Harmful if swallowed.

Acute toxicity (dermal) : Not classified

Acute toxicity (inhalation) : Inhalation:dust,mist: Harmful if inhaled.

PICKLINOX G2

LD50 oral ≈ 1368 mg/kg

LC50 inhalation rat (mg/l) ≈ 1,75

ATE CLP (dust,mist) 1,5 mg/l/4h

nitric acid ... % (7697-37-2)

LC50 inhalation rat (mg/l) > 2,6 mg/l/4h


LD50 oral rat ≈ 130 mg/kg

Skin corrosion/irritation : Causes severe skin burns and eye damage.

pH: ≈ 1

Serious eye damage/irritation : Causes serious eye damage.

pH: ≈ 1

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Acute aquatic toxicity : Not classified

Chronic aquatic toxicity : Not classified




12.2. Persistence and degradability


12.3. Bioaccumulative potential


Bioconcentration factor (BCF REACH) ≈ 0,5

12.4. Mobility in soil


12.5. Results of PBT and vPvB assessment


12.6. Other adverse effects


SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : This material and its container must be disposed of as hazardous waste.

Sewage disposal recommendations : Disposal must be done according to official regulations.

Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

14.1. UN number

UN-No. (ADR) : 3264

UN-No. (IMDG) : 3264

UN-No. (IATA) : 3264

UN-No. (ADN) : Not regulated

UN-No. (RID) : 3264

14.2. UN proper shipping name

Proper Shipping Name (ADR) : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

Proper Shipping Name (IMDG) : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

Proper Shipping Name (IATA) : Corrosive liquid, acidic, inorganic, n.o.s.

Proper Shipping Name (ADN) : Not regulated

Proper Shipping Name (RID) : Not applicable

Transport document description (ADR) : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (nitric acid ... % ; ammonium bifluoride), 8, II, (E)

Transport document description (IMDG) : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (nitric acid ... % ; ammonium bifluoride), 8, II

Transport document description (IATA) : UN 3264 Corrosive liquid, acidic, inorganic, n.o.s. (nitric acid ... % ; ammonium bifluoride), 8, II

Transport document description (RID) : UN 3264 (nitric acid ... % ; ammonium bifluoride), 8

14.3. Transport hazard class(es)

ADR

Transport hazard class(es) (ADR) : 8

Danger labels (ADR) : 8

:

IMDG

Transport hazard class(es) (IMDG) : 8

Danger labels (IMDG) : 8




:

IATA

Transport hazard class(es) (IATA) : 8

Hazard labels (IATA) : 8

:

ADN

Transport hazard class(es) (ADN) : Not regulated

RID

Transport hazard class(es) (RID) : 8

Danger labels (RID) : 8

:

14.4. Packing group

Packing group (ADR) : II

Packing group (IMDG) : II

Packing group (IATA) : II

Packing group (ADN) : Not regulated

Packing group (RID) : Not applicable

14.5. Environmental hazards

Dangerous for the environment : No

Marine pollutant : No

Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport

Classification code (ADR) : C1

Special provisions (ADR) : 274

Limited quantities (ADR) : 1l

Excepted quantities (ADR) : E2

Packing instructions (ADR) : P001, IBC02

Mixed packing provisions (ADR) : MP15

Portable tank and bulk container instructions (ADR)

: T11

Portable tank and bulk container special provisions (ADR)

: TP2, TP27

Tank code (ADR) : L4BN

Vehicle for tank carriage : AT

Transport category (ADR) : 2

Hazard identification number (Kemler No.) : 80

Orange plates :




Tunnel restriction code (ADR) : E

EAC code : 2X

APP code : B

- Transport by sea

Special provisions (IMDG) : 274

Limited quantities (IMDG) : 1 L

Excepted quantities (IMDG) : E2

Packing instructions (IMDG) : P001

IBC packing instructions (IMDG) : IBC02

Tank instructions (IMDG) : T11

Tank special provisions (IMDG) : TP2, TP27

EmS-No. (Fire) : F-A

EmS-No. (Spillage) : S-B

Stowage category (IMDG) : B

Stowage and handling (IMDG) : SW2

Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes.

MFAG-No : 154

- Air transport

PCA Excepted quantities (IATA) : E2

PCA Limited quantities (IATA) : Y840

PCA limited quantity max net quantity (IATA) : 0.5L

PCA packing instructions (IATA) : 851

PCA max net quantity (IATA) : 1L

CAO packing instructions (IATA) : 855

CAO max net quantity (IATA) : 30L

Special provisions (IATA) : A3

ERG code (IATA) : 8L

- Inland waterway transport

Not regulated

- Rail transport

No data available

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations

The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006:

3. Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008

PICKLINOX G2 - nitric acid ... %

3(b) Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10

PICKLINOX G2 - nitric acid ... %

Contains no substance on the REACH candidate list

Contains no REACH Annex XIV substances

VOC content : 0

15.1.2. National regulations

Germany

VwVwS Annex reference : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 4)

12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV

: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)




Netherlands

SZW-lijst van kankerverwekkende stoffen : None of the components are listed

SZW-lijst van mutagene stoffen : None of the components are listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding

: None of the components are listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid


NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling


Denmark

Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product

15.2. Chemical safety assessment


SECTION 16: Other information

Indication of changes:

Exposure controls/personal protection.

Abbreviations and acronyms:

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road

ATE Acute Toxicity Estimate

BCF Bioconcentration factor

CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008

DMEL Derived Minimal Effect level

DNEL Derived-No Effect Level

EC50 Median effective concentration

IARC International Agency for Research on Cancer

IATA International Air Transport Association

IMDG International Maritime Dangerous Goods

LC50 Median lethal concentration

LD50 Median lethal dose

LOAEL Lowest Observed Adverse Effect Level

NOAEC No-Observed Adverse Effect Concentration

NOAEL No-Observed Adverse Effect Level

NOEC No-Observed Effect Concentration

OECD Organisation for Economic Co-operation and Development

PBT Persistent Bioaccumulative Toxic

PNEC Predicted No-Effect Concentration

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006

RID Regulations concerning the International Carriage of Dangerous Goods by Rail

SDS Safety Data Sheet

STP Sewage treatment plant

TLM Median Tolerance Limit

vPvB Very Persistent and Very Bioaccumulative

Other information : The product must not be used for any application that is not allowed, in this case we will not be responsible for any damage caused. The user must respect current Safety, Health and Environmental legislation.

Full text of H- and EUH-statements:

Acute Tox. 3 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 3

Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3

Met. Corr. 1 Corrosive to metals, Category 1

Ox. Liq. 3 Oxidising Liquids, Category 3

Skin Corr. 1A Skin corrosion/irritation, Category 1A

Skin Corr. 1B Skin corrosion/irritation, Category 1B

H272 May intensify fire; oxidiser.

H290 May be corrosive to metals.

H301 Toxic if swallowed.

H302 Harmful if swallowed.




H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage

H331 Toxic if inhaled.

H332 Harmful if inhaled.

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product








Product name : PICKLINOX G10




Main use category : Metal surface treatment products, including galvanic and electroplating products














H332



H318




2.2. Label elements



GHS05

GHS07


Hazardous ingredients : ammonium bifluoride; nitric acid ... %

Hazard statements (CLP) : H302+H332 - Harmful if swallowed or if inhaled H314 - Causes severe skin burns and eye damage.

Precautionary statements (CLP) : P260 - Do not breathe dust, fume, gas, spray, vapours. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P314 - Get medical advice/attention if you feel unwell. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.






2.3. Other hazards



3.1. Substances

Not applicable

3.2. Mixtures


nitric acid ... %


13,75 - 20 Ox. Liq. 3, H272 Met. Corr. 1, H290 Acute Tox. 3 (Inhalation:vapour), H331 Skin Corr. 1A, H314

ammonium bifluoride


6,5 - 9,5 Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314



nitric acid ... % (CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1 (REACH-no) 01-2119487297-23-XXXX


ammonium bifluoride (CAS-No.) 1341-49-7 (EC-No.) 215-676-4 (EC Index-No.) 009-009-00-4 (REACH-no) 01-2119489180-38-XXXX





First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Get immediate medical advice/attention.

First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse immediately with plenty of water for 15 minutes. Get immediate medical advice/attention.

First-aid measures after eye contact : Rinse immediately with plenty of water. Get immediate medical advice/attention.

First-aid measures after ingestion : Obtain emergency medical attention.


Symptoms/effects : Causes severe burns.

Symptoms/effects after skin contact : Causes severe burns.

Symptoms/effects after eye contact : Causes serious eye damage.

Symptoms/effects after ingestion : May be harmful if swallowed.





Suitable extinguishing media : Carbon dioxide. Dry powder. Water spray.




: May release hazardous fumes. Hydrogen fluoride.


Firefighting instructions : Cool closed containers exposed to fire with water spray. Do not enter fire area without proper protective equipment, including respiratory protection.

Protection during firefighting : Wear recommended personal protective equipment.

Other information : Do not remove damaged packages. Move only undamaged packages out of fire zone.






General measures : Safety glasses with face shield. Gloves. Use self-contained breathing apparatus and chemically protective clothing.


Emergency procedures : Ventilate spillage area. Do not touch or walk on the spilled product.




Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.


For containment : Stop leak without risks if possible. Place in a suitable container for disposal in accordance with the waste regulations (see Section 13).

Methods for cleaning up : Neutralize with : Bases. Bicarbonate. Collect spills and put it into appropriated container. Do not use : Sand.


See Heading 8.



Additional hazards when processed : May be corrosive to metals. Provide local exhaust or general room ventilation.

Precautions for safe handling : Avoid contact with skin, eyes and clothing. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not breathe vapours.

Hygiene measures : Do not eat, drink or smoke when using this product.


Storage conditions : Keep container closed when not in use. Keep container in well ventilated place. Keep only in the original container in a cool, well ventilated place away from : Heat sources.

Incompatible materials : Metals.

Storage area : Store in a well-ventilated place. Store away from heat.

Special rules on packaging : Keep only in original container.


Not applicable.



PICKLINOX G10






















PICKLINOX G10












































nitric acid ... % (7697-37-2)


EU IOELV STEL (mg/m³) 2,6 mg/m³ 2.6 (EU)








nitric acid ... % (7697-37-2)



















































nitric acid ... % (7697-37-2)













France VME (mg/m³) 2,5 mg/m³ Fluorure F-

Germany TRGS 900 Occupational exposure limit value (mg/m³) 2,5 mg/m³ F-


USA - ACGIH ACGIH TWA (mg/m³) 2,5 mg/m³ F-




Hand protection:


Eye protection:









Appearance : Paste.

Colour : Translucent.

Odour : Pungent.


pH : ≈ 1


Melting point : Not applicable.

Freezing point : Not available

Boiling point : Not available

Flash point : Not applicable

Critical temperature : Not applicable

Auto-ignition temperature : <= Not applicable



Vapour pressure : Not available



Solubility : No data available





Viscosity, kinematic : Not available



Oxidising properties : Not available.



VOC content : 0


10.1. Reactivity

Decomposes. Risk of ignition.




Reacts violently with water. May react violently with acids.


Overheating. Protect from moisture. alcohol.


May be corrosive to metals. Strong bases. Acetone. alcohol. Reducing agent.


Nitric acid. Fluorine (F). Hydrogen fluoride. ammonia. Nitrogen oxides.



Acute toxicity (oral) : Oral: Harmful if swallowed.

Acute toxicity (dermal) : Not classified

Acute toxicity (inhalation) : Inhalation:dust,mist: Harmful if inhaled.

PICKLINOX G10


LC50 inhalation rat (mg/l) ≈ 1,75


nitric acid ... % (7697-37-2)

LC50 inhalation rat (mg/l) > 2,6 mg/l/4h


LD50 oral rat ≈ 130 mg/kg


pH: ≈ 1


pH: ≈ 1









12.1. Toxicity



















Waste treatment methods : This material and its container must be disposed of as hazardous waste.

Sewage disposal recommendations : Disposal must be done according to official regulations.

Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.



14.1. UN number

UN-No. (ADR) : 3264




UN-No. (RID) : 3264


Proper Shipping Name (ADR) : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

Proper Shipping Name (IMDG) : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

Proper Shipping Name (IATA) : Corrosive liquid, acidic, inorganic, n.o.s.


Proper Shipping Name (RID) : Not applicable

Transport document description (ADR) : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (nitric acid ... % ; ammonium bifluoride), 8, II, (E)

Transport document description (IMDG) : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (nitric acid ... % ; ammonium bifluoride), 8, II

Transport document description (IATA) : UN 3264 Corrosive liquid, acidic, inorganic, n.o.s. (nitric acid ... % ; ammonium bifluoride), 8, II

Transport document description (RID) : UN 3264 (nitric acid ... % ; ammonium bifluoride), 8


ADR

Transport hazard class(es) (ADR) : 8

Danger labels (ADR) : 8

:

IMDG

Transport hazard class(es) (IMDG) : 8

Danger labels (IMDG) : 8




:

IATA

Transport hazard class(es) (IATA) : 8

Hazard labels (IATA) : 8

:

ADN


RID

Transport hazard class(es) (RID) : 8

Danger labels (RID) : 8

:

14.4. Packing group





Packing group (RID) : Not applicable







Classification code (ADR) : C1







: T11


: TP2, TP27





Orange plates :





EAC code : 2X

APP code : B

- Transport by sea







Tank special provisions (IMDG) : TP2, TP27





Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes.

MFAG-No : 154

- Air transport









ERG code (IATA) : 8L


Not regulated

- Rail transport

No data available


Not applicable




Contains no REACH substances with Annex XVII restrictions



VOC content : 0


Germany

VwVwS Annex reference : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 4)



Netherlands












Denmark




































Acute Tox. 3 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 3









H302 Harmful if swallowed.




H332 Harmful if inhaled.

PICKLINOX L30 Safety Data Sheet







Product name : PICKLINOX L30




Main use category : Pickling acids













Acute toxicity (dermal), Category 2 H310


H331



H318




2.2. Label elements



GHS05

GHS06


Hazardous ingredients : hydrofluoric acid … %; ammonium bifluoride; nitric acid ... %

Hazard statements (CLP) : H301+H331 - Toxic if swallowed or if inhaled H310 - Fatal in contact with skin. H314 - Causes severe skin burns and eye damage.

Precautionary statements (CLP) : P260 - Do not breathe dust, fume, gas, mist, spray, vapours. P280 - Wear protective clothing, eye protection, face protection, protective gloves. P308+P311 - IF exposed or concerned: Call a doctor. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.






P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

2.3. Other hazards



3.1. Substances

Not applicable

3.2. Mixtures


nitric acid ... %

(CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1 (REACH-no) 01-2119487297-23

30 - 40 Ox. Liq. 3, H272 Met. Corr. 1, H290 Acute Tox. 3 (Inhalation), H331 Skin Corr. 1A, H314

hydrofluoric acid … %


5 - 9,5 Acute Tox. 2 (Oral), H300 Acute Tox. 1 (Dermal), H310 Acute Tox. 2 (Inhalation:dust,mist), H330 Skin Corr. 1A, H314

ammonium bifluoride


2 - 5 Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314



nitric acid ... % (CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1 (REACH-no) 01-2119487297-23


hydrofluoric acid … % (CAS-No.) 7664-39-3 (EC-No.) 231-634-8 (EC Index-No.) 009-003-00-1 (REACH-no) 01-2119458860-33

( 0,1 =<C < 1) Eye Irrit. 2, H319 ( 1 =<C < 7) Skin Corr. 1B, H314 (C >= 7) Skin Corr. 1A, H314

ammonium bifluoride (CAS-No.) 1341-49-7 (EC-No.) 215-676-4 (EC Index-No.) 009-009-00-4 (REACH-no) 01-2119489180-38





First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. Give oxygen or artificial respiration if necessary.

First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical advice/attention.

First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.

First-aid measures after ingestion : If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting because of corrosive effects.




Treat symptomatically.



Suitable extinguishing media : Carbon dioxide. Dry powder.



Fire hazard : In case of fire and/or explosion do not breathe fumes. Not flammable.





: Toxic fumes may be released.


Precautionary measures fire : Keep container closed when not in use.

Firefighting instructions : Cool closed containers exposed to fire with water spray.

Protection during firefighting : Complete protective clothing. EN 469. EN 659. Self-contained breathing apparatus. EN137. Wear recommended personal protective equipment.



General measures : Avoid contact with skin and eyes. Stop leak if safe to do so.




Protective equipment : Do not attempt to take action without suitable protective equipment.


Do not allow to enter drains or water courses.


For containment : Do not touch or walk on the spilled product. Collect as much as possible in clean container for (preferably) re-use or disposal.

Methods for cleaning up : Absorb remaining liquid with sand or inert absorbent and remove to safe place. Avoid non protected metal containers.

Other information : Dispose of materials or solid residues at an authorized site.


For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.



Precautions for safe handling : Do not breathe vapours. Avoid contact with skin, eyes and clothing.

Hygiene measures : Do not eat, drink or smoke when using this product. Take off immediately all contaminated clothing and wash it before reuse.


Storage conditions : Store in a well-ventilated place. Keep container tightly closed. Keep only in original container. Keep away from ignition sources.





PICKLINOX L30

EU Local name Acetic acid

EU IOELV TWA (mg/m³) 25 mg/m³

EU IOELV TWA (ppm) 10 ppm

EU IOELV STEL (mg/m³) 50 mg/m³


EU Notes Skin

EU Regulatory reference COMMISSION DIRECTIVE (EU) 2017/164

Czech Republic Local name Kyselina octová (Kyselina ethanová)


Czech Republic Expoziční limity (PEL) (ppm) 10 ppm

Czech Republic Expoziční limity (NPK-P) (mg/m³) 35 mg/m³

Czech Republic Expoziční limity (NPK-P) (ppm) 14,3 ppm



France Local name Acide acétique

France VME (mg/m³) 49 mg/m³




PICKLINOX L30

France VME (ppm) 10 ppm

France VLE (mg/m³) 25 mg/m³


France Note (FR) Valeurs recommandées/admises

France Regulatory reference Circulaire du Ministère du travail (réf.: INRS ED 984, 2016)

Germany Local name Essigsäure

Germany TRGS 900 Occupational exposure limit value (mg/m³) 25 mg/m³


Germany Remark (TRGS 900) DFG;EU;Y


Italy Local name Butossietanolo-2

Italy OEL TWA (mg/m³) 98 mg/m³

Italy OEL TWA (ppm) 20 ppm

Italy OEL STEL (mg/m³) 246 mg/m³


Italy Notes pelle


Netherlands Local name Azijnzuur


Netherlands Grenswaarde TGG 15MIN (mg/m³) 246 mg/m³

Netherlands Remark (MAC) H (Huidopname) Stoffen die relatief gemakkelijk door de huid kunnen worden opgenomen, hetgeen een substantiële bijdrage kan betekenen aan de totale inwendige blootstelling, hebben in de lijst een Haanduiding. Bij deze stoffen moeten naast maatregelen tegen inademing ook adequate maatregelen ter voorkoming van huidcontact worden genomen.


Poland Local name Kwas octowy

Poland NDS (mg/m³) 25 mg/m³

Poland NDSCh (mg/m³) 50 mg/m³


Portugal Local name Ácido acético



Portugal OEL - Ceilings (mg/m³) 2 mg/m³


Romania Local name Acid acetic

Romania OEL TWA (mg/m³) 25 mg/m³

Romania OEL TWA (ppm) 10 ppm




Slovakia Local name Kyselina octová (kyselina etánová)

Slovakia NPHV (priemerná) (mg/m³) 25 mg/m³

Slovakia NPHV (priemerná) (ppm) 10 ppm

Slovakia OEL STEL (mg/m³) 246 mg/m³


Slovakia Upozornenie (SK) K - znamená, že faktor môže byť ľahko absorbovaný kožou


Spain Local name Ácido acético




PICKLINOX L30

Spain VLA-ED (mg/m³) 25 mg/m³

Spain VLA-ED (ppm) 10 ppm

Spain VLA-EC (mg/m³) 50 mg/m³



Spain Spain - BLV 200 mg/g creatinine Parámetro: Ácido butoxiacético - Medio: Orina - Momento de muestreo: Final de la jornada laboral - Notas: Con hidrólisis


United Kingdom Local name Acetic acid

United Kingdom WEL TWA (mg/m³) 25 mg/m³

United Kingdom WEL TWA (ppm) 25 ppm

United Kingdom WEL STEL (mg/m³) 50 mg/m³


United Kingdom Remark (WEL) Sk (Can be absorbed through the skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity), BMGV (Biological monitoring guidance values are listed in Table 2)


USA - ACGIH Local name Acetic acid



USA - ACGIH ACGIH Ceiling (ppm) 2 ppm

USA - ACGIH Remark (ACGIH) URT & eye irr; pulm func


USA - OSHA Local name Acetic acid



USA - OSHA Remark (OSHA) (2) See Table Z-2.

hydrofluoric acid … % (7664-39-3)

EU Local name Hydrogen fluoride

EU IOELV TWA (mg/m³) 1,5 mg/m³

EU IOELV TWA (ppm) 1,8 ppm



Czech Republic Local name Fluorovodík

Czech Republic Expoziční limity (PEL) (mg/m³) 1,5 mg/m³




France Local name Fluorure d’hydrogène

France VME (mg/m³) 1,5 mg/m³

France VME (ppm) 1,8 ppm



Germany Local name Fluorwasserstoff



Germany Remark (TRGS 900) DFG,EU,Y,H

Italy Local name Acido fluoridrico


Italy OEL TWA (ppm) 1,8 ppm







Netherlands Local name Fluorwaterstof (als F)


Poland Local name Fluorowodór



Portugal Local name Ácido fluorídrico , expresso em F

Portugal OEL TWA (ppm) 0,5 ppm

Portugal OEL - Ceilings (ppm) 2 ppm

Romania Local name Acid fluorhidric

Romania OEL TWA (mg/m³) 1,5 mg/m³

Romania OEL TWA (ppm) 1,8 ppm



Slovakia NPHV (priemerná) (mg/m³) 1,5 mg/m³

Slovakia NPHV (priemerná) (ppm) 1,8 ppm


Spain Local name Fluoruro de hidrógeno

Spain VLA-ED (mg/m³) 1,5 mg/m³

Spain VLA-ED (ppm) 1,8 ppm



Spain Notes VLB® (Agente químico que tiene Valor Límite Biológico específico en este documento.), VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo. Todos estos agentes químicos figuran al menos en una de las directivas de valores límite indicativos publicadas hasta ahora (ver Anexo C. Bibliografía). Los estados miembros disponen de un tiempo fijado en dichas directivas para su transposición a los valores límites de cada país miembro. Una vez adoptados, estos valores tienen la misma validez que el resto de los valores adoptados por el país.)

United Kingdom Local name Hydrogen fluoride

United Kingdom WEL TWA (mg/m³) 1,5 mg/m³ (as F)

United Kingdom WEL TWA (ppm) 1,8 ppm (as F)

United Kingdom WEL STEL (mg/m³) 2,5 mg/m³ (as F)

United Kingdom WEL STEL (ppm) 3 ppm (as F)

USA - ACGIH Local name Hydrogen fluoride , as F

USA - ACGIH ACGIH TWA (ppm) 0,5 ppm


USA - ACGIH Remark (ACGIH) URT, LRT, skin, & eye irr

USA - OSHA Local name Hydrogen fluoride (as F)


nitric acid ... % (7697-37-2)














nitric acid ... % (7697-37-2)




















































nitric acid ... % (7697-37-2)







Hand protection:


Eye protection:









Colour : Colourless.

Odour : Pungent.


pH : ≈ 1


Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Auto-ignition temperature : No data available



Vapour pressure : No data available



Solubility : soluble in water.


Viscosity, kinematic : No data available


Explosive properties : No data available

Oxidising properties : No data available





10.1. Reactivity





Reacts violently with water. Danger of explosion on contact with : Chlorine trifluoride. Bromine trifluoride. May react violently with acids.





Do not allow contact with water. Overheating.




Fluorine (F). Hydrogen fluoride. ammonia. Nitrogen.



Acute toxicity (oral) : Oral: Toxic if swallowed.

Acute toxicity (dermal) : Dermal: Fatal in contact with skin.

Acute toxicity (inhalation) : Inhalation:dust,mist: Toxic if inhaled.

PICKLINOX L30


LD50 dermal ≈ 53 mg/kg

LC50 inhalation rat (mg/l) ≈ 2,98 mg/l



LC50 inhalation rat (Vapours - mg/l/4h) > 1310 mg/l/4h ppm/1h


LD50 oral 130 mg/kg OCDE 401

nitric acid ... % (7697-37-2)

LC50 inhalation rat (Vapours - mg/l/4h) > 2,65 mg/l/4h


pH: ≈ 1


pH: ≈ 1









12.1. Toxicity




LC50 fish 1 ≈ 51 mg/kg

NOEC chronic fish ≈ 4 mg/l 21 day

NOEC chronic crustacea ≈ 3,7 mg/l 21 day

NOEC chronic algae ≈ 50 mg/l 21 day



Persistence and degradability Readily biodegradable.















Waste treatment methods : This material and its container must be disposed of as hazardous waste. Dispose of contents/container in accordance with licensed collector’s sorting instructions.


In accordance with ADR

14.1. UN number

UN-No. (ADR) : 2922


Proper Shipping Name (ADR) : CORROSIVE LIQUID, TOXIC, N.O.S.

Transport document description (ADR) : UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. ( NITRIC ACID HYDROFLUORIC ACID), 8 (6.1), II, (E)


ADR

Transport hazard class(es) (ADR) : 8 (6.1)

Danger labels (ADR) : 8, 6.1

:

14.4. Packing group







Classification code (ADR) : CT1







: T7


: TP2




Special provisions for carriage - Loading, unloading and handling (ADR)

: CV13, CV28


Orange plates :





EAC code : 2X

APP code : B


Not applicable








Germany

VwVwS Annex reference : Water hazard class (WGK) 2, significant hazard to waters (Classification according to VwVwS, Annex 4)



Netherlands









Denmark


Pregnant/breastfeeding women working with the product must not be in direct contact with the product






































Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1

Acute Tox. 2 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 2


Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3








H300 Fatal if swallowed.


H310 Fatal in contact with skin.



H330 Fatal if inhaled.




PICKLINOX P2 Safety Data Sheet







Product name : PICKLINOX P2




Main use category : Acidic cleaner.

Industrial/Professional use spec : For professional use only












Acute toxicity (dermal), Category 2 H310

Acute toxicity (inhal.), Category 3 H331



H318




2.2. Label elements



GHS05

GHS06


Hazardous ingredients : ammonium bifluoride; hydrofluoric acid … %

Hazard statements (CLP) : H301+H331 - Toxic if swallowed or if inhaled H310 - Fatal in contact with skin. H314 - Causes severe skin burns and eye damage.

Precautionary statements (CLP) : P260 - Do not breathe dust, gas, fume, mist, spray, vapours. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water . P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P311 - IF exposed or concerned: Call a doctor. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.






2.3. Other hazards



3.1. Substances

Not applicable

3.2. Mixtures


nitric acid ... %


13,75 - 20 Ox. Liq. 3, H272 Met. Corr. 1, H290 Acute Tox. 3 (Inhalation), H331 Skin Corr. 1A, H314

hydrofluoric acid … %


7 - 9,5 Acute Tox. 2 (Oral), H300 Acute Tox. 1 (Dermal), H310 Acute Tox. 2 (Inhalation:dust,mist), H330 Skin Corr. 1A, H314

Bariumsulfate

(CAS-No.) 7727-43-7 (EC-No.) 231-784-4 (REACH-no) 01-2119491274-35

0,5 - 5 Not classified

ammonium bifluoride


1 - 5 Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314



nitric acid ... % (CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1 (REACH-no) 01-2119487297-23


hydrofluoric acid … % (CAS-No.) 7664-39-3 (EC-No.) 231-634-8 (EC Index-No.) 009-003-00-1 (REACH-no) 01-2119458860-33

( 0,1 =<C < 1) Eye Irrit. 2, H319 ( 1 =<C < 7) Skin Corr. 1B, H314 (C >= 7) Skin Corr. 1A, H314

ammonium bifluoride (CAS-No.) 1341-49-7 (EC-No.) 215-676-4 (EC Index-No.) 009-009-00-4 (REACH-no) 01-2119489180-38





First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. Give oxygen or artificial respiration if necessary.

First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical advice/attention.

First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.

First-aid measures after ingestion : If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting because of corrosive effects.




Treat symptomatically.



Suitable extinguishing media : Carbon dioxide. Dry powder.



Fire hazard : In case of fire and/or explosion do not breathe fumes. Not flammable.





: Toxic fumes may be released.


Precautionary measures fire : Keep container closed when not in use.

Firefighting instructions : Cool closed containers exposed to fire with water spray.

Protection during firefighting : Complete protective clothing. EN 469. EN 659. Self-contained breathing apparatus. EN137. Wear recommended personal protective equipment.



General measures : Avoid contact with skin and eyes. Stop leak if safe to do so.




Protective equipment : Do not attempt to take action without suitable protective equipment.


Do not allow to enter drains or water courses.


For containment : Do not touch or walk on the spilled product. Collect as much as possible in clean container for (preferably) re-use or disposal.

Methods for cleaning up : Absorb remaining liquid with sand or inert absorbent and remove to safe place. Avoid non protected metal containers.

Other information : Dispose of materials or solid residues at an authorized site.


For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.



Precautions for safe handling : Do not breathe vapours. Avoid contact with skin, eyes and clothing.

Hygiene measures : Do not eat, drink or smoke when using this product. Take off immediately all contaminated clothing and wash it before reuse.


Storage conditions : Store in a well-ventilated place. Keep container tightly closed. Keep only in original container. Keep away from ignition sources.





PICKLINOX P2














France Local name Fluorure d’hydrogène (Acide fluorhydrique)






PICKLINOX P2



France Note (FR) Valeurs règlementaires contraignantes

France Regulatory reference Article R4412-149 du Code du travail (réf.: INRS ED 984, 2016)




Germany Remark (TRGS 900) DFG;EU;Y;H








Netherlands Local name Fluorwaterstof

Netherlands Grenswaarde TGG 15MIN (mg/m³) 1 mg/m³ (als F)






Portugal Local name Sulfato de bário

Portugal OEL TWA (mg/m³) 5 mg/m³ I (Fraçao inalável), E (O valor aplica-se a partículas sem amianto e contendo menos de 1 % de sílica cristalina)



Portugal OEL - Ceilings (mg/m³) 2 mg/m³








Slovakia Local name Síran (sulfát) bárnatý

Slovakia NPHV (priemerná) (mg/m³) 4 mg/m³ inhalovateľná frakcia 1,5 mg/m³ respirabilná frakcia





Spain Local name Sulfato de bario





Spain Notes e (Este valor es para la materia particulada que no contenga amianto y menos de un 1% de sílice cristalina).




PICKLINOX P2

Spain Spain - BLV 2 mg/l Parámetro: Fluoruros - Medio: Orina - Momento de muestreo: Antes de la jornada laboral - Notas: F (Fondo. El indicador está generalmente presente en cantidades detectables en personas no expuestas laboraboralmente. Estos niveles de fondo están considerados en el valor VLB), I (Significa que el indicador biológico es inespecífico puesto que puede encontrarse después de la exposición a otros agentes químicos) 3 mg/l Parámetro: Fluoruros - Medio: Orina - Momento de muestreo: Final de la jornada laboral - Notas: F (Fondo. El indicador está generalmente presente en cantidades detectables en personas no expuestas laboraboralmente. Estos niveles de fondo están considerados en el valor VLB), I (Significa que el indicador biológico es inespecífico puesto que puede encontrarse después de la exposición a otros agentes químicos)


United Kingdom Local name Barium sulphate

United Kingdom WEL TWA (mg/m³) 10 mg/m³ inhalable dust 4 mg/m³ respirable dust





USA - ACGIH Local name Barium sulfate

USA - ACGIH ACGIH TWA (mg/m³) 5 mg/m³




USA - ACGIH Remark (ACGIH) Pneumoconiosis






nitric acid ... % (7697-37-2)






















nitric acid ... % (7697-37-2)



























































France Local name Fluorure d’hydrogène








Germany Remark (TRGS 900) DFG,EU,Y,H






Netherlands Local name Fluorwaterstof (als F)





Portugal Local name Ácido fluorídrico , expresso em F


Portugal OEL - Ceilings (ppm) 2 ppm






Slovakia NPHV (priemerná) (mg/m³) 1,5 mg/m³



Spain Local name Fluoruro de hidrógeno

Spain VLA-ED (mg/m³) 1,5 mg/m³




Spain Notes VLB® (Agente químico que tiene Valor Límite Biológico específico en este documento.), VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo. Todos estos agentes químicos figuran al menos en una de las directivas de valores límite indicativos publicadas hasta ahora (ver Anexo C. Bibliografía). Los estados miembros disponen de un tiempo fijado en dichas directivas para su transposición a los valores límites de cada país miembro. Una vez adoptados, estos valores tienen la misma validez que el resto de los valores adoptados por el país.)

United Kingdom Local name Hydrogen fluoride

United Kingdom WEL TWA (mg/m³) 1,5 mg/m³ (as F)








USA - ACGIH Local name Hydrogen fluoride , as F



USA - ACGIH Remark (ACGIH) URT, LRT, skin, & eye irr



Bariumsulfate (7727-43-7)

Portugal Local name Sulfato de bário

Portugal OEL TWA (mg/m³) 5 mg/m³ I (Fraçao inalável), E (O valor aplica-se a partículas sem amianto e contendo menos de 1 % de sílica cristalina)


Slovakia Local name Síran (sulfát) bárnatý

Slovakia NPHV (priemerná) (mg/m³) 4 mg/m³ inhalovateľná frakcia 1,5 mg/m³ respirabilná frakcia


Spain Local name Sulfato de bario


Spain Notes e (Este valor es para la materia particulada que no contenga amianto y menos de un 1% de sílice cristalina).


United Kingdom Local name Barium sulphate

United Kingdom WEL TWA (mg/m³) 10 mg/m³ inhalable dust 4 mg/m³ respirable dust


USA - ACGIH Local name Barium sulfate

USA - ACGIH ACGIH TWA (mg/m³) 5 mg/m³

USA - ACGIH Remark (ACGIH) Pneumoconiosis



Appropriate engineering controls:

Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure that there is a suitable ventilation system. Measure concentrations regularly, and at the time of any change occuring in conditions likely to have consequences on workers exposure.


Wear suitable protective clothing.

Hand protection:

Chemical resistant PVC gloves (to European standard EN 374 or equivalent). The breakthrough time of the selected gloves must be greater than the intended use period.

Eye protection:



Long sleeved protective clothing. Chemical resistant safety shoes


Do not exceed the occupational exposure limits (OEL). This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used



Physical state : Solid

Appearance : Paste.




Colour : white.

Odour : Pungent.


pH : ≈ 1


Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Auto-ignition temperature : No data available



Vapour pressure : No data available


Relative density : No data available

Solubility : In water, material is partially soluble.


Viscosity, kinematic : No data available



Oxidising properties : No data available





10.1. Reactivity





Reacts violently with water. Danger of explosion on contact with : Chlorine trifluoride. Bromine trifluoride. May react violently with acids.


Do not allow contact with water. Overheating.




Fluorine (F). Hydrogen fluoride. ammonia. Nitrogen.



Acute toxicity (oral) : Oral: Toxic if swallowed.

Acute toxicity (dermal) : Dermal: Fatal in contact with skin.

Acute toxicity (inhalation) : Inhalation: Toxic if inhaled.

PICKLINOX P2


LD50 dermal ≈ 53 mg/kg

LC50 inhalation rat (Vapours - mg/l/4h) ≈ 3,81 mg/l/4h

ATE CLP (gases) 700 ppmv/4h


nitric acid ... % (7697-37-2)

LC50 inhalation rat (Vapours - mg/l/4h) > 2,65 mg/l/4h


LD50 oral 130 mg/kg OCDE 401





LC50 inhalation rat (Vapours - mg/l/4h) > 1310 mg/l/4h ppm/1h


pH: ≈ 1


pH: ≈ 1









12.1. Toxicity




LC50 fish 1 ≈ 51 mg/kg

NOEC chronic fish ≈ 4 mg/l 21 day

NOEC chronic crustacea ≈ 3,7 mg/l 21 day

NOEC chronic algae ≈ 50 mg/l 21 day



Persistence and degradability Readily biodegradable.












Waste treatment methods : This material and its container must be disposed of as hazardous waste. Dispose of contents/container in accordance with licensed collector’s sorting instructions.



14.1. UN number

UN-No. (ADR) : 2922




UN-No. (RID) : 2922


Proper Shipping Name (ADR) : CORROSIVE LIQUID, TOXIC, N.O.S.

Proper Shipping Name (IMDG) : CORROSIVE LIQUID, TOXIC, N.O.S.

Proper Shipping Name (IATA) : Corrosive liquid, toxic, n.o.s.





Proper Shipping Name (RID) : CORROSIVE LIQUID, TOXIC, N.O.S.

Transport document description (ADR) : UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II, (E)

Transport document description (IMDG) : UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II

Transport document description (IATA) : UN 2922 Corrosive liquid, toxic, n.o.s. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II

Transport document description (RID) : UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II


ADR

Transport hazard class(es) (ADR) : 8 (6.1)

Danger labels (ADR) : 8, 6.1

:

IMDG

Transport hazard class(es) (IMDG) : 8 (6.1)

Danger labels (IMDG) : 8, 6.1

:

IATA

Transport hazard class(es) (IATA) : 8 (6.1)

Hazard labels (IATA) : 8, 6.1

:

ADN


RID

Transport hazard class(es) (RID) : 8 (6.1)

Danger labels (RID) : 8, 6.1

:

14.4. Packing group





Packing group (RID) : II










Classification code (ADR) : CT1







: T7


: TP2




Special provisions for carriage - Loading, unloading and handling (ADR)

: CV13, CV28


Orange plates :


EAC code : 2X

APP code : B

- Transport by sea







Tank special provisions (IMDG) : TP2





Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation.

MFAG-No : 154

- Air transport









ERG code (IATA) : 8P


Not regulated




- Rail transport

Classification code (RID) : CT1

Special provisions (RID) : 274

Limited quantities (RID) : 1L

Excepted quantities (RID) : E2

Packing instructions (RID) : P001, IBC02

Mixed packing provisions (RID) : MP15

Portable tank and bulk container instructions (RID)

: T7

Portable tank and bulk container special provisions (RID)

: TP2

Tank codes for RID tanks (RID) : L4BN

Transport category (RID) : 2

Special provisions for carriage - Loading, unloading and handling (RID)

: CW13, CW28

Colis express (express parcels) (RID) : CE6

Hazard identification number (RID) : 86


Not applicable








Germany

VwVwS Annex reference : Water hazard class (WGK) 2, significant hazard to waters (Classification according to VwVwS, Annex 4)



Netherlands









Denmark


Pregnant/breastfeeding women working with the product must not be in direct contact with the product





Composition/information on ingredients. Hazards identification. Identification of the substance/mixture and of the company/undertaking. Regulatory information.

































Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1

Acute Tox. 2 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 2


Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3








H300 Fatal if swallowed.


H310 Fatal in contact with skin.



H330 Fatal if inhaled.




PICKLINOX G2 - market.varjenje.net · Romania Regulatory reference Legea 319/2006 privind...

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