PICKERING CREEK INDUSTRIAL PARK LIONVILLE. PA 19353 ...

|®is:

256 WELSH POOL ROAD PICKERING CREEK INDUSTRIAL PARK LIONVILLE. PA 19353

DESIGNERS CONSULTANTS ,

28 February 1986

Mr. Charles Lindberg SDMS DocIDGoldberg Zoina and Assoc. 568254

The GEO Building " ~ 320 Needham Street Newton Upper Falls, MA 02164

Dear Mr. Lindberg:

Please note the following items regarding our data reportsof January 27 (metals VOA's and BNA's) and January 28 (TCDD):

1. The reported' target compounds for VOA and BNA analyses were priority pollutants. Since HSL's are needed we searched the original data for the additional analytes and have attached revised reports(Attachment I).

2. The EPA data qualifier, B for target analytesdetected in the laboratory blank, has been added to the report forms where appropriate.. It is noted that the only targets present in the laboratory blanks were methylene chloride in the VOA blank and bis(2-ethylhexyl)phthalate in the BNA blank. The blank levels of both these analytes was below the CLP Contract Required Detection Limit.

3. Attachment II is a revised TCDD data report on which the surrogate recoveries have been corrected to reflect the observed inconsistency between levels in the calibration standard received from the EPA and the surrogate spiking solution made up in our laboratory from neat compounds. Also attached is a copy of the laboratory work sheet, on which relevant calculations were made, and the mass chromatograms.

4. Attachment III is the TCDD data report form for the re-extracted samples B-101A and B-102B. Re-extraction and analyses were performed because of the veryhigh recoveries obtained from the original analysisof these samples. More reasonable recoveries were obtained in the re-analysis.

5. BNA and TCDD fractions for sample B-105B were spikedwith the CLP BNA matrix spike mix and 2,3,7,8 TCDD,respectively. Unspiked sample was not analyzed for these parameters due to a miscommunication between GZA and WESTON Laboratory.

\!Zi|p23

6. Zinc was found in the method blank at a concentration of 0.030 mg/L. This concentration is consistent with previous determinations of zinc in the laboratorywater. Certified ultra-pure reagents are used for digestion so.that the reagents should not be a source of contamination. A method blank is prepared byusing an aliquot of laboratory water equivalent to the quantity of sample that is used in the analyses.Any contamination in the laboratory water would then be observed on analysis of the method blank. However, when processing samples, minimal amounts of laboratory water are used, and any contributions from contaminated^laboratory water should be much less than 10% of the concentration. Consequently, contributions from laboratory water should be less than 0.003 mg/L, and concentrations of zinc determined in the samples should be representative of the actual concentrations in the samples.

7. Both the computer data base and the original notebook entries have been reviewed for accurate transcriptionof data for the manganese results. The notebook and data base agree. Sample 8512-327-0030(SCC-GWS-B-102A)was diluted by a factor of 10 at the instrument in order for the response to fall within the calibrated range of the instrument. Sample 8512-327-0050(SCCGWS-B-001A) was diluted by a factor of 100. The result obtained for sample 0050 can be verified since this sample was also.replicated and spiked. The results for the replicate and spike are comparable to the initial result (the spike level was significantlyless than the concentration in the sample).

If you have any questions, please call me at (215) 524-0180.

Very Truly Yours

ROY F. WESTON, INC.

Carter P. Nulton, Ph.D. Organics Section ManagerWESTON Analytical Laboratories

CPN:ost

1

* _ Date of Report: January 28, 1986

RFWSN

8512-327-0010 -0020 -0030 -0040

• -0050 -0050 Dup-0060 -0070 -0090

-0050

GOLDBERG ZOINO AND ASSOCIATES SUMMARY REPORT

FOR SAMPLES RECEIVED DECEMBER 5, 1985

Concentration (mg/L)

SAMPLE DESCRIPTION A1 . Be Ba Ca Sr

SCC-GWS-B-105A < 0 . 0 2 SCC-GWS-B-105B < 0 . 0 2 SCC-GWS-B-102A < 0 . 0 2 SCC-GWS-B-102B <0.5 < 0 . 0 2 <0.1 145 2.43 SCC-GWS-B-001A < 0 . 0 2 Laboratory Duplicate — < 0 . 0 2 SCC-QAC-SB-001 < 0 . 0 2 SCC-QAC-FB-001 < 0 . 0 2 SCC-GWS-B-101A < 0 . 0 2 Laboratory Blank <0.5 < 0 . 0 2 <0.1 <0.005 <0.05 Blank Spike — 100%

Rec.

Blank Spike Dup. 100% Rec.

Matrix Spike 100% Rec.

ManagerWESTON Analytical Laboratories

DATE O F REPORT; 0 1 / 8 5 / 8 8C l . . . U : : . N I ! l G V L i f t B K b — /0 1 . L - - * L . I f t f t S G V C L i f t i r?AT,f t S l . l l ' iMARY REPORT FOR SAMPLES RECEIVED;; 12-8-85 W „ 0 „ NOMRER " 00 10- 10-•09 .

DATE: SAMPLE COLLECTED;: 18-4-85 8 A DP EE COLLECTED BY:;, , UNKN0U0

AG CD OR CU FT HO

RFUSN DEOCRIP TION MG/L HG/L r iG/L MG/L MG/L 00/L JG/L

85 12-327-00 10 80C-G W 8-B-105 A < „ 0 10 , ,061 <,, 0 0 5 < 0 10 < 0 „ 08 176 - 0 08 0 8C -GUS-B-105B < „ 0 10 , ,047 < „ 005 < „ 0 10 < 0 „ 0 2 18 „ 4 \ „ -0080 BCC-GSU-B- 102 A < ., 0 10 <„010 < „ 005 <„ 010 < 0 „ 02 „ 056 1 „ 5

() () 40 -0050

8CC-GU8-B-102R 8C C -• G W 8 -B ••0 0 IA

<„ 010 < „ 0 10

< ., 010. < . , 0 10

< ,. 005 < „ 005

„ 0 TO < „ 0 10

( 0 „ 0 2 < 0 „ 0 2

7 „ 80 „ 067

< „ 5

-005!< HATEIX 8PIKE . ,06? , ,024 , ,006 , ,210 149 „ 158 -005K SPIKE RECOVERY 138% 83„5% . 120% 105% 74 ,, 5% 91 „ 0% -005R -0058.

REPLICATE PRECISION

. <„oio NC

<; , / ) io NC

<„005 NC

<„010 NC

< 0 „ 0 2 NC

„ 060 1 1 „ 021

-0060 -0070

8CC-QAC-SB-001 8CC-QAC-FB-001

<„010 <„010

(„010 <„010

<„005 <„005

<„0 10 <„0I0

, ,052 < 0 „ 0 2

„ 0 47 . „ 126

< „ 5 < „ 5

-0090 BCC-GUS-B-101A < „ 010 , ,024 <„005 , ,010 < 0 „ 02 35 „ 0 < „ 5 METHOD BLANK <„0 10 <„0 10 <„005 <„010 <0,, 02 < „ 020 METHOD SPIKE . ,063 , ,023 , ,005 ,. 204 „ 152 „ 114

SPIKE RECOVERY 126% 118% 114% 102% 76 „ 0% 114% METHOD SPIKE , ,066 . ,020 „ 005 „2!2 „ 157 „ 1 1 I

SPIKE RECOVERY 132% 101% 116% 106% 78 5% 11 1%

K MN NA NI P' B 55 B SE PIG/!... MG/L MG/L PiG/L MG/L MG/L MG/L

RFWSN DE8CRIPTION

85 12-: •0 0 10 •0020 •0030 ••0040 •0050

8C G-G W8-B •••• 105A 8CG-GU8-B-105R SCC-GSU-R- 102A BCC-GUS-B-102B SCC-GUS-B-001A

4 „ 59 , ,219 ,, 190 12 „ 3 1 „ 3 1

123

< „ 10 < „ TO < „ 10 „ 160 < „ 10

< , ,005 < ,, 005 < „ 005 < „ 005 < „0()5

< „ 060 < „060 < ,,060•(,,060 < „ 060

< „ 005 < „ 005 < „ 0 0 5 < „ 005 < 005

•005K •OOSK

MATRIX SPIKE SPIKE RECOVERY

. ,430 „010 , , 113 112%

.009 91.0%

-005!. . MATRIX SPIKE 1„ 46 ••0051.. . SPIKE REGG VERY 80 „ 0% -005R REPLICATE -005S PRECISION () () 60 SC C-•Q AC •••• SB -001

-0070 SCC-OAC-FB-001 -0090 SCC-GUS-B- 10 1A

1 „ 06 21„10% < „ 015 < „ 015

10 „ 4

< „ 10 NO

< ., 10 < ., 10 „ 150

< „ 005 NC

< „ 005 < „ 005 < . ,005

< „ 060 NC

< ,. 060 < „ 060 < „ 060

<

<

005 NC 005 005 005

METHOD BLANK •( , ,015 < ., 10 < „ 060 < „ 005 METHOD SPIKE , ,114 , ,410 „ 107 „ 009

SPIKE REGOVERY 114% 103% 107% 99.0% METHOD SPIKE „ 122 , ,420 „ 115 ,,011

SPIKE RECOVERY 122% 105% 1 15% 112% METHOD .SPIKE „ 010

SPIKE RECOVERY 102%

00i... DBElRG Z0X N0 a A8 8 0CIATL 8 TL . y zn

i v !G /L !ri A /!.. HG / i.

REUSN D E B C R T P T I ON

8512-327 •••• 0010 8C C G i,J3 •••• B 105 A < 0 10 „ aov..c -•0020 8C0-• G W 8-• B - 105R < „ 010 ,. 088 •••• () ()20 S C 0-G8U •••• B •• • 102 A < 0 10 „ 0 15 -• 0040 8CC-RU8-B- 102B < „ 0 -10 , ,046 •"0050 8CC-Gy8-•B •• 00 1A < „ 0 10 , ,014 -005K HAIRIX 8P IRK , ,086 „ 068 -005K 8PIKE i01(212FRY 67 „ 8% 102%

005R REPLIGATE <„<>10 . „ 0 1 1 -0058 PREG181ON NO 2 4 „ 0 0 % •-0 0 60 8G G (i) AG 8B ~001 < „ 010 , ,014

0070 8G G Q A G E fi -001 < „ 0 10 „ 0 1 1 •••• 0090 8GG •••• GU8 B -10 1A < „ 010 , ,035 •

f lETHOD BLANK < „ 010 <0 „ 05 „ 030 METHOD 8P TKF , ,040 „ () 60

8PTKE REGGOERY 80„4% 120% NET HOD 8PIKE , ,087 ,. 060

SPIKE REGOUERY 75„4% 120%

RFU8N DE8GRIPIION C Y A NI D E - - A C Y A NI D E T O T A L

i5 12-327-•0010 8GGGU8-B- 105A < „ 01 hG/L -0020 8GG-GWS-B-I05B <„01 HG/L •-0030 8GC-G8U-B-102A <„()! I1G/L -0040 8GG-GU8-B-102B 0 10 IIG/ ,,020 HG/I... -0050 SCC-GUS-B-001A < „ 01 HG/I . -0060 8CC-QAG-8R-001 <„0I HG/L -0090 SGG-.GU.I3-B-10 1A < „ 0I HG/L.

RFU8N DF8GRIPTION TOTAL ORGANIC CARBON TOTAL ORBANIG HALOGEN

8512-327 -00 40 8GG • •• 0 W 8-B- 102B 1140 HG/L 16500 iJG/L •••• ( )04R REPLICATE 18800 UG/L -0048 PREGISION 1 3 „ 0 3 %

HETi- iOD BLANK < „ 5 H G / L NETHOD SPIKE 4„92 HG/L

SPIKE RECOOERY 97 „ 2 % METHOD SPIKE 4„92 HG/L

SPIKE RECOOERY . 97, . 2 %

RFWSN DE8GRIPTION SlJi .EIDE

8512-327-0040 8C G-R LI8 •••• B-102B 3,, 60 HG/L -004K 8CC-GW8-B-102B 54,, 4 HG/L -004K SPIKE REGOUERY 102 % -004R 8CG-GWS-B-102B 3„60 HG/L -0043 PREGI8ION 1 1 „ 76 %

PREPARED BY APPRQUED F STEPHANIE DORBS EARL H„ HANSEN, PH„D„ DATA HANAGER HANAGER UE8TON ANALYTICAL EARORATORIES WE3TON ANALY"( ' IGAi. . . i . .AR0RAT0R.1E

DATE OF REPORT: December 13, 1985

ROY F. WESTON ORGANIC ANALYSIS DATA SUMMARY

FOR GZA

WATER-PESTICIDE/PCB SUMMARY REPORT

W.O. NO. 0010-10-09

R.r.W. NO.: 8512-337 5AMPLE BE5CRIPI I Ok:

DFT I TMTTS' 0010 B105 A

OOPO B105B

0030 B102A

QQ40B102B

0050 B001A

0060 SB001

BATE COLLECTLB: 12/4/85 12/4/85' 12/4/85 12/4/85 12/4/85 12/4/85 BATE EXTRACTLb: BATE ANALYZED-:

IP/6/85 12/11/85

12/6/85 12/11/85

jzmm.

12/11/85 IP/6/8512/11/85

12/6/85 12/11/85

1P/6/85.12/11/85

PARAMETER, vg/L yg/L MATRIX SP A1pha-BHC .05 N.D. N.D. N.D. N.D. JUL JL. Beta-BHC .05 Delta-BHC ,05 Gamma-BHC(L i ndane)Heptachlor

.05 ,05

obsc 95°L

Aldrin .05 47% Heptachlor Epoxide ,05 N.D. Endosulfan I .05 D iel dr in 7TTT 60% 4,4-DDE .10 N.D. Endr in , 1 0 60% EndosuI fan FT .10 4,4-DDD .10 Endrin Aldehyde" . 1 0 Endosulfan Sulfate .10 4,4-DDT .10 87% MethoxychlorEndrin Ketone

.50

.50 JUL

Chlordane .50 Toxaphene 1 . 0 Aroclor-1016 ,50 Arodor-1221 3U~ Arocior-1232 ,50 Aroclor-1242 ,50 Aroclor-1248 .50 Aroclor-1254 o~ Aroclor-1260 1 . 0

Di lut ion Factor 100 100 10 100 10 1 0 N.S. = Not Spiked N.D. = Not Detected < detection limit

Approved By:

irl M. Hansen, Ph.D. Manager WESTON Analytical Laboratories

DATE OF REPORT: December 13, 1985

ROY F. WESTON ORGANIC ANALYSIS DATA SUMMARY

FOR GZA .

WATER-PEST ICIDE/PCB SUMMARY REPORT

W.O. NO. 0010-10-09

R.F.W. NO.: 8512 327-0090 327/ 221L 2Z1L 5AHPLE DE5CMNI0N: B101A B1 ank Blank Sp B1 SP Pup

BATE COLLLClLb: 12/4/85 DATE EXTRAi i l tb : 12/6/85 12/6/85 12/6/85 12/6/85 DATE ANALV2LB: 12/11/85 12/11/85 12/11/85 12/11/85

PARAMETER, ug/L Alpha-BHC I .D. N.D. N.S. N.S. Beta-BHC Delta-BHC Gamma-BHC(L indane) 91% 68% Heptachlor 100% 78% Aldrin 795 655 Heptachlor Epoxide I .S. N.S. Endosulfan I D iel dr in 67% 60% 4,4-DDE I .S. I .S. Endrin 110% 100% EndosuI fan I I N.S. N,S. A,4-DDD Endrin Aldehyde Endosulfan Sulfate A,4-DDT 47% 41% Methoxychlor I .S. I .S. Endrin Ketone Chlordane Toxaphene Aroc1or-1016 Aroclor-1221 Aroclor-1232 Aroclor-12A2 Aroc1or-12A8 Aroclor-1254 Aroclor-

Di lut ion Factor 100

N.S. = Not Spiked N.D. = Not Detected < detection limit

Approved By:

Earl M. Hansen, Ph.D. Manager WESTON Analytical Laboratories

ATTACHMENT I

ROY F . WESTON ORGANIC ANALYSIS DATA SUMMARY

1 VOLATILE HAZARDOUS SUBSTANCE L IST COMPOUNDS

CLIENT: GZA GCMS FILE NAME: 1217W002219

SAMPLE DESC: SCC-GWS-B-105A MATRIX: Water

RFY/ #: 8512-327-0010 METHOD: "LOWy MED LEVEL CLP (Circle One'

DILUTION FACTOR: 500DATE COLLECTED: December 4, 1985

PH N/A Z MOISTURE N/ADATE ANALYZED: December 18, 1985

WORK ORDER #:

CASCAS (Circle One)(Circle One] NumberNumber 7B-87-5 1. 2-Dtchloropropane 5000 U5000 U74-87-3 Chloromethane 10061-02- 6 Trans-1. 3-Dichloropropene 5000 U5000 U74-83-9 Bromomethane 79-01-6 Trichloroethene 1700 J

75-01 Vinyl Chloride 5000 U 124-48-1 Dibromochloromethane 5000 U

75-00-3 Chloroethane 5000 U 79-00-5 1.1. 2-Trichloroethane 5000 U

76-09-2 Methylene Chloride 18000 B 71-43-2 Benzene W[>.50000067-64-1 Acetone

5000 U 10061-01-5 ci>-1. 3-Dichloropropene 5000 u 75-15-0 Carbon DiauHide

110-75-8 2-Chloroethylvinylether 5000 u 75-35-4 1. 1-Qichloroethene 5000 U

75-25-2 Bromoform 5000 u 75-34-3 1, 1-Dichloroethane 600 J

591-78-6 4-Methyl-2-Pentanone 5000 U1800 J 106-10-1 2-Hexanone 5000 u 156-60-5 Trans-1, 2-Dichloroethene

67-66-3 Chloroform s o o n u 127-18-4 Tetrachloroethene 800 J

107-06-2 1. 2-Dichloroethane 7600 79-34-5 1. 1.2. 2-Tetrachloroethane 5000 U7900

5000 U 106-88-3 Toluene 1700 J 78-93-3 2-Butanone

71-55-6 1,1. 1-Trichloroethane 106-90-7 Chlorobenzene 920 J5000 U

5500 U 100-41-4 Ethylbenzene 2900 J 56-23-5 Carbon Tetrachloride

Vinyl Acetate 5000 u 100-42-5 Styrene 5000 UBromodichloromethane

Total Xylenes 5onn 11

SURROGATE RECOVERY:

1,1-DICHLOROETHANE di 106 TOLUENE dg 109 p-BROMOFLUOROBENZENE 1 1 5

Data reporting qualifiers: t~

U - NOT DETECTED COMMENT:

. NR - NOT REQUESTED J - PRESENT AT LESS THAN DETECTION LIMIT B - ANALYTE PRESENT IN BLANK ;

z/t_y /?(_ APPROVED BY: /. j~- /u I<•—DATE:

—1— ft,— Earl M. Hansen, Ph.D Manager WESTON Ana ly t ica l Labora tor ies

R0* F . WLS10N

ORGANIC ANALYSIS DATA SUMMARY

VOLATILE HAZARDOUS SUBSTANCE L IST COMPOUNDS

GCMS FILE NAME: 1217W002220GZACLIENT: MATRIX: Water

SAMPLE DESC: SCC-GWS-B-1Q5B MED LEVEL CLP (Circle One)METHODl ; Ct°£>8512-327-0020RFW H:

DILUTION FACTOR: 1 DATE COLLECTED:December 4, 1985 NA % MOISTURE NA

DATE ANALYZED: December 18, 1985 PH

WORK ORDER #:

CAS «•»9 /\piug/KgC ug/KflCAS irele One)^Circle One) NumberNumber 78-87-5 1. 2-Dtchloropropane 8 J

74-87-3 Chloromethane 10 U 10061-02-6 Tran»-1, 3-Dichloropropene 10 U

74-83-9 Bromomethane 10 u 79-01-6 Trichloroethane 32

75-01- Vinyl Chloride 8 J 124-48-1 Dibromochloromethane 10 U

75-00-3 Chloroethane 10 U 79-00-5 1.1. 2-Trichloroethane 8 J

75-09-2 Methylene Chloride 6 JB 71-43-2 Benzene 146 J67-84-1 Acetone 10061-01-5 cit-1. 3-Dichloropropene 10 U75-15-0 Carbon Disulfide 10 U 110-75-8 2-Chloroethylvinylether 10 U

75-35-4 1. 1-Oichloroethene 0 T! 75-25-2 Bromolorm 10 U

75-34-3 1. 1-Dichloroethane 210 591-78-6 4-Methyl-2-Pentanone 10 U

156-60-5 Trans-1. 2-Dichloroethene JO. 106-10-1 2-Hexanone 10 U67-86-3 Chloroform XJ_ 127-18-4 Tetrachloroethene 9 J

107-06-2 1. 2-Dichloroethane ML 79-34-5 1. 1.2, 2-Tetrachloroethane 10 u

78-93-3 2-Betanone 10 u 106-88-3 Toluene

71-55-6 1.1, 1-Trichloroethane LL11. 106-90-7 Chlorobenzene 20

56-23-5 Carbon Tetrachloride i o n , 100-41-4 Ethylbenzene 10 U108-06-4 Vinyl Acetate 10 u 100-42-5 Styrene 10 U75-27-4 Bromodichloromethane 10 U

Total Xylenes 17

SURROGATE RECOVERY:

110 TOLUENE dg 100 p-BROMOFLUOROBENZENE 108

1,1-DICHLOROETHANE du

D a t a r e p o r t i n g q u a l i f i e r s :

COMMENT:U NOT DETECTED

NR NOT REQUESTED PRESENT AT LESS THAN DETECTION LIMITJ ANALYTE PRESENT IN BLANKB

APPROVED BY: /n,DATE: February 28. 1986 Earl M. Hansen, Ph.D

P- Manager WESTON Analytical Laboratories

ROY F . W t i l U N



GCMS FILE NAME: 1217W002218GZACLIENT: M A T R I X : WaterSCC-GWS-B-102ASAMPLE DESC:

LEVEL CLP (Circle One!METHODl : ( j - j jH)8512-327-0030RFV/ #:

DATE

DATE

WORK

CAS Number

74-87-3 74-83-9

75-01 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 156-80-5 67-66-3 107-06-2 78 93-3 71-55-6 56-23-5 106-06-4 75-27-4

DILUTION FACTOR: 1COLLECTED: December 4, 1985

PH NAANALYZED: narpmher IS- 1 Qftfi

ORDER #: ;

Chlornmethane Brpmpmethane Vinyl Chloride

Chloroethane Methylene Chloride

Acetone Carbon Disulfide 1. 1-Oichloroethene 1, 1-Dichloroethane Trans-1. 2-Dichloroethene

Chloroform 1. 2-Dichloroethane

2-Butanone 1,1, 1-Trichloroethane Carbon Tetrachloride Vinyl Acetate Bromodichloromethane

ug/Kfl CAS rcW On*) Number

7B-87-512-LL

10061-02-6

10 u 79-01-6 124-46-1

10 u

10 u 79-00-59 JB 71-43-2XL 10061-01-510 u

10 u 110-75-8 75-25-210 u 591-78-610 u 106-10-110 u 127-18-410 u 79-34-57 J 106-88-310 u 106-90-7iq u

10 u 100-41-4 100-42-5

JUL

% MOISTURE

1. 2-D»chloropropane Trans-1. 3-Dichloropropene Trichloroethene Dibromochloromethane 1.1. 2-Trichloroethane

Benzene cis-1. 3-Dichloropropene 2-Chloroethylvinylether Bromoform 4-Methyl-2-Pentanone

2-Hexanone Tetrachloroethene 1.1.2. 2-Tetrachloroethane

Toluene Chlorobenzene Ethylberuene Styrene Total Xylenes

NA

"9/Ldr ug/Kg Circle One)

10 U 10 u 6 J 10 U 1 J 9 J

10 U 10 U

10 U 10 U 10 U

3 J 10 U 6 J A J

2 J 10 U 7 J

SURROGATE RECOVERY:

1,1-DICHLOROETHANE du TOLUENE dB p-BROMOFLUOROBENZENE

93 113 120


U NR

J B

NOT DETECTED NOT REQUESTED PRESENT AT LESS ANALYTE PRESENT

THAN DETECTION IN BLANK

LIMIT

COMMENT:

APPROVED BY:DATE: February 28, 1986 Earl M. Hansen, Ph.D Manager WESTON Ana ly t ica l Labora tor ies



GCMS FILE NAME: 1217W002216GZACLIENT: MATR IX: WaterSCC-GWS-B-102BSAMPLE DESC: METHOD: (LCW) MED LEVEL CLP (Circle One8512-327-0040RFV #:

DATE

DATE

WORK

CAS Number

74-67-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 156-60-5 67-66-3 107-06-2 78-93-3 71-55-6 56-23-5 106-05-4

75-27-4

DILUTION FACTOR: 1COLLECTED: December 4, 1985 PH NAANALYZED: December 18, 1985

ORDER #:

CASf u9/pB^uC/Kfl

Chloromethane Bromomethane Vinyl Chloride

Chloroethane Methylene Chloride

Acetone Carbon DiauKide 1. 1-Dichloroethene 1, 1 -Dichloroethene Trans-1. 2-Dichloroethene

Chloroform 1, 2-Dichloroethane 2-Butanone 1.1, I'-Trichloroethane Carbon Tetrachloride Vinyl Acetate Bromodichloromethane

One) Number 78-87-515 10061-02-62 J 79-01-67 J 124-48-13 J 79-00-5 71-43-2 10061-01.-5

* * *

75 110-75-8920 75-25-2250 591-78-6610

* * * 106-10-1

127-18-4 79-34-5 106-88-3

* * * 106-90-7 100-41-410 u 100-42-54 J

75-69-4

% MOISTURE NA

f u9^Lerug/ltfl L——(Circle One)

1. 2-Dtchloropropane Tran*-1. 3-Dichloropropene Trichloroethene Dibromochloromethane V. 1. 2-Trichloroethane Benzene cit-1. 3-Dtchloropropene 2-Chloroethylvinylether Bromoform 4-Methyl-2-Pentanone

2-Hexanone Tetrachloroethene 1, 1.2. 2-Tetrachloroethane

Toluene Chlorobenzene Ethylbenzene Styrene Total Xylenes

270 10 U * * *

9 J

* * *

10 II 10 u 92

2.600 •k'k'k

* * *

* * *

* * *

* * *

530 * * *

Trichlorofluoromethane 8 J

SURROGATE RECOVERY:

1,1-DICHLOROETHANE di * *

TOLUENE dg JJJL p-BROMOFLUOROBENZENE 146


U NR

J

---

NOT DETECTED NOT REQUESTED PRESENT AT LESS THAN DETECTION LIMIT

COMMENT: ^^undetermined possible interference

***see dilution (lab dut>)

B - ANALYTE PRESENT IN BLANK

DATE: February 28, 1986 APPROVED BY:_ E a r l M . H a n s e n , P h . D Manager WESTON Ana ly t ica l Labora tor ies



CLIENT: GZA GCMS FILE NAME: 1217WQ02217

SAMPLE DESC: Lab

S C C - G W S - B - 1 0 2 B / n l m M A T R I X : W a t e r

RFV #: S s i z - s z y - o o ^ Q R P METHOD :~(LOV/) MED LEVEL C L P ( C i r c l e O n e )

DATE COLLECTED DECEMBER A, 1.985 DILUTION F A C T O R : 1,000

DATE ANALYZED DECEMBER 18, 1985 PH N/A X M O I S T U R E H/A

WORK ORDER #:

X»fl7£brufl/Kfl CAS ^ug/jWug/ICg

Number {Circle One! Number (Circle One)

7B-87-5 1. 2-Dtchloropropene 10000 u

CAS

74-87-3 Chloromethane 10000 u 10000 u 10061-02-6 Trans-1, 3-D*chloropropene 10000 u74-83-9 Bromomethane

79-01-6 Trichloroethene 5200075-01-4 Vinyl Chloride 10000 u 124-48-1 Dibromochloromethane 10000 u75-00-3 Chloroethane .10000 u 79-00-5 1 . 1 . 2 - T r » c h k > r o e t h a n e 8200 J75-09-2 Methylene Chloride 200000 B 71-43-2 Benzene 9300067-84-1 Acetone 1200000

10000 u 10061-01-5 cis-1. 3-D*chloropropene 10000 U75-15-0 Carton Disulfide 860 J 110-75-8 2-Chloroethylvinylether 10000 u75-35-4 1. 1-Dichloroethene

75-25-2 Bromoform 10000 u75-34-3 1. 1-Dichloroethane 10000 u 591-78-6 4 -Methyl-2 -Pentanone 29000156-60-5 Trans-1, 2-Dichloroethene 10000 u

3300 J 106-10-1 2-Hexanone 10000 u67-66-3 Chloroform 127-18-4 Tetrachtoroethene 20000107-06-2 1, 2-Dichioroethane 66000 79-34-5 1 . 1 , 2 , 2 - T e t r a c h l o r o e t h a n e b700 J78-93-3 2-Butanone AOOOOO 106-88-3 Toluene71-55-6 1 , 1 . 1 - T r i c h l o r o e t h a n e 23000 R 2 0 0 0 106-90-7 Chlorobenzene56-23-5 Carbon Tetrachloride 2200 J 15000 100-41-4 Ethylbenzene106-05-4 Vinyl Acetate 10000 U 12000 100-42-5 Stytene 700 J75-27-4 Bromodichloromethane 10000 U

Total Xylenes 29000

SURROGATE RECOVERY:

1,1-DICHLOROETHANE du 1 1 1 TOLUENE dg 120

p-BROMOFLUOROBENZENE 122


U - NOT DETECTED COMMENT: NR - NOT REQUESTED _____

J - PRESENT AT LESS THAN DETECTION LIMIT B - ANALYTE PRESENT IN BLANK

DATE: 7 ^ / ^ ? / %( . APPROVED BY:_ ( ' ^ _ E a r l M . H a n s e n , . P h . D

Manager WESTON Ana ly t ica l Labora tor ies



GCMS FILE NAME: 1217W002215GZAC L I E N T :

SCC-GWS-B-001A M A T R I X : WATERSAMPLE DESC:

METHOD LOUS MED L E V E L C L P ( C i r c l e O n e )RFU 2: 8512-327-0050

S 1 DATE COLLECTED: DECEMBER A, I985 DILUTION FACTOR:_

DATE ANALYZED: DECEMBER 18. 1985 PH N/A % M O I S T U R E N/A

WORK ORDER If:

/|)or ug/Kg CAS ^uq/Qpf uq/KflCAS fCirc Number (Circle One)Circle One]Number

78-87-5 1. 2-Dichloropropane 10 U74-87-3 Chloromethane 10 U 10061-02-6 Trans-1. 3-Dichloropropene 10 u74-83-9 Bromomethane 10 u 79-01-6 Trichloroethane 10 u75-01-4 Vinyl Chloride 10 u 124-46-1 Dibromochloromethane 10 u75-00-3 Chloroethane 10 u 79-00-5 1 , 1 , 2 - T r i c h l o r o e t h a n e 10 u75-09-2 Methylene Chloride 7 JB 71-43-2 Benzene 10 u67-64-1 Acetone 10 U

10 u 10061-01-5 cis-1. 3-Dichloropropene 10 u75-15-0 Carbon Disulfide 10 u 110-75-8 2-Chloroethylvinylether 10 u75-35-4 1. 1-Oichloroethene

75-25-2 Bromoform 10 u75-34-3 1, 1 -Dichloroethane 10 U 10 u 591-78-6 4-Methyl-2-Pentanone 10 u156-60-5 Trans-1. 2-Dichloroethene

106-10-1 2-He*anone 10 u67-66-3 Chloroform 10 u 127-18-4 Tetrachloroethene 10 u 107-06-2 1. 2-Dichloroethane 10 u 79-34-5 1 , 1 , 2 . 2 - T e t r a c h l o r o e t h a n e 78-93-3 2-Butanone 10 u 10 u 106-88-3 Toluene71-55-6 1 . 1 , 1 - T r i c h l o r o e t h a n e 10 u 10 u 106-90-7 Chlorobenzene 10 u 56-23-5 Carbon Tetrachloride 10 u 100-41-4 Ethylbenzene106-05-4 Vinyl Acetate 10 u 10 u 100-42-5 Styrene75-27-4 Bromodichioromethane 10 u 10 u

Total Xylenes 10 u

SURROGATE RECOVERY:

1 , 1 - D I C H L O R O E T H A N E d u 96 TOLUENE d8 1 1 0 p-BROMOFLUOROBENZENE US-


COMMENT:U - NOT DETECTED NR - NOT REQUESTED

J - PRESENT AT LESS THAN DETECTION LIMIT B - ANALYTE PRESENT IN BLANK

APPROVED BY: /l* /—DATE: ^ F a r 1 M . H a n s e n , P h . D

Manager WESTON Ana ly t ica l Labora tor ies

ROY F . WESTON



GCMS F ILE NAME: 1217W0022UG Z ACLIENT:

MATRIX: WATER S C C - Q A C - S B O O lSAMPLE DESC METHOD1: /lo\L) MED LEVEL C L P ( C i r c l e O n e )8512-327-0060RFW DILUTION FACTOR: 1DATE COLLECTED: December 1985

PH N/A % MOISTURE N/A DATE ANALYZED: December 18 , 1985

WORK ORDER # :

CAS (vg/bor up/Kg CAS (ug/yx ug/Kfl ^^cireto One) Number ^"nCircle One)Nutnbtr

78-87-5 1. 2-Dichloropropane 10 U74-87-3 Chloromethane 10 U 10 u 10061-02-6 Trans-1. 3-Dichloropropene 10 u74-83-9 Bromomethane

79-01-6 Trichloroethene 10 u75-01• Vinyl Chloride 10 u 124-48-1 Dibromochloromethane 10 u10 u75-0O-3 Chloroethane 79-00-5 1 , 1 . 2 - T r i c h l o r o e t h a n e 10 u76-09-2 Methylene Chloride 5 JB 71-43-2 Benzene 10 u67-84-1 Acetone 10 U 10061-01-5 cis-1. 3-Dichloropropene 10 u75-15-0 Carton Disulfide 10 U 110-75-8 2-Chloroethylvinylether 10 u75-35-4 1. 1-Dichloroethene 10 U 75-25-2 Bromoform 10 u 75-34-3 1, 1-Dichloroethane 10 U 591-78-6 4-Methyl-2-Pentanone 10 u156-60-5 Trans-1. 2-Dichloroethene 10 u 106-10-1 2-Hexanone67-86-3 Chloroform 10 u 10 u 127-18-4 Tetrachloroethene 10 u 107-06-2 1, 2-Dichloroethane 10 u 79-34-5 1 . 1 . 2 . 2 - T e t r a c h l o r o e t h a n e 10 u 78-93-3 2-Butanone 11 106-88-3 Toluene 10 u 71-55-6 1 . 1 . 1 - T r i c h l o r o e t h a n e 10 u 106-90-7 Chlorobenzerve56-23-5 Carbon Tetrachloride 10 u 10 u 100-41-4 Ethylbenzene108-05-4 Vinyl Acetate 10 u 10 u 100-42-5 Styrene 10 u 75-27-4 Bromodichloromethane 10 u

Total Xylenes 10 u

SURROGATE RECOVERY:

1,1-DICHLOROETHANE du 92

TOLUENE dg m. p-BROMOFLUOROBENZENE ]_n

Data repor t ing qua l i f ie rs :

COMMENT:U - NOT DETECTED

NR - NOT REQUESTED J - PRESENT AT LESS THAN DETECTION L IMIT


APPROVED BY:DATE: Ear l M. Hansen, Ph.D

f Manager WESTON Ana ly t ica l Labora tor ies

ROY F . WE. ST ON ORGANIC AMALYSIS DATA SUMMARY


CLIENT: GZA GCMS F ILE NAME: 1217W002213

SAMPLE DESC: SCC-QAC-TBOO1 MATRI X:_ Water

RFW i f : 8512-327-0080 METHOD: LOU MED LEVEL CLP (C i rc le One)

DATE COLLECTED: December k , 1985 DILUTION FACTOR: ]

DATE ANALYZED: December 17 , 1985 PH N/A % MOISTURE N/A

WORK ORDER # :

/ijorug/Kf/jjwUQ/Kfl CASCAS 4© Number ircte One)(Circle One)Number 78-87-5 1. 2-Dtchloropropane 10 U

74-87-3 Chloromethane 10 U 1 0 u 10061-02-6 Trana-1, 3-Dichloropropene 1 0 u

74-83-9 Bromomethane 79-01-6 Tr»chloroethene 1 0 u

75-01 Vinyl Chloride 1 0 u 124-48-1 Dibromochloromethane 1 0 u1 0 u75-00-3 Chloroethane 79-00-5 1 . 1 . 2 - T r i c h l o r o e t h a n e 1 0 u

76-09-2 Methylene Chloride 1 3 B 71-43-2 Benzene 1 0 u1067-84-1 Acetone 10061-01-5 cis-1. 3-D»chloropropene 1 0 u

75-15-0 Carbon DiauMkJe 10 tJ 110-75-8 2-Chloroethylvinylether 1 0 u75-35-4 1.1-Qichloroethene 10 U 75-25-2 Bromoform 1 0 u75-34-3 1. 1-Oichloroethene 1 0 u 591-78-6 4-Methyl-2-Pentanone

156-60-5 Trans-1. 2-Dichloroethene 1 0 u JJL-LL k J 106-10-1 2-Hexanone 10 U67-66-3 Chloroform

127-18-4 Tetrachloroethene 1 0 u107-06-2 1, 2-Dichlorqethane 1 0 u 79-34-5 1, 1. 2. 2-Tetrachloroethar>e 1 0 u78-93-3 2-Butanone 1 0 u 106-88-3 Toluene 1 0 u71-55-6 1 . 1 . 1 - T r i c h l o r o e t h a n e 3 J 106-90-7 Chlorobenzene 1 0 u56-23-5 Carbon Tetrachloride 1 0 u 100-41-4 Ethylbenzene 1 0 u106-05-4 Vinyl Acetate 1 0 u

1 0 u 100-42-5 Styrene 1 0 u75-27-4 Bromodichloromethane Tota l Xylenes (0 u

SURROGATE RECOVERY:

1 ,1-DICHLOROETHANE du TOLUENE d8 111 p-BROMOFLUOROBENZENE l l A


U - NOT DETECTED COMMENT:

NR - NOT REQUESTED J - PRESENT AT LESS THAN DETECTION L IMIT B - ANALYTE PRESENT IN BLANK

APPROVED BY:_ / . . fr- si, . / *DATE:

r ' ^ Ear lEar l M.M. Hansen,Hansen, Ph.DPh.D Manager WESTON Ana ly t ica l Labora tor ies



1217W002221GCMS F ILE NAME:GZACLIENT: WaterMATRIX:SCC-GWS-B-101ASAMPLE DESC:

CLP (C i re le One]METHOD: LOV; MED LEVEL R F W # : 8FI7-R?7-onqn

DILUTION FACTOR: ' ,000 D A T E r n i I F P . T E D : December 4, 1985 N/AX MOISTUREPH N/AD A T E A N A I Y Z E D : D e c e m b e r 1 8 , 1 9 8 5

WORK ORDER H:

/jjq/por ug/Kfl^/I>kuq/ICBCAS CAS (Circle One)(Circle On*) NumberNumber

78-87-5 1. 2-Dtchtoropropane 71 0 J10,000 u74-87-3 Chlorometharve 10061-02-6 Trans-1, 3-Dichloropropene 10,000 U10,000 u74-83-9 Bromomethane 79-01-6 Trichloroethane 160,00010,000 u75-01-4 Vinyl Chloride 124-48-1 Dibromochloromethane 10,000 U10,000 u75-00-3 Chloroethane 79-00-5 1.1. 2-Trichloroethane 780 J82,000 B75-09-2 Methylene Chloride 71-43-2 Benzene 8,500 J10,000 u67-84-1 Acetone 10061-01-5 cis-1. 3-Dichloropropene 10,000 U10,000 uCarbon Disulfide75-15-0 110-75-8 2-Chloroethylvinylether 10,000 U700 J1. 1-Dichloroethene75-35-4 75-25-2 Bromoform 10,000 u1,800 J75-34-3 1, 1 -Dichloroethene 591-78-6 4-Methyl-2-Pentanone 10,000 u10,000 uTrans-1. 2-Dichloroethene156-60-5 106-10-1 2-Hexanone 10_J)00 u3,500 J67-66-3 Chloroform 127-18-4 Tetrachloroethene i ,800 J

107-06-2 1, 2-Dichloroethane 20^000 79-34-5 1.1.2, 2-Tetrachloroethane 10,000 u10,000 u78-93-3 2-Butanone 106-88-3 Toluene 19,00053,0001.1. 1-Trichloroethane71-55-6 106-90-7 Chlorobenzene 600 J10.000 uCarbon Tetrachloride56-23-5 100-41-4 Ethylbenzene 7,800 J10,000 u106-05-4 Vinyl Acetate

10,000 u 100-42-5 Styrene 740 J 75-27-4 Bromodichlorpmethane

Total Xylenes 3 ,600 J

75-69-4 Tr ich loro f luoro- 5,000 methane

SURROGATE RECOVERY:

1,1-DICHLOROETHANE du 104 100TOLUENE dB "WP-BR0M0FLU0R0BENZENE

D a t a repor t ing qua l i f ie rs :

COMMENT:U - NOT DETECTED

NR - NOT REQUESTED THAN DETECTION LIMIJ - PRESENT AT LESS

B - • A N A L Y T E P R E S E N T IN BLANK

APPROVED BY: "DATE:

E a r l M . H a n s e n , P h . D Manager WESTON Ana ly t ica l Labora tor ies

ROY F . w t i iun ORGAM IC ANALYSIS DATA SUMMARY


217W002212 GZA GCMS F ILE NAME:

CLIENT: WaterMATRIX: _Tr ip B lankSAMPLE DESC:

LOU MED LEVEL CLP (C i rc le One)METHOD:8512-327-0100RFW •?:

DILUTION FACTOR : ]December k, 1985DATE COLLECTED

PH N/A % MOISTURE N/ADecember 17, 1985DATE ANALYZED

WORK ORDER # :

/\)of ug/Kg CAS(Sty*CAS (Circle One)Circle One) NumberICircNumbtr TO78-87-5 1. 2-Dichloropropane10 UChloromethane174-87-3 10061-02-6 Trana-1. 3-Dichloropropene 10 U0 uBromomethane74-93-9 79-01-6 Trichloroethene 1 0 u10 U75-01-4 Vinyl Chloride Dibromochloromethane 1 0 u124-48-11 0 uChloroethane75-00-3 79-00-5 1.1. 2-Trichloroethane 1 0 u8 JBMethylene Chloride75-09-2 10 U71-43-2 Benzene10 U67-64-1 Acetone

10 U 10061-01-5 cis-1. 3-Dichloropropene 1 0 u 75-15-0 Carbon Disulfide

10 U 110-75-8 2-Chloroethylvinylether 1 0 u 75-35-4 1. 1-Dichloroethene

75-25-2 Bromoform 1 0 u1 0 u1. 1-Dichloroethane75-34-3 591-78-6 4-Methyl- 2-Pentanone 1 0 u1 0 uTrans-1. 2-Dichloroethene156-60-5

106-10-1 2-Hexanone 1 0 u1 0 u67-66-3 Chloroform

127-18-4 Tetrachloroethene 1 0 u1 0 u1. 2-D*chk>roethane107-06-2 79-34-5 1.1,2. 2-Tetrachloroethane 1 0 u1 0 u79-93-3 2-Butanone 1 0 u106-88-3 Toluene

71-55-6 1,1. 1-Trichloroethane 1 0 u 106-90-7 Chlorobenzene 1 0 u10 uCarbon Tetrachloride56-23-5 100-41-4 Ethylbenzene I P u1 0 u106-05-4 Vinyl Acetate 100-42-5 Styrene 10 U1 0 uBromodichloromethane75-27-4 Total Xylenes 1 0 u

SURROGATE RECOVERY:

1 ,1-DICHLOROETHANE du 1 0 1

TOLUENE dg 108

p-BROMOFLUOROBENZENE 109


nnr rTrn COMMENT: U - NOT DETECTED NR - NOT REQUESTED

J - PRESENT AT LESS THAN DETECTION L IMIT


n l t i ^L APPROVED BY: DATE: —' '— Hansen» Ph,D

Manager n r c t n u S n i l u t - i r a l I ahnratO

ROY F. WESTON SUMMARYORGANIC ANALYSIS DATA LIST COMPOUNDSVOLATILE HAZARDOUS SUBSTANCE

GCMS F ILE NAME: 1217W002199GZACLIENT: MATRIX: Water

Lab B lankSAMPLE DESC: (C i rc le OneiMETHOD: / 'LOW) MED LEVEL CLP

BGl7-R27-B1ankRFV/ * : 1DILUTION FACTOR

DATE COLLECTED: NA ; % MOISTURE N/APH N/A

DATE AKIAIYZED: December 17 , 1985

WORK ORDER H:

(og/j)or ug/KgCAS ircke One)CAS (Circl

(Circle OneJ Number Number

78-87-5 1. 2-D*chk>ropropane 10 U10 UChloromethanei74-67-3 10061-02- 6 Tran»-1, 3-Dichloropropene 10 u10 uBromomethane74-83-9 79-01-6 Trichloroethane 10 u10 u

75-01-* Vinyl Chloride 24-48-1 Dibromochloromethane 10 u10 uChloroethane75-00-3 79-00-5 1,1. 2-Trichloroethane 10 u

2 J75-09-2 Methylene Chloride 71-43-2 Benzene 10 u

10 U67-64-1 Acetone 10061-01-5 ci$-1, 3-Dichloropropene 10 u

10- UCarbon Disulfide75-15-0 110-75-8 2-Chloroethylvinylether 10 u10 U1. 1 -Oichloroethene75-35-4 75-25-2 Bromoform 10 u10 U1. 1-Oichloroethene75-34-3 591-78-6 4-Methyl-2-Pentanone 10 u10 uTrans-1 . 2-D ich loroethene 156-60-5

106-10-1 2-Hexanone 10 u10 u67-66-3 Chloroform

127-18-4 Tetrachloroethene 10 u10 u1. 2-Dtchtoroethane107-06-2 79-34-5 1. 1,2. 2-Tetrachloroethane 10 u10 u2-Butanone78-93-3 108-88-3 Toluene 10 u10 u1 1, 1-Trichloroethane71-55-6 106-90-7 Chlorobenzene 10 u10 uCarbon Tetrachloride56-23-5 100-41-4 Ethylbenzene 10 u10 u106-05-4 Vinyl Acetate 100-42-5 Styrene 10 u10 uBromodichloromethane75-27-4 Total Xylenes 10 u

SURROGATE RECOVERY: 1,1-DICHLOROETHANE du 105 TOLUENE dB 101 p-BROMOFLUOROBENZENE 98

D a t a , r e p o r t i n g q u a l i f i e r s :

.CTr rTrn COMMENT: u - NOT DETECTcD NR - NOT REQUESTED

J - PRESENT AT LESS THAN DETECTION L IMIT

B - ANALYTE PRESENT IN BLANK .

"Z APPROVED BY: • „ ! /• Ear l M. Hansen, Ph.D

' Manager WESTON Ana ly t ica l Labora tor ies

ROY F. WESTON, INC. ORGANIC ANALYSIS DATA SIWIARY

SEMI-VOLATILE HAZARDOUS SUBSTANCE LIST COMPOUNDS

GZA GC/MS FILE NAME: 0106B1603CLIENT: , _ SAMPLE DESC: _ SCC-GWS-B-105A MATRIX: Water ,DCU #• 8512-327-0010

December 4, 1985 METHOD: LOW/MED LEVEL CLP (Circle One)DATE COLLECTED: DATE EXTRACTED: December 8, 1985

DETECTION LIMIT: 10 ug/LDATE ANALYZED: January 6, 1986 D.F . : l xWORK ORDER #:

CAS Number

106-95-2

541-73-1 106-46-7 100-51-6 95-50-1 95-48-7 39638-32-9 106-44-5 621-64-7 67-72-1 9B95-3 78 59-1 88-75-5 105-67-9 65-85-0 111-91-1 120-83-2 120-82-1

91-20-3 106-47-8 87-68-3 59-50-7 91-57-6 77-47-4 88-06-2

95 95-4 91-58-7 88 74-4 131-11-3 206 96-8 99-09-2

Phenol bn(-2.-Chloroethyl(Ether 2-Chlorophenol

3-Dichlorobenzene 4-Dichlorobenzene

Benzyl Alcohol 1. 2-Dichlorobenzene 2-Methylphenol bis(2-chloroisopropyl(Ether 4-Methylpheni>l N-Nitroso-Di-n-Propylamtne Hexachloroethane Nitrobenzene Isophorone 2-Nttrophenol 2. 4-Dimethylphenol Benzoic Acid HI bisN2-Chloroethoxy(Methane 2. 4-Dichlorophenol 1. 2. 4-7nchlorobenzene Naphthalene 4-Chloroaniline Hexachlorobutadiene 4-Chloro-3-Methylphenol 2 -Methylnaphthalene Hexachlorocyclopentadiene 2. 4. 6-Tnchlorophenol 2. 4. 5-Tnchlorophenol ( 2 ) 2-Chloronaphthalene 2-Nitroaniline 111 Dimethyl Phthalate Acenaphthylene 3-Nitroamhne in

ug/l or ug/Kg (Circle One)

24 ND

20 ND

CAS ug/l or wg /Kg Number (Circle One

83 32-6 Acenaphthene ND 51-28-5 2. 4-Dinitrophenpl 00-02-7 4-Nitrophenol 32-64 9 Dibenzofuran 21-14-2 2 4-Dinitrotoluene

606-20-2 2 6-Dinitrotoluene 84-66-2 Diethylpnthalate 7005-72-3 4-Chlorophenyl-phenylether 86-73-7 Fiuorene 100-01-6

534-52-1 4-Nitroaniline 111 4, 6-Dinitrp-2-Methylphenol FT

86-30-6 N-Nitrpsodiphenylamme (1! 101-55-3 4-Brpmophenyl-phenylether 118-74-1 Hexachlorobenzene 87-86-5 Pentachlorophenol in 85-01-8 Phenanthrene 120-12-7 Anthracene 84-74-2 Di-n-Butylphthalate 206-44-0 Fluoranthene 129-00-0 Pyrene B5-68-7 Butylbenrylphthalate (91-94-1 3, 3'-Dichlorobenzidine (3T 56-55-3 Benzo(a(Anthracene 117-81-7 bis(2 -Ethylhexyl)Phthaiate 5J 218-01-9 Chrysene ND 117-84-0 Di-n-Octyl Phthalate £205-99-2 Benzo(b)Fluoranthene 207-08-9 Benzo(k(Fluoranthene 50-32-8 Benzo(a(Pyrene 193-39-5 lndeno<1.2. 3-ctJ(FVrene 53-70-3 Dibenz(a hlAnthrecene 191-24-2 Benzo^g. h. iperylene

{l) Cannot be separated from Diphenylamine ( ) MDL = 5X other HSL Compounds (3) MDL = 2X other HSL Compounds

U = NOT DETECTED J = PRESENT AT LESS THAN DETECTION LIMIT NR = NOT REQUESTED B = ANALYTE FOUND IN BLANK

Approved By: DATE: February 28, 1986 Earl M. Hansen, Ph.D.

Manager WESTON Analytical Laboratories

ROY F. WESTON, INC. ORGANIC ANALYSIS DATA SIW1ARY


GZA GC/MS FILE NAME: O1O9B1630CLIENT: SAMPLE DESC: _ ac.c - Gtujs -is-iosf t MATRIX: Dry m- 8512-327-0020 Sp ike

METHOD: ^LOW^MED LEVEL CLP (C i r c l e One )DATE COLLECTED: QACT.V.. DATE EXTRACTED: > r K , H 8 > ~ DETECTION LIMIT lOuq/LDATE ANALYZED:

D .F . : \ AWORK ORDER #:•

CAS Number

f ug Kg (Circle One)

CAS Number

(uflT^Pr ug 'Kg (Circle Ona

06-95 2 Phenol A8 83 32-9 Actnaphthene AO

95-57-8

11- A A A

541-73-1

bis( - 2- Ch)oroethyl)Eiher Chlorophenol 3-Dichlorobenzene

10 U

_20. 1 0

1-28-6 00-02-7 32-64 9

42. 4-Dinitrophenol

Nitrophenol Dibenzoluran

50

50 10

U

u 06-46-7 4-Dichlorobenzene TT 21-14-2 2 4:Dinitrotoluene A2

100-51-6 Benzyl Alcohol 10 u 606-20-2 2 6-Dinitrotoluene 10 U

95-50-1 2-Dichlorobenzene 5 J 84-66-2 Diethylphthalate

95-48-7 2-Methylphenoi 10 u 7005-72-3 4-Chlorophenyl-phenylether

39638-32-9 bts(2-Chloroisopropyl)Ether 10 u 86-73-7 Fluorene

106-44-5 621-64-7

4-Methylphenol N-Nitroso-Di-n-Propytamine': ki 534-52-1

00-01-6 4-Nitroanihne ill 4, 6-Dinitro-2-Methylphenol PT

50

50

U

U

67-72-1 Hexachtproethane 10 u 86-30-6 N-Nitrosodiphenylamme (1 ] 10 U

98-95-3 Nitrobenzene 101-55-3 4-Bromophenyl-phenylether

78-59-1 Isophorone 118-74-1 Hexachlorpbenzene

BB-75-5 2-Nitrophenol (87-86-5 Pentachlorophenot in 1 1 0

105-67-9 2, 4-Dimethylphenol 85-01-8 Phenanthrene 10 U

65-85-0 111-91-1 120-83-2

Benzoic AciO M bis' - 2-Chlorpethoxy)Methane 2. 4-Dichlorophenpl

61

10 10

U u

120-12-7 (84-74-2 206-44-0

Anthracene Di-n-Butylphthalate Fluoranthene

10 36 10

u

u 120-82-1 1. 2. 4-Tnchlorobenzene 37 129-00-0 Pyrene 37 91-20-3 Naphthalene 10 U B5-68-7 Buiyibenzyiphthalate 10 U

106-47-8 4-Chloroantltne 91-94-1 3. 3 -Dichlorobenzidine ( 3~J 20 U

87-68 3 Kexachlorobutadiene (56-55-3 Benzo<a(Anthracene 10 U

59-50-7 91-57-6

4-Chloro-3-MethylphenoP 2-Methylnaphthalene

88 10 U

117-81-7 (218-01-9

bis/2-Ethylhexylphthalate Chrysene

19 10 u

77-47-4 Hexachlorocyclopentadiene 117-84-0 Di-n-Octyl Phthalate

88-06-2 2. 4. 6-Trich)orophenol 205-99-2 Benzo(b)FIuoranthene

95 95-4 2. 4, 5-Trichlprophenol ( 2 ) 50 U 207-08-9 Benzo(k)Fluoranthene

91-58-7 2-Chloronaphthalene 10 U 50-32-8 Benzo(apvrene

88 74-4 2-Nitroaniline 111 50 U 193-39-5 IndenoQ.2. 3-cd)Pyrene

131-11-3 Dimethyl Phthalate 10 U 53-70-3 Dibenzta hlAnthracene

208-96-8 Acenaphthylene 10 U 191-24-2 Benzo(fl h. iperylene

99-09-2 3-Nitroaniline 111 50 U ( x ) Canno t be sepa ra ted f r om D ipheny lam ine ( ) MDL = 5X other HSL Compounds (3) MDL = 2X other HSL Compounds

U = NOT DETECTED J = PRESENT AT LESS THAN DETECTION LIMIT NR = NOT REQUESTED B = ANALYTE FOUND IN BLANK -i.

S p i k e d C o m p o u n d s Approved By: Ac

DATE: February 28, 1986 yr, Earl M. Hansen, Ph.D. Manager WESTON Analytical Laboratory

ROY F. WESTON, INC. ORGANIC ANALYSIS DATA SIWIARY


GZA GC/MS FILE. NAME: 01 09B1629 ' CLIENT: SCC-GWS-B-102ASAMPLE DESC: _ MATRIX: Water 8512 -327 - 0030RFW #: December T95T METHOD: (^LOW)MED LEVEL CLP (C i r c l e One )DATE COLLECTED: December 8 ,DATE EXTRACTED: DETECTION LIMIT: 10 ug /LJanuary 9 , 1953"DATE ANALYZED:

D . F . : 1WORK ORDER #:

(S)1[ugji or ug /Kg CAS or wg /Kg<S>«CAS (CircleOna) Number (Circle OneNumber

83 32-9 Acenaphthene 10 U 06-95-2 Phenol 10 U 51-28-5 2, 4,-Dinnrophenpl 50 U11-44-4 bi»(-2-Chloroethyl)Ether 00-02-7 4-Nitrophenpl 50 U95-57-8 2-Chlorophenol 32-64 9 Dibenzoturan 10 U 541-73-1 3-Dichlprobenzene 21-14-2 2 4-Dinitrotoluene106-46-7 1, 4-Dichlorobenzene

606 20-2 2 6-Dinitrotoluene100-51-6 Benzyl Alcohol I84-66-2 Diethylphthalate95-50-1 1. 2-Dichlorobenzene 7005-72-3 4-Chlorophenyl-phenylether95-48-7 2-Methylphenol 86-73-7 Fluorene39638-32-9 bis(2-chloroisopropyl(Ether

00-01-6 4-Nitroaniline106-44-5 4-Methylphenol 111 50 U

N-Nitroso-Di-n-Propylamine 534-52-1 4, 6-Dinitro-2-Methylphenol C 2 ) 5 0 u621-64-7 86-30-6 N-Nitrosodiphenylamine (1) 10 u67-72-1 Hexachloroethane 101-55-3 4-Bromophenyl-phenylether98-95-3 Nitrobenzene 118-74-1 Hexachlorobenzene78-59-1 Isophorone 87-86-5 Pentachlorpphenol88-75-5 2-Nitrophenol *?Q uHI 85-01-8 Phenanthrene105-67-9 2. 4-Dimethylphenol 10 u 120-12-7 Anthracene65-85-0 Benzoic Acid 50 UHI

10 U 84-74-2 Di-n-Butylphthalate111-91-1 btsl- 2-Chloroethoxy(Methane 206-44-0 Fluoranthene120-83-2 2. 4-Dichlorophenol 129-00-0 Pyrene120-82-1 1. 2. 4-Trichlorobenzene B5-68-7 Butylbenzylphthaiate91-20-3 Naphthalene 91-94-1 3. 3 -Dichlorobenzidine ( 3~J106-47-8 4-Chloroaniline 20 U

87-68 3 Kexachlorobutadiene 56-55-3 Benzo<a(Anthracene 10 u 117-81-7 bis(2-Ethylhexyl)Phthalate A J59-50-7 4-Chloro-3-Methylphenol

91-57-6 2-Methylnaphthalene 218-01-9 Chrysene 10 u 117-84-0 Di-n-Octyl Phthalate77-47-4 Hexachlorocydopentadiene 205-99-2 Benzo(b)Fluoranthene88-06-2 2. 4. 6-Tnchlorophenol 207-08-9 Benzolk )FIuoranthene95 95-4 2. 4 5-Trichlorophenol ( 2 ) 50 U 50-32-8 Benzo<apyrene51-58-7 2-Chloronaphthalene 10 u 193-39-5 lndeno(1. 2. 3-cd)Pyrene88 74-4 2-Nitroanihne 50 U111 53-70 3 Dibenzla hIAnthracene131-11-3 Dimethyl Phthalate 10 u

206-96-8 Acenaphthyiene 10 u 191-24-2 Benzoic h. iperylene

99-09-2 3-Nitroaniline 111 50 U i 1 ) Cannot be separated from Diphenylamine (2 ) MDL = 5X o the r HSL Compounds ( 3 ) MDL = 2X o the r HSL Compounds

U = NOT DETECTED' J = PRESENT AT LESS THAN DETECTION LIMIT NR = NOT REQUESTED B = ANALYTE FOUND IN BLANK

6^/*— St*Approved By: DATE: /%(> —Earl M. Hansen, Ph.D.


ROY F. WESTON, INC. ORGANIC ANALYSIS DATA SUWARY

SEMI-VOLATILE HAZARDOUS-SUBSTANCE LIST COMPOUNDS

GC/MS FILE NAME: 0109B1631 & 011IB1660f1:10 dilu-

MATRIX: Wat^r _ tion;

METHOD: OW^MED LEVEL CLP (C i r c l e One )

DETECTION LIMIT:_ 10 ug/LD.F.: lx & "lOx*

/J-or ug / Kg CAS ug'Kg (Circle One) Number (Circle One

83 32-9 Acenaphihene 10 U10 U 1-28-5 2. 4-Dinitrophenpl 50 U 00-02-7 4-Nitrophenpl 32-64 9 Dibenzoluran 10 U 21-14-2 2 4-Dinitrotoluene

606-20-2 2 6-DinitrotolueneII 84-66-2 Diethylphthalate10 u 7005-72-3 4-Chlorophenyl-phenylethcr 86-73-7 Fluorene 100-01-6 4-Nltroaniline 50 U111 534-52-1 4, 6-Dinitro-2-Methylphenol FT 86-30-6 N-Nitrosodiphenylamine (1) 10 U 101-55-3 4-Bromophenyl-phenylether 118-74-1 Hexachlorobenzene1700* (87-86-5 Pentachlorophenol 50 U10 U m 85-01-8 Phenanthrene 10 U 120-12-7 Anthracene50 U 84-74-2 Di-n-Butylphthalate10 U 1206-44-0 Fluoranthene 129-00-0 Pyrenc B5-68 7 Butylbenrylphthaiate 91-94-1 3. 3 -Dichlprobenzidine (3"7 20 U 56-55-3 Benzo<a(Anthracene 10 U 117-81-7 bis<2 -EthylhexyljPhthalate 218-01-9 Chrysene 117-84-0 Di-n-Octyl Phthalate -105-99-2 Benzo<b)Fluoranthene :07-08-9 Benzo(lc(Fluoranthene50 U bO-32-8 Benzo(a(Pyrene10 U

50 U 193-39-5 lrvdeno<1. 2. 3-cd)FVene

10 U S3-70-3 Dibenzia hlAnthracene 1191-24-2 Benzo<p. h. i)Perylene

50 U ( 1 ) Canno t be sepa ra ted f r om D ipheny l am ine ( 2 ) MDL = 5X o the r HSL Compounds ( 3 ) MDL = 2X o the r HSL Compounds

CLIENT: SAMPLE DESC: _ RFW #: DATE COLLECTED: DATE EXTRACTED: DATE ANALYZED: WORK ORDER

CAS Number

106-95-2 11-44-4

95-57-8 541-73-1 106-46-7 100-51-6 95-50-1 95-48-7 39638 32-9 106-44-5 621-64-7 67-72-1 98-95-3 78 59-1 88-75-5 105-67-9 65-85-0 111-91-1 120-83-2 120-82-1

91-20-3 106-47-8 87-68 3 59-50-7 91-57-6 77-47-4 88-06-2

95 95-4 91-58-7 88-74-4 131-11-3 206 96-8 99-09-2

#:

GZA SCC-GWS-B-102B 8512-327-0040 December 4. 1985 December 8, 1985 January 9. 1986

Pnenol sl-2-Chloroethyl(Ether -Chiorophenol 3-Dichlorobenzenc 4-Dichlorobenzene

Benzyl Alcohol . 2-Dichlorobenzene

2-Methylphenoi bis(2-chloroisopropyl(Ether 4-Methylphenol N-Nitroso-Di-n-Propylamme Hexachloroethane Nitrobenzene Isophorone 2-Ni!rophenol 2, 4-Dimethylphenol Benzoic Acid in

is(-2-Chloroethoxy(Methane 2. 4-Dichlorophenol 1. 2. 4-Trichlorobenzene Naphthalene 4-Chloroaniline Hexachlorobutadiene 4-Chloro-3-Methylphenol 2-Methylnaphthalene Hexachlorocyclopentadiene 2, 4. 6-Trichlorophenol 2. 4. 5-Tnchlorophenol ( 2 ) j 2-Chloronaphthalene 2-Niuoanilme ill Dimethyl Phthalate Acenaphthylene 3-Nitroaniline ill

J = PRESENT AT LESS THAN DETECTION LIMITU = NOT DETECTED NR = NOT REQUESTED B = ANALYTE FOUND IN BLANK



ROY F. WESTON, INC. ORGANIC ANALYSIS DATA SUftlARY


GZA GC/MS FILE NAME Oil1B1656CLIENT: SAMPLE DESC: SCC-GWS-B-OOIA MATRIX : Water RFU #• 8512-327-0050

DATE COLLECTED: December 4, 1985 METHOD: LOW/MED LEVEL CLP (Circle One) DATE EXTRACTED: December 8, 1985 DATE ANALYZED: January 11, 1986 . DETECTION LIMIT; 10 ug/L

D.F . : l xWORK ORDER #:

CAS ug/I or ug/ Kg CAS ug /Ior ug 'Kg Number (Circle One) Number (Circle One

83 32-9 Acanaphthene106-95 2 Pnenol 10 U 10 U

111-44-4 bis(-2-Chloroethyl)Ether 51-28-5 2. 4-Dinitrpphenpl 50 U

95-57-8 2-Chlprophenpl 00-02-7 4-Nitrophenol 50 U 132-64 9 Dibenzofuran 10 U541-73-1 1. 3-Dichlprobenzene 121-14-2 2 4-Dinitrotoluene106-46-7 1. 4-Dichlorobenzene 606-20-2 2 6-Dinitrotoluene100-51-6 Benzyl Alcohol

95-50-1 1. 2-Dichlprobenzene 84-66-2 Diethylphthalate 7005-72-3 4-Chlorophenyl-phenylethei95-48-7 2-Methylphenpi I86-73-7 Fluorene 10 U39638-32-9 bis(2-chloroisopropyl)Ether 100-01-6 4-Nitroaniline 50 U106-44-5 4-Methylphenol lil

621-64-7 N-Nitroso-Di-n-Propylamine 534-52-1 4, 6-Dinitro-2-Methylphenol (2)50 U

Hexachloroethane 86-30-6 N-Nitrosodiphenylamine (1) 10 U67-72-1 Nitrobenzene 101-55-3 4-Brpmophenyl-phenylether 10 U98-95-3

118-74-1 Hexachlprobenzene 10 U78-59-1 Isophorone

88-75-5 2-Nitrophenol 87-86-5 Pentachlorpphenpl 50 UM 05-67-9 2. 4-Dimethylphenol 85-01-8 Phenanthrene 10 u

120-12-7 Anthracene65-85-0 Benzoic Acid 50 UHE 111-91-1 bis'-2-Chloroethoxy)Methane 10 U 84-74-2 Di-n-Butylphthalate

1206-44-0 Fluoranthene120-83-2 2. 4-Dichlorophenol 129-00-0 Pyrene B5-68-7 Butylbenzylphthaiate 10 u

120-82-1 1. 2. 4-Trichlorobenzene

91-20-3 Naphthalene 3. 3-Dichlorobenzidme (3)106-47-8 4-Chloroaniline B1-94-1 20 U

56-55-3 Benzo<a (Anthracene 10 U87-68 3 Hexachlprobutadiene 117-81-7 bis<2-Ethylhexyl)Phthalate59-50-7 4-Chloro-3-Methylphenol

91-57-6 2-Methylnaphthalene [218-01-9 Chrysene 117-84-0 Di-n-Octyl Phthalate77-47-4 Hexachlorocyclopentadiene 205-99-2 Benzo(b)Fluoranthene88-06-2 2. 4. 6-Trichlorophenol 10 U

95 95-4 2. 4. 5-Tnchlprophenol ( 2 ) 50 U 207-08-9 Benzo<k)Fluoranthene

91-58-7 2-Chloronaphthalene 10 U 50-32-8 Benzo(a(Pyrene

88-74-4 2-Nitroanilme 111 50 U 193-39-5 IndenoO. 2. 3-ci3)Pyrene

131-11-3 Dimethyl Phthalate 10 U 53-70-3 Dibenzja hVknthracene

Acenaphthylene imr [191-24-2 Benzo^g. h, iPerylene 10 u206-96-8 3-Nitroaniline 50 U99-09 2 111 ( x ) Canno t be sepa ra ted f r om D ipheny l am ine

( 2 ) MDL = 5X o the r HSL Compounds ( 3 ) MDL = 2X o the r HSL Compounds




ROY F. WESTON, INC. ORGANIC ANALYSIS DATA SIM1ARY


CLIENT: GZA GC/MS FILE NAME: 0111 B16 5 7

SAMPLE DESC: _ SCC-QAL-SB-001 MATRIX: WaterDCU #• 8512-327-0060 DATE COLLECTED: December A , 1985 METHOD: (LOOMED LEVEL CLP (C i r c l e One ) DATE EXTRACTED: December 8 , 1985 DATE ANALYZED: Janua ry 11 , 1986 DETECTION LIMIT: 10 uq/L

WORK ORDER #: D .F . :

CAS 'CuB /Lor ug/ Kg CAS Number "^Circle One) Number (Circle One' 106-95 2 Phenol 10 U 83 32-9 Acenaphthene 10 U 11-44-4 bis(-2-Chloroethyl)Ether 51-28-5 2, 4-Dinitroph#nol 5 0 U

95-57-8 2-Chlorophenol 100-02-7 4-Nitrophenol 50 u 541-73-1 1 3-Dichlorobenzene 132-64 9 Dibenzcluran 10 u 106-46-7 1. 4-Dichlorobenzene 121-14-2 2 4-Dinitrotoluene

100-51-6 Benzyl Alcohol 606-20-2 2. 6-Dinitrotoluene

95-50-1 1. 2-Dichlorobenzene 64-66-2 Diethylphthalate

95-48-7 2-Methylphenol 7005-72-3 4-Chlorophenyl-phenyleTher

39638-32-9 bis(2-chloroisopropyl)Ether 186-73-7 Fluorene

106-44-5 4-Methylphenol 100-01-6 4-Nilroaniline 50 uill 621-64-7 N-Nitroso-Di-n-Propylamine 534-52-1 4, 6-Diniiro-2-Methylphenol )50 U 67-72-1 Hexachlproethane 86-30-6 N-Nitrosodiphcnylamme (11 10 u 98 95-3 Nitrobenzene 101-55-3 4-Brpmophenyl-phenylether

78 59-1 Isophorone 118-74-1 Hexachlprobenzene

88-75-5 2-Nitrophenol 87-86-5 Pentachlorophenol 50 u in 105-67-9 2. 4-Dimeihylphenol 85-01-8 Phenanthrene 10 u 65-85-0 Benzoic AciO 50 U 120-12-7 Anthracenein 111-91-1 bisl-2-Chloroethoxy)Methane 10 U 84-74-2 Di-n-Butylphthalaie

120-83-2 2. 4-Dichlorophenol 206-44-0 Fluoranthene

120-82-1 1. 2. 4-Trichlorobenzene 129-00-0 Pyrene 91-20-3 Naphthalene 85-66-7 Butylbenzylphthaiate

106-47-8 4-Chloroaniline 91-94-1 3 3'-Dichlorobenzidine (3) 20 U 87-68 3 Hexachlorobutadiene 56-55-3 BenzcKa(Anthracene 10 u 59-50-7 4-Chlpro-3-Methylphenol 117-81-7 bis(2-Ethylhexyl)Phthalate

91-57-6 2-Methylnaphth*lene [218-01-9 Chryaene

77-47-4 Kexachlorocvclopentadiene 117-84-0 Di-n-Octyl Phthalate

88-06-2 2. 4. 6-Trichlorophenol 205-99-2 Benzo(b)Fluoranthene

95 95-4 2. 4. 5-Trichlorophenol ( 2 j AO I I 207-08-9 Benzo(k)Fluoranthene

91-58-7 2-Chloronaphthalene 10 U 50-32-8 Benzo<apyrene

88-74-4 2-Nitroanilme 50 U 193-39-5 lndeno(1.2. 3-cd)Pyreneill 131-11-3 Dimethyl Phthalate 10 U 53-70-3 DibenzjahVAnthracene

206 96-8 Acenaphthylene 10 U II91-24-2 Benzofa. h, i)Perylenc

99-09-2 3-Niuoamline 50 U ill C1) Canno t be sepa ra ted f r om D ipheny l am ine ( 2 ) MDL = 5X o the r HSL Compounds ( 3 ) MDL = 2X o the r HSL Compounds


DATE: y -

'2-/^3/ o C Approved By:


ROY F, WESTON, INC. ORGANIC ANALYSIS DATA SUWARY


011 TBI 658 GZA GC/MS FILE NAME: 0111B1661 (1 :10 D i lu t ion)CLIENT: S C C - G W S - B - 1 0 1 ASAMPLE DESC: _ MATRIX: Water 8512-327-0090RFW #:

DATE COLLECTED: December A . 1985 METHOD: ("LOOMED LEVEL CLP (C i r c l e One ) DATE EXTRACTED: December 8 , 1985

DETECTION LIMIT: 10 uq/LDATE ANALYZED: Janua ry 11. 1986 D .F . : 1 x & 1 OxWORK ORDER #:

CAS /IJbf ugKg CAS sug'J/©rug/Kg

Numtor ire to One) Number lircto Or*1

106-95 2 Pnenpl 10 U 83 32 9 Acanaphthene 10 U

111-44-4 bis(-2-Chloroethyl)Elher 10 u 51-28-5 2, 4-Dinnrophenpl 50 U

95-57-8 2-Chlprophenol " 80 00-02-7 4-Nitfophenpl 50 U

541-73-1 1 3-Dichlorobenzene 1 2 0 132-64 9 Dibenzoturan 10 U

106-46-7 1. 4-Dichlorpbenzene 390 121-14-2 2 4-Dinitrotoluene

100-51-6 Benzyl Alcohol 1 AOO 606-20-2 2. 6-Dinitrotolciene

95-50-1 1. 2-Dichlorobenzene " 900 84-66-2 Diethylphthalate

95-48-7 2-Methylphenol 170 7005-72-3 4-Chlorophenyl-phenylethei

39638-32-9 bis(2-chloroisoprppyl)Ether 10 U 86-73-7 Fiuorene

106-44-5 4-Methylphenol 100-01-6 4-Nitroaniline 111 50 U

621-64-7 N-Nitroso-Di-n-Propylamme 534-52-1 4, 6-Dinitro-2-Methylphenol T3S"

67-72-1 Hexachloroethane B6-30-6 N-Nitrosodiphenylamine (1) 10 u 98 95-3 Nitrobenzene 101-55-3 4-Bromophenyl-phenyletner

78-59-1 Isophorone * 1900 118-74-1 Hexachlorobenzene

88-75-5 105-67-9

2-Nitrophenol 2. 4-Dimethylphenol

10 10

U U

87-86-5 185-01-8

Pentachlorophenol Phenanthrene

IN 50 10

U u

65-85-0 Benzoic Acid HI 50 U 120-12-7 Anthracene

111-91-1 bis' 2-Chloroethoxy)Methane 10 U 84-74-2 Di-n-Butylphthalaie

120-83-2 2. 4-Dichlorophenol 10 U 206-44-0 Fluoranthene

120-82-1 1. 2. 4-Trichlorobenzene * 270 129-00-0 Pyrene

91-20-3 Naphthalene 130 85-68-7 Butylbenrylphthalate

106-47-8 4-Chloroaniline 10 U 91-94-1 3, 3 -Dichlorobenzicine (3 ) 20 U

87-68 3 Hexachlorobutadtene 10 U B6-55-3 BenzcKa(Anthracene 10 U

59-50-7 4-Chloro-3-Methylphenol" 1 AO 117-81-7 bis(2-Ethylhexyl)Phthalate

91-57-6 2 -Methytnaphthalene 10 U 218-01-9 Chrytene

77-47-4 Hexachlorocyclopentadiene 117-84-0 Di-n-Octyl Phthalate

88-06-2 2. 4. 6-Tnchlorophenol 205-99-2 Benzo(b)Fluoranthene

95 95-4 2. 4. 5-Tfichlorophenol ( 2 ) 50 U 207-08-9 Benzo(k)Fluoranthene

91-58-7 2-Chloronaphthalene 10 U 50-32-8 Benzo<a (Pyrene

88 74-4 2-Nitroaniline 111 50 U 193-39-5 IndenoO. 2. 3-cd)Pyrene

131-11-3 Dimethyl Phthalate 180 53-70-3 Dibenzia hlAnthracene

206 96-8 Acenaphthytone 10 u 191-24-2 Benzo^g. h. iPerylene

99-09-2 3-Nitroaniline 111 50 U ( x ) ( 2 )

C a n n o t b e s e p a r a t e d f r o m D i p h e n y l a m i n e MDL = 5X o the r HSL Compounds

( 3 ) M D L = 2 X o t h e r H S L C o m p o u n d s


DATE* February 28, 1986 Approved By:


ROY F. WESTON, INC. ORGANIC ANALYSIS DATA SUMMARY

SEMI-VOLATILE HAZARDOUS S.UBSTANCE LIST COMPOUNDS

CLIENT: SAMPLE DESC:

DATE*COLLECTED: DATE EXTRACTED: DATE ANALYZED: WORK ORDER

CAS Number

106-95-2 111-44-4

95 57-8 541-73-1

106-46-7 100-51-6 95-50-1 95-48-7 39638-32-9 06-44-5

621-64-7 67-72-1 98-95-3 78-59-1 88-75-5 105-67-9 65-85-0 111-91-1 120-83-2 120-82-1

91-20-3 106-47-8 87-68 3 59-50-7 91-57-6 77-47-4 88-06-2 95 95-4 91-58-7 88 74-4 131-11-3 206 96-8 99-09-2

#:

GZA GC/MS FILE NAME: 0106B1593

Lab Blank Batch 308 MATRIX: . Water 8512-327-Blank N/A METHOD: LOW/MED LEVEL CLP (C i r c l e One ) December 8, 1985 January 6, 1986 . DETECTION LIMIT: 10 ug/L

Phenol bi$( - 2-ChloroethvUEiher 2-Chlorophenol 1 3-Dichlorobenzene 1.4-Dichlorobenzene Benzyl Alcohol 1. 2-Dichlorobenzene 2-Methylphcnol bit(2-chloroisopropyl(Ether 4-Methylphenol N-Nitroso-Di-n-Propylamine Hexachloroethane Nmobenzene Isophorone 2-Nitrophenol 2. 4-Dimethylphenol

Benzoic Acid M bisf - 2-Chloroethoxy(Methane 2. 4-Dichlorophenol 1. 2. 4-Trichlorobenzene Naphthalene 4-Chloroeniline Hexachlorobutadtene 4-Chloro-3-Methylphenol 2-Methylnaphthalene Hexachk>rocyclopentad»ene 2. 4. 6-Tnchlorophenol 2. 4. 5-Tnchlorophenol ( 'J" 2-Chloronaphthalene 2-Nitroaniline ill Dimethyl Phrhatate Acenaphthylene 3-Nitroanihne 111

D.F . : lx

ug /Ior ug • Kg CAS (Circle One) Number

83 32 6 51-28-5 100-02-7 132-64 9 121-14-2 606-20-2

84-66-2 7005-72-3 (86-73-7 100-01-6

534-52-1 86-30-6 101-55-3 118-74-1 187-86-5 85-01-8

50 U 120-12-7

10 U 84-74-2 206-44-0 129-00-0 B5-68 7 91-94-1 (56-55-3 117-81-7 [218-01-9 117-84-0 205-99-2

50 U 207-08-9

10 U 50-32-8

50 U 193-39-5 10 U 53-70-3

191-24-2

10 U

50 U ( * ) C a n n o t ( 2 ) MDL = ( 3 ) M D L =

ug /Ior ug 'Kg (Circle One

Acenaphthene 10 U 2. 4-Dinitrophenpl 50 U 4-Nrtro£henol_ Dibenzoluran 10 U

2 4-Dinitrotoluene 2 6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylethei Fluorene 4-Nitroaniline 111 4, 6-Dinitro-2-Methylphenol N-Nitrosodiphenylamine (1] 4-Brpmophenyl-phenylether Hexachlprobenzene Pentachlorpphenol in Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene Butylbenzylphthaiate 3 3 -Dichlorobenzidine ( 3 ) Benzo<a(Anthracene bis(2-Ethylhexyl)Phthalate Chrysene Di-n-Octyl Phthalate Benzo(b)Fluoranthene Benzo(k(Fluoranthene Benzo(a(Pyrene IndenoO. 2. 3-cd)Pyrene Dibenzla hVAnthracene Benzoic, h, i(Perylene

50 U UT

10 U

50 U 10 U

20 U 10 U 5 J 10 U

b e s e p a r a t e d f r o m D i p h e n y l a m i n e 5X o the r HSL Compounds 2 X o t h e r H S L C o m p o u n d s


Approved By: DATE: February 28, 1986 .Far! M. Hansen, Ph.D.

' Manager WESTON Analytical Laboratories

i 4# t «WATER SURROGATE REMCtiTI rteww»u,• g s i i . - ' i v t -

Contract No. Cr"2A~ _ Contract LaboratoryCaaa NO,

I outside of QC limitsVotatiles:• VALUES ARE OUTSIDE OF CONTRACT REQUIRED QC LIMITS Semi-Volatilea: — { outside of QC limits••'ADVISORY LIMITS ONLY _ ; outside of QC limitsPesticides:

Comments:

FORM II 7 / 0 5

W A T E R BLAUK SPIKE/01A A/K S P I K E D U P L I C A T E R E C O V E R T

project *CI3-1 3 6 1 3 3 L 7 C o n t r a c t o r & 3 K ( J a , - ( e n , Z ' « * ~ C l i e n t A 8 L i0 2 A

CONC. SPIKE SAMPLE CONC. % CONC. % RPOFRACTION COMPOUND RECADOED lug) RESULT es REC 6 S D 1,1-Dichloroethene A± 61 1 45• VOA

14 7 1 1 2 0TrichloroetheneSMO 1 3 75 130ChlorobenzeneSAMPLE NO. 13 76 125Toluene Benzene J_L 7 6 1 2 7

28 39 981,2.4-Trichlorobenzene t> -13- S± JtL. ML 31 46 118

B/N Acenaphthenc JL5L JAL 33. 1L SMO 2.4 Oinitrotoluene Ma_ SL( 4JL 1SL 38 96.

8JL 40 1 1 1 1 7SAMPLE NO. Di-n-Butylphthalate 23. AL 31 2 6 1 2 7Pyrene A± 88 A2L 3A 38 4 1 1 1 6N-Nitroso-Di-n-Propylamine ML 7O 33 JjL ICL

1,4-Dichlorobenzene w 23- AS. JJL. AM 28 39 97 50 9-103Pentachlorophenol ICQ AA 1A 3A J22. 2M

ACID 42 12 89Phenol 32. 3L 3SL 33. rt 40 2 7 1 2 3SMO 2-Chlorophenol 2jL 32 13 33. SL

SAMPLE NO. 42 23 974-Chloro-3-Methylphenol JUL XZL If 3L ±1L 50 10 804-Nitrophenol W1 2JL. 22. <21 23- AO. 15 5 6 1 2 3Lindane

PEST 20 4 0 - 1 3 1HeptachlorSMO 22 4 0 1 2 0Aldrin

SAMPLE NO. 18 5 2 1 2 6Dieldrin 2 1 5 6 1 2 1Endrin 27 3 8 1 2 74.4'DDT

*ASTERISKED VALUES ARE OUTSIDE QC LIMITS.

VOA« - out of ; outside QC limitsRECOVERY:outside QC limits B/N ^ out of J-L; outside QC limitsRPO: VOAs __r__ out of—:n_

R/N & out of —2L outside QC limits outside QC limitsACID.^ out of J£l\

ACID O out of A outside QC limits outside QC limitsPEST nut of ;PEST — out of —=_ outside QC limits

Comment*:

4/M

ATTACHMENT II

TABLE 1. TCDO DATA REPORT FORM GZA

Report Date: February 28, 1986Lab: Roy F. Weston

Column: CP-SIL-88Batch: 8512-327

GC/MS Analysis Rel Ion Instr. Abundance Surroqate Relative Ion AbundanceClient Sample Extra Aliquot TCDD (ppb)

ID ID Cleanup ml Heas . D .L . ID Date Time 320/322 332/334 % Acc 3Z0" "327 257 373" 737" "737

216025 83648 110335Blank 1000 ND .001 1/7/86 16:56 .76 107%

220401 88792 109455 8102A 0030 1000 ND .002 1/7/86 17:58 .81 106%

245328 89152 115522B105A 0010 1000 ND .002 1/7/86 18:29 .77 115%

1/7/86 18:59 .76 .78 106% 166080 217809 75896 229149 91259 116803B105B 0020 1000 .46* .002

266539 100061 133918Blank 1000 ND .001 1/8/86 9:24 .75 109%

9:55 110% 178124 64810 90092B001A 0050 1000 ND .001 1/8/86 .72 227520 85379 107816

Blank 1000 ND .001 1/8/86 10:36 .79 113% 1000 ND .002 1/8/86 11:17 .83 3,400%** 582247 10279 12407

B102B 0040 283531 109447 145674 SB-001 0060 1000 ND .001 1/8/86 11:52 .75 106%

1/8/86 13:05 .78 3,700%** 1563310 24031 30822 B-101A 0090 1000 ND .014

•Matrix spiked with 2,3,7,8 TCDD - 46% Recovery **As surrogate and internal standards are both included in the same solution added to each sample before

extraction, these extreme values may be due to matrix effects. These samples are being re-extracted for repeat analysis.

RB - Reagent Blank FB ~ Field Blank P - Partial Scan/Confirmatory Analysis ND - Not Detected N - Native TCDD Spike DL - Detection Limit D - Duplicate/Fortified Field Blank

Please Note: Surrogate Recoveries have been corrected as described in the cover letter.

CLIENT/SUBJECT _

TASK DESCRIPTION

PREPARED BY

MATH CHECK BY —

METHOD REV. BY . Csy\ a cuLijti& /•**-'

f v i A ' ' s ~ 7 c C & Xcdo/ Jr/W /Acr>isOs S

/scu o Zft/tuJ-j SO LXZ - Sy>*&6 lyO />, ^~

ft54 3-2. 9 -3 3^

AHA.

/23rf *3 $fcO

7/2

£6L0C±>dcu// *C-vt\ A7 ^

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flvu*. ^ / / - V J 0

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h a v~ Cfy\

hvust~/i MJ- /JLC 6 V • r7®? 9

=FW 10-05-C03/A-5/85

188.8-1

MIDRIC+MASS CHROMATOGRAM 02/16/86 17:41:00 SAMPLE: 2UL EX LAB SPIKING MIX CONDS.: DX RANGE: G 1, 487 LABEL: N -1> 4.8

DATA: 0216284 #1 CALI: TC #3

QUAN: A 1, 1.0 J 347

8

SCANS 300 TO

BASE: U 28, 3

400

698.

323 323.897 ± 0.580

379 14185. 31827. 14272.

RIC

V

300 8:28

T

312 1962. 11426. /V

338 560. 2965. . —-s,

340 9:27

A 355 544. 1068.

Si I

368 10:80

\. "1

388 10:33

I 408 SCAN

11:07 TIME

MIDRIC+MASS CHROMATOGRAMS DATA: 0216Z84 #1 SCANS 300 TO 400 02/16/86 17:41:80 SAMPLE: 2UL EX LAB SPIKING MIX

CALI: TC #3

CONDS.: DX RANGE: G 1, 407 LABEL: N -1/ 4.0 QUAN: A 1, 1.0 J 0 BASE: U 28,

379 3812.

89.1-1 10283. 3812.

332 332.099

315 343 362 ± 0.500

333. 356. 401. 2160. 826. 1459.

379 4280.

100.08420. 4280.

334 334.100 ± 0.500

312 336 347 369

. 291. 950.

125. 281. .

188. 295.

181. 382.

^ = 1 379

14185.

333.5-1 31027. 14272.

RIC 312 1962. 338 355 11426. 560. 544.

2965. 1060. f3" T8

300 320 340 360 380 400 SCAN 8:20 8:53 9:27 10:00 10:33 11:07 TIME

MIDRIC+MASS CHROMATOGRAMS 02/16/8617:41:00 SAMPLE: 2UL EX LAB SPIKING MIX CONDS.: OX RANGE: G 1, 487 LABEL: N -1, 4.0

312 864. 4568.

13.9-1

257

100.0-1

328

311 281. 743.

223.8-1

RIC 312 1962. 11426.

i 3

300 320 8:20 8:53

DATA: 8216Z84 #1 SCANS 300 TO CALI: TC #3

QUAN: A 1, 1.0 J 0 BASE: U 20, 3

338 210. 580.

343 255. 701. ,

361 442. 2387. =F

338 560. 2965.

340 9:27

355 544. 1060.

—7 360

10:00

400

378 205. 1209.

379 6376. 18358.

T 379

14185. 31027.

380 10:33

884.

257.077 1 0.500

6376.

328.098 ± 0.500

14272.

400 SCAN 11:07 TIME

MIDRIC+MASS CHROMATOGRAMS DATA: 0216284 #1 SCANS 309 TO 400 02/16/86 17:41:00 CALI: TC #3 SAMPLE: 2UL EX LAB SPIKING MIX CONOS.: DX RANGE: G 1/ 407 LABEL: N -1/ 4.0 QUAN: A 1, 1.0 J 0 BASE: U 20, 3

310 342.

100.0H 1505. 355.

320 320.096 ± 0.500

85.4n 303.

322 322.896 ± 0.500

379 14185. 31027. 14272.

RIC 312 1962. 338 355 11426. 560. 544.

2965. 1060. i

300 8:20

320 8:53

340 9:27

360 10:00

380 10:33

400 SCAN 11:07 TINE

ATTACHMENT III

t

TABLE 1. TCDO DATA REPORT FORM

Lab:

B a t c h : '

G Z A ( r e - e x t r a c t i o n s )

Roy F. Weston

8 5 1 2 - 3 2 7

Report Date: F e b r u a r y 2 9 , 1 9 8 6

C o l u m n : 3 0 m e t e r D B - 5

Client ID

—

1 0 2 B

1 0 1 A

Sample ID

B l a n k

0 0 4 0

0 0 9 0

Extra Cleanup

A1 iquot ml

1 . 0

1 . 0

1 . 0

TCDD Heas.

N D

N D

N D

.002

.006

.002

GC/MS Analysis

Time Instr.

ID Date

4 6 0 0 Z

4 6 0 0 Z

4 6 0 0 Z

2 - 1 6 - 3 6 1 8 : 3 1

2 - 1 6 - 8 6 1 8 : 5 8

2 - 1 6 - 8 6 1 9 : 2 0

Rel Ion Abundance

320/322 3327m

1.1 . 9 6

. 9 9

Surroqate % Acc

1 2 4

6 9

5 1

W Relative Ion Abundance

T57~ W

1 1 8 7 0

1 5 3 0 5

1 0 3 5 6

5 0 7 2

1 1 0 6 0

2 8 0 0 0

1W

4 6 5 1

1 1 5 4 6

1 4 6 2 8

RB - Reagent Blank FB - Field Blank P - Partial Scan/Confirmatory Analysis ND - Not Detected N - Native TCDD Spike DL - Detection Limit D - Duplicate/Fortified Field Blank

TABLE 2. INITIAL CALIBRATION StMMARY

TCDD Lour Resolution

Date In.tr. Sol. Measured V Mean IF Psed Percent ValleyID H.tlv Surrogate Native Surrogate (Applies for PC only)ID

</60C2- S . 3/v£/\h

v . 78

7 - 3 C

/ S3 .7S /.yjSo

QUALITY CONTROL StMMARY

Mean Accuracy, Surrogate Measurement.: 'of D*6*

Accuracy, Fortified/Spike Field Blank.: Sample # •

Bel. Biff.(X), Duplicate Analysis: Sample # —==—

Solution ID Codesi

PC " Performance check solution CC1 » Concentration calibration solution #1• 0.2 ug/mlCC2•Concentration calibration solution #2• 1.0 ug/mlCC3 - Concentration calibration solution #3• 5.0 ug/mlCCA•Concentration calibration solution #4 " 20.0 ug/mlCC5•Concentration calibration solution #5•40.0 ug/ml

g.7 IFB Am. 1 12/29/83

MIDRIC+MASS CHROMATOGRAMS 02/16/86 17:15:00 SAMPLE: 2UL CAL STD 1 CONDS.: DX RANGE: G 1, 445 LABEL: N -1, 4.0

DATA: 0216Z83 #1 CALI: TC #3

QUAN: A 1, 1.0 J 0

SCANS 300 TO

BASE: U 20, 3

400

38.6 497.

257 257.077 ± 0.500

100.0-1 1286.

328 328.098 ± 0.500

378 15680. 39342. 15680.

RIC

I I

300 8:20

I

OlO

1026. 6905.

< 320 8:53

337 740.

6319. • . I

340 9:27

360 747. 4100. ••-b w—^maam

I 360

10:00

I

I 380

10:33

394 622. 2173.

400 SCAN 11:07 TIME

MIDRIC+MASS CHROMATOGRAMS DATA: 0216Z83 #1 SCANS 300 TO 400 02/16/86 17:15:09 CALI: TC #3 SAMPLE: 2UL CAL STD 1 CONDS.: DX RANGE: G 1, 445 LABEL: N -1, 4.0 QUAN: A 1, 1.0 J 0 BASE: U 20,

75.2-1 1386.

320 320.096 ± 0.500

100.0-1 1844.

322 322.096 ± 0.500

378 15680.

850.3-1 39342. 15680.

RIC

318 OOl 360 394 1026. 740. 747. 622. 6905. 6319. . . 1 4100. V 2173. •

T n 300 320 340 360 380 400 SCAN 8:20 8:53 9:27 10:00 10:33 11:07 TIME

90.4-1

MIDRIC+MASS CHROMATOGRAMS 02/16/86 17:15:08 SAMPLE: 2UL CAL STD 1 CONDS.: DX RANGE: G 1, 445 LABEL: N -1#

DATA: 0216283 #1 CALI: TC #3

4.0 QUAN: A 1/ 1.0 J 0 BASE: U 20,

SCANS 300 TO 480

378 5009. 12945. 5024.

332

315 243. 479. .

330 177. 600.

347 226.

•620. . .

358 197. 543.

394 266. 1095.

332.093 ± 0.500

100.0-1 5560.

334

320 161. 448;

332 181. 996. i

350 160.

i 365;

360 229. 759.

390 182.

•182.

334.190 ± 0.500

282.8-1

378 15680. 39342. 15680.

RIC

300 8:20

318 1026. 6905. 1

320 8:53

337 740. 6319' '

340 9:27

360 747. 4100.

360 10:00

T 380

10:33

'M—~V,

394 622. 2173. .

400 SCAN 11:07 TIME

MIDRIC+flASS CHROMATOGRAM 02/16/86 17:15:00 SAMPLE: 2UL CAL STD 1 CONDS.: DX RANGE: G 1, 445 LABEL: N -1* 4.0

DATA: 0216Z83 #1 CALI: TC #3

QUAN: A 1/ 1.0 J 0

SCANS 309 TO

BASE: U 20/

400

100.0 497.

323 394 172. 667.

323.097 ± 0.500

378 15680. 39342. 15689.

MIDRIC+MASS CHROMATOGRAMS DATA: 0216282 #1 SCANS 300 TO 400 02/16/86 16:52:00 CALI: TC #3 SAMPLE: 2UL CAL STD 2 CONDS.: DX RANGE: G 1, 509 LABEL: N -1/ 4.0 QUAN: A 1, 1.0 J 0 BASE: U 20,

98.7n 1768.

257 310 542.

257.077 ± 0.500

2132.

100.0n 1792.

328 328.098

A,

317 236. 935. .—•

335 95. 138. f -m —

345 136. 334.

, r v.

361 195. 733.

388 206. 273. £5=

± 0.500

25952.

RIC

317 339 3611450. 331. 303.7098. 717. 1641.

mmSkm

T— T 1 300 320 340 360 380 400 SCAN 8:20 8:53 9:27 10:00 10:33 11:07 TIME

MIDRIC+MASS CHROMATOGRAMS 02/16/86 16:52:09 SAMPLE: 2UL CAL STD 2 CONDS.: DX RANGE: G 1, 589 LABEL: N -1, 4.0

80.1

320

318 235. 1131.•rCa

100.0

322

309 274. 1222.

419.7-1

RIC

317 1459. 7098.

300 320 8:20 8:53

DATA: 0216Z82 #1 CALI: TC #3

QUAN: A 1, 1.0 J

346 203. 501.

346 190. 381.

339 331. 717.

I

340 9:27

SCANS 300 TO

0 BASE: U 20, 3

358 112. 192.

356 117. 169.

361 303. 1641.

360 10:00

400

378 4938. 12923. 4952.

320.096 ± 0.500

377 6176. 15861. 6184.

322.096 ± 0.500

377 25902. 67237. 25952.

I

400 SCAN 11:07 TIME

MIDRIC+MASS CHROMATOGRAMS 02/16/86 16:52:00 SAMPLE: 2UL CAL STD 2 CONDS.: DX RANGE: G 1, 509 LABEL: N -1/

86.6-1

332

318 247. 1418.

100.0"

334

306 317 252.

•IS-,; 157.

448. l-i

RIC

317 1450. 7098.

T— 300 320 8:28 8:53

DATA: 0216Z82 #1 CALI: TC #3

4.0 QUAN: A 1, 1.0 J

335 128. 247.

346 176. 415.

336 69.

• 99.'

339 331.

I717. T mTk,

348 9:27

SCANS 300 TO 400

0 BASE: U 28,

367 217. 573.

356 123. 147. • • i

—T

3 377 5087. 13833.

377 25982. 67237.

< i

394 55. 214.

5016.

332.899 i 8.500

5792.

334.100 ± 0.500

25952.

361 303. 1641. T 360

10:80

t

400 SCAN 11:07 TIME

MIDRIC+MASS CHROMATOGRAM DATA: 0216Z82 #1 SCANS 300 TO 400 02/16/86 16:52:00 CALI: TC #3 SAMPLE: 2UL CAL STD 2 CONOS.: DX RANGE: G 1, 509 LABEL: N -1, 4.0 8UAN: A I, 1.0 J 0 BASE: U 20, 3

377 1086.

MIDRIC+hASS CHR0MAT0GRAM5 DATA: 0216Z81 #1 SCANS 300 TO 400 02/16/86 16:32:00 CALI: TC #3 SAMPLE: 2UL CAL STO 3

63.In

DATA: 0216281 #1 CAL1: TC #3

MIDRIC+MASS CHROMATOGRAMS 02/16/86 16:32:00 SAMPLE: 2UL CAL STD 3 CONDS.: DX RANGE: G 1, 409 LABEL: N -1, 4.0 QUAN: A 1, 1.0 J 0 BASE: U 20,

SCANS 300 TO 400

377 16883. 40730. 16928.

320 320.096 ± 0.500

309 315.

-437. ' •

389 295. 1240.

100.0-1

377 26781. 56466. 26816.

322 322.096 ± 0.500

305 406. 1188.

316 473.

.1145.

333 163. 269.

348 268. 920.

367 151. 183.

243.2-1

377 65216. 146362. 65216.

RIC

300 8:20

316 2984. 23257.

1 320 8:53

329 378. 522.

T

346 1374.

. 5307. 1

340 9:27

363 508.

• 954. •

360 10:00

389 1402. 3378.

400 SCAN 11:07 TIME

MIDRIC+MA5S CHRONATOGRAMS 02/16/86 16:32:00 SAMPLE: 2UL CAL STD 3 CONDS.: DX RANGE: G 1. 409 LABEL: N -1, 4.0

96.3-1

332

306 208. 280.

100.0-1

334

RIC

300 8:20

314 329 280. 159. 1070. 159.

55

316 329 2984. 378.

23257. 522. ~7— 320 8:53

DATA: 0216Z81 #1 CALI: TC #3

QUAN: A 1, 1.0 J 0

347 250. 1167

347 212.

• 212.

346 1374.

. 5307.

340 9:27

SCANS 300 TO

BASE: U 20, 3

363 184. 486.

363 503.

• 954. • '

360 10:00

400

377 4938. 11333.

377 65216. 146362.

389 298. 1041.

389 280.

,522. .

1402. 3378.

4768.

332.099 ± 0.500

4952.

334.100 ± 0.500

65216.

"I 400 SCAN

11:07 TIME

DATA: 0216Z81 #1 CALI: TC #3

MIDRIC+MASS CHROMATOGRAM 92/16/86 16:32:80 SAMPLE: 2UL CAL STD 3 CONOS.: DX RANGE: G 1, 409 LABEL: N -1, 4.0 QUAN: A 1, 1.0 J 0

SCANS 300 TO

BASE: U 20, 3

400

100.0-1 4776;

323 323.097 ± 0.500

377 65216. 146362. 65216.

RIC

300 8:20

31b 2984. 23257.

I 320 8:53

329 378. 522.

T i

346 1374. 5307.

i

340 9:27

363 508. 954. -

360 10:00

v

380 10:33

389 1402. 3378*.

400 SCAN 11:07 TIME

100.0-1

MIDRIC+MASS CHROMATOGRAMS 02/16/86 16:11:00 SAMPLE: 2UL CAL STD 4 CONDS.: DX RANGE: G 1. 408 LABEL: N -1/

DATA: 0216Z88 #1 CALI: TC #3

4.0 QUAN: A 1/ 1.0 J 0

SCANS 308 TO

BASE: U 20, 3

400

378 22748. 37045. 22752.

257 257.077 ± 0.500

5.5-1 1254.

328 328.098

± 0.500

378 152034.

MIDRIC+MASS CHRONATOGRAMS DATA: 0216Z80 #1 SCANS 309 TO 400 02/16/86 16:11:00 CALI: TC #3 SAMPLE: 2UL CAL STD 4 CONDS.: DX RANGE: G 1, 408 LABEL: N -1, 4.0 QUAN: A 1, 1.0 J 0 BASE: U 20, 3

378 60352.

100.0-1 111640. 60352.

320 320.096 ± 0.500

316 332 360 234. 328. 217. 910^ 775. 1018.

—h — 378

59520.

98.G-i 134351. 59520.

322 322.896 ± 0.500

305 338 245. 184. 665. 327j

378 152034.

252.0324544. 152064.

RIC

317 332 346 360 1247. 983. 854. 720. 6222. • • 3828. 3282. • HSU I I

1 I 300 8:20

320 8:53

340 9:27

360 10:00

400 SCAN 11:07 TIME

MIDRIC+MASS CHROMATOGRAMS DATA: 0216Z80 #1 SCANS 300 TO 400 02/16/86 16:11:08 SAMPLE: 2UL CAL STD 4

CALI: TC #3

CONOS.: DX RANGE: G 1. 408 LABEL: N -1, 4.8 QUAN: A 1, 1.0 J 0 BASE: U 20,

84.7-1 4288.

332 332.099 ± 0.500

311 332 344 366 383 342. 227. 213. 237. 191. 1176. . 763 j . 213. 378; 1001.

100.0-1 5064;

334 334.100 ± 0.500

308 180.

319 261.

331 183.

347 168.

360 216.

390 171.

482. 740, . 575. 527. 913. 3=

846.

378 152034. 324544. 152064.

A

RIC

317 332 346 360 1247. 983. 854. 720. 6222. 3828. 3282. HSU

400 SCAN300 320 340 360 9:27 10:00 10:33 11:07 TIME8:20 8:53

MIDRIC+MASS CHROMATOGRAM DATA: 0216Z80 #1 02/16/86 16:11:09 CALI: TC #3 SAMPLE: 2UL CAL STD 4 CONDS.: DX RANGE: G 1, 408 LABEL: N -1, 4.0 QUAN: 1, 1.0 J

305 317 336 346 171. 232. 270. 236. 702. 13351 .568. 710.

=F

RIC

317 332 346 1247. 983. 854. 6222. • ' 3828. • 3282.

— , jr— , "7 r

300 320 340 8:28 8:53 9:27

SCANS 300 TO

BASE: U 20, 3

360 720.

• 145U

360 10:00

400

377 10512. 21422. 10512,

323.097 ± 0.500

378 152034. 324544. 152064.

7 400 SCAN

11:07 TIME

100.0—i

MIDRIC+MASS CHROMATOGRAMS 02/16/86 15:14:00 SAMPLE: 2UL CAL STD 5 CONDS.: DX RANGE: G 1/ 426 LABEL: N -1/

DATA: 0216Z79 #1 CALI: TC #3

4.0 QUAN: A 1/ 1.0 J

SCANS 300 TO

BASE: U 20/ 3

400

377 50496. 90700. 50496.

257 257.077 ± 0.500

307 88. 351.

•+

348 105* 309.i _

3.9-1 1970.

328

345 63. 63. • A •

377 400896.

328.099 ± 0.500

87.6-1

HIDRIC+MASS CHROMATOGRAMS 02/16/86 15:14:00 SAMPLE: 2UL CAL STD 5 CONDS.: DX RANGE: G 1, 426 LABEL: N -1/ 4.0

DATA: 0216Z79 #1 CALI: TC #3

QUAN: A 1, 1.0 J 0

SCANS 300 TO

BASE: U 29, 3

400

377 151552. 266999. 151552.

320 320.096 ± 0.500

100.0-1

377 173054. 332359. 173056.

322 322.096 ± 0.500

231.7

-i —

377 400896. 761478. 400896.

RIC

300 8:20

314O J

253. 749.

1 320 8:53

340 9:27

359 454. 1146.

T 360

10:00

•

380 10:33

400 SCAN 11:07 TIME

MIDRIC+MASS CHRONATOGRAMS DATA: 0216Z79 #1 SCANS 300 TO 400 02/16/86 15:14:09 CALI: TC #3 SAMPLE: 2UL CAL STD 5 CONDS.: DX RANGE: G 1/ 426 LABEL: N -1/ 4.8 QUAN: A 1, 1.0 J 0 BASE: U 20,

84.2-1

332

I

A 100.0-1

i

314 63. 63. _ •=T="

346 96. 184. • ,

356 165. 310.•

376 5376. 10204.

388 267. 488.

334

319 27. 27. -

354 108.

,204.

377 400896. 761478.

RIC

300 8:20

314 253. 740.

~T~ 320 8:53

~~7— 340 9:27

359 454.

1146. I

360 10:00

380 10:33

4528.

332.099 ± 0.500

5376.

334.100 ± 0.500

400896.

~1 400 SCAN

11:07 TIME

MIDRIC+MASS CHROMATOGRAM DATA: 0216279 #1 SCANS 300 TO 400 02/16/86 15:14:00 SAMPLE: 2UL CAL STD 5

CALI: TC #3

CONDS.: DX RANGE: G 1, 426 LABEL: N -1, 4.0 QUAN: A 1, 1.0 J BASE: U 20, 3

377 21440. 48288. 21440. A

323.097 ± 0.500

314 71. 71. • '

343 77. 145. .

364 178. 454.

377 400896. 761478. 400896.

RIC

314 359 253. 454. 740. 1146.

j '

380 400 SCAN300 320 340 360 10:00 10:33 11:07 TIME8:20 8:53 9:27

40.3-1

257

M1DRIC+MASS CHROMATOGRAMS 02/16/86 18:31:00 SAMPLE: 2UL EX BLANK BATCH 373 CONDS.: DX RANGE: G 1/414 LABEL: N -1/

310 1079. 3102.

DATAJ 0216Z83 #1 CALI: TC #3

4.0 QUAN: A 1/ 1.0 J

346 490.

3234.

SCANS 300 TO

0 BASE: U 20/ 3

359 565. 3136.

400

379 398. 3155.

1098.

257.077 ± 0.500

100.0-1 2724.

328 328.098 ± 0.500

274.9n 7488.

RIC

400 SCAN 11:07 TIME8:20

300

MIDRIC+MASS CHROMATOGRAMS 02/16/86 18:31:00

DATAs 8216285 #1 CALI: TC #3

SCANS 300 TO 400

SAMPLE: 2UL EX BLANK BATCH 373 CONDS.: DX RANGE: G 1/414 LABEL: N -L 4.0 QUAN: A 1/ 1.0 J 0 BASE: U 20/ 3

e* • S- • 6 C O .OS

378 603. _

67.2-1 1284. .60*-* 673.

320 320.096

± 0.500

100.0-1 1002.

322 322.096

± 0.500

377 7235.

747.3-, 346

24132. 7488.

4688.

RIC 310 1780. 4820.

328 1165.

21708.

K 356 2768, 21460.

300 8:20

r 320 8:53

2696. v

7 340 9:27

\ r

360 10:00

400 SCAN 11:07 TIME

MIDRIC+MASS CHROMATOGRAMS DATA: 0216285 «1 SCANS 300 TO 400 02/16/86 18:31:00 CALI: TC #3 SAMPLE: 2UL EX BLANK BATCH 373

| CONDS.: DX RANGE: G 1, 414 LABEL: N -1, 4.0 QUAN: 1, 1.0 J 0 BASE: U 20,

78.5

332

100.01

334

336.li

RIC

1748.

332.099 ± 0.500

2228.

334.180 ± 0.500

7488.

300 320 400 SCAN 8:20 8:53 11:07 TIME

1.8-1

MIDRIC+MASS CHROMATOGRAMS 02/16/86 18:58:00 SAMPLE: 2UL 8512-327-0040/1028CONDS.: DX RANGE: G 1, 406 LABEL: N -1, 4.0 QUAN:

333 8267. 16144.

DATA: 0216Z86 #1 CALI: TC #3

1/ 1.0 J

SCANS 300 TO

0 BASE: U 20, 3 357

11124. 18068.

400

11136.

257 306 3044. 15960.

316 2632. 10503.

257.077 ± 0.500

100.0-1

323 606208. 1367690.

606208.

328

104.7

386 51072. 105522.

316 205824. 385485.

323 634880.

1476660.

336 933. 4267.

351 537. 924 j

379 5294. 15305.

392 8304. 16868. . -

328.098 ± 0.500

634880.

RIC

306 61568.

158436.

300 8:20

316 221696. 456328.

332 f\ 10048. / V _42600.

~T 340 9:27

350 3136. 10192.

r 360

10:00

365 7616.

27456.

379 17287. 72160.

I 380

10:33

. .

392 9392. 12688. • •

1 400 SCAN

11:07 TIME

65.4

MIDRIC+MASS CHROMATOGRAMS 02/16/86 18:58:00 SAMPLE: 2UL 8512-327-0040/102BCONDS.: DX RANGE: G I, 406 LABEL: N -1, 4.0

323 2364. 9118.

DATA: 0216286 #1 CALI: TC #3

QUAN: A 1/ 1.0 J 0

SCANS 300 TO

BASE: U 20/ 3

480

380 2140. 7344. 2364.

395 379.

. 1850.

320.096 ± 0.500

3616.

322.096 ± 0.500

323 634880. 1476660.

634880.

RIC

306 61568.

158436. „ 300 8:20

316 221636. 456328.

t

J 332

10048. V ,42600.

340 9:27

350 3136. 10192. I

r 360

10:00

365 7616. 27456. .

379 17287. 72160.

T 380

10:33

392 9392. 12688.

1 400 SCAN

11:07 TIME

MIDRIC+MASS CHROMATOGRAMS 02/16/86 18:58:00

DATA: CALI:

0216286 #1 TC #3

SCANS 300 TO 400

SAMPLE: CONDS.:

2UL 8512-327-8040/102BDX

RANGE: G 1, 406 LABEL: N -1# 322

4.0 QUAN: A 1, 1.0 J 0 BASE: U 20, 3

28268. 39808.

20288.

306 3128. 7087.

335 1413. 4215. '

350 704.

2230*.

366 4912.

13346.

379 5624. 11060.

332.099 ± 0.500

i /—»

4320.

309 477.

• 1281.

322 1091. 1777.

335 1304. 3990.

A 348 685. 2328.

358 540. 1722.

334.100 ± 0.500

z. K/ 'vA \/N. 323

634880. 1476660.

634880.

316 . 221696.

306 61568. 158436.

300 8:20

456328. ,

A Ai332 10048. 42600.

320 8:53

~1 340 9:27

350 3136. 10192.

365 7616. 27456.

^ 360

10:00

-

379 17287. 72160.

380 10:33

392 9392.

• 12688. • -1 400 SCAN

11:07 TIME

100.0-1

MIDRIC+MASS CHROMATOGRAMS 02/16/86 19:20:00 SAMPLE: 2UL 8512-327-0090/101A CONDS.: DX RANGE: G 1, 494 LABEL: N -1, 4.0 QUAN:

331 5384. 15060.

DATA: 0216287 #1 CALI: TC #3

SCANS 300 TO

1/ 1.0 J 0 BASE: U 20, 3

343 4092.

16564.

356 4429. 8878.

400

5384.

257 257.077

± 0.500

78.9-1

328

322 4216.

23516.

377 2607. 10356.

393 2605. 4193.

4248.

328.098 ± 0.500

326.9-n

RIC

316 8819. 48691.

332 7662. 26466,

347 13891. 80256.

377 17549. 77420.

17600.

380 400 SCAN8:20 10:33 11:07 TIME

300

62.6-1

DATA: 0216287 #1 CALI: TC #3

MIDRIC+MASS CHROMATOGRAMS 02/16/86 19:20:00 SAMPLE: 2UL 8512-327-0090/101ACONDS.: DX RANGE: G 1, 494 LABEL: N -1, 4.0 QUAN: A 1/ 1.0 J 0

316 2304. 14061.

339 354

SCANS 300 TO

BASE: U 20/ 3

400

..oS~

TCTTO 1—. ^

379 1768. 7574.

/ *<xv ) 2668.

320 320.096 ± 0.500

100.0-1

322

375 2723. 7191.

4264.

322.096 ± 0.500

412.8—1

RIC

347 13891. 80256.

361 8534. 76643.

377 17549. 77420.

A.. 17600.

I ; L-f1 VkA/K 360 380 400 SCAN

8:20 10:00 10:33 11:07 TIME 300

MIDRIC+MASS CHROMATOGRAHS 02/16/86 19:20:80

DATA: CALI:

0216Z87 #1 TC #3

SCANS 300 TO 400

SAMPLE: CONOS.:

2UL 8512-327-0090/101A DX

RANGE: G 1. 494 LABEL: N -1, 4.0 QUAN: A 1, 1.0 J 0 BASE: U 20, 377

5622. 100.0-1 28000.

5720.

332 332.099 ± 0.500

377 3470.

61.7n 14628. 3528.

334 334.100 ± 0.500

377

307.7-1, 347

13331.

17549. 77420.

17600.'

RIC

£/^/I

316 8819. 48691.

A. / \) 3

T

332 7662. 26466. n ' A 1

J V

80256. 361

8594. A 76648.

V\/v JVV\ /

300 8:20

320 8:53

340 9:27

400 SCAN 11:07 TIME

MIDRIC+MA5S CHROMATOGRAM 02/16/86 19:20:00 SAMPLE: 2UL 8512-327-0090/101A CONDS.: DX

DATA: 0216Z87 #1 CALI: TC #3

SCANS 360 TO 400

RANGE: G 1# 494 LABEL: N -1, 4.0 QUAN: A 1, 1.0 J 0 BASE: U 20, 3

4808.

PICKERING CREEK INDUSTRIAL PARK LIONVILLE. PA 19353 ...

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Transcript of PICKERING CREEK INDUSTRIAL PARK LIONVILLE. PA 19353 ...