PHYS 570 - Introduction to Synchrotron Radiationcsrri.iit.edu/~segre/phys570/10F/lecture_01.pdf ·...
Transcript of PHYS 570 - Introduction to Synchrotron Radiationcsrri.iit.edu/~segre/phys570/10F/lecture_01.pdf ·...
PHYS 570 - Introduction to Synchrotron Radiation
Term: Fall 2010Meetings: Tuesday & Thursday 10:00-11:15Location: 245 Engineering 1 BuildingInstructor: Carlo SegreOffice: 166A Life SciencesPhone: 312.567.3498email: [email protected]: Elements of Modern X-Ray Physics,
J. Als-Nielsen and D. McMorrow (Wiley, 2001)Web Site: http://csrri.iit.edu/˜segre/phys570/10F
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 1 / 19
Course Objectives
• Understand the means of production of synchrotron x-ray radiation
• Understand the function of various components of a synchrotronbeamline
• Be able to perform calculations in support of a synchrotronexperiment
• Understand the physics behind a variety of experimental techniques
• Be able to make an oral presentation of a synchrotron radiationresearch topic
• Be able to write a General User Proposal in the format used by theAdvanced Photon Source
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 2 / 19
Course Objectives
• Understand the means of production of synchrotron x-ray radiation
• Understand the function of various components of a synchrotronbeamline
• Be able to perform calculations in support of a synchrotronexperiment
• Understand the physics behind a variety of experimental techniques
• Be able to make an oral presentation of a synchrotron radiationresearch topic
• Be able to write a General User Proposal in the format used by theAdvanced Photon Source
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 2 / 19
Course Objectives
• Understand the means of production of synchrotron x-ray radiation
• Understand the function of various components of a synchrotronbeamline
• Be able to perform calculations in support of a synchrotronexperiment
• Understand the physics behind a variety of experimental techniques
• Be able to make an oral presentation of a synchrotron radiationresearch topic
• Be able to write a General User Proposal in the format used by theAdvanced Photon Source
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 2 / 19
Course Objectives
• Understand the means of production of synchrotron x-ray radiation
• Understand the function of various components of a synchrotronbeamline
• Be able to perform calculations in support of a synchrotronexperiment
• Understand the physics behind a variety of experimental techniques
• Be able to make an oral presentation of a synchrotron radiationresearch topic
• Be able to write a General User Proposal in the format used by theAdvanced Photon Source
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 2 / 19
Course Objectives
• Understand the means of production of synchrotron x-ray radiation
• Understand the function of various components of a synchrotronbeamline
• Be able to perform calculations in support of a synchrotronexperiment
• Understand the physics behind a variety of experimental techniques
• Be able to make an oral presentation of a synchrotron radiationresearch topic
• Be able to write a General User Proposal in the format used by theAdvanced Photon Source
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 2 / 19
Course Objectives
• Understand the means of production of synchrotron x-ray radiation
• Understand the function of various components of a synchrotronbeamline
• Be able to perform calculations in support of a synchrotronexperiment
• Understand the physics behind a variety of experimental techniques
• Be able to make an oral presentation of a synchrotron radiationresearch topic
• Be able to write a General User Proposal in the format used by theAdvanced Photon Source
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 2 / 19
Course Syllabus
• Focus on applications of synchrotron radiation
• Homework assignments, exams (?)
• In-class student presentations on research topics
• Choose a research article which features a synchrotron technique• Timetable will be posted
• Final project - writing a General User Proposal
• Start thinking about a suitable project right away• Make proposal and get approval before starting
• Visits to Advanced Photon Source (outside class)
• All students will need to request badges from APS• Go to http://www.aps.anl.gov/Users/New/ and register as a new user.• Use MRCAT (Sector 10) as location of experiment• Use Carlo Segre as local contact• State that your beamtime will be in the second week of October
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 3 / 19
Course Syllabus
• Focus on applications of synchrotron radiation
• Homework assignments, exams (?)
• In-class student presentations on research topics
• Choose a research article which features a synchrotron technique• Timetable will be posted
• Final project - writing a General User Proposal
• Start thinking about a suitable project right away• Make proposal and get approval before starting
• Visits to Advanced Photon Source (outside class)
• All students will need to request badges from APS• Go to http://www.aps.anl.gov/Users/New/ and register as a new user.• Use MRCAT (Sector 10) as location of experiment• Use Carlo Segre as local contact• State that your beamtime will be in the second week of October
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 3 / 19
Course Syllabus
• Focus on applications of synchrotron radiation
• Homework assignments, exams (?)
• In-class student presentations on research topics
• Choose a research article which features a synchrotron technique• Timetable will be posted
• Final project - writing a General User Proposal
• Start thinking about a suitable project right away• Make proposal and get approval before starting
• Visits to Advanced Photon Source (outside class)
• All students will need to request badges from APS• Go to http://www.aps.anl.gov/Users/New/ and register as a new user.• Use MRCAT (Sector 10) as location of experiment• Use Carlo Segre as local contact• State that your beamtime will be in the second week of October
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 3 / 19
Course Syllabus
• Focus on applications of synchrotron radiation
• Homework assignments, exams (?)
• In-class student presentations on research topics
• Choose a research article which features a synchrotron technique• Timetable will be posted
• Final project - writing a General User Proposal
• Start thinking about a suitable project right away• Make proposal and get approval before starting
• Visits to Advanced Photon Source (outside class)
• All students will need to request badges from APS• Go to http://www.aps.anl.gov/Users/New/ and register as a new user.• Use MRCAT (Sector 10) as location of experiment• Use Carlo Segre as local contact• State that your beamtime will be in the second week of October
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 3 / 19
Course Syllabus
• Focus on applications of synchrotron radiation
• Homework assignments, exams (?)
• In-class student presentations on research topics
• Choose a research article which features a synchrotron technique• Timetable will be posted
• Final project - writing a General User Proposal
• Start thinking about a suitable project right away• Make proposal and get approval before starting
• Visits to Advanced Photon Source (outside class)
• All students will need to request badges from APS• Go to http://www.aps.anl.gov/Users/New/ and register as a new user.• Use MRCAT (Sector 10) as location of experiment• Use Carlo Segre as local contact• State that your beamtime will be in the second week of October
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 3 / 19
Topics to be Covered (at a minimum)
• X-rays and their interaction with matter
• Sources of x-rays
• Refraction and reflection from interfaces
• Kinematical diffraction
• Diffraction by perfect crystals
• Photoelectric absorption
• Resonant scattering
• Small angle scattering (not in book)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 4 / 19
Resources for the Course
• Orange x-ray data booklet:http://xdb.lbl.gov/xdb-new.pdf
• Center for X-Ray Optics web site:http://cxro.lbl.gov
• X-ray Oriented Programs:http://www.esrf.eu/computing/scientific/xop2.1
• Hephaestus from the horae suite:http://cars9.uchicago.edu/˜ravel/software/abouthephaestus.html
• McMaster data on the Web:http://csrri.iit.edu/periodic-table.html
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 5 / 19
Resources for the Course
• Orange x-ray data booklet:http://xdb.lbl.gov/xdb-new.pdf
• Center for X-Ray Optics web site:http://cxro.lbl.gov
• X-ray Oriented Programs:http://www.esrf.eu/computing/scientific/xop2.1
• Hephaestus from the horae suite:http://cars9.uchicago.edu/˜ravel/software/abouthephaestus.html
• McMaster data on the Web:http://csrri.iit.edu/periodic-table.html
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 5 / 19
Resources for the Course
• Orange x-ray data booklet:http://xdb.lbl.gov/xdb-new.pdf
• Center for X-Ray Optics web site:http://cxro.lbl.gov
• X-ray Oriented Programs:http://www.esrf.eu/computing/scientific/xop2.1
• Hephaestus from the horae suite:http://cars9.uchicago.edu/˜ravel/software/abouthephaestus.html
• McMaster data on the Web:http://csrri.iit.edu/periodic-table.html
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 5 / 19
Resources for the Course
• Orange x-ray data booklet:http://xdb.lbl.gov/xdb-new.pdf
• Center for X-Ray Optics web site:http://cxro.lbl.gov
• X-ray Oriented Programs:http://www.esrf.eu/computing/scientific/xop2.1
• Hephaestus from the horae suite:http://cars9.uchicago.edu/˜ravel/software/abouthephaestus.html
• McMaster data on the Web:http://csrri.iit.edu/periodic-table.html
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 5 / 19
Resources for the Course
• Orange x-ray data booklet:http://xdb.lbl.gov/xdb-new.pdf
• Center for X-Ray Optics web site:http://cxro.lbl.gov
• X-ray Oriented Programs:http://www.esrf.eu/computing/scientific/xop2.1
• Hephaestus from the horae suite:http://cars9.uchicago.edu/˜ravel/software/abouthephaestus.html
• McMaster data on the Web:http://csrri.iit.edu/periodic-table.html
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 5 / 19
History of X-Ray Sources
• 1895 x-rays discovered byWilliam Rontgen
• 1st generationsynchrotrons initially usedin parasitic mode (SSRL,CHESS)
• 2nd generation werededicated sources (NSLS,SRC, CAMD)
• 3rd generation featuredinsertion devices (APS,ESRF, ALS)
• 4th generation are freeelectron lasers (LCLS)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 6 / 19
History of X-Ray Sources
• 1895 x-rays discovered byWilliam Rontgen
• 1st generationsynchrotrons initially usedin parasitic mode (SSRL,CHESS)
• 2nd generation werededicated sources (NSLS,SRC, CAMD)
• 3rd generation featuredinsertion devices (APS,ESRF, ALS)
• 4th generation are freeelectron lasers (LCLS)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 6 / 19
History of X-Ray Sources
• 1895 x-rays discovered byWilliam Rontgen
• 1st generationsynchrotrons initially usedin parasitic mode (SSRL,CHESS)
• 2nd generation werededicated sources (NSLS,SRC, CAMD)
• 3rd generation featuredinsertion devices (APS,ESRF, ALS)
• 4th generation are freeelectron lasers (LCLS)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 6 / 19
History of X-Ray Sources
• 1895 x-rays discovered byWilliam Rontgen
• 1st generationsynchrotrons initially usedin parasitic mode (SSRL,CHESS)
• 2nd generation werededicated sources (NSLS,SRC, CAMD)
• 3rd generation featuredinsertion devices (APS,ESRF, ALS)
• 4th generation are freeelectron lasers (LCLS)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 6 / 19
History of X-Ray Sources
• 1895 x-rays discovered byWilliam Rontgen
• 1st generationsynchrotrons initially usedin parasitic mode (SSRL,CHESS)
• 2nd generation werededicated sources (NSLS,SRC, CAMD)
• 3rd generation featuredinsertion devices (APS,ESRF, ALS)
• 4th generation are freeelectron lasers (LCLS)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 6 / 19
History of X-Ray Sources
• 1895 x-rays discovered byWilliam Rontgen
• 1st generationsynchrotrons initially usedin parasitic mode (SSRL,CHESS)
• 2nd generation werededicated sources (NSLS,SRC, CAMD)
• 3rd generation featuredinsertion devices (APS,ESRF, ALS)
• 4th generation are freeelectron lasers (LCLS)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 6 / 19
The Classical X-Ray
The classical plane wave representation of x-rays is:
E(r, t) = εEoei(k·r−ωt)
where ε is a unit vector in the direction of the electric field, k is thewavevector of the radiation along the propagation direction and ω is theangular frequency of oscillation of the radiation.
If E is in keV, the relationship among these quantities is given by:
~ω = hν = E , λν = c
λ = hc/E= (4.1357× 10−15eV · s)(2.9979× 108m/s)/E= 12.398/E in units of A
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 7 / 19
The Classical X-Ray
The classical plane wave representation of x-rays is:
E(r, t) = εEoei(k·r−ωt)
where ε is a unit vector in the direction of the electric field, k is thewavevector of the radiation along the propagation direction and ω is theangular frequency of oscillation of the radiation.If E is in keV, the relationship among these quantities is given by:
~ω = hν = E , λν = c
λ = hc/E= (4.1357× 10−15eV · s)(2.9979× 108m/s)/E= 12.398/E in units of A
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 7 / 19
The Classical X-Ray
The classical plane wave representation of x-rays is:
E(r, t) = εEoei(k·r−ωt)
where ε is a unit vector in the direction of the electric field, k is thewavevector of the radiation along the propagation direction and ω is theangular frequency of oscillation of the radiation.If E is in keV, the relationship among these quantities is given by:
~ω = hν = E , λν = c
λ = hc/E= (4.1357× 10−15eV · s)(2.9979× 108m/s)/E= 12.398/E in units of A
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 7 / 19
Elastic Scattering Geometry
k’
k
Q
an incident x-ray of wave number k
scatters elastically to k′
resulting in a scattering vector Qor in terms of momentum transfer: ~Q = ~k− ~k′
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 8 / 19
Elastic Scattering Geometry
k’
k
Q
an incident x-ray of wave number kscatters elastically to k′
resulting in a scattering vector Qor in terms of momentum transfer: ~Q = ~k− ~k′
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 8 / 19
Elastic Scattering Geometry
k’
k
Q
an incident x-ray of wave number kscatters elastically to k′
resulting in a scattering vector Q
or in terms of momentum transfer: ~Q = ~k− ~k′
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 8 / 19
Elastic Scattering Geometry
k’
k
Q
an incident x-ray of wave number kscatters elastically to k′
resulting in a scattering vector Qor in terms of momentum transfer: ~Q = ~k− ~k′
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 8 / 19
Thomson Scattering
plane wave of x-rays incident on a single electron
total scattered energy ≡ total incoming energyelectron is a point chargescattered intensity ∝ 1/R2
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 9 / 19
Thomson Scattering
plane wave of x-rays incident on a single electrontotal scattered energy ≡ total incoming energy
electron is a point chargescattered intensity ∝ 1/R2
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 9 / 19
Thomson Scattering
plane wave of x-rays incident on a single electrontotal scattered energy ≡ total incoming energyelectron is a point charge
scattered intensity ∝ 1/R2
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 9 / 19
Thomson Scattering
plane wave of x-rays incident on a single electrontotal scattered energy ≡ total incoming energyelectron is a point chargescattered intensity ∝ 1/R2
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 9 / 19
Thomson Scattering
Erad(R, t) = − −e4πε0c2R
ax(t ′) where t ′ = t − R/c
ax(t ′) = − e
mExoe
−iωt′cosψ = − e
mExoe
−iωte iωR/ccosψ
ax(t ′) = − e
mEine
iωR/ccosψ
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 10 / 19
Thomson Scattering
Erad(R, t) = − −e4πε0c2R
ax(t ′) where t ′ = t − R/c
ax(t ′) = − e
mExoe
−iωt′cosψ = − e
mExoe
−iωte iωR/ccosψ
ax(t ′) = − e
mEine
iωR/ccosψ
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 10 / 19
Thomson Scattering
Erad(R, t) = − −e4πε0c2R
ax(t ′) where t ′ = t − R/c
ax(t ′) = − e
mExoe
−iωt′cosψ = − e
mExoe
−iωte iωR/ccosψ
ax(t ′) = − e
mEine
iωR/ccosψ
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 10 / 19
Thomson Scattering
Erad(R, t) = − −e4πε0c2R
−em
EineiωR/ccosψ
Erad(R, t)
Ein= − e2
4πε0mc2e iωR/c
Rcosψ but k = ω/c
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 11 / 19
Thomson Scattering
Erad(R, t) = − −e4πε0c2R
−em
EineiωR/ccosψ
Erad(R, t)
Ein= − e2
4πε0mc2e iωR/c
Rcosψ but k = ω/c
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 11 / 19
Thomson Scattering
Erad(R, t)
Ein= − e2
4πε0mc2e ikR
Rcosψ = −ro
e ikR
Rcosψ
r0 = e2
4πε0mc2= 2.82× 10−5A
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 12 / 19
Scattering Cross-Section
detector of solid angle Ω at a distance R from electron
cross-section of incoming beam = Ao
Cross section of scattered beam (into detector) = R2Ω
IscattIo
=|Erad |2
|Ein|2R2Ω
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 13 / 19
Scattering Cross-Section
detector of solid angle Ω at a distance R from electroncross-section of incoming beam = Ao
Cross section of scattered beam (into detector) = R2Ω
IscattIo
=|Erad |2
|Ein|2R2Ω
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 13 / 19
Scattering Cross-Section
detector of solid angle Ω at a distance R from electroncross-section of incoming beam = Ao
Cross section of scattered beam (into detector) = R2Ω
IscattIo
=|Erad |2
|Ein|2R2Ω
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 13 / 19
Scattering Cross-Section
differential cross-section is obtained by normalizing
dσ
dΩ=
Iscatt(Io/Ao) Ω
=|Erad |2
|Ein|2R2
|Erad |2
|Ein|2= r2o
e ikRe−ikR
R2R2cosψ2
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 14 / 19
Scattering Cross-Section
differential cross-section is obtained by normalizing
dσ
dΩ=
Iscatt(Io/Ao) Ω
=|Erad |2
|Ein|2R2
|Erad |2
|Ein|2= r2o
e ikRe−ikR
R2R2cosψ2
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 14 / 19
Scattering Cross-Section
differential cross-section is obtained by normalizing
dσ
dΩ=
Iscatt(Io/Ao) Ω
=|Erad |2
|Ein|2R2
|Erad |2
|Ein|2= r2o
e ikRe−ikR
R2R2cosψ2
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 14 / 19
Scattering Cross-Section
differential cross-section is obtained by normalizing
|Erad |2
|Ein|2= r2o
e ikRe−ikR
R2R2cosψ2
dσ
dΩ= r2o cos
2ψ
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 15 / 19
Total Cross-Section
σ =8π
3r2o = 0.665× 10−24cm2 = 0.665barn
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 16 / 19
Total Cross-Section
1
Polarization factor = cos2ψ1
2
(1 + cos2ψ
)C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 17 / 19
Atomic Scattering
phase shift arises from scattering off differentportions of extended electron distribution
∆φ(r) = (k− k′) · r = Q · r
r θ
k’
k
Q
θ
|Q| = 2 |k| sinθ = 4πλ sinθ
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 18 / 19
Atomic Scattering
phase shift arises from scattering off differentportions of extended electron distribution
∆φ(r) = (k− k′) · r = Q · r
r θ
k’
k
Q
θ
|Q| = 2 |k| sinθ = 4πλ sinθ
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 18 / 19
Atomic Form Factor
the volume element at r contributes −roρ(r)d3r with phase factor e iQ·r
for an entire atom, integrate to get the atomic form factor f o(Q):
−ro f o(Q) = −ro∫ρ(r)e iQ·rd3r
3000 4000 5000 6000 7000Energy (eV)
f
f
the total atomic scattering factor is
f (Q, ~ω) = f o(Q)+ f ′(~ω)+ if ′′(~ω)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 19 / 19
Atomic Form Factor
the volume element at r contributes −roρ(r)d3r with phase factor e iQ·r
for an entire atom, integrate to get the atomic form factor f o(Q):
−ro f o(Q) = −ro∫ρ(r)e iQ·rd3r
3000 4000 5000 6000 7000Energy (eV)
f
f
the total atomic scattering factor is
f (Q, ~ω) = f o(Q)+ f ′(~ω)+ if ′′(~ω)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 19 / 19
Atomic Form Factor
the volume element at r contributes −roρ(r)d3r with phase factor e iQ·r
for an entire atom, integrate to get the atomic form factor f o(Q):
−ro f o(Q) = −ro∫ρ(r)e iQ·rd3r
3000 4000 5000 6000 7000Energy (eV)
f
f
the total atomic scattering factor is
f (Q, ~ω) = f o(Q)+ f ′(~ω)+ if ′′(~ω)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 19 / 19
Atomic Form Factor
the volume element at r contributes −roρ(r)d3r with phase factor e iQ·r
for an entire atom, integrate to get the atomic form factor f o(Q):
−ro f o(Q) = −ro∫ρ(r)e iQ·rd3r
3000 4000 5000 6000 7000Energy (eV)
f
f
the total atomic scattering factor is
f (Q, ~ω) = f o(Q)+ f ′(~ω)+ if ′′(~ω)
C. Segre (IIT) PHYS 570 - Fall 2010 August 24, 2010 19 / 19